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Namuaiv Lamprophyre Pipe in the Khibina Massif: Mechanism of Formation and Implications for the Nature of the Mantle Source of Late-Stage Magmatism in the Kola Alkaline Province Khibina地块Namuaiv煌斑岩管:形成机制及其对Kola碱性省晚期岩浆活动幔源性质的启示
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-12 DOI: 10.1134/S0869591125700067
D. R. Shaikhutdinova, L. V. Sazonova, N. M. Lebedeva, A. A. Nosova, A. V. Kargin, A. A. Arzamastsev, V. P. Kovach

This study presents petrographic, major and trace-element, and Sr-Nd isotopic data for rocks from the Namuaiv explosion pipe, which intrudes the Khibina massif in the Kola Alkaline Province (KAP). These rocks record the late stage magmatic event in the KAP’s evolution. The results provide insights into the formation mechanisms of alkaline-ultramafic explosion pipes and constrain the nature of the mantle source during the province’s late magmatic stages. The pipe’s formation involved two distinct lamprophyric magmas—aillikite and monchiquite—as well as associated hydrothermal processes. The initial aillikite magma pulse underwent fluid fragmentation, whereas the subsequent monchiquite magma produced a hybrid rock— monchiquite breccia with aillikite magmaclasts. The fluid phases produced during explosive emplacement of aillikite formed a breccia with a natrolite-rich matrix. Some magmaclasts that were not incorporated into the monchiquite matrix were instead cemented into hydrothermal natrolite breccias. Geochemical and isotopic contrasts between early pre-Khibina lamprophyre dikes (Terskiy Coast)—coeval with alkaline-ultramafic carbonatite massifs—and later dikes and pipes (Khibina massif) suggest a shift in the composition of carbonate-bearing metasomatic assemblages in the mantle source. Early melts involved K-Na amphibole, but this metasomatic phase was exhausted during large-scale melting, leading to source depletion. Late-stage melts were instead derived from a phlogopite-bearing source, formed by metasomatic overprinting of potassium-rich melts generated by incongruent amphibole melting. K-Na amphibole was involved in the generation of the early melts, but this metasomatic phase was exhausted during large-scale melting, leading to source depletion. Instead, late stage melts were derived from a phlogopite-bearing source formed by metasomatic overprinting of the early depleted source. The metasomatic agent was potassium-rich melts derived from incongruent melting of K-Na amphibole.

本文对侵入Kola碱性省Khibina地块的Namuaiv爆炸管岩石进行了岩石学、主量元素、微量元素和Sr-Nd同位素分析。这些岩石记录了KAP演化的晚期岩浆事件。研究结果揭示了本省晚岩浆期碱性-超镁铁质爆炸管的形成机制,约束了本省地幔源的性质。该管道的形成涉及两种不同的煌斑岩岩浆——埃利奇岩和蒙奇基岩——以及相关的热液作用。最初的艾似岩岩浆脉冲经历了流体破碎,而随后的蒙奇盖特岩浆产生了一种混合岩-蒙奇盖特角砾岩与艾似石岩浆浆岩。艾似石爆破就位过程中产生的流体相形成了富含钠云石基质的角砾岩。一些未被溶入monchiquite基质的岩浆岩被胶结成热液钠辉石角砾岩。早期的前希比纳煌斑岩岩脉(Terskiy海岸)与碱性超镁质碳酸盐岩地块同代,以及后期的岩脉和岩管(希比纳地块)的地球化学和同位素对比表明,地幔源区含碳酸盐交代组合的组成发生了转变。早期熔体涉及K-Na角闪孔,但该交代阶段在大规模熔体过程中耗尽,导致源耗竭。晚期熔体则来自含辉云母的矿源,由不一致角闪洞熔化产生的富钾熔体的交代叠印形成。K-Na角闪孔参与了早期熔体的形成,但该交代阶段在大规模熔融过程中耗尽,导致源枯竭。相反,晚期熔体来自早期枯竭源的交代叠印形成的含辉云母源。交代剂为钾钠角闪孔不均匀熔融产生的富钾熔体。
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引用次数: 0
Dynamic Component of Pressure during Metamorphism in a Thrust Zone 逆冲带变质作用中压力的动力分量
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-12 DOI: 10.1134/S0869591125700080
Sh. K. Baltybaev, E. S. Vivdich, O. P. Polyansky, V. G. Sverdlova

Elevated pressure (overpressure) was revealed in the southeastern fragment of the Raahe–Ladoga suture zone in Russia, within the Meyeri tectonic zone. It was caused by structural metamorphic transformations of rocks during collisional interaction of allochthonous and autochthonous blocks. It was supposed that tectonic interaction between the rigid crustal block of the Archean basement of the Karelian craton (autochthon) and the Proterozoic granulite block of the Svecofennian belt (allochthon) provided conditions for the formation of superlithostatic pressure anomalies. Mineral geobarometry and numerical thermomechanical modeling indicated pressures up to 9–11 kbar at a lithostatic pressure of 4–6 kbar. Based on the obtained results, it was argued that the nature of the local superlithostatic pressure (up to 7–9 kbar) established by mineral geobarometry and numerical thermomechanical modeling can be explained by tectonic interaction of blocks with heterogeneous physical and mechanical properties rather than by the errors of the applied mineral geobarometry tools.

在俄罗斯Meyeri构造带内,Raahe-Ladoga缝合带东南段显示高压(超压)。它是由异域块体与原生块体碰撞相互作用过程中岩石的构造变质作用引起的。认为卡累利阿克拉通太古宙基底的刚性地壳块体与斯韦芬尼带元古代麻粒岩块体的构造相互作用为超静岩压力异常的形成提供了条件。矿物地球气压和数值热力学模拟表明,在静岩压力为4-6千巴的情况下,压力高达9-11千巴。在此基础上,本文认为矿物地球压力和数值热力学模拟建立的局部超静岩压力(高达7-9 kbar)的性质可以用具有非均匀物理力学性质的块体的构造相互作用来解释,而不是用矿物地球压力工具的误差来解释。
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引用次数: 0
Basalt Melting in Dry and Hydrous Systems: Thermodynamic Modeling, Parameterization, and Comparison with Experimental Data 玄武岩在干燥和含水系统中的熔融:热力学建模、参数化和与实验数据的比较
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-12 DOI: 10.1134/S0869591125700109
A. V. Sapegina, A. L. Perchuk

Melting of metabasic rocks is a large-scale geologic process contributing to the formation of silicic volcanics and, especially, tonalite–trondhjemite–granodiorite (TTG) complexes, which make up a considerable portion of the ancient continental crust. Based on the phase equilibria modeling using the Perple_X program package, parameterization of melting was conducted for three compositions: anhydrous mid-ocean ridge basalt (MORB), MORB-H2O (2.78 wt % H2O), and hydrated basalt (altered oceanic crust, AOC, 2.78 wt % H2O) at 500–1600°C and 0.0001–3 GPa. The obtained relations show good consistency with limited experimental data and indicate that the volume of melt produced in hydrous systems (MORB-H2O and AOC) increases rapidly (up to 20 vol %) within 20–30°C above the hydrous solidus, which is followed by a more moderate increase in the degree of melting with increasing temperature. The modeling demonstrated that the near-solidus melts of the hydrous systems are rhyolitic and trachydacitic in composition. An increase in the degree of melting results in a decrease in SiO2 and alkalis and an increase in CaO, MgO, and FeO contents. Changes in melt volume and composition are considered in connection with peritectic reactions and variations in H2O content. The application of the parameterization of melting to metabasalts from the downgoing slabs in the Cascadia and Central Aleutian hot subduction zones revealed that these rocks underwent different degrees of melting along respective geotherms, and adakitic magmas are produced by such melting. The proposed parameterization of rock melting is useful for the analysis of the mechanisms of silicic rock formation in different geodynamic environments and can be implemented in the existing petrological and petrological–thermomechanical models.

变质岩的熔融作用是一个大规模的地质过程,形成了硅酸火山岩,特别是闪长岩-闪长岩-花岗闪长岩杂岩,构成了古代大陆地壳的相当一部分。利用Perple_X程序包建立相平衡模型,对500 ~ 1600℃、0.0001 ~ 3 GPa条件下无水洋中脊玄武岩(MORB)、MORB-H2O (2.78 wt % H2O)和含水玄武岩(蚀变洋壳,AOC, 2.78 wt % H2O)进行了熔融参数化。所得关系与有限的实验数据具有良好的一致性,表明在含水固相以上20 - 30°C范围内,含水体系(MORB-H2O和AOC)熔体体积迅速增加(可达20 vol %),随后随着温度的升高,熔体的程度增加较为温和。模拟结果表明,含水体系的近固相熔体主要为流纹岩和粗流质。随着熔融程度的增加,SiO2和碱含量减少,CaO、MgO和FeO含量增加。熔体体积和组成的变化被认为与包晶反应和水含量的变化有关。将熔融参数化方法应用于卡斯卡迪亚和阿留申中部热俯冲带下行板块的变质玄武岩,结果表明,这些岩石沿各自的地热经历了不同程度的熔融,并产生了埃达基岩浆。所提出的岩石熔融参数化有助于分析不同地球动力环境下硅质岩石的形成机制,并可应用于现有的岩石学和岩石热力学模型。
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引用次数: 0
Hybrid Metaandesites of Khangar Volcano, Sredinny Range, Kamchatka: Product of Interaction between Basaltic Magma and Basement Granitoids? 堪察加斯列丁尼山脉坎加尔火山杂化变质岩:玄武岩岩浆与基底花岗岩相互作用的产物?
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-12 DOI: 10.1134/S0869591125700092
M. L. Tolstykh, A. D. Babansky, M. M. Pevzner, Yu. A. Kostitsyn, N. N. Kononkova, L. A. Levitskaya, A. A. Plechova

Unique rocks were found in an outcrop of basement granodiorites in the southern part of the Khangar caldera. The bulk composition of these rocks corresponds to high-Mg andesite (SiO2 57–63 wt %, MgO 4–8 wt %, and K2O 1.4–2 wt %). The rocks contain coexisting quartz, oligoclase, and olivine phenocrysts and a propylitic mineral assemblage (albite, calcite, chlorite, and epidote). The largest phenocrysts are similar in composition to granodiorite minerals (oligoclase An22–28, quartz, and biotite). The olivine phenocrysts contain melt inclusions of basaltic composition (SiO2 45–48 wt %, MgO 7–10 wt %) with a high K2O content (up to 1.6 wt %). We suggest that these rocks were produced by interaction of basaltic melt with silicic intrusive material and with the xenogenic material of the granitoid intrusion.

在Khangar火山口南部的基底花岗闪长岩的露头中发现了独特的岩石。这些岩石的整体组成对应于高镁安山岩(SiO2 57 ~ 63 wt %, MgO 4 ~ 8 wt %, K2O 1.4 ~ 2 wt %)。岩石中含有共存的石英、寡长石和橄榄石斑晶,以及丙质矿物组合(钠长石、方解石、绿泥石和绿帘石)。最大的斑晶在成分上类似于花岗闪长岩矿物(寡晶岩An22-28、石英和黑云母)。橄榄石斑晶含有玄武岩成分的熔融包裹体(SiO2 45-48 wt %, MgO 7-10 wt %), K2O含量高(高达1.6 wt %)。我们认为这些岩石是玄武岩熔体与硅质侵入物和花岗岩类侵入物的异种物质相互作用的产物。
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引用次数: 0
Geochemistry of Metavolcanic Rocks from Northern Ethiopia: Insights for Neoproterozoic Tectonic Setting of Arabian–Nubian Shield 埃塞俄比亚北部变质火山岩地球化学:对阿拉伯-努比亚盾新元古代构造背景的认识
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-08 DOI: 10.1134/S0869591125700225
Misgan Molla, Mulugeta Alene, Takashi Sano, Daniel Meshesha, Hayelom Mengesha, Gebremariam Mesele

Major and trace element data were presented for the Mai Kenetal–Werii metavolcanic rocks within the Arabian–Nubian Shield to examine the petrogenesis and the tectonic setting of the area. Based on field observations and geochemical data, the metavolcanic rocks were classified into basalts, andesites, and dacite-rhyolites. The rocks are dominantly subalkaline (tholeiite to calc-alkaline) in composition. The low contents of Ni (0.1–78 ppm), Co (2–53 ppm), Cr (10–351 ppm), TiO2 (0.18–1.59 wt %), MgO (0.62–9.16 wt %) and relatively with high contents of Al2O3 (10.39–18.51 wt %) indicate that the rocks were formed from more evolved magmas. The chondrite-normalized REE patterns also showed moderate fractionation, with (La/Yb)N values ranging from 2.28 to 9.22, slightly negative to positive Eu anomalies (Eu/Eu*, 0.50–1.16), and relatively flat heavy REEs ((Gd/Yb)N = 0.12–1.79). The rocks display slight enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) relative to high field strength elements (HFSEs), representing rocks that were derived from more evolved magmas in a mature island arc setting. Whereas, the low ratios of Nb/La (0.17–1.66) and Nb/Yb (0.61–2.23), combined with low total REE content (ΣREE = 49.58–151.3 ppm), low Nb content (0.6–6.5 ppm), and high Zr/Nb ratios (20.7–96.67) indicate depleted mantle source. In addition, trace element ratios (Y/Nb = 4.11–15.44, Nb/Y = 0.06–0.24, La/Sc = 0.1–2.67, La/Y = 0.32–1.51 and La/Nb = 2.68–6.23) and discrimination diagrams (Zr/4–2Nb–Y, Th–Hf/3–Ta, and Th–Zr/117–Nb/16), indicate that the metavolcanic rocks have a calc-alkaline affinity that was formed in an island arc tectonic setting from subduction-related magmas within Arabian-Nubian Shield.

本文对阿拉伯-努比亚地盾内的Mai Kenetal-Werii变质火山岩进行了主量元素和微量元素数据分析,探讨了该地区的岩石成因和构造背景。根据野外观测和地球化学资料,将变质火山岩划分为玄武岩、安山岩和英安岩流纹岩。岩石成分主要为亚碱性(拉斑岩-钙碱性)。Ni (0.1 ~ 78 ppm)、Co (2 ~ 53 ppm)、Cr (10 ~ 351 ppm)、TiO2 (0.18 ~ 1.59 wt %)、MgO (0.62 ~ 9.16 wt %)含量较低,Al2O3 (10.39 ~ 18.51 wt %)含量相对较高,表明岩石形成于较演化的岩浆。球粒陨石归一化稀土模式也表现出中等分异,(La/Yb)N值在2.28 ~ 9.22之间,Eu/Eu*值为0.50 ~ 1.16,Eu/Eu*值为负~正,重稀土元素(Gd/Yb)N = 0.12 ~ 1.79)相对平坦。轻稀土元素(lree)和大离子亲石元素(LILEs)相对于高场强元素(hfse)有轻微的富集,表明岩石来源于成熟岛弧环境中较演化的岩浆。低Nb/La(0.17 ~ 1.66)、低Nb/Yb(0.61 ~ 2.23)、低REE含量(ΣREE = 49.58 ~ 151.3 ppm)、低Nb含量(0.6 ~ 6.5 ppm)、高Zr/Nb含量(20.7 ~ 96.67)表明地幔源枯竭。微量元素比值(Y/Nb = 4.11 ~ 15.44, Nb/Y = 0.06 ~ 0.24, La/Sc = 0.1 ~ 2.67, La/Y = 0.32 ~ 1.51, La/Nb = 2.68 ~ 6.23)和鉴别图(Zr/4 ~ 2nb - Y, Th-Hf / 3-Ta, Th-Zr /117 ~ Nb/16)表明,该变质火山岩具有钙碱性亲和力,形成于岛弧构造背景下,由阿拉伯-努比盾内俯冲相关岩浆形成。
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引用次数: 0
Geochronology and Geochemistry of Zhaibeishan Granite and Its Relationship with Copper Deposit in the Eastern Tianshan, NW China 东天山寨北山花岗岩年代学、地球化学特征及其与铜矿床的关系
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-08 DOI: 10.1134/S0869591125700213
Zhiyuan Sun, Tao Yang, Jingyu Zhao, Yonggang Sun, Xinfa Li, Xiaoqiang Zhu

The Zhaibeishan copper deposit is located at the eastern part of Aqishan-Yamansu metallogenic belt in eastern Tianshan. Zircon U-Pb geochronology, major and trace element, and Sr-Nd isotopic characteristics of Zhaibeishan granite and its relationship with mineralization have been studied. SHRIMP zircon U-Pb dating indicates an Early Carboniferous intrusive time (334.5 ± 2.6 Ma) of the granite. Chemically, Zhaibeishan granites have high silica (71.50–75.06%), aluminum (A/CNK = 1.02–1.23), sodium (Na2O/K2O = 0.95–23.83 with 6.89 on average), and total alkalis (Na2O + K2O = 6.65–8.43%), and low magnesium (<1%) and titanium (<1%) contents. The Chondrite-normalized REE patterns are characterized by enrichment of LREE relative to HREE (LaN/YbN = 4.05–6.85) with moderate negative Eu anomalies (δEu = 0.38–0.73). The Zhaibeishan granites show enrichment of K, Rb, (Large Ion Lithophile Elements), LREE and depletion of Nb, Ta, Ti, and P (High Field Strength Elements), indicating island arc magmatic characteristics. Sr-Nd isotopic data reveal that the ISr values range from 0.70473 to 0.70551, while εNd(T) values range from 2.3 to 3.2. We suggest that the Zhaibeishan granites formed in continental arc setting in subduction zone and were probably derived from the product of magma mixing between crust and mantle magmas and experienced subsequent fractional crystallization. Combined with the fluid inclusion and published ore-forming age and isotopic data, we suggest that porphyry mineralization and blind copper orebodies probably exist in the deep part of the Zhaibeishan copper mining area.

寨北山铜矿床位于东天山阿奇山—亚曼苏成矿带的东段。研究了寨北山花岗岩锆石U-Pb年代学、主微量元素、Sr-Nd同位素特征及其与成矿作用的关系。SHRIMP锆石U-Pb测年表明花岗岩的侵入时间为早石炭世(334.5±2.6 Ma)。化学性质上,寨北山花岗岩硅(71.50 ~ 75.06%)、铝(A/CNK = 1.02 ~ 1.23)、钠(Na2O/K2O = 0.95 ~ 23.83,平均6.89)、总碱(Na2O + K2O = 6.65 ~ 8.43%)含量高,镁(<1%)、钛(<1%)含量低。球粒陨石归一化稀土模式的特征是LREE相对于HREE富集(LaN/YbN = 4.05 ~ 6.85), δEu = 0.38 ~ 0.73)呈中等负异常。寨北山花岗岩表现出K、Rb(大离子亲石元素)、LREE富集,Nb、Ta、Ti、P(高场强元素)富集,具有岛弧岩浆特征。Sr-Nd的ISr值为0.70473 ~ 0.70551,εNd(T)值为2.3 ~ 3.2。认为寨北山花岗岩形成于俯冲带的大陆弧背景下,可能是壳幔岩浆混合作用的产物,并经历了随后的分离结晶过程。结合流体包裹体及已公布的成矿年龄和同位素资料,认为寨北山铜矿区深部可能存在斑岩成矿和隐伏铜矿体。
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引用次数: 0
Jadeitite in Metalherzolite of the El’denyr Massif, Chukotka: Mechanism and Setting of Its Formation 楚科奇地区El’denyr地块辉绿岩中的硬玉:形成机制与背景
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-05-30 DOI: 10.1134/S0869591125700055
B. A. Bazylev, G. V. Ledneva

The paper presents the first data on the petrography, mineralogy, and geochemistry of jadeitites from the El’denyr massif, Chukotka, Russia, as well as host metalherzolites and amphibolite inclusions in the jadeitites. The jadeitite is composed of an association of jadeite, omphacite, analcime, and pectolite with a Ba−Ti−Si accessory mineral. The host metalherzolite is made of an association of olivine, antigorite, diopside, chlorite, ferrite-chromite, chromium magnetite, and accessory awaruite, heazlewoodite, and pentlandite. The jadeitite contains inclusions with a relict coarse-grained hypidiomorphic-granular texture, which are considered to be relics of the metasomatized protolith of the jadeitite. This protolith was probably high-temperature hydrothermal diopsidite. The inclusions show local recrystallization of primary diopside to aegirine-augite and pseudomorphic development of a fine-grained aggregate of amphiboles (several generations of richterite, actinolite, magnesiokatophorite, K-richterite, and eckermannite), omphacite, pectolite, analcime, phlogopite, accessory maucherite and heazlewoodite after diopside/aegirine-augite and an associated unidentified mineral. The protolith was transformed in several stages before the onset of jadeite crystallization, and these transformations included metasomatic recrystallization and a complete change in its texture. During the last stage, crystallization of the euhedral concentrically zoned jadeite with analcime and pectolite from fluid was accompanied by the recrystallization and dissolution of the last reworked relics of the protolith represented by high-calcium omphacite in microgranular omphacite-jadeite aggregates of jadeitite. The formation of jadeitites and the accompanying metamorphism of the host lherzolites occurred at 500°C and 8.5 kbar, which corresponds to P–T conditions typical of the metamorphism of mantle wedge peridotites in the “warm” subduction regime. The presence of jadeitites in the El’denyr massif and high-pressure metamorphic rocks in the Ust’-Belaya massif, which were studied previously, allows us to consider the Ust’-Belaya terrane as a mélange of a subduction zone active in the Early–Middle Triassic that was deformed and disintegrated during its subsequent exhumation in the Cretaceous.

本文首次对俄罗斯楚科奇地区El’denyr地块的翡翠岩进行了岩石学、矿物学和地球化学研究,并对翡翠岩中的主辉闪岩和角闪岩包裹体进行了研究。该硬玉是由硬玉、红辉石、钙铝石和榴辉石与Ba - Ti - Si辅助矿物组合而成。主辉钼矿由橄榄石、反长辉石、透辉石、绿泥石、铁氧体铬铁矿、铬磁铁矿和附属辉钼矿、辉钼矿和镍钼矿组成。该翡翠岩包裹体具有残余的粗粒半自形粒状结构,被认为是翡翠岩交代原岩的遗迹。该原岩可能为高温热液透辉石。包裹体显示原生透辉石局部重结晶为艾格辉石,并在透辉石/艾格辉石及伴生不明矿物后发育成细粒角闪石(数代辉辉石、放线石、菱镁铁辉石、钾辉石和角菱辉石)、辉辉石、榴辉石、钙辉石、银辉石、辉辉石、副辉辉石和辉辉石)的假晶状集合体。原岩在翡翠结晶开始前经历了几个阶段的转变,这些转变包括交代再结晶和结构的完全改变。在最后阶段,由流体中钙铝石和胸石组成的自面状同心带硬玉的结晶,伴随着以高钙红辉石为代表的硬玉微粒红辉石-硬石集合体的最后重加工遗迹的再结晶和溶蚀。翡翠岩的形成和寄主橄榄岩的变质作用发生在500℃和8.5 kbar的温度下,符合地幔楔橄榄岩在“温暖”俯冲状态下变质的典型P-T条件。先前研究过的El ' denyr地块中的硬玉岩和Ust ' -Belaya地块中的高压变质岩,使我们能够将Ust ' -Belaya地块视为活动于早-中三叠世的俯冲带的一个分支,在随后的白垩纪挖掘过程中变形和解体。
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引用次数: 0
Volatile Contents During the Formation of Olivinite and Olivine-Monticellite Rocks of the Krestovskaya Alkaline–Ultrabasic Carbonatite Intrusion, Polar Siberia: Pyrolysis-Free Gas Chromatography-Mass Spectrometry Data 极地西伯利亚Krestovskaya碱性-超基性碳酸岩侵入体橄榄石和橄榄石-蒙脱石岩石形成过程中的挥发性成分:无热解气相色谱-质谱数据
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-05-30 DOI: 10.1134/S0869591125700031
L. I. Panina, E. Yu. Rokosova, A. T. Isakova, A. A. Tomilenko, T. A. Bul’bak
<div><p>The parental larnite-normative alkaline ultramafic (kamafugite) melt sequentially forming olivinite and olivine-monticellite rocks of the Krestovskaya alkaline–ultrabasic carbonatite intrusion is enriched with hydrocarbons (HC) and their derivatives, nitrogenated, chlorinated, fluorinated, sulfonated compounds, as well as H<sub>2</sub>O and CO<sub>2</sub> according to pyrolysis-free gas chromatography-mass spectrometry data (GC–MS). The aliphatic, cyclic, oxygenated compounds, and very few heterocyclic compounds are determined among the hydrocarbons. During the crystallization of <i>olivine</i> in olivinites, volatiles are enriched in hydrocarbons (59.30 rel %), excluding nitrogenated, chlorinated, and sulfonated derivatives and including predominant amount of oxygenated compounds (52.17 rel %) and subordinate amount of aliphatic and cyclic compounds (6.70 rel %). During the crystallization of <i>perovskite</i> in olivine-monticellite rocks, the amount of oxygenated hydrocarbons slightly decreases (34.77 rel %) and that of aliphatic and cyclic compounds increases up to 10.55 rel %. The crystallization of <i>monticellite</i> is accompanied by the predominance of aliphatic and cyclic hydrocarbons (59.67 rel %) and subordinate amounts of oxygenated hydrocarbons (29.35 rel %). The calculated H/(O + H) ratio of 0.78 and 0.77 for volatiles in olivine and perovskite, respectively, indicates the reducing conditions of crystallization of these minerals. On the stage of <i>olivine</i> crystallization in olivinite, the volatiles also contain 4.1 rel % of nitrogenated, 4.58 rel % of sulfonated, 0.19 rel % of chlorinated, 0.12 rel % of fluorinated hydrocarbons, 0.49 rel % CO<sub>2</sub>, and 31.17 rel % H<sub>2</sub>O. The crystallization of perovskite in the olivine-monticellite rocks is accompanied by the further accumulation of nitrogenated compounds up to 8.95 rel %, sulfonated (9.53 rel %) and chlorinated (11.33 rel %) hydrocarbons, and 16.48 rel % CO<sub>2</sub>. At this stage, the content of H<sub>2</sub>O in the volatiles decreases to 7.66 rel % due to its binding to cations and Al–Si-radicals of the melt into hydroxyl-bearing compounds. At the final stage of perovskite crystallization and the initial stage of <i>monticellite</i> crystallization, when volatiles were saturated in the critical amounts of chlorinated, nitrogenated, and sulfonated compounds and CO<sub>2</sub>, they become to dissolve in the melt and react with it: most of the considered volatiles, together with Ca and alkalis of the melt, form carbonate–salt compounds and the melt became silicate–salt in composition. According to GC–MS data, a residual gaseous phase of monticellite-hosted inclusions is characterized by only 2.29 rel % nitrogenated and 1.11 rel % sulfonated, 0.32 rel % chlorinated, and 0.35 rel % fluorinated hydrocarbons, 0.04 rel % CO<sub>2</sub> and 6.15 rel % H<sub>2</sub>O at an increase of hydrocarbons up to 89.63 rel %. The crystallization of monticellite was
无热解气相色谱-质谱分析(GC-MS)结果表明,克列斯托夫斯卡亚碱性-超基性碳酸盐侵入体的母岩辉岩-规范碱性超基性碳酸盐(kamafuite)熔体依次形成橄榄石和橄榄石- monticalite岩石,富含烃类(HC)及其衍生物、氮化、氯化、氟化、磺化化合物以及H2O和CO2。在烃类中确定了脂肪族、环状、含氧化合物和很少的杂环化合物。在橄榄石结晶过程中,挥发物主要富集碳氢化合物(59.30 rel %),不包括氮化、氯化和磺化衍生物,主要包括含氧化合物(52.17 rel %)和次要的脂肪族和环状化合物(6.70 rel %)。在橄榄石-蒙长石钙钛矿的结晶过程中,含氧烃含量略有下降(34.77 rel %),而脂肪族和环类化合物含量则上升至10.55 rel %。monticellite的结晶以脂肪族烃和环烃为主(59.67 rel %),含氧烃次之(29.35 rel %)。计算得出橄榄石和钙钛矿中挥发物的H/(O + H)比值分别为0.78和0.77,表明了这两种矿物结晶的还原条件。在橄榄石结晶阶段,挥发物还含有4.1%的氮化、4.58%的磺化、0.19%的氯化、0.12%的氟化烃、0.49%的CO2和31.17%的H2O。钙钛矿在橄榄石-蒙脱石岩石中的结晶过程伴随着氮化物、磺化烃(9.53雷尔%)和氯化烃(11.33雷尔%)以及CO2(16.48雷尔%)的进一步积累。在此阶段,挥发物中H2O的含量下降到7.66 rel %,这是由于它与熔体的阳离子和al - si自由基结合成含羟基化合物。在钙钛矿结晶的最后阶段和monticellite结晶的初始阶段,当挥发物饱和于临界量的氯化、氮化、磺化化合物和CO2中时,它们开始溶解在熔体中并与之反应:大多数被考虑的挥发物与熔体中的Ca和碱一起形成碳酸盐-盐化合物,熔体变成硅酸盐-盐成分。根据GC-MS数据,monticellat包裹体残余气相的特征是只有2.29雷尔%的氮化烃和1.11雷尔%的磺化烃,0.32雷尔%的氯化烃和0.35雷尔%的氟化烃,0.04雷尔%的CO2和6.15雷尔%的H2O,其中碳氢化合物增加到89.63雷尔%。蒙脱石的结晶过程伴随着硅酸盐和盐的不混相,随后是硅酸盐和盐组分的空间分离。
{"title":"Volatile Contents During the Formation of Olivinite and Olivine-Monticellite Rocks of the Krestovskaya Alkaline–Ultrabasic Carbonatite Intrusion, Polar Siberia: Pyrolysis-Free Gas Chromatography-Mass Spectrometry Data","authors":"L. I. Panina,&nbsp;E. Yu. Rokosova,&nbsp;A. T. Isakova,&nbsp;A. A. Tomilenko,&nbsp;T. A. Bul’bak","doi":"10.1134/S0869591125700031","DOIUrl":"10.1134/S0869591125700031","url":null,"abstract":"&lt;div&gt;&lt;p&gt;The parental larnite-normative alkaline ultramafic (kamafugite) melt sequentially forming olivinite and olivine-monticellite rocks of the Krestovskaya alkaline–ultrabasic carbonatite intrusion is enriched with hydrocarbons (HC) and their derivatives, nitrogenated, chlorinated, fluorinated, sulfonated compounds, as well as H&lt;sub&gt;2&lt;/sub&gt;O and CO&lt;sub&gt;2&lt;/sub&gt; according to pyrolysis-free gas chromatography-mass spectrometry data (GC–MS). The aliphatic, cyclic, oxygenated compounds, and very few heterocyclic compounds are determined among the hydrocarbons. During the crystallization of &lt;i&gt;olivine&lt;/i&gt; in olivinites, volatiles are enriched in hydrocarbons (59.30 rel %), excluding nitrogenated, chlorinated, and sulfonated derivatives and including predominant amount of oxygenated compounds (52.17 rel %) and subordinate amount of aliphatic and cyclic compounds (6.70 rel %). During the crystallization of &lt;i&gt;perovskite&lt;/i&gt; in olivine-monticellite rocks, the amount of oxygenated hydrocarbons slightly decreases (34.77 rel %) and that of aliphatic and cyclic compounds increases up to 10.55 rel %. The crystallization of &lt;i&gt;monticellite&lt;/i&gt; is accompanied by the predominance of aliphatic and cyclic hydrocarbons (59.67 rel %) and subordinate amounts of oxygenated hydrocarbons (29.35 rel %). The calculated H/(O + H) ratio of 0.78 and 0.77 for volatiles in olivine and perovskite, respectively, indicates the reducing conditions of crystallization of these minerals. On the stage of &lt;i&gt;olivine&lt;/i&gt; crystallization in olivinite, the volatiles also contain 4.1 rel % of nitrogenated, 4.58 rel % of sulfonated, 0.19 rel % of chlorinated, 0.12 rel % of fluorinated hydrocarbons, 0.49 rel % CO&lt;sub&gt;2&lt;/sub&gt;, and 31.17 rel % H&lt;sub&gt;2&lt;/sub&gt;O. The crystallization of perovskite in the olivine-monticellite rocks is accompanied by the further accumulation of nitrogenated compounds up to 8.95 rel %, sulfonated (9.53 rel %) and chlorinated (11.33 rel %) hydrocarbons, and 16.48 rel % CO&lt;sub&gt;2&lt;/sub&gt;. At this stage, the content of H&lt;sub&gt;2&lt;/sub&gt;O in the volatiles decreases to 7.66 rel % due to its binding to cations and Al–Si-radicals of the melt into hydroxyl-bearing compounds. At the final stage of perovskite crystallization and the initial stage of &lt;i&gt;monticellite&lt;/i&gt; crystallization, when volatiles were saturated in the critical amounts of chlorinated, nitrogenated, and sulfonated compounds and CO&lt;sub&gt;2&lt;/sub&gt;, they become to dissolve in the melt and react with it: most of the considered volatiles, together with Ca and alkalis of the melt, form carbonate–salt compounds and the melt became silicate–salt in composition. According to GC–MS data, a residual gaseous phase of monticellite-hosted inclusions is characterized by only 2.29 rel % nitrogenated and 1.11 rel % sulfonated, 0.32 rel % chlorinated, and 0.35 rel % fluorinated hydrocarbons, 0.04 rel % CO&lt;sub&gt;2&lt;/sub&gt; and 6.15 rel % H&lt;sub&gt;2&lt;/sub&gt;O at an increase of hydrocarbons up to 89.63 rel %. The crystallization of monticellite was","PeriodicalId":20026,"journal":{"name":"Petrology","volume":"33 3","pages":"241 - 252"},"PeriodicalIF":1.1,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Archean Block in the Core of the Paleoproterozoic Lapland-Kola Orogen: New Data on the Composition and Age of Rocks from the Poriya Guba Islands 古元古代拉普兰-科拉造山带核心的太古代地块:波里亚古巴群岛岩石组成和年龄的新资料
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-05-30 DOI: 10.1134/S0869591125700043
A. V. Samsonov, K. G. Erofeeva, O. A. Maksimov, A. V. Stepanova, Yu. O. Larionova

Petrological and geochronological (zircon, U-Th-Pb (LA-ICP-MS)) studies of rocks from the Poriya Guba tectonic mélange exposed on the Ozerchanka and Palenyi islands were carried out to decipher the composition and tectonic history of the Paleoproterozoic Lapland-Kola orogen (LKO). Tonalite–trondhjemite–granodiorite (TTG) (Grt)–CpxOpx gneisses dominate on Ozerchanka Island. They contain numerous bodies of mafic granulites and are intruded by syn- and post-tectonic granitoids. The TTG gneisses are Archean in age (>2.6 Ga, ТNd(DM) = 2.9–3.0 Ga). The HREE depletion in the gneisses indicates that the parental melts of their igneous protoliths were formed in equilibrium with a garnet-bearing residue. Mafic granulite bodies vary widely in geochemistry and likely represent fragments of several Paleoproterozoic mafic intrusions and dikes. Mineral assemblages in the gneisses recorded the early granulite-facies (Т = 780–820°С and Р = 8.6–9.4 kbar) and later amphibolite-facies (Т = 640–650°С and Р = 6.7–7.3 kbar) metamorphic events that occurred at 1.9 Ga according to zircon ages. On Palenyi Island, the banded GrtCpxOpx gneisses are predominant and vary in composition from basaltic andesites to rhyolites. The volcanic protoliths of these rocks have island-arc geochemical signatures, a Paleoproterozoic age of 1958 ± 6 Ma, and juvenile origin (εNd(1960) = +1.7 ÷ +3.1; ТNd(DM) = 2.2–2.3 Ga). These rocks were metamorphosed under the granulite-facies conditions at about 1.9 Ga. Two models can explain the presence of the Archean block in the Poriya Guba tectonic mélange, which is composed of the Paleoproterozoic juvenile island-arc complexes in the core of the LKO. First, this Archean block could represent a single fragment of Archean lithosphere that was separated during Paleoproterozoic continental rifting and opening of the Lapland–Kola ocean and then was tectonically juxtaposed with Paleoproterozoic subduction complexes during the Lapland-Kola collisional orogeny. Second, the Archean block may represent the margin of an adjacent Archean continent exposed in an erosional window within the Paleoproterozoic Poriya Guba tectonic nappe.

通过岩石学和年代学(锆石、U-Th-Pb (LA-ICP-MS))研究,对暴露在Ozerchanka岛和Palenyi岛上的Poriya Guba构造岩体进行了岩石学和年代学研究,揭示了拉普兰-科拉造山带(LKO)的古元古代组成和构造历史。Ozerchanka岛上主要发育闪长闪长(TTG) (Grt) -Cpx-Opx片麻岩。它们含有大量的基性麻粒岩体,并被同构造和后构造花岗岩侵入。TTG片麻岩年龄为太古宙(>2.6 Ga, ТNd(DM) = 2.9 ~ 3.0 Ga)。片麻岩中稀土元素的耗尽表明其火成岩原岩的母熔体与含石榴石的残留物平衡形成。基性麻粒岩在地球化学上的差异很大,可能代表了几种古元古代基性侵入岩和岩脉的碎片。片麻质矿物组合记录了早期麻粒岩相(Т = 780 ~ 820°С和Р = 8.6 ~ 9.4 kbar)和晚期角闪岩相(Т = 640 ~ 650°С和Р = 6.7 ~ 7.3 kbar)变质事件,根据锆石年龄,发生于1.9 Ga。在Palenyi岛上,带状的Grt-Cpx-Opx片麻岩占主导地位,其组成从玄武岩安山岩到流纹岩不等。这些岩石的火山原岩具有岛弧地球化学特征,古元古代年龄为1958±6 Ma,幼年成因(εNd(1960) = +1.7 ÷ +3.1);ТNd(DM) = 2.2-2.3 Ga)。这些岩石在约1.9 Ga的麻粒岩相条件下变质。两种模式可以解释古巴构造区间中太古宙地块的存在,该构造区间是由LKO核心的古元古代幼岛弧杂岩组成的。首先,该太古宙地块可以代表古元古代大陆裂陷和拉普兰-科拉洋开闭期间分离的单一太古宙岩石圈碎片,在构造上与拉普兰-科拉碰撞造山运动期间的古元古代俯冲杂岩并置。其次,太古代地块可能代表了古元古代波里亚古巴构造推覆体中暴露在侵蚀窗口中的相邻太古代大陆的边缘。
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引用次数: 0
Archean Pon’goma-Navolok Granulite–Charnockite–Enderbite Complex, Northern Karelia: Geological Structure, Composition, and Parameters of Formation 卡累利阿北部太古代Pon ' gama - navolok麻粒岩- charnocite - enderbite杂岩:地质构造、组成和形成参数
IF 1.1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-05-30 DOI: 10.1134/S0869591125700018
V. M. Kozlovskii, E. B. Kurdyukov, M. V. Strel’nikov, V. V. Travin, T. F. Zinger, M. A. Golunova, I. S. Volkov, S. A. Ushakova, V. I. Taskaev, A. I. Yakushev

The paper presents original detailed data obtained by the authors on the Archean Pon’goma-Navolok granulite and charnockite massif in northern Karelia: a geological map of the massif and its surroundings, data on the petrography of the magmatic and metamorphic rocks, and the PT parameters evaluated for major rock types by the techniques of multimineral thermomabometry and pseudosections. The Pon’goma-Navolok massif is determined to have formed as two intrusive phases at different crustal levels. The first intrusive phase corresponds to the massif of clinopyroxene–orthopyroxene charno-enderbites that crystallized at 8–11.2 kbar and 730–740°C. The second phase comprises dikes of orthopyroxene–biotite charnockites, which formed at 5.6–6.8 kbar and 830–850°C, and biotite granites, which crystallized at 6.8–7.0 kbar and 730–740°C. The dikes most likely correspond to different temperature and water-activity facies. The charnockites and granites were formed by processes of charnockitization and granitization of the charno-enderbites under the effect of saline aqueous solutions. The granulite-facies metamorphism of the metabasite blocks hosted in the charno-enderbite intrusion was of contact nature and was induced by the thermal effect of the charno-enderbites on the roof and wall rocks of the magma chamber. The high metamorphic temperatures of the metabasites (>900°C) and the absence of migmatization aureoles are explained by low water contents in the enderbites.

本文介绍了作者获得的卡累利阿北部太古代Pon’gama - navolok麻粒岩和绿粒岩地块的原始详细资料:地块及其周围的地质地图,岩浆岩和变质岩的岩石学资料,以及用多矿物测温和伪剖面技术对主要岩石类型进行的P-T参数评价。Pon’gama - navolok地块在不同的地壳水平上形成了两个侵入期。第一侵入期为斜辉石-正辉石charno- ender岩体,结晶温度为730 ~ 740℃,温度为8 ~ 11.2 kbar。第二阶段为正辉石-黑云母沙砾岩岩脉,形成于5.6 ~ 6.8 kbar和830 ~ 850℃,黑云母花岗岩形成于6.8 ~ 7.0 kbar和730 ~ 740℃。这些岩脉很可能对应不同的温度和水活动相。沙砾岩和花岗岩是在盐渍水溶液作用下,由沙砾岩的沙砾石化和花岗岩化作用形成的。辉绿岩体岩体的麻粒岩相变质作用为接触变质作用,是辉绿岩体对岩浆房顶板和围岩的热效应所致。变质岩的高变质温度(>900°C)和没有岩浆岩光晕是由底部低含水量解释的。
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引用次数: 0
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Petrology
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