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Ultra-sensitive laser-based contamination detection for space applications 用于空间应用的超灵敏激光污染检测
Pub Date : 2021-10-12 DOI: 10.1117/12.2602232
D. Raiser, J. Holburg, K. Mann, Ricardo Martins, A. Tighe
Molecular contamination due to outgassing of organic materials in vacuum can be a source of significant degradation for space equipment, especially for sensitive optical instruments. Thus, on-ground contamination measurements in vacuum are essential to ensure the flight hardware cleanliness and for making in-flight performance predictions. A suitable detection technique shall work in-situ and in real-time, i.e. it shall be possible to measure the real-time build-up of contamination layers of a few nanometers and less on surfaces in vacuum in the presence of an outgassing source. In this paper we address a new experimental setup for controlled contamination and high-sensitivity spectroscopic analysis of the contaminants on representative material for typical space optics. The central method of choice for the detection of organic contaminants incorporated in this setup is laser-induced fluorescence (LIF), which provides the demanded distinguishability of the applied contamination species. Different excitation wavelengths in the UV spectral range are used. LIF measurements are accompanied by in operando verification of amount and species of the contaminants by a thermoelectric quartz crystal microbalance (TQCM) and a mass spectrometer (MS). This parameter study aims for exploring the laser parameter dependent detection limits and the temperature-dependent condensation process with respect to various substrate-contaminant combinations, in order to reveal strategies to prevent contamination for space applications.
有机材料在真空中放气造成的分子污染可能是空间设备,特别是敏感光学仪器严重退化的一个原因。因此,真空中的地面污染测量对于确保飞行硬件清洁度和进行飞行性能预测至关重要。一种合适的检测技术应该在现场实时工作,也就是说,在排气源存在的情况下,它应该有可能在真空中测量几纳米或更小的污染层在表面上的实时积聚。本文提出了一种新的实验装置,用于对典型空间光学中具有代表性的材料上的污染物进行控制污染和高灵敏度光谱分析。该装置中有机污染物检测的主要选择方法是激光诱导荧光(LIF),它提供了应用污染物种所需的可区分性。在紫外光谱范围内使用不同的激发波长。LIF测量伴随着热电石英晶体微天平(TQCM)和质谱仪(MS)对污染物的数量和种类的验证。该参数研究旨在探索各种基材-污染物组合中与激光参数相关的检测限和与温度相关的冷凝过程,以便为空间应用揭示防止污染的策略。
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引用次数: 0
Bulk LIDT variances of fused silica: a material developer's perspective 熔融二氧化硅的体LIDT差异:材料开发人员的观点
Pub Date : 2021-10-12 DOI: 10.1117/12.2599501
F. Nürnberg, B. Kühn
Fused silica an optical material of choice for high energy laser applications offers a wide range of advantages in the UV and NIR wavelength range. Increasing laser performance (especially with critical fluences) require detailed information on laser induced damage threshold of the optical material itself, and not just the coating. Therefore, S-on-1 measurements according to ISO 21254-2 were commissioned from two different, experienced, and well-respected laboratories. The resulting LIDT (laser induced damage threshold) values are discussed in the context of current publications and differences are worked out. The measurements focus on the ns-pulse regime at 1064 and 355nm. The results differ up to a factor of 10 between different laboratories. In comparison to the literature study, we noticed a spread of measured values around a factor of 20. Non-binding recommendations of the standard as well as the optical setup have significant influence on the obtained LIDT values. However, depending on the optical design of the application, one or the other optical setup with the corresponding LIDT value can be relevant. In this respect there is no such thing as a single, generally applicable value. Nevertheless, a standard should enable material comparisons under sufficiently standardized conditions.
熔融二氧化硅是高能激光应用的首选光学材料,在紫外和近红外波长范围内具有广泛的优势。提高激光性能(特别是在关键影响下)需要光学材料本身的激光诱导损伤阈值的详细信息,而不仅仅是涂层。因此,根据ISO 21254-2的S-on-1测量由两个不同的,经验丰富的,备受尊敬的实验室委托。在当前出版物的背景下讨论了所得LIDT(激光诱导损伤阈值)值,并得出了差异。测量集中在1064和355nm的ns脉冲区。不同实验室的结果差异可达10倍。与文献研究相比,我们注意到测量值的分布约为20倍。标准的非约束性建议以及光学设置对获得的LIDT值有重大影响。但是,根据应用的光学设计,具有相应LIDT值的一个或另一个光学设置可能是相关的。在这方面,不存在单一的、普遍适用的价值。然而,一项标准应当能够在充分标准化的条件下进行材料比较。
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引用次数: 0
Spatio-temporal evolution of femtosecond laser pulses in dielectric multi-layers controlling the damage behavior 飞秒激光脉冲在介质多层中的时空演化控制损伤行为
Pub Date : 2021-10-12 DOI: 10.1117/12.2600528
M. Lenzner, Amir Khabbazi Oskouei, L. Emmert, M. Jupé, T. Willemsen, M. Steinecke, D. Ristau, W. Rudolph
When designing femtosecond laser mirrors, one tries to minimize the peak intensity within the high-index layers to increase the laser-induced damage threshold. Typically, the optimization procedure utilizes the electric field distribution in the layer stack generated by monochromatic irradiation. This approach is sufficient for certain structures like high-reflectors based on quarter-wave films. More complex structures require to take into account the exact evolution of the pulse parameters such as peak intensity and duration within the multi-layer system. We exemplify this by discussing a merit function that can be included in femtosecond optics design.
在设计飞秒激光反射镜时,应尽量减小高折射率层内的峰值强度,以提高激光损伤阈值。典型的优化过程是利用单色辐照产生的层叠中的电场分布。这种方法对于某些结构是足够的,比如基于四分之一波薄膜的高反射器。更复杂的结构需要考虑脉冲参数的确切演变,如峰值强度和持续时间在多层系统中。我们通过讨论可包含在飞秒光学设计中的优点函数来举例说明这一点。
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引用次数: 0
Degradation of optical coatings induced by high-intensity, 515 nm, sub-picosecond burst-mode laser beam 高强度、515 nm、亚皮秒爆发模式激光束对光学涂层的影响
Pub Date : 2021-10-12 DOI: 10.1117/12.2598668
U. Wegner, J. Meier, D. Rompotis, R. Secareanu, M. Emons, B. Monoszlai, M. Lederer
We are presenting our observations regarding laser induced degradation of coated optics exposed to the burst-mode pulsetrain of the optical pump-probe laser systems (PP-laser) at the European X-ray Free Electron Laser (EuXFEL). Degradation happens on HR and AR coatings from various suppliers during the course of prolonged exposure to the 515 nm, 800 fs burst-mode radiation. Since the lasers typically operate 24/7, coatings degrade within a few weeks to several months, depending on the requested burst lengths and number of pulses and hence integrated burst energies. Reduced performance of pointing- and pulse energy-stability and a drop of average power of the non-collinear optical parametric amplifiers (NOPAs) result. As user facility, the EuXFEL strives to maximize up-time and to reliably provide high quality x-ray and optical laser beam lines for user experiments, which is compromised to some extent by the observed coating degradation. In this report we show our investigations into the effect so far. In collaboration with the coating manufacturer Layertec GmbH, an improved mirror coating was found, which prolongs optics life time by nearly a factor of 3.
本文介绍了在欧洲x射线自由电子激光器(EuXFEL)上,暴露于光泵浦探测激光系统(PP-laser)的爆发模脉冲串下的涂层光学器件的激光诱导退化的观察结果。来自不同供应商的HR和AR涂层在长时间暴露于515 nm, 800 fs的爆发模式辐射过程中会发生降解。由于激光器通常24/7工作,涂层在几周到几个月内就会降解,这取决于所要求的爆发长度和脉冲数量,因此综合爆发能量。非共线光参量放大器(nopa)的指向和脉冲能量稳定性降低,平均功率下降。作为用户设备,EuXFEL努力最大限度地延长正常运行时间,并可靠地为用户实验提供高质量的x射线和光学激光光束线,这在一定程度上受到观察到的涂层降解的影响。在本报告中,我们将展示迄今为止对其影响的调查。与涂层制造商Layertec GmbH合作,发现了一种改进的镜面涂层,它将光学寿命延长了近3倍。
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引用次数: 0
Analysis of cumulative probability of growth of damage sites at the National Ignition Facility 国家点火装置损伤点增长的累积概率分析
Pub Date : 2021-10-12 DOI: 10.1117/12.2598943
Zhi-min Liao, C. Miller, D. Cross, C. Carr
The recent development utilizing automatic microscopy to identify damage sites on an optic for damage mitigation at the National Ignition Facility (NIF) has resulted in a large set of damage dataset for growth analysis. In this work we will examine how the pre and post installation damage sizes are used to analyze the cumulative probability of growth for damage sites that have been exposed to multiple laser shots. The analysis can form the basis to derive single-shot probability growth behavior of fused silica damage site as a function of size.
最近,美国国家点火装置(NIF)利用自动显微镜识别光学元件上的损伤部位以减轻损伤,从而产生了大量用于生长分析的损伤数据集。在这项工作中,我们将研究如何使用安装前和安装后的损伤尺寸来分析暴露于多次激光射击的损伤部位的累积增长概率。该分析可为推导石英熔凝损伤部位随尺寸的单次概率生长行为奠定基础。
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引用次数: 0
515-nm, femtosecond laser mirror thin film damage competition 515nm,飞秒激光反射薄膜损伤竞赛
Pub Date : 2021-10-12 DOI: 10.1117/12.2597206
R. Negres, C. Stolz, G. Batavičiūtė, A. Melninkaitis
This year’s competition is a continuation of the 2020 thin film damage competition conducted with nanosecond (ns) laser pulses and aimed to survey state-of-the-art visible high reflectors in the femtosecond (fs) pulse length regime. The requirements for the coatings were a minimum reflection of 99.5% at 0 degrees incidence angle at 532 nm. The fs-laser source available for testing in 2021 delivered pulses at 515 nm; as a result, to accommodate both ns- and fs-damage tests on the same samples, the latter tests were conducted at an incidence angle of 25 degrees to re-center the reflection spectral band of the coatings, i.e., a blue shift from 532 nm to 515 nm. The choice of coating materials, design, and deposition method were left to the participants. Laser damage testing of samples received in 2020 and new sample submissions in 2021 was per- formed at a single testing facility using the S-on-1 standardized test protocol with a 200-fs pulse length laser system operating at 5 kHz in a single-longitudinal mode. A double-blind test assured sample and submitter anonymity. The damage performance results (LIDT), sample rankings, details of the deposition processes, coating materials and substrate cleaning methods are shared. These experiments enabled not only direct comparison among the participants but also the performance contrast in two different pulse length regimes. We found that different deposition methods and coating materials yield comparably high laser resistance in the fs-pulse regime. Namely, hafnia/silica, hafnia/alumina/silica or tantala/alumina/silica multilayer coatings were the most damage resistant under exposure to fs-laser pulses within the coating deposition groups. In contrast, hafnia/silica coatings by e-beam were identified as best performers in the ns-pulse regime.
今年的竞赛是2020年薄膜损伤竞赛的延续,该竞赛使用纳秒(ns)激光脉冲进行,旨在调查飞秒(fs)脉冲长度范围内最先进的可见高反射器。对涂层的要求是在532 nm处,在0度入射角下的最低反射率为99.5%。2021年可用于测试的fs激光源提供515 nm的脉冲;因此,为了在同一样品上同时进行ns-和fs-损伤测试,后一种测试以25度的入射角进行,以重新定位涂层的反射光谱带,即从532 nm到515 nm的蓝移。涂层材料、设计和沉积方法的选择留给了参与者。对2020年收到的样品和2021年提交的新样品进行激光损伤测试,在单个测试设施中使用S-on-1标准化测试协议,使用200-fs脉冲长度的激光系统,在单纵向模式下以5 kHz工作。双盲测试保证了样本和提交者的匿名性。他们分享了损伤性能结果(LIDT)、样品排名、沉积过程细节、涂层材料和基材清洁方法。这些实验不仅可以在参与者之间进行直接比较,而且可以在两种不同的脉冲长度制度下进行性能对比。我们发现不同的沉积方法和涂层材料在fs脉冲下产生相当高的激光电阻。也就是说,铪/二氧化硅、铪/氧化铝/二氧化硅或钽/氧化铝/二氧化硅多层涂层在fs激光脉冲下的抗损伤能力最强。相比之下,电子束的铪/二氧化硅涂层被认为是ns脉冲状态下性能最好的涂层。
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引用次数: 0
Detection of contamination of protective windows in Laser Powder Bed Fusion by means of a line scan camera 用线扫描相机检测激光熔床防护窗的污染
Pub Date : 2021-10-12 DOI: 10.1117/12.2598589
Niklas Praetzsch, Hermann Sturzebecher, N. Pirch, F. Fischer, C. Haefner
In Laser Powder Bed Fusion (LPBF), there are high demands on the cleanliness of the protective window (PW). During processing, however, process-by-products may accumulate on the PW surface and thereby change the process boundary conditions. In this work, a methodology to assess the condition of PWs in a LPBF machine using a line scan camera is presented. Image processing is used to detect the degree of contamination on the PW surface by using a thresholding algorithm. The line scan camera results are further validated by ex-situ microscopic images of the contaminated surface of the PW. The higher resolution of these images enables the quantification of particle count and size distribution. Moreover, the influence of the contamination degree of the PWs on the beam quality is investigated. A laser focus shift of up to 22.6 mm against the direction of beam propagation within a caustic measurement as well as a minor decrease in relative density of 0.08 pp in 316L samples were detected due to the contamination. Based on this work, methods for monitoring the health condition of PWs in LPBF can be derived.
在激光粉末床熔融(LPBF)中,对保护窗(PW)的清洁度要求很高。然而,在加工过程中,工艺副产品可能积聚在PW表面,从而改变工艺边界条件。在这项工作中,提出了一种使用线扫描相机评估LPBF机器中PWs状况的方法。通过图像处理,采用阈值算法检测PW表面的污染程度。线扫描相机的结果进一步验证了PW污染表面的原位显微图像。这些图像的高分辨率使粒子计数和尺寸分布的量化。此外,还研究了PWs污染程度对光束质量的影响。由于污染,在316L样品中检测到激光焦点对光束传播方向的偏移高达22.6 mm,并且相对密度轻微下降0.08 pp。在此基础上,可以推导出监测LPBF中PWs健康状况的方法。
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引用次数: 0
The effect of chirp and wavelength for ultrafast bulk modification of solids with tightly focused laser pulses 啁啾和波长对紧密聚焦激光脉冲固体超快体改性的影响
Pub Date : 2021-10-12 DOI: 10.1117/12.2603492
E. Mareev, E. Migal, F. Potemkin
We report on the clear difference in the behavior of laser-matter interaction of tightly focused high-intensity pulses with the bulk of solids when chirping and tuning the wavelength of the laser driver from near-IR to mid-IR. In transparent dielectrics, laser wavelength scaling leads to the change in the heating mechanism which, in turn, leads to a weak dependence of the plasma formation threshold on the pulse duration in mid-IR (4.6 μm) and a significant impact in the case of the near-IR (1.24 μm) excitation. In the case of semiconductors, the ionization mechanism remains within the framework of the multiphoton approximation, but an increase in the photon order for excitation by mid-IR pulses leads to a decrease in delocalization processes and losses in the prefocal region.
我们报告了当啁啾和调谐激光驱动器的波长从近红外到中红外时,紧密聚焦的高强度脉冲与固体体的激光物质相互作用行为的明显差异。在透明介质中,激光波长的变化导致加热机制的改变,从而导致等离子体形成阈值对中红外(4.6 μm)脉冲持续时间的依赖性较弱,而在近红外(1.24 μm)激发下影响显著。在半导体的情况下,电离机制仍然在多光子近似的框架内,但是中红外脉冲激发的光子阶数的增加导致离域过程和焦前区域损失的减少。
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引用次数: 0
In-situ cleaning organic contaminants on SiO2 sol-gel antireflection film by low-pressure air plasma 低压空气等离子体原位清洗SiO2溶胶-凝胶增透膜上的有机污染物
Pub Date : 2021-10-12 DOI: 10.1117/12.2599668
Yuhai Li, Q. Bai, R. Shen, Peng Zhang, L. Lu, Xiao-Qing Yuan, X. Miao, W. Han, Hao Liu, Lin Huang, Caizhen Yao
Organic contaminants on optical components can degrade optical properties, thus limiting the energy enhancement of highpeak- power laser systems. It is still challenging to remove organic contaminants on the SiO2 sol-gel antireflection film and avoid damage. In this work, a low-pressure air plasma in-situ cleaning technique and a chemical reaction model of plasma cleaning were proposed to study the removal of organic contaminants. The optical properties of sol-gel AR films suffered from organic contaminants were evaluated by transmittance and laser-induced damage threshold, which recovered completely after 5 minutes of plasma cleaning without damage. Meanwhile, the hydrophilicity of the surface and the surface free energy were significantly increased after plasma treating. Surface composition analysis indicated that the CH and C-C bonds were reduced considerably, while abundant C=C and C=O bonds were produced after plasma cleaning. Optical emission spectrum analyzed the reactive species and its concentration in the air plasma as a reference for simulation. The chemical interaction process of oxygen radicals with organic contaminants was simulated by reactive molecular dynamics. The results can provide a guide for optical components in-situ cleaning.
光学元件上的有机污染物会降低光学性能,从而限制了高能激光系统的能量增强。如何去除SiO2溶胶-凝胶增透膜上的有机污染物并避免其损坏仍然是一个挑战。本文提出了一种低压空气等离子体原位清洗技术和等离子体清洗的化学反应模型来研究有机污染物的去除。通过透光率和激光损伤阈值来评价受有机污染物影响的溶胶-凝胶AR膜的光学性能,等离子清洗5分钟后完全恢复,无损伤。同时,等离子体处理后表面亲水性和表面自由能均显著提高。表面组成分析表明,等离子体清洗后,CH和C-C键明显减少,而大量的C=C和C=O键产生。光学发射光谱分析了空气等离子体中的反应物质及其浓度,作为模拟参考。用反应分子动力学方法模拟了氧自由基与有机污染物的化学相互作用过程。研究结果可为光学元件的原位清洗提供指导。
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引用次数: 0
Evaluation of alumina and silica coating materials for the NIF final turning mirrors NIF最终转向镜用氧化铝和二氧化硅涂层材料的评价
Pub Date : 2021-10-12 DOI: 10.1117/12.2598577
C. Stolz, J. Weng, Tsion Teklemarim, M. Brophy, P. Kupinski
One third of the exchanged final turning mirrors on the National Ignition Facility have been laser damaged by 3ω (351nm) target backscattered light. The mirrors are spectrally complex hafnia and silica multilayer dichroic coatings with high 1ω reflection for the forward propagating beam and low 3ω reflection to suppress propagation of target backscatter. Alumina, a wider bandgap high index material than hafnia, was selected to improve the 3ω laser damage resistance despite a lower refractive index. A 2-4x improvement in 3ω LIDT was demonstrated with adequate 1ω laser damage resistance. Nodule ejection was the dominate laser damage morphology. An 18% decrease in the refractive index between alumina and hafnia results in coating designs that are 3x thicker. Similarly, a decrease in refractive index also decreases the angular bandwidth resulting in increasing the number of mirror types from two to six over an angular range of 16 degrees. The significant improvement in 3ω LIDT has justified beginning a scale up demonstration to full aperture (0.3m2).
在国家点火装置上三分之一的交换的最后转向镜已经被3ω (351nm)目标背向散射光激光损坏。反射镜采用光谱复杂的半氟硅和二氧化硅多层二向色镀层,前向传播光束具有高1ω反射,抑制目标反向散射传播的低3ω反射。氧化铝是一种比半氟酸更宽的带隙高折射率材料,虽然折射率较低,但可以提高3ω激光损伤的抗损伤性。3ω LIDT改善2-4倍,具有足够的1ω激光损伤抗力。激光损伤的主要形态为弹射结节。氧化铝和半铝之间的折射率降低18%,导致涂层设计厚3倍。同样,折射率的降低也降低了角带宽,从而在16度角范围内增加了镜子类型的数量,从2个增加到6个。3ω LIDT的显著改进证明了开始对全孔径(0.3m2)进行放大演示是合理的。
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引用次数: 1
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Laser Damage
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