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Optimization of Two-Step Alkali Process of Lignin Removal from Basswood 椴木两步法碱法脱除木质素工艺的优化
Igor Wachter, Tomáš Štefko, Marek Rolinec
Abstract The aim of the research described in this article was to optimize the basic sulphur process of lignin removal from the raw radially cut basswood (Tilia Cordata) pieces of various thicknesses. Lignin removal took place chemically in several consecutive steps in which the influence of individual parameters was investigated (solutions of NaOH + Na2SO3, KOH + Na2SO3, its concentrations, time of leaching, efficacy of whitening agents, effect of sample washing between individual baths, etc.). Through experiments, it was found that the change of fresh NaOH + Na2SO3 solution during the experiment had no significant effect. In contrast, skipping the washing of the samples with boiling distilled water after the hydroxide bath had a significant effect on the rate and efficiency of lignin removal with H2O2 in the following step. When comparing the lignin removal efficiency of NaOH + Na2SO3 and KOH + Na2SO3, the delignification process was clearly demonstrated to be more effective using the KOH + Na2SO3 solution. Application of the above-mentioned procedures has helped to streamline the lignin removal process from solid basswood.
摘要以不同厚度的椴木(tila Cordata)为原料,研究了碱硫脱除木质素的工艺条件。木质素的去除是在连续的几个步骤中进行的,其中研究了单个参数的影响(NaOH + Na2SO3, KOH + Na2SO3溶液,其浓度,浸出时间,增白剂的效果,单个浴之间的样品洗涤效果等)。通过实验发现,实验过程中新鲜NaOH + Na2SO3溶液的变化没有明显的影响。相比之下,跳过氢氧化物浴后的沸腾蒸馏水洗涤,对下一步H2O2脱除木质素的速度和效率有显著影响。通过对比NaOH + Na2SO3和KOH + Na2SO3溶液对木质素的去除率,发现KOH + Na2SO3溶液对木质素的去除率更高。上述方法的应用有助于简化实椴木脱除木质素的过程。
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引用次数: 2
Elimination of Excessive Noise at the Open Office Workplace 消除开放式办公室工作间的过度噪音
P. Čekan, M. Rusko, Ján Iľko, Dieter Pietrucha
Abstract Open-plan office is a distraction to employee performance. According to a study by Cornell University, Ithaca, NY, working in a noisy office with ringtones, business conversations and office equipment sounds can lead to heart disease, because workplace noise causes stress. The paper focuses on noise analysis in an open-office work environment, the effect of noise on the selected operational position, as determined by standardized noise exposure LEX, 8h. Based on the results obtained, appropriate measures were proposed.
开放式办公室会影响员工的工作表现。根据纽约州伊萨卡市康奈尔大学的一项研究,在嘈杂的办公室里工作,伴随着铃声、商务谈话和办公设备的声音会导致心脏病,因为工作场所的噪音会导致压力。本文重点分析了开放式办公室工作环境中的噪声,噪声对选定工作位置的影响,由标准化噪声暴露LEX, 8h确定。在此基础上,提出了相应的措施。
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引用次数: 3
Environment and Safety Impacts of Additive Manufacturing: A Review 增材制造的环境和安全影响:综述
Eva Buranská, I. Buranský, L. Morovič, Katarína Líška
Abstract The paper is focused on additive manufacturing (AM) which is the process of producing objects from a three-dimensional (3D) model by joining materials layer by layer, as opposed to the subtractive manufacturing methodologies [1], directly from raw material in powder, liquid, sheet, or a filament form without the need for moulds, tools, or dies. The article demonstrates potential environmental implications of additive manufacturing related to the key issues including energy use, occupational health, waste and lifecycle impact. AM provides a cost-effective and time-efficient way to fabricating products with complicated geometries, advanced material properties and functionality. Based on this review, we identified that additive manufacturing will have a significant societal impact in the near future. A critical technical review of the promises and potential issues of AM is beneficial for advancing its further development.
本文的重点是增材制造(AM),它是通过一层一层地连接材料从三维(3D)模型生产物体的过程,而不是减法制造方法[1],直接从粉末、液体、片材或长丝形式的原材料中生产物体,而不需要模具、工具或模具。本文展示了增材制造对环境的潜在影响,涉及能源使用、职业健康、废物和生命周期影响等关键问题。增材制造提供了一种具有成本效益和时间效率的方法来制造具有复杂几何形状,先进材料性能和功能的产品。基于这一审查,我们确定增材制造将在不久的将来产生重大的社会影响。对增材制造的前景和潜在问题进行关键的技术审查有利于推进其进一步发展。
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引用次数: 4
Study of Explosion Characteristics of the Wheat Flour Dust Clouds in Dependence of the Particle Size Distribution 粒径分布对小麦粉粉尘云爆炸特性的影响研究
R. Kuracina, Zuzana Szabová, Eva Buranská
Abstract Fire protection is an important part of the industry where flammable and explosive dusts are found. Production, storage and transport of food powders such as flour can be very dangerous in terms of explosiveness. The article deals with the measurement of explosion characteristics of wheat flour dust. The measurements were carried out according to EN 14034-1+A1:2011 Determination of explosion characteristics of dust clouds. Part 1: Determination of the maximum explosion pressure pmax of dust clouds and the maximum rate of explosion pressure rise according to EN 14034-2+A1:2012 Determination of explosion characteristics of dust clouds - Part 2: Determination of the maximum rate of explosion pressure rise (dp/dt)max of dust clouds. A sample of wheat flour with a median particle size 84 μm exhibits the maximum explosion pressure 7.00 bar at the concentration of 600 g.m−3 and then explosion constant is 16.9 bar.s−1.m. A sample of wheat flour with a median particle size 50 μm exhibits the maximum explosion pressure 7.97 bar at the concentration of 1000 g.m−3 and the explosion constant 54.9 bar.s−1.m.Based on the results of the measurements, we found that the particle size distribution has a significant influence on the explosion parameters of the wheat flour samples.
摘要消防是存在易燃易爆粉尘的行业的重要组成部分。面粉等食品粉末的生产、储存和运输在爆炸性方面是非常危险的。本文对小麦粉粉尘的爆炸特性进行了测试。测量根据EN 14034-1+A1:2011粉尘云爆炸特性的测定进行。第1部分:根据EN 14034-2+A1:2012测定粉尘云的最大爆炸压力pmax和最大爆炸压力上升率。粉尘云爆炸特性的测定。第2部分:测定粉尘云的最大爆炸压力上升率(dp/dt)max。对中位粒径为84 μm的小麦粉试样,在600 g.m - 3的浓度下,最大爆炸压力为7.00 bar,爆炸常数为16.9 bar.s - 1 m。中位粒径为50 μm的小麦粉样品,在浓度为1000 g.m - 3时,最大爆炸压力为7.97 bar,爆炸常数为54.9 bar.s - 1 m。根据测量结果,我们发现粒度分布对小麦粉样品的爆炸参数有显著影响。
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引用次数: 2
Heat of Combustion as the Key Fire Characteristics of Electrical Cables 燃烧热是电缆火灾的关键特性
J. Martinka, P. Rantuch, Martina Hladová, Janka Sulová, A. Nečas, Denis Benko, K. Balog
Abstract This scientific study deals with investigation of the heat of combustion and effective heat of combustion of selected electrical cables. Two different electrical cables for rated voltage of 0.6/1 kV were investigated. Both cables were power three-core with cross-section area of each core of 1.5 mm2. The cores of both cables were made of a bar cooper wire. Insulations of conductors of both cables were made of silane cross-linked polyethylene without any inorganic filler, while the bedding and outer sheath were made of polyethylene-based copolymer (the beddings were filled with two fillers - aluminium hydroxide and calcium carbonate, while the outer sheath were filled only with aluminium hydroxide). Reaction to fire class of both cables was B2ca, s1, d0, a1. The main difference in the investigated cables was that the core of one of them was wrapped in a glass mica tape (this cable showed circuit integrity maintenance under fire conditions during 180 minutes). The heat of combustion and effective heat of combustion were determined by the oxygen bomb calorimeter according to the ISO 1716:2018 standard. The highest effective heat of combustion showed the insulation of wires (for both cables 42.47 ± 0.03 MJ/kg), lower value showed outer sheath (interval form13.61 to 15.26 MJ/kg) and the lowest value was determined for bedding (interval from 4.69 to 6.39 MJ/kg). The effective heath of combustion per unit of length of both investigated cables lies in the interval from 1.37 to 1.38 MJ/m. Therefore, there is no significant difference in effective heats of combustion of the electrical cables investigated.
摘要本科学研究涉及选定电缆的燃烧热和有效燃烧热的研究。研究了两种额定电压为0.6/1 kV的电缆。两根电缆均为电源三芯,每芯截面积为1.5 mm2。两根电缆的芯都是用一根铜线制成的。两根电缆导体的绝缘材料均为硅烷交联聚乙烯,不含无机填料,层理和外护套由聚乙烯基共聚物制成(层理内填充氢氧化铝和碳酸钙两种填料,外护套内仅填充氢氧化铝)。两根电缆的火灾反应等级分别为B2ca、s1、d0、a1。所研究的电缆的主要区别在于其中一根电缆的核心包裹在玻璃云母带中(该电缆在火灾条件下180分钟内显示电路完整性维护)。燃烧热和有效燃烧热采用氧弹量热计根据ISO 1716:2018标准测定。有效燃烧热最高的是导线绝缘(42.47±0.03 MJ/kg),最低的是护套(区间为13.61 ~ 15.26 MJ/kg),最低的是层理(区间为4.69 ~ 6.39 MJ/kg)。两种电缆单位长度的有效燃烧健康度在1.37 ~ 1.38 MJ/m之间。因此,所研究的电缆的有效燃烧热没有显着差异。
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引用次数: 2
Determination of Fire Risk of Selected Alcohols 选定醇类着火危险的测定
Denis Benko, J. Martinka, Tomáš Štefko, Igor Wachter, P. Rantuch
Abstract The aim of the research was to determine the fire risk of selected flammable liquids (alcohols). Four alcohols, methanol, ethanol, propanol, and butanol, were chosen for the research. Flammable liquids were examined in a cone calorimeter at 0 and 5 kW.m−2 heat fluxes. Both, the cone calorimeter and test procedure, were in accordance with ISO 5660-1:2015. The fire risk was evaluated mainly on the basis of heat release rate, effective heat of combustion and carbon monoxide yield. Comparison of the achieved parameters of selected alcohols shows that the fire risk of the investigated alcohols increases with increasing the molar mass of alcohol and applied heat flow.
摘要本研究的目的是确定选定的易燃液体(酒精)的火灾风险。选择甲醇、乙醇、丙醇和丁醇四种醇进行研究。在0和5 kW.m - 2热通量下,用锥形量热计检测易燃液体。锥形量热计和测试程序均符合ISO 5660-1:2015。火灾危险性评价主要依据放热率、有效燃烧热和一氧化碳产率。通过对所选醇类参数的比较可知,所选醇类的火灾危险性随着醇的摩尔质量和外加热流的增大而增大。
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引用次数: 0
Timing Parameters of Pyrotechnic Igniter Based on Magnesium Powder 基于镁粉的烟火点火器定时参数研究
V. Pelikan, R. Kuracina, Zuzana Szabová
Abstract Chemical igniters are used in the study of dispersed dusts. Energy released during their use is defined by EN 14034 at 2 x 5 kJ. The Standard does not define the exact composition of the pyrotechnic mixture. The condition of using the igniter is to release energy according to the Standard. This article is focused on pyrotechnic composition with magnesium powder. It deals with various ways of activating, preparing and sealing the pyrotechnic mixture in the igniter. These values are important for setting up a device for studying the explosive properties of dispersed dusts.
摘要化学点火器应用于粉尘的研究。在使用过程中释放的能量由EN 14034定义为2 x 5 kJ。本标准没有规定烟火混合物的确切成分。使用点火器的条件是按标准释放能量。本文主要研究了含镁粉的烟火药成分。介绍了在点火器中激活、制备和密封烟火混合物的各种方法。这些数值对于建立研究分散粉尘爆炸特性的装置具有重要意义。
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引用次数: 0
Microalgae Harvesting: A Review 微藻收获研究进展
Alexandra Kucmanová, K. Gerulová
Abstract Microalgae are photosynthetic autotrophic microscopic organisms growing in a range of aquatic and terrestrial habitats. They produce a huge complex of compounds in their surroundings which are of important use to humans. Their commercial use lies in human nutrition, animal and aquatic feed, in cosmetics products, natural pigments, pharmaceutical industry, bio-fertilizer for extracting high-value molecules, stable isotope biochemicals, and for the synthesis of antimicrobial, antiviral, antibacterial and anticancer drugs. Therefore, it is necessary to develop a simple, effective and economically advantageous method for harvesting the algal products. Magnetic separation is a simple separation process. Different synthesis methods have been used by researchers to obtain magnetic particles of varying size and shapes according to the algae to be studied. Chemical co-precipitation method has been the most commonly used method, which helps in synthesizing magnetic particles of the micro to nano range. Naked, coated and surface modified are the general types of magnetic particles used for algal harvesting with its own advantages and disadvantages.
微藻是一种光合自养微生物,生长在各种水生和陆生栖息地。它们在周围环境中产生大量对人类有重要用途的化合物。其商业用途包括人类营养、动物和水产饲料、化妆品、天然色素、制药工业、提取高价值分子的生物肥料、稳定同位素生化物质,以及合成抗菌、抗病毒、抗菌和抗癌药物。因此,有必要开发一种简单、有效、经济的藻类产品采收方法。磁选是一种简单的分离过程。研究人员使用不同的合成方法来获得不同大小和形状的磁性颗粒,根据要研究的藻类。化学共沉淀法是合成微纳米级磁性粒子最常用的方法。裸磁颗粒、包覆磁颗粒和表面改性磁颗粒是藻类收获的常用磁颗粒,各有优缺点。
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引用次数: 8
Study of Fire Characteristics of Industrial Dust 工业粉尘的燃烧特性研究
Zuzana Szabová, R. Kuracina
Abstract The article deals with the determination of fire characteristics of industrial dust samples. Particle size granulometry and determination of explosion parameters according to EN 14034 (Lower Explosion Limit LEL, Pmax, Kst) are presented. The minimum ignition temperatures of the dust layer and dispersed dust from the hot surface according to EN ISO / IEC 80079-20-2: 2016 were measured. It was found that LEL is 60 g.m−3, Pmax is 8.61 bar, and Kst is 89 bar.s−1.m. The minimum ignition temperature (MIT) of dust layer is 280 ° C and the minimum ignition temperature of dispersed dust is 400 ° C.
摘要本文论述了工业粉尘样品的燃烧特性的测定。根据en14034(爆炸下限LEL, Pmax, Kst)介绍了粒度、粒度测定和爆炸参数的测定。根据EN ISO / IEC 80079-20- 2:20 16的要求,测量了粉尘层和热表面分散粉尘的最低着火温度。LEL为60 g m−3,Pmax为8.61 bar, Kst为89 bar.s−1.1 m。粉尘层的最低着火温度为280℃,分散粉尘的最低着火温度为400℃。
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引用次数: 1
Risks Resulting from Reverse of Modification of Expansion Weapons 扩展武器反向改装带来的风险
P. Čekan, E. Belica, D. R. D. Sobrino
Abstract In general, the probability of an undesirable event occurring and its consequence is the gist of the risk characteristics. Thus, risk is part of all the activities that a person performs. The use of weapons and possession of weapons is a great risk. It makes difference who owns them, where they are used and under what circumstances. At present, the great risk is also associated with the possession and use of expansion weapons, also called acoustic weapons. This issue is still very sensitive; the aim of this article is to highlight the risks of reverse modification of such weapons. Publication of this contribution does not support or otherwise supports the use and sale of any type of weapons.
一般来说,不良事件发生的概率及其后果是风险特征的主旨。因此,风险是一个人从事的所有活动的一部分。使用和拥有武器是一种巨大的风险。谁拥有它们,在哪里使用它们以及在什么情况下使用它们都是有区别的。目前,巨大的风险还与拥有和使用扩张型武器有关,扩张型武器也被称为声武器。这个问题仍然非常敏感;本文的目的是强调对这类武器进行反向修改的危险。这篇文章的发表不支持或以其他方式支持任何类型武器的使用和销售。
{"title":"Risks Resulting from Reverse of Modification of Expansion Weapons","authors":"P. Čekan, E. Belica, D. R. D. Sobrino","doi":"10.2478/rput-2019-0017","DOIUrl":"https://doi.org/10.2478/rput-2019-0017","url":null,"abstract":"Abstract In general, the probability of an undesirable event occurring and its consequence is the gist of the risk characteristics. Thus, risk is part of all the activities that a person performs. The use of weapons and possession of weapons is a great risk. It makes difference who owns them, where they are used and under what circumstances. At present, the great risk is also associated with the possession and use of expansion weapons, also called acoustic weapons. This issue is still very sensitive; the aim of this article is to highlight the risks of reverse modification of such weapons. Publication of this contribution does not support or otherwise supports the use and sale of any type of weapons.","PeriodicalId":21013,"journal":{"name":"Research Papers Faculty of Materials Science and Technology Slovak University of Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74618698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Research Papers Faculty of Materials Science and Technology Slovak University of Technology
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