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Corrosion inhibition and Adsorption characteristics of 3,4,5-trihydroxy-n-(3,4-dimethoxy benzylidene) benzo hydrazide schiff base on aluminium in different concentration of Hydrochloric acid environment 不同浓度盐酸环境中 3,4,5-三羟基-n-(3,4-二甲氧基苯亚甲基)苯甲酰肼席夫碱对铝的缓蚀和吸附特性
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00029
Ankit Sharma, S. K. Arora, Manoj Kumar Batra, Rakhi Khandelwal
In the present paper we are presenting our studies on the synthesis of Schiff bases typically formed by condensation of 3,4,5-trihydroxy benzohydrazide and 3,4-dimethoxy benzaldehyde by microwave induced irradiation, reaction showed enhanced yield and less time, easier workup. The characterization of synthesized compound has been done on the basis of elemental analysis, spectral studies (FTIR,1HNMR, Mass) and surface morphology by Scanning Electron Microscopic (SEM). The structural composition of synthesized compound has been determined by X-Ray diffraction (XRD). The inhibition property of Schiff base 3,4,5-trihydroxy –N-(3,4dimethoxy benzylidene) benzo hydrazide on the corrosion of aluminum in 0.5N HCl,1NHCl, 2N HCl were studied using weight loss technique and electrochemical studies revealed mechanistic aspects of corrosion inhibition like potentiodynamic polarization measurements indicated the nature of inhibitor is a mixed type and impedance studies supported the formation of a protective layer of inhibitor on a metal surface. Adsorption of the inhibition molecule on aluminium surface was consistent with the Langmuir isotherm.
在本文中,我们介绍了通过微波诱导辐照合成希夫碱的典型方法,即由 3,4,5-三羟基苯甲酰肼和 3,4-二甲氧基苯甲醛缩合而成。合成化合物的表征是在元素分析、光谱研究(傅立叶变换红外光谱、1HNMR、质谱)和扫描电子显微镜(SEM)表面形貌的基础上完成的。通过 X 射线衍射 (XRD) 确定了合成化合物的结构组成。利用失重技术研究了希夫碱 3,4,5-三羟基-N-(3,4-二甲氧基苯亚甲基)苯并酰肼对铝在 0.5N HCl、1NHCl 和 2N HCl 中腐蚀的抑制特性,电化学研究揭示了腐蚀抑制的机理方面,如电位极化测量表明抑制剂的性质是混合型的,阻抗研究支持抑制剂在金属表面形成保护层。抑制剂分子在铝表面的吸附与 Langmuir 等温线一致。
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引用次数: 0
Water quality management of Shrimp culture in Temporary Ponds 临时池塘养虾的水质管理
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00038
Dileep Kumar
Studies were carried out on the physico-chemical parameters of pond water used for shrimp culture. The physical parameters studied were air and water temperature, water depth and transparency, total solids (TS), total dissolved solids (TDS) and total suspended solids (TSS). Chemical parameters studied were pH, salinity, total alkalinity and dissolved inorganic phosphates. These were recorded from the day of culture till the harvest period at 30 days interval. Air and water temperature were increased from the day of culture till the harvest period. Transparency of the water used for the culture was high (40±0.1cm) during initial days and reduced thereafter. Water depth was increased from the day of culture till the harvest period. Suspended and total solids recorded were high on day 90 and total dissolved solids were high (20±1.2mg/l) on the day of culture and harvest. The level of pH recorded was high (8.3±0.0) on day 60 and the level of salinity and total alkalinity recorded was high on day 30. The dissolved inorganic phosphate level was high (1.0±0.0mg/l) on the day of culture which became reduced during the growth and harvest period of shrimp. The feed consumption and gain of body weight were also recorded on each 10 days interval. The body weight was increased as the day of culture was increased and it was positively correlated with the quantity of the feed consumed.
对用于养虾的池塘水的物理化学参数进行了研究。研究的物理参数包括气温和水温、水深和透明度、总固体(TS)、总溶解固体(TDS)和总悬浮固体(TSS)。研究的化学参数包括 pH 值、盐度、总碱度和溶解性无机磷酸盐。这些参数从养殖当天开始记录,直至收获期,每隔 30 天记录一次。气温和水温从养殖日开始上升,直至收获期。养殖用水的透明度在最初几天较高(40±0.1 厘米),之后有所降低。水深从养殖日开始增加,直至收获期。第 90 天记录的悬浮固体和总固体含量较高,养殖和收获当天记录的溶解性总固体含量较高(20±1.2 毫克/升)。第 60 天记录的 pH 值较高 (8.3±0.0),第 30 天记录的盐度和总碱度较高。养殖当天的溶解性无机磷酸盐水平较高(1.0±0.0 毫克/升),在对虾生长和收获期间有所降低。每隔 10 天记录一次饲料消耗量和体重增加情况。体重随养殖日数的增加而增加,且与饲料消耗量呈正相关。
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引用次数: 0
Interpretation of Ground Water Quality Parameters with correlation matrix of different sampling sites of Jaipur (Rajasthan) 斋浦尔(拉贾斯坦邦)不同采样点地下水质量参数与相关矩阵的解读
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00030
Meenu Mangal, Nirmala Bansal, Girja Shanker Tailor, K. Kumawat, Surendrapal Solanki, Rohit Kumar Dhaked
Water is one of the utmost important constituents on earth. This study is based on physicochemical water quality parameters (pH, EC, TDS, TH, Ca2+ Mg2+, Na+, K+, F-, Cl- NO3-SO42-) biological Parameters (BOD, COD, DO) and calculation of water quality index to assess the water quality of a four sampling sites like Muhana (S1), Vatika (S2), Shivdaspura (S3) and Tiwadi (S4) of Jaipur (Rajasthan, India). Statistical analysis had been used to calculate the correlation coefficient of different parameters with WQI and determine the Irrigational nature of ground water. Among these parameters, EC has the highest positive correlation with Na+, Cl-, F- ion concentration whereas as TDS show strong negative correlation with Ca2+.
水是地球上最重要的成分之一。本研究基于物理化学水质参数(pH、EC、TDS、TH、Ca2+ Mg2+、Na+、K+、F-、Cl- NO3-SO42-)生物参数(生化需氧量、化学需氧量、溶解氧)和水质指数计算来评估斋浦尔(印度拉贾斯坦邦)的四个采样点的水质,如 Muhana (S1)、Vatika (S2)、Shivdaspura (S3) 和 Tiwadi (S4)。统计分析用于计算不同参数与水质指数的相关系数,并确定地下水的灌溉性质。在这些参数中,EC 与 Na+、Cl-、F- 离子浓度的正相关性最高,而 TDS 则与 Ca2+ 呈强烈的负相关。
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引用次数: 0
Comparative Study of efficacy of various solvent systems in extraction of morphine from viscera 从内脏中提取吗啡的各种溶剂系统功效比较研究
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00031
Shabina Fatma, Kriti Nigam
Morphine, the main alkaloid of opium, was first obtained from poppy seeds in 1805. It is a potent analgesic, though its use is limited due to tolerance, withdrawal, and the risk of abuse. Morphine is still routinely used today, though there are a number of semi-synthetic opioids of varying strength such as codeine, fentanyl, methadone, hydrocodone, hydromorphone, meperidine, and oxycodone. Morphine is used for the management of chronic, moderate to severe pain. Opioids, including morphine, are effective for the short term management of pain. Patients taking opioids long term may need to be monitored for the development of physical dependence, addiction disorder, and drug abuse.
吗啡是鸦片的主要生物碱,1805 年首次从罂粟种子中提取。它是一种强效镇痛剂,但由于耐受性、戒断和滥用风险,其使用受到限制。如今,吗啡仍被常规使用,但也有许多不同强度的半合成阿片类药物,如可待因、芬太尼、美沙酮、氢可酮、氢吗啡酮、美培林和羟考酮。吗啡用于治疗慢性、中度至重度疼痛。包括吗啡在内的阿片类药物对短期止痛有效。长期服用阿片类药物的患者可能需要接受监测,以防出现身体依赖、成瘾症和药物滥用。
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引用次数: 0
The Study of Non-biological (not from living things) Evidence 非生物(非来自生物)证据研究
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00035
Shabina Fatma, Kiran Kumari
Forensic chemistry is the application of chemistry and its subfield, forensic toxicology, in a legal setting. A forensic chemist can assist in the identification of unknown materials found at a crime scene. Specialists in this field have a wide array of methods and instruments to help identify unknown substances.
法医化学是化学及其子领域法医毒理学在法律环境中的应用。法医化学家可以协助鉴定在犯罪现场发现的未知物质。该领域的专家拥有多种方法和仪器来帮助鉴定未知物质。
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引用次数: 0
Blue-green Algae: Diversity and Community Structure in Rice fields of Saran, Bihar 蓝绿藻:比哈尔邦萨兰稻田中的蓝绿藻多样性和群落结构
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00034
Sachi Kumari, Amrendra Kumar Jha
This study aimed to characterize the abundance of BGA in various rice ecologies of Saran (Bihar) with isolate identification and diversity indices in relation to species wise distribution. These investigations were under taken during cultivation cycle of rice in the years 2020 and 2021. The density and frequency of various BGA species was evaluated with standard methods. The study revealed occurrence of particular BGA with temporal and spatial variation, whereas abundance of BGA drastically reduced in preceding period of the study possibly due to effect of environmental constraints in the Saran district of Bihar.
本研究旨在通过分离鉴定和与物种分布相关的多样性指数,描述 BGA 在萨兰(比哈尔邦)各种水稻生态中的丰度特征。这些调查是在 2020 年和 2021 年水稻种植周期内进行的。采用标准方法评估了各种 BGA 物种的密度和频率。研究结果表明,特定 BGA 的出现具有时间和空间上的差异,而可能由于比哈尔邦萨兰地区环境制约因素的影响,BGA 的丰度在研究前期急剧下降。
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引用次数: 0
Analysis of different Explosive substance 不同爆炸物质的分析
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00036
Shabina Fatma, Kiran Kumari
Explosive wing: An explosion is a chemical reaction which is basically exothermic in nature, the products get heated up to extremely high temperature and exert high pressure that shatters the confining walls. The explosion reactions are rapid, and are associated with oxidation reaction. Releasing heat, light and large volume of gas. Explosive material: Consists of chemical compounds or their mixture which when subjected to sudden shock (mechanical or thermal) get oxidised, Releases huge amount of energy in a extremely short period of time (which can be observed in the form of explosion)
爆炸翼爆炸是一种化学反应,其本质是放热反应,产物被加热到极高的温度并产生高压,从而击碎密闭的墙壁。爆炸反应迅速,与氧化反应有关。释放热、光和大量气体。爆炸材料:由化合物或其混合物组成,当受到突然冲击(机械或热冲击)时会被氧化,在极短的时间内释放出巨大的能量(可通过爆炸形式观察到)。
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引用次数: 0
Updates on Novel Treatments for Rheumatoid Arthritis 类风湿关节炎新疗法的最新进展
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00039
Bhashpitha Naredla, Usharani Sagarla, Prasanthi. D
Chronic joint inflammation is a hallmark of the systemic inflammatory illness known as rheumatoid arthritis (RA), which ultimately causes severe disability and early death. Around 1% of people worldwide are affected by it, and women are 2-3 times more likely to be affected than males. Preclinical RA, genetic influences and environmental influences all have a role in the etiology of the illness. Since there is no recognized treatment for RA, achieving the lowest disease activity and, if possible, recovery remains the key goals of care. The literature on the various RA therapy options, their mechanisms of action, side effects and innovative drug delivery systems that are currently being used for medication administration are highlighted in this review, with non-steroidal anti-inflammatory drug delivery systems receiving the most attention. The most popular medications from each class are reviewed, including corticosteroids, non-steroidal anti-inflammatory medicines (NSAIDs), disease-modifying anti-rheumatic drugs (DMARDs) and biologics. Traditional medication therapy has various drawbacks, including inadequate bioavailability, first pass metabolism, gastrointestinal enzyme degradation, limited solubility and permeability, food interactions and toxicity. Innovative drug delivery technologies such as microspheres, nanoparticles, dendrimers, liposomes and others, hold great promise since they have been able to overcome the drawbacks of traditional drug delivery systems. The current review compares and contrasts numerous unique drug delivery methods that have been investigated for using anti-rheumatic medications, as well as the benefits of using these novel methods over traditional drug delivery methods.
慢性关节炎症是被称为类风湿性关节炎(RA)的全身性炎症性疾病的特征,最终导致严重残疾和早期死亡。全世界约有 1%的人患有这种疾病,女性患病的几率是男性的 2-3 倍。临床前 RA、遗传影响和环境影响都是该病的病因。由于目前还没有公认的治疗 RA 的方法,因此将疾病活动度降到最低,并在可能的情况下实现康复仍是治疗的主要目标。本综述重点介绍了有关各种 RA 治疗方案、其作用机制、副作用以及目前用于给药的创新给药系统的文献,其中非甾体抗炎药物给药系统最受关注。本综述介绍了各类最常用的药物,包括皮质类固醇、非甾体抗炎药(NSAIDs)、改善病情抗风湿药(DMARDs)和生物制剂。传统药物疗法存在各种缺点,包括生物利用度不足、首过代谢、胃肠道酶降解、溶解度和渗透性有限、食物相互作用和毒性。微球、纳米颗粒、树枝状聚合物、脂质体等创新给药技术能够克服传统给药系统的缺点,因此大有可为。本综述比较和对比了已研究用于抗风湿药物的多种独特给药方法,以及使用这些新型方法与传统给药方法相比的优势。
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引用次数: 0
Extraction of Poison from Viscera 从内脏中提取毒药
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00037
Shabina Fatma, Kiran Kumari
The examination of viscera, stomach wash, vomit, etc to determine poisons of vegetable origin, inorganic salts, metals, synthetic drugs, pesticides, alcohol, and other general poisons. Examination of powders, pills, capsules, syringes, vials, etc. Determination of alcohol in blood and urine in drunk driving cases.
检查内脏、洗胃液、呕吐物等,以确定植物源毒物、无机盐、金属、合成药物、杀虫剂、酒精和其他一般毒物。检查粉末、药丸、胶囊、注射器、药瓶等。在酒后驾车案件中测定血液和尿液中的酒精含量。
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引用次数: 0
Reproductive Performance and Larval quality of Freshwater Prawn Broodstock of different water resources 不同水资源淡水对虾幼体的繁殖性能和幼体质量
Pub Date : 2023-11-11 DOI: 10.52711/2349-2988.2023.00032
Dileep Kumar
The present study was conducted to compare the reproductive performance and offspring quality of adults of the giant freshwater prawn, Macrobrachium rosenbergii broodstock from four different sites (1) Ganga riverine wild breeders (GW) (2) Ganga riverine pond-reared (GP) breeders (3) Gandak riverine wild breeders (gp); and (4) Gandak riverine pond-reared breeders (gw) were grown out in culture ponds and collected as broodstock at the end of grow-out culture period. M. rosenbergii females were individually stocked for 120 days in three 1500L freshwater recirculation system tanks and fed a commercial diet. Ovarian development, molting and spawning events were checked daily. In addition a number of egg and larval quality parameters were determined. The breeding frequency, fecundity, egg laying success rate, egg dimensions and egg hatchability were not significantly different between animals from the four different sources. However, there were significant differences in terms of offspring quality between the different broodstock sources. Individual dry weight, larval development rate, time to reach the post-larval stage, post-larval survival and tolerance to ammonia toxicity were all better in offspring originating from all broods did not significantly differ in terms of breeding frequency, fecundity and egg dimensions. However, larval quality of Ganga riverine wild and Ganga riverine pond-reared breeders was markedly better than that of Gandak riverine wild reared stock and Gandak riverine pond-reared stock in terms of larval development, survival and post larval production. These results indicate that broodstock sourcing deserves proper attention in hatchery operations of M. rosenbergii. It furthermore proves that domesticated (pond-reared) animals are not necessarily inferior as breeders as compared to wild-sourced animals. The results may also point out the potential to selectively breed stocks with improved characteristics adapted to the local culture environment.
本研究比较了来自四个不同地点(1)赣江河畔野生种虾(GW);(2)赣江河畔池塘饲养种虾(GP);(3)犍为河畔野生种虾(gp);以及(4)犍为河畔池塘饲养种虾(gw)的大宗淡水对虾成体的繁殖性能和后代质量。在三个 1500L 的淡水循环系统水箱中分别放养雌性罗氏沼虾 120 天,并投喂商品饲料。每天检查卵巢发育、蜕皮和产卵情况。此外,还测定了一些卵子和幼虫质量参数。四种不同来源动物的繁殖频率、受精率、产卵成功率、卵的尺寸和卵的孵化率没有显著差异。然而,不同来源的鱼种在后代质量方面存在显著差异。在个体干重、幼虫发育率、达到幼虫后期阶段的时间、幼虫后期存活率和对氨毒性的耐受性方面,所有育雏来源的后代都更好,但在繁殖频率、繁殖力和卵的大小方面没有显著差异。然而,在幼虫发育、存活率和幼虫后期产量方面,赣江野生种群和赣江池塘饲养种群的幼虫质量明显优于甘达克河野生种群和甘达克河池塘饲养种群。这些结果表明,在罗氏鲑的孵化操作中,应适当注意雏鱼的来源。此外,它还进一步证明,驯化(池塘饲养)的动物与野生来源的动物相比,其繁殖能力并不一定差。研究结果还指出,有可能选择性地培育出适应当地养殖环境、具有改良特性的种群。
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引用次数: 0
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