Shahab Khan, Faizan Ur Rahman, Inam Ullah, Salman Khan, Zarif Gul, Fazal Sadiq, Tufail Ahmad, Sayed M. Shakil Hussain, Ijaz Ali, Muhammad Israr
In this article, we explore the role of nanotechnology in addressing water scarcity through water desalination. The scope of nanotechnology in water treatment is discussed, emphasizing the potential of 2D nanomaterials such as hexagonal boron nitride (h-BN), graphene, and quantum dots in revolutionizing desalination technologies. Various water desalination techniques, including membrane distillation (MD), solar-powered multi-stage flash distillation (MSF), and multi-effect distillation (MED), are analyzed in the context of nanomaterial applications. The review highlights the energy-intensive nature of conventional water treatment methods and underscores nanomaterials’ potential to enhance efficiency and sustainability in water desalination processes. Challenges facing desalination, such as scalability and environmental impact, are acknowledged, setting the stage for future research directions.
{"title":"Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots","authors":"Shahab Khan, Faizan Ur Rahman, Inam Ullah, Salman Khan, Zarif Gul, Fazal Sadiq, Tufail Ahmad, Sayed M. Shakil Hussain, Ijaz Ali, Muhammad Israr","doi":"10.1515/revic-2024-0013","DOIUrl":"https://doi.org/10.1515/revic-2024-0013","url":null,"abstract":"In this article, we explore the role of nanotechnology in addressing water scarcity through water desalination. The scope of nanotechnology in water treatment is discussed, emphasizing the potential of 2D nanomaterials such as hexagonal boron nitride (h-BN), graphene, and quantum dots in revolutionizing desalination technologies. Various water desalination techniques, including membrane distillation (MD), solar-powered multi-stage flash distillation (MSF), and multi-effect distillation (MED), are analyzed in the context of nanomaterial applications. The review highlights the energy-intensive nature of conventional water treatment methods and underscores nanomaterials’ potential to enhance efficiency and sustainability in water desalination processes. Challenges facing desalination, such as scalability and environmental impact, are acknowledged, setting the stage for future research directions.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"17 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141190438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Green nanotechnology comprises the use of natural sources such as plant extracts as both reducing and stabilizing agents thereby reducing the reliance on hazardous chemicals. Recent breakthroughs in nanotechnology involve the incorporation of various metals to create mono and bimetallic nanoparticles, catalyzing transformative shifts. However, concerns arise due to the environmental impact of traditional synthesis methods. An alternative approach focuses on biosynthesized metal nanoparticles using clay, specifically Bentonite, MMT (Montmorillonite) and Kaolinite as supportive materials, emphasizing the prevention of agglomeration with clay and the use of plant extracts. The integration of clay, especially Bentonite, MMT and Kaolinite enhances the stability and functionality. The review emphasizes mitigating environmental impact by reducing metal ions and explores the use of phytochemicals fro environmentally friendly nanoparticle synthesis. Incorporating clay minerals not only improves synthesis efficiency but also minimizes the ecological footprint. Future research is expected to focus on integrative approaches in plant nanotechnology, particularly in agriculture and broader plant science. The comprehensive review covers literature from 2015 to 2023, providing systematic and interpretative data, highlighting progress and potential in eco-friendly metal nanoparticles synthesis supported on clay minerals.
{"title":"Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review","authors":"Manash Pratim Barman, Dipanwita Basak, Debasis Borah, Deepmoni Brahma, Mandira Debnath, Hemaprobha Saikia","doi":"10.1515/revic-2024-0008","DOIUrl":"https://doi.org/10.1515/revic-2024-0008","url":null,"abstract":"Green nanotechnology comprises the use of natural sources such as plant extracts as both reducing and stabilizing agents thereby reducing the reliance on hazardous chemicals. Recent breakthroughs in nanotechnology involve the incorporation of various metals to create mono and bimetallic nanoparticles, catalyzing transformative shifts. However, concerns arise due to the environmental impact of traditional synthesis methods. An alternative approach focuses on biosynthesized metal nanoparticles using clay, specifically Bentonite, MMT (Montmorillonite) and Kaolinite as supportive materials, emphasizing the prevention of agglomeration with clay and the use of plant extracts. The integration of clay, especially Bentonite, MMT and Kaolinite enhances the stability and functionality. The review emphasizes mitigating environmental impact by reducing metal ions and explores the use of phytochemicals fro environmentally friendly nanoparticle synthesis. Incorporating clay minerals not only improves synthesis efficiency but also minimizes the ecological footprint. Future research is expected to focus on integrative approaches in plant nanotechnology, particularly in agriculture and broader plant science. The comprehensive review covers literature from 2015 to 2023, providing systematic and interpretative data, highlighting progress and potential in eco-friendly metal nanoparticles synthesis supported on clay minerals.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"63 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141169712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Baneesh Patial, Ajay Bansal, Renu Gupta, Susheel K. Mittal
The novel semiconductor photocatalytic material bismuth vanadate (BiVO4) is gaining significant attention in research due to its unique characteristics, which include a low band gap, good responsiveness to visible light, and non-toxic nature. However, intrinsic constraints such as poor photogenerated charge transfer, slow water oxidation kinetics, and fast electron–hole pair recombination limit the photocatalytic activity of BiVO4. Building heterojunctions has shown to be an effective strategy for enhancing charge separation and impeding electron–hole pair recombination over the last few decades. This review covers the state-of-the-art developments in heterojunction nanomaterials based on BiVO4 for photocatalysis. It explores heterojunction design, clarifies reaction mechanisms, and highlights the current developments in applications including photocatalytic water splitting and organic matter degradation. Finally, it offers a preview of the development paths and opportunities for BiVO4-based heterojunction nanomaterials in the future. This comprehensive assessment of BiVO4-based heterojunctions provides insightful knowledge to researchers in materials science, chemistry, and environmental engineering that will drive advances and breakthroughs in these important fields.
{"title":"BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation","authors":"Baneesh Patial, Ajay Bansal, Renu Gupta, Susheel K. Mittal","doi":"10.1515/revic-2024-0009","DOIUrl":"https://doi.org/10.1515/revic-2024-0009","url":null,"abstract":"The novel semiconductor photocatalytic material bismuth vanadate (BiVO<jats:sub>4</jats:sub>) is gaining significant attention in research due to its unique characteristics, which include a low band gap, good responsiveness to visible light, and non-toxic nature. However, intrinsic constraints such as poor photogenerated charge transfer, slow water oxidation kinetics, and fast electron–hole pair recombination limit the photocatalytic activity of BiVO<jats:sub>4</jats:sub>. Building heterojunctions has shown to be an effective strategy for enhancing charge separation and impeding electron–hole pair recombination over the last few decades. This review covers the state-of-the-art developments in heterojunction nanomaterials based on BiVO<jats:sub>4</jats:sub> for photocatalysis. It explores heterojunction design, clarifies reaction mechanisms, and highlights the current developments in applications including photocatalytic water splitting and organic matter degradation. Finally, it offers a preview of the development paths and opportunities for BiVO<jats:sub>4</jats:sub>-based heterojunction nanomaterials in the future. This comprehensive assessment of BiVO<jats:sub>4</jats:sub>-based heterojunctions provides insightful knowledge to researchers in materials science, chemistry, and environmental engineering that will drive advances and breakthroughs in these important fields.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"23 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140934329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Saleh Bufarwa, Reem El-Seifat, Hana Binhamad, Rehab Hesien
Scientists are searching for reactive oxygen species, which have been associated with various health issues like heart problems, neurological disorders, inflammation, and aging. Salen complexes have proven to be effective in multiple oxidative stress situations and have been used as catalase and superoxide mimetics. To explore this further, three mixed complexes were synthesized using a Schiff base (salen) and a sugar (d-glucose) with Co(II), Ni(II), and Cu(II) ions. These complexes were then diagnosed by different analytical and spectral techniques. Stoichiometry, stereochemistry, some physical properties, and the method of bonding complexes were measured. Comparisons of the IR and 1HNMR spectra of the ligands with the complexes demonstrated the involvement of the azomethine group of the ligand in the chelation process. The mass spectra and TGA agree with the proposed formula of the complexes, and the conductivity and UV–Vis data supported the octahedral geometry of the complexes, and information was obtained from partial parameter calculations by molecular modeling. The metal complexes exhibited strong antimicrobial and antioxidant properties when compared to standard drugs. The like-superoxide and catalyst mimetic complexes were screened using DPPH ABTS, revealing their effectiveness.
{"title":"Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base","authors":"Saleh Bufarwa, Reem El-Seifat, Hana Binhamad, Rehab Hesien","doi":"10.1515/revic-2023-0028","DOIUrl":"https://doi.org/10.1515/revic-2023-0028","url":null,"abstract":"Scientists are searching for reactive oxygen species, which have been associated with various health issues like heart problems, neurological disorders, inflammation, and aging. Salen complexes have proven to be effective in multiple oxidative stress situations and have been used as catalase and superoxide mimetics. To explore this further, three mixed complexes were synthesized using a Schiff base (salen) and a sugar (<jats:sc>d</jats:sc>-glucose) with Co(II), Ni(II), and Cu(II) ions. These complexes were then diagnosed by different analytical and spectral techniques. Stoichiometry, stereochemistry, some physical properties, and the method of bonding complexes were measured. Comparisons of the IR and <jats:sup>1</jats:sup>HNMR spectra of the ligands with the complexes demonstrated the involvement of the azomethine group of the ligand in the chelation process. The mass spectra and TGA agree with the proposed formula of the complexes, and the conductivity and UV–Vis data supported the octahedral geometry of the complexes, and information was obtained from partial parameter calculations by molecular modeling. The metal complexes exhibited strong antimicrobial and antioxidant properties when compared to standard drugs. The like-superoxide and catalyst mimetic complexes were screened using DPPH ABTS, revealing their effectiveness.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"59 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140828899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shahab Khan, Hong-Wei Zheng, Huan Jiao, Shahroz Saleem, Zarif Gul, Jehan Y. Al-Humaidi, Areej Al Bahir, Raed H. Althomali, Arshad Ali, Mohammed M. Rahman
This article critically examines the reduction mechanisms and energy transfer processes between trivalent europium ions (Eu3+) and divalent europium ions (Eu2+) in materials synthesized in an air atmosphere. It also encompasses various materials and conditions, including a critical analysis of the reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials. Specific investigations include exploring the reduction process in BaMgSiO4:Eu, focusing on factors influencing the reaction. The article also covers low-temperature self-reduction, addressing conditions and mechanisms such as the charge compensation model and laser-induced reduction. Additionally, it explores the influence of charge compensation on luminescent properties, emphasizing enhancements in red emission. Investigations into the role of oxygen vacancies in the reduction of Eu3+ and their implications on material properties are presented. This article further digs into abnormal reduction processes and the formation of defect centers in Eu3+-doped pollucite, proposing a substitution defect model for the self-reduction of europium ions in silicate Ba(Eu)MgSiO4 phosphors. Unusual reduction phenomena, such as reduction via boiling water in Yb2Si2O7:Eu3+ phosphors, and reductions in various glass systems, including porous glass, ZnO–B2O3–P2O5 glasses, aluminoborosilicate glasses, europium-doped Li2B4O7 glass, and aluminosilicate oxyfluoride glass (AOG), are also thoroughly examined.
{"title":"Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere","authors":"Shahab Khan, Hong-Wei Zheng, Huan Jiao, Shahroz Saleem, Zarif Gul, Jehan Y. Al-Humaidi, Areej Al Bahir, Raed H. Althomali, Arshad Ali, Mohammed M. Rahman","doi":"10.1515/revic-2024-0011","DOIUrl":"https://doi.org/10.1515/revic-2024-0011","url":null,"abstract":"This article critically examines the reduction mechanisms and energy transfer processes between trivalent europium ions (Eu<jats:sup>3+</jats:sup>) and divalent europium ions (Eu<jats:sup>2+</jats:sup>) in materials synthesized in an air atmosphere. It also encompasses various materials and conditions, including a critical analysis of the reduction mechanism and energy transfer between Eu<jats:sup>3+</jats:sup> and Eu<jats:sup>2+</jats:sup> in Eu-doped materials. Specific investigations include exploring the reduction process in BaMgSiO<jats:sub>4</jats:sub>:Eu, focusing on factors influencing the reaction. The article also covers low-temperature self-reduction, addressing conditions and mechanisms such as the charge compensation model and laser-induced reduction. Additionally, it explores the influence of charge compensation on luminescent properties, emphasizing enhancements in red emission. Investigations into the role of oxygen vacancies in the reduction of Eu<jats:sup>3+</jats:sup> and their implications on material properties are presented. This article further digs into abnormal reduction processes and the formation of defect centers in Eu<jats:sup>3+</jats:sup>-doped pollucite, proposing a substitution defect model for the self-reduction of europium ions in silicate Ba(Eu)MgSiO<jats:sub>4</jats:sub> phosphors. Unusual reduction phenomena, such as reduction via boiling water in Yb<jats:sub>2</jats:sub>Si<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>:Eu<jats:sup>3+</jats:sup> phosphors, and reductions in various glass systems, including porous glass, ZnO–B<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>–P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> glasses, aluminoborosilicate glasses, europium-doped Li<jats:sub>2</jats:sub>B<jats:sub>4</jats:sub>O<jats:sub>7</jats:sub> glass, and aluminosilicate oxyfluoride glass (AOG), are also thoroughly examined.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"9 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140828706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rebeka Rudolf, Peter Majerič, Žiga Jelen, Andrej Horvat, Damjan Krajnc
This review provides a detailed inventory analysis of the manufacturing process of a cosmetic cream using gold nanoparticles (AuNPs) and hydroxylated fullerene water complex (3HFWC) as novel nanocomponents for cream. The inventory analysis was focused on the evaluation of the two raw materials of the nanocomponents, the consumption of electricity and water, which enabled an insight into the process flows within the production process. The data obtained from this analysis of the inventory of nanocomponents provide an insight into the potential improvements that can be made in the manufacturing process of nanocomponents, in order to reduce the environmental impact of the production of new cosmetic creams. These results will serve as the basis for the second part of the analysis, where a life cycle analysis will be carried out to assess the environmental impacts of cream production from the acquisition of raw materials to the disposal of the final product.
{"title":"The environmental impact of using gold nanoparticles and 3HFWC in cosmetics, as determined with LCA methodology","authors":"Rebeka Rudolf, Peter Majerič, Žiga Jelen, Andrej Horvat, Damjan Krajnc","doi":"10.1515/revic-2024-0012","DOIUrl":"https://doi.org/10.1515/revic-2024-0012","url":null,"abstract":"This review provides a detailed inventory analysis of the manufacturing process of a cosmetic cream using gold nanoparticles (AuNPs) and hydroxylated fullerene water complex (3HFWC) as novel nanocomponents for cream. The inventory analysis was focused on the evaluation of the two raw materials of the nanocomponents, the consumption of electricity and water, which enabled an insight into the process flows within the production process. The data obtained from this analysis of the inventory of nanocomponents provide an insight into the potential improvements that can be made in the manufacturing process of nanocomponents, in order to reduce the environmental impact of the production of new cosmetic creams. These results will serve as the basis for the second part of the analysis, where a life cycle analysis will be carried out to assess the environmental impacts of cream production from the acquisition of raw materials to the disposal of the final product.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"81 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140828705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The study aims to synthesize a selective matrix imprinted sorbent for the extraction of parathion and malathion. The structural unit of the polymeric framework was 2-methylpropanoic acid, the intermolecular crosslinker was ethylene glycol dimethacrylate, the polymerization initiator was azobisisobutyronitrile, the porogen was xylene, and the analyte was parathion. The synthesis was carried out under conditions of heating the reaction mixture to 65 °C, after which the matrix was washed with methanol to remove the analyte. For comparison purposes, non-imprinted control polymer was used as a negative control, which was prepared similarly, but without the addition of the analyte. The identification and quantification of organophosphates were performed by gas chromatography, and the morphological characteristics of the sorbents were evaluated by scanning electron microscopy. The optimal buffer for the purification of organophosphates was acetate buffer with a pH of 4; the optimal organic eluent was methanol. The limit of detection for para- and malathion was 0.1 μg/ml; the limit of quantification was 0.3 μg/ml. Linearity in the extraction conditions was observed in the range of 0.1–1 μg/ml for parathion and 0.1–2 μg/ml for malathion. The developed method will enable quick, selective, and cost-effective extraction of organophosphates from various substrates.
{"title":"Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent","authors":"Bandar R. Alsehli","doi":"10.1515/revic-2024-0010","DOIUrl":"https://doi.org/10.1515/revic-2024-0010","url":null,"abstract":"The study aims to synthesize a selective matrix imprinted sorbent for the extraction of parathion and malathion. The structural unit of the polymeric framework was 2-methylpropanoic acid, the intermolecular crosslinker was ethylene glycol dimethacrylate, the polymerization initiator was azobisisobutyronitrile, the porogen was xylene, and the analyte was parathion. The synthesis was carried out under conditions of heating the reaction mixture to 65 °C, after which the matrix was washed with methanol to remove the analyte. For comparison purposes, non-imprinted control polymer was used as a negative control, which was prepared similarly, but without the addition of the analyte. The identification and quantification of organophosphates were performed by gas chromatography, and the morphological characteristics of the sorbents were evaluated by scanning electron microscopy. The optimal buffer for the purification of organophosphates was acetate buffer with a pH of 4; the optimal organic eluent was methanol. The limit of detection for para- and malathion was 0.1 μg/ml; the limit of quantification was 0.3 μg/ml. Linearity in the extraction conditions was observed in the range of 0.1–1 μg/ml for parathion and 0.1–2 μg/ml for malathion. The developed method will enable quick, selective, and cost-effective extraction of organophosphates from various substrates.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"4 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140636552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The controlled synthesis of precise carbon nanostructures with high electron conductivity, high reaction activity, and structural stability plays a significant role in practical applications yet largely unmet. Metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and coordination polymers (CPs) as crystalline porous materials (CPMs) have shown extraordinary porosity, tremendous structural diversity, and highly ordered pores, offering a platform for precise controlled carbon materials (CMs) with regular porous structures and high performances. Some recent studies have shown that CMs derived from CPMs with high specific surface area, superior chemical stability, excellent electrical conductivity offer a great opportunity for electrochemical energy storage and conversion. In this review, we summarize recent milestones of CPMs derived CMs in the field of capacitive energy storage. We hope the more precise design and control at the atomic level of CPMs could provide us a constructive view of the structure-activity relationship between CMs and electrochemical capacitors, as well as future trends and prospects.
{"title":"Carbon materials derived by crystalline porous materials for capacitive energy storage","authors":"Hang Wang, Yiting Li, Longyu Wang, Jieting Jin","doi":"10.1515/revic-2023-0039","DOIUrl":"https://doi.org/10.1515/revic-2023-0039","url":null,"abstract":"The controlled synthesis of precise carbon nanostructures with high electron conductivity, high reaction activity, and structural stability plays a significant role in practical applications yet largely unmet. Metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and coordination polymers (CPs) as crystalline porous materials (CPMs) have shown extraordinary porosity, tremendous structural diversity, and highly ordered pores, offering a platform for precise controlled carbon materials (CMs) with regular porous structures and high performances. Some recent studies have shown that CMs derived from CPMs with high specific surface area, superior chemical stability, excellent electrical conductivity offer a great opportunity for electrochemical energy storage and conversion. In this review, we summarize recent milestones of CPMs derived CMs in the field of capacitive energy storage. We hope the more precise design and control at the atomic level of CPMs could provide us a constructive view of the structure-activity relationship between CMs and electrochemical capacitors, as well as future trends and prospects.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"143 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140585134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Khalida Naseem, Asad Aziz, Mohammad Ehtisham Khan, Shahzaib Ali, Awais Khalid
This review article covers the biogenic synthesis of metal nanoparticles (MNPs) having definite shape and size while using extract obtained from different biological sources such as bacteria, fungi, algae and plants. These biological materials are composed of chloroplast, thylakoid, different types of enzymes extracted from different biogenic sources, different phytochemicals such as phenols, flavonoids, and citric acid having functional groups such as sulfate, carboxyl, amino, amide and hydroxyl groups. These functional groups and enzymes act as efficient reductants to convert metal ions into metal atoms and alternatively metal atoms combine to form MNPs while long hydrocarbon chains present in these bio-macromolecules act as cage to stabilize them for prolong time. Effect of nature of source extract, different reaction conditions such as extract amount, salt amount and solvent used during MNPs preparation process have been critically discussed here in detail. Use of synthesized bioinorganic NPs in various areas including their effectiveness in fighting against bacteria, viruses, fungi, cancer, inflammation, and their potential role in catalytic reduction of environmental harmful substances into friendly products has also been described in a clear and concise manner along with their future consideration.
{"title":"Bioinorganic metal nanoparticles and their potential applications as antimicrobial, antioxidant and catalytic agents: a review","authors":"Khalida Naseem, Asad Aziz, Mohammad Ehtisham Khan, Shahzaib Ali, Awais Khalid","doi":"10.1515/revic-2023-0040","DOIUrl":"https://doi.org/10.1515/revic-2023-0040","url":null,"abstract":"This review article covers the biogenic synthesis of metal nanoparticles (MNPs) having definite shape and size while using extract obtained from different biological sources such as bacteria, fungi, algae and plants. These biological materials are composed of chloroplast, thylakoid, different types of enzymes extracted from different biogenic sources, different phytochemicals such as phenols, flavonoids, and citric acid having functional groups such as sulfate, carboxyl, amino, amide and hydroxyl groups. These functional groups and enzymes act as efficient reductants to convert metal ions into metal atoms and alternatively metal atoms combine to form MNPs while long hydrocarbon chains present in these bio-macromolecules act as cage to stabilize them for prolong time. Effect of nature of source extract, different reaction conditions such as extract amount, salt amount and solvent used during MNPs preparation process have been critically discussed here in detail. Use of synthesized bioinorganic NPs in various areas including their effectiveness in fighting against bacteria, viruses, fungi, cancer, inflammation, and their potential role in catalytic reduction of environmental harmful substances into friendly products has also been described in a clear and concise manner along with their future consideration.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"37 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140585007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cisplatin coined a term Metallodrug and later a tradition of Metallodrugs was established. Later, severe renal and metabolic toxicities of the platinum based drugs prompted the medicinal chemists to develop new and novel metallotherapeutics with different metal cores. Henceforth, chemists designed the metal complexes based on copper, cobalt, vanadium iron and zinc. These complexes were reported for their antibacterial, anticancer, antidiabetic and enzyme inhibitors. Later, chemists also focused on lanthanide metal ions and resulted in the design of metal complexes for the application of bio imaging cellular studies as well as chemotherapeutic agents. This review throws a light on the recent advances in the development of the samarium complexes as efficient and versatile biological agents. Samarium complexes based on various ligand systems and ancillary ligands have been mentioned in this review stating their biological efficacy and potency against variable cancer cell lines, their DNA interactive behaviour.
顺铂（Cisplatin）创造了 "金属药物"（Metallodrug）这一术语，随后金属药物的传统便建立起来。后来，铂类药物严重的肾毒性和代谢毒性促使药物化学家们开发出具有不同金属内核的新型金属治疗药物。因此，化学家们设计出了基于铜、钴、钒铁和锌的金属复合物。据报道，这些配合物具有抗菌、抗癌、抗糖尿病和酶抑制作用。后来，化学家们又把目光投向了镧系金属离子，并设计出了用于生物成像细胞研究和化疗药物的金属复合物。本综述介绍了钐配合物作为高效、多用途生物制剂的最新进展。本综述提到了基于各种配体系统和辅助配体的钐配合物，并说明了它们对不同癌细胞系的生物功效和效力，以及它们的 DNA 交互作用行为。
{"title":"Applications of samarium complexes as cytotoxic, bioimaging and DNA interacting agents: a comprehensive review","authors":"Poonam R. Inamdar, Shashikant Bhandari, Mrunalini Kulkarni, Neeta Rai, Anuja Kolsure","doi":"10.1515/revic-2023-0026","DOIUrl":"https://doi.org/10.1515/revic-2023-0026","url":null,"abstract":"Cisplatin coined a term Metallodrug and later a tradition of Metallodrugs was established. Later, severe renal and metabolic toxicities of the platinum based drugs prompted the medicinal chemists to develop new and novel metallotherapeutics with different metal cores. Henceforth, chemists designed the metal complexes based on copper, cobalt, vanadium iron and zinc. These complexes were reported for their antibacterial, anticancer, antidiabetic and enzyme inhibitors. Later, chemists also focused on lanthanide metal ions and resulted in the design of metal complexes for the application of bio imaging cellular studies as well as chemotherapeutic agents. This review throws a light on the recent advances in the development of the samarium complexes as efficient and versatile biological agents. Samarium complexes based on various ligand systems and ancillary ligands have been mentioned in this review stating their biological efficacy and potency against variable cancer cell lines, their DNA interactive behaviour.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"14 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140074978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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