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Cyanide Degradation from Mining Effluent Using Two Reagents: Sodium Metabisulphite and the Metabisulphite Mixture with Hydrogen Peroxide 偏亚硫酸氢钠和偏亚硫酸氢溶液两种试剂降解矿山废水中氰化物的研究
IF 0.3 Pub Date : 2019-09-09 DOI: 10.18180/TECCIENCIA.2018.25.1
Gonzalo Aranguri Llerena, Iván Alberto Reyes López
Cyanide ion (CN-) is widely used in different industrial operations, such as jewelry, steel manufacture, gold and silver extraction and electroplating. However, industrial emissions containing the CN- ion have to be treated to comply with environmental regulations. This research aimed to degrade free cyanide (CNL) present in the tailing of a metallurgical plant that processes gold-bearing ores and uses sodium cyanide (NaCN) as a leaching reagent.  Sodium metabisulfite (Na2S2O5) and sodium metabisulfite with hydrogen peroxide  (Na2S2O5 + H2O2) were used as oxidizing agents. To evaluate the effect of the factors, we used a factorial design with three independent variables: stirring time, reagent excess percentage, type of reagent and a dependent variable: CNL degradation (mg/L). According to the analysis of variance (ANOVA), the variables influenced significantly CNL degradation, being the most relevant the reagent excess percentage and according to the results, the maximum CNL degradation was 97.67% when 400% of Na2S2O5excess was added with 4 hours of stirring.
氰化物离子(CN-)广泛用于不同的工业操作,如珠宝、钢铁制造、金银提取和电镀。然而,含有CN离子的工业排放物必须进行处理,以符合环境法规。本研究旨在降解一家冶金厂尾矿中存在的游离氰化物(CNL),该厂以氰化钠(NaCN)为浸出剂处理含金矿石。使用偏亚硫酸氢钠(Na2S2O5)和具有过氧化氢的偏亚硫酸钠(Na2O5+H2O2)作为氧化剂。为了评估这些因素的影响,我们使用了三个自变量的析因设计:搅拌时间、试剂过量百分比、试剂类型和因变量:CNL降解(mg/L)。根据方差分析(ANOVA),这些变量显著影响CNL降解,其中最相关的是试剂过量百分比,根据结果,当在搅拌4小时的情况下添加400%的Na2S2O5过量时,最大CNL降解为97.67%。
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引用次数: 5
Programming of Job Shop Production Systems with Fuzzy Logic 模糊逻辑下作业车间生产系统的编程
IF 0.3 Pub Date : 2019-09-09 DOI: 10.18180/TECCIENCIA.2018.25.5
Luis Eduardo Leguizamon Castellanos
This article proposes a decision-making algorithm based on the "fuzzy logic" as an optimization technique, which allows to find a good solution to the problem of determining the priority (sequencing) of service or manufacture of jobs in the programming of intermittent production systems, Job Shop. The combinatorial nature and complexity of the problem motivates the exploration of other alternatives solutions to the traditionally used. Initially, the fuzzy logic controller structure (number of input variables, rules and output) is determined in accordance with the objective functions to be optimized. Triangular membership functions are selected for the batch size, the delivery date, the processing time, the number of tools required in each operation, and the priority of the processing the jobs. The fuzzy rules base is defined, and the controller model is formulated (fuzzification, evaluation and defuzzification). The algorithm is developed in Matlab’s ®Simulink ®Fuzzy logic toolbox, achieving better results than those obtained with other methods.
本文提出了一种基于“模糊逻辑”的决策算法作为优化技术,可以很好地解决间歇生产系统作业车间规划中作业的服务或制造优先级(排序)问题。问题的组合性质和复杂性促使人们探索传统方法之外的其他替代解决方案。首先,根据要优化的目标函数确定模糊逻辑控制器的结构(输入变量的个数、规则的个数和输出的个数)。对于批量大小、交货日期、加工时间、每次操作所需的工具数量以及加工作业的优先级,选择三角形隶属函数。定义了模糊规则库,建立了控制器模型(模糊化、评价和去模糊化)。该算法是在Matlab的®Simulink®模糊逻辑工具箱中开发的,比使用其他方法获得的结果更好。
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引用次数: 3
Methodological Proposal to Correct and Adjust a Geodesic Leveling Data 大地水准测量资料校正与调整的方法建议
IF 0.3 Pub Date : 2019-09-09 DOI: 10.18180/TECCIENCIA.2019.26.3
José Ricardo Guevara-Lima, Sandra Milena González-Giraldo, Juan Sebastián Sánchez-Cárdenas
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引用次数: 0
Characterizing the Mechanical Properties of Steel AISI-SAE 4140 to Apply a Plasma Nitriding Process AISI-SAE 4140钢等离子体氮化力学性能的表征
IF 0.3 Pub Date : 2019-09-09 DOI: 10.18180/TECCIENCIA.2018.24.8
Giovanny Andres Olaya Esparragoza, Adrian Guerrero Galvis, aldrin belisario velosa pacheco
Surface treatments give physical and chemical properties to the materials, without them showing any change in their dimensions. Plasma nitriding is a thermochemical treatment, which increases some mechanical properties of metallic materials. In this article the characterization of the mechanical and micro-structural properties of an AISI-SAE 4140 steel is presented. To carry out the metallographic characterization, stress, hardness, abrasive wear and X-ray diffraction tests, the AISI-SAE 4140 steel was mechanized and prepared delivered in a hardened state (quenched and tempered) produced by Shah Alloys Ltd. making test pieces with their corresponding ASTM standards and nitrifying by plasma half of these at 500oC for 10 hours. A thickness of 6.78 μm was obtained from the nitride layer that the material acquired. A microstructural constitution was found formed by martensite and austenite retained in the base material, maintaining the same structure with the thermochemical process. The nitrided surface showed in its atomic chemical composition (At%) the presence of 8.04% N, 1.69% O and 1.38% Al (element of great importance to achieve great hardness), revealing an increase of 18.55% of surface hardness and 78.87% of wear resistance. Regarding the tensile properties, there is a 77.65% decrease in its elongation when subjected to medium and low tensile loads, presenting a deformation of 0.09 mm for the last stress effort of 600 MPa.
表面处理使材料具有物理和化学性质,而不会使其尺寸发生任何变化。等离子体氮化是一种热化学处理,它可以提高金属材料的一些机械性能。本文介绍了AISI-SAE 4140钢的力学性能和微观结构性能的表征。为了进行金相表征、应力、硬度、磨损和X射线衍射测试,机械化并制备了AISI-SAE 4140钢,该钢由Shah Alloys有限公司生产,处于硬化状态(淬火和回火),使用其相应的ASTM标准制备试件,并在500℃下通过等离子体对其中一半进行氮化10小时。从该材料获得的氮化物层获得了6.78μm的厚度。发现基体材料中残留的马氏体和奥氏体形成了微观结构,并通过热化学过程保持了相同的结构。氮化表面的原子化学组成(At%)显示,8.04%的N、1.69%的O和1.38%的Al(对获得高硬度非常重要的元素)的存在,表明表面硬度提高了18.55%,耐磨性提高了78.87%。关于拉伸性能,当受到中等和低拉伸载荷时,其伸长率降低77.65%,在600MPa的最后应力作用下呈现0.09mm的变形。
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引用次数: 1
ANTICORROSIVE PROPERTIES OF CHROMIUM COATINGS ON AISI H13 STEEL BY GASEOUS NITRIDING IN VACUUM aisi h13钢真空气体氮化镀铬层的防腐性能
IF 0.3 Pub Date : 2019-09-09 DOI: 10.18180/TECCIENCIA.2018.24.5
J. Olaya, H. Cifuentes
This paper shows the results of this process through the performance of a duplex treatment that combines the application a single chromium hard coating Cr(VI) on a AISI H13 steel with a thermochemical treatment of vacuum gas nitriding. The thickness of the electroplated coating was 15 μm, and N2 was used as precursor gas, with a flow of 100 ml/min at a pressure of 1.2 kPa to produce a CrxNy coating. The existing phases were determined by means of X-ray diffraction, and the corrosion resistance was evaluated via potentiodynamic polarization and electrochemical impedance spectroscopy techniques in a three-electrode electrochemical cell. Characterization via XRD determined the presence of chromium nitrides of type Cr2N, with an important orientation along the plane (300) associated with the partial pressure of N2 and the thermodynamic behavior. The corrosion resistance results showed a significant decrease in the corrosion current density compared with those exhibited by samples chromed by electroplating with AISI H13 steel without nitriding. These results, coupled with the sealing of characteristic microcracks of the electroplated chrome coating, could improve the corrosion resistance, because of the existence of the CrxNy phase.
本文通过在AISI H13钢上涂覆单一铬硬涂层Cr(VI)与真空气体氮化的热化学处理相结合的双重处理,展示了该工艺的结果。电镀涂层的厚度为15μm,使用N2作为前驱体气体,在1.2kPa的压力下以100ml/min的流量制备CrxNy涂层。通过X射线衍射测定了存在的相,并通过动电位极化和电化学阻抗谱技术在三电极电化学电池中评估了其耐腐蚀性。通过XRD的表征确定了Cr2N型氮化铬的存在,其沿平面(300)的重要取向与N2的分压和热力学行为有关。耐腐蚀性结果显示,与用AISI H13钢电镀而不氮化的样品相比,腐蚀电流密度显著降低。由于CrxNy相的存在,这些结果与电镀铬涂层特征微裂纹的密封相结合,可以提高其耐腐蚀性。
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引用次数: 2
Effect of Climate Change on Rainfall in the Upper Basin of Chicamocha River in 1980-2012 1980-2012年气候变化对Chicamocha河上游流域降水的影响
IF 0.3 Pub Date : 2019-09-09 DOI: 10.18180/TECCIENCIA.2018.24.9
L. Garavito, Carlos Andrés Caro Camargo
Indications suggest that anthropic activities have altered the atmospheric composition, causing alterations in elements generating extreme weather events and contributing to what we know today as global warming, through global and local changes in the rain regime and other climatic variables that interact in the hydrological cycle, causing extreme events with greater frequency. It is necessary to know the trends and extreme events of rains in order to have a basis for the adaptation and prevention of natural disasters caused by these macroclimatic phenomena. Through non-parametric tests, we found an increasing trend in rainfall between 5% to 20% average, in comparison with the behavior in the period of 1980 to 1990. Similarly, the influence of the macroclimatic variables in rainfall behavior is null.
有迹象表明,人类活动改变了大气成分,通过全球和局部雨势的变化以及水文循环中相互作用的其他气候变量,导致极端天气事件的要素发生变化,并导致我们今天所知的全球变暖,从而导致极端事件的频率更高。有必要了解降雨的趋势和极端事件,以便为适应和预防这些大气候现象造成的自然灾害奠定基础。通过非参数测试,我们发现与1980年至1990年期间的行为相比,降雨量呈平均5%至20%的增长趋势。同样,大气候变量对降雨行为的影响是零的。
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引用次数: 0
Physical Characterization of Breast Implants Submitted to High Energy X-Rays 高能x射线下乳房植入物的物理特性研究
IF 0.3 Pub Date : 2019-09-02 DOI: 10.18180/tecciencia.2019.26.8
Sandra Leiva, M. Plazas, L. Barretto
Based on clinical experience and various studies, it has been found that breast prostheses present failures that are related to a radiotherapy treatment. However, there are currently few studies that analyze the impact of radiotherapy on the material of the prosthesis. Accordingly, the aim of this paper is to characterize the material of silicone breast implants with high cohesiveness. In order to carry out the research a characterization based on mechanical tests, rheology, and spectrophotometry and scanning electron microscopy. This was done with the objective of identifying changes in the prosthesis before and after being irradiated with high energy x-ray photons. To perform the study, 4 breast implants were used. These implants were subjected to the aforementioned tests. The researcher repeated the observation in the second and the third month. Finally, when comparing the results, the mechanical changes are shown in the coating. In the internal material small changes were generated in the elastic and viscous modules. To conclude, effective changes were observed after radiotherapy treatment in the prosthetic material.
根据临床经验和各种研究,已经发现乳房假体的失败与放射治疗有关。然而,目前很少有研究分析放疗对假体材料的影响。因此,本文的目的是表征具有高内聚性的硅胶乳房植入物的材料。为了进行表征研究,采用了力学试验、流变学、分光光度法和扫描电子显微镜。这样做的目的是识别在用高能x射线光子照射之前和之后假体的变化。为了进行这项研究,使用了4个乳房植入物。对这些植入物进行上述测试。研究人员在第二个月和第三个月重复了这一观察结果。最后,当比较结果时,涂层中显示了机械变化。在内部材料中,弹性和粘性模块发生了微小变化。总之,在放射治疗后,在假体材料中观察到了有效的变化。
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引用次数: 0
se of Biofuels in the Aeronautical Industry. Case of the Colombian Air Force. 生物燃料在航空工业中的应用。哥伦比亚空军案例。
IF 0.3 Pub Date : 2019-07-08 DOI: 10.18180/TECCIENCIA.2019.26.7
M. Mayorga, Juan Guillermo Cadavid Estrada, J. Páez, C. L. Santamaría, M. Gómez
The present work makes a review of the uses of biofuels in the aeronautical industry, considering military aviation. The state of the art contemplates researches for the production and characterization of the different alternatives that can partially or totally replace fossil fuels of aviation, aiming to reduce the emissions of greenhouse gases. In the local case, through the development of a research project endorsed by Colciencias, the use of biofuels for aircraft engines has been evaluated. In the first phase, ground tests were carried out to justify and present the results of the options considered. In this way, an outline is made of the production of biokerosene and FAME produced at laboratory level, as well as the inherent challenges to incorporate these two biofuels in mixtures with Jet Fuel in a commercial level for the national scope
本工作从军用航空的角度对生物燃料在航空工业中的应用进行了回顾。现有技术考虑对不同替代品的生产和表征进行研究,这些替代品可以部分或完全取代航空化石燃料,旨在减少温室气体的排放。在当地,通过开发一个由Colciencias认可的研究项目,对生物燃料用于飞机发动机的情况进行了评估。在第一阶段,进行了地面试验,以证明和介绍所考虑的备选方案的结果。通过这种方式,概述了实验室生产的生物煤油和FAME的生产,以及在国家范围内将这两种生物燃料与喷气燃料混合使用的固有挑战
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引用次数: 7
Multi-Agent System Used for Recommendation of Historical and Cultural Memories 用于历史文化记忆推荐的多Agent系统
IF 0.3 Pub Date : 2019-07-08 DOI: 10.18180/TECCIENCIA.2019.26.6
Nancy Yaneth Gelvez García, Andrés David Ballén Duarte, H. E. E. Cuchango
espanolEn el presente documento se realiza la propuesta de un sistema de recomendacion basado en multi-agentes que permite analizar el comportamiento de un usuario cuando este visualiza memorias historicas y culturales, ofreciendo recorridos recomendados mediante las calificaciones y tiempos de duracion al observar las obras de arte. Tambien se muestra la arquitectura del sistema, el servidor utilizado para el desarrollo del sistema multiagente, asi como la comunicacion entre agentes necesarias para llevar a cabo un recorrido recomendado y la funcionalidad requerida para sugerir los nuevos recorridos a un usuario. El sistema multiagente utiliza una red neuronal que permite analizar el comportamiento de un usuario en un recorrido; mediante la retroalimentacion por la red neuronal se verifican los datos estableciendo los gustos del usuario. Para generar las recomendaciones se uso un dataset de informacion de memorias historicas y culturales, como tambien un api para el almacenamiento de usuarios. Para la visualizacion del funcionamiento del sistema, este prototipo se conecto con un aplicativo de realidad aumentada que permite a los usuarios acceder a las obras de arte y utilizar preferencias predefinidas EnglishIn this document the proposal of a recommendation system based on multi agent is made allowing the analysis of user behavior when visiting historical and cultural memories, giving recommendations based on qualifications and duration times for the observation of art pieces. It is also possible to see the system architecture, the server used for the development of the multiagent system, as well as the communication between agents to carry out a route, and the functionality for recommending new routes to a user. The multi-agent system uses a neural network that allows to analyze the behavior of a user in a route; using the feedback given for the neural network the data is checked, allowing determine the user preferences. A set of historical and cultural memory data set is used to generate recommendations; in addition, a user storage API is employed. For the system visualization, this prototype is connected with an augmented reality application that allows users access to visit art pieces and use predefined preferences
本文件提出了一个基于多智能体的推荐系统,允许分析用户在可视化历史和文化记忆时的行为,通过评级和持续时间提供推荐的路线,以观察艺术品。它还显示了系统架构、用于开发多智能体系统的服务器、执行推荐路径所需的代理之间的通信以及向用户推荐新路径所需的功能。多智能体系统使用神经网络来分析用户在路径上的行为;通过神经网络的反馈,通过建立用户的品味来验证数据。为了生成建议,我们使用了历史和文化记忆的信息数据集,以及用于存储用户的api。为visualizacion系统的运作,该原型连接一个增强现实应用程序允许用户访问和使用预定义偏好的杰作EnglishIn this document之提案建议system based on多种agent is made允许the analysis of user behavior when visiting历史文化记忆,给予建议based on qualifications and duration times for the观测of art pieces。还可以看到系统架构、用于开发多智能体系统的服务器、代理之间携带路由的通信以及向用户推荐新路由的功能。多智能体系统使用神经网络来分析用户在道路上的行为;= = references = = = =外部链接= = *“神经网络”*“神经网络”*“神经网络”*“神经网络”*“神经网络”*“神经网络”*“神经网络”*“神经网络”*“神经网络”一套历史和文化记忆数据用于生成建议;= =地理= =根据美国人口普查局的数据,该镇总面积为,其中土地和(1.)水。对于系统可视化,这个原型连接到一个增强现实应用程序,允许用户访问艺术品并使用预定义的偏好
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引用次数: 3
Green inorganic pigment production with spinel structureCoCr2O4by solution combustion synthesis 溶液燃烧合成尖晶石结构的绿色无机颜料CoCr2O4
IF 0.3 Pub Date : 2019-05-15 DOI: 10.18180/TECCIENCIA.2019.26.5
E. A. Miranda, Alex Arbey Lopera Sepúlveda, Juan Fernando Montoya Carvajal, Stiven Villada Gil, Ó. R. Baena
In this research, inorganic pigment with spinel structure CoCr 2 O 4 was synthesized by the solution combustion synthesis using glycine as fuel in an one-step. The powders as-prepared after combustion and then calcined at 700 °C during 6 hours, were characterized by the X-ray diffraction (XRD), and both samples showed the peaks corresponding to the expected spinel structure. which showed that the spinel structure was obtained in the combustion reaction.  Images of field emission scanning electron microscope (FE-SEM) showed the formation of porous and agglomeration of particles with, irregular shape. Finally, diffuse reflectance visible spectra were showed with an absorption band in the range of 570 nm -670 nm, which is due to electronic transitions corresponding to 4 A 2 (F) → 4 T 1 (P) when the cation of Co 2+ in tetrahedrical position and electronic transitions 4 A 2g → 4 T 2g of Cr 3+ in octaedrical positions. Color coordinates CIEL*a*b* correspond to a green color, which is consistent with the diffuse reflectance spectra.
本研究以甘氨酸为燃料,采用溶液燃烧法一步合成了尖晶石结构的无机颜料CoCr2O4。燃烧后制备的粉末,然后在700°C下煅烧6小时,通过X射线衍射(XRD)进行表征,两个样品都显示出与预期尖晶石结构相对应的峰。这表明在燃烧反应中获得了尖晶石结构。场发射扫描电子显微镜(FE-SEM)图像显示,颗粒形成多孔和团聚,形状不规则。最后,漫反射可见光谱的吸收带在570 nm-670 nm范围内,这是由于对应于4 A2(F)的电子跃迁→ 当Co2+阳离子在四面体位置时的4T1(P)和电子跃迁4A2g→ Cr 3+在八面体位置上为4 T 2 g。颜色坐标CIEL*a*b*对应于绿色,其与漫反射光谱一致。
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引用次数: 3
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