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Dislocation imaging through mapping based on the combination of an electron energy-loss spectroscope with a scanning transmission electron microscope 基于电子能量损失光谱仪和扫描透射电子显微镜组合的映射位错成像
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-07-14 DOI: 10.1080/09500839.2021.1949066
Susumu Yamada
ABSTRACT This study analysed the electronic structures of dislocations in 9Cr steel using a spherical aberration-corrected scanning transmission electron microscope equipped with a monochromated electron energy-loss spectroscope. This is the first study to report that dislocations broaden a zero-loss peak (ZLP) and also induce an absorption phenomenon at approximately 0.5 eV in the ZLP tail, which are interpreted to be related to phonon scatterings by dislocations and interference effect of multiple beams, respectively. This work also experimentally demonstrates that the use of a spectrum-imaging method allows imaging of dislocations through ZLP broadening. The approach proposed herein is a promising technique for detecting dislocations in high Cr steel.
摘要本研究使用配备单色电子能量损失光谱仪的球面像差校正扫描透射电子显微镜分析了9Cr钢中位错的电子结构。这是第一项报道位错加宽零损失峰(ZLP)并在大约0.5处引起吸收现象的研究 ZLP尾部的eV,分别被解释为与位错引起的声子散射和多束干涉效应有关。这项工作还通过实验证明,使用光谱成像方法可以通过ZLP加宽对位错进行成像。本文提出的方法是一种很有前途的检测高铬钢中位错的技术。
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引用次数: 0
Concentration-gradient-driven anisotropic spinodal decomposition kinetics: nitriding of metallic alloys 浓度梯度驱动的各向异性旋多分解动力学:金属合金的氮化
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-07-06 DOI: 10.1080/09500839.2021.1948130
K. Sasidhar, M. Gururajan, S. Meka
ABSTRACT The effect of crystallographically oriented, unidirectional concentration gradients on spinodal decomposition in cubic crystalline solids with elastic and interfacial energy anisotropy is discussed. Phase-field simulations reveal that the kinetics of spinodal decomposition occurring in such systems is dependent on the degree of misorientation between the direction of composition gradient and the preferred crystallographic orientation for growth of spinodal fluctuations; the larger is the misorientation, the slower the kinetics. This phenomenon has been used to explain the well-known grain-orientation-dependent N-uptake kinetics observed during nitriding of metallic alloys. Several plausible causes have been proposed in the literature for the grain-orientation-dependent N-uptake kinetics during nitriding. However, this study reveals that this phenomenon is observed exclusively and without exception in alloy systems having a spinodal instability. The N-uptake kinetics in such systems is known to be dependent on the kinetics of spinodal decomposition. Consequently, anisotropic spinodal decomposition kinetics occurring owing to the presence of a surface-directed N-composition gradient in poly-crystalline metals has been shown to be a more fundamental cause for the phenomenon.
摘要讨论了在具有弹性和界面能各向异性的立方晶体中,晶体取向的单向浓度梯度对旋节分解的影响。相场模拟表明,在这样的系统中发生的旋节分解的动力学取决于组成梯度的方向和旋节波动生长的优选结晶取向之间的取向差的程度;取向差越大,动力学越慢。这一现象已被用来解释在金属合金氮化过程中观察到的众所周知的晶粒取向相关的氮吸收动力学。文献中提出了氮化过程中晶粒取向相关的氮吸收动力学的几个可能原因。然而,这项研究表明,这种现象在具有旋节不稳定性的合金系统中无一例外地被观察到。已知这种系统中的N吸收动力学取决于旋节分解的动力学。因此,由于在多晶金属中存在表面定向的N组成梯度而发生的各向异性旋节分解动力学已被证明是该现象的更根本原因。
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引用次数: 0
Magnetic properties and magnetic phase transition in square-octagon lattice: Monte Carlo study 方八边形晶格的磁性能和磁相变:蒙特卡罗研究
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-07-03 DOI: 10.1080/09500839.2021.1922775
A. Jabar, R. Masrour, M. Hamedoun, A. Benyoussef, A. Hourmatallah, N. Benzakour, A. Rezzouk, K. Bouslykhane, J. Kharbach
ABSTRACT The magnetic properties and magnetic phase transition in square-octagon lattice with mixed spins 3/2 and 5/2 were investigated by Monte Carlo simulations. The ground state phase diagrams of square-octagon structure were obtained under the effect of crystal field and exchange interactions. The thermal partial, total magnetizations and magnetic susceptibilities of square-octagon lattice are obtained for a fixed magnetic parameter. The reduced Néel temperature is noticed. The variation of total magnetizations with the crystal field of square-octagon structure is shown. The magnetic hysteresis cycle of square-octagon structure, with mixed spins S  = 3/2 and σ  = 5/2 for several exchange interactions, temperatures and crystal fields, is found.
摘要用蒙特卡罗模拟方法研究了自旋为3/2和5/2的正方形八边形晶格的磁性能和磁相变。在晶体场和交换相互作用的作用下,得到了方八边形结构的基态相图。在固定的磁参数下,得到了方八边形晶格的热部分磁化率、总磁化率和磁化率。注意到内埃尔温度降低。给出了方八边形结构的总磁化率随晶体场的变化。具有混合自旋S的方形八边形结构的磁滞循环 = 3/2和σ = 发现了几种交换相互作用、温度和晶体场的5/2。
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引用次数: 1
Effects of carbon fibers with different particle sizes on the physical properties of MoS2-filled PTFE composites 不同粒径碳纤维对二硫化钼填充PTFE复合材料物理性能的影响
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-07-03 DOI: 10.1080/09500839.2021.1917780
Ke-wei Zhang, X. Ji, Y. Mi, Lei Gao, Tianyu Wang
ABSTRACT A series of polytetrafluoroethylene (PTFE) composites filled with CF (carbon fiber) and MoS2 (molybdenum disulfide) were prepared by cold-pressing sintering. The tensile strength and elongation at the breakpoint of the samples were measured with a bench-top tensile machine, friction and wear performance were tested with an abrasion machine, and the morphology and microscopic structure were analysed by SEM. The results show that the tensile strength, the elongation at breakage, and the wear resistance were all improved after filling compared to the pure PTFE. The CF/MoS2/PTFE composites filled with CF (particle size 7.498 μm) had the optimal tensile strength and elongation at the breakpoint. Correspondingly, the wear rate was the smallest when the particle size was 23.733 μm.
摘要:采用冷压烧结法制备了CF(碳纤维)和MoS2(二硫化钼)填充的聚四氟乙烯(PTFE)复合材料。用台式拉伸机测试了试样的抗拉强度和断裂伸长率,用磨损机测试了试样的摩擦磨损性能,并用扫描电镜分析了试样的形貌和显微组织。结果表明,与纯PTFE相比,填充后的拉伸强度、断裂伸长率和耐磨性均有提高。以CF(粒径为7.498 μm)填充的CF/MoS2/PTFE复合材料具有最佳的抗拉强度和断裂伸长率。相应地,当粒径为23.733 μm时,磨损率最小。
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引用次数: 5
Lattice expansion and phase stability in nanocrystalline titanium thin films 纳米晶钛薄膜的晶格膨胀和相稳定性
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-06-22 DOI: 10.1080/09500839.2021.1937367
J. Chakraborty
ABSTRACT Crystallite-size-dependent lattice expansion of the hcp Ti phase has been observed by X-ray diffraction of polycrystalline Ti thin films. X-ray line profile analysis (XLPA) revealed a systematic reduction of crystallite size in the hcp Ti phase with decreasing film thickness. Increase of specific volume (i.e. volume/atom) of the hcp Ti phase with decreasing crystallite size has confirmed such lattice expansion. The observed lattice expansion has been simulated using an existing theoretical model after appropriately incorporating a crystallite-size-dependent width of the grain boundaries. It is further revealed that decreasing crystallite size and accompanying lattice expansion leads to lattice instability of the hcp Ti phase and eventually to a hcp-fcc phase transformation of elemental Ti in these thin films as reported earlier by the author.
摘要用X射线衍射方法观察了多晶Ti薄膜中hcp-Ti相的晶粒尺寸相关晶格膨胀。X射线线轮廓分析(XLPA)显示,随着膜厚度的减小,hcp-Ti相中的晶粒尺寸有系统地减小。hcp-Ti相的比体积(即体积/原子)随着晶粒尺寸的减小而增加,证实了这种晶格膨胀。在适当地结合晶粒尺寸相关的晶界宽度之后,已经使用现有的理论模型模拟了观察到的晶格膨胀。进一步揭示了晶粒尺寸的减小和伴随的晶格膨胀导致hcp-Ti相的晶格不稳定性,并最终导致元素Ti在这些薄膜中的hcp-fcc相变,正如作者早些时候报道的那样。
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引用次数: 0
Microstructural and mechanical characterisation of non-equiatomic Al2.1Co0.3Cr0.5FeNi2.1 high-entropy alloy fabricated via wire-arc additive manufacturing 线弧增材制造非等原子Al2.1Co0.3Cr0.5FeNi2.1高熵合金的组织和力学性能
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-06-07 DOI: 10.1080/09500839.2021.1936257
K. Osintsev, S. Konovalov, V. Gromov, I. Panchenko, Y. Ivanov
ABSTRACT Gas metal arc welding based on wire arc additive manufacturing was adopted to fabricate a non-equiatomic Al2.1Co0.3Cr0.5FeNi2.1 thick-walled component. The combined cable wire composed of three filaments with different elemental compositions was used as the feeding material. The microstructure and mechanical properties of the as-deposited component were investigated. The deposited sample consisted of dendrite grains ranging in size from 5 to 15 µm and interdendritic regions. The compressive yield strength and ultimate compressive strength of the obtained material are 550 and 1899 MPa. The microhardness test revealed an average value of 463 HV. The nanohardness and the elastic modulus of the sample are 10.4 and 304 GPa, respectively. Energy-dispersive spectroscopy showed that the elemental distribution in the top, middle, and bottom areas of the sample is uniform. X-ray diffraction analysis revealed two main phases of Al-Ni-Co-rich B2 and Fe-Cr-rich A2 in the material.
摘要采用基于焊丝电弧焊增材制造的气体保护焊方法,制备了非等原子Al2.1Co0.3Cr0.5FeNi2.1厚壁构件。使用由三根不同元素组成的细丝组成的组合电缆线作为馈电材料。研究了沉积态成分的微观结构和力学性能。沉积的样品由尺寸从5到15的枝晶颗粒组成 µm和枝晶间区域。所得材料的抗压屈服强度和极限抗压强度分别为550和1899 MPa。显微硬度测试显示平均值为463HV。样品的纳米硬度和弹性模量分别为10.4和304 GPa。能量色散光谱表明,样品的顶部、中部和底部区域的元素分布均匀。X射线衍射分析揭示了材料中富含Al-Ni-Co的B2和富含Fe-Cr的A2两个主要相。
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引用次数: 10
Stress-induced martensitic transformation in metastable austenite grains during nanoindentation investigation 纳米压痕研究中亚稳奥氏体晶粒应力诱导马氏体转变
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-06-07 DOI: 10.1080/09500839.2021.1936258
B. He, X. Shang
ABSTRACT In general, the formation of martensite in the metastable austenite grains in steels during nanoindentation investigations is believed to be induced by strain as the plastic deformation of austenite takes place prior to the martensitic transformation. However, it is not clear whether the formation of martensite occurs without the prior initiation of plasticity (stress-induced martensitic transformation) during nanoindentation measurement. The present work demonstrates that the martensitic transformation can be triggered during elastic deformation of austenite under an ultralow load when the indenter is close to the annealing twin boundaries. The indentation pressure interacts with the martensite transformation strain, providing the mechanical interaction energy to overcome the nucleation barrier of the martensite embryo. The present work suggests that the annealing twin boundaries can also serve as the nucleation sites of martensite and the stress-induced martensitic transformation is possible during nanoindentation investigation.
一般来说,在纳米压痕研究过程中,在钢的亚稳奥氏体晶粒中马氏体的形成被认为是由应变引起的,因为奥氏体的塑性变形发生在马氏体转变之前。然而,在纳米压痕测量中,马氏体的形成是否在没有塑性(应力诱导马氏体转变)的前提下发生尚不清楚。研究表明,在超低载荷作用下,当压头靠近退火孪晶边界时,奥氏体的弹性变形可触发马氏体相变。压痕压力与马氏体相变应变相互作用,为克服马氏体胚的成核屏障提供了机械相互作用能。本研究表明,退火孪晶界也可以作为马氏体的成核位点,在纳米压痕研究过程中,应力诱导马氏体转变是可能的。
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引用次数: 3
Gibbs energy minimisation model for the austenite-ferrite phase transformation in Fe-C-X-Y alloys Fe-C-X-Y合金奥氏体-铁素体相变的吉布斯能量最小化模型
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-06-03 DOI: 10.1080/09500839.2021.1909166
Alexandre Mathevon, M. Perez, V. Massardier, D. Fabrègue, P. Chantrenne, P. Rocabois
ABSTRACT A new model has been developed to predict austenite ferrite transformation kinetics in steels. For each alloying element, the concentration profile is computed solving a unique diffusion equation (including the 2 phases and the interface). The interface is described assuming linear variation of chemical potentials, saving thus computational time. Interface motion is driven by the minimisation of Gibbs energy. The model naturally reproduces the transition between thermodynamic equilibria (Para equilibrium, Local equilibrium with negligible partitioning, Local equilibrium) during heating. The validity of the model for reverse transformation has been validated on ternary and quaternary systems Fe-C-(Mn-Si-Mo) on decarburisation experiments.
摘要建立了一个预测钢中奥氏体-铁素体转变动力学的新模型。对于每个合金元素,通过求解唯一的扩散方程(包括两相和界面)来计算浓度分布。假设化学势的线性变化来描述界面,从而节省了计算时间。界面运动是由吉布斯能的最小化驱动的。该模型自然地再现了加热过程中热力学平衡(准平衡、可忽略分配的局部平衡、局部平衡)之间的转变。在Fe-C-(Mn-Si-Mo)三元系和四元系脱碳实验中验证了反变换模型的有效性。
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引用次数: 3
Enhanced ferroelectricity for nanoporous barium titanate: a phase-field prediction 纳米多孔钛酸钡的增强铁电性:相场预测
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-06-03 DOI: 10.1080/09500839.2021.1933641
Cheng Xie, He Zhao, L. Du, H. Du, Pingping Wu
ABSTRACT Porous ferroelectric materials show great potential for achieving competitive dielectric/piezoelectric properties with light weight. In this study, a phase-field model was employed to simulate the ferroelectric domain structure evolution of porous barium titanate. It is suggested that the ferroelectric/dielectric/piezoelectric properties are strongly influenced by the porosity level and the size of pores for porous ceramics. It is demonstrated that the ferroelectric switching behaviour, the remnant polarisation, the dielectric constant and the piezoelectric constant are enhanced in nanoporous ferroelectrics with ellipse-shaped pores by introducing mechanisms of symmetry breaking. By providing a means of achieving enhanced properties, nanoporous ferroelectrics with ellipse-shaped pores may have a broad impact on the applications of ferroelectrics and enhance the utility of the materials for selected applications.
多孔铁电材料在实现具有竞争力的介电/压电性能和轻质性能方面显示出巨大的潜力。本研究采用相场模型模拟多孔钛酸钡的铁电畴结构演变过程。结果表明,多孔陶瓷的铁电/介电/压电性能受孔隙率和孔隙尺寸的影响较大。通过引入对称破缺机制,证明了椭圆孔纳米多孔铁电体的铁电开关性能、残余极化、介电常数和压电常数得到了提高。通过提供一种实现增强性能的方法,具有椭圆形孔的纳米多孔铁电体可能对铁电体的应用产生广泛的影响,并在选定的应用中提高材料的实用性。
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引用次数: 5
Alan Lidiard Alan Lidiard
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-05-04 DOI: 10.1080/09500839.2021.1908638
Peter Grout, Richard Catlow, Robin Grimes
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引用次数: 0
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Philosophical Magazine Letters
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