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Pilot-scale production of high-purity vaterite-type calcium carbonate from desalination brine using industrial by-products 利用工业副产品脱盐盐水中试生产高纯度水晶石型碳酸钙
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-27 DOI: 10.1016/j.resconrec.2026.108807
Sehun Kim , Won Jo , Seungwon Ihm , Abdallatif Abdalrhman , Jinuk Heo , Myoung-Jin Kim
The rapid growth of global desalination raises concerns over high-salinity brine disposal. Vaterite, a valuable but unstable polymorph of CaCO₃, is difficult to mass-produce. This study reports the first pilot-scale production of high-purity vaterite using actual desalination brine and cement kiln dust. A 1-ton system was built and operated at the SWA-WTIIRA desalination complex in Jubail, Saudi Arabia. Through calcium elution and carbonation, conditions were optimized to achieve ≥95 % vaterite content and sub-3 µm particle size. Controlling carbonation temperature and drying prevented transformation to calcite. The process yielded porous, spherical vaterite particles (>20 m²/g surface area, >98.5 % purity). Techno-economic analysis estimated production costs at $2.5/kg, significantly below commercial pharmaceutical-grade vaterite. These findings demonstrate a scalable, low-cost strategy for valorizing desalination brine and industrial by-products, offering both environmental and economic benefits.
全球海水淡化的快速增长引发了人们对高盐度盐水处理的担忧。碳酸钙₃是一种有价值但不稳定的多晶型,很难大规模生产。本研究报告了首次利用实际海水淡化盐水和水泥窑粉尘中试生产高纯度水晶石。在沙特阿拉伯朱拜勒的SWA-WTIIRA海水淡化厂建造并运行了一个1吨重的系统。通过钙洗脱和碳酸化,优化工艺条件,得到≥95%的水晶石含量和小于3µm的粒径。控制碳酸化温度和干燥可防止方解石的转变。该工艺产生多孔的球形水晶石颗粒(表面积为20 m²/g,纯度为98.5%)。技术经济分析估计生产成本为每公斤2.5美元,大大低于商业制药级杂物矿。这些发现证明了一种可扩展的、低成本的策略,可以使海水淡化盐水和工业副产品增值,同时提供环境和经济效益。
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引用次数: 0
Applying semi-supervised learning algorithms in real-environment solid waste classification 半监督学习算法在现实环境固体废物分类中的应用
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-23 DOI: 10.1016/j.resconrec.2026.108806
Dong–Ying Lan , Pin–Jing He , Hui–Huang Zou , Rong–Rong Kan , Yi Wang , Fan Lü , Hua Zhang
To improve intelligent solid waste identification, this study developed semi-supervised learning (SSL) models utilizing pseudo-labeling and consistency regularization techniques. Based on 10,261 image patches covering multiple categories of recyclable solid waste, we evaluated four SSL models (FixMatch, FlexMatch, FreeMatch, and SoftMatch models) across varying labeled data ratio (10%–90%) against a supervised learning (SL) baseline. Results demonstrated that the classification accuracy for the test dataset significantly improved (p < 0.05) as the proportion of labeled data increased in the training dataset, rising from 0.843 ± 0.012 to 0.954 ± 0.004. In the external validation, SSL models exhibited notably stronger robustness and generalizability compared to the SL model which achieved an accuracy of only 0.653 ± 0.122. The FixMatch model, in particular, attained an accuracy of 0.810 ± 0.013. These findings underscore the potential of SSL-based approaches in solid waste recycling systems.
为了提高智能固体废物识别,本研究利用伪标签和一致性正则化技术开发了半监督学习(SSL)模型。基于覆盖多种可回收固体废物类别的10,261个图像补丁,我们根据监督学习(SL)基线,在不同的标记数据比率(10%-90%)下评估了四种SSL模型(FixMatch, FlexMatch, FreeMatch和SoftMatch模型)。结果表明,随着标记数据在训练数据集中所占比例的增加,测试数据集的分类准确率显著提高(p < 0.05),从0.843±0.012提高到0.954±0.004。在外部验证中,SSL模型的鲁棒性和泛化性明显强于SL模型,后者的准确率仅为0.653±0.122。特别是FixMatch模型,达到了0.810±0.013的精度。这些发现强调了基于ssl的方法在固体废物回收系统中的潜力。
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引用次数: 0
Probabilistic modeling of European Li-ion battery production and recycling 欧洲锂离子电池生产和回收的概率模型
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-02-03 DOI: 10.1016/j.resconrec.2026.108817
Loïs Miraux, Tanguy Manescau, Vincent Bos
The deployment of lithium-ion battery production and recycling capacities is central to the EU’s ambitions for strategic autonomy and climate neutrality, yet announced projects face high uncertainty. Using a new database of project announcements, a probabilistic framework and a system dynamics model of battery demand, aging, and second-life use, this study estimates effective capacities for European Gigafactories, Spokes and Hubs over 2020-2035. Results indicate that cell production could reach 750-855 GWh/yr by 2035 (45-51% of announcements), far below projected demand exceeding 1,500 GWh/yr. With unconstrained international waste imports supplying them, recycling capacities could reach 0.72 Mt batteries/yr (Spokes) and 0.28 Mt black mass/yr (Hubs), yielding closed-loop recycling rates of 9-10% for key metals. However, without imports, domestic feedstock scarcity causes 30-50% attrition of recycling capacities, especially if electric vehicle batteries enter second-life, worsening circularity. Overall, meeting EU circularity and strategic autonomy goals will require faster deployment and reliable feedstock access.
锂离子电池生产和回收能力的部署对欧盟实现战略自主和气候中和的雄心至关重要,但已宣布的项目面临着很高的不确定性。利用项目公告的新数据库、概率框架和电池需求、老化和二次使用的系统动力学模型,本研究估计了2020-2035年欧洲超级工厂、辐条和枢纽的有效产能。结果表明,到2035年,电池产量将达到750-855吉瓦时/年(占公告的45-51%),远低于超过1,500吉瓦时/年的预计需求。在不受限制的国际废物进口供应下,回收能力可达到72万吨电池/年(辐条)和28万吨黑质量/年(轮毂),关键金属的闭环回收率为9-10%。然而,在没有进口的情况下,国内原料短缺导致回收能力消耗30-50%,特别是如果电动汽车电池进入二次使用阶段,循环性就会恶化。总体而言,实现欧盟循环和战略自治目标需要更快的部署和可靠的原料接入。
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引用次数: 0
Falling forests, rising emissions: Does the road to economic development pass through protected rainforests? 森林减少,排放增加:经济发展的道路要经过受保护的雨林吗?
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-02-03 DOI: 10.1016/j.resconrec.2026.108819
Spyros Foteinis
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引用次数: 0
Corrigendum to ‘Food waste shock for reducing methane emissions from sewer pipelines’ “减少污水管道甲烷排放的厨余冲击”的勘误表
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-31 DOI: 10.1016/j.resconrec.2026.108820
Mohamadali Mohit , Om Prakash , Masoud Makian , Ali Ashraf Joolaei , Xueqing Shi , Jong-Han Lee , Dong-Hoon Kim
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引用次数: 0
Wasting the Risk, or Risking the Waste? Understanding the trends of critical raw material loss into waste streams during copper and aluminium processing 浪费风险,还是浪费风险?了解铜和铝加工过程中关键原材料流入废物流的趋势
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-22 DOI: 10.1016/j.resconrec.2026.108803
Ella Lausberg , Joël Brugger , Rahul Ram , John R. Owen , Deanna Kemp , Micheal S. Moats , Jonathan Hamisi , Vanessa N.L. Wong
Many critical raw materials (CRM) necessary in the transition to carbon-neutral energy reside in the waste streams of mining projects, as they are by-products and often not recovered alongside the primary metal. This work aims to document (i) the loss and potential recovery of by-product metals during the host commodity processing and (ii) the consequences of non-recovery, via a multi-scale risk–reward analysis. The information on the deportment of by-product metals through processing circuits is crucial for treating them as a resource, without which they risk near-permanent loss when treated as ‘waste’. We review the deportment of tellurium and selenium as by-products of copper processing; and gallium, scandium and rare earth elements in aluminium processing, as these CRMs are representative of different geological settings, mining methods, processing circuits, and waste types. We classify the scale of the effects of their non-recovery using three risk categories: comprehensive differentiation covers individual risks (environmental, social, governance and economic); complex differentiation covers the interactions of compounding factors that alter the magnitude and timeframe of their impact; and ecological/systems diffraction comprises systematic, long-term effects that disproportionally affect vulnerable communities and locations globally. We offer a new perspective on by-product elements that rely on the production chain of primary commodities but are rarely recovered economically because of the lack of refinery infrastructure and technologies. We suggest that incentives to promote waste management strategies that preserve CRM resources for concurrent recovery or future reprocessing could substantially mitigate supply risks, while reducing social and environmental risk and impact.
向碳中性能源过渡所需的许多关键原材料(CRM)存在于采矿项目的废物流中,因为它们是副产品,通常不能与原金属一起回收。这项工作旨在通过多尺度风险-回报分析,记录(i)在东道国商品加工过程中副产品金属的损失和潜在回收,以及(ii)不回收的后果。通过加工电路处理副产物金属的信息对于将其作为一种资源至关重要,否则当它们被视为“废物”时,它们将面临近乎永久的损失。综述了铜加工副产物碲和硒的研究进展;铝加工中的镓、钪和稀土元素,因为这些crm代表了不同的地质环境、采矿方法、加工电路和废物类型。我们使用三种风险类别对其无法恢复的影响规模进行分类:综合区分涵盖个体风险(环境、社会、治理和经济);复杂差异包括改变其影响的大小和时间范围的复合因素的相互作用;生态/系统衍射包括对全球脆弱社区和地区造成不成比例影响的系统性长期影响。我们对依赖初级商品生产链的副产品元素提供了新的视角,但由于缺乏炼油基础设施和技术,这些副产品很少能经济地回收。我们建议,鼓励促进废物管理策略,以保留CRM资源用于并发回收或未来再处理,可以大大减轻供应风险,同时减少社会和环境风险和影响。
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引用次数: 0
Priorities for enhancing resilience of SDG causal network from a human-nature perspective 从人与自然的角度加强可持续发展目标因果网络弹性的优先事项
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-10 DOI: 10.1016/j.resconrec.2025.108774
Yiming Su , Guangjin Zhou , Mingyuan Wang , Xiaoyun Li , Tao Liang , Lingqing Wang , Jian Hu , Jixi Gao , Wenwu Zhao , Siyuan Tao , Peter E. Holm , Jörg Rinklebe , Riqi Zhang , Cong-Qiang Liu , Rong Gong , Yizhong Huan
Strong interactions among six Sustainable Development Goals (SDGs)—food (2), water (6), energy (7), economy (8), climate (13), and ecology (15) (FWEECE)—reflect the core nexus of the human-nature relationship under global change. However, research on their causal interactions is limited, and priorities for global transformation remain elusive. Here, we developed an integrated index to assess global progress in SDG coordination-evenness, and applied Gated Recurrent Unit, Panel Vector Autoregression, and link prediction models to capture the SDG causal network among 33 targets in FWEECE. Using machine learning and network analysis, we then prioritized SDG targets. We further simulated network perturbations to identify priority actions that enhance network resilience. The results indicated limited global progress in both the coordination and evenness of these SDGs since 2000, with target 2.4 (sustainable agriculture) identified as the key priority for future progress. Mitigating high-weight trade-offs, especially from targets 15.2 (sustainable forest management) to 8.2 (economic productivity), while strengthening 84% of synergies, led by 6.6 (water-related ecosystem) to 2.c (food price stability), presents an effective strategy for advancing FWEECE. Our study provides new insights into human-earth coupling, contributing global governance transformations for the 2030 Agenda.
粮食(2)、水(6)、能源(7)、经济(8)、气候(13)和生态(15)六个可持续发展目标(FWEECE)之间的密切互动反映了全球变化下人与自然关系的核心联系。然而,对其因果关系的研究有限,全球转型的优先事项仍然难以捉摸。在这里,我们开发了一个综合指数来评估可持续发展目标协调均匀性的全球进展,并应用门控循环单元、面板向量自回归和链接预测模型来捕捉FWEECE中33个目标之间的可持续发展目标因果网络。通过机器学习和网络分析,我们确定了可持续发展目标的优先级。我们进一步模拟网络扰动,以确定增强网络弹性的优先行动。结果表明,自2000年以来,全球在这些可持续发展目标的协调和均匀性方面进展有限,目标2.4(可持续农业)被确定为未来进展的关键优先事项。减少高权重权衡,特别是从目标15.2(可持续森林管理)到8.2(经济生产力),同时加强84%的协同效应,从目标6.6(与水有关的生态系统)到目标2.c(粮食价格稳定),是推进森林和生态环境评估的有效战略。我们的研究为人类-地球耦合提供了新的见解,有助于实现2030年议程的全球治理转型。
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引用次数: 0
Securing low-carbon rare earth supply for the renewable energy sector: Demand, circularity, and carbon mitigation of neodymium and dysprosium 确保可再生能源部门的低碳稀土供应:钕和镝的需求、循环性和碳减排
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-13 DOI: 10.1016/j.resconrec.2026.108784
Peize Wang , Tingting Liu , Gangqi Cheng , Yufeng Wu , Shengnan Wang , Kun Zhu
With the rapid growth of China’s new energy vehicles (NEVs) and wind power sectors, demand for neodymium and dysprosium is surging, while their supply is constrained by limited reserves, mining policies, and carbon-intensive production. Yet existing studies have rarely examined resource constraints and emission reduction targets within a unified framework, and have not fully integrated demand, supply, and the mitigation effects of recycling. To address this gap, this study develops an integrated material flow and carbon emission assessment framework for neodymium and dysprosium under the renewable energy transition and projects their supply-demand dynamics. The results show that by 2060, cumulative demand from NEVs is projected to reach 535.2-985.6 kilotonnes (kt) of neodymium and dysprosium combined, while wind power is expected to require a further 182.4-455.4 kt in total. Supply forecasts indicate that neodymium demand can be met under policy liberalization, but gaps emerge under quota-controlled and worsen when accounting for production losses. In contrast, dysprosium faces long term shortages across all scenarios. Recycling plays a critical role: neodymium recycling can largely meet renewable demand and reduce dependence on mining, while dysprosium recycling remains limited due to scarcity. A carbon emission assessment framework is also developed for neodymium and dysprosium production. Power mix optimization could reduce emissions by 7.1-16.5 million tonnes CO₂-equivalent (Mt CO₂-eq) for neodymium and 3.6-8.5 Mt CO₂-eq for dysprosium, while recycling contributes 3.3-5 and 1-1.4 Mt CO₂-eq reductions, respectively. Combining recycling with a cleaner power mix is essential to securing rare earth supply and reducing lifecycle emissions.
随着中国新能源汽车(nev)和风力发电行业的快速增长,对钕和镝的需求激增,而它们的供应受到有限储量、采矿政策和碳密集型生产的限制。然而,现有的研究很少在统一的框架内审查资源限制和减排目标,也没有充分综合考虑回收的需求、供应和缓解效果。为了解决这一差距,本研究开发了可再生能源转型下钕和镝的综合物质流和碳排放评估框架,并预测了它们的供需动态。结果显示,到2060年,新能源汽车的累计需求预计将达到535.2-985.6千吨(kt)钕和镝的总和,而风电预计将进一步需要182.4-455.4千吨(kt)。供应预测表明,在政策自由化的情况下,钕的需求可以得到满足,但在配额控制下出现缺口,考虑到生产损失,缺口会进一步扩大。相比之下,镝在所有情况下都面临长期短缺。回收利用发挥着至关重要的作用:钕的回收利用可以在很大程度上满足可再生需求,减少对采矿的依赖,而镝的回收利用由于稀缺性仍然有限。还为钕和镝的生产制定了碳排放评估框架。动力结构优化可以减少钕的710 - 1650万吨二氧化碳当量(Mt CO₂-eq)和镝的360 - 850万吨二氧化碳当量(Mt CO₂-eq),而回收分别可以减少330 -5万吨和1- 140万吨二氧化碳当量。将回收利用与更清洁的能源组合相结合,对于确保稀土供应和减少生命周期排放至关重要。
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引用次数: 0
Environmental intensities of consumption reveal synergy between welfare and environmental policies beyond income effect 消费的环境强度揭示了福利与环境政策之间超越收入效应的协同效应
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-17 DOI: 10.1016/j.resconrec.2026.108791
Juudit Ottelin, Julia Sborz, Meng Jiang, Konstantin Stadler
The efficiency of public versus private sectors has interested policymakers and researchers for decades. Management research has highlighted that private ownership can improve the efficiency of production. However, regarding environmental efficiency, the public sector often outperforms the private sector. Furthermore, the so-called synergy hypothesis suggests that countries with a strong public sector might be better positioned to address environmental problems than other countries, because of their already existing governance related to welfare. Yet, empirical evidence so far has mostly suggested otherwise. Here, we contribute to these debates by 1) providing an analysis of the consumption-based environmental intensities of government versus household consumption and 2) testing the synergy hypothesis using the environmental intensities as the measure of environmental performance. Our results show that government consumption has lower carbon, material, and land use intensities compared to household consumption – particularly in services, and in most countries, also in energy. Yet, in several countries, households have lower intensities for tangible goods and food, potentially pointing to shortcomings in public procurement policies. We also find support for the synergy hypothesis: countries with higher public social expenditure (% of GDP) tend to have lower environmental intensities, even when controlling for final demand per capita.
几十年来,政策制定者和研究人员一直对公共部门与私营部门的效率感兴趣。管理学研究强调,私有制可以提高生产效率。然而,在环境效率方面,公共部门的表现往往优于私营部门。此外,所谓的协同作用假说认为,拥有强大公共部门的国家可能比其他国家更有能力解决环境问题,因为它们已经存在与福利有关的治理。然而,迄今为止的经验证据大多表明情况并非如此。在这里,我们通过以下方式为这些争论做出贡献:1)对基于消费的政府与家庭消费的环境强度进行分析;2)使用环境强度作为环境绩效的衡量标准来检验协同效应假设。我们的研究结果表明,与家庭消费相比,政府消费的碳、材料和土地使用强度更低——尤其是在服务业,在大多数国家,能源消费也是如此。然而,在一些国家,家庭对有形商品和食品的需求强度较低,这可能表明公共采购政策存在缺陷。我们还发现了对协同假说的支持:公共社会支出(占GDP的百分比)较高的国家往往具有较低的环境强度,即使在控制人均最终需求的情况下也是如此。
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引用次数: 0
Global production potential and environmental benefits of alternative proteins from biowaste 生物废物中替代蛋白质的全球生产潜力和环境效益
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-15 Epub Date: 2026-01-29 DOI: 10.1016/j.resconrec.2026.108818
Xue Bai , Yi Gong , Wei Wei , Wen Wang , Minghao Zhuang , Yi Yang
Upcycling biowaste into insect and microbial proteins can enhance food system circularity; however, their global production potential and environmental benefits remain uncertain. In 2020, global biowaste could generate 58 Mt of insect protein or 146 Mt of microbial protein—exceeding global meat protein or meeting 53%–100% of soybean meal protein demand. Using Life Cycle Assessment combined with global scenario analysis, substituting soybean meal with alternative proteins yields moderate GHG reductions (-13 to -25 kg CO2e kg⁻¹ protein). Substituting meat protein yields larger GHG reductions (-107 to -1230 kg CO2e kg⁻¹ protein), alongside decreases in terrestrial acidification (-0.003 to -1.2 kg SO2e), eutrophication (-0.2 to -1.2 kg PO4e) and fine particulate matter (-0.03 to -0.24 kg PM2.5e). Globally replacing soybean meal first and then progressively meat could mitigate 0.9–12.2 Gt CO2e yr⁻¹ by 2050. However, achieving higher mitigation levels require greater technological innovation, institutional support, and cultural shifts.
将生物垃圾升级为昆虫和微生物蛋白质可以增强食物系统的循环;然而,它们的全球生产潜力和环境效益仍然不确定。到2020年,全球生物废弃物可产生5800万吨昆虫蛋白或1.46亿吨微生物蛋白,超过全球肉类蛋白或满足53%-100%的豆粕蛋白需求。使用生命周期评估结合全球情景分析,用替代蛋白质替代豆粕可产生适度的温室气体减排(-13至-25千克二氧化碳- 2e千克毒血症)。替代肉类蛋白质可以产生更大的温室气体减排(-107至-1230千克二氧化碳当量),同时减少陆地酸化(-0.003至-1.2千克二氧化硫当量),富营养化(-0.2至-1.2千克PO4e)和细颗粒物(-0.03至-0.24千克PM2.5e)。到2050年,在全球范围内先取代豆粕,然后逐步取代肉类,可以每年减少0.9-12.2亿吨二氧化碳(毒血症)。然而,实现更高的缓解水平需要更大的技术创新、制度支持和文化转变。
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引用次数: 0
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