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Wpływ spieniania chemicznego na strukturę i wybrane właściwości PA6 wzmocnionego włóknem szklanym
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-11-17 DOI: 10.14314/polimery.2022.10.1
Zbadano wpływ procesu spieniania chemicznego na strukturę (SEM) oraz wybrane właściwościpoliamidu 6 wzmocnionego włóknem szklanym (30, 60 % mas.). Oznaczono gęstość, właściwościmechaniczne przy rozciąganiu i udarność Charpy’ego. Jako porofor stosowano Hydrocerol ITP 825w ilości 2% mas. Wielkość porów i stopień spieniania zależały od odległości od punku wtryskiwania.Najmniejszą wielkość porów (64 μm) stwierdzono w przypadku poliamidu zawierającego 60% mas.włókna szklanego.
研究了化学发泡工艺对玻璃纤维(30,60%质量)增强聚酰胺6的结构(SEM)和性能的影响。使用2%质量的Hydrocerol ITP 825w作为多孔载体。孔隙的大小和发泡程度取决于距注射点的距离。对于含有60%质量玻璃纤维的聚酰胺,发现最小孔径(64μm)。
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引用次数: 0
The influence of calcium carbonate and its modifications on the extrusion process and selected functional properties of polypropylene cast films 研究了碳酸钙及其改性剂对聚丙烯铸膜挤出工艺及功能性能的影响
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-11-17 DOI: 10.14314/polimery.2022.10.6
The purpose of the article was to determine the influence of calcium carbonate and its modification (with stearic acid) on selected properties of composite polypropylene films and their processing. Polypropylene composites containing, respectively, 5, 10, 20 and 30 wt% filler, were made in twin-screw extrusion process with cold granulation. Films, on the other hand, were produced in single-screw extrusion process (an extruder with a screw with diameter d = 20 mm and ratio l/d = 24) using a flat head (so-called cast films) and a chill roll type cooling and pull-back device. The pull-back rotational speed was selected so as to obtain films of a thickness of approx. 120 µm, irrespectively of the composite being processed. The assessment of the effect of the addition of applied fillers on the magnitude of the melt volume-flow rate (MVR) of polypropylene and the processing characteristic of extrusion process was made (the flow resistance and the variations in volumetric flow rate were determined). It was demonstrated how variations in the processability of polymeric material determined the correction of extrusion process setup parameters (pull-back system speed). The processability of composite films under extensional flow conditions was also determined by evaluating the extensional viscosity (ηE) of the composites. The strength values of composite films were determined under static tension conditions and in puncture tests. The effect of the content and modification of CaCO3 on the film haze and gloss was also assessed. The investigation carried out has demonstrated a direct effect of the addition of calcium carbonate and its modification on the processability and selected functional properties of composite films. The study has also proved that stearic acid is an effective modifier of processing properties, not only in shear flow conditions, but also under extensional flow conditions – smaller ηE values are exhibited by films containing modified calcium carbonate.
本文的目的是确定碳酸钙及其改性(硬脂酸)对复合聚丙烯薄膜的选定性能及其加工的影响。采用双螺杆冷造粒挤压法制备了填充量分别为5%、10%、20%和30%的聚丙烯复合材料。另一方面,薄膜是在单螺杆挤压过程中生产的(螺杆直径d = 20 mm,比l/d = 24的挤出机),使用平头(所谓的铸膜)和冷辊式冷却和回拉装置。选择回拉转速,得到的薄膜厚度约为。120µm,与所加工的复合材料无关。评价了外加填料的加入对聚丙烯熔体体积流率(MVR)的大小和挤出工艺特性的影响(确定了流动阻力和体积流率的变化)。演示了聚合物材料可加工性的变化如何决定挤出工艺设置参数的修正(回拉系统速度)。通过评价复合材料的拉伸粘度ηE,确定了复合材料薄膜在拉伸流动条件下的可加工性。在静态拉伸条件下和穿刺试验中测定了复合膜的强度值。评价了CaCO3的含量和改性对膜雾度和光泽度的影响。研究表明,碳酸钙的加入及其改性对复合薄膜的加工性能和选定的功能性能有直接影响。研究还证明,硬脂酸是一种有效的工艺性能调节剂,不仅在剪切流动条件下,而且在拉伸流动条件下,含有改性碳酸钙的薄膜的ηE值都较小。
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引用次数: 0
Influence of various forms of cellulose on the mechanical properties of polymer composites modified in a constant magnetic field 恒磁场下不同形式纤维素对改性高分子复合材料力学性能的影响
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-11-16 DOI: 10.14314/polimery.2022.10.4
E. Miękoś, M. Zieliński, D. Sroczyński, A. Fenyk
The paper presents the study of polymer composites on epoxy resin matrix, polymerized in the environment of a constant magnetic field. The composites contained admixtures of various forms of cellulose – microcrystalline cellulose and cellulose from waste hemp straw fibers – in an amount ranging from 10 to 30 wt%. Changes in the mechanical properties due to the effect of a constant magnetic field with a magnetic induction value of B = 0.5 T. The composites additionally contained magnetic particles in the form of carbonyl iron, in the amount of 10 wt%.
本文研究了在恒定磁场环境下聚合的环氧树脂基聚合物复合材料。该复合材料含有各种形式的纤维素的混合物——微晶纤维素和废弃大麻秸秆纤维中的纤维素——含量从10%到30%不等。由于磁感应值为B=0.5T的恒定磁场的影响而导致的机械性能的变化。复合材料还含有含量为10wt%的羰基铁形式的磁性颗粒。
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引用次数: 0
Environmentally hazard and toxic exoskeletons of marine crustaceans wastes in synthesizing N-deacetylated chitin 海洋甲壳类废弃物外骨骼合成n -去乙酰化几丁质的环境危害和毒性
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-11-16 DOI: 10.14314/polimery.2022.10.5
Rasha E El-Mekawy
High molecular weight chitosan was synthesized from shrimp shells. Chemical structure of chitosan was confirmed using FT-IR, XRD, TGA, and SEM analyses. Physicochemical properties of chitosan such as molecular weight (800 000 g/mol), deacetylation degree (80%), ash content (1%) indicating effectiveness of demineralization step in removing minerals, water binding capacity (4220%), and fat binding capacity (537%), were determined. FT-IR spectra exhibited characteristic joint band at 3365 cm-1 due to –OH and –NH2 regarding to the conversion of chitin acetyl group to NH2 of chitosan.
以虾壳为原料合成了高分子量壳聚糖。通过红外光谱、X射线衍射、热重分析和扫描电镜分析,确定了壳聚糖的化学结构。测定了壳聚糖的物理化学性质,如分子量(80万g/mol)、脱乙酰度(80%)、灰分(1%),表明脱矿步骤对矿物的去除效果、水结合能力(4220%)和脂肪结合能力(537%)。由于壳聚糖乙酰基转化为NH2的–OH和–NH2,FT-IR光谱在3365 cm-1处显示出特征性的结合带。
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引用次数: 0
Homo- and copolymerization of 2-benzothiazoylacrylamide with α-methyl styrene and methyl acrylate: synthesis, characterization and reactivity 2-苯并噻唑基丙烯酰胺与α-甲基苯乙烯和丙烯酸甲酯的共聚:合成、表征和反应性
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-11-04 DOI: 10.14314/polimery.2022.10.3
A. Al-Mokaram, Ameen Hadi Mohammed, Hiba A. Ghani
2-benzothiazolyl acrylamide (BTA) monomer was synthesized by reacting of 2-aminobenzothiazole with acryloyl chloride. Homo- and copolymerization of this monomer with α-methylstyrene (MSt) and methyl acrylate (MA) was carried out in dimethylsulfoxide (DMSO) solution. The prepared homo-and copolymers were characterized by Fourier Transform Infrared (FTIR) and their thermal stability was studied by thermogravimetric analysis (TGA). The composition of copolymers and the reactivity coefficients (r1, r2) were determined on the basis of sulfur analysis using linearization methods proposed by Fineman-Ross and Kelen-Tudos and the Mayo-Lewis intersection method. The derived (r1, r2) for BTA-co-MSt and BTA-co-MA are: (0.197, 0.230) and (0.294, 4.314), respectively. The microstructure of the copolymers and the distribution of the monomer sequences in the copolymers were calculated statistically, the results obtained are consistent with the values (r1, r2). BTA with MSt form alternative copolymer whilst BTA-co-MA tends to be block with MA.
以2-氨基苯并噻唑与丙烯酰氯反应合成了2-苯并噻唑丙烯酰胺(BTA)单体。在二甲基亚砜(DMSO)溶液中,该单体与α-甲基苯乙烯(MSt)和丙烯酸甲酯(MA)进行了均聚和共聚。用傅立叶变换红外光谱(FTIR)对制备的均聚物和共聚物进行了表征,并用热重分析(TGA)研究了它们的热稳定性。共聚物的组成和反应系数(r1,r2)是在硫分析的基础上使用Fineman-Ross和Kelen-Tudos提出的线性化方法和Mayo-Lewis交叉法确定的。BTA-co-MSt和BTA-co-MA的推导值(r1,r2)分别为:(0.197,0.230)和(0.294,4.314)。对共聚物的微观结构和单体序列在共聚物中的分布进行了统计计算,得到的结果与值(r1,r2)一致。BTA与MSt形成替代共聚物,而BTA-co-MA倾向于与MA嵌段。
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引用次数: 0
Gamma-induced grafting of rice straw cellulose with polyvinylpyrrolidone γ诱导聚乙烯吡咯烷酮接枝稻草纤维素
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-10-26 DOI: 10.14314/polimery.2022.9.6
M. Suhartini, Zetryana Puteri Tachrim, Niken Hayudanti Anggarini, R. Rahmawati, Amanda Prasetyani, June Melawati, D. Deswita, B. Sugeng
Cellulose obtained from rice straw was grafted with polyvinylpyrrolidone (Cell-g-PVP). The process was induced by simultaneous gamma iradiation (Co-60). The presence of the grafted PVP chains was confirmed by FT-IR, XRD and EDS methods. The influence of the iradiation dose (20 and 30 kGy) on the reaction efficiency and thermal stability of Cell-g-PVP was investigated. The grafting yield at the dose of 30 kGy was about 56%. The higher dose of radiation resulted in better thermal stability. The AAS results showed that Ni(II), Cu(II), and Cr(II) ions can be adsorbed by Cell-g-PVP. The order of ion metals adsorption capacity of Cell-g-PVP was Cu(II) > Ni(II) > Cr(II). The adsorption isotherm of Cu(II) metal ion using the Cell-g-PVP followed the Langmuir adsorption isotherm whereas the chemical adsorption and the adsorption energy were constant on all sides of the copolymer.
以稻草为原料,用聚乙烯吡咯烷酮(Cell-g-PVP)接枝纤维素。该过程是由同时γ射线辐照(Co-60)诱导的。通过FT-IR、XRD和EDS等方法证实了接枝PVP链的存在。研究了辐照剂量(20和30kGy)对Cell-g-PVP反应效率和热稳定性的影响。30kGy剂量的接枝率约为56%。辐射剂量越高,热稳定性越好。原子吸收光谱结果表明,Cell-g-PVP可以吸附Ni(II)、Cu(II)和Cr(II)离子。Cell-g-PVP对离子金属的吸附能力依次为Cu(II)>Ni(II)>Cr(II)。使用Cell-g-PVP对Cu(II)金属离子的吸附等温线遵循Langmuir吸附等温线,而化学吸附和吸附能在共聚物的所有侧面上都是恒定的。
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引用次数: 0
New legal regulations on nanoforms of substances in the context of the legal certainty principle 在法律确定性原则的背景下,关于物质纳米形态的新法律法规
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-10-24 DOI: 10.14314/polimery.2022.9.2
M. Jurewicz
New legal regulations concerning nanomaterials in the scope of the legal certainty principle were discussed. Commission Regulation (EU) 2018/1881 of 03/12/2018 amending the REACH regulation with regard to Annexes I, III, VI-XII is the first normative act on chemicals that sets out the requirements for the registration of nanoforms of substances. The new requirements for nanomaterials will serve to implement the principle of legal certainty in this area. The presented analysis of the introduced amendments to the annexes to the REACH regulation indicates some shortcomings of the new legal regulations.
讨论了在法律确定性原则范围内有关纳米材料的新法律规定。2018年3月12日欧盟委员会法规(EU) 2018/1881修订了REACH法规关于附件I、III、VI-XII的规定,这是第一个关于化学品的规范性法案,规定了纳米形式物质的注册要求。对纳米材料的新要求将有助于在这一领域实施法律确定性原则。通过对REACH法规附件修正案的分析,指出了新法规的一些不足之处。
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引用次数: 0
Analysis of the influence of selected Slicer parameters on the mapping accuracy in the FFF method 分析FFF方法中切片器参数选择对映射精度的影响
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-10-24 DOI: 10.14314/polimery.2022.10.2
G. Budzik, M. Zaborniak, Jakub Roczniak
The methodology and measurement results of the machine part produced directly from the 3D-CAD numerical model are presented. Representative additive techniques based on polymer processing were used. The accuracy of replication of CAD numerical models was assessed in terms of both external surface analysis and part volume.
介绍了直接利用3D-CAD数值模型生产机械零件的方法和测量结果。采用了具有代表性的基于聚合物加工的添加剂技术。从外表面分析和零件体积两方面评估了CAD数值模型复制的准确性。
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引用次数: 0
Aging behavior of three-proof polyurethane coatings under UV radiation 紫外线辐射下三防聚氨酯涂料的老化行为
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-09-29 DOI: 10.14314/polimery.2022.9.4
Jianfa Wang, Zhengzhou Gu, Jie Zhao, Susu Zhang, Peiyao Li, Chao Meng, J. Sui, Xiaoyi Zhang, Shaokai Hu, Jiaying Pan, Junyi Li
The influence of UV radiation on the physical and mechanical properties of polyurethane resins and three-proof polyurethane coatings was examined. Changes of mechanical properties and the gloss of resins and coatings were determined. The structure of materials was confirmed using scanning microscopy SEM and Fourier transform infrared spectroscopy FTIR; thermogravimetric TGA and DTG studies were also performed. It turned out that the gloss of finished protective coatings was worse than the gloss of individual resins, and aging significantly lowered these values (from 81.3° to 8.9° in case of resins and from 61.1° to 2.8° in case of coatings after 1200 hours of irradiation). Tensile strength of resins decreased constantly during aging while their elongation at break decreased than increased reaching minimum at exposure time of 100 hours. In case of coatings, both tensile strength and elongation at break firstly decreased than increased reaching minimum at exposure time of 800 hours; after long exposure time, more than 1200 hours, these properties decreased again.
研究了紫外线辐射对聚氨酯树脂和三防聚氨酯涂料物理力学性能的影响。测定了树脂和涂层的力学性能和光泽度的变化。利用扫描显微镜、扫描电镜和傅里叶变换红外光谱对材料的结构进行了确证;热重TGA和DTG研究也进行了。结果表明,成品保护涂层的光泽度比单个树脂的光泽度差,老化显著降低了这些值(树脂的光泽度从81.3°降至8.9°,涂层在辐照1200小时后从61.1°降至2.8°)。在时效过程中,树脂的抗拉强度不断下降,断裂伸长率先下降后增加,在100h时达到最小值。涂层的抗拉强度和断裂伸长率均先下降后上升,在800h时达到最小值;在长时间曝光后,超过1200小时,这些性能再次下降。
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引用次数: 0
Class C fly ash as a substitute for mineral fillers in asphalt mixtures C类粉煤灰在沥青混合料中替代矿物填料
IF 1.6 4区 工程技术 Q2 Chemical Engineering Pub Date : 2022-09-23 DOI: 10.14314/polimery.2022.9.5
Sajjad Ali, Dr. Muhammad Owais Raza Siddiqui, S. M. Noman, Tahreem Beg, Danmei Sun
The influence of class C fly ash as a substitute for mineral aggregate on the stability and density of asphalt mixtures containing 3.5−6 wt% of bitumen was investigated. For the fly ash concentration (in relation to the replaced aggregate) 25, 50, 75 and 100 wt%, the optimal asphalt content (OAC) was determined, respectively, 5.75, 4.82, 4.42, 4.4 and 4 wt%. The stability increased with the increase in the content of fly ash. The results confirm the possibility of replacing mineral aggregates with fly ash.
研究了C类粉煤灰作为矿物骨料的替代品对沥青含量为3.5-6wt%的沥青混合料的稳定性和密度的影响。对于粉煤灰浓度(相对于更换的集料)25、50、75和100wt%,确定了最佳沥青含量(OAC),分别为5.75、4.82、4.42、4.4和4wt%。稳定性随粉煤灰含量的增加而增加。结果证实了用粉煤灰代替矿物骨料的可能性。
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引用次数: 0
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Polimery
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