Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988813
J. Obaleye, A. Tella, G. K. Obiyenwa, Nzikahyel Simon, M. D. Olawale
4-Methoxyaniline-5,10,15,20-tetraphenylporphyrinatozinc(II), [(ZnTPP(MOAN)] 1 was synthesized (MOAN = 4-methoxyaniline) and characterized by elemental analysis and spectroscopic techniques. The molecular structure of 1 was determined by single-crystal X-ray crystallography. The structure revealed a triclinic crystal system and the space group P1 with the central metal adopting slightly distorted square pyramidal geometry with 4-methoxyaniline in the axial position. The antimicrobial activities were carried out using a well diffusion method and the zone of inhibition of four bacteria and two fungi was measured.
{"title":"Zinc(II) Complex of Meso-Tetraphenylporphyrin With 4-Methoxyaniline: Crystal Structure and Antimicrobial Activities of 4-Methoxyaniline-5, 10, 15, 20-Tetraphenyl-Porphyrinatozinc (II)","authors":"J. Obaleye, A. Tella, G. K. Obiyenwa, Nzikahyel Simon, M. D. Olawale","doi":"10.1080/15533174.2014.988813","DOIUrl":"https://doi.org/10.1080/15533174.2014.988813","url":null,"abstract":"4-Methoxyaniline-5,10,15,20-tetraphenylporphyrinatozinc(II), [(ZnTPP(MOAN)] 1 was synthesized (MOAN = 4-methoxyaniline) and characterized by elemental analysis and spectroscopic techniques. The molecular structure of 1 was determined by single-crystal X-ray crystallography. The structure revealed a triclinic crystal system and the space group P1 with the central metal adopting slightly distorted square pyramidal geometry with 4-methoxyaniline in the axial position. The antimicrobial activities were carried out using a well diffusion method and the zone of inhibition of four bacteria and two fungi was measured.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74238282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988799
Meili Zhang
A new Zn(II) complex, {[Zn2(CH3O-ip)2(bib)]·(H2O)}n (1) (CH3O-H2ip = 5-methoxyisophthalic acid, bib = 1,4-bis(2-methyl-imidazol-1-yl)butane, was synthesized and studied by elemental analysis, IR spectroscopy and X-ray crystallography. Complex 1 crystallizes in triclinic system with space group Pī, and exhibits a two-dimensional (2-D) (3,4)-connected net. In addition, thermal gravimetric analysis (TGA) and luminescent property of 1 were investigated.
{"title":"Synthesis, Crystal Structure, and Luminescent Property of One Zinc(II) Complex Based on 5-Methoxyisophthalate Ligand","authors":"Meili Zhang","doi":"10.1080/15533174.2014.988799","DOIUrl":"https://doi.org/10.1080/15533174.2014.988799","url":null,"abstract":"A new Zn(II) complex, {[Zn2(CH3O-ip)2(bib)]·(H2O)}n (1) (CH3O-H2ip = 5-methoxyisophthalic acid, bib = 1,4-bis(2-methyl-imidazol-1-yl)butane, was synthesized and studied by elemental analysis, IR spectroscopy and X-ray crystallography. Complex 1 crystallizes in triclinic system with space group Pī, and exhibits a two-dimensional (2-D) (3,4)-connected net. In addition, thermal gravimetric analysis (TGA) and luminescent property of 1 were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74246827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988803
Ling-qian Kong, Jianzhong Xu, Shengli Li, Da-cheng Li, J. Dou
Two new crown complexes, {[K(18-C-6)]2[Sn(i-mnt)3]}n·nC4H10O (1) and [Na(18-C-6)H2O]2[Sn(i-mnt)3]·2H2O·0.5C2H4Cl2 (2), have been prepared (i-nmt = 1,1-dicyanoethene-2,2-dithiolate), and characterized by elemental analysis, IR spectra and X-ray diffraction. In complexes 1 and 2, the coordination sphere for the Sn atom is slightly distorted trigonal bipyramid. The K(18-C-6) cations in complex 1 are linked to the Sn ion through the N atoms of the bridging C2S2(CN)22− anions, therefore forming two-dimensional network. For complex 2, because the coordinated H2O molecule to the Na+ prevents the further molecular structural extension, it is only a discrete trinuclear SnNa2 complex.
{"title":"Synthesis and Crystal Structures of New 18-Crown-6 Complexes With M2[Sn(i-mnt)3](M = K, Na)","authors":"Ling-qian Kong, Jianzhong Xu, Shengli Li, Da-cheng Li, J. Dou","doi":"10.1080/15533174.2014.988803","DOIUrl":"https://doi.org/10.1080/15533174.2014.988803","url":null,"abstract":"Two new crown complexes, {[K(18-C-6)]2[Sn(i-mnt)3]}n·nC4H10O (1) and [Na(18-C-6)H2O]2[Sn(i-mnt)3]·2H2O·0.5C2H4Cl2 (2), have been prepared (i-nmt = 1,1-dicyanoethene-2,2-dithiolate), and characterized by elemental analysis, IR spectra and X-ray diffraction. In complexes 1 and 2, the coordination sphere for the Sn atom is slightly distorted trigonal bipyramid. The K(18-C-6) cations in complex 1 are linked to the Sn ion through the N atoms of the bridging C2S2(CN)22− anions, therefore forming two-dimensional network. For complex 2, because the coordinated H2O molecule to the Na+ prevents the further molecular structural extension, it is only a discrete trinuclear SnNa2 complex.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86488535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988801
Qiaoli Wang, Haiyan Jiang, S. Ding, H. Noh, B. Moon, B. Choi, Jinsheng Shi, J. Jeong
Monoclinic-structured BiVO4 microcrystals with butterfly-like morphology were synthesized with alcoho-hydrothermal method. Compared with irregular morphologies BiVO4, the butterfly-like BiVO4 possessed higher surface area and lower energy band gap, which is conducive to promote the rapid adsorption of organic pollutants on the surface of BiVO4 and absorb the light with lower energy. Photocatalysis experiment results showed that the degradation efficiency of the butterfly-like BiVO4 for degradation MO solution is far higher than irregular morphologies BiVO4. It indicates the excellent photocatalytic activity of the butterfly-like BiVO4 may be related to its special morphology, high surface area, and low band gap energy.
{"title":"Butterfly-like BiVO4: Synthesis and Visible Light Photocatalytic Activity","authors":"Qiaoli Wang, Haiyan Jiang, S. Ding, H. Noh, B. Moon, B. Choi, Jinsheng Shi, J. Jeong","doi":"10.1080/15533174.2014.988801","DOIUrl":"https://doi.org/10.1080/15533174.2014.988801","url":null,"abstract":"Monoclinic-structured BiVO4 microcrystals with butterfly-like morphology were synthesized with alcoho-hydrothermal method. Compared with irregular morphologies BiVO4, the butterfly-like BiVO4 possessed higher surface area and lower energy band gap, which is conducive to promote the rapid adsorption of organic pollutants on the surface of BiVO4 and absorb the light with lower energy. Photocatalysis experiment results showed that the degradation efficiency of the butterfly-like BiVO4 for degradation MO solution is far higher than irregular morphologies BiVO4. It indicates the excellent photocatalytic activity of the butterfly-like BiVO4 may be related to its special morphology, high surface area, and low band gap energy.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89546541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988805
D. Ding, Jian-ling Wang
A selective and sensitive chromogenic and fluorogenic dual signal responding fluoride-sensor (L), comprising the well-known rhodamine 6G fluorophore and 2,2′-bipyridine was prepared and spectroscopically characterized. After mercury ion was added to the CH3CN solution of L, a color change from colorless to pink-red, which indicated that the sensor can serve as a sensitive “naked-eye” indicator for mercury ion. The high emission selectivity is due to the formation of L-Hg2+ 1:2 complex leads to spirocycle opening of L.
{"title":"Highly Sensitive Fluorescent Probe for Selective Detection of Hg2+","authors":"D. Ding, Jian-ling Wang","doi":"10.1080/15533174.2014.988805","DOIUrl":"https://doi.org/10.1080/15533174.2014.988805","url":null,"abstract":"A selective and sensitive chromogenic and fluorogenic dual signal responding fluoride-sensor (L), comprising the well-known rhodamine 6G fluorophore and 2,2′-bipyridine was prepared and spectroscopically characterized. After mercury ion was added to the CH3CN solution of L, a color change from colorless to pink-red, which indicated that the sensor can serve as a sensitive “naked-eye” indicator for mercury ion. The high emission selectivity is due to the formation of L-Hg2+ 1:2 complex leads to spirocycle opening of L.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89070762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988810
Zheng-Jun Liu, Xiao-Miao Chen, S. Hao, M. Cheng
Two new transition metal complexes [Cu(4-Cbsgly)(phen)]·0.5H2O (1), [Ni(4-Cbsgly)(phen)2]·3H2O (2) [4-CbsglyH2 = (4-chlorobenzenesulfonyl-glycine acid, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, TG analysis, and single-crystal X-ray diffraction. The complexes 1 and 2 are assembled by various kinds of hydrogen bonds and π-π stacking interactions into the 1D chain and 2D layer, respectively. Two-dimensional layer in 2 are further connected to form sandwich-like structure through weak O–H···O and C–H···O interactions. Furthermore, the thermal stability of complexes 1 and 2 were investigated.
{"title":"Syntheses, Crystal Structures, and Thermal Properties of Two Transition Metal Complexes With 4-Chlorobenzenesulfonyl-glycine Acid Ligand","authors":"Zheng-Jun Liu, Xiao-Miao Chen, S. Hao, M. Cheng","doi":"10.1080/15533174.2014.988810","DOIUrl":"https://doi.org/10.1080/15533174.2014.988810","url":null,"abstract":"Two new transition metal complexes [Cu(4-Cbsgly)(phen)]·0.5H2O (1), [Ni(4-Cbsgly)(phen)2]·3H2O (2) [4-CbsglyH2 = (4-chlorobenzenesulfonyl-glycine acid, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, TG analysis, and single-crystal X-ray diffraction. The complexes 1 and 2 are assembled by various kinds of hydrogen bonds and π-π stacking interactions into the 1D chain and 2D layer, respectively. Two-dimensional layer in 2 are further connected to form sandwich-like structure through weak O–H···O and C–H···O interactions. Furthermore, the thermal stability of complexes 1 and 2 were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88613142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988800
Huarui Wang, Jian-ge Wang
One three-dimensional (3D) coordination polymer, [Zn(L)(bimb)0.5]n (1) (L = 5-methoxyisophthalate, bimb = 1,4-bis(imidazol-1-yl)-butane), was synthesized and studied by elemental analysis, IR spectroscopy, and X-ray crystallography. This complex belongs to monoclinic system with space group P21/n, and exhibits a 3D (3,4)-connected net. In the structure of 1, the L ligand connects Zn(II) ions giving rise to a 2D helical layer. Adjacent ones are joined by bimb pillars to generate a novel 3D pillared-layer framework. Furthermore, luminescent property of 1 was also investigated.
{"title":"Synthesis, Crystal Structure, and Luminescent Property of One 3D Pillared-Layer Complex Based on 5-Methoxyisophthalate and 1,4-Bis(imidazol-1-yl)-butane Ligands","authors":"Huarui Wang, Jian-ge Wang","doi":"10.1080/15533174.2014.988800","DOIUrl":"https://doi.org/10.1080/15533174.2014.988800","url":null,"abstract":"One three-dimensional (3D) coordination polymer, [Zn(L)(bimb)0.5]n (1) (L = 5-methoxyisophthalate, bimb = 1,4-bis(imidazol-1-yl)-butane), was synthesized and studied by elemental analysis, IR spectroscopy, and X-ray crystallography. This complex belongs to monoclinic system with space group P21/n, and exhibits a 3D (3,4)-connected net. In the structure of 1, the L ligand connects Zn(II) ions giving rise to a 2D helical layer. Adjacent ones are joined by bimb pillars to generate a novel 3D pillared-layer framework. Furthermore, luminescent property of 1 was also investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80560068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2014.988795
M. Yilmaz, D. Tatar, E. Sonmez, Ç. Çırak, Ş. Aydoğan, R. Gunturkun
In this study, Al doped ZnO thin films were synthesized by sol gel spin coating technique. To investigate the effect of Al doping on ZnO properties, Al doping concentration was diversified in the range of 0–5 mol%. The effect of Al doping on structural, morphological, optical and electrical properties of ZnO thin films was evaluated by XRD, SEM, UV-VIS and four point probe measurements. All results whether pure or Al doped ZnO thin films were described in detail and they indicated that the films prepared in this study can be used in many nanotechnological applications.
{"title":"Investigation of Structural, Morphological, Optical, and Electrical Properties of Al Doped ZnO Thin Films Via Spin Coating Technique","authors":"M. Yilmaz, D. Tatar, E. Sonmez, Ç. Çırak, Ş. Aydoğan, R. Gunturkun","doi":"10.1080/15533174.2014.988795","DOIUrl":"https://doi.org/10.1080/15533174.2014.988795","url":null,"abstract":"In this study, Al doped ZnO thin films were synthesized by sol gel spin coating technique. To investigate the effect of Al doping on ZnO properties, Al doping concentration was diversified in the range of 0–5 mol%. The effect of Al doping on structural, morphological, optical and electrical properties of ZnO thin films was evaluated by XRD, SEM, UV-VIS and four point probe measurements. All results whether pure or Al doped ZnO thin films were described in detail and they indicated that the films prepared in this study can be used in many nanotechnological applications.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78529901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-02DOI: 10.1080/15533174.2015.1031012
Li Yan, Mingzhe Sun
One novel compound constructed from aromatic acid and N-heterocyclic ligands has been synthesized by hydrothermal reaction: [Mn(ipm)(1,8-NDC)(H2O)]2 (1) [ipm = 5-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)-2-methoxyphenol, 1,8-NDC = naphthalene-1,8-dicarboxylic acid]. The title compound was obtained by controlling the ratio of the starting materials and a reaction temperature at 170°C and was characterized by elemental analysis, IR, single-crystal X-ray diffraction, and thermogravimetric analysis (TGA). Single-crystal X-ray investigation reveals that compound 1 is zero dimensional (0D) structure, and the existence of hydrogen bonds and π-π interactions lead the 0D to 1D chain framework. Hydrogen bonds interactions are powerful noncovalent intermolecular interactions for directing supramolecular architectures. TGA shows three clear courses of weight loss, which corresponds to the decomposition of different ligands. At room temperature, compound 1 exhibits emission at 535 nm upon excitation at 325 nm. Fluorescent spectrum displays that compound 1 is potential luminescent material.
{"title":"Syntheses, Crystal Structure, and Photoluminescence Property of One Novel Compound Derived From Dicarboxylate and N-Donor Ligands","authors":"Li Yan, Mingzhe Sun","doi":"10.1080/15533174.2015.1031012","DOIUrl":"https://doi.org/10.1080/15533174.2015.1031012","url":null,"abstract":"One novel compound constructed from aromatic acid and N-heterocyclic ligands has been synthesized by hydrothermal reaction: [Mn(ipm)(1,8-NDC)(H2O)]2 (1) [ipm = 5-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)-2-methoxyphenol, 1,8-NDC = naphthalene-1,8-dicarboxylic acid]. The title compound was obtained by controlling the ratio of the starting materials and a reaction temperature at 170°C and was characterized by elemental analysis, IR, single-crystal X-ray diffraction, and thermogravimetric analysis (TGA). Single-crystal X-ray investigation reveals that compound 1 is zero dimensional (0D) structure, and the existence of hydrogen bonds and π-π interactions lead the 0D to 1D chain framework. Hydrogen bonds interactions are powerful noncovalent intermolecular interactions for directing supramolecular architectures. TGA shows three clear courses of weight loss, which corresponds to the decomposition of different ligands. At room temperature, compound 1 exhibits emission at 535 nm upon excitation at 325 nm. Fluorescent spectrum displays that compound 1 is potential luminescent material.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84198203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Two new tetrachloromanganate(II) salts, [4FBzTPP]2[MnCl4] (1) and [4ClBzTPP]2[MnCl4]·2H2O (2) ([4FBzTPP]+ = 1-(4′-fluorobenzyl)triphenylphosphonium; [4ClBzTPP]+ = 1-(4′-chlorobenzyl)triphenylphosphonium), have been prepared and characterized by elemental analyses, UV-Vis, IR, ESI-MS, molar conductivity and single-crystal X-ray diffraction. The single-crystal structure analysis shows that compound 1 crystallizes in the monoclinic space group P21/c, while 2 is triclinic P-1. Both 1 and 2 comprise one [MnCl4]2– anion and two cations, and the [MnCl4]2– anion exhibits distorted tetrahedral coordination geometry. The C‒H···Cl, C‒H···π hydrogen bonds and π···π stacking interactions in 1 and the C‒H···Cl, O‒H···Cl hydrogen bonds in 2 result in the forming of a 3D network structure in the solids.
{"title":"Syntheses, Crystal Structures, and Weak Interactions of Two 4-Substituted Benzyl Triphenylphosphonium Salts Containing Tetrachloromanganate(II) Anion","authors":"Hui-Qing Ye, Ye-Long Qian, Yan-Hui Pan, Man-Na Li, Xue-ni Lin, Xiao-Xu Zheng, Hua-Tang Cai, Xiao-ping Liu, Lemin Yang, Jia-rong Zhou","doi":"10.1080/15533174.2014.988798","DOIUrl":"https://doi.org/10.1080/15533174.2014.988798","url":null,"abstract":"Two new tetrachloromanganate(II) salts, [4FBzTPP]2[MnCl4] (1) and [4ClBzTPP]2[MnCl4]·2H2O (2) ([4FBzTPP]+ = 1-(4′-fluorobenzyl)triphenylphosphonium; [4ClBzTPP]+ = 1-(4′-chlorobenzyl)triphenylphosphonium), have been prepared and characterized by elemental analyses, UV-Vis, IR, ESI-MS, molar conductivity and single-crystal X-ray diffraction. The single-crystal structure analysis shows that compound 1 crystallizes in the monoclinic space group P21/c, while 2 is triclinic P-1. Both 1 and 2 comprise one [MnCl4]2– anion and two cations, and the [MnCl4]2– anion exhibits distorted tetrahedral coordination geometry. The C‒H···Cl, C‒H···π hydrogen bonds and π···π stacking interactions in 1 and the C‒H···Cl, O‒H···Cl hydrogen bonds in 2 result in the forming of a 3D network structure in the solids.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88261940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：