To improve the dewatering of bentonite slurries, a combined approach using polymeric ferric sulfate (PFS) and preloading was introduced into a pretreatment program for electroosmotic dewatering. The mechanisms underlying the promotion of electroosmotic dewatering by PFS and the optimization of the flocculation-preloading-electroosmosis process were investigated. The flocculation effect of the slurry was positively correlated with PFS. A 2 % PFS solution increased flocculation settlement by 164.3 %, mainly by promoting the conversion of weakly bound water into free water and increasing the effective stress of the bentonite slurry. The bridging action of PFS flocculation promoted the formation of clear water flow channels, thus enhancing electroosmotic dewatering. Additionally, PFS reduced the proportion of electroosmotic dewatering in the FPE dewatering process, leading to lower power consumption. Preloading promoted dewatering and minimized the variations in flocculation settlement resulting from different PFS dosages during the flocculation dewatering stage. During electroosmosis, the pressure loading induced the closure of cracks formed due to negative pore water pressure, thereby increasing both the current and drainage volume. Furthermore, an optimized treatment scheme combining flocculation, preloading, and electroosmosis (3.10 h of flocculation and 18.33 h of preloading) produced optimized dewatering results. This study presents a potentially effective solution for mitigating the environmental impact of bentonite slurries.
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