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Impact of Solid Content in the Electrospinning Solution on the Physical and Chemical Properties of Polyacrylonitrile (PAN) Nanofibrous Mats 静电纺丝溶液中固体含量对聚丙烯腈(PAN)纳米纤维毡物理化学性能的影响
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2020-09-28 DOI: 10.14502/tekstilec2020.63.225-232
T. Grothe, J. L. Storck, Marius Dotter, A. Ehrmann
Polyacrylonitrile (PAN) belongs to the group of polymers that are often used for electrospinning, as it can be applied as a pre-cursor for carbon nanofibres and is spinnable from the low-toxic solvent dimethyl sulfoxide (DMSO). While the influence of different spinning parameters on fibre morphology and mass per unit area was investigated in a previous study, here we report on the impact of the spinning solution, using DMSO as a solvent and wire-based (needleless) electrospinning. Our results show that a broad range of solid contents can be applied, providing the opportunity to tailor the fibre diameter distribution or to optimize the areal weight of the nanofibrous mat by changing this parameter, while the chemical composition of the fibres remains identical.
聚丙烯腈(PAN)属于经常用于静电纺丝的聚合物组,因为它可以用作碳纳米纤维的前驱体,并且可以从低毒溶剂二甲基亚砜(DMSO)中纺丝。虽然在之前的一项研究中研究了不同纺丝参数对纤维形态和单位面积质量的影响,但在这里,我们报道了使用二甲基亚砜作为溶剂和丝基(无针)静电纺丝的纺丝溶液的影响。我们的研究结果表明,可以应用广泛的固体含量,从而有机会通过改变该参数来调整纤维直径分布或优化纳米纤维垫的面积重量,同时纤维的化学成分保持不变。
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引用次数: 9
Determination of Working Methods and Normal Times of Technological Sewing Operation using MTM System 用MTM系统确定工艺缝纫作业的工作方法和正常时间
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2020-09-28 DOI: 10.14502/tekstilec2020.63.203-215
Snježana Kirin, A. H. Šajatović
Working processes in the technological sewing process are performed on machine systems characterized by machine-manual work, where the worker and the machine work simultaneously. Such a work system requires a great deal of responsibility in terms of quality, quantity, and the accurate and timely execution of tasks, which requires the quick and accurate response and extremely good psychomotor and visual skills of workers. This paper presents the process of determining the working method and normal times for the technological operation of runstitching women’s blouse collars, which includes the design of an ergonomically designed workplace, the selection and technical equipment of the universal sewing machine and the determination of the optimal work method and normal times using the Methods-Time Measurement (MTM) system. The research results obtained indicate that the technical equipment of a universal sewing machine has a significant impact on the structure of the technological sewing operation and the working method, i.e. the number of auxiliary manual technological suboperations. Improving technical equipment, i.e. increasing the number of automated functions used on a universal sewing machine, reduces the number of auxiliary manual suboperations, reduces the time required to perform the technological operation and increases work productivity.
工艺缝纫过程中的工作过程是在机器系统上进行的,其特点是机器-手动工作,工人和机器同时工作。这样的工作体系要求对任务的质、量、准确、及时的执行承担很大的责任,这就要求工人的反应迅速、准确,并具备极好的心理运动和视觉技能。本文介绍了女式衬衫平缝领工艺操作的工作方法和正常工作时间的确定过程,包括工效设计的工作场所设计、通用缝纫机的选型和技术设备以及采用方法-时间测量(MTM)系统确定最佳工作方法和正常工作时间。研究结果表明,通用缝纫机的工艺装备对工艺缝纫操作的结构和工作方法,即辅助人工工艺子操作的数量有显著影响。改进技术设备,即增加通用缝纫机上使用的自动化功能的数量,减少辅助人工子操作的数量,减少执行工艺操作所需的时间,提高工作效率。
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引用次数: 3
Study of Elastic Warp Knitted Bands: Production and Properties 弹性经编带的生产及性能研究
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2020-06-30 DOI: 10.14502/tekstilec2020.63.113-123
O. Kyzymchuk, Nemyrovycha-Danchenko str. Kyiv Ukraine Design, L. Melnyk, Svitlana Arabuli
Elastic fi tted goods are identifi ed as a separate group of medical textiles. This group includes elastic bandages, abdominal binders, posture correctors, corsets, recliners, etc. Elastic knitted bands are widely used in rehabilitation and prophylactic goods. This research studied the properties of elastic warp knitted bands that were made on an 18E gauge crochet machine. In order to reduce the product weight and to increase its comfort, a partial set (2-in/1-out) of elastomeric threads is used. This yarn is the main component of elastic fabric that aff ects stretch properties and end-use. In the warp knitted band, the polyurethane thread is usually used as longitudinal inlay yarn, which is located between the loop’s overlap and underlap. In order to study the eff ect of polyurethane pre-elongation before knitting on band properties, seven pairs of gears were used and elongation was varied from 280% to 395%. The weft fi lling yarn connects the separate wales into the band. To prevent contact between polyurethane threads and the human body, the weft yarns were laid on both sides of the inlay yarn. The movements of weft guides were in opposite directions. In order to study the eff ect of weft yarn diameter on cover factor and bands properties, 2 ends, 4 ends or 6 ends of 16.7 tex polyester yarn were used to achieve corresponding overall linear densities of 33.4 tex, 66.8 tex and 100.2 tex. It was concluded that the partial drawing-in of the guide bar with polyurethane thread facilitated a reduction of up to 20% in the basis weight of the elastic band, while ensuring suffi cient stretch properties. The impact of technological factors on the structural parameters and properties of the elastic band was established.
弹性纺织品被定义为一组单独的医用纺织品。这类产品包括弹性绷带、腹部固定器、姿势矫正器、紧身胸衣、躺椅等。弹性针织带广泛用于康复和预防用品。研究了在18E规格钩针机上制作的弹性经编带的性能。为了减少产品重量并增加其舒适性,使用了部分(2英寸/1英寸)的弹性体螺纹。这种纱线是弹性织物的主要成分,会影响拉伸性能和最终用途。在经编带中,聚氨酯线通常用作纵向镶嵌线,位于环的重叠部分和下重叠部分之间。为了研究编织前聚氨酯预伸长率对织带性能的影响,使用了七对齿轮,伸长率在280%-395%之间变化。纬纱将单独的纵行连接到带中。为了防止聚氨酯线与人体接触,纬纱铺设在镶嵌纱的两侧。引纬器的运动方向相反。为了研究纬纱直径对覆盖系数和带性能的影响,使用16.7 tex聚酯纱的2头、4头或6头来获得33.4 tex、66.8 tex和100.2 tex的相应总线密度。得出的结论是,带有聚氨酯螺纹的导杆的局部拉伸有助于弹性带基重减少20%,同时确保有效的拉伸性能。建立了工艺因素对弹性带结构参数和性能的影响。
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引用次数: 3
Removal of Reactive Black 5 dye from Aqueous Media using Powdered Activated Carbon – Kinetics and Mechanisms 粉状活性炭去除水中活性黑5染料的动力学和机理
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2020-06-30 DOI: 10.14502/tekstilec2020.63.151-161
I. Bonic, Andrea Palac, Ana Sutlović, B. Vojnović, M. Cetina, Savska c. Ecology, Croatia Hr Zagreb
The textile industry is considered one of the major environmental polluters, primarily due to the quantity and composition of wastewater. It is therefore important to examine its diff erent treatment methods. For this purpose, the isothermal adsorption of Reactive Black 5 dye on powdered activated carbon at 25(±1) °C and 45(±1) °C was carried out to determine the eff ect of initial dye concentration, contact time and temperature on the adsorption process. In order to investigate the mechanism of adsorption of Reactive Black 5 dye on activated carbon, kinetic studies have also been carried out. Experimental data were analysed using a pseudo-fi rst-order and pseudo-second-order kinetic models, as well as an intraparticle diff usion model. Standard Gibbs free energy values of the adsorption process were also calculated, while the morphological analysis of activated carbon before and after adsorption was performed using a scanning electron microscope. The effi ciency of activated carbon as an adsorbent for Reactive Black 5 dye is evidenced by the fact that more than 60% of dye is adsorbed after 30 minutes regardless of initial concentration and temperature. The experimental data also showed that adsorption is kinetically controlled assuming a pseudo-second-order process, and that intraparticle diff usion is not the only process that infl uences the adsorption rate. Negative values of standard Gibbs free energy indicate that the adsorption reaction is spontaneous, while a higher negative value for temperature of 45 °C compared to 25 °C shows that a higher temperature is more energetically favourable for the adsorption of Reactive Black 5.
纺织业被认为是主要的环境污染源之一,主要是由于废水的数量和成分。因此,检查其不同的治疗方法是很重要的。为此,对活性黑5染料在粉末活性炭上在25(±1)°C和45(±一)°C下的等温吸附进行了研究,以确定染料初始浓度、接触时间和温度对吸附过程的影响。为了研究活性黑5染料在活性炭上的吸附机理,还进行了动力学研究。实验数据使用伪一阶和伪二阶动力学模型以及粒子内扩散模型进行分析。还计算了吸附过程的标准吉布斯自由能值,同时使用扫描电子显微镜对吸附前后的活性炭进行形态分析。活性炭作为活性黑5染料的吸附剂的效率证明了这样一个事实,即无论初始浓度和温度如何,超过60%的染料在30分钟后被吸附。实验数据还表明,假设吸附是一个伪二阶过程,吸附是受动力学控制的,颗粒内扩散并不是影响吸附速率的唯一过程。标准吉布斯自由能的负值表明吸附反应是自发的,而与25°C相比,45°C温度的负值更高表明更高的温度在能量上更有利于活性黑5的吸附。
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引用次数: 1
Chemical and Morphological Modification of PAN Nanofibrous Mats with Addition of Casein after 添加酪蛋白后PAN纳米纤维毡的化学和形态改性
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2020-03-05 DOI: 10.14502/tekstilec2020.63.38-49
E. Diestelhorst, F. Mance, Al Mamun, A. Ehrmann
Electrospun polyacrylonitrile (PAN) nanofi brous mats belong to typical precursor materials of carbon nanofi bres. They have, however, the problem that they need to be fi xed or even stretched during stabilisation and ideally also during carbonisation in order to avoid undesired conglutinations and deformations of the original nanofi bre morphology, resulting in brittle behaviour of the macroscopic nanofi brous mat, which impedes several applications. In an earlier investigation, blending PAN with ZnO was shown to increase fi bre diameters and lead to unproblematic stabilisation and carbonisation of nanofi brous mats. ZnO, on the other hand, may have a negative impact on biotechnological applications such as tissue engineering. Here, we thus report on the morphological and chemical modifi cations due to blending PAN electrospinning solutions with diff erent amounts of casein. By optimising the PAN : casein ratio, relatively thick, straight nanofi bres are obtained, which can be stabilised and carbonised unambiguously, without the well-known negative impact on cell adhesion due to the addition of ZnO.
电纺聚丙烯腈(PAN)纳米纤维毡属于典型的碳纳米纤维前驱体材料。然而,它们存在的问题是,在稳定过程中,理想情况下,在碳化过程中,它们需要被固定甚至拉伸,以避免原始纳米纤维形态的不期望的粘合和变形,从而导致宏观纳米纤维垫的脆性行为,这阻碍了一些应用。在早期的研究中,将PAN与ZnO共混可以增加纤维直径,并导致纳米纤维毡的无问题稳定和碳化。另一方面,ZnO可能对组织工程等生物技术应用产生负面影响。因此,我们在这里报道了由于将PAN静电纺丝溶液与不同量的酪蛋白混合而引起的形态和化学改性。通过优化PAN与酪蛋白的比例,可以获得相对较厚的直纳米纤维,其可以被稳定化和碳化,而不会因添加ZnO而对细胞粘附产生众所周知的负面影响。
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引用次数: 4
Real-Time Quality Assessment of Neppy Mélange Yarn Manufacturing Using Macropixel Analysis 用宏像素分析法实时评价Neppy Mélange纱生产质量
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2019-11-14 DOI: 10.14502/tekstilec2019.62.242-247
Habiba Halepoto, Tao Gong, Kashif Kaleem
The aim of this paper is to provide a simple MATLAB-based model to determine the real-time homogeneity of neppy mélange yarn fabrics. Currently, the mélange yarn industry relies solely on visual assessment and experience. This algorithm, however, proposes a solution for the mélange yarn industry. The designed algorithm presented in this paper, which is based on kernel density function and macropixel analysis, was implemented for the real-time nep detection of neppy mélange yarns and calculated an inhomogeneity of neps of around 91%. This strategy would be useful for the mélange yarn industry and can also be used in other types of fashion yarns.
本文的目的是提供一个简单的基于MATLAB的模型来确定棉结纱织物的实时均匀性。目前,兰热纱线行业完全依赖视觉评估和经验。然而,该算法为兰热纱线行业提供了一种解决方案。本文提出的基于核密度函数和宏像素分析的算法被用于棉结纱线的棉结实时检测,并计算出约91%的棉结不均匀性。这一策略对兰热纱线行业很有用,也可以用于其他类型的时尚纱线。
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引用次数: 9
Comparative Performance of Synthesised Silica Nanoparticles for Enhanced Hydrophilic Properties on Cotton 合成二氧化硅纳米颗粒增强棉花亲水性的性能比较
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2019-11-14 DOI: 10.14502/tekstilec2019.62.278-287
N. Chakraborty, Y. Sharma
Chemicals in nano-form are free from aggregates and low concentration eff ective. The nanoparticles of certain chemicals have been found to be of substantial importance for application in textiles as well as allied fi elds. Nano-silica is one of such nanoparticles possessing enormous potential for multi-functional application on cotton. However, the cost of nanoparticles is remarkably high, thus limiting their commercial applications. This study discusses the manufacture of silica nanoparticles in a laboratory, their characterisation, succeeded by their application on cotton. The performance was compared with those obtained with tailormade silica nanoparticles from manufacturers. It was found that laboratory-made silica nanoparticles are relatively capable of developing a parallel fi nishing eff ect on cotton compared to those obtained with tailormade silica nanoparticles.
纳米形态的化学物质无聚集体,浓度低。人们发现某些化学物质的纳米颗粒在纺织品和相关领域的应用具有重要意义。纳米二氧化硅是其中一种具有巨大多功能应用潜力的纳米颗粒。然而,纳米颗粒的成本非常高,从而限制了它们的商业应用。本研究讨论了二氧化硅纳米颗粒在实验室的制造,它们的特性,成功的应用在棉花上。比较了厂商定制的二氧化硅纳米颗粒的性能。实验发现,与定制的二氧化硅纳米颗粒相比,实验室制备的二氧化硅纳米颗粒相对能够在棉花上产生平行整理效果。
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引用次数: 1
Thermal Resistance and Moisture Management Behaviour of Nettle/Polyester Nonwoven Fabrics 荨麻/聚酯非织造布的耐热性和湿度管理性能
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2019-11-14 DOI: 10.14502/tekstilec2019.62.258-268
S. Sinha, Akshay Sharma, S. Maity
Thermal resistance and moisture management characteristics are important attributes of textile materials for the characterisation of their ability to provide thermal comfort. Nettle fi bre consists of a hollow core that is expected to enable good thermal and moisture regulation properties. Nonwoven fabrics of three diff erent mass per unit area values, made from nettle, polyester and blends thereof, were prepared on a needlepunching machine, maintaining the same punch density and depth of penetration. The thermal conductivity, water vapour permeability, water retention, wicking, moisture management, drying rate and air permeability of these fabrics were evaluated. Nonwoven fabric prepared with 100% nettle fi bres exhibited good thermal conductivity, while polyester fabric demonstrated good thermal insulation. The nettle fi bre fabric showed good water retention, drying rate and moisture management properties. On the other hand, polyester-enriched fabric exhibited good wicking behaviour.
耐热性和水分管理特性是纺织材料提供热舒适性的重要特性。Nettle纤维由一个中空芯组成,有望实现良好的热调节和湿度调节性能。在针刺机上制备由荨麻、聚酯及其混合物制成的每单位面积具有三种不同质量值的非织造织物,保持相同的穿孔密度和穿透深度。对这些织物的导热性、水蒸气渗透性、保水性、吸湿性、水分管理、干燥速率和透气性进行了评价。用100%麻纤维制备的非织造布具有良好的导热性,而聚酯织物具有良好的隔热性。该麻织物具有良好的保水性、干燥速率和水分管理性能。另一方面,富含聚酯纤维的织物表现出良好的吸湿性能。
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引用次数: 4
A New Method of Printing Multi-Material Textiles by Fused Deposition Modelling (FDM) 熔融沉积建模(FDM)打印多材料纺织品的新方法
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2019-11-14 DOI: 10.14502/tekstilec2019.62.248-257
Rimma Uysal, Orlando Fl Usa D Print Lab, Jack B. Stubbs
3D printing is considered to be the key technology for future production processes. It has recently found its way into the fi eld of the textile industry and promises to revolutionise the textile supply chain. It is of particular interest for the production of customised items and other structures which cannot be produced with common techniques. Large apparel companies have already integrated 3D printing into their manufacturing processes to print parts like soles and accessories. However, 3D printed garments that are ready to wear can still not be found. Due to the lack of suitable printing materials, research in 3D printed textiles is still in its initial stage. This research contributes to the development of 3D printed textiles by using Fused Deposition Modelling (FDM). In this study, a new method for printing textile-like surfaces was developed which combines diff erent materials into an interrelated fl exible structure. Several textile-like surfaces were designed on this basis and fi nally applied to a wearable garment. Furthermore, the advantages of 3D printing for the textile supply chain were demonstrated.
3D打印被认为是未来生产过程的关键技术。它最近进入了纺织行业,并承诺将彻底改变纺织供应链。它对定制物品和其他无法用普通技术生产的结构的生产特别感兴趣。大型服装公司已经将3D打印集成到其制造过程中,以打印鞋底和配件等零件。然而,3D打印的成衣仍然找不到。由于缺乏合适的打印材料,3D打印纺织品的研究仍处于初级阶段。这项研究有助于利用熔融沉积建模(FDM)开发3D打印纺织品。在这项研究中,开发了一种打印类似纺织品表面的新方法,该方法将不同的材料组合成一个相互关联的柔性结构。在此基础上设计了几种类似纺织品的表面,并最终应用于可穿戴服装。此外,还展示了3D打印在纺织品供应链中的优势。
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引用次数: 25
Influence of Basic Colour Parameters on Colour Memory 基本色彩参数对色彩记忆的影响
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2019-11-14 DOI: 10.14502/tekstilec2019.62.232-241
Car Ajda, Bračko Sabina
We frequently need to compare two or more colours, and we can rely only on the colour impression from our memory. Colours are not stored in our memories in their actual state and they can gradually be erased. This paper addresses the subject of short-term colour memory. The approach is based on an experiment where subjects observed a given colour for a certain period of time. The purpose of the research was to determine the relation between the reference colour, time delay and the accuracy in recalling of the colour from the subject’s memory. The colours studied in the research were presented with no association to bodies, shapes or textures. The main variables in the observing conditions were the basic colour parameters which defi ne the colour, i.e. hue, saturation and brightness. The analysis of the fi nal results showed that colour is not stored in our memories correctly and that it loses its basic parameters after 10 s. As the time delay increases, the accuracy of the colour impression in our memory diminishes. Colour is stored in our memory as clearer and more saturated. Bright colours are remembered as even brighter, while dark colours are stored as darker. The sensation of hue is generally stored very precisely, while the deviation in hue depends on the observed colour.
我们经常需要比较两种或两种以上的颜色,我们只能依靠记忆中的颜色印象。颜色不会以它们的实际状态储存在我们的记忆中,它们可以逐渐被抹去。本文讨论了短期色彩记忆的问题。这种方法是基于一项实验,实验对象在一段时间内观察一种特定的颜色。该研究的目的是确定参考颜色、时间延迟和受试者回忆颜色准确性之间的关系。研究中所研究的颜色与身体、形状或纹理没有联系。观测条件中的主要变量是定义颜色的基本颜色参数,即色调、饱和度和亮度。对最终结果的分析表明,颜色不能正确地存储在我们的记忆中,并且在10秒后它会失去其基本参数。随着时间延迟的增加,我们记忆中颜色印象的准确性就会降低。在我们的记忆中,颜色是更清晰、更饱和的。明亮的颜色在记忆中更亮,而暗的颜色在记忆中更暗。色相的感觉通常是非常精确地储存起来的,而色相的偏差则取决于所观察到的颜色。
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引用次数: 1
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