CeF3-doped oxyfluoride scintillating glasses with the composition 50SiO2 – 20Al2O3 – 10BaF2 – 10Gd2O3 – 10Li2O (SABGL) were synthesized via the melt-quenching method under a carbon-reducing environment to stabilize Ce3+. The optical absorption spectra confirmed the characteristic 4f → 5d transitions of Ce3+ and a slight red shift associated with structural modifications at higher CeF3 contents. Photoluminescence (PL) measurements revealed strong blue emission centered at ∼438 nm, increasing monotonically with CeF3 concentration up to 1.5 wt%. Excitation spectra showed distinct bands from both Ce3+ and Gd3+, confirming efficient Gd3+ → Ce3+ energy transfer. Time-resolved PL decay exhibited tri-exponential behavior, indicating multiple Ce3+ environments typical of an amorphous glass host, with the fastest component reflecting efficient radiative relaxation. Under X-ray excitation, all samples produced clear blue radioluminescence, and X-ray imaging of an IC chip demonstrated spatial resolutions of 11.0–11.8 LP/mm, comparable to commercial BGO. Radiation-shielding parameters calculated using WinXCom showed high mass attenuation coefficients and elevated effective atomic numbers (Zeff ≈ 32–36 at low energies), attributed to the incorporation of Ba, Gd, and Ce. Compared with a Cs2O-Fe2O3-P2O5 reference glass, the SABGL system exhibited superior attenuation below ∼0.07 MeV, confirming its suitability for low-energy photon detection and shielding. Overall, the combined scintillation performance, high spatial resolution, and favorable photon-interaction properties demonstrate that CeF3-doped SABGL glasses, particularly the 1.5 wt% composition is promising, scalable candidates for low-energy X-ray imaging and radiation-shielding applications.
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