Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.989587
Pingping Zhou, Xiaohui Li, Yanli Dong, Hui-min Liu
A new heterometallic compound, namely [CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-thiophenedicarboxylic acid, DMF = N,N′-dimethylformamide), has been solvothermally synthesized and characterized by elemental analysis and single crystal X-ray diffraction. Compound 1 features a complicated three-dimensional (3D) framework based on heterometallic -{Cd-COO-Ba}n- inorganic chains. In addition, the luminescent properties of this compound were also investigated at room temperature.
采用溶剂热法合成了一种新的杂金属化合物[CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-噻吩二羧酸，DMF = n, n ' -二甲基甲酰胺)，并用元素分析和x射线单晶衍射对其进行了表征。化合物1具有基于杂金属-{Cd-COO-Ba}n-无机链的复杂三维(3D)结构。此外，还研究了该化合物在室温下的发光性能。
{"title":"Synthesis, Structure and Photoluminescent Properties of a New Ba(II)-Doped Cd(II) Coordination Polymer","authors":"Pingping Zhou, Xiaohui Li, Yanli Dong, Hui-min Liu","doi":"10.1080/15533174.2014.989587","DOIUrl":"https://doi.org/10.1080/15533174.2014.989587","url":null,"abstract":"A new heterometallic compound, namely [CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-thiophenedicarboxylic acid, DMF = N,N′-dimethylformamide), has been solvothermally synthesized and characterized by elemental analysis and single crystal X-ray diffraction. Compound 1 features a complicated three-dimensional (3D) framework based on heterometallic -{Cd-COO-Ba}n- inorganic chains. In addition, the luminescent properties of this compound were also investigated at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77837861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.989580
Yi Li, Xiaoxi Gao, Changmin Hou, Kaifeng Yu
The purpose of this study was to investigate the possibility for parenteral delivery of Gamma-linolenic acid methyl ester without chemical modification using a microemulsion. Microemulsions composed of gamma-linolenic acid methyl ester and Tween 80 were prepared using PEG 400 as a cosurfactant. The effect of formulation variables on the particle size of the microemulsion was investigated. TEM image indicates the liquid droplets of the microemulsion are spheral shape. The mean droplet size of microemulsion system (Tween 80: GLA = 3:1) by PCS was about 50 nm and no changes were noted for at least six months.
{"title":"Physicochemical Characterization and Evaluation of a Microemulsion System for Gamma-Linolenic Acid Methyl Ester","authors":"Yi Li, Xiaoxi Gao, Changmin Hou, Kaifeng Yu","doi":"10.1080/15533174.2014.989580","DOIUrl":"https://doi.org/10.1080/15533174.2014.989580","url":null,"abstract":"The purpose of this study was to investigate the possibility for parenteral delivery of Gamma-linolenic acid methyl ester without chemical modification using a microemulsion. Microemulsions composed of gamma-linolenic acid methyl ester and Tween 80 were prepared using PEG 400 as a cosurfactant. The effect of formulation variables on the particle size of the microemulsion was investigated. TEM image indicates the liquid droplets of the microemulsion are spheral shape. The mean droplet size of microemulsion system (Tween 80: GLA = 3:1) by PCS was about 50 nm and no changes were noted for at least six months.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84224282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.989585
Yanli Lu, P. Ma, Mingxue Li, Danyun Chen, Xueyan Zou
Up to now, main group gallium(III) complexes with thiosemicarbazones have been comparatively rare. Here, a main group six-coordinated gallium(III) complex [Ga(L)2]NO3·H2O (1) (HL = 2-acetylpyrazine N4-phenylthiosemicarbazone) has been synthesized and characterized by elemental analysis, IR and UV/Vis spectroscopy, mass spectrometry, and single-crystal X-ray diffraction. The cytotoxicity data suggest that 1 exhibits significant antiproliferative activity in vitro against three human cancer cells. Its possible apoptotic mechanism has been evaluated in HepG2 cells. 1 induces a dose-dependent apoptosis in HepG2 cells and the apoptosis is associated with reduction of mitochondrial membrane potential.
{"title":"A Main Group Gallium(III) Complex Derived from 2-Acetylpyrazine N4-phenylthiosemicarbazone: Synthesis, Crystal Structure and Biological Evaluation","authors":"Yanli Lu, P. Ma, Mingxue Li, Danyun Chen, Xueyan Zou","doi":"10.1080/15533174.2014.989585","DOIUrl":"https://doi.org/10.1080/15533174.2014.989585","url":null,"abstract":"Up to now, main group gallium(III) complexes with thiosemicarbazones have been comparatively rare. Here, a main group six-coordinated gallium(III) complex [Ga(L)2]NO3·H2O (1) (HL = 2-acetylpyrazine N4-phenylthiosemicarbazone) has been synthesized and characterized by elemental analysis, IR and UV/Vis spectroscopy, mass spectrometry, and single-crystal X-ray diffraction. The cytotoxicity data suggest that 1 exhibits significant antiproliferative activity in vitro against three human cancer cells. Its possible apoptotic mechanism has been evaluated in HepG2 cells. 1 induces a dose-dependent apoptosis in HepG2 cells and the apoptosis is associated with reduction of mitochondrial membrane potential.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81888315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.989583
Maryam Khabazipour, S. Shariati, F. Safa
In the present study, simple and versatile methods for preparation of SBA-3, SBA-15, and KIT-6 mesoporous silica magnetite nanoparticles (Fe3O4@SBA and Fe3O4@KIT-6 MNPs) were developed. The chemically synthesized magnetite nanoparticles were utilized for preparation of mesoporous MNPs with Fe3O4 core and mesoporous silica (SBA-3, SBA-15, and KIT-6) shell. The size and chemical structures of the synthesized nanoparticles were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectrophotometery (FT-IR). The synthesized mesoporous MNPs showed super paramagnetic property and the surface area of synthesized Fe3O4@SBA-3, Fe3O4@SBA-15, and Fe3O4@KIT-6 via BET was obtained as 627.87, 510.95, and 241.68 m2 g−1, respectively.
{"title":"SBA and KIT-6 Mesoporous Silica Magnetite Nanoparticles: Synthesis and Characterization","authors":"Maryam Khabazipour, S. Shariati, F. Safa","doi":"10.1080/15533174.2014.989583","DOIUrl":"https://doi.org/10.1080/15533174.2014.989583","url":null,"abstract":"In the present study, simple and versatile methods for preparation of SBA-3, SBA-15, and KIT-6 mesoporous silica magnetite nanoparticles (Fe3O4@SBA and Fe3O4@KIT-6 MNPs) were developed. The chemically synthesized magnetite nanoparticles were utilized for preparation of mesoporous MNPs with Fe3O4 core and mesoporous silica (SBA-3, SBA-15, and KIT-6) shell. The size and chemical structures of the synthesized nanoparticles were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectrophotometery (FT-IR). The synthesized mesoporous MNPs showed super paramagnetic property and the surface area of synthesized Fe3O4@SBA-3, Fe3O4@SBA-15, and Fe3O4@KIT-6 via BET was obtained as 627.87, 510.95, and 241.68 m2 g−1, respectively.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75633739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.988806
Xiu-ping Li, Rongxiang Zhao, Heng Jiang, Y. Zhai, Pei-hua Ma
ZnO-CeO2-TiO2 composite oxide was rapidly synthesized by the combustion method using ascorbic acid as combustion agent. The synthesized sample was characterized by XRD, FI-IR, UV-Vis, BET, and SEM. The morphologies and the ultraviolet absorption properties of ZnO-CeO2-TiO2 composite oxide were optimized by changing molar ratio of burning agent, zinc, titanium and cerium ions. The composite oxide exhibits stronger ultraviolet absorption and better photocatalytic properties when mole ratios of burning agent, zinc, titanium, and cerium ions are 8:4:0.25:1. The reason can be attributed to together ZnO, TiO2 with CeO2 degraded and decolorized the methylene blue. The composite oxide shows better decolorizing effect when the molar ratio of burning agent, zinc, titanium, and cerium ions is 8:1:0.25:1. The reason can be attributed to the XRD pattern peak of the composite is completely the same as CeO2, but the composite has better crystalline, so the properties of composite is superior to CeO2.
{"title":"Preparation and Catalytic Properties of ZnO-CeO2-TiO2 Composite","authors":"Xiu-ping Li, Rongxiang Zhao, Heng Jiang, Y. Zhai, Pei-hua Ma","doi":"10.1080/15533174.2014.988806","DOIUrl":"https://doi.org/10.1080/15533174.2014.988806","url":null,"abstract":"ZnO-CeO2-TiO2 composite oxide was rapidly synthesized by the combustion method using ascorbic acid as combustion agent. The synthesized sample was characterized by XRD, FI-IR, UV-Vis, BET, and SEM. The morphologies and the ultraviolet absorption properties of ZnO-CeO2-TiO2 composite oxide were optimized by changing molar ratio of burning agent, zinc, titanium and cerium ions. The composite oxide exhibits stronger ultraviolet absorption and better photocatalytic properties when mole ratios of burning agent, zinc, titanium, and cerium ions are 8:4:0.25:1. The reason can be attributed to together ZnO, TiO2 with CeO2 degraded and decolorized the methylene blue. The composite oxide shows better decolorizing effect when the molar ratio of burning agent, zinc, titanium, and cerium ions is 8:1:0.25:1. The reason can be attributed to the XRD pattern peak of the composite is completely the same as CeO2, but the composite has better crystalline, so the properties of composite is superior to CeO2.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80208496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.989584
S. Sheshmani, M. Ghadermazi
A 3D metal organic structure of a p-block metal ion, Sn(IV) atom, formulated as [Sn(pydc)(HOC2H5)(CH3)2]2, was synthesized and characterized. This complex is binuclear with two bridging oxygen atoms of carboxylate groups. Each of the two Sn(IV) atoms is also coordinated by the chelate (pydc)2− ligand and two terminal CH3 groups as well as by one terminal HOC2H5 group. Based upon the molecular structure analysis, the coordination environment around each Sn(IV) atom is distorted pentagonal bipyramid. The hydrogen bonding between carbonyl and ethoxy groups of two neighboring neutral complexes produce the Zig-Zag arrangements.
{"title":"Metal Organic Structure Built from Binuclear Sn(IV) Complex: Synthesis, Characterization, and X-Ray Structural Studies","authors":"S. Sheshmani, M. Ghadermazi","doi":"10.1080/15533174.2014.989584","DOIUrl":"https://doi.org/10.1080/15533174.2014.989584","url":null,"abstract":"A 3D metal organic structure of a p-block metal ion, Sn(IV) atom, formulated as [Sn(pydc)(HOC2H5)(CH3)2]2, was synthesized and characterized. This complex is binuclear with two bridging oxygen atoms of carboxylate groups. Each of the two Sn(IV) atoms is also coordinated by the chelate (pydc)2− ligand and two terminal CH3 groups as well as by one terminal HOC2H5 group. Based upon the molecular structure analysis, the coordination environment around each Sn(IV) atom is distorted pentagonal bipyramid. The hydrogen bonding between carbonyl and ethoxy groups of two neighboring neutral complexes produce the Zig-Zag arrangements.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88758987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.989530
S. Khanahmadzadeh, G. Hosseiny
Cellulose and cellulose acetate/Fe2TiO5 nanocomposites have been synthesized successfully. Nanocomposites indicate a ferromagnetic paramagnetic behavior, as evidenced by using vibrating sample magnetometer at room temperature. Fourier transform infrared spectrometry, scanning electron microscopy, and simultaneous thermal analysis (STA) were used to characterize, diagnosis, morphology, and particle size, respectively, and to measure the thermal properties of samples. STA investigations reveal that the thermal stability of the cellulose and cellulose acetate is significantly enhanced with the addition of nanofillers. The results indicated that Fe2TiO5 nanopowders were distributed in cellulose and cellulose acetate matrix with particle size between 25 and 75 nm.
{"title":"Synthesis, Characterization, and Thermal Properties of Fe2TiO5/Cellulose and Cellulose Acetate Nanocomposites","authors":"S. Khanahmadzadeh, G. Hosseiny","doi":"10.1080/15533174.2014.989530","DOIUrl":"https://doi.org/10.1080/15533174.2014.989530","url":null,"abstract":"Cellulose and cellulose acetate/Fe2TiO5 nanocomposites have been synthesized successfully. Nanocomposites indicate a ferromagnetic paramagnetic behavior, as evidenced by using vibrating sample magnetometer at room temperature. Fourier transform infrared spectrometry, scanning electron microscopy, and simultaneous thermal analysis (STA) were used to characterize, diagnosis, morphology, and particle size, respectively, and to measure the thermal properties of samples. STA investigations reveal that the thermal stability of the cellulose and cellulose acetate is significantly enhanced with the addition of nanofillers. The results indicated that Fe2TiO5 nanopowders were distributed in cellulose and cellulose acetate matrix with particle size between 25 and 75 nm.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83558408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-05-03DOI: 10.1080/15533174.2014.988823
Yin‐Qiu Liu
A new manganese(II) complex: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II) was prepared by the method of solvothermal synthesis, and its two-dimensional coordination polymeric network was determined by X-ray diffraction. It crystallized in monoclinic, space group C2/c, with a = 36.934(14) Å, b = 6.468(2) Å, c = 7.435(3) Å, ß = 91.733(7)°, Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3. Under ultraviolet radiation of 338 nm the emissions of the title complex mainly result from its ligand: cinnamic acid.
采用溶剂热合成的方法制备了一种新的锰(II)配合物:Catena-(diaqua-tetrakis(µ2-cinnamato-o,o ')-锰(II)，并用x射线衍射测定了其二维配位聚合物网络。晶型为单斜晶，空间群为C2/c, a = 36.934(14) Å， b = 6.468(2) Å， c = 7.435(3) Å， ß = 91.733(7)°，Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3。在338nm的紫外辐射下，标题配合物的发光主要来自其配体肉桂酸。
{"title":"Synthesis, Crystal Structure, and Luminescent Properties of a Two-Dimensional Mn(II) Coordination Polymer: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II))","authors":"Yin‐Qiu Liu","doi":"10.1080/15533174.2014.988823","DOIUrl":"https://doi.org/10.1080/15533174.2014.988823","url":null,"abstract":"A new manganese(II) complex: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II) was prepared by the method of solvothermal synthesis, and its two-dimensional coordination polymeric network was determined by X-ray diffraction. It crystallized in monoclinic, space group C2/c, with a = 36.934(14) Å, b = 6.468(2) Å, c = 7.435(3) Å, ß = 91.733(7)°, Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3. Under ultraviolet radiation of 338 nm the emissions of the title complex mainly result from its ligand: cinnamic acid.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84084980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-28DOI: 10.1080/15533174.2015.1137045
Xuanwen Liu, Junhua You, Yanyan Wang, Ye-Qi Yu, Na Su, And Rui Guo
A novel 1D alternating copper(II) chain complex of the composition {[Cu3(dmg)2(Hdmg)2(4,4′-bpy)]n⋅n[Cu(Hdmg)2(4,4′-bpy)]⋅0.5nH2dmg⋅5nH2O} (H2dmg = dimethylglyoxime, 4,4′-dpy = 4,4′-dipyridine) (1) was synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structure of 1 consists of neutral 1D alternating copper(II) chains [Cu3(dmg)2(Hdmg)2(4,4′-bpy)]n, [Cu(Hdmg)2(4,4′-bpy)] mononuclear units, noncoordinated H2dmg and lattice water molecules. 1D alternating copper(II) chains is built up of trinuclear unit, in which copper ions are linked by three kinds of bridging ligands: dmg, Hdmg and 4,4′-bpy. The authors also studied the electronic structure and orbital energies of 1 by DFT methods, and the results are consistent with UV-vis spectrum.
{"title":"Synthesis, Structure, and DFT Studies of a Novel 1D Alternating Copper(II) Chain Polymer With 4,4′-Bipyridine and Dimethylglyoxime Mixed Ligand","authors":"Xuanwen Liu, Junhua You, Yanyan Wang, Ye-Qi Yu, Na Su, And Rui Guo","doi":"10.1080/15533174.2015.1137045","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137045","url":null,"abstract":"A novel 1D alternating copper(II) chain complex of the composition {[Cu3(dmg)2(Hdmg)2(4,4′-bpy)]n⋅n[Cu(Hdmg)2(4,4′-bpy)]⋅0.5nH2dmg⋅5nH2O} (H2dmg = dimethylglyoxime, 4,4′-dpy = 4,4′-dipyridine) (1) was synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structure of 1 consists of neutral 1D alternating copper(II) chains [Cu3(dmg)2(Hdmg)2(4,4′-bpy)]n, [Cu(Hdmg)2(4,4′-bpy)] mononuclear units, noncoordinated H2dmg and lattice water molecules. 1D alternating copper(II) chains is built up of trinuclear unit, in which copper ions are linked by three kinds of bridging ligands: dmg, Hdmg and 4,4′-bpy. The authors also studied the electronic structure and orbital energies of 1 by DFT methods, and the results are consistent with UV-vis spectrum.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79527490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2016-04-25DOI: 10.1080/15533174.2015.1137046
Yiwu Tang, Zhenyu Wu, Cun Li
CdS quantum dots (QDs) and N719/QDs cosensitized solar cells based on ZnO nanorod arrays as photoanodes were successfully constructed. The influence of deposition times for CdS QDs on photovoltaic performance of ZnO/CdS photoanodes has been studied. The optimized photovoltaic performance was obtained from the device of the ZnO/CdS(10) electrode, with a VOC of 0.52 V, a JSC of 5.07 mA cm−2, a FF of 18.36, and an η of 0.48%. The cosensitized solar cell exhibited 35% enhancement in power conversion efficiency compared with the device sensitized by CdS QDs only.
成功构建了以ZnO纳米棒阵列为光阳极的CdS量子点(QDs)和N719/QDs共敏太阳能电池。研究了CdS量子点沉积时间对ZnO/CdS光阳极光电性能的影响。ZnO/CdS(10)电极器件的光伏性能达到了最佳，VOC为0.52 V, JSC为5.07 mA cm−2,FF为18.36，η为0.48%。与仅用CdS量子点敏化的太阳能电池相比，共敏太阳能电池的功率转换效率提高了35%。
{"title":"Efficient CdS/N719 Cosensitized Solar Cells Based on ZnO Nanorod Arrays","authors":"Yiwu Tang, Zhenyu Wu, Cun Li","doi":"10.1080/15533174.2015.1137046","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137046","url":null,"abstract":"CdS quantum dots (QDs) and N719/QDs cosensitized solar cells based on ZnO nanorod arrays as photoanodes were successfully constructed. The influence of deposition times for CdS QDs on photovoltaic performance of ZnO/CdS photoanodes has been studied. The optimized photovoltaic performance was obtained from the device of the ZnO/CdS(10) electrode, with a VOC of 0.52 V, a JSC of 5.07 mA cm−2, a FF of 18.36, and an η of 0.48%. The cosensitized solar cell exhibited 35% enhancement in power conversion efficiency compared with the device sensitized by CdS QDs only.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78044510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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