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Thermal History and Fluid Regime during the Formation of the Eldjurta Biotite Granite Massif (Greater Caucasus): Reconstructions Based on Isotope (δ18O, δD) and Geochemical Data 埃尔德尤尔塔生物花岗岩群(大高加索地区)形成过程中的热历史和流体制度:根据同位素(δ18O、δD)和地球化学数据进行重建
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-17 DOI: 10.1134/S0869591124700140
E. O. Dubinina, A. S. Avdeenko, A. A. Nosova, Yu. N. Chizhova, S. E. Borisovskiy, O. M. Zhilicheva, A. Ya. Dokuchaev

Based on the geochemical and isotopic (δ18О, δD) data, the thermal and fluid conditions during the formation of the Eldjurta granite massif were reconstructed. Analysis of rocks collected from the core of the Tyrnyauz Superdeep Well (TSW) within the depth range of 1427–3923 m revealed their homogeneous isotopic parameters: the δ18O values of bulk samples, quartz, feldspars, and biotite in 12 samples of biotite granites are 8.50 ± 0.33, 9.55 ± 0.22, 8.40 ± 0.33 and 5.45 ± 0.40‰, respectively. The δD values in the biotite vary from −103.3 to −95.6‰. The closure temperatures of the oxygen isotope system of quartz are 440–980°C. The rock cooling history was reconstructed using a new approach based on the analysis of single quartz grains. This approach can be used for detailed reconstructions of thermal history during formation of intrusive bodies. The definite samples were used to demonstrate that Dodson’s equation is valid for description of the δ18O values of quartz in a granite system. The data obtained suggest that the studied part of the massif was formed in at least two almost simultaneous stages. The lower part of the massif was crystallized first, and the second injection of granite melt arrived immediately after the first portion has been crystallized, but had no yet had time to cool significantly. The Tc values in the lower part of the massif indicate the re-opening of the oxygen isotope system of quartz, with subsequent long-term isotope re-equilibration between minerals. This leads to decrease of the observed Tc values and the calculated cooling rates, which is related to increasing volume of the intrusive body and cooling within already heated rocks. Estimates of the isotopic parameters of the water component indicate the absence of exotic water fluid (meteoric or buried waters) during cooling of the massif. The variations of the δ18O values in the minerals of the Eldjurta biotite granites can be described in terms of a simple retrograde exchange at the cooling stage.

根据地球化学和同位素(δ18О、δD)数据,重建了埃尔德尤尔塔花岗岩群形成过程中的热和流体条件。对从 1427-3923 米深度范围内的 Tyrnyauz 超深井(TSW)岩心采集的岩石进行的分析表明,这些岩石具有同质同位素参数:在 12 个生物花岗岩样品中,大块样品、石英、长石和生物花岗岩的 δ18O 值分别为 8.50 ± 0.33、9.55 ± 0.22、8.40 ± 0.33 和 5.45 ± 0.40‰。黑云母的 δD 值在 -103.3 至 -95.6‰ 之间。石英氧同位素系统的闭合温度为 440-980°C。岩石冷却历史的重建采用了一种基于单个石英颗粒分析的新方法。这种方法可用于详细重建侵入体形成过程中的热历史。确定的样品被用来证明多德森方程对描述花岗岩体系中石英的 δ18O 值是有效的。所获得的数据表明,所研究的地块至少是在两个几乎同时的阶段形成的。地块的下部首先结晶,第二股花岗岩熔体在第一部分结晶后立即注入,但尚未来得及明显冷却。地块下部的 Tc 值表明石英的氧同位素系统重新开放,随后矿物之间进行了长期的同位素再平衡。这导致观测到的 Tc 值和计算出的冷却速率下降,这与侵入体体积增大和已加热岩石内部冷却有关。对水成分同位素参数的估计表明,在地块冷却过程中不存在外来水流体(陨石水或埋藏水)。埃尔德尤尔塔生物花岗岩矿物中 δ18O 值的变化可以用冷却阶段的简单逆向交换来描述。
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引用次数: 0
The First Discovery of Archean Dolerite Dikes in the Western Part of the Aldan Shield 在阿尔丹地盾西部地区首次发现阿新纪辉绿岩尖峰
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-17 DOI: 10.1134/S0869591124700152
K. G. Erofeeva, Yu. O. Larionova, A. V. Samsonov

Dolerite dikes were studied in the western part of the Aldan terrane, in the middle reaches of the Tokko River. These dolerite dikes form a swarm of submeridional trend about 1 km wide. The dolerites of the thickest dike preserve their primary textural and structural features and mineral composition: plagioclase + pigeonite + augite + titanomagnetite. Dolerite in the chilled margins and central parts of the dike are homogeneous in composition, corresponds to low-Mg tholeiites, has low contents of Ti and other HFSE, with weak enrichment in light REE and small negative Nb anomalies. Sm–Nd isotope data on magmatic minerals of dolerite from the central part of the dike yield a good linear regression in an isochron diagram that gives to an age of 2510 ± 64 Ma, which probably corresponds to the crystallization age of the basalt. Metadolerites in a thin dike retain plagioclase porphyritic structures, but the pyroxenes are completely replaced by amphibole and chlorite. The metadolerites are contrastingly different in low contents of MgO, Cr, and Ni and in higher contents of TiO2, Fe2O3, P2O5, Nb, and all REE. The differences in the composition of the dikes may be explained by the longterm (about 65%) crystallization differentiation of the initial melt and the emplacement of the residual melt from a shallow intermediate magma chamber via opening cracks. Such conditions probably may have existed in tectonically stable intraplate settings. The age of the dolerites of the dike swarm is comparable to that of the anorogenic granites of the Nelyuki complex (~2.4–2.5 Ga), which are widespread in the western part of Aldan granulite–gneiss terrane. Our data bridge some gaps in characteristics of intraplate anorogenic magmatism that occurred in the western Aldan Shield in the Late Archean and marked the final consolidation of a large block of Archean crust in the Chara–Olekma granite–greenstone area.

摘要 在托克河中游的阿尔丹地层西部研究了辉绿岩堤。这些辉绿岩堤形成了一个宽约 1 公里的潜势群。最厚的辉绿岩堤保留了其主要的纹理和结构特征以及矿物成分:斜长石+白云石+橄榄石+榍石。冷硬边缘和堤坝中央部分的辉绿岩成分均一,属于低镁透辉石,钛和其他高频闪长岩含量较低,轻稀土元素富集较弱,铌负异常较小。来自堤坝中部的辉绿岩岩浆矿物的 Sm-Nd 同位素数据在等时线图中产生了良好的线性回归,得出了 2510 ± 64 Ma 的年龄,这可能与玄武岩的结晶年龄相符。薄堤中的偏闪长岩保留了斜长石斑状结构,但辉石完全被闪石和绿泥石取代。这些辉绿岩在氧化镁、铬和镍的含量较低,而在二氧化钛、三氧化二铁、五氧化二磷、铌和所有稀土元素的含量较高方面存在明显差异。岩钉的成分差异可能是由于初始熔体的长期(约 65%)结晶分异以及残余熔体通过开口裂缝从浅层中间岩浆室移出造成的。这种情况很可能存在于构造稳定的板块内部环境中。堤群中的辉绿岩的年龄与Nelyuki复合体的奥陶系花岗岩的年龄(约2.4-2.5 Ga)相当,后者广泛分布于阿尔丹花岗岩-片麻岩地层的西部。我们的数据弥补了板内阳离子岩浆活动特征方面的一些空白,这些活动发生在晚阿尔歇世阿尔丹地盾西部,标志着Chara-Olekma花岗岩-绿岩地区一大块阿尔歇世地壳的最终整合。
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引用次数: 0
Genesis of Triassic Buziwannan Granites in the West Kunlun Orogen Belt, China: Constraints from in Situ Major, Trace and Sr Isotope Analyses of Plagioclase 中国西昆仑造山带三叠纪布子湾南花岗岩的成因:斜长岩原位主要、微量和锶同位素分析的制约因素
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-17 DOI: 10.1134/S086959112470019X
Lin Wang, Peiwen Chen, Qingdong Zeng, Renchang Mi, Runsheng Han

Buziwannan granodiorite and monzogranite associated with gold–polymetallic mineralization are located in the West Kunlun Orogen Belt in northwest China. Granodiorite was emplaced earlier than monzogranite. To determine the genesis of plagioclase from two intrusions and their relation with mineralization, the major, trace elemental, and Sr isotopic compositions of plagioclase were determined through LA-ICP-MS and LA-MC-ICP-MS respectively. The results indicated that the plagioclase from granodiorite had a high-An (around 40%) core and low-An (around 33%) rim, while the plagioclase from monzogranite was uniform with an An value around 18%. The (87Sr/86Sr)i ratios of plagioclase decreased with decreasing An value, which may be caused by small-scale crustal contamination and/or magma mixing. The crystallization process of plagioclase is mainly accompanied by the exsolution of magmatic H2O, and the pressure changes caused by the loss of magma H2O. These magmatic fluids are rich in ore-forming elements, such as Au–Ag–Cu–Zn, and form skarn mineralization near the wall rocks. Because of the co-crystallization of plagioclase, hornblende, and biotite, as well as the addition of minor felsic magma with lower Sr isotopic composition, the plagioclase from monzogranite exhibits low and uniform An values. In addition, a large amount of magmatic H2O carrying ore-forming elements was released during the emplacement of granodiorite, which caused the monzogranite to lose its metallogenic potential.

摘要 与金多金属矿化有关的布子湾南花岗闪长岩和单斜花岗岩位于中国西北部的西昆仑造山带。花岗闪长岩的成因早于单斜花岗岩。为了确定两个侵入体中斜长岩的成因及其与成矿作用的关系,通过LA-ICP-MS和LA-MC-ICP-MS分别测定了斜长岩的主要元素、微量元素和锶同位素组成。结果表明,花岗闪长岩中的斜长岩具有高An(约40%)核心和低An(约33%)边缘,而单斜长岩中的斜长岩则很均匀,An值约为18%。斜长岩的(87Sr/86Sr)i 比值随 An 值的降低而降低,这可能是小规模地壳污染和/或岩浆混合造成的。斜长石的结晶过程主要伴随着岩浆 H2O 的溶出和岩浆 H2O 损失引起的压力变化。这些岩浆流体富含成矿元素,如金-银-铜-锌,并在壁岩附近形成矽卡岩矿化。由于斜长石、角闪石和斜长石的共晶体化,以及加入了少量 Sr 同位素组成较低的长纤维岩浆,来自单斜长花岗岩的斜长石表现出低而均匀的 An 值。此外,在花岗闪长岩的成岩过程中,大量携带成矿元素的岩浆 H2O 被释放出来,使单斜花岗岩失去了成矿潜力。
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引用次数: 0
Amudzhikan Volcano-Plutonic Association of the Eastern Part of the West-Stanovoy Superterrane (Central Asian Orogenic Belt): Age, Sources, and Tectonic Setting 西-斯坦诺沃伊超断裂带(中亚造山带)东部的阿穆奇坎火山-岩浆岩协会:年龄、来源和构造背景
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-15 DOI: 10.1134/S0869591124700103
A. M. Larin, A. B. Kotov, E. B. Sal’nikova, V. P. Kovach, V. M. Savatenkov, S. D. Velikoslavinskii, N. G. Rizvanova, N. A. Sergeeva, T. M. Skovitina, N. Y. Zagornaya

Geochronological (U-Pb zircon, ID-TIMS), isotope-geochemical (Nd, Sr, Pb), and geochemical studies of rocks of the Amanan and Amudzhikan intrusive complexes and volcanic rocks of the Ukurey Formation in the eastern part of the West Stanovoy superterrane of the Central Asian Orogenic Belt were performed. The assignment of granitoids of these complexes to high-potassium C-type adakites is substantiated. It is established that the studied rocks are cogenetic and can be ascribed to a single Amudzhikan volcano-plutonic association formed in the age range of 133 ± 1–128 ± 1 Ma. The igneous complexes of this association belong to the Stanovoy volcano-plutonic belt, which extends in the sublatitudinal direction from the Pacific Ocean inward the North Asian continent for more than 1000 km, subparallel to the Mongol-Okhotsk suture zone, and assembles the tectonic structures of the Dzhugdzhur-Stanovoy and West-Stanovoy superterranes. The formation of the Stanovoy Belt is related to the closure of the Mongolo-Okhotsk Ocean and the collision between North Asian and Sino-Korean continents at ~140 Ma. The subsequent collapse of the collisional orogen, which was accompanied by large-scale lithospheric extension and delamination of the lower part of the continental lithosphere, led to upwelling of asthenospheric mantle. This caused melting of the lithospheric mantle and continental crust and, as a consequence, the formation of both mafic (shoshonitic) melts and anatectic crustal melts of the adakite type. The mixing of these melts led to the formation of the parental magmas of the Amudzhikan magmatic association. The crustal component in the source was of heterogeneous nature and finally formed as a result of the Early Cretaceous collision event. It is characterized by the upper-crustal isotopic signatures: increased Rb/Sr and U/Pb ratios and a decreased Sm/Nd ratio in the source. The mantle component is represented by enriched lithospheric mantle of the Central Asian Orogenic Belt, the formation of which is associated with subduction processes and closure of the Mongol-Okhotsk paleoocean. Metasomatic transformation of the mantle with the introduction of melts and fluids with isotopic parameters of an EMII-type source or upper crust occurred at this stage.

对中亚造山带西斯坦诺沃伊超断裂带东部的阿曼南和阿姆日干侵入复合体岩石以及乌库列伊地层火山岩进行了地质年代(U-Pb 锆石、ID-TIMS)、同位素地球化学(钕、锶、铅)和地球化学研究。证实了这些复合体的花岗岩属于高钾 C 型阿达克岩。研究结果表明,所研究的岩石是同源的,可归因于形成于 133 ± 1-128 ± 1 Ma 年龄段的单一阿穆奇坎火山-岩浆岩联合体。该联合体的火成岩复合体属于斯坦诺沃伊火山-板岩带,该带从太平洋向北亚大陆的次纵向延伸了1000多公里,与蒙古-奥霍次克缝合带近于平行,并集合了朱格德朱尔-斯坦诺沃伊和西-斯坦诺沃伊超岩体的构造结构。斯坦诺沃伊带的形成与蒙古-奥霍次克洋的关闭以及北亚大陆和中朝大陆在大约 140 Ma 时的碰撞有关。随后的碰撞造山带塌陷伴随着大规模的岩石圈延伸和大陆岩石圈下部的分层,导致了星体层地幔的上涌。这引起了岩石圈地幔和大陆地壳的熔化,并因此形成了黑云母(闪长岩)熔体和安山岩类型的地壳熔体。这些熔体的混合形成了阿姆河岩浆群的母岩浆。岩浆源中的地壳成分具有异质性,最终形成于早白垩世碰撞事件。其特征是上地壳同位素特征:Rb/Sr 和 U/Pb 比值增大,Sm/Nd 比值减小。地幔成分由中亚造山带富集的岩石圈地幔代表,其形成与俯冲过程和蒙古-奥霍次克古海洋的关闭有关。在这一阶段,地幔发生了变质,引入了具有 EMII 型源或上地壳同位素参数的熔体和流体。
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引用次数: 0
Gneisses and Granitoids of the Basement of the Nepa-Botuoba Anteclise: Constraints for Relation of the Archean and Paleoproterozoic Crust in the Boundary Zone between the Tungus Superterrane and Magan Terrane (South Siberian Craton) 尼帕-博图奥巴反斜长岩基底片麻岩和花岗岩:通古斯超岩系和马干地层(南西伯利亚克拉通)边界带的阿新世和古新生代地壳关系的制约因素
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-15 DOI: 10.1134/S0869591124700139
O. M. Turkina, A. V. Plyusnin, T. V. Donskaya, I. V. Afonin, S. S. Sanin

The paper presents geochemical and geochronological data on gneisses and granitoids from three deep boreholes (Yalykskaya-4, Danilovskaya-532, Srednenepskaya-1) in the basement of the southwestern part of the Nepa-Botuoba anteclise. Based on U-Pb zircon dating, three stages of granitoid magmatism were identified: ∼2.8, 2.0 and 1.87 Ga. At ca. 2.8 Ga magmatic TTG protoliths of biotite–amphibole gneisses (Yalykskaya-4 borehole) were formed, these rocks represent the Mesoarchean crust and experienced thermal effects typical of the Tungus superterrane of the Siberian craton at the terminal Neoarchean (∼2.53 Ga). Biotite gneissic granites (∼2.0 Ga) (Danilovskaya-532 borehole), which correlate in age with the granitoids of the basement of the Magan terrane and the Akitkan orogenic belt, were derived from a metasedimentary source formed by the erosion of predominantly Paleoproterozoic juvenile crust rocks. The 1.88 Ga A-type granite (Srednenepskaya-1 borehole) corresponds to the main stage of post-collision granite magmatism within the South Siberian magmatic belt. The ca. 2.8 Ga biotite–amphibole gneisses mark the eastern boundary of the Archean crust with Paleoproterozoic juvenile crust in the south of the Tungus superterrane, which are separated by a transitional zone intruded by granites having intermediate isotopic characteristics. The isotopic composition of Paleoproterozoic gneisses and granitoids indicates that marginal southern Magan terrane in contact with the Tungus superterrane includes blocks of both Archean and Paleoproterozoic crust, thus showing similarity with the Akitkan orogenic belt and accretionary orogens. The final amalgamation of the Tungus superterrane with blocks of the eastern part of the Siberian platform basement corresponds to a milestone of 1.88 Ga.

本文介绍了尼泊尔-博图奥巴反斜长岩西南部基底的三个深钻孔(Yalykskaya-4、Danilovskaya-532 和 Srednenepskaya-1)中片麻岩和花岗岩的地球化学和地球同步学数据。根据 U-Pb 锆石年代测定法,确定了花岗岩岩浆活动的三个阶段:2.8、2.0 和 1.87 Ga。在大约 2.8 Ga 的岩浆 TTG 原岩中形成了黑云母-闪长片麻岩(Yalykskaya-4 号钻孔),这些岩石代表了中新世地壳,并在新元古代末期(∼2.53 Ga)经历了西伯利亚克拉通通古斯超岩带的典型热效应。黑云母片麻岩(2.0 Ga ∼ 2.0 Ga)(Danilovskaya-532 号钻孔)在年龄上与马干地台和阿基坦造山带基底的花岗岩相关联,来自主要由古生代幼壳岩侵蚀形成的变质岩源。1.88 Ga A 型花岗岩(Srednenepskaya-1 号钻孔)与南西伯利亚岩浆带中碰撞后花岗岩岩浆活动的主要阶段相对应。约 2.8 Ga 的生物玢岩2.8Ga的生物玢岩-闪长岩片麻岩标志着通古斯超特异性岩带南部的奥陶纪地壳与古新生代幼生代地壳的东部边界,两者之间由具有中间同位素特征的花岗岩侵入的过渡带分隔。古新生代片麻岩和花岗岩的同位素组成表明,与通古斯超跨接触的马干南部边缘陆相包括阿切安和古新生代地壳区块,从而显示出与阿基坦造山带和增生造山带的相似性。通古斯超岩系与西伯利亚地台基底东部岩块的最终合并,相当于1.88 Ga的里程碑。
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引用次数: 0
Titanium Partitioning between Zircon and Melt: an Experimental Study at High Temperatures 锆石与熔体之间的钛分离:高温下的实验研究
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-15 DOI: 10.1134/S0869591124700085
A. A. Borisov, S. E. Borisovskiy

Experiments on titanium partitioning between zircon and silicate melt were conducted at temperatures 1300 and 1400°С at 1 atm total pressure. Additionally, the Ti content in zircons of a few experimental series from (Borisov and Aranovich, 2019) was measured and a critical analysis of experimental literature was carried out. It was demonstrated that at high temperatures (1200–1450°С) DTi values lie in the range from 0.02 to 0.04 regardless of pressure, melt composition, and water content. Based on obtained data, the impossibility of zircon crystallization from high temperature basic melts once more was shown. It was shown that “Ti in zircon” geothermometer cannot describe Ti content in our experimental zircons and, possibly, cannot be applied to dry high-titanium melts at 1 atm total pressure.

在 1300 和 1400°С 温度和 1 atm 总压下,进行了锆石和硅酸盐熔体之间的钛分配实验。此外,还测量了一些实验系列(Borisov 和 Aranovich,2019 年)中锆石的钛含量,并对实验文献进行了批判性分析。结果表明,在高温(1200-1450°С)条件下,无论压力、熔体成分和含水量如何,DTi 值都在 0.02 至 0.04 之间。根据获得的数据,再次证明了锆石不可能从高温碱性熔体中结晶。结果表明,"锆石中的钛 "地温计无法描述我们实验锆石中的钛含量,也可能无法应用于总压为 1 atm 的干燥高钛熔体。
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引用次数: 0
Three Types of Olivine Crystal Size Distribution in Dunites from the Yoko-Dovyren Layered Massif as Signals of Their Different Crystallization History 横沟-多维连层状块岩中三种类型的橄榄石晶体尺寸分布是其不同结晶历史的信号
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-15 DOI: 10.1134/S0869591124700115
S. N. Sobolev, A. A. Ariskin, G. S. Nikolaev, I. V. Pshenitsyn

Crystal size distributions (CSD) of olivine were obtained for 17 samples of plagiodunite and Pl‑bearing dunite from the central part of the Yoko-Dovyren massif, northern Baikal region, Russia. Three types of CSD were identified: loglinear, bimodal, and lognormal. Combining these data with the results of petrological reconstructions, which earlier revealed two main types of the Dovyren magmas (using the method of geochemical thermometry), we proposed a basic scenario of interaction between magmatic suspensions of different temperature to explain the diversity of the CSD. The intratelluric olivine transported by magmas of different temperature, which had not subjected to abrupt cooling or heating in the chamber, retained an original loglinear CSD. For some portions of the hottest magma (∼1290°C), it is assumed that the original olivine evolved into a bimodal CSD due to accelerated crystallization at faster cooling of the high-temperature injections contacting relatively cold crystal mush (∼1190°C). An interpretation of the lognormal CSD suggests that part of the olivine crystals composing the protocumulate systems efficiently interacted with the pore melt infiltrating upward during the compaction of the underlying crystal mush. This led to cycles of partial dissolution and regrowth of the olivine grains resulting in a final lognormal CSD. The infiltrating hot melt, which was undersaturated with immiscible sulfide liquid, could dissolve sulfides preexisting in the low-temperature mush. This produced dunites with lognormal CSD relatively depleted in sulfur and chalcophile elements. The lognormal CSD is considered to be a marker of crystal mush regions through which the focused infiltration of the pore melt proceeded.

研究人员从俄罗斯贝加尔湖地区北部横-多维连山丘中部的 17 个橄榄石和含铂白云石样本中获得了橄榄石的晶体尺寸分布(CSD)。确定了三种类型的 CSD:对数线性、双峰和对数正态。我们将这些数据与岩石学重建结果(早先利用地球化学测温方法)相结合,发现了多维伦岩浆的两种主要类型,并提出了不同温度的岩浆悬浮物之间相互作用的基本方案,以解释 CSD 的多样性。由不同温度的岩浆运移而来的岩浆内橄榄石,在岩浆室中没有受到骤冷或骤热的影响,保留了原有的对数线性 CSD。对于最热岩浆(1290°C 以下)中的某些部分,假定原始橄榄石演变为双峰 CSD,这是由于高温注入接触相对较冷的晶泥(1190°C 以下)时,在较快冷却过程中加速结晶所致。对数正态 CSD 的解释表明,在压实下层晶泥的过程中,构成原岩体系的部分橄榄石晶体与向上渗透的孔隙熔体有效地相互作用。这导致橄榄石晶粒部分溶解和重新生长的循环,最终形成对数正态 CSD。渗入的热熔体与不溶解的硫化物液体不饱和,可以溶解低温晶泥中预先存在的硫化物。这就产生了对数正态 CSD 的云英岩,硫和亲铝元素相对贫乏。对数正态 CSD 被认为是晶泥区域的标志,孔隙熔体的集中渗入就是通过晶泥区域进行的。
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引用次数: 0
Role of Liquid Immiscibility in the Formation of the Rare Metal Granites of the Katugin Massif, Aldan Shield 液体不溶性在阿尔丹地盾卡图金地块稀有金属花岗岩形成过程中的作用
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-15 DOI: 10.1134/S0869591124700127
E. V. Tolmacheva, S. D. Velikoslavinskii, A. B. Kotov, A. M. Larin, E. V. Sklyarov, D. P. Gladkochub, T. V. Donskaya, T. M. Skovitina, V. P. Kovach, O. L. Galankina

The paper discusses possible immiscibility between fluoride salt (“cryolite”) and silicate liquids into which the parental melt of the Katugin massif exsolves, and the petrological implications of this phenomenon. Results of a detailed study of the cryolite and zircon are presented. Liquid immiscibility is demonstrated to have triggered the massive crystallization of zircon and, together with the processes of subsequent evolution of the cryolite melt, contributed to the formation of the large cryolite bodies. Data on mineral-hosted inclusions were used to estimate the crystallization temperatures of fluoride salt and silicate melts and outline the pathways of their evolution during the formation of the massif. It is shown that the granites of the Katugin and West Katugin massifs were most likely derived from distinct sources, that differed mainly in fluorine content. Data on the chemical composition of three zircon generations identified in the granites of the Katugin massif are presented.

论文讨论了卡图金山地块母熔体溶入的氟化盐("冰晶石")和硅酸盐液体之间可能存在的不溶性,以及这一现象对岩石学的影响。本文介绍了对冰晶石和锆石的详细研究结果。结果表明,液体的不溶性引发了锆石的大量结晶,并与冰晶石熔体的后续演化过程一起,促成了大型冰晶石体的形成。有关矿物包裹体的数据被用来估算氟化盐和硅酸盐熔体的结晶温度,并勾勒出它们在地块形成过程中的演化路径。研究表明,卡图金山和西卡图金山丘的花岗岩很可能来自不同的矿源,它们主要在氟含量上存在差异。本文介绍了在卡图金山地块花岗岩中发现的三代锆石的化学成分数据。
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引用次数: 0
Properties of Fluids during Metasomatic Alteration of Metamorphic Rocks under P–T Conditions of the Middle Crust: An Example from the Bolshie Keivy Region, Belomorian–Lapland Orogen, Fennoscandian Shield 中地壳 P-T 条件下变质岩变质蜕变过程中流体的性质:以芬诺斯堪地盾贝洛莫利亚-拉普兰造山带博尔希-凯维地区为例
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-15 DOI: 10.1134/S0869591124700097
S. A. Bushmin, Y. A. Vapnik, M. V. Ivanov, A. B. Kol’tsov, Y. M. Lebedeva, O. V. Aleksandrovich, E. V. Savva

Properties of fluids under P–T conditions of the middle crust were studied with reference to the metasomatic alteration of metamorphic rocks (amphibolite facies) of the Bolshie Keivy nappe of the Keivy terrane of the Belomorian–Lapland collision orogen of the Fennoscandian shield. Properties of the fluids were studied in five selected types of rocks: metamorphic schists and gneisses with graphite, metasomatic quartz rocks with a high content of graphite, kyanite–quartz veins with wall-rock metasomatites, and metasomatic quartz-bearing kyanite rocks and anchimonomineral quartz veins. NaCl, CaCl2, CO2, N2, CH4, heavier hydrocarbons, and graphite were identified in the fluid inclusions using microthermometry and Raman spectroscopy. Using the method of multiequilibrium thermobarometry for mineral associations and the density of CO2 inclusions, a retrograde P–T path was calculated, which reflects the P–T exhumation history of the rocks. An explanation was proposed for the presence of water inclusions with NaCl of low salinity among inclusions of high salinity with NaCl and CaCl2. Comparison of data on the H2O activity (inferred from mineral equilibria) and salt content (data on fluid inclusions) with those of a model fluid (thermodynamic model of the H2O–NaCl–CaCl2–CO2 system) showed a good agreement between natural and model data. Natural and model data were synthesized to analyze variations in the phase state and chemical composition, fluid properties, including H2O activity, density, and salinity along the retrograde P–T trend.

研究了中地壳 P-T 条件下的流体性质,并参考了芬诺斯康地盾贝洛莫利亚-拉普兰碰撞造山带基维地层博尔希基维岩脉变质岩(闪长岩面)的变质蚀变情况。在五种选定的岩石中研究了流体的性质:含石墨的变质片岩和片麻岩、石墨含量高的变质石英岩、含壁岩变质岩的辉绿岩-石英脉、含辉绿岩的变质石英岩和锚定矿物石英脉。利用微测温和拉曼光谱鉴定了流体包裹体中的 NaCl、CaCl2、CO2、N2、CH4、较重的碳氢化合物和石墨。利用矿物关联的多平衡热压法和二氧化碳包裹体的密度,计算出了一条逆行的 P-T 路径,反映了岩石的 P-T 排泄史。提出了在高盐度的氯化钠和氯化钙包裹体中存在低盐度氯化钠水包裹体的解释。将 H2O 活性数据(根据矿物平衡推断)和盐含量数据(流体包裹体数据)与模型流体数据(H2O-NaCl-CaCl2-CO2 系统热力学模型)进行比较后发现,天然数据与模型数据非常一致。综合自然数据和模型数据,分析了沿逆行 P-T 变化趋势的相态和化学成分、流体性质(包括 H2O 活性、密度和盐度)的变化。
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引用次数: 0
Metamorphosed Ultramafic and Mafic Lithoclasts and Detrital Minerals from Sandstones of Clastic Ophiolitic Deposits of the Rassokha Terrane: A Setting of Formation of the Chersky Range Ophiolites 拉索卡地层碎屑蛇绿岩沉积砂岩中变质的超基性和镁基性岩屑和碎屑矿物:切尔斯基山脉蛇绿岩的形成背景
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-05-27 DOI: 10.1134/S0869591124700048
G. V. Ledneva, B. A. Bazylev, S. N. Sychev, A. V. Rogov

Ophiolite-derived clastic rocks of the Rassokha terrane in the Chersky Range of the Verkhoyansk−Kolyma folded area were studied to obtain representative characteristics of the eroded source metamorphosed ultramafic and mafic rocks, to gain an insight into the possible geodynamic setting in which the protoliths of these rocks were formed, and to identify the possible source of the eroded material. The composition of lithoclasts and detrital minerals of the serpentinite and listwanite sandstones suggests that their source was composed of serpentinite, chloritite, listwanite, and dolomite rocks and that this source was proximal. Prior to the source erosion, the ultramafic and mafic rocks were metamorphosed and recrystallized, listwanite was formed, and the ultramafic rocks were tectonically disintegrated and combined with units of carbonate rocks (dolomite). Ultramafic rocks from lithoclasts experienced allochemical metamorphic retrogression during at least the latest stage of their serpentinization in a nonoceanic setting, where also the listwanite was formed. The Late Neoproterozoic ophiolites of the collisional belt of the Chersky Range were the most probable source for the protoliths of the clastic material. The protoliths of the ophiolite rock were probably formed in a backarc setting. Considered together with the published ages, our data indicate that relics of suprasubduction oceanic lithosphere of the Neoproterozoic basin occurred in the Chersky Range.

摘要 对上霍扬斯克-科雷马褶皱区切尔斯基山脉拉索卡岩系的蛇绿岩衍生碎屑岩进行了研究,以获得侵蚀源变质超基性岩和黑云母岩的代表性特征,深入了解这些岩石原岩形成的可能地球动力环境,并确定侵蚀物质的可能来源。蛇纹石砂岩和鳞片砂岩的岩石碎屑和碎屑矿物成分表明,它们的来源是由蛇纹石、绿泥石、鳞片砂岩和白云石岩石组成的,而且这个来源很近。在岩源侵蚀之前,超基性岩和黑云母岩经过变质和重结晶,形成了鳞片皖石,超基性岩经过构造解体,与碳酸盐岩(白云岩)单元结合在一起。来自碎屑岩的超基性岩至少在其蛇绿岩化的最近阶段经历了分配化学变质逆退,在非大洋环境中也形成了鳞片岩。切尔斯基山脉碰撞带的新近纪晚期蛇绿岩是碎屑物质原岩的最可能来源。蛇绿岩的原岩很可能是在弧后环境中形成的。结合已公布的年龄,我们的数据表明新近纪盆地的超俯冲洋岩石圈遗迹出现在切尔斯基山脉。
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引用次数: 0
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Petrology
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