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Data-driven environmental and operational assessment of industrial lithium brine extraction 数据驱动的工业锂盐水提取环境和操作评估
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-06 DOI: 10.1016/j.resconrec.2026.108779
Meiqi Yang , Hongxu Chen , Kaijie Yang , Zhiyong Jason Ren
Global lithium demand is rising rapidly, but the environmental performance of industrial-scale extraction remains poorly understood. The costs, freshwater requirements, chemical inputs, and energy use of multistage evaporation ponds and direct lithium extraction (DLE) are rarely assessed under real operating conditions, and DLE is seldom examined as a complete industrial process. Here, we present a comprehensive data-driven assessment of industrial lithium brine projects worldwide, applying hierarchical clustering, correlation analysis, and Bayesian statistics to compare evaporation ponds and DLE. Our results show that brine chemistry plays a decisive role in process feasibility and environmental burdens. High-quality brines enable evaporation ponds with lower water and energy use but limited recovery, while low-quality brines require DLE, which achieves higher recovery at much higher resource costs. By linking impurity ratios, recovery efficiency, and chemical demand, this work establishes a systematic framework connecting brine quality to environmental impacts, providing guidance for sustainable lithium production.
全球锂需求正在迅速增长,但工业规模开采的环境绩效仍鲜为人知。多级蒸发池和直接锂提取(DLE)的成本、淡水需求、化学投入和能源使用很少在实际操作条件下进行评估,也很少将其作为一个完整的工业过程进行研究。在这里,我们提出了一个全面的数据驱动的评估全球工业锂盐水项目,应用层次聚类,相关分析和贝叶斯统计比较蒸发池和DLE。结果表明,卤水化学在工艺可行性和环境负担方面起着决定性作用。高质量的卤水使蒸发池的水和能源消耗较低,但回收率有限,而低质量的卤水需要DLE,以更高的资源成本实现更高的回收率。通过将杂质比、回收率和化学需求联系起来,本研究建立了一个将盐水质量与环境影响联系起来的系统框架,为可持续锂生产提供指导。
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引用次数: 0
Recycling colored silk fibroin from silk waste for versatile applications in dyeing, adsorbing and printing 从废丝中回收彩色丝素,用于印染、吸附和印花等多种用途
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-03 DOI: 10.1016/j.resconrec.2025.108771
Suju Fan , Jianming Chen , John H. Xin , Xungai Wang
Colored textile waste has been a concern due to the complexity of textile recycling and environmental issues in waste landfills. This study creatively repurposed dyed silk waste for versatile applications in fabric dyeing, water cleaning, and cotton printing. First, dyed silk waste was reclaimed into colored silk fibroin (CSF) for wool dyeing at 75 °C and pH 2.5, achieving 76% dye reuse. After further recycling the dye effluent, over 63% silk fibroin (SF) was recovered, and the remaining water was suitable for reuse in CSF dyeing. Second, the recycled SF could be pulverized into powders as adsorbents, featuring a maximum adsorption capacity of 82.79 mg/g for acid dyes. Finally, wastewater-adsorbed SF was used as pigments for cotton printing with good washing and crocking fastness. In this work, a waste recycling strategy is proposed to promote the resource conservation and waste valorization by producing new colored fabrics and lowering dye contamination.
由于纺织品回收的复杂性和垃圾填埋场的环境问题,有色纺织品废料一直受到关注。本研究创造性地重新利用染色丝绸废料,将其应用于织物染色、水洗和棉印花等多种用途。首先,将染色废丝回收成彩色丝素(CSF),在75℃、pH 2.5条件下对羊毛进行染色,染料回用率达到76%。染料废水进一步回收后,丝素(SF)回收率超过63%,剩余水适合用于CSF染色。其次,回收的SF可粉碎成粉末作为吸附剂,对酸性染料的最大吸附容量为82.79 mg/g。最后,利用废水吸附的SF作为棉印花颜料,具有良好的耐洗牢度和耐腐蚀牢度。在此工作中,提出了一种废物回收策略,通过生产新的彩色织物和降低染料污染来促进资源节约和废物增值。
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引用次数: 0
Optimization of ultrasound-assisted extraction of brominated flame retardants from acrylonitrile butadiene styrene (ABS) derived from e-waste: Efficiency and life cycle assessment 超声波辅助提取电子垃圾中丙烯腈-丁二烯-苯乙烯(ABS)中溴化阻燃剂的优化:效率和生命周期评估
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-02 DOI: 10.1016/j.resconrec.2025.108770
Imane Belyamani , Layla Gripon , Laurent Cauret
The removal of brominated flame retardants (BFRs) from acrylonitrile butadiene styrene derived from e-waste was investigated using ultrasound-assisted extraction (UAE). A Taguchi experimental design evaluated the effects of solvent type, particle size, and solvent-to-polymer ratio on extraction performance. Optimal conditions (diethyl ether, <500 µm particles, 1:10 ratio) enabled 98.5 % BFR removal, thus reducing persistent organic pollutants content below regulatory limits. Ethanol, while more environmentally favorable, achieved lower removal efficiencies. Structural and thermal analyses confirmed the integrity of the polymer and supported effective debromination, with increased glass transition temperatures and reduced thermal degradation. Life cycle assessment identified solvent use, drying, and micronization as the most environmentally impactful stages. Incineration showed the lowest impacts, within a system boundary excluding metal recovery, outperforming UAE combined with mechanical recycling. Despite its drawbacks, incineration remains the most sustainable option for high-BFR plastics under current conditions, highlighting the need for a realistic evaluation of circular strategies.
采用超声辅助萃取法(UAE)研究了从电子垃圾中提取的丙烯腈-丁二烯-苯乙烯中去除溴化阻燃剂(BFRs)的工艺。田口实验设计评估了溶剂类型、粒径和溶剂与聚合物比对萃取性能的影响。最佳条件(乙醚,<;500µm颗粒,1:10比例)使98.5%的BFR去除率,从而将持久性有机污染物含量降低到法规限制以下。乙醇虽然更环保,但去除效率较低。结构和热分析证实了聚合物的完整性,并支持有效的脱溴,提高了玻璃化转变温度,减少了热降解。生命周期评估确定溶剂使用、干燥和微粉化是对环境影响最大的阶段。在不包括金属回收的系统边界内,焚烧表现出最低的影响,优于联合机械回收的阿联酋。尽管有其缺点,在当前条件下,焚烧仍然是高bfr塑料最可持续的选择,突出了对循环战略进行现实评估的必要性。
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引用次数: 0
Clean heating, cleaner cities: The effect of northern winter clean heating policy on carbon emission reduction and pollution reduction in China 清洁供暖,清洁城市:北方冬季清洁供暖政策对中国碳减排和污染减排的影响
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-01 DOI: 10.1016/j.resconrec.2025.108762
Qingshen Kong , Yi Xiao , Haonan Yang , Huan Huang
Coal-burning heating in China has long contributed to severe air pollution and high energy consumption. China launched the Northern Clean Heating Policy (CHPP) in 2017 to promote a shift to clean energy for heating. Using a multi-period DID model with panel data from 2014 to 2022, this study assesses the impact of CHPP on carbon emission intensity (CEI) and sulfur dioxide emission intensity (SEI). Results show that CHPP significantly reduces CEI and SEI. Four mediating variables, including total and average levels of government environmental attention and clean energy consumption, play key roles in the effectiveness of the policy. The effect is more notable in cities with higher temperatures, lower resource dependence, lower energy consumption, classification in the second pilot wave, key governance regions, and dispersed spatial layouts. As a sustainable development strategy, CHPP promotes green development through clean heating, providing valuable practical references for global environmental protection and the sustainable energy transition.
长期以来,中国的燃煤供暖造成了严重的空气污染和高能耗。2017年,中国启动了北方清洁供暖政策(CHPP),以促进向清洁能源供暖的转变。利用2014 - 2022年面板数据的多期DID模型,评估了CHPP对碳排放强度(CEI)和二氧化硫排放强度(SEI)的影响。结果表明,CHPP显著降低了CEI和SEI。政府环境关注度和清洁能源消费的总水平和平均水平四个中介变量对政策的有效性起关键作用。在温度较高、资源依赖程度较低、能耗较低、第二波试点分类、重点治理区域和空间布局分散的城市中,这种效应更为显著。热电联产作为一种可持续发展战略,通过清洁供热促进绿色发展,为全球环境保护和能源可持续转型提供了宝贵的实践参考。
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引用次数: 0
The changing trend of global food and nutrition production inequality 全球粮食和营养生产不平等的变化趋势
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-31 DOI: 10.1016/j.resconrec.2025.108765
Wenli Qiang , Jiayi Liu , Xing Ma , Khizar Abbas , Lifei Feng , Gang Liu
Global food and nutrition production has undergone significant changes over the past few decades. Yet the inequality of nutrition and its sources on various scales remains poorly understood. By analyzing detailed production and nutrition coefficient data for 80 food categories across 182 countries and regions from 1986 to 2020, we reveal varying trends in inequality across each food category. The inequality in oil crops, vegetables, stimulants, pulses, and sugars has increased, whereas inequality in fruits, livestock, and aquatic products has decreased over time. The primary source of global food production inequality in 1986 was the difference between income groups. However, by 2020, the focus had shifted to internal inequality within income groups. Cereals had contributed most to inequalities in energy, protein, mineral, and vitamin production, while oil crops were the main driver of fat inequality. Our results suggest that it is essential to implement nutrition-oriented food production strategies and trade policies to effectively improve global food security.
过去几十年来,全球粮食和营养生产发生了重大变化。然而,营养的不平等及其来源在不同的尺度上仍然知之甚少。通过分析1986年至2020年182个国家和地区80种粮食类别的详细生产和营养系数数据,我们揭示了每种粮食类别之间不平等的不同趋势。随着时间的推移,油料作物、蔬菜、兴奋剂、豆类和糖的不平等程度有所增加,而水果、牲畜和水产品的不平等程度有所下降。1986年全球粮食生产不平等的主要原因是收入群体之间的差异。然而,到2020年,焦点已经转移到收入群体内部的不平等。谷物是造成能量、蛋白质、矿物质和维生素产量不平等的主要原因,而油料作物是造成脂肪不平等的主要原因。我们的研究结果表明,实施以营养为导向的粮食生产战略和贸易政策是有效改善全球粮食安全的关键。
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引用次数: 0
Efficient lithium recovery from industrial lithium iron phosphate (LFP) blackmass using formic acid-enabled hydrometallurgy 甲酸湿法冶金从工业磷酸铁锂(LFP)黑质中高效回收锂
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-30 DOI: 10.1016/j.resconrec.2025.108766
Ayesha Tasawar , Daniel Dotto Munchen , Alexander Birich , Rungsima Yeetsorn , Walter Sebastian Scheld , Waritnan Wanchan , Benjamin Butz , Bernd Friedrich
As millions of LFP batteries reach their end of life, the challenge of selectively extracting lithium from industrial blackmass, loaded with impurities, has become a focal point for sustainable innovation in battery recycling. However, industrial-scale LFP recycling remains technically challenging due to the complex composition of real battery waste, including high graphite content, binders, and metallic inclusions that undermine conventional leaching processes. In this research study, a selective, green hydrometallurgical approach tailored for impurity-rich LFP blackmass is presented. Using only trace (“hint of acid”) amounts of formic acid with hydrogen peroxide and two-step leaching, achieving ∼94.5% lithium extraction in the two-step formic acid route, whereas the trace sulfuric acid + H₂O₂ condition delivers the highest selectivity, reaching >95% lithium recovery with negligible iron co-leaching, and producing lithium carbonate as an end product (confirmed by XRD and SEM) without the environmental burden of aggressive reagents or high-temperature treatment. Key to this process is careful control of solution pH and oxidation conditions, allowing a scalable, cost‑effective route to close the loop on LFP materials, and proving that the high‑yield lithium recovery and environmental responsibility can be achieved in the same process.
随着数以百万计的LFP电池寿命的结束,从工业黑质中选择性地提取锂的挑战已经成为电池回收可持续创新的焦点。然而,工业规模的LFP回收在技术上仍然具有挑战性,因为实际电池废物的成分复杂,包括高石墨含量、粘合剂和金属夹杂物,这些都会破坏传统的浸出工艺。在本研究中,提出了一种针对富含杂质的LFP黑质定制的选择性绿色湿法冶金方法。在过氧化氢和两步浸出中仅使用微量(“微量酸”)的甲酸,在两步甲酸路线中实现了~ 94.5%的锂提取,而微量硫酸+ h2o条件具有最高的选择性,在忽略铁共浸出的情况下,锂回收率达到>;95%,最终产品碳酸锂(通过XRD和SEM证实)没有腐蚀性试剂或高温处理的环境负担。该工艺的关键是仔细控制溶液pH值和氧化条件,允许可扩展的,成本有效的路线来闭合LFP材料的循环,并证明在同一过程中可以实现高产量的锂回收和环境责任。
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引用次数: 0
Identification of common types of plastics by vibrational spectroscopic techniques 用振动光谱技术鉴定普通塑料
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-30 DOI: 10.1016/j.resconrec.2025.108767
Maria P.Garcia Tovar , Maria A.Villarreal Blanco , Oliva M. Primera-Pedrozo , Macy K. Christianson , Chih-Feng Wang , Pavel Valencia Acuña , John H. Miller , Luis de la Torre , Samuel P.Hernández Rivera
Polyethylene Terephthalate (PET), High-Density Polyethylene (HDPE), Polyvinyl Chloride (PVC), Low-Density Polyethylene (LDPE), Polypropylene (PP), and Polystyrene (PS) account for most plastic use worldwide, with production nearing 380 million tons annually. A considerable portion enters municipal solid waste and landfills, creating long-term environmental concerns. Scaling recycling operations requires automated sorting technologies, with spectroscopy and machine learning offering promising solutions. In this study, a six-class convolutional neural network (CNN) was developed for plastic identification using vibrational spectroscopies. Raman Scattering (RS) spectra collected from recycling samples enabled accurate chemical differentiation while assessing the influence of visible features such as color. A CNN trained on RS data achieved 100 % classification accuracy. To strengthen field applicability, Attenuated Total Reflectance–Fourier Transform Infrared (ATR-FTIR) spectroscopy was incorporated, achieving 95% accuracy with a similar CNN model. These findings demonstrate the potential of integrating spectroscopy with deep learning for reliable plastic classification, advancing development of scalable, field-ready recycling technologies.
聚对苯二甲酸乙二醇酯(PET)、高密度聚乙烯(HDPE)、聚氯乙烯(PVC)、低密度聚乙烯(LDPE)、聚丙烯(PP)和聚苯乙烯(PS)占全球塑料使用量的大部分,年产量接近3.8亿吨。相当一部分进入城市固体废物和垃圾填埋场,造成长期的环境问题。扩展回收操作需要自动分拣技术,光谱和机器学习提供了有前途的解决方案。在这项研究中,开发了一个六类卷积神经网络(CNN)用于振动光谱的塑料识别。从回收样品中收集的拉曼散射(RS)光谱可以在评估颜色等可见特征的影响时进行精确的化学区分。在RS数据上训练的CNN达到了100%的分类准确率。为了增强现场适用性,采用了衰减全反射-傅里叶变换红外(ATR-FTIR)光谱,使用类似的CNN模型,准确率达到95%。这些发现表明,将光谱学与深度学习相结合,可以实现可靠的塑料分类,促进可扩展的现场回收技术的发展。
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引用次数: 0
Weaving the energy transition web: Structural dynamics and drivers of the global lithium-cobalt-nickel trade network 编织能源转型网络:全球锂钴镍贸易网络的结构动态和驱动因素
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-30 DOI: 10.1016/j.resconrec.2025.108768
Chao Wang , Kangyu Tan , Ming K. Lim , Pezhman Ghadimi
The accelerating global energy transition has created unprecedented demand for critical minerals essential for batteries and clean energy technologies. While existing research has examined individual metal trade networks, the core scientific question of how these minerals jointly evolve as an integrated “energy transition web” remains unanswered. This study addresses this gap by constructing a multi-layer aggregated trade network for lithium-cobalt-nickel spanning 2010–2024. It uses complex network and quadratic assignment procedure (QAP) regression to identify mechanisms shaping network dynamics and their implications for supply-chain resilience. The results show that the network has transformed from sparse to a dense “small-world” structure, dominated by an intensifying Asian core. Traditional drivers such as economic scale have weakened, whereas environmental and strategic factors have emerged as primary drivers. These findings demonstrate that the global critical-mineral system is evolving into more interconnected yet more politically segmented energy-transition web, highlighting emerging vulnerabilities and informing future resource-security strategies.
全球能源转型加速,对电池和清洁能源技术所必需的关键矿物产生了前所未有的需求。虽然现有的研究已经检查了单个金属贸易网络,但这些矿物如何共同演变为一个综合的“能源过渡网络”的核心科学问题仍然没有答案。本研究通过构建一个跨越2010-2024年的锂钴镍多层聚合贸易网络来解决这一差距。它使用复杂网络和二次分配过程(QAP)回归来确定形成网络动力学的机制及其对供应链弹性的影响。结果表明,该网络已从稀疏结构转变为密集的“小世界”结构,并以不断强化的亚洲核心为主导。经济规模等传统驱动因素减弱,环境和战略因素成为主要驱动因素。这些发现表明,全球关键矿产系统正在演变成相互联系更加紧密但政治上更加分割的能源转型网络,突出了新出现的脆弱性,并为未来的资源安全战略提供信息。
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引用次数: 0
End-of-life portable lithium-ion batteries in Japan: Generation, collection system effectiveness, and unidentified flows 日本的报废便携式锂离子电池:产生、收集系统的有效性和未确定的流量
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-26 DOI: 10.1016/j.resconrec.2025.108754
Masahiro Oguchi , Atsushi Terazono , Kazuo Hasunuma
End-of-life (EoL) management of lithium-ion batteries (LIBs) presents significant environmental and safety challenges. We estimated Japan’s EoL portable LIB generation and assessed the effectiveness of its collection systems. A survey of 33 electrical and electronic equipment categories found that 82 % of them contained LIBs, with many incorporating built-in batteries, leading to disposal in inappropriate waste streams. In 2020, approximately 8160 tonnes of EoL LIBs were generated, with six key categories—smartphones, laptops, tablets, cordless vacuum cleaners, power banks, and motor-assisted bicycles. Although Japan’s official collection schemes cover 77 % of EoL generation, only 14 % is actually collected. Possible paths for the rest 86 % include disposal in municipal solid waste, export with secondhand products, and untracked collections from businesses. Even considering these, however, the destination of nearly 40 % of EoL LIBs remains unknown, highlighting the need to identify remaining flows to enhance collection frameworks that ensure sustainable resource management and safe disposal.
锂离子电池(lib)的寿命终止(EoL)管理提出了重大的环境和安全挑战。我们估计了日本的EoL便携式LIB生成,并评估了其收集系统的有效性。一项针对33种电气和电子设备类别的调查发现,82%的产品含有锂电池,其中许多产品内置电池,导致其被丢弃在不适当的废物流中。2020年,大约有8160吨的EoL lib被生产出来,主要有六个类别——智能手机、笔记本电脑、平板电脑、无线吸尘器、移动电源和电动辅助自行车。尽管日本官方的收集计划覆盖了77%的EoL发电量,但实际上只收集了14%。其余86%的可能途径包括城市固体废物处理,二手产品出口,以及企业无追踪收集。然而,即使考虑到这些,近40%的EoL lib的目的地仍然未知,这突出表明需要确定剩余的流量,以加强收集框架,确保可持续的资源管理和安全处置。
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引用次数: 0
Regional dynamics of Nd stocks, flows, and required industrial capacities: insights from EV and wind turbine material flows 钕储量、流量和所需工业能力的区域动态:来自电动汽车和风力涡轮机材料流的见解
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-26 DOI: 10.1016/j.resconrec.2025.108761
Olivier Karl Anton Heldwein , Fridolin Krausmann , Johann Fellner
Neodymium is a critical raw material essential for electric vehicle (EV) motors and wind turbines in a decarbonized energy system. This study applies stock-driven, dynamic material flow analysis to investigate stock-flow development of Nd in light-duty EVs and wind turbines under the IEA’s Net-Zero-Emissions Scenario across five world regions and explores recycling potentials to meet regional demand. It shows that China keeps exporting as primary production exceeds domestic demand and could leverage refining capacity for recycling. In Europe, secondary supply temporarily surpasses demand as stocks decrease, while India’s circularity potential is hampered by continuous stock-growth. In the US, planned primary production and recycling could cover demand by the 2040s. Globally, secondary supply could meet >60 % of Nd-demand in light-duty EVs and wind in 2050, with mining decreasing from its 2035 peak to current levels. Fast mining expansion and the subsequent shift to secondary production require strategic planning and political support.
在脱碳能源系统中,钕是电动汽车(EV)电机和风力涡轮机必不可少的关键原材料。本研究采用库存驱动的动态物料流分析,在国际能源署(IEA)的净零排放情景下,在全球五个地区调查轻型电动汽车和风力涡轮机中钕的库存流动发展情况,并探索回收潜力,以满足区域需求。这表明,由于初级生产超过国内需求,中国继续出口,可以利用炼油能力进行回收。在欧洲,由于库存减少,二级市场供应暂时超过需求,而印度的循环潜力受到库存持续增长的阻碍。在美国,计划中的初级生产和回收可以在21世纪40年代之前满足需求。在全球范围内,到2050年,二次供应可以满足轻型电动汽车和风能60%的钕需求,采矿从2035年的峰值下降到目前的水平。矿业的快速扩张和随后向二次生产的转变需要战略规划和政治支持。
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引用次数: 0
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Resources Conservation and Recycling
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