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Life-cycle assessment and techno-economic analysis of negative carbon sustainable aviation fuels from paper sludge 造纸污泥负碳可持续航空燃料的生命周期评价及技术经济分析
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-31 DOI: 10.1016/j.resconrec.2026.108824
Jiawei Huang, Yinqiao Wang, Sunkyu Park, Kai Lan
Paper sludge, a solid waste from paper mills, is a promising feedstock for producing sustainable bioproducts and decarbonizing the pulp and paper industry. This study developed a life cycle assessment and techno-economic analysis to explore the environmental and economic feasibility of sustainable aviation fuel (SAF) produced from paper sludge with carbon capture and storage (CCS). The analysis is integrated with full-scale process design and rigorous simulation models developed in Aspen Plus. Our results show that, with CCS, the global warming potential (GWP) of SAF reaches negative carbon at –166.4 to –108.7 g CO2eq/MJ with a minimum fuel selling price (MFSP) of $8.0–$10.0/gasoline gallon equivalent (GGE). Without CCS, the GWP increases to 38.8–71.6 g CO2eq/MJ, but the MFSP decreases to $5.2–$7.0/GGE. SAF production from paper sludge with CCS offers a potential solution to advance the decarbonization of the aviation sector and pulp and paper industries toward net-zero emissions.
造纸污泥是一种来自造纸厂的固体废物,是生产可持续生物产品和脱碳制浆造纸工业的有前途的原料。本研究开发了生命周期评估和技术经济分析,以探索采用碳捕获和储存(CCS)技术从纸污泥中生产可持续航空燃料(SAF)的环境和经济可行性。该分析与Aspen Plus开发的全尺寸工艺设计和严格的仿真模型相结合。我们的研究结果表明,采用CCS, SAF的全球变暖潜能值(GWP)在- 166.4至- 108.7 g CO2eq/MJ时达到负碳,最低燃料销售价格(MFSP)为8.0 - 10.0美元/汽油加仑当量(GGE)。没有CCS, GWP增加到38.8 ~ 71.6 g CO2eq/ GGE,而MFSP降低到5.2 ~ 7.0美元/GGE。利用CCS技术从纸污泥中生产SAF,为推动航空业和纸浆造纸行业实现净零排放的脱碳提供了一个潜在的解决方案。
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引用次数: 0
Global greenhouse gas emissions from coal-fired power plants 燃煤电厂的全球温室气体排放
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-31 DOI: 10.1016/j.resconrec.2026.108808
Mikalai Filonchyk , Michael P. Peterson , Haowen Yan , Liang Zhou , Lifeng Zhang , Yi He , Shuwen Yang
Coal-fired power plants are one of the primary sources of greenhouse gas (GHG) emissions worldwide, releasing approximately 13.6939 GtCO2eq annually. This study analyses GHG emissions from 2422 coal-fired power plants (6525 units) with a total installed capacity of 2125 GW. Using a bottom-up approach, CO2, CH4, and N2O emissions are calculated based on individual plant characteristics, including capacity, coal type, and load factor. The findings indicate a predominance of subcritical coal-fired power plants, the least efficient, with specific emissions of 6.95 MtCO2eq/GW. Bituminous coal is the largest emission source, accounting for 41 % of global GHG emissions from coal power. Significant regional disparities were identified with over 70 % of global coal power emissions originating from China, India, and the United States. China alone accounts for more than half (52 %) of total emissions. Special attention is given to power plants using unknown types of coal that are responsible for 31 % of emissions, highlighting substantial gaps in monitoring systems. The results indicate that while advanced coal technologies, including ultra-supercritical units and carbon capture and storage (CCS), can reduce emissions to some extent, their mitigation potential within the existing coal fleet remains limited relative to the goals of the Paris Agreement.
燃煤电厂是全球温室气体(GHG)排放的主要来源之一,每年释放约13.6939亿吨二氧化碳当量。本研究分析了总装机容量为2125吉瓦的2422座燃煤电厂(6525台)的温室气体排放情况。采用自下而上的方法,CO2、CH4和N2O的排放量是基于单个工厂的特性计算的,包括产能、煤炭类型和负荷系数。研究结果表明,亚临界燃煤电厂占主导地位,效率最低,具体排放量为6.95 MtCO2eq/GW。烟煤是最大的排放源,占全球煤电温室气体排放量的41%。研究发现,全球超过70%的煤电排放来自中国、印度和美国,存在显著的地区差异。仅中国就占了总排放量的一半以上(52%)。特别关注的是使用未知类型煤炭的发电厂,这些发电厂占排放量的31%,突出了监测系统的巨大差距。结果表明,虽然包括超超临界装置和碳捕集与封存(CCS)在内的先进煤炭技术可以在一定程度上减少排放,但相对于《巴黎协定》的目标,它们在现有煤炭船队中的减排潜力仍然有限。
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引用次数: 0
PRecTimber 2.0: Forecasting quantitative and qualitative potentials for wood circularity in Germany, Finland, and Sweden pretimber 2.0:预测德国、芬兰和瑞典木材循环的数量和质量潜力
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-30 DOI: 10.1016/j.resconrec.2026.108813
Vijhay Krisshna Mahenthren , Gabriele Weber-Blaschke , Mark Hughes , Michael Risse
National bioeconomy strategies in Germany, Finland, and Sweden are expected to increase wood demand, putting pressure on already strained forest resources. Circularity of wood products can reduce this demand by improving resource efficiency, but barriers like uncertain availability and quality of post-consumer wood hinder implementation. This study optimizes and extends the PRecTimber model to forecast post-consumer wood quantities and qualities in Germany (revised with quality information), Finland, and Sweden. By 2050, predicted post-consumer wood volumes are 14.11 Mt in Germany, 1.64 Mt in Finland, and 2.74 Mt in Sweden, mainly from the construction sector. Our quality assessment methodology with scenario analysis (status quo S0 and improved scenarios S1–S2 with +10 and +20 percentage-point gains in key quality factors) reveals that the shares of post-consumer construction sawnwood suitable for lifespan extension and material recycling, respectively, are 25 % and 59 % under S0, 36 % and 50 % under S1, and 49 % and 38 % under S2. Leveraging these quantity and quality insights, policy reforms can support industries and technological innovation to optimize the use of post-consumer wood.
德国、芬兰和瑞典的国家生物经济战略预计将增加木材需求,给已经紧张的森林资源带来压力。木材产品的循环利用可以通过提高资源效率来减少这种需求,但消费后木材的可得性和质量不确定等障碍阻碍了实施。本研究优化并扩展了PRecTimber模型,以预测德国(根据质量信息修订)、芬兰和瑞典的消费后木材数量和质量。到2050年,预计消费后的木材量在德国为1411万吨,芬兰为164万吨,瑞典为274万吨,主要来自建筑部门。我们的质量评估方法与情景分析(现状S0和改进情景S1 - S2,关键质量因素提高10个百分点和20个百分点)显示,消费后建筑锯木适用于延长使用寿命和材料回收的比例分别为S0下的25%和59%,S1下的36%和50%,S2下的49%和38%。利用这些数量和质量的见解,政策改革可以支持行业和技术创新,以优化消费后木材的使用。
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引用次数: 0
Reconfiguring China’s interprovincial rice distribution to support low-carbon goals under climate change 重新配置中国省际稻米分配,支持气候变化下的低碳目标
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-30 DOI: 10.1016/j.resconrec.2026.108816
Jintao Yang , Fang-He Zhao , Manchun Li , Penghui Jiang , Zhepeng Hu
Current understanding of low-carbon food distribution is limited by the lack of observed grain flow data and forward-looking scenario analysis. In this study, we construct China’s interprovincial rice distribution network for 2020 using 30,524 observed trade records. We then project provincial rice supply and demand dynamics for 2030 under four Shared Socioeconomic Pathway (SSP) scenarios, employing the Global Agro-Ecological Zones (GAEZ) and Future Land Use Simulation (FLUS) models. Subsequently, a scenario-based linear programming framework is applied to explore optimized low-carbon trade configurations. Results indicate that, compared to simulations focused solely on minimizing transport costs, observed trade flows capture substantial long-distance interprovincial exchanges that cost-based models tend to overlook. Moreover, optimized flows could reduce total carbon emissions from rice distribution by 16.1%-20.5% in 2030. These findings offer robust empirical and modeling evidence to inform the reconfiguration of grain distribution systems and support region-specific adaptation strategies under future climate change.
由于缺乏观测到的粮食流动数据和前瞻性情景分析,目前对低碳食品分布的认识受到限制。在本研究中,我们利用30,524个观察到的贸易记录构建了2020年中国省际大米分销网络。然后,我们利用全球农业生态区(GAEZ)和未来土地利用模拟(FLUS)模型,在四种共享社会经济路径(SSP)情景下预测了2030年各省稻米供需动态。随后,应用基于场景的线性规划框架,探索优化的低碳贸易配置。结果表明,与只关注最小化运输成本的模拟相比,观察到的贸易流量捕获了基于成本的模型往往忽略的大量长途省际交流。此外,优化后的流程可在2030年将大米配送过程中的碳排放总量减少16.1%-20.5%。这些发现为粮食分配系统的重新配置提供了强有力的经验和模型证据,并为未来气候变化下的区域适应策略提供了支持。
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引用次数: 0
Potential SCMs for low-carbon concrete in Australia: Cradle-to-gate LCA and cost perspectives 澳大利亚低碳混凝土的潜在scm:从摇篮到闸门的LCA和成本观点
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-29 DOI: 10.1016/j.resconrec.2026.108823
Yulin Patrisia , Nghia P. Tran , Chamila Gunasekara , David W. Law , Tuan D. Ngo , Sujeeva Setunge
Concrete production is a major source of global emissions, and incorporating supplementary cementitious materials (SCMs) offers a pathway to lower carbon construction. This study evaluates the life cycle and cost performance of eight alternative SCMs in Australia: recycled concrete powder (RCP), clay brick powder (CBP), recycled glass powder (RGP), lithium slag powder (LSP), red mud powder (RMP), limestone calcined clay (LC2), steel slag powder (SSP) and pond ash (PA). The study considers 83 mixes containing these SCMs, as reported in the literature, which achieved 30–40 MPa. The results showed that LC2 achieved the lowest GWP (283 kg CO₂-eq/m³; 8.22 kg CO₂-eq/MPa) and the lowest cost (∼133 AU$/m³). RGP and LSP also reduced ADPF to 71–70 MJ/MPa, while RMP and LSP achieved the lowest strength-normalised costs (3.8–3.9 AU$/MPa). CBP and PA performed worse due to poor reactivity and higher costs (>4.3 AU$/MPa). These findings highlight the potential of LC2, RGP, LSP, and RMP to support circular, low-carbon concrete in Australia.
混凝土生产是全球排放的主要来源,添加补充胶凝材料(scm)为低碳建筑提供了一条途径。本研究评估了澳大利亚8种可替代的SCMs的生命周期和性价比:再生混凝土粉(RCP)、粘土砖粉(CBP)、再生玻璃粉(RGP)、锂渣粉(LSP)、赤泥粉(RMP)、石灰石煅烧粘土(LC2)、钢渣粉(SSP)和池塘灰(PA)。据文献报道,该研究考虑了83种含有这些SCMs的混合物,达到30-40 MPa。结果表明,LC2具有最低的GWP (283 kg CO₂-eq/m³;8.22 kg CO₂-eq/MPa)和最低的成本(约133 AU$/m³)。RGP和LSP也将ADPF降低到71-70 MJ/MPa,而RMP和LSP的强度标准化成本最低(3.8-3.9 AU$/MPa)。由于反应性差和成本较高(>;4.3澳元/兆帕),CBP和PA表现较差。这些发现突出了LC2、RGP、LSP和RMP在澳大利亚支持循环低碳混凝土方面的潜力。
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引用次数: 0
Global production potential and environmental benefits of alternative proteins from biowaste 生物废物中替代蛋白质的全球生产潜力和环境效益
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-29 DOI: 10.1016/j.resconrec.2026.108818
Xue Bai , Yi Gong , Wei Wei , Wen Wang , Minghao Zhuang , Yi Yang
Upcycling biowaste into insect and microbial proteins can enhance food system circularity; however, their global production potential and environmental benefits remain uncertain. In 2020, global biowaste could generate 58 Mt of insect protein or 146 Mt of microbial protein—exceeding global meat protein or meeting 53%–100% of soybean meal protein demand. Using Life Cycle Assessment combined with global scenario analysis, substituting soybean meal with alternative proteins yields moderate GHG reductions (-13 to -25 kg CO2e kg⁻¹ protein). Substituting meat protein yields larger GHG reductions (-107 to -1230 kg CO2e kg⁻¹ protein), alongside decreases in terrestrial acidification (-0.003 to -1.2 kg SO2e), eutrophication (-0.2 to -1.2 kg PO4e) and fine particulate matter (-0.03 to -0.24 kg PM2.5e). Globally replacing soybean meal first and then progressively meat could mitigate 0.9–12.2 Gt CO2e yr⁻¹ by 2050. However, achieving higher mitigation levels require greater technological innovation, institutional support, and cultural shifts.
将生物垃圾升级为昆虫和微生物蛋白质可以增强食物系统的循环;然而,它们的全球生产潜力和环境效益仍然不确定。到2020年,全球生物废弃物可产生5800万吨昆虫蛋白或1.46亿吨微生物蛋白,超过全球肉类蛋白或满足53%-100%的豆粕蛋白需求。使用生命周期评估结合全球情景分析,用替代蛋白质替代豆粕可产生适度的温室气体减排(-13至-25千克二氧化碳- 2e千克毒血症)。替代肉类蛋白质可以产生更大的温室气体减排(-107至-1230千克二氧化碳当量),同时减少陆地酸化(-0.003至-1.2千克二氧化硫当量),富营养化(-0.2至-1.2千克PO4e)和细颗粒物(-0.03至-0.24千克PM2.5e)。到2050年,在全球范围内先取代豆粕,然后逐步取代肉类,可以每年减少0.9-12.2亿吨二氧化碳(毒血症)。然而,实现更高的缓解水平需要更大的技术创新、制度支持和文化转变。
{"title":"Global production potential and environmental benefits of alternative proteins from biowaste","authors":"Xue Bai ,&nbsp;Yi Gong ,&nbsp;Wei Wei ,&nbsp;Wen Wang ,&nbsp;Minghao Zhuang ,&nbsp;Yi Yang","doi":"10.1016/j.resconrec.2026.108818","DOIUrl":"10.1016/j.resconrec.2026.108818","url":null,"abstract":"<div><div>Upcycling biowaste into insect and microbial proteins can enhance food system circularity; however, their global production potential and environmental benefits remain uncertain. In 2020, global biowaste could generate 58 Mt of insect protein or 146 Mt of microbial protein—exceeding global meat protein or meeting 53%–100% of soybean meal protein demand. Using Life Cycle Assessment combined with global scenario analysis, substituting soybean meal with alternative proteins yields moderate GHG reductions (-13 to -25 kg CO<sub>2</sub>e kg⁻¹ protein). Substituting meat protein yields larger GHG reductions (-107 to -1230 kg CO<sub>2</sub>e kg⁻¹ protein), alongside decreases in terrestrial acidification (-0.003 to -1.2 kg SO<sub>2</sub>e), eutrophication (-0.2 to -1.2 kg PO<sub>4</sub>e) and fine particulate matter (-0.03 to -0.24 kg PM<sub>2.5</sub>e). Globally replacing soybean meal first and then progressively meat could mitigate 0.9–12.2 Gt CO<sub>2</sub>e yr⁻¹ by 2050. However, achieving higher mitigation levels require greater technological innovation, institutional support, and cultural shifts.</div></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":"228 ","pages":"Article 108818"},"PeriodicalIF":10.9,"publicationDate":"2026-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic mechanochemical activation and carbon-thermal shock for full-component upcycling of retired photovoltaic modules 退役光伏组件全组件升级循环的协同机械化学活化和碳-热冲击
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-28 DOI: 10.1016/j.resconrec.2026.108822
Lanbin Wang, Zishuo Wang, Jing Wu, Beikai Zhang, Jiadong Yu, Jinhui Li
This study introduces mechanochemical activation–instantaneous carbon thermal shock (CTS) as a synergistic strategy for the high-value utilization of all components in retired crystalline-Si photovoltaic (PV) modules, addressing recycling bottlenecks such as limited metal recovery, high chemical consumption, and low-value treatment of Si. Mechanochemical ball milling effectively disrupts the Ag–Si interface and glassy interlayers, increasing the specific surface area and inducing lattice distortions. This lowers the reaction activation energy, enabling high leaching efficiencies for Ag (99.5%) and Al (94%) while markedly reducing the required nitric acid dosage. Subsequent CTS, with its ultrafast heating, overcomes the kinetic limitations of silica reduction, rapidly converting the acid-leached Si residue into high-purity, highly crystalline SiC. The synthesized SiC is well suited for high-temperature electronic devices and thermal management applications due to its excellent thermal stability, high thermal conductivity, and semiconducting properties. Life cycle and economic analyses indicate that, compared with conventional hydrometallurgical methods, the proposed process reduces the environmental footprint by 88.19% and lowers material treatment costs, offering an economically viable pathway for green, closed-loop recycling of PV waste.
本研究介绍了机械化学活化-瞬时碳热冲击(CTS)作为一种协同策略,用于退役晶体硅光伏(PV)模块中所有组件的高价值利用,解决回收瓶颈,如有限的金属回收,高化学消耗和低价值Si处理。机械化学球磨有效地破坏了Ag-Si界面和玻璃化夹层,增加了比表面积并引起晶格畸变。这降低了反应活化能,使银(99.5%)和铝(94%)的浸出效率高,同时显著减少所需的硝酸用量。随后的CTS凭借其超快加热,克服了二氧化硅还原的动力学限制,将酸浸后的硅渣快速转化为高纯度、高结晶的SiC。由于其优异的热稳定性、高导热性和半导体特性,合成的SiC非常适合于高温电子器件和热管理应用。生命周期和经济分析表明,与传统的湿法冶金方法相比,该工艺减少了88.19%的环境足迹,降低了材料处理成本,为光伏废弃物的绿色闭环回收提供了一条经济可行的途径。
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引用次数: 0
Sustainable innovation: Artificial Intelligence-assisted design of bio-based plastics 可持续创新:生物基塑料的人工智能辅助设计
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-28 DOI: 10.1016/j.resconrec.2026.108814
Selene Paz Adaglio , Romina Ingrassia , Gisela Tubio , Ariel Di Loreto , María Julia Boggione
This work presents a machine learning-driven methodology for bioplastic formulation design, valorizing eggshell waste as reinforcement. Two bioplastic formulations were developed: bioplastic from Droguería Industrial San Juan starch (BADSJ) and bioplastic from Biopack starch (BAS), reinforced with eggshell powder (ESP). PCA was performed on thickness, moisture, solubility, puncture strength (Ps), deformation at break point (Pd), biodegradability and opacity. Six machine learning algorithms were evaluated. Random Forest ntree = 200 and Linear Support Vector Machine (SVM) achieved the best performance, achieving 83.3% accuracy and 0.81 Kappa. These models estimated concentration ranges associated with improved Ps and Pd. The SVM exhibited higher predictive consistency, with R² of 0.9724 and lower error metrics (RMSE: 0.1422; MAE: 0.1043) compared to Random Forest. SVM predicted broader range of eggshell concentrations (0.47–1.47%) associated with improved Ps and Pd values, indicating better differentiation between formulations. These models provide a data-driven framework for optimizing bioplastic formulations and reducing experimental iterations.
这项工作提出了一种机器学习驱动的生物塑料配方设计方法,将蛋壳废料作为强化物。开发了两种生物塑料配方:Droguería Industrial San Juan淀粉(BADSJ)生物塑料和Biopack淀粉(BAS)生物塑料,蛋壳粉(ESP)增强。对厚度、水分、溶解度、穿刺强度(Ps)、断裂点变形(Pd)、生物降解性和不透明度进行主成分分析。评估了六种机器学习算法。随机森林ntree = 200和线性支持向量机(SVM)表现最好,准确率达到83.3%,Kappa为0.81。这些模型估计了与Ps和Pd改善相关的浓度范围。与随机森林相比,SVM的预测一致性更高,R²为0.9724,误差指标更低(RMSE: 0.1422; MAE: 0.1043)。支持向量机预测的蛋壳浓度范围(0.47-1.47%)与Ps和Pd值的提高相关,表明配方之间的差异更大。这些模型为优化生物塑料配方和减少实验迭代提供了数据驱动的框架。
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引用次数: 0
Transforming textile waste into materials using fungi 利用真菌将纺织废料转化为材料
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-27 DOI: 10.1016/j.resconrec.2026.108812
Maidu Silm , Qixiang Jiang , Anu Kisand , Alexander Bismarck , Mitchell P. Jones
Textile waste from ‘fast fashion’ has considerable environmental impact and is an EU priority area. Colonising textiles with fungi provides a unique solution, with options to bond them together to create composite materials, fruit them to provide mushrooms (source of chitin-glucan complex), or both. We produced mycelium-textile composites in analogy to traditional prepreg-based composite manufacturing, consolidating multiple textile stacks colonised with Ganoderma lucidum into a single material of customisable thickness and free-form geometry. An oxygen gradient existed through the cross-section of textile stacks, resulting in more growth on surface than core plies. Consolidated composites comprising only surface layers achieved tensile strengths up to ∼14 MPa. Their flexural and shear strengths (7 MPa and 0.5 MPa, respectively) indicated suitability for semi-structural construction applications. Waste textile substrate could also be fruited (5.7% w/w yield). These advances expand the stalled application of mycelium composites and provide a nature-based solution to textile upcycling.
来自“快时尚”的纺织废料对环境有相当大的影响,是欧盟的优先领域。用真菌在纺织品上定居提供了一种独特的解决方案,可以选择将它们粘合在一起以制造复合材料,或者将它们果实制成蘑菇(几丁质-葡聚糖复合物的来源),或者两者兼而有之。我们生产了菌丝纺织复合材料,类似于传统的基于预浸料的复合材料制造,将多种纺织材料与灵芝结合成一种可定制厚度和自由几何形状的材料。氧梯度通过纺织堆的横截面存在,导致表面比芯层生长更多。仅包含表层的固结复合材料的抗拉强度可达~ 14 MPa。它们的抗折和抗剪强度(分别为7 MPa和0.5 MPa)表明适合半结构施工应用。废纺织基质也可以得到果实(5.7% w/w产率)。这些进展扩大了停滞不前的菌丝复合材料的应用,并为纺织品升级回收提供了一种基于自然的解决方案。
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引用次数: 0
Pilot-scale production of high-purity vaterite-type calcium carbonate from desalination brine using industrial by-products 利用工业副产品脱盐盐水中试生产高纯度水晶石型碳酸钙
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-27 DOI: 10.1016/j.resconrec.2026.108807
Sehun Kim , Won Jo , Seungwon Ihm , Abdallatif Abdalrhman , Jinuk Heo , Myoung-Jin Kim
The rapid growth of global desalination raises concerns over high-salinity brine disposal. Vaterite, a valuable but unstable polymorph of CaCO₃, is difficult to mass-produce. This study reports the first pilot-scale production of high-purity vaterite using actual desalination brine and cement kiln dust. A 1-ton system was built and operated at the SWA-WTIIRA desalination complex in Jubail, Saudi Arabia. Through calcium elution and carbonation, conditions were optimized to achieve ≥95 % vaterite content and sub-3 µm particle size. Controlling carbonation temperature and drying prevented transformation to calcite. The process yielded porous, spherical vaterite particles (>20 m²/g surface area, >98.5 % purity). Techno-economic analysis estimated production costs at $2.5/kg, significantly below commercial pharmaceutical-grade vaterite. These findings demonstrate a scalable, low-cost strategy for valorizing desalination brine and industrial by-products, offering both environmental and economic benefits.
全球海水淡化的快速增长引发了人们对高盐度盐水处理的担忧。碳酸钙₃是一种有价值但不稳定的多晶型,很难大规模生产。本研究报告了首次利用实际海水淡化盐水和水泥窑粉尘中试生产高纯度水晶石。在沙特阿拉伯朱拜勒的SWA-WTIIRA海水淡化厂建造并运行了一个1吨重的系统。通过钙洗脱和碳酸化,优化工艺条件,得到≥95%的水晶石含量和小于3µm的粒径。控制碳酸化温度和干燥可防止方解石的转变。该工艺产生多孔的球形水晶石颗粒(表面积为20 m²/g,纯度为98.5%)。技术经济分析估计生产成本为每公斤2.5美元,大大低于商业制药级杂物矿。这些发现证明了一种可扩展的、低成本的策略,可以使海水淡化盐水和工业副产品增值,同时提供环境和经济效益。
{"title":"Pilot-scale production of high-purity vaterite-type calcium carbonate from desalination brine using industrial by-products","authors":"Sehun Kim ,&nbsp;Won Jo ,&nbsp;Seungwon Ihm ,&nbsp;Abdallatif Abdalrhman ,&nbsp;Jinuk Heo ,&nbsp;Myoung-Jin Kim","doi":"10.1016/j.resconrec.2026.108807","DOIUrl":"10.1016/j.resconrec.2026.108807","url":null,"abstract":"<div><div>The rapid growth of global desalination raises concerns over high-salinity brine disposal. Vaterite, a valuable but unstable polymorph of CaCO₃, is difficult to mass-produce. This study reports the first pilot-scale production of high-purity vaterite using actual desalination brine and cement kiln dust. A 1-ton system was built and operated at the SWA-WTIIRA desalination complex in Jubail, Saudi Arabia. Through calcium elution and carbonation, conditions were optimized to achieve ≥95 % vaterite content and sub-3 µm particle size. Controlling carbonation temperature and drying prevented transformation to calcite. The process yielded porous, spherical vaterite particles (&gt;20 m²/g surface area, &gt;98.5 % purity). Techno-economic analysis estimated production costs at $2.5/kg, significantly below commercial pharmaceutical-grade vaterite. These findings demonstrate a scalable, low-cost strategy for valorizing desalination brine and industrial by-products, offering both environmental and economic benefits.</div></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":"228 ","pages":"Article 108807"},"PeriodicalIF":10.9,"publicationDate":"2026-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Resources Conservation and Recycling
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