Satyajit M. Deshmukh, Sonali R. Dhokpande, Amaya Sankhe, Ajinkya Khandekar
The textile industry contributes significantly to the expansion of the world economy, however, it is also notorious for producing large amounts of trash and harming the environment. Effective waste management techniques depend on having a thorough understanding of the forms and makeup of waste from the textile sector. The objective of this paper is to study effluent wastewater technologies to efficiently treat and control the wastewater produced during textile production operations. It is well known that the textile industry generates vast amounts of wastewater, some of which may be contaminated with heavy metals, chemicals, dyes, and organic compounds. This effluent can have serious negative effects on the environment if it is not adequately treated, including contaminating soil and water sources, removing aquatic life, and possibly endangering human health. Due to the inclusion of dyes, heavy metals, and other chemicals, the discharge of untreated or improperly treated effluent from textile processes leads to water contamination. Textile waste can leak hazardous compounds into the environment and contaminate the soil, both of which have an impact on air quality. The environmental impact of the textile industry is further exacerbated by the energy and resource use involved in production. At several points in the textile supply chain, waste is generated. Fibre trimmings, fly waste, and yarn waste are produced during the fibre production, spinning, and weaving operations. There are numerous ways and technologies for treating wastewater, including advanced oxidation processes (AOPs), biological treatment systems, and membrane-based technologies. The formation of eco-friendly materials and advancements in recycling technology help to make the textile industry more closed-loop and sustainable. In conclusion, managing waste from the textile sector is a significant environmental concern that calls for creative solutions and environmentally friendly procedures.
{"title":"Effluent wastewater technologies for textile industry: a review","authors":"Satyajit M. Deshmukh, Sonali R. Dhokpande, Amaya Sankhe, Ajinkya Khandekar","doi":"10.1515/revic-2024-0046","DOIUrl":"https://doi.org/10.1515/revic-2024-0046","url":null,"abstract":"The textile industry contributes significantly to the expansion of the world economy, however, it is also notorious for producing large amounts of trash and harming the environment. Effective waste management techniques depend on having a thorough understanding of the forms and makeup of waste from the textile sector. The objective of this paper is to study effluent wastewater technologies to efficiently treat and control the wastewater produced during textile production operations. It is well known that the textile industry generates vast amounts of wastewater, some of which may be contaminated with heavy metals, chemicals, dyes, and organic compounds. This effluent can have serious negative effects on the environment if it is not adequately treated, including contaminating soil and water sources, removing aquatic life, and possibly endangering human health. Due to the inclusion of dyes, heavy metals, and other chemicals, the discharge of untreated or improperly treated effluent from textile processes leads to water contamination. Textile waste can leak hazardous compounds into the environment and contaminate the soil, both of which have an impact on air quality. The environmental impact of the textile industry is further exacerbated by the energy and resource use involved in production. At several points in the textile supply chain, waste is generated. Fibre trimmings, fly waste, and yarn waste are produced during the fibre production, spinning, and weaving operations. There are numerous ways and technologies for treating wastewater, including advanced oxidation processes (AOPs), biological treatment systems, and membrane-based technologies. The formation of eco-friendly materials and advancements in recycling technology help to make the textile industry more closed-loop and sustainable. In conclusion, managing waste from the textile sector is a significant environmental concern that calls for creative solutions and environmentally friendly procedures.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"28 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Organometallics are chemical compounds that consist of carbon-metal linkages. They have emerged as a result of the combination of organic and inorganic chemistry and exhibit a stable metal-carbon bond in solution. These compounds possess properties that lie between those of ionic and covalent bonds, making them highly significant in various industries. The fact that organometallics are present in all living organisms further emphasises their importance. In this overview, we will explore general reactions, such as substitution and insertion reactions, as well as different techniques for creating organometallic complexes. Additionally, we will provide a brief synthesis review of various types of organometallic complexes, including carbonyls, hydrides, alkyls, carbenes, and carbines. Organometallic compounds find extensive applications in stoichiometric chemical processes in both research and industry. Moreover, they serve as catalysts to enhance these reactions, making them more than just theoretical compounds. For example, organotin compounds are widely used as fire retardants, polymers, medications, insecticides, and stabilizers for polyvinyl chloride.
{"title":"Organometallic complexes and reaction methods for synthesis: a review","authors":"Kwestan Namiq Aziz, Karzan Mahmood Ahmed, Rebaz Anwar Omer, Aryan Fathulla Qader, Eman Ibraheem Abdulkareem","doi":"10.1515/revic-2024-0037","DOIUrl":"https://doi.org/10.1515/revic-2024-0037","url":null,"abstract":"Organometallics are chemical compounds that consist of carbon-metal linkages. They have emerged as a result of the combination of organic and inorganic chemistry and exhibit a stable metal-carbon bond in solution. These compounds possess properties that lie between those of ionic and covalent bonds, making them highly significant in various industries. The fact that organometallics are present in all living organisms further emphasises their importance. In this overview, we will explore general reactions, such as substitution and insertion reactions, as well as different techniques for creating organometallic complexes. Additionally, we will provide a brief synthesis review of various types of organometallic complexes, including carbonyls, hydrides, alkyls, carbenes, and carbines. Organometallic compounds find extensive applications in stoichiometric chemical processes in both research and industry. Moreover, they serve as catalysts to enhance these reactions, making them more than just theoretical compounds. For example, organotin compounds are widely used as fire retardants, polymers, medications, insecticides, and stabilizers for polyvinyl chloride.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"32 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141948066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Muhammad Sajid, Ghazala Iram, Aqsa Nawaz, Wajeeha Qayyum, Ahmad Farhan, Muhammad Azam Qamar, Haq Nawaz, Asma Shahid
Carbon is one of the most abundant minerals in the universe. The world’s energy needs are being unmet due to the exponential rise in population. Since its inception 20 years ago, carbon and its allotropes, including fullerenes, carbon nanotubes, and graphene, have been marketed as potential energy storage and generation materials. By solving important issues like accumulation and inadequate thermodynamic compatibility, carbon fiber, expanded graphite, and carbon nanotubes are promising functional materials that can be used to improve the performance of bipolar plates further. There are several potential uses for carbon-based nanomaterials (CBNMs) in the energy area. This mini-review provides an overview of the synthetic routes employed for producing CBNMs, categorizing them based on their types, elucidating their diverse applications in fuel energy systems, and emphasising the uses of CBNMs in energy. The advantages and disadvantages of several synthetic processes have been examined and compared. The types of CBNMs, like carbon nanotubes, graphene, carbon dots, and fullerenes, are explored in terms of their unique structural properties and fabrication methods. Furthermore, the utilization of CBNMs in fuel energy systems, such as fuel cells, energy storage devices, and catalysis, is comprehensively reviewed.
{"title":"Carbon-based nanomaterials: synthesis, types and fuel applications: a mini-review","authors":"Muhammad Sajid, Ghazala Iram, Aqsa Nawaz, Wajeeha Qayyum, Ahmad Farhan, Muhammad Azam Qamar, Haq Nawaz, Asma Shahid","doi":"10.1515/revic-2024-0017","DOIUrl":"https://doi.org/10.1515/revic-2024-0017","url":null,"abstract":"Carbon is one of the most abundant minerals in the universe. The world’s energy needs are being unmet due to the exponential rise in population. Since its inception 20 years ago, carbon and its allotropes, including fullerenes, carbon nanotubes, and graphene, have been marketed as potential energy storage and generation materials. By solving important issues like accumulation and inadequate thermodynamic compatibility, carbon fiber, expanded graphite, and carbon nanotubes are promising functional materials that can be used to improve the performance of bipolar plates further. There are several potential uses for carbon-based nanomaterials (CBNMs) in the energy area. This mini-review provides an overview of the synthetic routes employed for producing CBNMs, categorizing them based on their types, elucidating their diverse applications in fuel energy systems, and emphasising the uses of CBNMs in energy. The advantages and disadvantages of several synthetic processes have been examined and compared. The types of CBNMs, like carbon nanotubes, graphene, carbon dots, and fullerenes, are explored in terms of their unique structural properties and fabrication methods. Furthermore, the utilization of CBNMs in fuel energy systems, such as fuel cells, energy storage devices, and catalysis, is comprehensively reviewed.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"69 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Saleh M. Bufarwa, Reem M. El-Sefait, Dalal K. Thbayh, Mustapha Belaidi, Rehab K. Al-Shemary, Rema. M. Abdusamea, Marei M. El-Ajaily, Béla Fiser, Hanan A. Bader, Abdulsalam A. Saleh, Mohamad M. Bufarwa
Enticed by the present scenario of infectious diseases, four new Co(II), Ni(II), Cu(II), and Cd(II) complexes of Schiff base ligand were synthesized from 6,6′-((1E-1′E)(phenazine-2,3-dielbis(azanylidene)-bis-(methanylidene)-bis-(3-(diethylamino)phenol)) (H 2 L) to ascertain as effective drug for antituberculosis, anti-inflammatory, antioxidant, cytotoxic and antimicrobial activities. The organic ligand and its metal(II) complexes were characterized by numerous physical and spectroscopic methods, which showed that the complexes have a general formula, [ML], (where M = Co(II) (C1), Ni(II) (C2), Cu(II) (C3) and Cd(II) (C4)), for metal complexes have been proposed and have a square planar geometry, are amorphous in nature, and are thermally stable. Data highlight obtained from activity testing against tuberculosis, inflammation, and oxidants that all compounds are significantly active against these symptoms. Also, was to evaluate the effectiveness of various compounds against bacterial and fungal strains. Specifically, four bacterial strains (Bacillus subtilis, Staphylococcus aureus, Escherichia coli, and Pseudomonas aeruginosa) and two fungal strains (Aspergillus flavus and Candida albicans) were tested and compared to the results of some standard drugs. The results revealed that compound C4 was more effective against bacterial strains than the comparison standard drugs. In addition, C3 was found to be the most effective of the comparison antibiotics against fungi, while the other compounds showed moderate antifungal activity. Moreover, to support the vitro results, certain computational studies as molecular docking studies, DFT, MESP, and AMEDT were also conducted to confirm the effectiveness of an organic ligand and its complexes against tuberculosis. These studies revealed that C4 is the most effective against tuberculosis and has desirable effects such as absorption, no degradation and no hepatotoxicity, etc.
{"title":"Antituberculosis, antimicrobial, antioxidant, cytotoxicity and anti-inflammatory activity of Schiff base derived from 2,3-diaminophenazine moiety and its metal(II) complexes: structural elucidation, computational aspects, and biological evaluation","authors":"Saleh M. Bufarwa, Reem M. El-Sefait, Dalal K. Thbayh, Mustapha Belaidi, Rehab K. Al-Shemary, Rema. M. Abdusamea, Marei M. El-Ajaily, Béla Fiser, Hanan A. Bader, Abdulsalam A. Saleh, Mohamad M. Bufarwa","doi":"10.1515/revic-2024-0007","DOIUrl":"https://doi.org/10.1515/revic-2024-0007","url":null,"abstract":"Enticed by the present scenario of infectious diseases, four new Co(II), Ni(II), Cu(II), and Cd(II) complexes of Schiff base ligand were synthesized from 6,6′-((1E-1′E)(phenazine-2,3-dielbis(azanylidene)-bis-(methanylidene)-bis-(3-(diethylamino)phenol)) (H <jats:sub> 2 </jats:sub> L) to ascertain as effective drug for antituberculosis, anti-inflammatory, antioxidant, cytotoxic and antimicrobial activities. The organic ligand and its metal(II) complexes were characterized by numerous physical and spectroscopic methods, which showed that the complexes have a general formula, [ML], (where M = Co(II) (C1), Ni(II) (C2), Cu(II) (C3) and Cd(II) (C4)), for metal complexes have been proposed and have a square planar geometry, are amorphous in nature, and are thermally stable. Data highlight obtained from activity testing against tuberculosis, inflammation, and oxidants that all compounds are significantly active against these symptoms. Also, was to evaluate the effectiveness of various compounds against bacterial and fungal strains. Specifically, four bacterial strains (<jats:italic>Bacillus subtilis</jats:italic>, <jats:italic>Staphylococcus aureus</jats:italic>, <jats:italic>Escherichia coli</jats:italic>, and <jats:italic>Pseudomonas aeruginosa</jats:italic>) and two fungal strains (<jats:italic>Aspergillus flavus</jats:italic> and <jats:italic>Candida albicans</jats:italic>) were tested and compared to the results of some standard drugs. The results revealed that compound C4 was more effective against bacterial strains than the comparison standard drugs. In addition, C3 was found to be the most effective of the comparison antibiotics against fungi, while the other compounds showed moderate antifungal activity. Moreover, to support the vitro results, certain computational studies as molecular docking studies, DFT, MESP, and AMEDT were also conducted to confirm the effectiveness of an organic ligand and its complexes against tuberculosis. These studies revealed that C4 is the most effective against tuberculosis and has desirable effects such as absorption, no degradation and no hepatotoxicity, etc.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"11 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kashaf Ul Khair, Khalil Ahmad, Muhammad Kashif, Khalida Naseem, Khizar Qureshi, Hammad Majeed
Mercury pollution is disturbing, human health by causing many serious types of diseases. Therefore, elimination of mercury from water bodies is very important that is gaining attention among researchers, and researchers are setting priority measures to make mercury free water. One such measure is the use of MOFs and their composites which are extensively applied for the removal of Hg from water, because of displaying majestical characteristics like high water stability, tunable porosity and surface area as well as easy to synthesize. In this review, we discussed the elimination of Hg ions using MOFs and their composites. We also discussed how MOFs and their composites can be modified that can be more reliable and efficient for removal of pollutants from water particularly mercury ions. Furthermore, we explored the challenges in the application of MOFs and present measures to boost the application range of MOFs. In the same way we also discussed potential of MOFs and their composites to overcome difficulties and research directions for the elimination of Hg (II) ions from water bodies. We expect that this review will offer inclusive and clear understanding to researchers about MOFs and their composite for practical applications to remove mercury from water bodies.
{"title":"Mercury removal from water: insights from MOFs and their composites","authors":"Kashaf Ul Khair, Khalil Ahmad, Muhammad Kashif, Khalida Naseem, Khizar Qureshi, Hammad Majeed","doi":"10.1515/revic-2024-0056","DOIUrl":"https://doi.org/10.1515/revic-2024-0056","url":null,"abstract":"Mercury pollution is disturbing, human health by causing many serious types of diseases. Therefore, elimination of mercury from water bodies is very important that is gaining attention among researchers, and researchers are setting priority measures to make mercury free water. One such measure is the use of MOFs and their composites which are extensively applied for the removal of Hg from water, because of displaying majestical characteristics like high water stability, tunable porosity and surface area as well as easy to synthesize. In this review, we discussed the elimination of Hg ions using MOFs and their composites. We also discussed how MOFs and their composites can be modified that can be more reliable and efficient for removal of pollutants from water particularly mercury ions. Furthermore, we explored the challenges in the application of MOFs and present measures to boost the application range of MOFs. In the same way we also discussed potential of MOFs and their composites to overcome difficulties and research directions for the elimination of Hg (II) ions from water bodies. We expect that this review will offer inclusive and clear understanding to researchers about MOFs and their composite for practical applications to remove mercury from water bodies.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"2019 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Muhammad Naeem Ayub, Muhammad Fazle Rabbee, Umer Shahzad, Mohsin Saeed, Saad M. Al-Baqami, Khalid A. Alzahrani, Md. Reazuddin Repon, Md. Rezaur Rahman, Mohammad Mizanur Rahman Khan, Mohammed M. Rahman
Today world is looking for a cheap, environment friendly and efficient substitute of fossil fuel. Because due to large consumption of the fossil fuels on daily basis in whole world, emission of hazardous gases have produced lethal effects on human being. In this scenario hydrogen energy has emerged in form of clean, renewable and more efficient energy. Now the key challenge is that efficient production of the green hydrogen at commercial scale to meet demand of hydrogen. The electrolysis of water is the best pathway to achieve efficient hydrogen production. For this purpose the synthesis and improvement of low cast, active as well as stable catalysts or electrolysis is prerequisite for hydrogen production by electro-catalytic method for splitting of water. Main focus of this review is that, how we can perform the electrolysis of water by various techniques using novel methods especially electro-catalysts in term of activity, efficiency, large surface area, porosity, and stability. This will be performed by the method of two-half cell reaction one is the Hydrogen Evolution Reaction (HER) other one Oxygen Evolution Reaction (OER), where reaction proceeded in both medium acidic as well as alkaline phases. Particular attention is given to produce green clean hydrogen production from usable water and its physical and chemical storages for further uses for the support of human sustainability. Basically the recent strategy is to prepare, design and development of nanoscale materials/composite with non-noble metals and with also nanostructured with noble-metals will be discussed in this approach. The increased efficiency and utility have been the focal points of the use of diverse materials from different classes. To increase the electro-catalytic efficiency in OER and HER, we will discuss about new analyses methods and insights into studying the chemical compositions, shapes, surface area, porosity, and synergy of catalysts and the active sites of nanostructured electro-catalysts. This review will further provide the picture of current state of developments as well as recent progress for mechanized efficient production of clean hydrogen (i.e., HER) from water by electrocatalytic method using various nanoscale materials in a broad scale.
当今世界正在寻找一种廉价、环保和高效的化石燃料替代品。由于全世界每天都要消耗大量的化石燃料，有害气体的排放对人类造成了致命的影响。在这种情况下，氢能以清洁、可再生和更高效的能源形式出现了。现在的关键挑战是如何以商业规模高效生产绿色氢气，以满足氢气需求。电解水是实现高效制氢的最佳途径。为此，合成和改良低铸造、活性和稳定的催化剂或电解催化剂是利用电催化方法分水制氢的先决条件。本综述的重点是，我们如何利用新方法，特别是在活性、效率、大表面积、多孔性和稳定性方面的电催化剂，通过各种技术进行水的电解。这将通过两个半电池反应的方法来实现，一个是氢进化反应（HER），另一个是氧进化反应（OER），反应同时在酸性和碱性介质中进行。从可用水中生产绿色清洁氢气，并对其进行物理和化学储存，以进一步用于支持人类的可持续发展，这一点受到了特别关注。近期的基本策略是制备、设计和开发纳米级材料/与非贵金属的复合材料，并在此方法中讨论与贵金属的纳米结构。提高效率和实用性一直是使用不同种类材料的焦点。为了提高 OER 和 HER 的电催化效率，我们将讨论研究催化剂的化学成分、形状、表面积、孔隙率和协同作用以及纳米结构电催化剂活性位点的新分析方法和见解。本综述将进一步介绍利用各种纳米材料通过电催化方法从水中机械化高效生产清洁氢气（即 HER）的发展现状和最新进展。
{"title":"Recent advances on hydrogen generation based on inorganic metal oxide nano-catalyst using water electrolysis approach","authors":"Muhammad Naeem Ayub, Muhammad Fazle Rabbee, Umer Shahzad, Mohsin Saeed, Saad M. Al-Baqami, Khalid A. Alzahrani, Md. Reazuddin Repon, Md. Rezaur Rahman, Mohammad Mizanur Rahman Khan, Mohammed M. Rahman","doi":"10.1515/revic-2024-0026","DOIUrl":"https://doi.org/10.1515/revic-2024-0026","url":null,"abstract":"Today world is looking for a cheap, environment friendly and efficient substitute of fossil fuel. Because due to large consumption of the fossil fuels on daily basis in whole world, emission of hazardous gases have produced lethal effects on human being. In this scenario hydrogen energy has emerged in form of clean, renewable and more efficient energy. Now the key challenge is that efficient production of the green hydrogen at commercial scale to meet demand of hydrogen. The electrolysis of water is the best pathway to achieve efficient hydrogen production. For this purpose the synthesis and improvement of low cast, active as well as stable catalysts or electrolysis is prerequisite for hydrogen production by electro-catalytic method for splitting of water. Main focus of this review is that, how we can perform the electrolysis of water by various techniques using novel methods especially electro-catalysts in term of activity, efficiency, large surface area, porosity, and stability. This will be performed by the method of two-half cell reaction one is the Hydrogen Evolution Reaction (HER) other one Oxygen Evolution Reaction (OER), where reaction proceeded in both medium acidic as well as alkaline phases. Particular attention is given to produce green clean hydrogen production from usable water and its physical and chemical storages for further uses for the support of human sustainability. Basically the recent strategy is to prepare, design and development of nanoscale materials/composite with non-noble metals and with also nanostructured with noble-metals will be discussed in this approach. The increased efficiency and utility have been the focal points of the use of diverse materials from different classes. To increase the electro-catalytic efficiency in OER and HER, we will discuss about new analyses methods and insights into studying the chemical compositions, shapes, surface area, porosity, and synergy of catalysts and the active sites of nanostructured electro-catalysts. This review will further provide the picture of current state of developments as well as recent progress for mechanized efficient production of clean hydrogen (i.e., HER) from water by electrocatalytic method using various nanoscale materials in a broad scale.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"36 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141738157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A great deal of attention has been pressed to the hazards caused by the remains of antibiotics in the environment. Fluorescent sensing materials are favored for their rapid qualitative and quantitative detection of antibiotics, with carbon quantum dots (CQDs) being widely used as typical fluorescent materials. CQDs have demonstrated superior performances in conducting antibiotic diagnosis, which makes them a key tool for tackling antibiotic residues. This review article investigates recent advances in CQDs for the assessment and determination of antibiotics residues, involved antibiotic assay components are classified according to the assay mechanism as Static quenching effect (SQE), Dynamic quenching effect (DQE), Internal filtering effect (IFE), and Förster resonance energy transfer (FRET) quenching mechanisms. We hope to provide valuable guidelines for the preparation of high-quality probes as well as limited detection of antibiotics, so as to promote the advancement of CQDs in the antimicrobial field.
{"title":"Recent advances in carbon quantum dots for antibiotics detection","authors":"Guojun Ding, Fanyong Yan, Shangpeng Yang, Yang Fu","doi":"10.1515/revic-2024-0025","DOIUrl":"https://doi.org/10.1515/revic-2024-0025","url":null,"abstract":"A great deal of attention has been pressed to the hazards caused by the remains of antibiotics in the environment. Fluorescent sensing materials are favored for their rapid qualitative and quantitative detection of antibiotics, with carbon quantum dots (CQDs) being widely used as typical fluorescent materials. CQDs have demonstrated superior performances in conducting antibiotic diagnosis, which makes them a key tool for tackling antibiotic residues. This review article investigates recent advances in CQDs for the assessment and determination of antibiotics residues, involved antibiotic assay components are classified according to the assay mechanism as Static quenching effect (SQE), Dynamic quenching effect (DQE), Internal filtering effect (IFE), and Förster resonance energy transfer (FRET) quenching mechanisms. We hope to provide valuable guidelines for the preparation of high-quality probes as well as limited detection of antibiotics, so as to promote the advancement of CQDs in the antimicrobial field.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"122 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sonali R. Dhokpande, Satyajit M. Deshmukh, Ajinkya R. Khandekar, Amaya A. Sankhe
Carbon-based adsorbents like graphene and its derivatives, carbon nanotubes, activated carbon, and biochar are commonly used for removing heavy metals from water solutions. The changeable exterior functional groups of efficient carbon adsorbents for HMs are one of their key features. Detailed documentation of the synthesis and interactions of functionalized carbon adsorbents with metals in an aqueous solution is crucial for advancing the utilization of these materials in HM exclusion. This paper reviews the carbon-based adsorbent for material removal. It examines several carbon adsorbents’ exterior functional groups to better understand how they eliminate HMs from aqueous solutions. First, the controlling mechanisms for the deletion of aqueous HMs by carbon adsorbents are described, with a particular emphasis on the functions of exterior functional groups. The following section lists and organises the numerous synthetic techniques that are frequently employed to add heteroatoms to carbon surfaces, particularly oxygen, nitrogen, and sulphur, to increase their exterior properties and their sorptive capabilities towards HMs in aqueous solutions. Following that, the impact of dissimilar functional groups on the adsorption characteristics of HMs on carbon adsorbents is examined. While the adsorption capacity and metal removal efficiency of the changed carbonaceous materials are high, the alteration operation is complicated, particularly chemical modification. This review analyses the shortcomings that are now present and offers ideas for future research while emphasising the removal of inorganic and organic components utilising carbon-based materials as adsorbents. In summary, there is room for additional study on the efficacy of functional carbon adsorbents for the removal of heavy metals and their potential uses in various fields. This includes the development of new materials and techniques to enhance adsorption efficiency and selectivity for specific heavy metals, along with the investigation of additional functionalities for these carbon adsorbents in various industrial processes. There is a need for continued innovation and collaboration in this field to address the growing concerns regarding heavy metal pollution and to explore the full capabilities of functional carbon adsorbents.
石墨烯及其衍生物、碳纳米管、活性炭和生物炭等碳基吸附剂常用于去除水溶液中的重金属。吸附重金属的高效碳吸附剂可改变外部官能团是其主要特点之一。详细记录功能化碳吸附剂的合成及其与水溶液中金属的相互作用，对于推动利用这些材料排除 HM 至关重要。本文回顾了用于去除材料的碳基吸附剂。它研究了几种碳吸附剂的外部官能团，以更好地了解它们是如何从水溶液中去除 HM 的。首先，介绍了碳吸附剂去除水溶液中 HMs 的控制机制，并特别强调了外部官能团的功能。下一节列出并整理了大量常用的合成技术，这些技术可在碳表面添加杂原子，特别是氧、氮和硫，以增加碳的外部特性及其对水溶液中 HMs 的吸附能力。随后，我们研究了不同官能团对碳吸附剂上 HMs 吸附特性的影响。虽然改变后的碳质材料具有较高的吸附能力和金属去除效率，但改变操作复杂，尤其是化学改性。本综述分析了目前存在的不足，并为今后的研究提供了思路，同时强调了利用碳基材料作为吸附剂去除无机和有机成分。总之，对于功能性碳吸附剂去除重金属的功效及其在各个领域的潜在用途，还有进一步研究的空间。这包括开发新材料和新技术，以提高对特定重金属的吸附效率和选择性，以及研究这些碳吸附剂在各种工业流程中的其他功能。该领域需要不断创新和合作，以解决人们日益关注的重金属污染问题，并探索功能性碳吸附剂的全部功能。
{"title":"A review of carbon-based adsorbents for the removal of organic and inorganic components","authors":"Sonali R. Dhokpande, Satyajit M. Deshmukh, Ajinkya R. Khandekar, Amaya A. Sankhe","doi":"10.1515/revic-2024-0027","DOIUrl":"https://doi.org/10.1515/revic-2024-0027","url":null,"abstract":"Carbon-based adsorbents like graphene and its derivatives, carbon nanotubes, activated carbon, and biochar are commonly used for removing heavy metals from water solutions. The changeable exterior functional groups of efficient carbon adsorbents for HMs are one of their key features. Detailed documentation of the synthesis and interactions of functionalized carbon adsorbents with metals in an aqueous solution is crucial for advancing the utilization of these materials in HM exclusion. This paper reviews the carbon-based adsorbent for material removal. It examines several carbon adsorbents’ exterior functional groups to better understand how they eliminate HMs from aqueous solutions. First, the controlling mechanisms for the deletion of aqueous HMs by carbon adsorbents are described, with a particular emphasis on the functions of exterior functional groups. The following section lists and organises the numerous synthetic techniques that are frequently employed to add heteroatoms to carbon surfaces, particularly oxygen, nitrogen, and sulphur, to increase their exterior properties and their sorptive capabilities towards HMs in aqueous solutions. Following that, the impact of dissimilar functional groups on the adsorption characteristics of HMs on carbon adsorbents is examined. While the adsorption capacity and metal removal efficiency of the changed carbonaceous materials are high, the alteration operation is complicated, particularly chemical modification. This review analyses the shortcomings that are now present and offers ideas for future research while emphasising the removal of inorganic and organic components utilising carbon-based materials as adsorbents. In summary, there is room for additional study on the efficacy of functional carbon adsorbents for the removal of heavy metals and their potential uses in various fields. This includes the development of new materials and techniques to enhance adsorption efficiency and selectivity for specific heavy metals, along with the investigation of additional functionalities for these carbon adsorbents in various industrial processes. There is a need for continued innovation and collaboration in this field to address the growing concerns regarding heavy metal pollution and to explore the full capabilities of functional carbon adsorbents.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"97 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abdelkarim Chaouiki, Siti Fatimah, Hamid Ahchouch, Mohamed Bakhouch, Maryam Chafiq, Jungho Ryu, Young Gun Ko
Metal-organic frameworks (MOFs) represent a fusion of compelling porous structures, alluring physical and chemical attributes, and extensive possibilities for application. The inherent capability of employing these organic constituents has paved the path for the construction of MOFs, permitting imaginative pre-design and post-synthetic adjustments through apt reactions. This adaptability not only enriches the structural variety of MOFs but also uncovers pathways for customizing their characteristics to align with precise application needs. In this context, click chemistry has emerged as a potent and resilient tool in the creation and modification of diverse functional materials, with a promising application in MOF structures. These MOF architectures undergo postsynthetic modifications through the application of “click” chemistry. This approach, characterized by its efficiency and selectivity, proves instrumental in tailoring and enhancing the properties of MOFs, thereby expanding their utility across a spectrum of scientific and industrial applications. Herein, we illuminate recent MOF structures achieved through the postsynthetic application of “click” chemistry. Our exploration delves into the forefront of strategies propelling the postsynthetic modification process, with a dedicated focus on the structural complexities, synthesis methodologies, and the prospective applications of these modified MOF architectures. Our intention is to actively contribute to the continuous discourse on applications of click chemistry in the development of MOF architectures, encouraging scientists to dedicate their expertise and efforts towards the advancement of these multifunctional materials.
{"title":"Transformative applications of “click” chemistry in the development of MOF architectures − a mini review","authors":"Abdelkarim Chaouiki, Siti Fatimah, Hamid Ahchouch, Mohamed Bakhouch, Maryam Chafiq, Jungho Ryu, Young Gun Ko","doi":"10.1515/revic-2023-0037","DOIUrl":"https://doi.org/10.1515/revic-2023-0037","url":null,"abstract":"Metal-organic frameworks (MOFs) represent a fusion of compelling porous structures, alluring physical and chemical attributes, and extensive possibilities for application. The inherent capability of employing these organic constituents has paved the path for the construction of MOFs, permitting imaginative pre-design and post-synthetic adjustments through apt reactions. This adaptability not only enriches the structural variety of MOFs but also uncovers pathways for customizing their characteristics to align with precise application needs. In this context, click chemistry has emerged as a potent and resilient tool in the creation and modification of diverse functional materials, with a promising application in MOF structures. These MOF architectures undergo postsynthetic modifications through the application of “click” chemistry. This approach, characterized by its efficiency and selectivity, proves instrumental in tailoring and enhancing the properties of MOFs, thereby expanding their utility across a spectrum of scientific and industrial applications. Herein, we illuminate recent MOF structures achieved through the postsynthetic application of “click” chemistry. Our exploration delves into the forefront of strategies propelling the postsynthetic modification process, with a dedicated focus on the structural complexities, synthesis methodologies, and the prospective applications of these modified MOF architectures. Our intention is to actively contribute to the continuous discourse on applications of click chemistry in the development of MOF architectures, encouraging scientists to dedicate their expertise and efforts towards the advancement of these multifunctional materials.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"14 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141521265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohsin Saeed, Umer Shahzad, Muhammad Fazle Rabbee, Jehan Y. Al-Humaidi, Hadi M. Marwani, Shujah Ur Rehman, Anam Shabbir, Muhammad Naeem Ayub, Raed H. Althomali, Muhammad Nadeem Asghar, Mohammed M. Rahman
The versatile nature of metal sulfide nanostructures has led to their meteoric rise in popularity. The compositions, morphologies, and sizes of these nanostructures may be tuned, giving them distinct features. Here we look at the many uses of metal sulfide nanostructures, with an emphasis on their possible benefits in the fields of biology, ecology, and energy storage. Because of their remarkable optical characteristics and high degree of biocompatibility, metal sulfide nanostructures have great potential in the biological fields of bioimaging, medication administration, and photothermal treatment. Additionally, because of their large surface area and adsorption capability, these nanostructures show outstanding performance in environmental remediation, which includes pollutant removal and wastewater treatment. Because of their great conductivity and electrochemical activity, metal sulfide nanostructures are also in great demand for energy storage applications such supercapacitors, hydrogen storage, and lithium-ion batteries. This review provides a comprehensive analysis of recent progress in synthesizing various metal sulfides with transition metal elements. Effective physiochemical and biological approaches are employed in their production to control the structures, dimensions, and compositions of these sulfides.
{"title":"Comprehensive reviews on the potential applications of inorganic metal sulfide nanostructures in biological, environmental, healthcare, and energy generation and storage","authors":"Mohsin Saeed, Umer Shahzad, Muhammad Fazle Rabbee, Jehan Y. Al-Humaidi, Hadi M. Marwani, Shujah Ur Rehman, Anam Shabbir, Muhammad Naeem Ayub, Raed H. Althomali, Muhammad Nadeem Asghar, Mohammed M. Rahman","doi":"10.1515/revic-2024-0016","DOIUrl":"https://doi.org/10.1515/revic-2024-0016","url":null,"abstract":"The versatile nature of metal sulfide nanostructures has led to their meteoric rise in popularity. The compositions, morphologies, and sizes of these nanostructures may be tuned, giving them distinct features. Here we look at the many uses of metal sulfide nanostructures, with an emphasis on their possible benefits in the fields of biology, ecology, and energy storage. Because of their remarkable optical characteristics and high degree of biocompatibility, metal sulfide nanostructures have great potential in the biological fields of bioimaging, medication administration, and photothermal treatment. Additionally, because of their large surface area and adsorption capability, these nanostructures show outstanding performance in environmental remediation, which includes pollutant removal and wastewater treatment. Because of their great conductivity and electrochemical activity, metal sulfide nanostructures are also in great demand for energy storage applications such supercapacitors, hydrogen storage, and lithium-ion batteries. This review provides a comprehensive analysis of recent progress in synthesizing various metal sulfides with transition metal elements. Effective physiochemical and biological approaches are employed in their production to control the structures, dimensions, and compositions of these sulfides.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"33 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141190289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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