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A review on biogenic synthesized zinc oxide nanoparticles: synthesis, characterization, and its applications 生物合成氧化锌纳米颗粒综述:合成、表征及其应用
IF 4.1 3区 化学 Q2 Chemistry Pub Date : 2024-01-01 DOI: 10.1515/revic-2023-0022
Aklilu Melese, Walelign Wubet, Abdu Hussen, Kenaegzer Mulate, Afework Hailekiros
Nanotechnology is the most innovative field of the twenty-first century. Worldwide, intensive research is being done to commercialize nano products. Due to their unique or improved physical and chemical properties relative to bulk material, nanomaterials, especially nanoparticles have seen an enormous interest over the past few decades. As environmentally benign alternative nanoparticles are currently being produced “biologically” by means of plant or microorganism-mediated synthesis. Due to its outstanding biocompatibility, affordability, and low toxicity, and cost-effectiveness, ZnO NPs have emerged as one of the most widely used metal oxide nanoparticles in various applications. Interestingly, due to its multiple medical, health, environmental, and economic advantages, the green technique of synthesis employing plant materials has been discovered to be suitable for the production of ZnO nanoparticles. A variety of characterization methods have been used to assess the characteristics of ZnO NPs produced with green strategies, including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), and UV–Vis spectroscopy and others. The value of these techniques reveals important information about the structural, morphological, and optical characteristics of ZnO NPs. In order to support future biomedical and other research, this review provides an overview of recent developments in the green synthesis of ZnO NPs with a focus on natural sources such as plants, bacteria, fungi, and algae as well as their characterizations, and various applications, including, antimicrobial, anticancer, antioxidant, photocatalytic, anti-inflammatory, anti-diabetics, and anti-aging applications.
纳米技术是二十一世纪最具创新性的领域。全世界都在为纳米产品的商业化进行深入研究。在过去的几十年里,纳米材料,尤其是纳米颗粒,因其相对于大块材料的独特或改进的物理和化学性质,受到了人们的极大关注。作为对环境无害的替代品,纳米粒子目前正通过植物或微生物介导的合成方法进行 "生物 "生产。由于 ZnO NPs 具有出色的生物相容性、经济性、低毒性和成本效益,它已成为各种应用中最广泛使用的金属氧化物纳米粒子之一。有趣的是,由于其在医疗、健康、环境和经济方面的多重优势,人们发现利用植物材料进行合成的绿色技术非常适合生产氧化锌纳米粒子。人们采用了多种表征方法来评估采用绿色策略生产的氧化锌纳米粒子的特性,包括 X 射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅立叶变换红外光谱(FTIR)和紫外可见光谱等。这些技术的价值在于揭示 ZnO NPs 结构、形态和光学特性的重要信息。为了支持未来的生物医学和其他研究,本综述概述了氧化锌氮氧化物绿色合成的最新进展,重点介绍了植物、细菌、真菌和藻类等天然来源的氧化锌氮氧化物及其表征和各种应用,包括抗菌、抗癌、抗氧化、光催化、抗炎、抗糖尿病和抗衰老等应用。
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引用次数: 0
Polyoxometalates as next-generation of theragnostic gadgets in cancer 多金属氧酸盐作为新一代癌症诊断工具
IF 4.1 3区 化学 Q2 Chemistry Pub Date : 2023-12-04 DOI: 10.1515/revic-2023-0008
Fahimeh Aminolroayaei, Ali Mehri, Daryoush Shahbazi-Gahrouei, Mahboubeh Rostami
Polyoxometalates (POMS) are a class of mineral clusters of transition metals or rare-earth elements linked together by Oxo ligands. POMs have been identified as antibacterial, antiviral, and anticancer agents after decades of research since the onset of the 20th century. Furthermore, in recent years POMs have been studied for their applications in diagnosis, photodynamic therapy, photothermal therapy, and theragnostic. However, these last-mentioned POM applications have rarely been reviewed. Considering the potential characteristic features of POMs, comprising their easy, inexpensive, and scalable synthesis, and with special attention to the challenges of their application, POMs would be great alternatives to many conventional medical tools in the field of cancer treatment and diagnosis. In this review, we report recent updated research around utilizing POMs in cancer diagnosis and theragnostic. Publications are on basic topics including POMs in magnetic resonance imaging (MRI), POMs in computed tomography (CT), POMs in cancer photoluminescence (PL) imaging, POMs in multimodality, POMs in radiation therapy applications, POMs as radiosensitizer and promotor of drug release, and POMs in theragnostic applications. It is hoped that this review paper will be useful for those researchers who are interested in expanding the applications of polyoxometalates in the field of cancer treatment and diagnosis.
多金属氧酸盐(POMS)是一类由氧配体连接在一起的过渡金属或稀土元素的矿物簇。自20世纪初以来,经过几十年的研究,聚甲醛已被确定为抗菌、抗病毒和抗癌药物。此外,近年来pom在诊断、光动力治疗、光热治疗和诊断等方面的应用也得到了广泛的研究。然而,这些最后提到的POM应用程序很少被审查。考虑到POMs的潜在特征,包括其简单、廉价和可扩展的合成,并特别注意其应用中的挑战,POMs将成为癌症治疗和诊断领域许多传统医疗工具的重要替代品。在这篇综述中,我们报告了最近关于利用聚甲醛在癌症诊断和治疗中的最新研究。出版物的基本主题包括POMs在磁共振成像(MRI)中的应用,POMs在计算机断层扫描(CT)中的应用,POMs在癌症光致发光(PL)成像中的应用,POMs在多模态中的应用,POMs在放射治疗中的应用,POMs作为放射增敏剂和药物释放促进剂的应用,以及POMs在治疗中的应用。希望本文能对有意拓展多金属氧酸盐在癌症治疗和诊断领域应用的研究人员有所帮助。
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引用次数: 0
Advances in the improvement of photocatalytic activity of BiOCl nanomaterials under visible light 提高BiOCl纳米材料可见光光催化活性的研究进展
IF 4.1 3区 化学 Q2 Chemistry Pub Date : 2023-11-22 DOI: 10.1515/revic-2023-0013
Linjing Hao, Haoran Sang, Yuwei Hou, Peng Li, Jie Zhang, Jing-He Yang
Photocatalysis is an effective way to alleviate the energy crisis and environmental pollution. Bismuth Chloride Oxide (BiOCl) is one of the most widely studied metal oxides due to its unique surface and electronic structure. However, the wide band gap of BiOCl and the high complexation rate of photogenerated electron–hole pairs limit its photocatalytic efficiency. Increasingly, efforts are being made to improve the performance of this range of photocatalysts. The article reviews the progress of research to enhance the photocatalytic activity of BiOCl nanomaterials. Strategies to improve the photocatalytic performance of single-phase BiOCl include morphological control, component adjustment, crystal facet control, and defects construction. Strategies to improve the photocatalytic activity of BiOCl-based composites include surface modification, immobilization of photocatalysts, impurity doping, and the construction of heterojunctions. In addition, the challenges and trends of BiOCl photocatalysts are discussed and summarized. Hopefully, this review will be helpful for the research and application of BiOCl photocatalysts.
光催化是缓解能源危机和环境污染的有效途径。氯化铋氧化物(BiOCl)由于其独特的表面和电子结构而成为研究最广泛的金属氧化物之一。然而,BiOCl的宽带隙和光生电子-空穴对的高络合速率限制了其光催化效率。人们正越来越多地努力提高这一系列光催化剂的性能。本文综述了增强BiOCl纳米材料光催化活性的研究进展。提高单相BiOCl光催化性能的策略包括形态控制、组分调整、晶面控制和缺陷构建。提高biocl基复合材料光催化活性的策略包括表面改性、光催化剂固定化、杂质掺杂和异质结的构建。此外,对BiOCl光催化剂面临的挑战和发展趋势进行了讨论和总结。希望对BiOCl光催化剂的研究和应用有所帮助。
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引用次数: 0
Green synthesis of strontium oxide nanoparticles and strontium based nanocomposites prepared by plant extract: a critical review 绿色合成氧化锶纳米粒子和植物提取物制备的锶基纳米复合材料:综述
3区 化学 Q2 Chemistry Pub Date : 2023-10-06 DOI: 10.1515/revic-2023-0011
Muhammad Imran Din, Sania Rehman, Zaib Hussain, Rida Khalid
Abstract Recently, strontium oxide nanoparticles (SrO NPs) have become the center of attention due to potential features and promising applications. The physicochemical approaches possess many limitations including extreme experimental conditions, highly complex instruments and use of hazardous chemicals. An eco-friendly and sustainable approach from biogenic sources for formation of SrO NPs is an emerging trend nowadays to effectively replace conventional approaches. This review study all those aspects that facilitate the reader for understanding all biogenic approaches of SrO NPs for their use in different applications with less toxicity issues. In this study, firstly we discuss in detail about plant and other biogenic assemblies based on the synthesis of SrO NPs after which parameters affecting the synthesis of SrO NPs are discussed and finally excellent biomedical applications of SrO NPs along with mechanism are summarized. The literature also showed that green synthesized SrO NPs are highly biocompatible in nature and showed excellent anti-bacterial, anti-oxidant and anti-fungal potential. Hence, this study will provide an understanding to researchers about recent trends for the formation of SrO NPs through different biogenic assemblies and their potential biomedical applications.
近年来,氧化锶纳米颗粒(SrO NPs)因其潜在的特性和广阔的应用前景而成为人们关注的焦点。物理化学方法具有许多局限性,包括极端的实验条件,高度复杂的仪器和使用危险化学品。利用生物源形成SrO NPs的生态友好和可持续的方法是当今有效取代传统方法的新兴趋势。这篇综述研究了所有有助于读者理解SrO NPs的所有生物源性方法,以及它们在不同应用中的低毒性问题。本文首先详细讨论了基于SrO NPs合成的植物和其他生物源组装体,然后讨论了影响SrO NPs合成的参数,最后总结了SrO NPs在生物医学上的良好应用及其机理。文献还表明,绿色合成的SrO NPs在自然界中具有高度的生物相容性,并具有良好的抗菌、抗氧化和抗真菌潜力。因此,本研究将有助于研究人员了解SrO NPs通过不同生物源组装形成的最新趋势及其潜在的生物医学应用。
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引用次数: 0
Porous materials: Covalent Organic Frameworks (COFs) as game-changers in practical applications, a review 多孔材料:共价有机框架(COFs)在实际应用中的改变
3区 化学 Q2 Chemistry Pub Date : 2023-09-21 DOI: 10.1515/revic-2023-0018
Amsal Shahbaz, Khalil Ahmad, Khizar Qureshi, Hammad Majeed, Ifzan Arshad, Tabinda Tabinda, Tehreema Iftikhar, None Kashaf-ul Khair, Muhammad Ashfaq, Habib Ur Rehman Shah, Muhammad Zubair Ahmad, Shern-long Lee
Abstract Covalent Organic Frameworks (COFs) represents a class of remarkable porous materials composed of organic building blocks that are covalently linked in a periodic manner to form crystalline structures. High surface area, high porosity, tunable pore size, and high stability are their exceptional properties, which make them attractive candidates for various applications in the fields of catalysis, energy storage devices, biomedical applications, gas separation and storage applications. In fact, the great interest shown in COFs gave us a stimulus to review the output of the recent substantial efforts in this area. Meanwhile, the development of portable and sophisticated systems based on these particles is believed to create deeper insights for the scientists to embark on new investigations to pave the way for discovering new fundamental characteristics of COFs, modifications. Furthermore, the effect of modifications/fractionalizations on the performance of COFs will be thoroughly explained and challenging problems are mentioned. Moreover, the paper covers an inclusive collection of referenced recent research articles, providing readers with a comprehensive understanding of the subject matter and an extensive bibliography for further exploration. Through this comprehensive overview, the paper alleviates the noteworthy contributions of COFs in driving innovation and progress in a range of key scientific disciplines.
摘要:共价有机框架(COFs)是一类由有机构建块组成的显著多孔材料,这些有机构建块以周期性的方式共价连接形成晶体结构。高表面积、高孔隙率、可调孔径和高稳定性是其独特的特性,使其在催化、储能装置、生物医学应用、气体分离和存储应用等领域具有广泛的应用前景。事实上,对COFs表现出的极大兴趣促使我们审查最近在这一领域的大量努力的产出。与此同时,基于这些粒子的便携式复杂系统的发展被认为为科学家们提供了更深入的见解,从而开始新的研究,为发现COFs的新基本特征、修饰铺平道路。此外,修改/分馏化对COFs性能的影响将被彻底解释,并提到具有挑战性的问题。此外,本文涵盖了一个包容性的集合,参考了最近的研究文章,为读者提供了一个全面的了解的主题和广泛的参考书目,以进一步探索。通过这一综合综述,本文总结了COFs在推动一系列关键科学学科创新和进步方面的显著贡献。
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引用次数: 2
Inorganic hydrogels: synthetic strategies, properties and applications 无机水凝胶:合成策略、性质及应用
3区 化学 Q2 Chemistry Pub Date : 2023-09-18 DOI: 10.1515/revic-2023-0019
Elena V. Parfenyuk, Ekaterina S. Dolinina
Abstract Hydrogels are widely used in various areas of human life. The vast majority of hydrogel materials used are polymer-based. Despite a number of advantages compared to polymer-based materials, studies on inorganic hydrogels are very limited and scattered. They are rarely offered as a basis for development of new functional materials. This review is an attempt to draw attention of researches to inorganic hydrogels. It describes currently existing methods for the synthesis of such hydrogels, their properties, and shows possible applications of the hydrogel materials.
摘要水凝胶广泛应用于人类生活的各个领域。绝大多数使用的水凝胶材料是聚合物基的。尽管与聚合物基材料相比,无机水凝胶具有许多优点,但对其的研究非常有限和分散。它们很少作为开发新功能材料的基础。本文综述了无机水凝胶的研究现状,以期引起人们对无机水凝胶研究的重视。它描述了目前合成这种水凝胶的现有方法,它们的性质,并展示了水凝胶材料的可能应用。
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引用次数: 1
Frontmatter 头版头条
3区 化学 Q2 Chemistry Pub Date : 2023-09-01 DOI: 10.1515/revic-2023-frontmatter3
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引用次数: 0
Acyclic diaminocarbenes (ADCs) and their catalytic activity in metal catalysed organic transformation reactions 非环二氨基卡宾(ADC)及其在金属催化有机转化反应中的催化活性
IF 4.1 3区 化学 Q2 Chemistry Pub Date : 2023-08-25 DOI: 10.1515/revic-2022-0037
A. Maurya, Rajpal Tyagi
Abstract Acyclic diaminocarbenes (ADCs)–Metal complex having strong donor ability and thermal stability led to extensive usability across every area of inorganic and organometallic chemistry. The unique properties of acyclic diaminocarbenes (ADCs) provide certain advantages over other carbene ligands and have the potential to make a great impact in catalysis. Further, the straightforward synthesis of M–ADCs (metal bound acyclic diaminocarbenes) complexes via metal-mediated reaction provides a wide range of well-defined metal carbene catalysts, which might inspire more researchers to devise unsymmetrically substituted, chiral, and novel acyclic carbene compounds. Although the above synthetic route is limited to a few late transition metals, but have great opportunities to expand the scope of this method. The application of M–ADCs complexes as a catalyst for several organic transformation reactions such as various cross-coupling reactions and asymmetric synthesis like hydroarylation, hydroazidation, hydroamination, cyclization and addition reactions which have shown comparable or even higher activities than the analogous M–NHCs based on all the reports presented. Recent findings of donor ability of several ADC ligands would be useful in fine-tuning the electronic properties, and then a catalyst with a certain combination of donicity and steric requirement could open new doors in catalytic reactivity. Thus, the objective of this review is to assess the recent growths that have been made in designing novel and chiral ADCs ligands and synthesizing ADCs–Metal complexes and to highlight catalytic activities of metal acyclic diaminocarbene complexes for cross-coupling reactions.
摘要无环二氨基卡宾(ADC)-具有强大供体能力和热稳定性的金属络合物在无机和有机金属化学的各个领域都具有广泛的可用性。无环二氨基卡宾(ADC)的独特性质提供了优于其他卡宾配体的某些优势,并有可能在催化中产生巨大影响。此外,通过金属介导的反应直接合成M–ADC(金属结合的无环二氨基卡宾)复合物提供了一系列定义明确的金属卡宾催化剂,这可能会激励更多的研究人员设计不对称取代的、手性的和新型的无环卡宾化合物。虽然上述合成路线仅限于少数晚期过渡金属,但有很大的机会扩大这种方法的范围。M–ADC络合物作为催化剂在几种有机转化反应中的应用,如各种交叉偶联反应和不对称合成,如加氢芳基化、加氢叠氮化、加氢胺化、环化和加成反应,这些反应显示出与类似的M–NHCs相当甚至更高的活性。最近对几种ADC配体的供体能力的发现将有助于微调电子性质,然后具有一定的多尼性和空间要求组合的催化剂可以在催化反应性方面打开新的大门。因此,本综述的目的是评估最近在设计新型手性ADC配体和合成ADC-金属络合物方面取得的进展,并强调金属非环二氨基卡宾络合物对交叉偶联反应的催化活性。
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引用次数: 0
The coordination chemistry and supramolecular interactions of 2-(2′-Pyridyl)imidazole ligand: a comprehensive review with theoretical insight 2-(2 ' -吡啶基)咪唑配体的配位化学和超分子相互作用:具有理论见解的综合综述
IF 4.1 3区 化学 Q2 Chemistry Pub Date : 2023-08-10 DOI: 10.1515/revic-2023-0016
Debabrata Singha, Sasthi Charan Halder, A. D. Jana, N. Pal
Abstract This review explores the role of 2-(2′-Pyridyl)imidazole (PyimH) as a coordinating ligand and also its role as a supramolecular agent through hydrogen bonding and π⋯π interaction. Two N coordination sites make 2-(2′-Pyridyl)imidazole an analogous ligand to 2,2′-bipyridine. The syn orientation of imidazole and pyridine sp 2 nitrogen makes it a bidentate chelating ligand. PyimH mainly produces discrete coordination complexes (0D), but in a few cases, 1D coordination polymers are observed due to bridging co-ligands like oxalate, dicyanamide, tricyanomethanide, croconate, thiocyanate, and iso-thiocyanate. These discrete coordination units and co-ligand bridged 1D coordination polymers are further augmented to higher dimensional supramolecular systems having linear, zig-zag, ladder-shaped, ribbon-like, and helical geometry. These supramolecular structures are stabilized by intermolecular hydrogen bonding interaction (N–H⋯N, N–H⋯O, O–H⋯N, O–H⋯O, and C–H⋯O) and π⋯π interaction capability of PyimH ligand. PyimH generally acts as an excellent chelating ligand for a range of metal ions and is also a capable supramolecular glueing agent due to hydrogen bonding and π-stacking ability.
本文综述了2-(2 ' -吡啶基)咪唑(PyimH)作为配位体的作用,以及它通过氢键和π⋯π相互作用作为超分子剂的作用。两个N配位使2-(2′-吡啶基)咪唑成为类似于2,2′-联吡啶的配体。咪唑和吡啶sp 2氮的同向取向使其成为双齿螯合配体。PyimH主要产生离散配位配合物(0D),但在少数情况下,由于桥接的共配体,如草酸盐、二氰酰胺、三氰甲烷、croconate、硫氰酸盐和异硫氰酸盐,可以观察到一维配位聚合物。这些离散配位单元和共配体桥接的一维配位聚合物进一步扩展到具有线性、锯齿形、阶梯形、带状和螺旋几何形状的高维超分子体系。这些超分子结构通过分子间氢键相互作用(N - h⋯N, N - h⋯O, O - h⋯N, O - h⋯O和C-H⋯O)和PyimH配体的π⋯π相互作用能力来稳定。PyimH通常作为一系列金属离子的优秀螯合配体,由于氢键和π堆积能力,它也是一种功能强大的超分子胶合剂。
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引用次数: 0
Catalytic oxidation degradation of volatile organic compounds (VOCs) – a review 挥发性有机化合物(VOCs)的催化氧化降解研究进展
IF 4.1 3区 化学 Q2 Chemistry Pub Date : 2023-07-28 DOI: 10.1515/revic-2023-0015
Wenju Liu, Zheng Zhang, Kailong Yuan, Dang R. Dang, Peng Jin, Xiaofei Han, Qun Ge
Abstract Volatile organic compounds (VOCs) are considered one of the significant contributors to air pollution because they are toxic, difficult to remove, come from a wide range of sources, and can easily cause damage to the environment and human health. There is an urgent need for effective means to reduce their emissions. The current treatment technologies for VOCs include catalytic oxidation, adsorption, condensation, and recovery. Catalytic oxidation technology stands out among the others thanks to its high catalytic efficiency, low energy requirement, and lack of secondary pollution. The difficulty of this technology lies in the development of efficient catalysts. The research on loaded noble metal catalysts and non-noble metal oxide catalysts in this area over the past few years is briefly described in this work. Firstly, the catalytic destruction mechanism of organic volatile compounds is introduced. Secondly, the effects of structural modulation during catalytic oxidation, such as the adjustment of noble metal particle size and morphology, metal doping, and defect engineering, on the conformational relationships are discussed. Finally, the challenges faced by thermal catalytic oxidation for the degradation of VOCs are discussed, and the prospects for its development are presented.
摘要挥发性有机化合物(VOCs)被认为是造成空气污染的重要因素之一,因为它们有毒,难以去除,来源广泛,容易对环境和人类健康造成损害。迫切需要有效的手段来减少它们的排放。目前VOCs的处理技术包括催化氧化、吸附、冷凝和回收。催化氧化技术因其催化效率高、能耗低、无二次污染而脱颖而出。这项技术的难点在于开发高效的催化剂。本文简要介绍了近年来负载型贵金属催化剂和非贵金属氧化物催化剂在该领域的研究进展。首先介绍了有机挥发性化合物的催化破坏机理。其次,讨论了催化氧化过程中的结构调节,如贵金属颗粒大小和形态的调整、金属掺杂和缺陷工程,对构象关系的影响。最后,讨论了热催化氧化降解挥发性有机物所面临的挑战,并对其发展前景进行了展望。
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引用次数: 1
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