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Model of the Formation of Monzogabbrodiorite–Syenite–Granitoid Intrusions by the Example of the Akzhailau Massif (Eastern Kazakhstan) 以阿克扎伊劳地块(哈萨克斯坦东部)为例的蒙左闪长岩-闪长岩-花岗岩侵入体形成模型
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S086959112402005X
P. D. Kotler, S. V. Khromykh, A. V. Zakharova, D. V. Semenova, A. V. Kulikova, A. G. Badretdinov, E. I. Mikheev, A. S. Volosov

This paper presents a model of the formation of a multiphase Akzhailau granitoid massif formed within a Caledonian block of the Earth’s crust in the Hercynian time. This work is based on the results of major and trace element composition, geochronological, mineralogical and isotope-geochemical studies. Three stages of the formation of the Akzhailau massif are distinguished, which differ significantly from the previously accepted concepts about the multicomplex and polychronous origin of this intrusion: (1) the formation of moderately alkaline A2-type leuсogranites (308–301 Ma); (2) intrusion of monzodiorites into the base of leucogranites (~295 Ma), increasing degree of partial melting of protoliths with the formation of syenites and moderately alkaline granites of I-type (294–292 Ma); (3) intrusion of dikes and small bodies of alkaline ferroeckermannite A1-type leucogranites in the west and north of massif (~289 Ma). The Akzhailau massif was formed within about 15 Myr in the middle–upper crust through the interaction of plume-related subalkaline basitic magmas with metamorphosed crustal protolith of the orogenic structure.

本文介绍了在海西时代地壳喀里多尼亚区块内形成的多相阿克恰劳花岗岩块的形成模型。这项工作基于主要和微量元素组成、地质年代、矿物学和同位素地球化学研究的结果。阿克扎伊劳地块的形成分为三个阶段,与之前公认的关于该侵入体的多复合和多时间起源的概念大相径庭:(1) 形成中等碱性的 A2 型白花岗岩(308-301Ma);(2) 单斜闪长岩侵入白花岗岩底部(约 295Ma),原岩部分熔化程度增加,形成正长岩和中等碱性的 I 型花岗岩(294-292Ma);(3) 在地块西部和北部侵入尖晶岩和小块碱性铁长斑岩 A1 型白花岗岩(约 289 Ma)。阿克恰劳岩块是在中上地壳约 15 Myr 内,通过与羽状亚碱性玄武质岩浆与造山构造的变质地壳原岩相互作用而形成的。
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引用次数: 0
Genesis of Dunite from the Guli Puton according to Olivine-Hosted Melt Inclusion Data 根据橄榄石寄生熔融包体数据看古力普顿的 Dunite 的成因
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124020061
L. I. Panina, A. T. Isakova, E. Yu. Rokosova

Olivine from the dunite of the Guli pluton crystallized from olivine–melanephelinite magma at temperatures above 1260°C according to the melt inclusion study. The melts were enriched with volatile components (S, CO2, F, H2O, slightly Cl) and contained high amount of incompatible elements. In addition, olivine hosts sporadic inclusions of picrite-basalt composition, which are close to picrite–meimechite melts preserved in chromite from dunite according to literature data. This suggests the influx of picrite–meimechite melts and their mixing with melanephelinite magma during the formation of dunites in the magma chamber. Based on the indicator ratios of incompatible elements, these melts and melanephelinite magma had different sources, which were located in undepleted mantle at different depths and derived through different degree of partial melting.

根据熔融包裹体研究,古里岩体的云英岩中的橄榄石由橄榄石-梅兰橄榄石岩浆在1260°C以上的温度下结晶而成。熔体中富含挥发性成分(S、CO2、F、H2O、少量 Cl),并含有大量不相容元素。此外,橄榄石中还夹杂着零星的闪长岩-玄武岩成分的包裹体,根据文献数据,这些包裹体与白云母铬铁矿中保存的闪长岩-梅氏岩熔体相近。这表明在岩浆室形成云英岩的过程中,闪长岩-梅氏岩熔体流入并与黑云母岩浆混合。根据不相容元素的指标比例,这些熔体和黑云母岩浆有不同的来源,它们位于不同深度的未贫化地幔中,并通过不同程度的部分熔化而得到。
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引用次数: 0
Mineralogical Characteristics and Magmatic Evolution Significance of Garnets in the Late Jurassic Granites in Xingcheng, Eastern North China Craton 华北东部克拉通兴城晚侏罗世花岗岩中石榴石的矿物学特征及其岩浆演化意义
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124020085
Shiyao Gao, Zhongjie Xu, Fufeng Zhao, Ke Cao, Nanyu Tang

A series of Mesozoic granites related to the subduction of the ancient Pacific plate are widely developed in the eastern part of the North China Craton. These granites contain garnet as a minor phase. Garnet records important information such as magma composition, temperature and pressure, and is an important object in the study of petrological evolution of granites. We take the late Jurassic garnet–bearing monzogranite in Xingcheng, Liaoning as the research object, and the magmatic evolution process in the study area is discussed by the in–situ element geochemical variation and the Raman effect of magmatic garnet girdle. It is found that the garnet has a zonation structure in which the contents of MnO and CaO increase and then decrease, while the contents of FeO and MgO decrease and then increase from the core to the edge. Through the simulation of the crystallization sequence of garnet and biotite, it is found that the garnet has “M” type “spessartine bell–shaped profile”, Mn/(Ca + Mg + Fe) value and Mn/Fe value, which reflects that the crystallization pattern of minerals in the magma is dominated by biotite crystallization to garnet crystallization. It is considered that forward and reverse girdle can exist in the same garnet; the separation and crystallization of minerals in the late magmatic evolution is the main reason for the change in the compositional profile of the garnet. This is consistent with the late evolution of granitic magmas in the northeastern of the North China Craton after the late Jurassic.

华北克拉通东部广泛发育着一系列与古太平洋板块俯冲有关的中生代花岗岩。这些花岗岩中含有石榴石这一次要物相。石榴石记录了岩浆成分、温度和压力等重要信息,是研究花岗岩岩石学演化的重要对象。我们以辽宁兴城晚侏罗世含石榴石的单斜花岗岩为研究对象,通过岩浆石榴石腰带的原位元素地球化学变化和拉曼效应,探讨了研究区的岩浆演化过程。研究发现,石榴石具有从核心到边缘MnO和CaO含量先增加后减少,FeO和MgO含量先减少后增加的带状结构。通过模拟石榴石和黑云母的结晶顺序,发现石榴石呈 "M "型 "菱形钟状剖面",Mn/(Ca+Mg+Fe)值和Mn/Fe值,反映了岩浆中矿物的结晶模式是由黑云母结晶到石榴石结晶为主。认为同一石榴石中可能存在正向腰带和反向腰带;岩浆演化后期矿物的分离和结晶是石榴石成分剖面变化的主要原因。这与侏罗纪晚期以后华北克拉通东北部花岗岩岩浆演化的晚期特征是一致的。
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引用次数: 0
Meta-Ultramafic Rocks of the Maksyutov Complex, Southern Urals: High-Pressure Si–Al Metasomatism and Carbonatization at the Crust–Mantle Interface in the Subduction Zone 南乌拉尔马克秀托夫复合体的元超基性岩:俯冲带地壳-地幔界面的高压硅-铝变质作用和碳化作用
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124010065
A. L. Perchuk, N. G. Zinovieva, A. V. Sapegina, P. M. Valizer, V. M. Kozlovsky, V. M. Grigorieva, S. T. Podgornova
<p><b>Abstract</b>—The Maksyutov eclogite–blueschist Complex is characterized by a complicated fold-and-thrust structure that has been formed during the Late Devonian collision between the subducting Baltica margin (East European Plate) and the Magnitogorsk island arc. Eclogites are the most studied rocks of the Complex; their formation and exhumation are usually associated with the collisional stage of the orogen development. At the same time, the origin of meta-ultramafic rocks, which together with eclogites form sheets and boudins within metasedimentary rocks (schists and quartzites), still remains unknown. This paper presents the results of the first detailed petrological study of meta-ultramafic rocks represented by antigorite−chlorite and magnesite−antigorite meta-harzburgites, and chlorite−antigorite metaorthopyroxenite. Mineral compositions and textural relationships between minerals in the meta-harzburgites indicate at least two stages of rock transformations. Minerals of the early mineral paragenesis (first stage)—olivine, accessory chromite, and low-fluorine Ti-clinohumite – have a metamorphic genesis; ultrahigh-pressure (UHP) conditions of their formation are discussed. Partial replacement of olivine by orthopyroxene-bearing parageneses with Cr−Al antigorite and/or high-chromium chlorite is established for the second stage. The phase equilibria modeling using the Perple_X software package demonstrates that formation of antigorite−orthopyroxene paragenesis was associated with Si−Al metasomatism at: <i>T</i> ~ 630°С, <i>P</i> ~ 2 GPa, log<span>({{a}_{{{text{Si}}{{{text{O}}}_{{text{2}}}}}}})</span>  ~ −0.6, log<span>({{a}_{{{text{A}}{{{text{l}}}_{2}}{{{text{O}}}_{3}}}}})</span> ~ −2.5. It is important to note that the mineral paragenesis is highly sensitive to <span>({{a}_{{{text{Si}}{{{text{O}}}_{{text{2}}}}}}})</span>: a slight decrease in log <span>({{a}_{{{text{Si}}{{{text{O}}}_{{text{2}}}}}}})</span> relative to the above value would lead to the growth of olivine with antigorite, and an increase would lead to the growth of orthopyroxene. The latter may explain the formation of meta-orthopyroxenites, which are widely distributed among the meta-ultramafic rocks of the Maksyutov Complex. Similar calculations performed for the range of <span>({{X}_{{{text{C}}{{{text{O}}}_{2}}}}})</span> = 0.01–0.05 in H<sub>2</sub>O–CO<sub>2</sub> fluid showed the replacement of silicate minerals by magnesite under the established thermodynamic conditions. Carbonation and Si−Al metasomatism are specific features of high-pressure transformations of meta-ultramafic rocks, which have not been established in the associated eclogites, quartzites, and shales. Such selective fluid influence on different rock types is interpreted as a result of their different tectono-metamorphic evolution: meta-ultramafic rocks are fragments of the suprasubduction mantle, which were tectonically juxtoposed with the rocks of the subducting plate (eclogites and metasedimentary r
摘要--马克绍托夫斜长岩-蓝斜岩复合体的特征是在晚泥盆世俯冲的波罗的海边缘(东欧板块)与马格尼托哥尔斯克岛弧之间的碰撞过程中形成的复杂的褶皱-推覆构造。斜长岩是研究最多的复合岩;它们的形成和出露通常与造山运动发展的碰撞阶段有关。与此同时,与碎屑岩一起在变质岩(片岩和石英岩)中形成片岩和包岩的元超基性岩的起源仍然未知。本文介绍了对以锑绿泥石和菱镁锑绿泥石元哈尔茨堡岩以及绿泥石-锑绿泥石元黄辉石为代表的元超基性岩进行的首次详细岩石学研究的结果。元哈尔茨堡石的矿物成分和矿物之间的纹理关系表明,岩石转化至少经历了两个阶段。早期矿物副成因(第一阶段)的矿物--橄榄石、附属铬铁矿和低氟钛黝帘石--具有变质成因;讨论了它们形成的超高压(UHP)条件。在第二阶段,橄榄石被含正长石的副橄榄石与铬铝反橄榄石和/或高铬绿泥石部分置换。使用 Perple_X 软件包进行的相平衡建模表明,锑橄榄石-正辉石副成岩作用的形成与硅-铝偏析作用有关,其温度为 T ~ 630°С :T ~ 630°С, P ~ 2 GPa, log({{a}_{text{Si}}{{text{O}}}_{{text{2}}}}}}}) ~ -0.6, log({{a}_{text{A}}{{text{l}}}_{2}}{{text{O}}}_{3}}}}}) ~ -2.5。值得注意的是,矿物成因对 ({{a}_{text{Si}}{{text{O}}}_{text{2}}}}}}})非常敏感:相对于上述值,对数({{a}_{text{Si}}{{text{O}}}_{text{2}}}}}}}) 的轻微下降会导致橄榄石与反橄榄石的生长,而对数({{a}_{text{Si}}{{text{O}}}_{text{2}}}}}}}) 的增加则会导致正辉石的生长。后者可能解释了广泛分布于马科尤托夫岩群的元超基性岩中的元正辉石的形成。在 H2O-CO2 流体中,在 ({{X}_{{text{C}}{{text{O}}}_{2}}}}}) = 0.01-0.05 的范围内进行的类似计算显示,在既定的热力学条件下,硅酸盐矿物被菱镁矿取代。碳化和Si-Al变质作用是元奥陶系岩石高压转化的具体特征,而在相关的辉绿岩、石英岩和页岩中尚未得到证实。流体对不同岩石类型的这种选择性影响被解释为它们不同的构造-变质演化的结果:元超基性岩是超俯冲地幔的碎片,在构造上与俯冲板块的岩石(斜长岩和变质岩)并置。
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引用次数: 0
Chlorine Solubility in Silicate Melts: New Experiments and Thermodynamic Mixing Model 氯在硅酸盐熔体中的溶解度:新实验和热力学混合模型
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124010028
L. Y. Aranovich, M. A. Golunova, J. A. D. Connolly, M. V. Ivanov

We present new experimental data on Cl solubility in model basalt melts of eutectic compositions diopside (Di)–albite (Ab) and Di–anorthite ± quartz (Qtz). The starting glasses were equilibrated with aqueous NaCl–CaCl2 fluid at 4 kbar in the temperature range of 900–1200°C. The experiments show that Cl solubility decreases with increasing NaCl in the fluid. Ca–Na partitioning between melts and fluid is weekly temperature dependent and resembles that of the plagioclase–fluid system. The newly obtained experimental data, along with previously published results on the model granite melting in the presence of (Na,K)Cl brines (Aranovich et al., 2013), are used to calibrate an empirical thermodynamic model for salt species (NaCl, KCl, and CaCl2) in silicate melt. Calculations show that Cl solubility in haplogranite melt decreases with increasing K/Na ratio in the fluid (and correspondingly, melt). The data acquired on Ca and Na partitioning between melt and fluid make it possible to model the evolution of the Ca/Na ratio in the crystallization course of basalt melts. At a high pressure (10 kbar), Cl solubility in model granite increases with increasing Н2О content. The calculated phase diagram for a simple pseudo-ternary system Ab–H2O–NaCl demonstrates complex phase relations and, correspondingly, evolution of the Н2О and NaCl concentrations in the melt. This complex evolution is illustrated by data on the composition of quartz-hosted melt and fluid inclusions from granites in the Verkhneurmisskii massif in the Badzhal volcano-plutonic zone.

摘要 我们提供了关于Cl在共晶成分透辉石(Di)-橄榄石(Ab)和透辉石±石英(Qtz)模型玄武岩熔体中溶解度的新实验数据。在 900-1200°C 的温度范围内,用 NaCl-CaCl2 水溶液在 4 千巴条件下平衡起始玻璃。实验表明,随着流体中 NaCl 的增加,Cl 的溶解度会降低。熔体和流体之间的钙呐分配每周都与温度有关,与斜长石-流体系统相似。新获得的实验数据与之前发表的关于存在(Na,K)Cl 盐水的花岗岩熔融模型结果(Aranovich 等人,2013 年)一起,用于校准硅酸盐熔体中盐物种(NaCl、KCl 和 CaCl2)的经验热力学模型。计算结果表明,随着流体(以及相应的熔体)中 K/Na 比率的增加,Cl 在单斜体熔体中的溶解度降低。根据获得的熔体和流体中 Ca 和 Na 的分配数据,可以模拟玄武岩熔体结晶过程中 Ca/Na 比率的演变。在高压(10 千巴)下,Cl 在模型花岗岩中的溶解度随着 Н2О 含量的增加而增加。计算得到的简单伪三元体系 Ab-H2O-NaCl 的相图显示了复杂的相关系,并相应地显示了熔体中 Н2О 和 NaCl 浓度的演变。巴德扎尔火山-岩浆岩带 Verkhneurmisskii 地块花岗岩中石英托管熔体和流体包裹体的成分数据说明了这种复杂的演变。
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引用次数: 0
The Potential Role of Sulfur during Granulite-facies Metamorphism, Oxidation, and Geochemical Transformation of the Granitoid Lower Crust 硫在花岗岩期变质、氧化和花岗岩下壳地球化学转变过程中的潜在作用
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124010041
Daniel E. Harlov

The role of S during high-grade metamorphism is a topic that has not garnered much interest in the literature until recently. In this review, the role of S as an active component in high grade hypersaline fluids is reviewed per a series of regional studies involving orthopyroxene-bearing granulite-facies granitoids. These include the Shevaroy Block and Nilgiri Block, southern India; the Bamble Sector, southwest Norway; the Val Strona traverse of the Ivrea-Verbano Zone, northern Italy; and the Lewisian Complex, northwest Scotland. In each these terranes, S-bearing, high-grade, low H2O activity fluids are conjectured to have been present during granulite-facies metamorphism and to have contributed to the dehydration of the rock, the oxidation state of the rock, and trace element mobility, leaving behind pyrite and/or pyrrhotite as traces of its presence. The various mineral equilibria reactions between the various oxidation states of S in these fluids and the oxide and silicate minerals encountered by the fluid are explored and a coherent framework of interdependent chemical reactions are developed, which describe both oxidation of the rock and the formation of pyrite and pyrrhotite during both peak- and post-peak metamorphism.

摘要 S在高品位变质过程中的作用是一个直到最近才在文献中引起广泛关注的话题。在这篇综述中,通过一系列涉及含正辉石花岗岩成因花岗岩的区域研究,对S作为高品位超盐流体中活性成分的作用进行了综述。这些地区包括印度南部的谢瓦洛伊区块和尼尔吉里区块、挪威西南部的班布尔区块、意大利北部伊夫雷亚-韦尔巴诺区的瓦尔斯特罗纳横断面以及苏格兰西北部的刘易斯岩群。据推测,在这些地层中,花岗岩成因变质过程中都存在含 S 的高品位、低 H2O 活性流体,这些流体对岩石的脱水、岩石的氧化状态和微量元素的流动性起到了作用,并留下了黄铁矿和/或黄铁矿的痕迹。研究探讨了这些流体中各种氧化态的 S 与流体中遇到的氧化物和硅酸盐矿物之间的各种矿物平衡反应,并建立了一个相互依存的化学反应的连贯框架,该框架描述了高峰变质和后高峰变质过程中岩石的氧化以及黄铁矿和黄铁矿的形成。
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引用次数: 0
“In the Wake of a Big Ship”: The Sailing Must Go on! "在大船的后面":航行必须继续
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124010107
L.Ya. Aranovich
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引用次数: 0
Metasomatism in the Precambrian Crust of the Siberian Craton: Results of a Study of Garnet(±Orthopyroxene)–Biotite–Feldspar Xenolith Rocks from Yubileinaya and Sytykanskaya Kimberlite Pipes, Yakutia 西伯利亚克拉通前寒武纪地壳中的变质作用:来自雅库特 Yubileinaya 和 Sytykanskaya 金伯利岩岩坑的石榴石(± 奥陶斜长石)-生物长石异长岩的研究结果
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124010090
N. E. Seliutina, O. G. Safonov, V. O. Yapaskurt, D. A. Varlamov, I. S. Sharygin, K. M. Konstantinov, V. M. Kozlovskiy

Xenoliths in kimberlites are the most promising material for studying the composition and structure of the lower levels of the continental crust. This study is aimed at the estimation of P–T parameters and fluid regime of metamorphism for garnet–biotite–feldspar and orthopyroxene–garnet–biotite–feldspar rocks found as xenoliths in kimberlites of the Yubileynaya and Sytykanskaya pipes, Yakutian kimberlite province. The seven studied samples show inverse dependences of relative contents of garnet and orthopyroxene, orthopyroxene and biotite, garnet and plagioclase, plagioclase and potassium feldspar. This indicates a consistent series of transformations of the assemblage garnet + plagioclase + orthopyroxene ± quartz to the assemblage garnet + biotite + potassium feldspar. In this process, the replacement of plagioclase by potassium feldspar was the leading reaction. Evidence of this reaction is specific reaction textures in the rocks, negative correlations between the contents of the minerals, and petrochemical characteristics of the rocks. Modeling of the mineral assemblages of the xenoliths using the pseudosection approach (PERPLE_X) revealed two groups of rocks corresponding to different depth levels of the Siberian cratonic crust. For rocks without orthopyroxene or with this mineral as single relics, the pressure was estimated at 9.5–10 kbar, and it is 6–7 kbar for orthopyroxene-bearing samples. The xenolith rocks have close metamorphic peak temperatures of 750–800°C. They experienced 200–250°C cooling and 3–4 kbar decompression, regardless of the level of the crust at which they had initially occurred. This indicates that the metamorphic evolution of the rocks during their exhumation was probably associated with collisional processes during the amalgamation of individual terrains of the Siberian craton. Xenoliths enriched in K-feldspar might have been products of metamorphic reactions with participation of aqueous–(carbonic)–salt fluids, which were sourced from basaltic magmas in the lower crust. The most strongly metasomatized rocks were located closest to the place of accumulation of crystallizing magmas.

摘要 金伯利岩中的闪长岩是研究大陆地壳低层组成和结构的最有前途的材料。本研究旨在估算在雅库特金伯利岩区 Yubileynaya 和 Sytykanskaya 管道的金伯利岩中发现的石榴石-生物长石和正长石-石榴石-生物长石异长岩的 P-T 参数和变质流体机制。所研究的七个样本显示了石榴石和正长石、正长石和斜长石、石榴石和斜长石、斜长石和钾长石相对含量的反比关系。这表明石榴石+斜长石+正长石±石英组合到石榴石+斜长石+钾长石组合的一系列转化过程是一致的。在这一过程中,钾长石取代斜长石是最主要的反应。这种反应的证据是岩石中特定的反应纹理、矿物含量之间的负相关以及岩石的石油化学特征。利用假吸积法(PERPLE_X)建立的岩石矿物组合模型显示,有两组岩石对应于西伯利亚板块地壳的不同深度。对于不含正辉石或只含正辉石的岩石,压力估计为 9.5-10 千巴,而对于含正辉石的样品,压力估计为 6-7 千巴。异质岩的变质峰值温度接近 750-800°C。它们经历了 200-250°C 的冷却和 3-4 千巴的减压,与最初发生的地壳水平无关。这表明,这些岩石在出露过程中的变质演化可能与西伯利亚陨石坑各个地形汞齐化过程中的碰撞过程有关。富含钾长石的异长岩可能是变质反应的产物,其中有来自下地壳玄武质岩浆的含水(碳酸)盐类流体的参与。变质作用最强烈的岩石位于最靠近岩浆结晶聚集地的地方。
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引用次数: 0
Separation of Salts NaCl and CaCl2 in Aqueous-Carbon Dioxide Deep Fluids 水二氧化碳深层流体中 NaCl 和 CaCl2 的分离
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124020036
M. V. Ivanov, S. A. Bushmin

The possibility of changing the ratio of the concentrations of NaCl and CaCl2 salts in fluid phases formed as a result of heterogenization of the H2O–CO2–NaCl–CaCl2 fluid with a decrease in P-T parameters has been studied. A well-known experimental fact regarding the ternary systems H2O–CO2–NaCl and H2O–CO2–CaCl2 is the greater tendency of the H2O–CO2–CaCl2 system to separate into coexisting predominantly aqueous-salt and aqueous-carbon dioxide phases compared to the similar system H2O–CO2–NaCl. This experimental fact can be interpreted as a greater affinity of NaCl for CO2 compared to CaCl2. Using a recently developed numerical thermodynamic model of the H2O–CO2–NaCl–CaCl2 quaternary fluid system, it was possible to identify geologically significant consequences of this difference in the interaction of NaCl and CaCl2 with CO2. Multistage heterogenization of the H2O–CO2–NaCl–CaCl2 fluid with a significant decrease in P-T parameters ultimately leads to the formation of aqueous-carbon dioxide fluid phase f2, the salt component of which is significantly enriched in NaCl and depleted in CaCl2 compared to the initial fluid. The fluid phase f1 formed at each stage of heterogenization has a predominantly water-salt composition with the ratio of the mole fractions of NaCl and CaCl2 salts, differing little from that in the initial fluid. However, the total mole fraction of salt in the f1 phase, as a rule, significantly exceeds that in the original fluid. The density of phase f1 significantly exceeds the density of phase f2. During the process of multistage heterogenization of the fluid phase f1, there is no formation of a fluid with a significant enrichment of CaCl2 compared to the initial ratio of the mole fractions of NaCl and CaCl2. At the same time, successive multiple separation of the f2 phase leads to the enrichment of its salt component in NaCl. Under favorable conditions, this process can lead to the formation of a fluid with almost pure NaCl salt. Changes in the salt composition of the fluid H2O–CO2–NaCl–CaCl2 are considered in application to the evolution of fluid composition along the regressive branch of the P-T trend of HP metamorphism and syngranulite metasomatism in the Lapland granulite belt.

我们研究了改变 H2O-CO2-NaCl-CaCl2 流体异质化后形成的流体相中 NaCl 和 CaCl2 盐浓度比例的可能性,同时降低了 P-T 参数。关于 H2O-CO2-NaCl 和 H2O-CO2-CaCl2 三元体系的一个众所周知的实验事实是,与类似的 H2O-CO2-NaCl 体系相比,H2O-CO2-CaCl2 体系更倾向于分离成主要共存的水相-盐相和水相-二氧化碳相。这一实验事实可以解释为,与 CaCl2 相比,NaCl 对 CO2 的亲和力更大。利用最近开发的 H2O-CO2-NaCl-CaCl2 四元流体系统数值热力学模型,可以确定 NaCl 和 CaCl2 与二氧化碳相互作用的这种差异在地质学上的重大影响。H2O-CO2-NaCl-CaCl2流体多级异质化,P-T参数显著降低,最终形成水相-二氧化碳流体相f2,与初始流体相比,其中的盐成分明显富含NaCl,贫含CaCl2。在每个异质化阶段形成的流体相 f1 主要由水-盐组成,其中 NaCl 和 CaCl2 盐的摩尔分数比与初始流体中的差别不大。然而,f1 相中盐的总摩尔分数通常大大超过初始流体中的总摩尔分数。在 f1 相流体的多级异质化过程中,与 NaCl 和 CaCl2 的初始摩尔分数比相比,没有形成 CaCl2 明显富集的流体。与此同时,f2 相的连续多次分离会导致其盐组分中 NaCl 的富集。在有利条件下,这一过程可导致形成一种几乎含有纯 NaCl 盐的流体。考虑了流体 H2O-CO2-NaCl-CaCl2 盐成分的变化,并将其应用于拉普兰花岗岩带 HP 变质作用和共花岗岩变质作用的 P-T 趋势回归分支的流体成分演变。
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引用次数: 0
Geochemical Thermometry of Ore-Bearing Gabbronorites from an Apophysis of the Yoko-Dovyren Massif: Composition, Amount of Olivine, and Conditions of Sulfide Saturation in the Parental Magma 横沟-多维连地块透辉岩含矿石的地球化学测温:母岩浆中的成分、橄榄石含量和硫化物饱和状态
IF 1 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-22 DOI: 10.1134/S0869591124010089
I. V. Pshenitsyn, A. A. Ariskin, S. N. Sobolev

The temperature and compositional parameters of the parental magma of ore-bearing apophysis DV10 of the Yoko-Dovyren massif are estimated by the method of geochemical thermometry based on results of thermodynamic modeling of the equilibrium crystallization of the melts of 24 rocks. The thermometric calculations were carried out using the COMAGMAT-5.3 program with increments of 0.5 mol % to a maximum degree of crystallization 75–85%, under oxygen fugacity controlled by the QFM buffer. The model crystallization sequence of minerals was as follows: olivine (Ol) + Cr-Al spinel (Spl) → plagioclase (Pl) → high-Ca pyroxene (Cpx) → orthopyroxene (Opx). Silicate−sulfide immiscibility was calculated to occur mostly before the onset of plagioclase crystallization, which is consistent with initial sulfide saturation of the parental magma. The calculation results demonstrate the convergence and intersection of the model liquid lines of descent at temperatures of about 1185oC. When applied to the average composition of apophysis DV10, this temperature indicates the existence of suspension of the original crystals, including 52.1 wt % cumulus olivine (Fo83.6), 2.3 wt % plagioclase (An79.7), 0.24 wt % clinopyroxene (Mg# 88.8), 1 wt % aluminochromite (Cr# 0.62), and about 0.2% sulfide liquid in a moderately magnesian melt (53.6 wt % SiO2, 7.4 wt % MgO). Therewith the sulfur concentration at sulfide saturation (SCSS) was estimated at 0.083 wt %. This heterogeneous system had a viscosity of 4.71 log units (Pa s) and integral density of 2929 kg/m3. Such rheological properties do not contradict the possibility of the migration and emplacement of the protocumulus mush from the main Dovyren chamber. However, a more probable scenario is the localized accumulation of olivine in the trough-shaped part of the DV10 subchamber, which preceded or occurred in parallel to the accumulation of segregated sulfides.

摘要 根据 24 块岩石熔体平衡结晶的热力学建模结果,采用地球化学测温法估算了横沟-多维连地块 DV10 含矿岩浆母岩的温度和成分参数。测温计算使用 COMAGMAT-5.3 程序进行,增量为 0.5 摩尔%,最大结晶度为 75-85%,氧富集度由 QFM 缓冲控制。矿物的模型结晶顺序如下:橄榄石(Ol)+铬铝尖晶石(Spl)→斜长石(Pl)→高碳辉石(Cpx)→正辉石(Opx)。根据计算,硅酸盐-硫化物互不相溶主要发生在斜长石开始结晶之前,这与母岩浆的初始硫化物饱和是一致的。计算结果证明,模型液体下降线在约 1185 摄氏度的温度下趋同并相交。当应用于透辉石 DV10 的平均成分时,该温度表明存在原始晶体的悬浮物,包括 52.1 重量%的积橄榄石(Fo83.6)、2.3重量%的斜长石(An79.7)、0.24重量%的褐辉石(Mg# 88.8)、1重量%的铝铬铁矿(Cr# 0.62)和约0.2%的硫化物液体。因此,硫化物饱和时的硫浓度(SCSS)估计为 0.083 wt %。该异质体系的粘度为 4.71 对数单位(帕秒),整体密度为 2929 千克/立方米。这样的流变特性与原球茎蘑菇从多维伦主室迁移和移位的可能性并不矛盾。不过,更有可能的情况是,橄榄石在 DV10 亚室的槽形部分局部堆积,这种堆积发生在离析硫化物堆积之前或同时发生。
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Petrology
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