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Analiza składu kopolimeru na podstawie symulacji małych układów reakcyjnych 基于小反应体系模拟的共聚物组成分析
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2022-01-17 DOI: 10.14314/polimery.2022.1.2
J. Lechowicz
Metodą symulacji Monte Carlo zbadano przebieg gradientowej kopolimeryzacji monomerów dwufunkcyjnych. Skład kopolimeru wyznaczono poprzez uśrednienie składu kolejnych segmentów łańcuchów makrocząsteczek. Zmiana wielkości segmentów pozwoliła na oszacowanie profilu gradientu składu małych układów reakcyjnych. Zastosowana procedura nie wymaga dużego układu obliczeniowego.
蒙特卡罗模拟研究了两种功能单体的梯度共聚反应。通过平均大分子链的后续链段的组成来确定共聚物的组成。片段大小的变化允许估计小反应系统的梯度分布。所使用的程序不需要大型计算系统。
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引用次数: 0
Poly(vinyl chloride)-supported triazoles grafted onto calix[4]arene for chromium ions extraction 杯[4]芳烃接枝聚氯乙烯负载三唑萃取铬离子
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-12-30 DOI: 10.14314/polimery.2021.11.6
Ammar Said, Mokhtar Dardouri, Fayçel Ammari, Abid Ouerghui, Nicholas P. Power, F. Meganem
A new suitable material was synthesized using click reaction between dialkynyl-p-tert-butylcalix[4]arene and poly(vinyl chloride) azide (PVC-N3). This novel dialkynyl-p-tert-butylcalix[4]arene with triazole groups grafted onto PVC polymer (PVC-0.75CX[4]) has an excellent extraction capability for chromium ions from aqueous solutions. It shows a unique ability to extract chromium (VI) ions from aqueous solutions, thanks to the soft cavity, the presence of π-triazole rings and hydrogen bonds. Cr (VI) ion sorption capacity is 95.5% at pH = 3.
采用二芳基对叔丁基杯[4]芳烃与聚(氯乙烯)叠氮化物(PVC-N3)的点击反应合成了一种新的合适材料。这种新型的具有三唑基团的二芳基对叔丁基杯[4]芳烃接枝到PVC聚合物(PVC-0.75CX[4])上,对水溶液中的铬离子具有优异的萃取能力。由于软腔、π-三唑环和氢键的存在,它显示出从水溶液中提取铬(VI)离子的独特能力。在pH=3时,Cr(VI)离子的吸附能力为95.5%。
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引用次数: 0
Determination of moxifloxacin hydrochloride in AVELOX pharmacological formulations using modified potentiometer sensors 改良电位计传感器测定AVELOX药物制剂中盐酸莫西沙星的含量
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-12-25 DOI: 10.14314/polimery.2021.11.4
Sachin Kumar, Sushil K. Sindhu, Praveen Kumar, A. Sharma, S. Sagadevan
Three different carbon paste (CP), silk-screen (SP) and poly (vinyl chloride) (PVC) modified electrodes were obtained to verify the reliability of AVELOX, the generic name of which is Moxifloxacin HCl (AV-MOXH). The sensing membranes were containing AVELOX ion associated complexes with sodium tetraphenylborate (NaTPB), phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and ammonium reineckate (RN) as electroactive materials. All three electrodes gave fast, viable, and near-Nernstian linear responses over a relative wide concentration range that ranged from 1.010-6 to 1.010-2 mol / L AV-MOXH at 25° C with a monovalent cationic decrease. The sensors demonstrated a good discernment of AV-MOXH from numerous inorganic and organic compounds such as glucose, sucrose, Na+, Ca+, etc. Additionally, the isothermal coefficients along with selectivity coefficients were calculated. The modified Screen Printed Electrode sensor appeared to be highly sensitive for the determination of AV-MOXH. The electrode response was observed in pH range 2--6 for ISPE electrodes and IPVC electrodes and 3--7 for ICPE electrodes under various temperature conditions. The short response time, lifetime validity, recovery, and all the methods of validation such as limit of detection and limit of quantification were estimated. The potentiometric method turned out to be suitable for determining AV-MOXH in pharmacological formulations, and the findings obtained are comparable to the “HPLC official method” in terms of the agreement. As a result, the postulated potentiometric approach was verified in accordance with IUPAC guidelines.
获得了三种不同的碳糊(CP)、丝网(SP)和聚氯乙烯(PVC)修饰电极,以验证AVELOX的可靠性。传感膜含有AVELOX离子缔合物与四苯基硼酸钠(NaTPB)、磷钼酸(PMA)、磷钨酸(PTA)和Reineck酸铵(RN)作为电活性材料。在相对较宽的浓度范围内,所有三个电极都给出了快速、可行且接近能斯特的线性响应,在25°C下,浓度范围为1.010-6至1.010-2 mol/L AV-MOXH,单价阳离子减少。传感器证明了AV-MOXH与许多无机和有机化合物(如葡萄糖、蔗糖、Na+、Ca+等)的良好区分。此外,还计算了等温系数和选择性系数。改进的丝网印刷电极传感器似乎对AV-MOXH的测定高度敏感。在不同的温度条件下,ISPE电极和IPVC电极的pH范围为2-6,ICPE电极的pH为3-7。估计了短响应时间、寿命有效性、回收率以及所有验证方法,如检测限和定量限。电位法被证明适用于测定药理学制剂中的AV-MOXH,所获得的结果在协议方面与“HPLC官方方法”相当。因此,根据IUPAC指南验证了假定的电位法。
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引用次数: 0
The new functional filler TiO2-SiO2/polyhedral oligomeric hybrid silsesquioxane as a potential modifier of polyethylene 新型功能填料TiO2-SiO2/多面体低聚杂化硅氧烷作为聚乙烯的潜在改性剂
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-12-23 DOI: 10.14314/polimery.2021.11.5
Arkadiusz Kloziński, Damian Ambrożewicz, Paulina Jakubowska, B. Dudziec, E. Andrzejewska, B. Marciniec, T. Jesionowski
The paper presents preliminary application studies of the innovative TiO2-SiO2/ POSS filler as a potential low-density polyethylene modifier. It was found that the addition of the filler increases the stiffness and hardness of the composite and slightly changes the intensity of its color.
本文介绍了新型TiO2-SiO2/POS填料作为一种潜在的低密度聚乙烯改性剂的初步应用研究。研究发现,填料的加入增加了复合材料的硬度和硬度,并略微改变了其颜色的强度。
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引用次数: 3
Synthesis of polymer-grafted gold nanoparticles via gamma radiation γ辐射合成聚合物接枝金纳米粒子
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-11-30 DOI: 10.14314/polimery.2021.11.2
Abdul Khaliq Mokhtar, N. Mohd Hidzir, I. A. Rahman, F. Mohamed, N. A. M. Radzali
The research focused on the synthesis of poly(tetrafluoroethylene) (PTFE) grafted with gold nanoparticles (AuNP). The Turkevich method, one of the common techniques of AuNP synthesis, was used to obtain an AuNP solution with a nanoparticle size of 20 nm. The PTFE-AuNP samples were subsequently irradiated and the absorbed doses were 0.5, 2, 5, 10 and 20 kGy. It was noticed that samples irradiated with 0.5 and 2 kGy were less stable and less concentrated than samples irradiated with higher doses due to aggregation and formation of precipitation after 30 days.
研究了金纳米粒子接枝聚四氟乙烯(PTFE)的合成。Turkevich方法是AuNP合成的常见技术之一,用于获得纳米颗粒尺寸为20nm的AuNP溶液。随后照射PTFE AuNP样品,并且吸收的剂量为0.5、2、5、10和20kGy。注意到,用0.5和2kGy照射的样品比用更高剂量照射的样品更不稳定,浓度更低,这是由于30天后聚集和形成沉淀。
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引用次数: 4
Pineapple leaf fibers as a reinforcement of biocomposites - an overview 菠萝叶纤维作为生物复合材料的增强材料综述
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-11-29 DOI: 10.14314/polimery.2021.11.1
R. Mohamed, N. Hapizi, M. N. Norizan, Nur Khairunnisa
Based on 87 references, a literature review was presented on PLA reinforced with pineapple leaf fibers (PALF). The properties of PALF were compared with those of other natural fibers. Mechanical properties of PLA composites and factors influencing them, such as filler content, adhesion at the interface between polymer fiber and matrix, as well as fiber length and their modification were discussed. Potential applications of PLA/PALF composites were also presented.
在87篇文献的基础上,对菠萝叶纤维增强聚乳酸(PLA)进行了综述。并与其他天然纤维的性能进行了比较。讨论了聚乳酸复合材料的力学性能及其影响因素,如填料含量、聚合物纤维与基体界面的附着力、纤维长度和改性等。展望了PLA/PALF复合材料的应用前景。
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引用次数: 1
Influence of weather conditions on the durability of acrylic-polyurethane car coatings in an industrial area 某工业区气候条件对丙烯酸-聚氨酯汽车涂料耐久性的影响
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-11-24 DOI: 10.14314/polimery.2021.10.1
Magdalena Białomazur, I. Jasińska, K. Kowalczyk, Marlena Musik, K. Pasierbiewicz, R. Wróbel
The influence of weather conditions on the durability of acrylic-polyurethane car coatings during their exposure to industrial plants (Grupa Azoty, Zakłady Chemiczne "Police" SA) was investigated. The surface structure and the general appearance of the paint coatings (after 16 months of the test) were examined using an optical microscope and a scanning electron microscope, an optical profilometer and a gloss meter. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) were used to study the composition and chemical structure of the coatings. Convex spots of various sizes were observed on the surface of the tested coatings. Quantitative profilometric analysis showed a clear increase in surface roughness. However, the results of the XPS and FTIR tests did not confirm the chemical degradation of the tested samples. It was shown that the convexities observed on the surfaces of the aged coatings were atmospheric deposits consisting mainly of oxygen, calcium, phosphorus, iron, silicon and carbon. Thorough cleaning of the surfaces resulted in their complete removal.
天气条件对丙烯酸-聚氨酯汽车涂料暴露于工业工厂(Grupa Azoty, Zakłady Chemiczne“Police”SA)期间耐久性的影响进行了调查。使用光学显微镜和扫描电子显微镜、光学轮廓仪和光泽度仪检查油漆涂层的表面结构和总体外观(经过16个月的测试)。利用x射线光电子能谱(XPS)和傅里叶变换红外光谱(FTIR)研究了涂层的组成和化学结构。在被测涂层表面观察到不同大小的凸点。定量轮廓分析表明,表面粗糙度明显增加。然而,XPS和FTIR测试的结果并没有证实被测样品的化学降解。结果表明,老化涂层表面的凸起是大气沉积物,主要由氧、钙、磷、铁、硅和碳组成。彻底清洗表面使其完全去除。
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引用次数: 1
Influence of molecular weight on dielectric properties and piezoelectric constant of poly(vinylidene fluoride) membranes obtained by electrospinning 分子量对静电纺丝聚偏氟乙烯膜介电性能和压电常数的影响
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-11-24 DOI: 10.14314/polimery.2021.10.4
Aminatul Sobirah Zahari, M. H. Mazwir, I. I. Misnon
A significant influence of the molecular weight on the dielectric properties and piezoelectric constant of poly(vinylidene fluoride) (PVDF) membranes obtained by electrospinning was demonstrated. Electrochemical impedance spectroscopy and d33 meter were used to evaluate dielectric properties and piezoelectric constant respectively. The presence of the β-phase was determined by Fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction (XRD). The membranes with the lowest molecular weight (180,000 g/mol) possessed the best dielectric properties. They also had the highest piezoelectric constant (21 pC/N) and dielectric constant (2.9 at 50 Hz) as well as the highest β-phase content (80.25%).
分子量对静电纺丝聚偏氟乙烯(PVDF)膜的介电性能和压电常数有显著影响。分别用电化学阻抗谱和d33测量仪对介电性能和压电常数进行了评价。通过傅立叶变换红外光谱(FTIR)和X射线衍射(XRD)测定了β相的存在。分子量最低(180000g/mol)的膜具有最佳的介电性能。它们还具有最高的压电常数(21pC/N)和介电常数(在50Hz时为2.9)以及最高的β相含量(80.25%)。
{"title":"Influence of molecular weight on dielectric properties and piezoelectric constant of poly(vinylidene fluoride) membranes obtained by electrospinning","authors":"Aminatul Sobirah Zahari, M. H. Mazwir, I. I. Misnon","doi":"10.14314/polimery.2021.10.4","DOIUrl":"https://doi.org/10.14314/polimery.2021.10.4","url":null,"abstract":"A significant influence of the molecular weight on the dielectric properties and piezoelectric constant of poly(vinylidene fluoride) (PVDF) membranes obtained by electrospinning was demonstrated. Electrochemical impedance spectroscopy and d33 meter were used to evaluate dielectric properties and piezoelectric constant respectively. The presence of the β-phase was determined by Fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction (XRD). The membranes with the lowest molecular weight (180,000 g/mol) possessed the best dielectric properties. They also had the highest piezoelectric constant (21 pC/N) and dielectric constant (2.9 at 50 Hz) as well as the highest β-phase content (80.25%).","PeriodicalId":20319,"journal":{"name":"Polimery","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2021-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43977360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Nanogels obtained by gamma radiation induced polymerization 射线诱导聚合法制得纳米凝胶
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-10-29 DOI: 10.14314/polimery.2021.9.1
Nurul Amirah Shafie, M. Hamzah, R. R. Ali
The influence of 2-(dimethylamino)ethyl methacrylate (DMAEMA) concentration on the temperature sensitivity of nanogels based on N-isopropylacrylamide (NIPAAM), poly(vinylpyrrolidone) (PVP), poly(ethylene glycol) diacrylate (PEGDA) by gamma radiation induced polymerization was investigated. Dynamic light scattering (DLS) and zeta potential measurements were used to characterize the nanogels. Temperature has been found to cause the nanogel particles to swell and shirnkage, allowing controlled dosing of the drug contained in capsules. The developed nanogels are promising materials with great potential for biomedical applications.
研究了甲基丙烯酸2-(二甲氨基)乙酯(DMAEMA)浓度对γ辐射聚合N-异丙基丙烯酰胺(NIPAAM)、聚乙烯吡咯烷酮(PVP)、聚乙二醇二丙烯酸酯(PEGDA)纳米凝胶温度敏感性的影响。动态光散射(DLS)和ζ电位测量用于表征纳米凝胶。研究发现,温度会导致纳米凝胶颗粒膨胀和收缩,从而可以控制胶囊中药物的剂量。所开发的纳米凝胶是一种极具生物医学应用潜力的材料。
{"title":"Nanogels obtained by gamma radiation induced polymerization","authors":"Nurul Amirah Shafie, M. Hamzah, R. R. Ali","doi":"10.14314/polimery.2021.9.1","DOIUrl":"https://doi.org/10.14314/polimery.2021.9.1","url":null,"abstract":"The influence of 2-(dimethylamino)ethyl methacrylate (DMAEMA) concentration on the temperature sensitivity of nanogels based on N-isopropylacrylamide (NIPAAM), poly(vinylpyrrolidone) (PVP), poly(ethylene glycol) diacrylate (PEGDA) by gamma radiation induced polymerization was investigated. Dynamic light scattering (DLS) and zeta potential measurements were used to characterize the nanogels. Temperature has been found to cause the nanogel particles to swell and shirnkage, allowing controlled dosing of the drug contained in capsules. The developed nanogels are promising materials with great potential for biomedical applications.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2021-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46085709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis and applications of calcium-aluminum layered double hydroxides - an overview 钙铝层状双氢氧化物的合成及应用综述
IF 1.6 4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2021-10-29 DOI: 10.14314/polimery.2021.10.2
Ira Wahadah Md Ghazali, Farah Liyana Bohari, N. Dzulkifli, A. Abdullah, I. Fatimah, Sheikh Ahmad Izaddin Sheikh Mohd Ghazali
The synthesis and application of layered calcium-aluminum double hydroxides (Ca-Al LDHs) for the encapsulation of organic anions is discussed. The mechanism of the encapsulation process was explained. These types of compounds have great potential and can be used in targeted therapies, including in drug dosing systems.
讨论了层状钙铝双氢氧化物(Ca-Al - LDHs)在有机阴离子包封中的合成及应用。说明了包封过程的机理。这些类型的化合物具有巨大的潜力,可用于靶向治疗,包括药物给药系统。
{"title":"Synthesis and applications of calcium-aluminum layered double hydroxides - an overview","authors":"Ira Wahadah Md Ghazali, Farah Liyana Bohari, N. Dzulkifli, A. Abdullah, I. Fatimah, Sheikh Ahmad Izaddin Sheikh Mohd Ghazali","doi":"10.14314/polimery.2021.10.2","DOIUrl":"https://doi.org/10.14314/polimery.2021.10.2","url":null,"abstract":"The synthesis and application of layered calcium-aluminum double hydroxides (Ca-Al LDHs) for the encapsulation of organic anions is discussed. The mechanism of the encapsulation process was explained. These types of compounds have great potential and can be used in targeted therapies, including in drug dosing systems.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2021-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44390602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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Polimery
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