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Old is gold? Vehicle maintenance material demand of lifetime extension: dynamic stock modelling 老就是金?延长车辆维修材料使用寿命的需求:动态库存建模
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-14 DOI: 10.1016/j.resconrec.2025.108752
Luja von Köckritz , Oreane Edelenbosch , Sebastiaan Deetman , Frederike Arp , Roel Brouwer , Raoul Schram , Marianne Zanon-Zotin , Detlef van Vuuren
Transport vehicles are a major driver of global material extraction, making their material needs central to circular economy strategies. Yet few studies address the material implications of maintenance, leaving the link between vehicle lifetime extension and maintenance poorly quantified. Using a new global, stock-driven model, IMAGE Materials, coupled to the IMAGE integrated assessment model, we link material demand to transport services and account for scheduled maintenance for land-based transport. Results show that maintenance adds ∼30 % of material demand for road vehicles and up to 100 % for high-speed rail. Maintenance flows for road modes are rubber-intensive, while rail requires steel. Still, lifetime extension leads to a net reduction in total material demand of ∼16 % (95.8 Mt) in 2100, but increased maintenance partly offsets these savings, adding 69.5 Mt with age-related or 29.3 Mt with age-capped maintenance material growth. These findings highlight maintenance as a structural component of vehicle material demand, requiring complementary policies like standards and repair incentives.
运输车辆是全球材料开采的主要驱动力,使其材料需求成为循环经济战略的核心。然而,很少有研究涉及维修的物质影响,使得车辆寿命延长和维修之间的联系难以量化。我们使用新的全球库存驱动模型IMAGE Materials与IMAGE综合评估模型相结合,将材料需求与运输服务联系起来,并考虑陆基运输的定期维护。结果表明,维护增加了公路车辆材料需求的30%,高速铁路增加了100%。公路模式的维护流程是橡胶密集型的,而铁路需要钢铁。尽管如此,寿命延长导致2100年总材料需求净减少约16%(9580万吨),但维护费用的增加部分抵消了这些节省,与年龄相关的维护材料增长增加了6950万吨,或与年龄限制的维护材料增长增加了2930万吨。这些发现强调,维修是汽车材料需求的一个结构性组成部分,需要标准和维修奖励等配套政策。
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引用次数: 0
Securing low-carbon rare earth supply for the renewable energy sector: Demand, circularity, and carbon mitigation of neodymium and dysprosium 确保可再生能源部门的低碳稀土供应:钕和镝的需求、循环性和碳减排
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-13 DOI: 10.1016/j.resconrec.2026.108784
Peize Wang , Tingting Liu , Gangqi Cheng , Yufeng Wu , Shengnan Wang , Kun Zhu
With the rapid growth of China’s new energy vehicles (NEVs) and wind power sectors, demand for neodymium and dysprosium is surging, while their supply is constrained by limited reserves, mining policies, and carbon-intensive production. Yet existing studies have rarely examined resource constraints and emission reduction targets within a unified framework, and have not fully integrated demand, supply, and the mitigation effects of recycling. To address this gap, this study develops an integrated material flow and carbon emission assessment framework for neodymium and dysprosium under the renewable energy transition and projects their supply-demand dynamics. The results show that by 2060, cumulative demand from NEVs is projected to reach 535.2-985.6 kilotonnes (kt) of neodymium and dysprosium combined, while wind power is expected to require a further 182.4-455.4 kt in total. Supply forecasts indicate that neodymium demand can be met under policy liberalization, but gaps emerge under quota-controlled and worsen when accounting for production losses. In contrast, dysprosium faces long term shortages across all scenarios. Recycling plays a critical role: neodymium recycling can largely meet renewable demand and reduce dependence on mining, while dysprosium recycling remains limited due to scarcity. A carbon emission assessment framework is also developed for neodymium and dysprosium production. Power mix optimization could reduce emissions by 7.1-16.5 million tonnes CO₂-equivalent (Mt CO₂-eq) for neodymium and 3.6-8.5 Mt CO₂-eq for dysprosium, while recycling contributes 3.3-5 and 1-1.4 Mt CO₂-eq reductions, respectively. Combining recycling with a cleaner power mix is essential to securing rare earth supply and reducing lifecycle emissions.
随着中国新能源汽车(nev)和风力发电行业的快速增长,对钕和镝的需求激增,而它们的供应受到有限储量、采矿政策和碳密集型生产的限制。然而,现有的研究很少在统一的框架内审查资源限制和减排目标,也没有充分综合考虑回收的需求、供应和缓解效果。为了解决这一差距,本研究开发了可再生能源转型下钕和镝的综合物质流和碳排放评估框架,并预测了它们的供需动态。结果显示,到2060年,新能源汽车的累计需求预计将达到535.2-985.6千吨(kt)钕和镝的总和,而风电预计将进一步需要182.4-455.4千吨(kt)。供应预测表明,在政策自由化的情况下,钕的需求可以得到满足,但在配额控制下出现缺口,考虑到生产损失,缺口会进一步扩大。相比之下,镝在所有情况下都面临长期短缺。回收利用发挥着至关重要的作用:钕的回收利用可以在很大程度上满足可再生需求,减少对采矿的依赖,而镝的回收利用由于稀缺性仍然有限。还为钕和镝的生产制定了碳排放评估框架。动力结构优化可以减少钕的710 - 1650万吨二氧化碳当量(Mt CO₂-eq)和镝的360 - 850万吨二氧化碳当量(Mt CO₂-eq),而回收分别可以减少330 -5万吨和1- 140万吨二氧化碳当量。将回收利用与更清洁的能源组合相结合,对于确保稀土供应和减少生命周期排放至关重要。
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引用次数: 0
Mapping waste mismanagement: Detecting litter hotspots with geospatial AI and pedestrian imagery 测绘垃圾管理不善:利用地理空间人工智能和行人图像检测垃圾热点
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-10 DOI: 10.1016/j.resconrec.2025.108772
Nicolás Valenzuela-Levi, Cristobal Nilo, Javiera Ponce-Méndez, Nicolás Gálvez Ramírez
This study introduces a novel methodology for urban litter detection and management by combining enhanced pedestrian inspection with automated visual registry, GPS, and machine learning. To establish the model, the research team collected over 10,000 georeferenced point-of-view (POV) images across three predetermined routes in downtown Santiago, Chile. A pre-trained YOLOv8 deep learning model was successfully utilized to binary classify the presence of litter in each image, achieving a precision of 89.03%. Subsequently, a multivariate logistic regression model quantified the correlation between these detection results and urban contextual variables, such as proximity to non-residential activities and transport hubs. The key finding demonstrates that litter occurrence is significantly more prevalent in areas surrounding metro stations and bus stops, thereby providing empirical data to inform targeted, spatially optimized waste management strategies. This approach offers a scalable, low-cost solution for cities globally, particularly in the Global South.
本研究介绍了一种新的城市垃圾检测和管理方法,该方法将增强的行人检查与自动视觉注册、GPS和机器学习相结合。为了建立该模型,研究小组在智利圣地亚哥市中心的三条预定路线上收集了超过10,000张地理参考点(POV)图像。利用预训练的YOLOv8深度学习模型对每张图像中是否存在凋落物进行二值分类,准确率达到89.03%。随后,一个多元逻辑回归模型量化了这些检测结果与城市环境变量(如与非住宅活动和交通枢纽的接近程度)之间的相关性。关键发现表明,垃圾发生在地铁站和公交车站周围地区更为普遍,从而为有针对性的空间优化垃圾管理策略提供了经验数据。这种方法为全球城市,特别是南半球城市提供了一种可扩展的低成本解决方案。
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引用次数: 0
Priorities for enhancing resilience of SDG causal network from a human-nature perspective 从人与自然的角度加强可持续发展目标因果网络弹性的优先事项
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-10 DOI: 10.1016/j.resconrec.2025.108774
Yiming Su , Guangjin Zhou , Mingyuan Wang , Xiaoyun Li , Tao Liang , Lingqing Wang , Jian Hu , Jixi Gao , Wenwu Zhao , Siyuan Tao , Peter E. Holm , Jörg Rinklebe , Riqi Zhang , Cong-Qiang Liu , Rong Gong , Yizhong Huan
Strong interactions among six Sustainable Development Goals (SDGs)—food (2), water (6), energy (7), economy (8), climate (13), and ecology (15) (FWEECE)—reflect the core nexus of the human-nature relationship under global change. However, research on their causal interactions is limited, and priorities for global transformation remain elusive. Here, we developed an integrated index to assess global progress in SDG coordination-evenness, and applied Gated Recurrent Unit, Panel Vector Autoregression, and link prediction models to capture the SDG causal network among 33 targets in FWEECE. Using machine learning and network analysis, we then prioritized SDG targets. We further simulated network perturbations to identify priority actions that enhance network resilience. The results indicated limited global progress in both the coordination and evenness of these SDGs since 2000, with target 2.4 (sustainable agriculture) identified as the key priority for future progress. Mitigating high-weight trade-offs, especially from targets 15.2 (sustainable forest management) to 8.2 (economic productivity), while strengthening 84% of synergies, led by 6.6 (water-related ecosystem) to 2.c (food price stability), presents an effective strategy for advancing FWEECE. Our study provides new insights into human-earth coupling, contributing global governance transformations for the 2030 Agenda.
粮食(2)、水(6)、能源(7)、经济(8)、气候(13)和生态(15)六个可持续发展目标(FWEECE)之间的密切互动反映了全球变化下人与自然关系的核心联系。然而,对其因果关系的研究有限,全球转型的优先事项仍然难以捉摸。在这里,我们开发了一个综合指数来评估可持续发展目标协调均匀性的全球进展,并应用门控循环单元、面板向量自回归和链接预测模型来捕捉FWEECE中33个目标之间的可持续发展目标因果网络。通过机器学习和网络分析,我们确定了可持续发展目标的优先级。我们进一步模拟网络扰动,以确定增强网络弹性的优先行动。结果表明,自2000年以来,全球在这些可持续发展目标的协调和均匀性方面进展有限,目标2.4(可持续农业)被确定为未来进展的关键优先事项。减少高权重权衡,特别是从目标15.2(可持续森林管理)到8.2(经济生产力),同时加强84%的协同效应,从目标6.6(与水有关的生态系统)到目标2.c(粮食价格稳定),是推进森林和生态环境评估的有效战略。我们的研究为人类-地球耦合提供了新的见解,有助于实现2030年议程的全球治理转型。
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引用次数: 0
Mapping the global flow of fiber-reinforced polymer composites and supply chain energy requirements 绘制纤维增强聚合物复合材料和供应链能源需求的全球流动图
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-10 DOI: 10.1016/j.resconrec.2026.108787
Zhuoer Li, Mihaela Banu, Daniel R. Cooper
Production of fiber-reinforced polymer composites is materially-inefficient and energy-intensive. This study identifies improvement opportunities by conducting a material flow and energy analysis of the 2024 global composite supply chain. Bayesian inference is used to reconcile production material flow data extracted from academic and grey literature (e.g., industry reports) with data noise assigned using a Pedigree Matrix, generating balanced mass flows with quantified uncertainty. Supply chain energy requirements are determined by coupling the material flows with feedstock and process energy intensities collected from LCA literature and databases.
In 2024, around 12.2 Mt of composites entered use, requiring around 2030 PJprimary to produce and generating approximately 2.5 Mt of manufacturing scrap. Component production from feedstocks accounted for 45% of primary energy demand (60:40, thermoset:thermoplastic), followed by resin (40%) and fiber (15%) production. This study discusses opportunities and challenges in transitioning to lower-energy production, including alternatives to energy-intensive oil-based feedstocks and more efficient manufacturing processes. Energy attributable to system material losses (determined using input–output analysis) rivaled those of the largest end-use sectors. This study examines strategies to increase system-level material utilization by boosting closed-loop recycling of mass-production scrap (e.g., from injection molding) and shifting from low-yield (semi-)manual processes to automated manufacturing (e.g., pultrusion).
纤维增强聚合物复合材料的生产是材料效率低下和能源密集型的。本研究通过对2024年全球复合材料供应链进行物料流和能量分析,确定了改进机会。贝叶斯推理用于调和从学术和灰色文献(例如,行业报告)中提取的生产物料流数据与使用系谱矩阵分配的数据噪声,生成具有量化不确定性的平衡质量流。供应链能源需求是通过将物料流与从LCA文献和数据库收集的原料和过程能源强度相结合来确定的。2024年,约有1220万吨复合材料投入使用,需要大约2030年的PJprimary来生产,并产生约250万吨的制造废料。原料的组件生产占一次能源需求的45%(60:40,热固性:热塑性),其次是树脂(40%)和纤维(15%)生产。本研究讨论了向低能源生产过渡的机遇和挑战,包括替代能源密集型石油原料和更高效的制造工艺。可归因于系统材料损失的能源(利用投入产出分析确定)可与最大的最终用途部门相媲美。本研究探讨了提高系统级材料利用率的策略,通过促进大规模生产废料的闭环回收(例如,从注射成型)和从低产量(半)手工工艺转向自动化制造(例如,拉挤)。
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引用次数: 0
Toward circular, value-added recycling of modified-poly(ethylene terephthalate): Microstructure and performance across multiple fused particle fabrication cycles 改性聚对苯二甲酸乙酯的循环增值回收:在多个熔合颗粒制造周期中的微观结构和性能
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-09 DOI: 10.1016/j.resconrec.2026.108781
Mohammad Sagor Hosen , Heon E. Park , Mark P. Staiger
Dimensional instability remains a principal concern in extrusion-based additive manufacturing, driven by volumetric shrinkage stemming from microstructural changes, especially throughout closed-loop recycling of semicrystalline polymers such as poly(ethylene terephthalate) (PET). The present study investigates the microstructural evolution and corresponding volumetric shrinkage of modified-PET (mPET) quantifying key microstructural contents (i.e., degree of crystallinity, and mobile and rigid amorphous fractions) across 4 fused particle fabrication cycles for the first time. The results reveal proto-spherullite formation in recycled mPET microstructure and associated microstructural changes that cause progressive volumetric shrinkage. The degree of crystallinity and rigid amorphous content are found to vary as a function of the FPF cycle number. Notably, recycled mPET exhibited an increase in density from 1.23 to 1.30 g/cm³ and volumetric shrinkage from 0 to 4.8 % following 4 FPF cycles. The study observations have important implications for predicting dimensional accuracy in 3D-printed parts manufactured from both virgin and recycled semicrystalline polymers using extrusion-based additive manufacturing.
尺寸不稳定性仍然是基于挤压的增材制造的主要问题,由微观结构变化引起的体积收缩驱动,特别是在半晶聚合物(如聚对苯二甲酸乙酯)(PET)的闭环回收过程中。本研究研究了改性pet (mPET)的微观结构演变和相应的体积收缩率,首次量化了4个熔融颗粒制造周期中的关键微观结构含量(即结晶度、可移动和刚性非晶部分)。结果揭示了再生mPET微观结构中原始球晶的形成和相关的微观结构变化导致了渐进的体积收缩。发现结晶度和刚性非晶含量随FPF循环数的变化而变化。值得注意的是,经过4次FPF循环后,再生mPET的密度从1.23 g/cm³增加到1.30 g/cm³,体积收缩率从0增加到4.8%。研究结果对于预测3d打印部件的尺寸精度具有重要意义,这些部件是使用基于挤压的增材制造技术由原始和回收的半晶聚合物制造的。
{"title":"Toward circular, value-added recycling of modified-poly(ethylene terephthalate): Microstructure and performance across multiple fused particle fabrication cycles","authors":"Mohammad Sagor Hosen ,&nbsp;Heon E. Park ,&nbsp;Mark P. Staiger","doi":"10.1016/j.resconrec.2026.108781","DOIUrl":"10.1016/j.resconrec.2026.108781","url":null,"abstract":"<div><div>Dimensional instability remains a principal concern in extrusion-based additive manufacturing, driven by volumetric shrinkage stemming from microstructural changes, especially throughout closed-loop recycling of semicrystalline polymers such as poly(ethylene terephthalate) (PET). The present study investigates the microstructural evolution and corresponding volumetric shrinkage of modified-PET (mPET) quantifying key microstructural contents (<em>i.e.</em>, degree of crystallinity, and mobile and rigid amorphous fractions) across 4 fused particle fabrication cycles for the first time. The results reveal proto-spherullite formation in recycled mPET microstructure and associated microstructural changes that cause progressive volumetric shrinkage. The degree of crystallinity and rigid amorphous content are found to vary as a function of the FPF cycle number. Notably, recycled mPET exhibited an increase in density from 1.23 to 1.30 g/cm³ and volumetric shrinkage from 0 to 4.8 % following 4 FPF cycles. The study observations have important implications for predicting dimensional accuracy in 3D-printed parts manufactured from both virgin and recycled semicrystalline polymers using extrusion-based additive manufacturing.</div></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":"228 ","pages":"Article 108781"},"PeriodicalIF":10.9,"publicationDate":"2026-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145915293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Material performance, economic feasibility, and greenhouse gas emissions of natural pozzolans in concrete: A review and meta-analysis 混凝土中天然火山灰的材料性能、经济可行性和温室气体排放:综述和荟萃分析
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-09 DOI: 10.1016/j.resconrec.2025.108769
Asahi Amitani, Sabbie A. Miller
There is an urgent need to decarbonize cement and concrete production. One of the most rapidly implementable strategies is to partially replace Portland cement (PC) in concrete with supplementary cementitious materials (SCMs), such as natural pozzolans (NPs), which are globally abundant but underused. Current studies have focused on only one or a subset of NPs and used inconsistent approaches for estimating their environmental impacts and production costs, hindering the ability to compare these SCMs and determine their best applications. We systematically review NPs—including calcined clays, diatomaceous earth, pumice, scoria, and tuff—to examine both their composition as well as their contributions to fresh and hardened concrete properties. We use a harmonized assessment approach to examine greenhouse gas (GHG) emissions and costs from producing concrete with these NPs, and we concurrently examine experimental results from the review with these emissions and cost findings. Our results show that these NPs can offer necessary composition, improve durability, and offer desired contributions to strength with proper mixture proportioning. On average, NP concretes resulted in 7–24 % GHG emissions reduction, while lowering consumption of the costliest constituent, PC. These results demonstrate that, with appropriate selection and processing, NPs offer a scalable, cost-effective route to partial PC replacement, advancing concrete decarbonization.
目前迫切需要对水泥和混凝土进行脱碳生产。最快速实施的策略之一是用补充胶凝材料(SCMs)部分取代混凝土中的波特兰水泥(PC),例如全球丰富但未充分利用的天然火山灰(NPs)。目前的研究只关注一种或一部分NPs,并且使用了不一致的方法来估计其环境影响和生产成本,从而阻碍了比较这些SCMs并确定其最佳应用的能力。我们系统地回顾了nps——包括煅烧粘土、硅藻土、浮石、矿渣和凝灰岩——来研究它们的组成以及它们对新混凝土和硬化混凝土性能的贡献。我们使用统一的评估方法来检查使用这些NPs生产混凝土的温室气体(GHG)排放和成本,并同时使用这些排放和成本调查结果来检查审查的实验结果。我们的研究结果表明,这些NPs可以提供必要的成分,提高耐久性,并通过适当的混合比例提供所需的强度贡献。平均而言,NP混凝土减少了7 - 24%的温室气体排放,同时降低了最昂贵的成分PC的消耗。这些结果表明,通过适当的选择和处理,NPs为部分PC替代提供了一种可扩展的、具有成本效益的途径,促进了混凝土的脱碳。
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引用次数: 0
Discover how interprovincial electricity transmission policies on transforming the regional variations in grid emission factors in China 探索省际输电政策如何改变中国电网排放因子的区域差异
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-08 DOI: 10.1016/j.resconrec.2025.108773
Boda Xin , Yiyun Yu , Meiyi Li , Yiming Gu , Yahui Zhang , Junfeng Wang
Interprovincial electricity transmission is vital for decarbonizing China's power system, yet its impact on Grid Emission Factors (GEFs) remains underexplored. This study employs the Medium-to-Long-Term Provincial Grid Emission Factor Model (MLGEFM) to simulate provincial GEFs and carbon trajectories from 2020 to 2035 under four transmission scenarios. Results reveal significant national decarbonization, with the average GEF falling from 0.559 to 0.320 tCO₂/MWh by 2035 under the Emission Targeted Scenario (ETS). However, transmission mechanisms exert heterogeneous regional impacts. While scale expansion reduces GEFs in central and southern China (e.g., -20.0% in Henan), it inadvertently raises GEFs in north and east China (e.g., +24.7% in Beijing). In contrast, structural optimization under ETS further reduces GEFs by 7.6% in Beijing and 13.1% in Shanghai. Although all scenarios achieve a national carbon peak around 2030, ETS achieves the optimal trajectory with a lower peak magnitude and steeper decline.
省际电力传输对中国电力系统的脱碳至关重要,但其对电网排放因子的影响仍未得到充分探讨。本文采用中长期省级电网排放因子模型(MLGEFM),模拟了2020 - 2035年四种输电情景下的省级电网排放因子和碳排放轨迹。结果显示,在排放目标情景(ETS)下,到2035年,全国平均GEF从0.559下降到0.320 tCO₂/MWh。然而,传播机制具有异质性的区域影响。虽然规模扩张降低了中国中部和南部的全球环境融资(例如,河南-20.0%),但它无意中提高了中国北部和东部的全球环境融资(例如,北京+24.7%)。相比之下,碳排放交易体系下的结构优化进一步减少了北京7.6%和上海13.1%的全球环境基金。尽管所有情景都在2030年左右达到全国碳排放峰值,但ETS实现了峰值幅度更小、下降幅度更大的最佳轨迹。
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引用次数: 0
Data-driven optimization for sustainable copper recovery and electrolyte recycling in hydrometallurgical processes 湿法冶金过程中可持续铜回收和电解液循环的数据驱动优化
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-08 DOI: 10.1016/j.resconrec.2026.108782
Jiaqi Liao , Han Cheng , Shibing Cai , Jincheng Lu , Zhezhen Yan , Ning Duan , Fuyuan Xu
To address challenges in precise copper concentration prediction and optimal electrolyte diversion in copper hydrometallurgy, this study develops a multi-model framework integrating machine learning (ML) prediction, mechanistic constraints, and collaborative optimization. Among 11 algorithms, the Bayesian-optimized extremely randomized trees (ET) model outperforms others in predicting circulating tank effluent copper concentration, achieving an R2 of 0.839, a MAPE of 1.20%, and 18.68-fold higher accuracy than mechanistic models. SHAP analysis identifies key factors influencing copper concentration. Leveraging ET predictions and mechanistic material conservation, a strategy encompassing dynamic benchmarks, segmented diversion, and closed-loop regulation enables real-time optimization of copper concentration and diversion through two-stage electrowinning, with annual energy savings of 4.72 million kWh. This multi-model methodology provides a replicable paradigm for the intelligent transformation of copper hydrometallurgy, boosting resource conservation and recycling in metallurgy. Its cross-model integration extends to multi-objective optimization in other complex metallurgical processes, offering far-reaching environmental and economic benefits.
为了解决铜湿法冶金中精确铜浓度预测和最佳电解质转移的挑战,本研究开发了一个集成机器学习(ML)预测、机械约束和协同优化的多模型框架。在11种算法中,贝叶斯优化的极度随机树(ET)模型在预测循环水箱出水铜浓度方面优于其他算法,R2为0.839,MAPE为1.20%,准确率比机械模型高18.68倍。SHAP分析确定了影响铜浓度的关键因素。利用ET预测和机械材料节约,一种包含动态基准、分段导流和闭环调节的策略可以通过两阶段电积实现铜浓度和导流的实时优化,每年可节省472万千瓦时的能源。这种多模型方法为铜湿法冶金的智能化改造提供了可复制的范例,促进了冶金资源的节约和循环利用。它的跨模型集成扩展到其他复杂冶金过程的多目标优化,提供深远的环境和经济效益。
{"title":"Data-driven optimization for sustainable copper recovery and electrolyte recycling in hydrometallurgical processes","authors":"Jiaqi Liao ,&nbsp;Han Cheng ,&nbsp;Shibing Cai ,&nbsp;Jincheng Lu ,&nbsp;Zhezhen Yan ,&nbsp;Ning Duan ,&nbsp;Fuyuan Xu","doi":"10.1016/j.resconrec.2026.108782","DOIUrl":"10.1016/j.resconrec.2026.108782","url":null,"abstract":"<div><div>To address challenges in precise copper concentration prediction and optimal electrolyte diversion in copper hydrometallurgy, this study develops a multi-model framework integrating machine learning (ML) prediction, mechanistic constraints, and collaborative optimization. Among 11 algorithms, the Bayesian-optimized extremely randomized trees (ET) model outperforms others in predicting circulating tank effluent copper concentration, achieving an R<sup>2</sup> of 0.839, a MAPE of 1.20%, and 18.68-fold higher accuracy than mechanistic models. SHAP analysis identifies key factors influencing copper concentration. Leveraging ET predictions and mechanistic material conservation, a strategy encompassing dynamic benchmarks, segmented diversion, and closed-loop regulation enables real-time optimization of copper concentration and diversion through two-stage electrowinning, with annual energy savings of 4.72 million kWh. This multi-model methodology provides a replicable paradigm for the intelligent transformation of copper hydrometallurgy, boosting resource conservation and recycling in metallurgy. Its cross-model integration extends to multi-objective optimization in other complex metallurgical processes, offering far-reaching environmental and economic benefits.</div></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":"227 ","pages":"Article 108782"},"PeriodicalIF":10.9,"publicationDate":"2026-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recycling high-level liquid waste into covalent organic framework confined unsymmetrical single Pd-N2 site toward H2O2 photosynthesis 将高放废液转化为限制不对称单Pd-N2位点的共价有机框架进行H2O2光合作用
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-08 DOI: 10.1016/j.resconrec.2026.108783
Zhi Gao , Ruitao You , Kecheng Pan , Qingsheng Huang , Zhenzhen Xu , Long-Shuai Zhang , Jian-Ping Zou
Herein, we show a bioinspired nitrogen-rich covalent organic framework (COFTGTp) with high acid stability and excellent radiation resistance in simulated high-level liquid waste (HLLW). It exhibits the intriguing local self-adaptive behavior to precisely recognize Pd2+ in 3 M HNO3, achieving a high adsorption capacity (317.4 mg g-1) and >99.98% recovery efficiency. Importantly, even in 17 competing ions, the COFTGTp still shows the remarkable Pd2+ selectivity and outstanding Kd value. EXAFS results disclose that the Pd2+ confined in COFTGTp interlayer displays the unsymmetrical Pd-N2 single-site pattern. Noticeably, the Pd2+-confined COFTGTp obtained from HLLW effectively drives O2-to-H2O2 photosynthesis (3002 µmol g-1 h-1). The mechanism studies confirm that the unsymmetrical Pd-N2 site favors the formation of key *HOOH intermediate. The recovery of Pd from HLLW to make a photocatalyst is proposed for the first time, which may stimulate the research into the design of novel COFs to upcycle metal waste into functional, catalytic materials.
在此,我们在模拟高放废液(HLLW)中展示了一种具有高酸稳定性和优异耐辐射性的富氮共价有机骨架(COFTGTp)。在3 M HNO3中精确识别Pd2+,具有良好的局部自适应行为,吸附量高达317.4 mg g-1,回收率高达99.98%。重要的是,即使在17个竞争离子中,COFTGTp仍然表现出显著的Pd2+选择性和出色的Kd值。EXAFS结果表明,限制在COFTGTp层中的Pd2+表现出不对称的Pd-N2单位点模式。值得注意的是,从HLLW中获得的Pd2+限制性COFTGTp有效地驱动了o2 - h2o2的光合作用(3002µmol g-1 h-1)。机理研究证实,Pd-N2位点的不对称有利于关键*HOOH中间体的形成。本文首次提出了从高废渣中回收Pd制备光催化剂的方法,这可能会激发新型COFs的设计研究,从而将金属废物升级为功能催化材料。
{"title":"Recycling high-level liquid waste into covalent organic framework confined unsymmetrical single Pd-N2 site toward H2O2 photosynthesis","authors":"Zhi Gao ,&nbsp;Ruitao You ,&nbsp;Kecheng Pan ,&nbsp;Qingsheng Huang ,&nbsp;Zhenzhen Xu ,&nbsp;Long-Shuai Zhang ,&nbsp;Jian-Ping Zou","doi":"10.1016/j.resconrec.2026.108783","DOIUrl":"10.1016/j.resconrec.2026.108783","url":null,"abstract":"<div><div>Herein, we show a bioinspired nitrogen-rich covalent organic framework (COF<sub>TGTp</sub>) with high acid stability and excellent radiation resistance in simulated high-level liquid waste (HLLW). It exhibits the intriguing local self-adaptive behavior to precisely recognize Pd<sup>2+</sup> in 3 M HNO<sub>3</sub>, achieving a high adsorption capacity (317.4 mg g<sup>-1</sup>) and &gt;99.98% recovery efficiency. Importantly, even in 17 competing ions, the COF<sub>TGTp</sub> still shows the remarkable Pd<sup>2+</sup> selectivity and outstanding <em>K</em><sub>d</sub> value. EXAFS results disclose that the Pd<sup>2+</sup> confined in COF<sub>TGTp</sub> interlayer displays the unsymmetrical Pd-N<sub>2</sub> single-site pattern. Noticeably, the Pd<sup>2+</sup>-confined COF<sub>TGTp</sub> obtained from HLLW effectively drives O<sub>2</sub>-to-H<sub>2</sub>O<sub>2</sub> photosynthesis (3002 µmol g<sup>-1</sup> h<sup>-1</sup>). The mechanism studies confirm that the unsymmetrical Pd-N<sub>2</sub> site favors the formation of key *HOOH intermediate. The recovery of Pd from HLLW to make a photocatalyst is proposed for the first time, which may stimulate the research into the design of novel COFs to upcycle metal waste into functional, catalytic materials.</div></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":"227 ","pages":"Article 108783"},"PeriodicalIF":10.9,"publicationDate":"2026-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Resources Conservation and Recycling
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