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Influence of Humidity on the Electric Resistivity of Leather: Mathematical Modelling 湿度对皮革电阻率的影响:数学模型
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-04 DOI: 10.14502/tekstilec.65.2022097
G. De Mey, I. Kazani, M. Hylli, P. Berberi
A mathematical model is presented to simulate the electric resistivity of leather samples as a function of humidity. It will be shown that absolute and not relative humidity is the crucial parameter. The model assumes that the leather includes channels that can absorb water from the surrounding environment. This effect primarily determines the electric conductivity of the leather samples. The theoretical results from the model are quite closely in line with experimental measurements.
提出了一个数学模型来模拟皮革样品的电阻率作为湿度的函数。结果表明,绝对湿度而非相对湿度是关键参数。该模型假设皮革包括可以吸收周围环境中水分的通道。这种效应主要决定了皮革样品的导电性。该模型的理论结果与实验测量结果非常吻合。
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引用次数: 0
Characterization of PAN-TiO2 Nanofiber Mats and their Application as Front Electrodes for Dye-sensitized Solar Cells PAN-TiO2纳米纤维垫的表征及其在染料敏化太阳能电池前电极中的应用
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-12-20 DOI: 10.14502/tekstilec.65.2022081
Marius Dotter, Lion Lukas Placke, J. L. Storck, Uwe Güth
In the context of the energy transition to renewables, the spotlight is on large systems connected to the power grid, but this also offers room for smaller, more specialized applications. Photovoltaics, in particular, offer the possibility of the self-sufficient supply of smaller electrical appliances on smaller scales. The idea of making previously unused surfaces usable is by no means new, and textiles such as backpacks, tent tarpaulins and other covers are particularly suitable for this purpose. In order to create a non-toxic and easily recyclable product, dye-sensitized solar cells (DSSC), which can be manufactured through electrospinning with a textile feel, are an attractive option here. Therefore, this paper investigates a needle electrospun nanofiber mat, whose spin solution contains polyacrylonitrile (PAN) dissolved in dimethyl sulfoxide (DMSO) as well es TiO2 nanoparticles. In addition to characterization, the nanofiber mat was dyed in a solution containing anthocyanins to later serve as a front electrode for a dye-sensitized solar cell. Although of lower efficiency, the DSSC provides stable results over two months of measurement.
在能源向可再生能源转型的背景下,人们关注的焦点是连接到电网的大型系统,但这也为更小、更专业的应用提供了空间。特别是光电,提供了在较小规模上自给自足供应较小电器的可能性。将以前未使用过的表面变为可用的想法并不新鲜,背包、帐篷油布和其他覆盖物等纺织品特别适合这一目的。为了创造一种无毒且易于回收的产品,染料敏化太阳能电池(DSSC)是一个有吸引力的选择,它可以通过静电纺丝制造,具有纺织品的感觉。因此,本文研究了一种针状静电纺丝纳米纤维垫,其纺丝溶液中含有溶解在二甲亚砜(DMSO)中的聚丙烯腈(PAN)和二氧化钛纳米粒子。除了表征外,纳米纤维垫在含有花青素的溶液中染色,随后用作染料敏化太阳能电池的前电极。虽然效率较低,但DSSC在两个月的测量中提供了稳定的结果。
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引用次数: 1
Use of Banana Peel in the Development of a Less Flammable Polyester Composite 香蕉皮在开发低可燃聚酯复合材料中的应用
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-12-14 DOI: 10.14502/tekstilec.65.2022074
Ferdausee Rahman Anannya, F. Afroz, G. Kibria, M. L. Rahman, Nasrin Jamine, M. Mahmud
This study attempted to produce a cheap polyester composite material using an agricultural waste banana peel in the structure. Banana fibre has been used in composites as reinforcements, but banana peel has never been used with polyester before. The possibility of improved thermal and flammability properties of a composite due to increased moisture in the structure, and the char-forming ability of the cellulosic part of banana peel or the production of highly flammable material due to the presence of carbohydrates in the structure were the assumptions. To tackle the second assumption, aluminium trihydrate (ATH) was added. The handmade composites showed a drastic drop in tensile strength from 38.02 MPa to 16.72 MPa due to a lack of chemical bonding between the constituents. The impact and flexural strength showed some improvement with the addition of banana peel, along with ATH, to record results of 10.92 kg/cm and 49 MPa, respectively, after the initial drop that occurred when only ATH was added. However, these results were still inferior to the properties of pure polyester. The results of flammability and thermal resistance matched the second assumption, as flame retardancy was kept under control by the presence of ATH. The absorbency properties remained almost unaffected.
本研究试图在结构中使用农业废弃香蕉皮来生产一种廉价的聚酯复合材料。香蕉纤维在复合材料中用作增强材料,但香蕉皮以前从未与聚酯一起使用过。由于结构中的水分增加,复合材料的热性能和可燃性得到改善的可能性,以及香蕉皮的纤维素部分的成炭能力或由于结构中存在碳水化合物而产生高度可燃材料的可能性是假设。为了解决第二个假设,加入了三水合铝(ATH)。复合材料的抗拉强度从38.02 MPa急剧下降到16.72 MPa,主要是由于组分之间缺乏化学键合。与仅添加ATH时相比,添加香蕉皮和ATH后,冲击强度和弯曲强度有所提高,分别达到10.92 kg/cm和49 MPa。然而,这些结果仍然不如纯聚酯的性能。可燃性和耐热性的结果符合第二种假设,因为阻燃性是由ATH的存在控制的。吸收性能几乎未受影响。
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引用次数: 2
Fastness Improvement of a Crystalline Liquid Thermochromic Print on Cotton Fabric by the Application of Silica Nanoparticles from Rice-Husk 稻壳二氧化硅纳米颗粒应用于棉织物上提高结晶液体热致变色印花牢度
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-11-29 DOI: 10.14502/tekstilec.65.2022061
Jantera Sekar Tirta, Hoerudin, Ida Nuramdhani
Most commercially available thermochromic dyes are not resistant to washing and rubbing when applied to textile materials. This is due to their low affinity for fibre. The addition of silica extracted from rice husk ash using the sol-gel method was performed to improve colour fastness and maintain the stability of thermochromic dyes printed on cotton fabrics. The rice husks used in this study were derived from the Baroma rice variety with silica content in ash and silica gel of 97.05% and 99.20%. The morphological structures and particle sizes of the silica obtained were analysed using a scanning electron microscope (SEM) and particle size analyser (PSA). The particle sizes of the silica product, thermochromic dye and silica-dye mixture were 53.64–60.66 nm, 2.603 nm and 5.827 nm, respectively. The printing process of silica: the dye mixture was applied to cotton fabric in a ratio of 1:1. Fluid of silica: the dye showed good stability until the seventh day of observation. Colour fastness to washing assessed using a staining scale was better with the addition of silica than without silica, i.e. 3–4 in the first washing and 3 in the third washing. Similarly, fastness to rubbing was also better with the addition of silica, i.e. 3–4 dry rubbings and 3 wet rubbings. Moreover, the combination of silica, binder, PDMS and dye (in a ratio of 1:1:1:1) gave the best colour fastness to washing and rubbing.
大多数市售的热致变色染料在应用于纺织材料时不耐洗涤和摩擦。这是由于它们对纤维的亲和力低。采用溶胶-凝胶法从稻壳灰中提取二氧化硅,以提高棉织物热致变色染料的色牢度并保持其稳定性。本研究所用的稻壳来源于Baroma水稻品种,其灰分和硅胶中二氧化硅含量分别为97.05%和99.20%。使用扫描电子显微镜(SEM)和粒度分析仪(PSA)分析了所得二氧化硅的形态结构和粒度。二氧化硅产物、热致变色染料和二氧化硅染料混合物的粒径分别为53.64–60.66 nm、2.603 nm和5.827 nm。二氧化硅的印刷工艺:将染料混合物按1:1的比例应用于棉织物上。二氧化硅流体:直到观察的第七天,染料显示出良好的稳定性。使用染色量表评估的耐洗色牢度在添加二氧化硅的情况下比不添加二氧化硅的要好,即第一次洗涤时为3-4,第三次洗涤时3。同样,添加二氧化硅的耐摩擦牢度也更好,即3-4块干拓片和3块湿拓片。此外,二氧化硅、粘合剂、PDMS和染料的组合(比例为1:1:1:1)具有最佳的耐洗涤和耐摩擦色牢度。
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引用次数: 0
Basic Parameters of Medical Textile Materials for Removal and Retention of Exudate from Wounds 用于去除和保留伤口渗出物的医用纺织材料的基本参数
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-11-07 DOI: 10.14502/tekstilec.65.2022064
M. Riabchykov, L. Nazarchuk, O. Tkachuk
The article focuses on predicting the properties of textile materials intended for the treatment of wounds. The main requirements for medical textile materials for liquid transportation were identified. Exudate from wounds and therapeutic fluids from a dressing must move through material with the necessary efficiency. This ensures that unwanted substances are removed from the wound and the necessary moisture is maintained. These requirements can be provided using a mathematical model of the process. Such a model can be substantiated by solving a non-linear differential diffusion equation. For this purpose, the function of changing the moisture content inside a textile material was approximated using a polynomial function that satisfies the boundary conditions. This approximation made it possible to reduce the problem to the solution of an ordinary differential equation with respect to time. The obtained analytical solution of the change in moisture content with respect to time and coordinate includes two diffusion constants. The results of macro-experiments, together with analytical results, made it possible to determine the diffusion coefficient and the nonlinearity coefficient in an explicit form. The results made it possible to predict the moisture content at a given point of textile material at any given time, the total amount of absorbed liquid and the intensity of absorption. The resulting function can recommend the geometric and physical parameters of medical textile materials for the treatment of wounds with a given intensity of exudate sorption.
这篇文章的重点是预测用于治疗伤口的纺织材料的性能。确定了用于液体运输的医用纺织材料的主要要求。伤口渗出物和敷料中的治疗液必须以必要的效率通过材料。这样可以确保不需要的物质从伤口中去除,并保持必要的水分。这些要求可以使用过程的数学模型来提供。这样的模型可以通过求解非线性微分扩散方程来证实。为此,使用满足边界条件的多项式函数来近似改变纺织材料内部水分含量的函数。这种近似使得将问题简化为关于时间的常微分方程的解成为可能。所获得的水分含量随时间和坐标变化的解析解包括两个扩散常数。宏观实验的结果与分析结果一起,使以明确的形式确定扩散系数和非线性系数成为可能。这些结果使预测纺织材料在任何给定时间给定点的含水量、吸收液体的总量和吸收强度成为可能。所得到的函数可以推荐用于治疗具有给定渗出物吸附强度的伤口的医用织物材料的几何和物理参数。
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引用次数: 1
Physical-mechanical Properties of Aged Knitted Fabric for Swimsuits 老化针织泳装面料的物理力学性能
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-10-19 DOI: 10.14502/tekstilec.65.2022048
Katarina Krstović, V. M. Potočić Matković, Ivana Salopek Čubrić, G. Čubrić
The physical and mechanical properties of knitted fabrics for sports swimsuits are analysed in this paper. The knitted fabrics were experimentally aged in seawater and exposed to the sun continuously for 100 hours. Data were processed for nine knitted fabrics with the same raw material composition, polyamide and elastane in different proportions. The physical-mechanical properties of all nine samples before and after aging, as well as the drying rate and water absorption capacity, were examined. The results show that the properties of the knitted fabric changed in all samples. The sample with a higher elastane content (59% PA and 41% EL) is less sensitive to changes in mass per unit area and thickness after aging (−0.89% and 0.40%). The results of maximum wetted radius absorption water on the top and bottom of the knitted fabric, spreading speed absorption and drying time are shown. The results show that the values of the maximum wetted radius of absorbed water and the spreading speed increase for all samples, while the drying time for the knitted fabrics show different results.
本文对运动泳衣用针织物的物理力学性能进行了分析。将针织织物在海水中进行实验老化,并在阳光下连续暴露100小时。对九种具有相同原料组成、不同比例的聚酰胺和弹性纤维的针织织物的数据进行了处理。测试了所有9个样品在老化前后的物理力学性能,以及干燥速率和吸水能力。结果表明,所有样品的针织物性能都发生了变化。弹性纤维含量较高(59%PA和41%EL)的样品对老化后单位面积质量和厚度的变化不太敏感(-0.89%和0.40%)。显示了针织物顶部和底部的最大润湿半径吸水率、铺展速度吸收率和干燥时间的结果。结果表明,所有样品的最大吸水润湿半径和铺展速度都有所增加,而针织物的干燥时间则不同。
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引用次数: 0
The Influence of Water Hardness on the Agronomic Traits of Foreign Fibre Flax Varieties in the Republic of Croatia 水硬度对克罗地亚共和国外来纤维亚麻品种农艺性状的影响
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-10-19 DOI: 10.14502/tekstilec.65.2022031
J. Butorac, R. Brunšek, M. Pospišil, Z. Augustinović
The amount and quality of fibres depend on a whole range of factors, the most important being variety, agroecological conditions, agrotechnics and the degree of fibre flax plant maturity, the purpose for which flax is grown, retting and processing. The retting of fibre flax is the most complex stage in the processing of flax into fibre. The aim of this study was to gain knowledge about the acclimatization ability of foreign varieties that can potentially be adapted to climatic in Republic Croatia. Therefore, this paper presents the results of achieved agronomic traits (dry stem yield, dry stem after retting, total fibre yield, long fibre yield, share of total fibre and share of long fibre) of five foreign varieties of fibre flax. The selected varieties were retted in very soft, medium hard and hard water. Variety trials with fibre flax were set up over three years (2012–2014) at two locations (Zagreb) on anthropogenized eutric cambisol and (Križevci) on pseudogley on level terrain. The trials were carried out according to the RCBD in four replications. According to the results of the three-year research into the agronomic traits of fibre flax, significant differences were identified among the varieties studied. The varieties Agatha, Viola and Electra recorded the highest values of studied traits. Statistically significant differences were only recorded among different water hardness for long fibre yield in 2012 and share of total fibre in 2013 in Zagreb. The highest yields and share of fibres were recorded when the fibre flax was retted in very soft water.
纤维的数量和质量取决于一系列因素,最重要的是品种、农业生态条件、农业技术和纤维亚麻植物的成熟程度、亚麻的种植、加工和加工目的。亚麻纤维的沤制是亚麻加工成纤维过程中最复杂的一个阶段。这项研究的目的是获得有关外来品种的适应能力的知识,这些品种可能适应克罗地亚共和国的气候。因此,本文介绍了5个国外纤维亚麻品种的农艺性状(干茎产量、干茎烘干后产量、总纤维产量、长纤维产量、总纤维占比和长纤维占比)的测定结果。所选品种分别在极软、中硬和硬水中蒸炼。在为期三年(2012-2014)的两个地点(萨格勒布)进行了亚麻纤维的品种试验,分别是在人工种植的eutric cambisol (Križevci)和在平坦地形上的pseudodogley (Križevci)。根据RCBD进行了四次重复试验。对纤维亚麻的农艺性状进行了3年的研究,发现不同品种间存在显著差异。阿加莎、维奥拉和伊莱克特拉的研究性状值最高。在萨格勒布,只有在2012年长纤维产量和2013年总纤维份额的不同水硬度之间有统计学显著差异。当纤维亚麻在非常软的水中蒸煮时,纤维的产量和纤维份额最高。
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引用次数: 0
Investigating Properties of Electrically Conductive Textiles: A Review 导电纺织品性能研究综述
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-10-19 DOI: 10.14502/tekstilec.65.2022045
A. Shabani, M. Hylli, I. Kazani
Electro-conductive textiles are mostly fabrics that have conductive elements or electronics integrated into them to achieve electrical characteristics. They have acquired considerable attention in applications involving sensors, communications, heating textiles, entertainment, health care, safety etc. To produce electro-conductive textiles, several techniques, e.g. chemical treating with conductive polymers on various textile materials, or using different technologies, e.g. knitting, weaving, embroidery techniques to include conductive threads into fabric interconnections etc., are being used. Electro-conductive fabrics are flexible enough to be adapted to quick changes in any particular application, beginning with wearable purposes and sensing needs as specified by many different groups. The ability of electro-conductive textiles to conduct electricity is the most essential property they must possess. In addition, the applications that may be worn should have stable electrical, thermal and mechanical qualities. The most recent developments in the field of electro-conductive textiles represent the aim of this review, which analyses these properties, including the investigation of methods that are used to obtain conductive textiles, their electrical properties, thermal properties, and beyond that, the scientific methods that are used to measure and investigate electro-conductive textiles. We also focused on the textile materials used in studies, as well as the technologies used to make them conductive, which may be a guide for different interested groups for use in a variety of smart applications.
导电纺织品大多是具有导电元件或集成在其中的电子器件以实现电气特性的织物。它们在涉及传感器、通信、加热纺织品、娱乐、医疗保健、安全等的应用中获得了相当大的关注。为了生产导电纺织品,几种技术,例如在各种纺织品材料上用导电聚合物进行化学处理,或使用不同的技术,例如针织、编织、,将导电线包括在织物互连等中的刺绣技术正在被使用。导电织物具有足够的灵活性,可以适应任何特定应用中的快速变化,从许多不同群体指定的可穿戴目的和传感需求开始。导电纺织品的导电能力是它们必须具备的最基本的特性。此外,可能磨损的应用应具有稳定的电气、热和机械性能。导电纺织品领域的最新发展代表了本综述的目的,本综述分析了这些性能,包括研究用于获得导电纺织品的方法、它们的电性能、热性能,以及除此之外,用于测量和研究导电纺织品的科学方法。我们还重点介绍了研究中使用的纺织材料,以及用于使其导电的技术,这可能会为不同兴趣群体在各种智能应用中的使用提供指导。
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引用次数: 1
Filtration in Pharmaceutical Industries and Role of Textile 过滤在制药工业和纺织中的作用
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-10-19 DOI: 10.14502/tekstilec.65.2022036
Akhtarul Islam Amjad
Filtration is considered the keystone for clarification and control of contamination in pharmaceutical and biopharmaceutical manufacturing. From production to in-process to chemical and research laboratories to the purification of water for sterile and nonsterile products, all of which involve some form of filtration in order to achieve a good manufacturing practice (GMP). Textile materials possess a significant contribution to the pharmaceutical filtration system. Textile material in pharmaceutical filtration is used in the form of filter media or medium. Flexible in nature, large pore distribution and non-metallic properties of textile materials have led to widespread use as filter media for many years. In filtration processes, a proper selection of filter media/ membrane material is usually the most critical aspect for ensuring efficient separation. Generally, solid-liquid and solid-gas separation is done by the filter media. This paper emphasises solid-liquid filtration. Moreover, this paper reviews the water requirement, filtration processes and the role of textile in the filtration system of pharmaceutical industries. This paper also offers insight into the current market trend and COVID-19 impact on the pharmaceutical filtration industry. Furthermore, gathered information may be helpful to those studying and working in pharmaceutical engineering, filtration technology, and wastewater treatment and can get knowledge about filtration systems.
过滤被认为是制药和生物制药生产中澄清和控制污染的关键。从生产到过程中到化学和研究实验室,再到无菌和非无菌产品的水净化,所有这些都涉及某种形式的过滤,以实现良好的生产规范(GMP)。纺织材料对药物过滤系统有着重要的贡献。药物过滤中的纺织材料以过滤介质或介质的形式使用。纺织材料的柔性、大孔分布和非金属特性导致其作为过滤介质的广泛使用多年。在过滤过程中,正确选择过滤介质/膜材料通常是确保有效分离的最关键方面。通常,固液和固体气体的分离是通过过滤介质进行的。本文强调固液过滤。此外,本文还综述了纺织物在制药工业过滤系统中的用水量、过滤工艺和作用。本文还深入了解了当前的市场趋势以及新冠肺炎对制药过滤行业的影响。此外,收集的信息可能有助于那些在制药工程、过滤技术和废水处理领域学习和工作的人,并可以获得有关过滤系统的知识。
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引用次数: 0
Study of the Influence of the Surface Roughness of Knitted Fabrics from Natural Fibres on the Light Fastness of Their Colours 天然纤维针织物表面粗糙度对其颜色耐光性影响的研究
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2022-10-19 DOI: 10.14502/tekstilec.65.2022035
O. Semeshko, Yulia Saribyekova, T. Asaulyuk, Sergey Myasnykov, Irina Kulish, Ihor Horokhov
The article examines the influence of the surface properties of knitted fabrics from cotton and wool of various knitted structures on the light fastness of their colours. The surface properties of knitted fabrics of single plain, 1×1 rib and French piqué knitted structures were evaluated by determining their roughness using a non-contact optical method for processing digital images of the knitted fabric’s surface. The roughness profiles of the corresponding knitted fabric samples were obtained, and the main indicators of surface roughness were calculated: the profile height at ten points Rz and the arithmetic mean profile deviation Ra . Cotton knitted fabrics were dyed with the Bezaktiv Cosmos dye brand, which are bifunctional reactive dyes with monochlorotriazine / vinyl sulfone active groups, and wool knitted fabrics were dyed with acid dyes. The light fastness of the samples was evaluated after exposure to the Light Fastness Tester (Mercury-Tungsten Lamp) RF 1201 BS (REFOND) with a PCE-TCR 200 colorimeter. Colour measurements were averaged for each sample. Total colour difference (dE) was measured on the dyed cotton knitted fabrics samples after light exposure. According to the obtained roughness profiles of cotton and wool knitted fabrics, it can be concluded that the studied knitted fabrics are characterized by different roughness, which depends on their knitted structures. At the same time, a relationship was found between an increase in the roughness of knitted fabrics and the photodestruction of colours by reactive and acid dyes on cotton and wool knitted fabrics, respectively. The results show that the surface structure of knitted fabrics, that is the knitted structure, impacts the process of colour photodestruction and that the amount of dye that has undergone photodestruction increases with the increasing surface roughness of the knitted fabric.
本文研究了不同针织结构的棉、毛针织物的表面性能对其耐光牢度的影响。采用非接触光学方法处理针织物表面的数字图像,通过测定其粗糙度,评估了单层平纹、1×1罗纹和法式皮克针织物的表面性能。获得了相应针织物样品的粗糙度轮廓,并计算了表面粗糙度的主要指标:十点处的轮廓高度Rz和算术平均轮廓偏差Ra。棉针织物用Bezaktiv Cosmos染料品牌染色,这是一种具有单氯三嗪/乙烯基砜活性基团的双功能活性染料,羊毛针织物用酸性染料染色。样品的耐光性在暴露于具有PCE-TCR 200色度计的耐光度测试仪(汞灯)RF 1201 BS(REFOND)之后进行评估。对每个样品的颜色测量值取平均值。测定了染色棉针织物样品在光照后的总色差(dE)。根据所获得的棉和毛针织物的粗糙度分布,可以得出结论,所研究的针织物具有不同的粗糙度,这取决于它们的针织结构。同时,发现针织物粗糙度的增加与棉针织物和羊毛针织物上活性染料和酸性染料对颜色的光破坏之间存在关系。结果表明,针织物的表面结构,即针织结构,会影响颜色的光分解过程,并且经过光分解的染料量随着针织物表面粗糙度的增加而增加。
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引用次数: 0
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