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Development of lab-scale gasification systems for different possible applications 为各种可能的应用开发实验室规模的气化系统
Pub Date : 2023-11-27 DOI: 10.14232/analecta.2023.4.25-33
Emese Sebe, Gábor Nagy, A. Kállay
The goal of gasification is the conversion of solid fuels or carbonaceous wastes to gas that can be further used energetically or for chemically utilisation. Due to cost-effectiveness and gaining experience, the industrial application of new systems and raw materials or mixtures must be preceded by laboratory-scale experiments. The manuscript presents the laboratory scale gasification systems we designed and used, as well as the difficulties experienced during the implementation (e.g. water introduction, sealing, etc.). In addition to these, the results of one-, two- and three-stage experiments are presented as examples, where different materials such as a mixture of wood and canteen waste, brown coal and refuse derived fuel (RDF) were used for testing the system.
气化的目标是将固体燃料或含碳废料转化为气体,并进一步用于能源或化学利用。出于成本效益和积累经验的考虑,新系统和原料或混合物的工业应用必须先进行实验室规模的实验。本手稿介绍了我们设计和使用的实验室规模气化系统,以及在实施过程中遇到的困难(如水引入、密封等)。此外,还以单级、二级和三级实验为例,介绍了不同材料(如木材和食堂垃圾混合物、褐煤和垃圾衍生燃料(RDF))的实验结果。
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引用次数: 0
Solid-phase extraction as promising sample preparation method for compound of emerging concerns analysis 固相萃取法是分析新关注化合物的理想样品制备方法
Pub Date : 2023-11-27 DOI: 10.14232/analecta.2023.4.16-24
Dušan Rakić, I. Antić, J. Živančev, Maja Buljovčić, Z. Šereš, N. Đurišić-Mladenović
Today’s environment is under the influence of numerous substances and most of them are not covered by current national and international regulations. Substances that are classified as contaminants of emerging concern, CECs, are not regulated nor systematically controlled in the environment, and they belong to the different chemical classes such as pesticides in current use, pharmaceutically active compounds (PhACs), personal care products, illicit drugs, hormones, micro- and nano-plastics, per- and poly-fluoroalkyl substances (PFAS), and many others. Once released CECs end up in surface water where they can be either accumulated or transported to the other environmental compartments, i.e. soil (by irrigation), underground water, or drinking water. The aim of the research was to investigate the efficiency of different selected solid-phase extraction (SPE) cartridges for preparation of water samples for simultaneous analysis of several CECs. For this purpose, a model mix solution of selected CECs in concentration relevant to environmental appearance was used. The selected CECs (14 PhACs, 11 pesticides in current use, and 4 PFAS) represented emerging contaminants with different properties, including polarities, and varying adverse effect on the environment and human health. Different types of sorbents were investigated: (i) commercial single-layer HLB, (ii) homemade multi-layer I: HLB plus a mix of WAX, WCX, and PPL, and (iii) multi-layer II: mix of WAX, WCX, and PPL plus HLB. The results revealed that the single-layer sorbent showed better efficiency in extraction of the analyzed CECs. Multi-layer sorbent should be further investigated to elucidate the possible reason for the poor extraction of some compounds, as development of a balanced extraction for a wider range of contaminants with different polarities, especially for non-target analysis of chemical residues, is required in order to capture the occurrence of the full profile of micropollutants.
当今的环境受到众多物质的影响,其中大多数物质都不在现行国家和国际法规的管辖范围之内。被归类为新关注污染物(CECs)的物质在环境中既不受监管,也不受系统控制,它们属于不同的化学类别,如目前使用的杀虫剂、药用活性化合物(PhACs)、个人护理产品、违禁药物、激素、微塑料和纳米塑料、全氟烷基和多氟烷基物质(PFAS)等。一旦释放出来,CECs 最终会进入地表水,在地表水中积累或迁移到其他环境区划,即土壤(通过灌溉)、地下水或饮用水。研究的目的是调查不同固相萃取(SPE)滤芯在制备水样以同时分析多种 CECs 时的效率。为此,使用了与环境外观浓度相关的选定 CECs 模型混合溶液。所选的 CECs(14 种 PhACs、11 种当前使用的农药和 4 种 PFAS)代表了新出现的污染物,它们具有不同的性质(包括极性),对环境和人类健康的不利影响也各不相同。研究了不同类型的吸附剂:(i) 商用单层 HLB;(ii) 自制多层 I:HLB 加 WAX、WCX 和 PPL 的混合物;(iii) 多层 II:WAX、WCX 和 PPL 加 HLB 的混合物。结果表明,单层吸附剂在萃取所分析的 CECs 方面表现出更高的效率。应进一步研究多层吸附剂,以阐明某些化合物萃取效果不佳的可能原因,因为需要开发一种平衡萃取法,以萃取更多不同极性的污染物,特别是用于化学残留物的非目标分析,从而捕捉微污染物的全貌。
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引用次数: 0
The mechanical properties of biodegradable modified polymer packaging 可生物降解改性聚合物包装的机械性能
Pub Date : 2023-11-27 DOI: 10.14232/analecta.2023.4.34-39
Pál Patrik Dézsi, Z. Heiner, Gábor Gulyás, Katalin Pappné Sziládi
In this research, a lactic acid-based biodegradable polymer (polylactic acid, PLA) was chemically modified and the mechanical material property changes were studied. The hardness and elastic modulus were determined with a nanoindentation instrument. The modified PLA was compared to the unmodified control group. Each group contained 5 different samples and t-test was performed to compare the mean difference of the hardness and elastic modulus between the two groups. A statistically significant result was obtained both in the hardness and elastic modulus due to the modification. The treated sample structure has become more inhomogeneous as well. The elastic modulus of the modified PLA reduced in its hardness and elastic modulus compared to the control PLA.
本研究对一种乳酸基生物降解聚合物(聚乳酸)进行了化学改性,并研究了其材料机械性能的变化。用纳米压痕仪测定了硬度和弹性模量。改性聚乳酸与未改性对照组进行了比较。每组包含 5 个不同的样品,通过 t 检验来比较两组之间硬度和弹性模量的平均差异。结果表明,改性聚丙烯在硬度和弹性模量方面都具有统计学意义。处理后的样品结构也变得更加不均匀。与对照组相比,改性聚乳酸的硬度和弹性模量都有所降低。
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引用次数: 0
Examination of the Composition and Dielectric Properties of Wines from the Csongrád Wine Region Csongrád葡萄酒产区葡萄酒成分和介电性能的研究
Pub Date : 2023-07-13 DOI: 10.14232/analecta.2023.3.33-40
Blanka Juhász, Z. Jákói, Balázs Lemmer
In Hungary, viticulture and winemaking have a very long tradition and culture. Nowadays, more and more consumers are paying attention to the nutritional properties of the food they consume, in addition to their enjoyment value. Wines can have an outstanding antioxidant content. The amount of antioxidants can be influenced by a number of parameters (wine-making technology, grape variety, area under vines, etc.). Antioxidants play an important role in the preservation of health, as well as inhibiting oxidation processes in food. Dielectric material analysis methods are also increasingly used in the food industry. The great advantages of dielectric testing include its chemical-free nature and the speed of the test. In our studies, we have investigated the food properties, i.e. alcohol, acid and antioxidant content and dielectric properties of different wine samples
在匈牙利,葡萄种植和酿酒有着悠久的传统和文化。如今,越来越多的消费者除了关注食物的享受价值外,还关注食物的营养特性。葡萄酒的抗氧化剂含量很高。抗氧化剂的含量会受到许多参数的影响(酿酒技术、葡萄品种、葡萄种植面积等)。抗氧化剂在保持健康和抑制食物氧化过程中起着重要作用。介质材料分析方法在食品工业中的应用也越来越广泛。电介质测试的巨大优点包括它的无化学性质和测试速度。在我们的研究中,我们研究了不同葡萄酒样品的食品性能,即酒精、酸和抗氧化剂含量以及介电性能
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引用次数: 0
Static and dynamic compression load tests of conically connected, screw fixed dental abutment 锥形连接螺钉固定牙基台静、动压缩载荷试验
Pub Date : 2023-07-13 DOI: 10.14232/analecta.2023.3.1-12
Győző Körtvélyessy, D. Hangyási, Tamás Tarjányi, Z. Tóth, Danica Matusovits, István Pelsőczi-Kovács, Z. Baráth
The basis of the long-term success of dental implants is the mechanical stability of the implant and the superstructure anchored in it. In order to investigate the mechanical behaviour of the conical connection in implant-abutment units, static and dynamic load tests were performed with different conical angles and various Grade 4-5 titanium implant materials. The assembled units were mounted in self-developed loading machine and in an Instron ElectroPuls E3000 fatigue machine. For static loading, the samples were loaded with a force from 0 N to 500 N in steps of 100 N. For dynamic loading, the samples were loaded for 30,000 cycles with a force of 250 ± 150 N. In case of static testing, the compression caused by the load was measured in both horizontal and vertical directions, while in the case of dynamic fatigue, only horizontal deformation was defined. In both cases, the drive-out (reverse) torque values of the fixing screws were determined after loading. No significant differences were found between the tested materials in the reverse torque after the static load, however, significant differences were shown with regards to the alterations in cone angle (p < 0.001). After dynamic loading, significant differences (p < 0.001) were also observed between the reverse torques of the fixing screw in different angles. The static and dynamic test results showed the same tendency: under the same load conditions, the conical angle value of the implant-abutment connection revealed significant differences in the loosening of the fixing screw. In summary, it is recommended to use higher conical angle connection to avoid larger deformations in lengths and diameters of the implant at the connection and essential torque reduction of the fixing screw. Our results may contribute to the understanding of the long-term success of dental implants.
牙种植体长期成功的基础是种植体的机械稳定性和锚定在其上的上层结构。为了研究种植体-基台单元中锥形连接的力学行为,采用不同的锥形角度和不同的4-5级钛种植体材料进行了静、动载荷试验。组装后的部件分别安装在自行研制的装载机和Instron ElectroPuls E3000疲劳机上。静态加载时,试样受0 - 500 N的力,按100 N的级数进行加载。动态加载时,试样受250±150 N的力,进行3万次循环加载。静态测试时,在水平和垂直方向上测量荷载引起的压缩,而在动态疲劳情况下,只定义水平变形。在这两种情况下,加载后确定固定螺钉的驱动(反向)扭矩值。静载荷后的反向扭矩在被测材料之间没有显著差异,但在锥角的变化方面显示出显著差异(p < 0.001)。动态加载后,不同角度固定螺钉的反向扭矩也有显著差异(p < 0.001)。静态和动态试验结果显示出相同的趋势:在相同的载荷条件下,种植体-基台连接的圆锥角值显示出固定螺钉松动的显著差异。综上所述,建议使用较大的圆锥角连接,以避免在连接处种植体的长度和直径发生较大的变形,并减少固定螺钉的扭矩。我们的结果可能有助于理解种植体的长期成功。
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引用次数: 0
Monitoring the process of yogurt spoilage by dielectric measurements and spread plate method 用介电测量法和铺板法监测酸奶变质过程
Pub Date : 2023-07-13 DOI: 10.14232/analecta.2023.3.41-47
Réka Dobozi
In my research work, I primarily focused on the investigation of yogurt (made from home-made raw milk) spoilage by microbiological and dielectric measurements. During the experiment, I continuously monitored the changes in aerobic and anaerobic Lactobacillus cell counts of the product, as a possible spoilage process would cause the deteriorative microbes to displace the lactic acid bacteria, and I also monitored the changes in the dielectric properties of the sample material at 400 MHz frequency. The research results verified that there is a strong correlation between the variation in live cell counts and dielectric parameters in both aerobically and anaerobically cultured lactic acid bacteria. The main conclusions of the results are that the change in the bacterial count, and thus the deterioration process leading to it, can be indirectly monitored in the dairy product under study by low-frequency determination of both the dielectric constant and the loss factor.
在我的研究工作中,我主要是通过微生物和电介质测量来研究酸奶(由自制的原料牛奶制成)的腐败。在实验过程中,我连续监测了产品的好氧和厌氧乳酸杆菌细胞计数的变化,因为可能的变质过程会导致变质微生物取代乳酸菌,我还监测了样品材料在400 MHz频率下介电性能的变化。研究结果证实了好氧和厌氧培养乳酸菌的活细胞计数变化与介电参数之间存在很强的相关性。研究结果的主要结论是,通过低频测量介电常数和损耗因子,可以间接监测所研究乳制品中细菌数量的变化以及导致细菌数量变化的变质过程。
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引用次数: 0
The existence of gluten-free and functional pasta in Hungary 无麸质功能性面食在匈牙利的存在
Pub Date : 2023-07-13 DOI: 10.14232/analecta.2023.3.13-18
Krisztián Szűcs
Nowadays, instead of traditional wheat grains, alternative cereals, also known as pseudocereals, are increasingly coming to the fore. The reason for this is, among other things, that more and more people struggle with food allergies and intolerances. Gluten-related disease - such as gluten sensitivity - is a chronic disease of the small intestine with malabsorption, which is triggered by gluten, a vegetable protein found in certain cereals, in people who are sensitive to it. Because of this, the demand for foods in which alternative gluten-free pseudocereals play a prominent role has understandably increased. Our research and development goal was aimed at getting to know and examining the different raw materials and their functional enrichment possibilities, which has led to the development of a new range of pasta products.
如今,替代传统小麦谷物的替代谷物,也被称为假谷物,越来越多地脱颖而出。原因之一是,越来越多的人与食物过敏和不耐受作斗争。麸质相关疾病,如麸质敏感性,是一种小肠吸收不良的慢性疾病,是由麸质引发的,麸质是一种植物蛋白,存在于某些谷物中,对麸质敏感的人群中。正因为如此,对替代无麸质假谷物发挥突出作用的食品的需求可以理解地增加了。我们的研发目标是了解和研究不同的原料及其功能丰富的可能性,从而开发出一系列新的面食产品。
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引用次数: 0
Elemental Analysis of Contaminated Biomass Ashes for Phytomining of Rare Earth Elements 污染生物质灰中稀土元素的元素分析
Pub Date : 2023-07-13 DOI: 10.14232/analecta.2023.3.26-32
Truong Dinh Phi, Zsolt Dobó, H. Kovács
Phytomining of rare earth elements (REEs) provides a potential possibility for metal recovery at brownfields where conventional mining technique is not reasonable or profitable. The holistic concept of phytomining is instituted from three scientific sectors. Phytoextraction is the first stage referred to accumulation of REEs in plants. This is followed by the enrichment process aiming to elevate metal concentration into solid remains. Eventually, extraction technology is applied to reclaim these valuable metals from the bio-ores. The main goal of this study is to identify a possible location for REEs phytomining, which lays the groundwork for further investigations. To do that, different woody biomass from disparate contaminated spots was harvested and examined. A brownfield land located in Gyöngyösoroszi, Hungary has been selected based on the elemental analysis of ash samples obtained from the incineration of the collected plants at 500 °C. The outcomes also preliminarily indicate the viability of phytomining in recovering REEs.
在传统采矿技术不合理或不盈利的棕地,植物法开采稀土元素为金属回收提供了潜在的可能性。植物挖掘的整体概念是从三个科学部门建立的。植物提取是植物积累稀土元素的第一个阶段。接下来是浓缩过程,目的是将金属浓度提高到固体残留物中。最终,提取技术被应用于从生物矿石中回收这些有价值的金属。本研究的主要目标是确定稀土植物挖掘的可能位置,为进一步的研究奠定基础。为了做到这一点,从不同的污染地点收集并检查了不同的木质生物质。根据对收集的植物在500°C下焚烧获得的灰烬样本进行元素分析,选择了位于匈牙利Gyöngyösoroszi的一片棕地。这些结果也初步表明了植物提取在回收稀土元素中的可行性。
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引用次数: 0
Merge in the Ethereum Blockchain 在以太坊区块链中合并
Pub Date : 2023-07-13 DOI: 10.14232/analecta.2023.3.19-25
András Bertalan, Balázs Gyenge, K. Kacz
The food industry has been at the forefront of rapid implementation for several technological innovations. One of the main reasons for this is that food security has been of paramount importance in supplying a growing population, taking into account both quantitative and qualitative requirements. And the necessary development could only be ensured by incorporating the latest developments. Blockchain technology is also a tool to consider in terms of how it can help track food chains. Its widespread application is only a decade old, but in some areas, for example, the operation of cryptocurrencies has already accumulated enough experience to see if it really lives up to the hopes attached to it, and what problems still stand in the way of further spread. With this material, our primary goal is to present a significant technological change that aims to solve one of the main problems of blockchain-based data management. It will be presented how the technology works (with a specific focus on the proof of work mechanism) and the transition to a truly significant platform, the proof of stake mechanism at Ethereum. This gives us an idea of how much a relatively new technology can undergo changes, and at what rate a seemingly significant problem (in this case, e.g. environmental impact) can decrease. This potential for development provides the basis for counting blockchains as a technology that can be applied in other areas, such as the food industry. In addition to scientific treatises, we often rely on Internet sources in the material, since the change occurred so quickly that publications in scientific journals could not yet track it or only in a narrower circle.
食品工业一直处于快速实施几项技术创新的前沿。造成这种情况的一个主要原因是,考虑到数量和质量的要求,粮食安全对供应不断增长的人口至关重要。只有结合最新的发展才能确保必要的发展。区块链技术也是一种工具,可以考虑如何帮助跟踪食物链。它的广泛应用只有十年的历史,但在某些领域,例如,加密货币的运作已经积累了足够的经验,可以看到它是否真的不负人们对它的期望,以及还有哪些问题阻碍着它的进一步推广。有了这些材料,我们的主要目标是提出一个重大的技术变革,旨在解决基于区块链的数据管理的主要问题之一。它将介绍该技术的工作原理(特别关注工作量证明机制)以及向真正重要的平台(以太坊的权益证明机制)的过渡。这让我们了解一项相对较新的技术可以经历多大程度的变化,以及一个看似重大的问题(在这种情况下,例如环境影响)可以以何种速度减少。这种发展潜力为将区块链视为一种可以应用于其他领域(如食品行业)的技术提供了基础。除了科学论文之外,我们还经常依赖网络资源来获取材料,因为变化发生得如此之快,以至于科学期刊上的出版物还无法追踪到它,或者只能在一个较小的范围内。
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引用次数: 0
Effects of photovoltaic systems on the behavior of harmonic components in low voltage network 光伏系统对低压电网谐波分量行为的影响
Pub Date : 2023-04-27 DOI: 10.14232/analecta.2023.2.32-47
R. Lipták, I. Bodnár
Renewable energy sources, especially solar systems, have become increasingly important energy sources in recent times. Connecting large PV systems to utility networks can cause a number of operational problems for distribution networks. The extent of these problems depends directly on the percentage of PV penetration and the geographical location of the installation. Possible problems caused by PV systems: over-voltage, output power fluctuation, harmonic distortion, frequency fluctuation Harmonic distortion is a serious energy quality problem which can occur in photovoltaic systems due to the use of power inverters that convert direct current to alternating current. The resulting harmonics can cause parallel and series resonances, transformer overheating, and protection device malfunctions, which can reduce the reliability of power supply systems.
近年来,可再生能源,特别是太阳能系统,已成为越来越重要的能源来源。将大型光伏系统连接到公用事业网络可能会给配电网带来许多操作问题。这些问题的严重程度直接取决于光伏渗透率的百分比和安装的地理位置。光伏系统可能出现的问题:过电压、输出功率波动、谐波失真、频率波动谐波失真是光伏系统中由于使用了将直流转换为交流的逆变器而可能出现的严重的电能质量问题。由此产生的谐波会引起并联和串联谐振、变压器过热和保护装置故障,从而降低供电系统的可靠性。
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引用次数: 0
期刊
Analecta Technica Szegedinensia
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