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Drifting plasmons in two-dimensional electron channels: circuit analogy. 二维电子通道中的漂移质子:电路类比。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2023.0312
O Sydoruk

Plasmons in two-dimensional electron channels have potential applications in the terahertz frequency range. Equivalent circuit models provide a convenient framework for analysing the plasmons. This article introduces a circuit model for plasmons in the presence of a dc current that flows in a gated channel. It is shown that drifting plasmons can be described by an LC-transmission line with distributed dependent sources. A circuit analogue of the Dyakonov-Shur instability is demonstrated. Then, a lumped-element transmission line with dependent sources is analysed, and non-reciprocity is demonstrated for examples of a right- and a left-handed transmission line. Effects of ohmic loss are discussed. The results could be used for the design of non-reciprocal transmission line devices. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

二维电子通道中的等离子体在太赫兹频率范围内具有潜在的应用价值。等效电路模型为分析质子提供了方便的框架。本文介绍了在有直流电流流过门控通道时的质子电路模型。研究表明,漂移质子可以用具有分布式依赖源的 LC 传输线来描述。演示了 Dyakonov-Shur 不稳定性的电路模拟。然后,分析了具有从属源的块状元件传输线,并以右手和左手传输线为例演示了非互斥性。还讨论了欧姆损耗的影响。这些结果可用于非互易传输线设备的设计。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题期刊的一部分。
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引用次数: 0
The past, present and future of multi-scale modelling applied to wave-structure interaction in ocean engineering. 海洋工程中波浪与结构相互作用多尺度建模的过去、现在和未来。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2023.0316
V Sriram, Shaswat Saincher, S Yan, Q W Ma

Concepts and evolution of multi-scale modelling from the perspective of wave-structure interaction have been discussed. In this regard, both domain and functional decomposition approaches have come into being. In domain decomposition, the computational domain is spatially segregated to handle the far-field using potential flow models and the near field using Navier-Stokes equations. In functional decomposition, the velocity field is separated into irrotational and rotational parts to facilitate identification of the free surface. These two approaches have been implemented alongside partitioned or monolithic schemes for modelling the structure. The applicability of multi-scale modelling approaches has been established using both mesh-based and meshless schemes. Owing to said diversity in numerical techniques, massively collaborative research has emerged, wherein comparative numerical studies are being carried out to identify shortcomings of developed codes and establish best-practices in numerical modelling. Machine learning is also being applied to handle large-scale ocean engineering problems. This paper reports on the past, present and future research consolidating the contributions made over the past 20 years. Some of these past as well as future research contributions have and shall be actualized through funding from the Newton International Fellowship as the next generation of researchers inherits the present-day expertise in multi-scale modelling. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

从波与结构相互作用的角度讨论了多尺度建模的概念和演变。在这方面,出现了领域分解和功能分解两种方法。在域分解法中,计算域在空间上被分离,利用势流模型处理远场,利用纳维-斯托克斯方程处理近场。在功能分解中,速度场被分为非旋转部分和旋转部分,以方便识别自由表面。这两种方法已与结构建模的分区或整体方案一起实施。多尺度建模方法的适用性已通过基于网格和无网格方案得以确立。由于数值技术的多样性,出现了大规模的合作研究,通过开展比较数值研究,找出已开发代码的不足之处,并确立数值建模的最佳做法。机器学习也被应用于处理大规模海洋工程问题。本文报告了过去、现在和未来的研究情况,总结了过去 20 年来所做的贡献。其中一些过去和未来的研究贡献已经并将通过牛顿国际奖学金的资助得以实现,下一代研究人员将继承当今多尺度建模方面的专业知识。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题刊物的一部分。
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引用次数: 0
A theoretical perspective on solid-state ionic interfaces. 固态离子界面的理论视角。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2023.0313
Javier Carrasco

Solid-state ionic conductors find application across various domains in materials science, particularly showcasing their significance in energy storage and conversion technologies. To effectively utilize these materials in high-performance electrochemical devices, a comprehensive understanding and precise control of charge carriers' distribution and ionic mobility at interfaces are paramount. A major challenge lies in unravelling the atomic-level processes governing ion dynamics within intricate solid and interfacial structures, such as grain boundaries and heterophases. From a theoretical viewpoint, in this Perspective article, my focus is to offer an overview of the current comprehension of key aspects related to solid-state ionic interfaces, with a particular emphasis on solid electrolytes for batteries, while providing a personal critical assessment of recent research advancements. I begin by introducing fundamental concepts for understanding solid-state conductors, such as the classical diffusion model and chemical potential. Subsequently, I delve into the modelling of space-charge regions, which are pivotal for understanding the physicochemical origins of charge redistribution at electrified interfaces. Finally, I discuss modern computational methods, such as density functional theory and machine-learned potentials, which offer invaluable tools for gaining insights into the atomic-scale behaviour of solid-state ionic interfaces, including both ionic mobility and interfacial reactivity aspects. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

固态离子导体在材料科学的各个领域都有应用,特别是在能量存储和转换技术中的重要作用。要在高性能电化学装置中有效利用这些材料,就必须全面了解和精确控制电荷载流子在界面上的分布和离子迁移率。一项重大挑战在于如何揭示离子在晶界和异相等错综复杂的固体和界面结构中的原子级动力学过程。在这篇 "视角 "文章中,我将从理论角度概述目前对固态离子界面相关关键方面的理解,尤其侧重于电池用固态电解质,同时对近期的研究进展进行个人批判性评估。我首先介绍了理解固态导体的基本概念,如经典扩散模型和化学势。随后,我深入探讨了空间电荷区的建模,这对于理解电化界面电荷再分布的物理化学起源至关重要。最后,我将讨论密度泛函理论和机器学习电位等现代计算方法,这些方法为深入了解固态离子界面的原子尺度行为(包括离子迁移性和界面反应性)提供了宝贵的工具。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题期刊的一部分。
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引用次数: 0
Unmanned aerial vehicles equipped with sensor packages to study spatiotemporal variations of air pollutants in industry parks. 无人驾驶飞行器配备传感器包,用于研究工业园区空气污染物的时空变化。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2023.0314
Lang Chen, Xiaobing Pang, Zhentao Wu, Riyang Huang, Junyu Hu, Yi Liu, Lei Zhou, Jue Zhou, Zhiwen Wang

Unmanned aerial vehicles (UAVs) equipped with a miniaturized sensor package were developed for aerial observations, which realizes aerial observations affordable to scientists in atmospheric science and achieves aerial measurements in high spatial resolution. UAVs are deployed to a variety of aerial detecting tasks in different scientific scenarios including chemical industry parks (CIPs) with hazardous gases emissions, and some places difficult for humans to reach. In this study, UAV sensing technology was deployed to detect air pollutants in a suburb, a CIP and a natural gas plant, respectively. The effects of atmospheric conditions such as the atmospheric boundary layer height, long-distance transport and atmospheric stability on the spatiotemporal variations of the air pollutants vertical profiles were investigated by the UAV. The UAV with the sensor package was deployed to capture the methane (CH4) leakages in a natural gas plant. The spatiotemporal variations of CH4 in both vertical and horizontal directions studied by UAV were employed to calculate accurate CH4 emissions, which is crucial to reducing the emissions of greenhouse gases. The low-cost UAV sensing technology for air pollutants was developed by Dr. Xiaobing Pang, who was funded by the Newton Fellowship in 2009 and worked in the University of York. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

无人驾驶飞行器(UAV)配备了微型传感器包,用于空中观测,实现了大气科学科学家可负担得起的空中观测,并实现了高空间分辨率的空中测量。无人机被部署到不同的科学场景中执行各种空中探测任务,包括排放有害气体的化学工业园区(CIPs)和一些人类难以到达的地方。在本研究中,无人机传感技术分别用于探测郊区、化工园区和天然气厂的空气污染物。无人机研究了大气边界层高度、远距离传输和大气稳定性等大气条件对空气污染物垂直剖面时空变化的影响。无人机与传感器包一起部署,用于捕捉天然气厂的甲烷(CH4)泄漏。通过无人机研究 CH4 在垂直和水平方向上的时空变化,计算出准确的 CH4 排放量,这对减少温室气体排放至关重要。低成本无人机空气污染物传感技术是由约克大学庞小兵博士开发的,他于2009年获得了牛顿奖学金的资助。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题刊物的一部分。
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引用次数: 0
Ultra-high-cardinality geometric shaping in the finite SNR regime. 有限信噪比条件下的超高心率几何整形。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2024.0059
Sebastiaan Goossens, Yunus Can Gültekin, Olga Vassilieva, Inwoong Kim, Paparao Palacharla, Chigo Okonkwo, Alex Alvarado

Four-dimensional (4D) constellations with up to 131 072 points (17 bit/4D-sym) are designed for the first time using geometric shaping. The constellations are optimized in terms of mutual information (MI) and generalized MI (GMI) for the additive white Gaussian noise (AWGN) channel, targeting a forward error correction (FEC) rate of 0.8 at finite signal-to-noise ratios. The presented 15-17 bit constellations are currently the highest-performing constellations in the literature, having a gap to the AWGN capacity as low as 0.17 dB (MI) and 0.45 dB (GMI) at 17 bit/4D-sym. For lower cardinalities, our constellations match or closely approach the performance of previously published optimized constellations. We also show that (GMI-)optimized constellations with a symmetry constraint, optimized for a FEC rate of 0.8, perform nearly identical to their unconstrained counterparts for cardinalities above 8 bit/4D-sym. A symmetry constraint for MI-optimized constellations is shown to have a negative impact in general. The proposed procedure relies on a Monte-Carlo-based approach for evaluating performance and is extendable to other (nonlinear) channels. Stochastic gradient descent is used for the optimization algorithm for which the gradients are computed using automatic differentiation. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

利用几何整形技术首次设计了多达 131 072 个点(17 位/4D-sym)的四维(4D)星座。这些星座针对加性白高斯噪声(AWGN)信道的互信息(MI)和广义 MI(GMI)进行了优化,目标是在有限信噪比条件下实现 0.8 的前向纠错(FEC)率。所提出的 15-17 位星座是目前文献中性能最高的星座,在 17 位/4D-sym 时与 AWGN 容量的差距低至 0.17 dB(MI)和 0.45 dB(GMI)。对于较低的心数,我们的星座与之前发布的优化星座性能相当或接近。我们还表明,针对 0.8 的 FEC 速率进行优化的具有对称性约束的(GMI)优化星座,在 8 位/4D-sym 以上的心率下,其性能几乎与无约束的同类星座相同。经 MI 优化的星座对称约束一般会产生负面影响。所提出的程序依靠基于蒙特卡洛的方法来评估性能,并可扩展到其他(非线性)信道。优化算法采用随机梯度下降法,梯度是通过自动微分计算得出的。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题期刊的一部分。
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引用次数: 0
Unlocking the hidden dimension: power of chirality in scientific exploration. 打开隐藏的维度:手性在科学探索中的力量。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2023.0321
Aras Kartouzian, Robert P Cameron

In the boundless landscape of scientific exploration, there exists a hidden, yet easily accessible, dimension that has often not only intrigued and puzzled researchers but also provided the key. This dimension is chirality, the property that describes the handedness of objects. The influence of chirality extends across diverse fields of study from the parity violation in electroweak interactions to the extremely large macroscopic systems such as galaxies. In this opinion piece, we will delve into the power of chirality in scientific exploration by examining some examples that, at different scales, demonstrate its role as a key to a better understanding of our world. Our goal is to incite researchers from all fields to seek, implement and utilize chirality in their research. Going this extra mile might be more rewarding than it seems at first glance, in particular with regard to the increasing demand for new functional materials in response to the contemporary scientific and technological challenges we are facing. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

在无边无际的科学探索中,存在着一个隐秘但又容易获得的维度,它不仅常常令研究人员感到好奇和困惑,而且还提供了一把钥匙。这个维度就是手性,即描述物体手性的属性。手性的影响横跨多个研究领域,从电弱相互作用中的奇偶性违反到星系等超大型宏观系统。在这篇评论文章中,我们将深入探讨手性在科学探索中的力量,研究一些在不同尺度上证明手性是更好地理解我们世界的关键的例子。我们的目标是激励各个领域的研究人员在研究中寻求、实施和利用手性。多走一英里可能会比乍看起来更有收获,尤其是在我们面临当代科技挑战时,对新型功能材料的需求日益增长。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题刊物的一部分。
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引用次数: 0
SU-8-meta-phenylenediamine-conjugated thin film for temperature sensing. 用于温度传感的 SU-8-甲基苯二胺共轭薄膜。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-23 Epub Date: 2024-09-09 DOI: 10.1098/rsta.2023.0322
Hani Barhum, Mohammad Attrash, Inga Brice, Toms Salgals, Madhat Matar, Mariam Amer, Ziad Abdeen, Jānis Alnis, Vjačeslavs Bobrovs, Abdul Muhsen Abdeen, Pavel Ginzburg

Polymers have distinctive optical properties and facile fabrication methods that have been well-established. Therefore, they have immense potential for nanophotonic devices. Here, we demonstrate the temperature-sensing potential of SU8-meta-phenylenediamine (SU8-mPD), produced by epoxy amination of the SU-8 polymer. Its properties were examined through a series of molecular structural techniques and optical methods. Thin layers have demonstrated optical emission and absorption in the visible range around 420 and 520 nm, respectively, alongside a strong thermal responsivity, characterized by the 18 ppm °C-1 expansion coefficient. A photonic chip, comprising a thin 5-10 μm SU8-mPD layer, encased between parallel silver and/or gold thin film mirrors, has been fabricated. When pumped by an external light source, this assembly generates a pronounced fluorescent signal that is superimposed with the Fabry-Pérot (FP) resonant response. The chip undergoes mechanical deformation in response to temperature changes, thereby shifting the FP resonance and encoding temperature information into the fluorescence output spectrum. The time response of the device was estimated to be below 1 s for heating and a few seconds for cooling, opening a new avenue for optical sensing using SU8-based polymers. Thermoresponsive resonant structures, encompassing strong tunable fluorescent properties, can further enrich the functionalities of nanophotonic polymer-based platforms. This article is part of the theme issue 'Celebrating the 15th anniversary of the Royal Society Newton International Fellowship'.

聚合物具有独特的光学特性,其简便的制造方法已得到广泛认可。因此,它们在纳米光子器件方面具有巨大的潜力。在这里,我们展示了 SU8-间苯二胺(SU8-mPD)的温度传感潜力,它是通过环氧胺化 SU-8 聚合物制得的。我们通过一系列分子结构技术和光学方法对其特性进行了研究。薄层分别在 420 纳米和 520 纳米的可见光范围内显示出光学发射和吸收,同时还具有很强的热响应性,其膨胀系数为 18 ppm ℃-1。我们已经制造出一种光子芯片,它由 5-10 μm 的 SU8-mPD 薄层组成,封装在平行的银和/或金薄膜镜之间。当外部光源泵浦时,该组件会产生明显的荧光信号,并与法布里-佩罗(FP)共振响应叠加。芯片会随着温度的变化而发生机械变形,从而移动 FP 共振,并将温度信息编码到荧光输出光谱中。据估计,该装置的加热时间响应低于 1 秒,冷却时间响应低于几秒钟,这为使用 SU8 基聚合物进行光学传感开辟了一条新途径。热致共振结构具有很强的可调荧光特性,可进一步丰富基于纳米聚合物的光子平台的功能。本文是 "庆祝英国皇家学会牛顿国际奖学金 15 周年 "主题期刊的一部分。
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引用次数: 0
Managing the heat: In-Vessel Components. 热管理:舱内组件。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-09 Epub Date: 2024-08-26 DOI: 10.1098/rsta.2023.0408
Jenny Cane, Alan Barth, Jaime Farrington, Ethan Flynn, Simon Kirk, James Lilburne, Zsolt Vizvary

The Spherical Tokamak for Energy Production (STEP) programme aims to deliver a first-of-a-kind fusion prototype powerplant (SPP). The SPP plasma places extreme heat, particle and structural loads onto the plasma-facing components (PFCs) of the divertor, limiters and inboard and outboard sections of the first wall. The PFCs must manage the heat and particle loads and wider powerplant requirements relating to safety, net power generation, tritium breeding and plant availability. To enable STEP PFC concepts to be identified that satisfy these wide-ranging requirements, an iterative design ('Decide & Iterate') methodology has been used to synchronize a prioritized set of decisions, within the fast-paced, iterative, whole plant concept design schedule. This paper details the 'Decide and Iterate' methodology and explains how it has enabled the identification of the SPP PFC concepts. These include innovative PFC solutions such as a helium-cooled discrete and panel limiter design to increase tritium breeding while providing sufficient coverage and enabling individual limiter replacement; the integration of the outboard first wall with the breeding zone to enhance fuel self-sufficiency and power generation; and the use of heavy water (D2O) within the inboard first wall and divertor PFCs to increase tritium breeding within the outboard breeding zone. This article is part of the theme issue 'Delivering Fusion Energy - The Spherical Tokamak for Energy Production (STEP)'.

用于能源生产的球形托卡马克(STEP)计划旨在提供一种首创的聚变原型动力装置(SPP)。SPP 等离子体对分流器、限幅器以及第一壁的内侧和外侧部分的等离子体面组件 (PFC) 造成极大的热量、粒子和结构负荷。PFC 必须能够承受热量和粒子负荷,并满足与安全、净发电量、氚培育和发电厂可用性有关的更广泛的发电厂要求。为了使 STEP PFC 概念能够满足这些广泛的要求,我们采用了一种迭代设计("决定与迭代")方法,在快节奏、迭代的全厂概念设计计划内同步进行一系列优先决策。本文详细介绍了 "决策与迭代 "方法,并解释了该方法如何帮助确定 SPP PFC 概念。其中包括创新的 PFC 解决方案,如氦气冷却的分立和面板限制器设计,以增加氚的孕育,同时提供足够的覆盖范围并实现单个限制器的更换;外侧第一壁与孕育区的整合,以提高燃料自给率和发电量;以及在内侧第一壁和分流器 PFC 中使用重水(D2O),以增加外侧孕育区的氚孕育。本文是 "提供聚变能源--球形托卡马克用于能源生产(STEP)"专题的一部分。
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引用次数: 0
The Spherical Tokamak for Energy Production (STEP) in context: UK public sector approach to fusion energy. 能源生产球形托卡马克(STEP)的背景:英国公共部门对聚变能源的态度。
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-09 Epub Date: 2024-08-26 DOI: 10.1098/rsta.2023.0401
Adam Baker

The UK's fusion energy approach has developed over the past 5 years to include government policy initiatives and a range of public sector investments designed to be delivered in partnership with the private sector. These have aimed to create an environment that stimulates innovation and investment to deliver economic as well as scientific and environmental benefits throughout the lifetime of the public sector fusion energy programme. The Spherical Tokamak for Energy Production acts as a focus and anchor for both public and private sector efforts to develop fusion energy, developing the supply chain and potential for Intellectual Property development and export opportunities well ahead of the anticipated STEP completion date of 2040. This is maximized by the UK's approach to a holistic research and innovation programme backed up by a regulatory and skills programme. This article is part of the theme issue 'Delivering Fusion Energy - The Spherical Tokamak for Energy Production (STEP)'.

在过去的 5 年中,英国的聚变能源方法得到了发展,包括政府政策倡议和一系列旨在与私营部门合作实施的公共部门投资。这些措施旨在创造一个激励创新和投资的环境,以便在公共部门聚变能源计划的整个生命周期内实现经济、科学和环境效益。能源生产球形托卡马克是公共和私营部门开发核聚变能源的重点和支柱,在 STEP 预计的 2040 年竣工日期之前,它就已经开发了供应链和知识产权开发潜力,并提供了出口机会。英国在监管和技能计划的支持下,开展了一项全面的研究和创新计划,从而最大限度地实现了这一目标。本文是 "提供聚变能源--用于能源生产的球形托卡马克(STEP)"专题的一部分。
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引用次数: 0
Controlling a new plasma regime. 控制新的等离子体系统
IF 4.3 3区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-09 Epub Date: 2024-08-26 DOI: 10.1098/rsta.2023.0403
M Lennholm, S Aleiferis, S Bakes, O P Bardsley, M van Berkel, F J Casson, F Chaudry, N J Conway, T C Hender, S S Henderson, B Kool, M Lafferty, H F Meyer, J Mitchell, A Mitra, R Osawa, R Otin, A Parrot, T Thompson, G Xia, The Step Team

Success of the UK's Spherical Tokamak for Energy Production (STEP) programme requires a robust plasma control system. This system has to guide the plasma from initiation to the burning phase, maintain it there, produce the desired fusion power for the desired duration and then terminate the plasma safely. This has to be done in a challenging environment with limited sensors and without overloading plasma-facing components. The plasma parameters and the operational regime in the STEP prototype will be very different from tokamaks, which are presently in operation. During fusion burn, the plasma regime in STEP will be self-organizing, adding further complications to the plasma control system design. This article describes the work to date on the design of individual controllers for plasma shape and position, magneto hydrodynamic instabilities, heat load and fusion power. Having studied 'normal' operation, the article discusses the philosophy of how the system will handle exceptions, when things do not go exactly as planned. This article is part of the theme issue 'Delivering Fusion Energy - The Spherical Tokamak for Energy Production (STEP)'.

英国的球形托卡马克能源生产(STEP)计划要取得成功,需要一个强大的等离子体控制系统。该系统必须引导等离子体从起始阶段进入燃烧阶段,维持等离子体在燃烧阶段的状态,在所需的持续时间内产生所需的聚变功率,然后安全地终止等离子体。这必须在一个传感器有限的挑战性环境中完成,并且不能使面向等离子体的部件超载。STEP 原型的等离子体参数和运行机制与目前运行的托卡马克有很大不同。在聚变燃烧过程中,STEP 中的等离子体状态将是自组织的,从而进一步增加了等离子体控制系统设计的复杂性。本文介绍了迄今为止针对等离子体形状和位置、磁流体力学不稳定性、热负荷和聚变功率的单个控制器的设计工作。在研究了 "正常 "运行之后,文章讨论了系统如何处理异常情况的理念,即当事情没有完全按计划进行时。这篇文章是 "提供聚变能源--球形托卡马克用于能源生产(STEP)"专题的一部分。
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引用次数: 0
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