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Adhesion and Stab-resistant Properties of FDM-printed Polymer/Textile Composites fdm打印聚合物/纺织复合材料的粘接和抗刺性能
Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-09-13 DOI: 10.14502/tekstilec.66.2023050
Siver Cakar, Andrea Ehrmann
Stab-resistant clothing has been used for centuries by soldiers. Today, it is also used by policemen and other people in dangerous jobs or situations. While chain-mail or metal inserts in protective vests are heavy and uncomfortable, lightweight and bendable alternatives are currently the subject of investigation. Special textile fabrics offer a certain level of stab-resistance that can be improved by different coatings. In this study, we investigated composites of different flexible 3D printing materials, used for the fused deposition modelling (FDM) technique, on woven fabrics. Besides the adhesion between both parts of these composites, the quasi-static stab-resistant properties were investigated and compared with those of pure textile fabrics and 3D prints, respectively.
几个世纪以来,士兵们一直穿着防刺服。今天,警察和其他从事危险工作或情况的人也使用它。虽然防护背心中的锁子甲或金属嵌件既笨重又不舒服,但目前正在研究轻便且可弯曲的替代品。特殊的纺织织物提供一定程度的抗刺性,可以通过不同的涂层来改善。在这项研究中,我们研究了不同柔性3D打印材料的复合材料,用于机织织物的熔融沉积建模(FDM)技术。研究了复合材料的准静态抗刺性能,并分别与纯纺织织物和3D打印材料进行了比较。
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引用次数: 0
TiO2 and ZnO as Advanced Photocatalysts for Effective Dye Degradation in Textile Wastewater 二氧化钛和氧化锌作为纺织废水染料有效降解的高级光催化剂
Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-08-31 DOI: 10.14502/tekstilec.66.2023045
Barbara Simončič, Dominika Glažar
Textile wastewater, which consist of a complex mixture of synthetic dyes and other organic and inorganic compounds derived from various wet chemical textile processes, can have a harmful effect on the environment; therefore, it must be properly treated before being discharged into municipal wastewater treatment plants and natural water bodies. In this scientific review, the main physical, chemical and biological processes for the removal of dyes from textile wastewater are presented, focusing on photocatalysis, which is a promising advanced oxidation process. The mechanism of photocatalysis is described and the methods used to determine the efficiency of photocatalytic degradation of dyes are presented. Recent studies involving single photocatalytic treatments of real textile wastewaters in the presence of TiO2 and ZnO as catalysts are presented. The advantages of combined processes of photocatalysis in conjunction with other chemical, physical and biological treatments to increase the efficiency of wastewater treatment are discussed. Accordingly, photocatalysis combined with H2O2, photocatalytic ozonation, a hybrid system of photocatalysis and membrane filtration, and coupled photocatalytic-biological processes are described.
纺织废水由各种湿化学纺织工艺产生的合成染料和其他有机和无机化合物的复杂混合物组成,可能对环境产生有害影响;因此,在排放到城市污水处理厂和自然水体之前,必须进行适当的处理。本文综述了纺织废水染料脱除的主要物理、化学和生物工艺,重点介绍了光催化脱除染料是一种很有前途的高级氧化工艺。介绍了光催化降解染料的机理和测定光催化降解效率的方法。介绍了以TiO2和ZnO为催化剂对纺织废水进行单次光催化处理的最新研究进展。讨论了光催化与其它化学、物理和生物处理相结合提高废水处理效率的优点。据此,介绍了光催化与H2O2结合、光催化臭氧化、光催化与膜过滤的混合系统以及光催化与生物耦合过程。
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引用次数: 0
Investigating the Effect of Knot Configuration and Suture Diameter on the Knot Performance of Silk Sutures 研究结型和缝线直径对丝线打结性能的影响
Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-08-28 DOI: 10.14502/tekstilec.66.2023028
S. Natarajan, V. Ramesh Babu, S. Ariharasudhan, P. Chandrasekaran, S. Sundaresan
Knot configurations serve as the foundation for postoperative tissue repair. Loosening surgical knots during or after tying might lead to an unsuccessful suture and compromise the outcome. This investigation was car­ried out to study the mechanical properties of knotted silk sutures that are made from braided structures with three different diameters. A maximum tensile strength (33.24 N) and minimum breaking elongation (15%) of dry suture, maximum tensile strength (22.6 N) and minimum breaking elongation (13.6%) of wet suture were achieved with five throws and a diameter of 0.3 mm with surgeon’s square knot.
结结构是术后组织修复的基础。在打结过程中或打结后松开手术结可能导致缝合不成功并影响结果。本文研究了由三种不同直径的编织结构制成的结丝缝合线的力学性能。干缝线的最大抗拉强度为33.24 N,最小断裂伸长率为15%;湿缝线的最大抗拉强度为22.6 N,最小断裂伸长率为13.6%。
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引用次数: 0
3D Printing on Textiles – Overview of Research on Adhesion to Woven Fabrics 纺织品上的3D打印——机织织物附着力研究综述
Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-08-18 DOI: 10.14502/tekstilec.66.2023055
Tanja Nuša Kočevar
3D printing on textiles has great potential to influence developments in various industries. It enables the production of new, potentially personalised products in areas such as technical textiles, protective clothing, medical products, fashion, textile and interior design. 3D printing can also contribute to waste-free production processes. In the method of 3D printing on textiles, the material is applied directly to the textile substrate to create 3D objects, patterns or designs on the surface. The fused deposition modelling (FDM) technology, where thermoplastic filaments are extruded and deposited in thin layers based on a 3D model, is widely used for this purpose. A precise control of factors such as temperature and speed is essential in FDM to regulate the flow of polymer material during the printing process. The most commonly used polymer for 3D printing on textiles using FDM is polylactic acid (PLA). Acrylonitrile butadiene styrene (ABS) is another widely used material, known for its low shrinkage rate and high printing accuracy, while thermoplastic polyurethane (TPU) is used due to its exceptional mechanical properties, e.g. tensile strength, flexibility, durability and corrosion resistance. Good adhesion between 3D printed objects and the textile surface is essential for the production of quality products. Adhesion depends on various factors, e.g. textile properties, printing parameters and the type of polymer used. The composition of the woven fabric, including the areal density, warp and weft density, yarn count, fabric thickness and weave pattern, significantly affects the adhesion strength of the 3D printed polymer. When considering double weaves, which allow different materials in the upper and lower layers, better adhesion properties are found than at single weaves. A cross-sectional analysis revealed that the polymer penetrates deeper into a double-woven fabric, resulting in improved adhesion. In general, the study highlights the advantages of double weaves for 3D printing applications on textiles.
纺织品上的3D打印具有巨大的潜力,可以影响各个行业的发展。它能够在技术纺织品、防护服、医疗产品、时装、纺织品和室内设计等领域生产新的、可能个性化的产品。3D打印还有助于实现零浪费的生产过程。在纺织品上的3D打印方法中,将材料直接应用于纺织品基材上,在表面上创建3D物体、图案或设计。熔融沉积建模(FDM)技术被广泛用于这一目的,其中热塑性长丝被挤出并沉积在基于3D模型的薄层中。在FDM中,精确控制温度和速度等因素对于调节打印过程中聚合物材料的流动至关重要。使用FDM在纺织品上进行3D打印最常用的聚合物是聚乳酸(PLA)。丙烯腈-丁二烯-苯乙烯(ABS)是另一种广泛使用的材料,以其低收缩率和高印刷精度而闻名,而热塑性聚氨酯(TPU)因其卓越的机械性能而被使用,例如拉伸强度,柔韧性,耐久性和耐腐蚀性。3D打印对象与纺织品表面之间良好的附着力对于生产高质量的产品至关重要。附着力取决于各种因素,如纺织性能、印刷参数和所用聚合物的类型。机织织物的组成,包括面密度、经纬密度、纱线支数、织物厚度和编织图案,对3D打印聚合物的粘附强度有显著影响。当考虑双层编织时,它允许不同的材料在上层和下层,发现比单编织更好的粘合性能。横截面分析表明,聚合物可以深入渗透到双层织物中,从而提高附着力。总的来说,该研究强调了双编织在纺织品上3D打印应用的优势。
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引用次数: 0
Study on Effect of Consumer Age, Family Income and Family Size on Fast Fashion Consumption Pattern 消费者年龄、家庭收入和家庭规模对快时尚消费模式的影响研究
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-07-17 DOI: 10.14502/tekstilec.66.2022100
Sushil Kumar Bishnoi, R. Guru
The aim of the study was to analyse the impact of various consumer attributes on the fast fashion consumption pattern. The effect of consumer age, family income and family size on the percentage of monthly income spent on clothing and percentage of monthly clothing consumption spent on fast fashion by consumers in NCR (National Capital Region) of India was studied in this research. Causal research was employed in this study. Correlations among the variables were established using the response surface methodology (Box-Behnken experimental design) to understand whether the impact is significant or not. Control factors, studied at 3 levels of variation, were age, monthly family income and family size. The responses for the experiment were the percentage of monthly income (per person) spent on clothing and the percentage of monthly clothing consumption spent on fast fashion. The study revealed that age and monthly family income have a strong influence on the percentage of monthly income spent on clothing, while family size has a negligible or no effect on the percentage of monthly income spent on clothing. It was also found that age, monthly family income and family size have a strong influence on the percentage of monthly clothing consumption spent on fast fashion. The demand for fast fashion and clothing is rising at a very high rate, which has made it hard for retail brands and apparel manufacturers to meet the consumer expectations. The analysis of consumer behaviour provides the advantage to fashion brands in anticipating and meeting consumer demands in a more efficient manner to create brand loyalty.
本研究的目的是分析各种消费者属性对快时尚消费模式的影响。本研究研究研究了印度NCR(国家首都地区)消费者年龄、家庭收入和家庭规模对消费者每月用于服装的收入百分比和每月用于快时尚的服装消费百分比的影响。本研究采用因果关系研究。使用响应面方法(Box-Behnken实验设计)建立变量之间的相关性,以了解影响是否显著。在3个变异水平上研究的控制因素是年龄、家庭月收入和家庭规模。实验的答案是每月收入(每人)在服装上的支出百分比和每月服装消费在快时尚上的支出比例。研究表明,年龄和家庭月收入对月收入在服装上的支出比例有很大影响,而家庭规模对月收入的服装支出比例几乎没有影响。研究还发现,年龄、家庭月收入和家庭规模对每月服装消费在快时尚上的比例有很大影响。对快时尚和服装的需求正在以非常高的速度增长,这使得零售品牌和服装制造商很难满足消费者的期望。对消费者行为的分析为时尚品牌提供了优势,可以更有效地预测和满足消费者需求,从而创造品牌忠诚度。
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引用次数: 0
Tailoring of multifunctional cotton fabric by embedding a TiO2+ZnO composite into a chitosan matrix 壳聚糖基包埋TiO2+ZnO复合材料对多功能棉织物的裁剪
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-07-07 DOI: 10.14502/tekstilec.66.2023049
B. Tomšič, Špela Bajrič, Kaja Cergonja, Gracija Čepič, Ana Gerl, Egshig Ladislav Varga, Marina Panoska, Svjetlana Peulić, Jasna Skoko, M. Gorjanc, B. Simončič
The use of nanomaterials to functionalise textiles offers new opportunities for chemical modification of textile fibres’ surfaces to achieve multifunctional protective properties. In this study, novel coatings were tailored on cotton fabric by embedding a mixture of TiO2 and ZnO nanoparticles (NPs) of different molar ratios into a chitosan polymer matrix. The excitation energies of the TiO2+ZnO composites generated in the coatings ranged from 3.20 eV to 3.25 eV, indicating that the photocatalytic performance of the functionalised cotton was driven by UV light. The presence of TiO2+ZnO composites increased the UV protection factor (UPF) of the cotton fabric from 4.2 for the untreated sample to 15–21 for the functionalised samples. The UPF values of the coatings slightly decreased after repeated washing. The ZnO in the TiO2+ZnO composites conferred biocidal activity to the coatings, which were resistant to washing at higher ZnO concentrations. In addition, the TiO2 in the TiO2+ZnO composites was responsible for the enhanced photocatalytic self-cleaning of the functionalised cotton, which was observed during the initial period of illumination at lower ZnO concentrations in the composite. The main advantage of these TiO2+ZnO composite coatings is their multifunctionality, which cannot be provided by single-component TiO2 or ZnO coatings. Moreover, these coatings have wide-ranging practical applications, as they were composed of commercially available nanomaterials and were applied using conventional pad–dry–cure equipment.
利用纳米材料功能化纺织品,为纺织纤维表面的化学改性提供了新的机会,从而实现多功能防护性能。在本研究中,通过将不同摩尔比的TiO2和ZnO纳米粒子(NPs)的混合物包埋在壳聚糖聚合物基体中,在棉织物上定制了新型涂层。TiO2+ZnO复合材料的激发能在3.20 eV ~ 3.25 eV之间,表明功能化棉的光催化性能是由紫外光驱动的。TiO2+ZnO复合材料的存在使棉织物的UV防护系数(UPF)从未处理样品的4.2提高到功能化样品的15-21。反复洗涤后,涂层的UPF值略有下降。TiO2+ZnO复合材料中的氧化锌使涂层具有良好的杀菌活性,耐高浓度氧化锌的洗涤。此外,TiO2+ZnO复合材料中的TiO2负责增强功能化棉花的光催化自清洁,这是在复合材料中较低ZnO浓度的初始照明期间观察到的。这些TiO2+ZnO复合涂层的主要优点是其多功能性,这是单组分TiO2或ZnO涂层所不能提供的。此外,这些涂层具有广泛的实际应用,因为它们由市售的纳米材料组成,并使用传统的垫干固化设备进行应用。
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引用次数: 0
Investigation of Bleaching of Cotton Fabrics with UV-TiO2 UV-TiO2漂白棉织物的研究
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-06-28 DOI: 10.14502/tekstilec.66.2023019
S. Eren, Aliye Akarsu Özenç
Titanium dioxide exhibits photocatalytic properties under ultraviolet (UV) irradiation. In this study, an environmentally friendly, fast and efficient technique for bleaching cotton fabrics is presented, utilising the photocatalytic property of TiO2. Raw cotton fabric samples were treated with TiO2-containing and TiO2-free treatment solutions (hydrogen peroxide and sodium hydroxide) under UV irradiation in order to bleach the samples. The results showed that cotton fabrics treated with TiO2 were bleached satisfactorily without severe strength loss.
二氧化钛在紫外线(UV)照射下表现出光催化性能。在这项研究中,提出了一种环保、快速、高效的棉织物漂白技术,利用TiO2的光催化性能。在紫外线照射下用含TiO2和不含TiO2的处理溶液(过氧化氢和氢氧化钠)处理原棉织物样品,以漂白样品。结果表明,经TiO2处理的棉织物漂白效果良好,强度没有严重损失。
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引用次数: 0
Antimicrobial Active Chitosan-Based Cotton Yarns: Effect of Chitosan Solution Concentration 壳聚糖溶液浓度对抗菌活性棉纱的影响
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-06-28 DOI: 10.14502/tekstilec.66.2023021
Emilija Toshikj, O. Petrovski, M. Petrovska, I. Jordanov
Using the exhaustion-pad-dry-rinse method, chitosan was applied to alkaline-scoured and bleached cotton yarns in a solution with concentrations ranging from 0.2–1% to achieve good antimicrobial activity against the bacteria Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive). Studied samples were also assessed by measuring the amount of introduced chitosan, amount of accessible amino groups, mechanical properties, whiteness index and the b* colour coordinate. Alkaline-scoured and bleached cotton yarns treated with all concentrations of the chitosan solution showed good antimicrobial activity against Escherichia coli and Staphylococcus aureus. Better antimicrobial activity was achieved against Escherichia coli. Increasing the concentration of chitosan solution deteriorated the mechanical properties of chitosan-treated cotton yarns. The optimal concentration of chitosan solution incorporated in the exhaustion phase to obtain chitosan-treated yarns with good antimicrobial activity and mechanical properties was 0.6%. The best antimicrobial treatment should minimise potential economic costs while providing functionality.
用壳聚糖在0.2 ~ 1%的浓度范围内对碱洗漂白棉纱进行处理,获得了良好的抑菌活性,对革兰氏阴性大肠杆菌和革兰氏阳性金黄色葡萄球菌具有良好的抑菌活性。通过壳聚糖的引入量、可及氨基的含量、力学性能、白度指数和b*色坐标对样品进行了评价。经不同浓度壳聚糖溶液处理的碱洗漂白棉纱对大肠杆菌和金黄色葡萄球菌均有良好的抑菌活性。对大肠杆菌具有较好的抑菌活性。增加壳聚糖溶液的浓度会使经壳聚糖处理的棉纱力学性能变差。壳聚糖溶液的最佳掺入浓度为0.6%,可获得具有良好抗菌活性和力学性能的壳聚糖处理纱线。最好的抗菌治疗应在提供功能性的同时最大限度地降低潜在的经济成本。
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引用次数: 1
Awareness of the Environmental Impact of Clothing Production and Consumption among Slovenian Women Customers 斯洛文尼亚妇女消费者对服装生产和消费对环境影响的认识
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-06-20 DOI: 10.14502/tekstilec.66.2023001
Tanja Sedej, Jani Toroš
The textile industry, where clothing industry has an important share, is one of the most polluting industries in the world, wherefore clothing consumption has a significant impact on the environment. The consumption of clothing has been increasing quickly along with the growth of the middle classes in developing nations and the fast-fashion business model. At the same time, consumers are becoming more and more aware of the importance of sustainability, and they have been changing their consumer behaviour accordingly. In this study, we focused our attention on awareness of the environmental impact of clothing production and consumption from the point of view of consumer knowledge, linked to different generations, marital statuses, living environments, family income and type of purchasing store. The study reveals a high-level consumer-evaluated knowledge regarding the effects of clothing production and consumption, but also still the purchasing preference in fast fashion stores.
纺织业是世界上污染最严重的行业之一,服装业在其中占有重要份额,因此服装消费对环境有着重大影响。随着发展中国家中产阶级的增长和快时尚商业模式的发展,服装消费一直在快速增长。与此同时,消费者越来越意识到可持续性的重要性,他们也在相应地改变自己的消费行为。在这项研究中,我们从消费者知识的角度,将注意力集中在对服装生产和消费的环境影响的认识上,这与不同的世代、婚姻状况、生活环境、家庭收入和购买商店的类型有关。该研究揭示了高水平的消费者对服装生产和消费影响的评价知识,但仍然是快时尚商店的购买偏好。
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引用次数: 0
The Stability of the Chitosan Coating on Polyester Fabric in the Washing Process 壳聚糖涂层在涤纶织物洗涤过程中的稳定性
IF 0.7 Q3 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-06-16 DOI: 10.14502/tekstilec.66.2023010
T. Pušić, T. Kaurin, Marko Liplin, A. Budimir, M. Čurlin, K. Grgić, Ana Sutlović, J. Volmajer Valh
The sensitivity of chitosan to environmental conditions and processing conditions can stress its structure and cause degradation of this polymer on various application carriers. The stability of chitosan in a designed textile structure of standard polyester fabric with chitosan was analysed in a multiple washing process with a standard detergent by studying the properties before and after 10 washing cycles. The chitosan was coated on standard and alkali treated polyester fabrics. Washing was performed with an ECE A reference detergent at 60 °C according to the Standard protocol HRN EN ISO 6330 in 10 cycles. The washing stability of chitosan onto polyester fabrics was monitored by a staining test, zeta potential, breaking force, breaking elongation, pilling propensity, touch, whiteness, moisture transport, antimicrobial activity and morphological features. The staining test confirmed the wash stability of chitosan coated on alkali hydrolised polyester fabrics, while the chitosan coated on standard polyester fabric disappeared. Zeta potential proved to be the significant parameter for determining chitosan` stability. The tensile properties of fabric samples were harmonised with other characterisation parameters. Coating of polyester fabric with chitosan increased the elasticity of all samples. The antimicrobial activity of polyester fabrics coated with chitosan against Staphylococcus aureus was reduced by 20% after 10 washing cycles. All the characterisation parameters proved that polyester fabric as a chitosan carrier should be surface modified for designing a stable bioactive textile structure of chitosan and polyester.
壳聚糖对环境条件和加工条件的敏感性会影响其结构,并导致其在各种应用载体上的降解。通过研究10次洗涤前后的性能,用标准洗涤剂多次洗涤,分析了壳聚糖在设计的标准涤纶织物结构中的稳定性。将壳聚糖涂覆在标准和碱处理的涤纶织物上。根据标准方案HRN EN ISO 6330,用ECE A参考洗涤剂在60°C下进行10次洗涤。通过染色试验、zeta电位、断裂力、断裂伸长率、起球倾向、触感、白度、水分输送、抗菌活性和形态等指标监测壳聚糖在涤纶织物上的洗涤稳定性。染色试验证实了涂覆在碱水解聚酯织物上的壳聚糖的洗涤稳定性,而涂覆在标准聚酯织物上的壳聚糖则消失。Zeta电位是决定壳聚糖稳定性的重要参数。织物样品的拉伸性能与其他表征参数一致。用壳聚糖对涤纶织物进行涂层处理,提高了所有样品的弹性。经壳聚糖涂层处理的涤纶织物经过10次洗涤后,对金黄色葡萄球菌的抗菌活性降低了20%。所有的表征参数都表明,作为壳聚糖载体的聚酯织物需要进行表面改性,以设计稳定的壳聚糖和聚酯生物活性织物结构。
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引用次数: 1
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