Pub Date : 2021-08-31DOI: 10.21776/ub.jpacr.2021.010.02.569
E. Horozić, M. Ibišević, D. Husejnagić, Enida Karić, N. Hasić, Amina Hajdarević
In this study, metal complex of Copper(II) with a Schiff base derived from 2,2-dihydroxyindane-1,3-dione and 2-aminoethanoic acid were synthesized. The product are characterized by spectral methods. The antimicrobial activity was tested on reference bacterial strains and the antioxidant capacity was analyzed by using the DPPH and FRAP methods. The spectral data indicates that the Schiff base coordinates the Copper(II) as a tridentate ONO donor ligand. The compounds showed weaker antimicrobial activity on certain tested microorganisms. In vitro testing of antioxidant activity showed a significant reducing ability of the complex, as well as inhibitory activity against DPPH radicals.
{"title":"Spectral Analysis and In vitro Biological Activity of Cu(II) Complex with Tridentate ONO Schiff Base Ligand","authors":"E. Horozić, M. Ibišević, D. Husejnagić, Enida Karić, N. Hasić, Amina Hajdarević","doi":"10.21776/ub.jpacr.2021.010.02.569","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.02.569","url":null,"abstract":"In this study, metal complex of Copper(II) with a Schiff base derived from 2,2-dihydroxyindane-1,3-dione and 2-aminoethanoic acid were synthesized. The product are characterized by spectral methods. The antimicrobial activity was tested on reference bacterial strains and the antioxidant capacity was analyzed by using the DPPH and FRAP methods. The spectral data indicates that the Schiff base coordinates the Copper(II) as a tridentate ONO donor ligand. The compounds showed weaker antimicrobial activity on certain tested microorganisms. In vitro testing of antioxidant activity showed a significant reducing ability of the complex, as well as inhibitory activity against DPPH radicals.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"29 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86849551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-30DOI: 10.21776/ub.jpacr.2021.010.02.572
R. M. Iqbal, I. Susanti, Rahadian Abdul Rachman, Tri Agusta Pradana, E. P. Toepak
Dye is an important compound in textile industry. The famous dye for coloring of textile is methylene blue. Methylene blue degradation has been difficult when carried out naturally by microorganisms. The advanced oxidative process is a promising method to degrade methylene blue using semiconductor material TiO2 and its modification. The modification catalyst of TiO2 such as TiO2-N, TiO2/zeolite-NaY and TiO2-N/zeolite-NaY. These materials were synthesized by mixing TiO2 and urea, then followed by impregnation of the mixture to zeolite-NaY as support material. The materials have been synthesized then characterized by XRD, and FTIR. Degradation of methylene blue on the synthesized materials was tested under UV light for 5, 20, 30, 40, and 50 minutes. The results showed that the diffractogram of TiO-N/zeolite-NaY and TiO2/zeolite-Y has a similar spesific peak with TiO2 and zeolite-NaY. It indicates that the impregnation process was sucessfully. TiO2/zeolite-NaY and TiO2-N/zeolite-NaY also showed the excellent activity for degrading methylene blue, which reached up to 99% for 3 hours of reaction.
染料是纺织工业的重要原料。著名的纺织品染色染料是亚甲基蓝。当由微生物自然进行亚甲基蓝降解时，降解是困难的。利用半导体材料TiO2及其改性的先进氧化工艺是一种很有前途的降解亚甲基蓝的方法。TiO2的改性催化剂有TiO2- n、TiO2/沸石- nay和TiO2- n /沸石- nay。这些材料是通过将TiO2和尿素混合，然后将混合物浸渍到沸石- nay作为载体材料合成的。对材料进行了合成，并用XRD和FTIR对其进行了表征。在紫外光下测试合成材料对亚甲蓝的降解时间，分别为5、20、30、40和50分钟。结果表明:TiO2 - n /沸石- nay和TiO2/沸石- y的衍射图与TiO2和沸石- nay具有相似的特异峰;结果表明，浸渍工艺是成功的。TiO2/沸石- nay和TiO2- n /沸石- nay对亚甲基蓝的降解也表现出优异的活性，反应3小时降解率可达99%。
{"title":"Synthesis, Characterization, and Photocatalytic Activity of N-Doped TiO2/Zeolite-NaY for Methylene Blue Removal","authors":"R. M. Iqbal, I. Susanti, Rahadian Abdul Rachman, Tri Agusta Pradana, E. P. Toepak","doi":"10.21776/ub.jpacr.2021.010.02.572","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.02.572","url":null,"abstract":"Dye is an important compound in textile industry. The famous dye for coloring of textile is methylene blue. Methylene blue degradation has been difficult when carried out naturally by microorganisms. The advanced oxidative process is a promising method to degrade methylene blue using semiconductor material TiO2 and its modification. The modification catalyst of TiO2 such as TiO2-N, TiO2/zeolite-NaY and TiO2-N/zeolite-NaY. These materials were synthesized by mixing TiO2 and urea, then followed by impregnation of the mixture to zeolite-NaY as support material. The materials have been synthesized then characterized by XRD, and FTIR. Degradation of methylene blue on the synthesized materials was tested under UV light for 5, 20, 30, 40, and 50 minutes. The results showed that the diffractogram of TiO-N/zeolite-NaY and TiO2/zeolite-Y has a similar spesific peak with TiO2 and zeolite-NaY. It indicates that the impregnation process was sucessfully. TiO2/zeolite-NaY and TiO2-N/zeolite-NaY also showed the excellent activity for degrading methylene blue, which reached up to 99% for 3 hours of reaction.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78373510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-20DOI: 10.21776/ub.jpacr.2021.010.02.584
M. Muhaimin, Muhammad Irhash Shalihin, M. Latief
Premna serratifolia known as bebuas has long been used by Malay comunity for both food and traditional medicine. The most notable advantage of this plant is to heal woman after childbirth and to raise the notion that contains anti-inflammatory bioactive compounds. In this study, the hexane extract of bebuas was only contained steroids. Meanwhile the ethanol extract contained various secondary metabolites such as phenolics, alkaloids, flavonoids, steroids and saponins. The ethanol extract was further separated since the targeted compound isolate was an alkaloid. The isolate obtained was a yellow crystal which transformed to yellow oil after being exposed to air. The anti-inflammatory evaluation of the compound gave a result with a strong activity with ED50 = 4.06 mg/KgBW. Characterization by UV-Vis and FT-IR showed that the isolate’s spectra pattern had similarities with bufotenine. It revealed that the isolate shared the same basic skeleton with the bufotenine, especially the indole skeleton. Furthermore, it also shared the same physical form with bufotenine. These evidences strengthened the assumption that the isolate was an indole alkaloid.
{"title":"Anti-Inflammatory Activity of an Indole Alkaloid Isolated from Bebuas (Premna serratifolia)","authors":"M. Muhaimin, Muhammad Irhash Shalihin, M. Latief","doi":"10.21776/ub.jpacr.2021.010.02.584","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.02.584","url":null,"abstract":"Premna serratifolia known as bebuas has long been used by Malay comunity for both food and traditional medicine. The most notable advantage of this plant is to heal woman after childbirth and to raise the notion that contains anti-inflammatory bioactive compounds. In this study, the hexane extract of bebuas was only contained steroids. Meanwhile the ethanol extract contained various secondary metabolites such as phenolics, alkaloids, flavonoids, steroids and saponins. The ethanol extract was further separated since the targeted compound isolate was an alkaloid. The isolate obtained was a yellow crystal which transformed to yellow oil after being exposed to air. The anti-inflammatory evaluation of the compound gave a result with a strong activity with ED50 = 4.06 mg/KgBW. Characterization by UV-Vis and FT-IR showed that the isolate’s spectra pattern had similarities with bufotenine. It revealed that the isolate shared the same basic skeleton with the bufotenine, especially the indole skeleton. Furthermore, it also shared the same physical form with bufotenine. These evidences strengthened the assumption that the isolate was an indole alkaloid.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"41 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90640201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-20DOI: 10.21776/ub.jpacr.2021.010.02.544
K. Goroya, G. Abadi, Yoseph Alresawum Asresahegn
The present study aimed to determine concentration of heavy and trace metals (Fe, Cu, Mn, Zn, Co, Cd, Pb, As, and Hg) in honey by inductively coupled plasma optical emission spectrometry (ICP-OES). Samples passed through wet digestion methods following the optimum digestion condition by applying the reagents (30mL HNO3:30mL H2O2) at temperature of 270°C for 3 hours. The average concentrations of the metals are found in the range of 5.32-28.6 mg/kg for Fe, 0.24-0.749mg/kg for Cu, 0.627-4.401mg/kg Zn, 0.41-3.15mg/kg for Mn, 0.08-0.112 mg/kg for Co, 0.25-0.325mg/kg for Pb, 0.24-0.46mg/kg for As, ND-0.031mg/kg for Hg and 0.02-0.03mg/kg for Cd. This study shows that the honey in the studied area is a good sources of essential metals (Fe, Cu, Mn, Co and Zn) as they are found to be in the permissible limit. Moreover, the maximum concentration of the toxic metals determined in this work are below the level of toxicity as per the standard set by WHO/FAO.
{"title":"Determination of Heavy and Trace Metals in Honey Using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) in South Eastern Zone of Tigray Region, Northern Ethiopia","authors":"K. Goroya, G. Abadi, Yoseph Alresawum Asresahegn","doi":"10.21776/ub.jpacr.2021.010.02.544","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.02.544","url":null,"abstract":"The present study aimed to determine concentration of heavy and trace metals (Fe, Cu, Mn, Zn, Co, Cd, Pb, As, and Hg) in honey by inductively coupled plasma optical emission spectrometry (ICP-OES). Samples passed through wet digestion methods following the optimum digestion condition by applying the reagents (30mL HNO3:30mL H2O2) at temperature of 270°C for 3 hours. The average concentrations of the metals are found in the range of 5.32-28.6 mg/kg for Fe, 0.24-0.749mg/kg for Cu, 0.627-4.401mg/kg Zn, 0.41-3.15mg/kg for Mn, 0.08-0.112 mg/kg for Co, 0.25-0.325mg/kg for Pb, 0.24-0.46mg/kg for As, ND-0.031mg/kg for Hg and 0.02-0.03mg/kg for Cd. This study shows that the honey in the studied area is a good sources of essential metals (Fe, Cu, Mn, Co and Zn) as they are found to be in the permissible limit. Moreover, the maximum concentration of the toxic metals determined in this work are below the level of toxicity as per the standard set by WHO/FAO.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91185064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-20DOI: 10.21776/UB.JPACR.2021.010.02.551
Mentari Luthfika Dewi, T. M. Fakih, Resty Imfyani Sofyan
Tyrosinases are essential metal-containing enzymes in the biosynthesis of melanin, therefore responsible for pigmentation of the skin. The upregulation of tyrosinase enzyme activities leads to hyperpigmentation that will become a health problems and interfere psychosocially. Inhibition of tyrosinase enzyme activity, both competitive and non-competitive become widely developed for most anti hyperpigmentation agent. Natural antioxidants are one of the potential compounds for this purpose. Red grape seeds contain high levels of antioxidant compounds, such as procyanidin, prodelphinidin, and propelargonidin. In this research in silico studies, including molecular docking, molecular dynamics simulations, and toxicity predictions, were used to assess the activity of the three molecules of polyphenolic compounds on macromolecules of the tyrosinase enzyme. Molecular docking studies show that the compound propelargonidin has the highest affinity against the macromolecule of the tyrosinase enzyme, with a binding free energy value of −32.87 kJ/mol. These results were confirmed in molecular dynamics simulations that show strong interactions at the macromolecular active site of the tyrosinase enzyme. Toxicity prediction results show that the three polyphenolic compound molecules were classified in the High-Class Category, which shows that safety is not guaranteed, but is likely, not carcinogenic and nongenotoxic. Therefore, the compound propelargonidin is predicted to be able to interact strongly with the tyrosinase enzyme. The results in this research are useful for further study in the development of tyrosinase enzyme inhibitors.
{"title":"The Discovery of Tyrosinase Enzyme Inhibitors Activity from Polyphenolic Compounds in Red Grape Seeds through In Silico Study","authors":"Mentari Luthfika Dewi, T. M. Fakih, Resty Imfyani Sofyan","doi":"10.21776/UB.JPACR.2021.010.02.551","DOIUrl":"https://doi.org/10.21776/UB.JPACR.2021.010.02.551","url":null,"abstract":"Tyrosinases are essential metal-containing enzymes in the biosynthesis of melanin, therefore responsible for pigmentation of the skin. The upregulation of tyrosinase enzyme activities leads to hyperpigmentation that will become a health problems and interfere psychosocially. Inhibition of tyrosinase enzyme activity, both competitive and non-competitive become widely developed for most anti hyperpigmentation agent. Natural antioxidants are one of the potential compounds for this purpose. Red grape seeds contain high levels of antioxidant compounds, such as procyanidin, prodelphinidin, and propelargonidin. In this research in silico studies, including molecular docking, molecular dynamics simulations, and toxicity predictions, were used to assess the activity of the three molecules of polyphenolic compounds on macromolecules of the tyrosinase enzyme. Molecular docking studies show that the compound propelargonidin has the highest affinity against the macromolecule of the tyrosinase enzyme, with a binding free energy value of −32.87 kJ/mol. These results were confirmed in molecular dynamics simulations that show strong interactions at the macromolecular active site of the tyrosinase enzyme. Toxicity prediction results show that the three polyphenolic compound molecules were classified in the High-Class Category, which shows that safety is not guaranteed, but is likely, not carcinogenic and nongenotoxic. Therefore, the compound propelargonidin is predicted to be able to interact strongly with the tyrosinase enzyme. The results in this research are useful for further study in the development of tyrosinase enzyme inhibitors.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"9 1 1","pages":"104-112"},"PeriodicalIF":0.0,"publicationDate":"2021-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82844580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-20DOI: 10.21776/ub.jpacr.2021.010.02.483
Ernesta Wae, R. Tjahjanto, Diah Mardiana
Sea water as a raw material resources for the kitchen salt production, besides containing NaCl, has also containing other dissolved salts such as hygroscopic calcium and magnesium salts. The high content of other salts cause industrial NaCl has a low quality. This aim research was to find out the effect of seawater evaporation on NaCl content changes. Seawater obtained from Nggolonto, Nagekeo, NTT, was used with an initial volume of 200 mL, then it was concentrated in varying of final volume, i.e. 20, 23, 25, 27 and 29 mL. The NaCl content was calculated based on total chloride ion content, corrected toward magnesium and calcium ions content and the presence of sulphate anion. In addition, the chloride and magnesium also calcium ions content was analyzed volumetrically, while the sulphate anion was determined spectrophotometrically. The research result showed that NaCl content increase significantly up to 27 mL of final volume and was constantly afterward. Furthermore, the highest of NaCl content obtained from final volume of 29 mL was 96.01%. Nevertheless, comparing to SNI 06-0303-1989, its content was still below the standard of 98.5%.
{"title":"Study of Sodium Chloride Production Using Gradual Evaporation of Seawater from Nggolonio Sea, East Nusa Tenggara","authors":"Ernesta Wae, R. Tjahjanto, Diah Mardiana","doi":"10.21776/ub.jpacr.2021.010.02.483","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.02.483","url":null,"abstract":"Sea water as a raw material resources for the kitchen salt production, besides containing NaCl, has also containing other dissolved salts such as hygroscopic calcium and magnesium salts. The high content of other salts cause industrial NaCl has a low quality. This aim research was to find out the effect of seawater evaporation on NaCl content changes. Seawater obtained from Nggolonto, Nagekeo, NTT, was used with an initial volume of 200 mL, then it was concentrated in varying of final volume, i.e. 20, 23, 25, 27 and 29 mL. The NaCl content was calculated based on total chloride ion content, corrected toward magnesium and calcium ions content and the presence of sulphate anion. In addition, the chloride and magnesium also calcium ions content was analyzed volumetrically, while the sulphate anion was determined spectrophotometrically. The research result showed that NaCl content increase significantly up to 27 mL of final volume and was constantly afterward. Furthermore, the highest of NaCl content obtained from final volume of 29 mL was 96.01%. Nevertheless, comparing to SNI 06-0303-1989, its content was still below the standard of 98.5%.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"190 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74448486","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-16DOI: 10.21776/ub.jpacr.2021.010.01.571
A. Fadaei, T. Razavi
Surfactants are one of the most commonly found xenobiotics in municipal and industrial wastewater. The purpose of this study was to compare ultraviolet/ultrasonic (UV/US) and ultraviolet/zinc oxide (UV/ZnO) processes in the removal of LAS from aqueous media.In this study, a medium-pressure UV lamp (125 W), an ultrasonic device (400 W and 42 kHz), and ZnO nanoparticles (NPs) were used. The concentration of LAS was 0.5, 14, and 21 mg/L in all experiments. Contact time of 8, 16, and 24 minutes, pH of 3, 7, and 11, and NP concentrations of 50, 100, 150 mg/L were selected. Detergent extraction was performed using methylene blue active substances.The results showed that the efficiency of UV/US process in the removal of LAS was 89.35%, while the removal efficiency of UV/ZnO process was 81.27%. In both processes, the rate of detergent removal increased by elongating the contact time from 8 to 24 minutes. The efficiency of UV/US process in LAS removal was greater than that of the UV/ZnO process. The findings showed that the removal efficiency of UV/US process was directly correlated with pH, while it had an inverse correlation with the removal efficiency of UV/ZnO process.
{"title":"Comparison of the Efficiency of Ultraviolet/Ultrasonic (UV/US) and Ultraviolet/Zinc Oxide (UV/ZnO) Technologies as Advanced Oxidation Processes in the Removal of Linear Alkylbenzene Sulfonate (LAS), an Anionic Detergent, from Aqueous Media","authors":"A. Fadaei, T. Razavi","doi":"10.21776/ub.jpacr.2021.010.01.571","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.01.571","url":null,"abstract":"Surfactants are one of the most commonly found xenobiotics in municipal and industrial wastewater. The purpose of this study was to compare ultraviolet/ultrasonic (UV/US) and ultraviolet/zinc oxide (UV/ZnO) processes in the removal of LAS from aqueous media.In this study, a medium-pressure UV lamp (125 W), an ultrasonic device (400 W and 42 kHz), and ZnO nanoparticles (NPs) were used. The concentration of LAS was 0.5, 14, and 21 mg/L in all experiments. Contact time of 8, 16, and 24 minutes, pH of 3, 7, and 11, and NP concentrations of 50, 100, 150 mg/L were selected. Detergent extraction was performed using methylene blue active substances.The results showed that the efficiency of UV/US process in the removal of LAS was 89.35%, while the removal efficiency of UV/ZnO process was 81.27%. In both processes, the rate of detergent removal increased by elongating the contact time from 8 to 24 minutes. The efficiency of UV/US process in LAS removal was greater than that of the UV/ZnO process. The findings showed that the removal efficiency of UV/US process was directly correlated with pH, while it had an inverse correlation with the removal efficiency of UV/ZnO process.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74876597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-14DOI: 10.21776/ub.jpacr.2021.010.01.530
Dhimas Yudistira, D. Purwonugroho, T. Setianingsih
This study aims to determine the effect of sea sand modification with SDBS for adsorption of Fe3+. Sea sand was treated with 0.1 M HCl solution at 25oC. Organo-quartz was prepared at SDBS concentration of below, equal, and above the CMC value by shaking the mixture for 4 hours at 100 rpm. Characterization by FTIR spectrophotometry showed a change in the spectra pattern. The activation caused increasing of -OH silanol while modifications make them decrease. Characterization with SEM showed that the morphology of the sea sand was not uniform with irregular white chunks. The EDX results showed that the dominant elements were C (13.89% ± 10.86), O (40.48% ± 6.58), Si (16.51% ± 8.13), and Fe (11.68% ± 14.38). Adsorption was carried out using Fe3+ at 50 ppm. The Fe3+ analysis was conducted by AAS. The adsorption value by activated sea sand was 58.22% ± 7.23% whereas without treatment sea sand was 70.46% ± 5.54, and the modified sea sand was 53.24% ± 4.86. The lower adsorption is probably caused by the dissolved iron oxides in sea sand during activation.
本研究旨在确定SDBS改性海砂对Fe3+的吸附效果。用0.1 M HCl溶液在25℃下处理海砂。在SDBS浓度低于、等于和高于CMC值的条件下，在100 rpm下振荡4小时，制备有机石英。用FTIR分光光度法进行表征，发现光谱模式发生了变化。活化使-OH硅醇含量增加，修饰使-OH硅醇含量减少。SEM表征表明，海砂形貌不均匀，呈不规则白色块状。EDX结果显示，主要元素为C(13.89%±10.86)、O(40.48%±6.58)、Si(16.51%±8.13)和Fe(11.68%±14.38)。用50 ppm的Fe3+进行吸附。采用原子吸收光谱法进行Fe3+分析。活性海砂吸附值为58.22%±7.23%，未处理海砂吸附值为70.46%±5.54，改性海砂吸附值为53.24%±4.86。较低的吸附可能是由于活化过程中溶解在海砂中的氧化铁所致。
{"title":"Synthesis of Organo-Quartz from Lumajang Sea Sand Using Sodium Dodecyl Benzene Sulfonate (SDBS) Modificator for Adsorption of Fe3+","authors":"Dhimas Yudistira, D. Purwonugroho, T. Setianingsih","doi":"10.21776/ub.jpacr.2021.010.01.530","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.01.530","url":null,"abstract":"This study aims to determine the effect of sea sand modification with SDBS for adsorption of Fe3+. Sea sand was treated with 0.1 M HCl solution at 25oC. Organo-quartz was prepared at SDBS concentration of below, equal, and above the CMC value by shaking the mixture for 4 hours at 100 rpm. Characterization by FTIR spectrophotometry showed a change in the spectra pattern. The activation caused increasing of -OH silanol while modifications make them decrease. Characterization with SEM showed that the morphology of the sea sand was not uniform with irregular white chunks. The EDX results showed that the dominant elements were C (13.89% ± 10.86), O (40.48% ± 6.58), Si (16.51% ± 8.13), and Fe (11.68% ± 14.38). Adsorption was carried out using Fe3+ at 50 ppm. The Fe3+ analysis was conducted by AAS. The adsorption value by activated sea sand was 58.22% ± 7.23% whereas without treatment sea sand was 70.46% ± 5.54, and the modified sea sand was 53.24% ± 4.86. The lower adsorption is probably caused by the dissolved iron oxides in sea sand during activation.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"106 9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80073131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-14DOI: 10.21776/ub.jpacr.2021.010.01.562
Amal Rezka Putra, Khoirunnisa Fauziah Asyikin, Robertus Dwi Hendarto, A. Ariyanto, E. Lestari, S. Juliyanto, Ahsanal Fikri
Radiochemical purity testing of [153Sm]Sm-EDTMP usually uses the Thin Layer Chromatography method. The mobile phase used is a mixture of 25% ammonia and water. However, the lowest ratio of 25% ammonia in the mobile phase is unknown. Therefore, research related to the use of the lowest concentration in the radiochemical purity test of [153Sm]Sm-EDTMP is necessary. This research method includes labelling of EDTMP using Samarium-153, preparation of the mobile phase with variations in the concentration of 25% ammonia: water, radiochemical purity test and data analysis using t-test statistics. The results of this study are the concentration of 25% ammonia: water (1: 9) to (1: 200) still shows good separation with Rf of [153Sm]SmCl3 and [153Sm]Sm-EDTMP at 0.0, 1.0 respectively, whereas with a thinner concentration of ammonia indicates less optimal separation with Rf [153Sm]SmCl3 at 0.35 to 1.0. Comparison of concentrated ammonia concentrations of 1: 9 and dilute 1: 200 was performed using a statistical t-test. The results of the data analysis showed that the two methods were not significantly different, indicated by the t-value of 0.82 less than 2.78. The conclusion of this study is that the lowest concentration of 25% ammonia and water in the radiochemical purity test of [153Sm]Sm-EDTMP is 1: 200.
{"title":"The Use of Low Ammonia Concentration in the Radiochemical Purity Test of [153Sm]Sm-EDTMP by Using the Thin Layer Chromatography Method","authors":"Amal Rezka Putra, Khoirunnisa Fauziah Asyikin, Robertus Dwi Hendarto, A. Ariyanto, E. Lestari, S. Juliyanto, Ahsanal Fikri","doi":"10.21776/ub.jpacr.2021.010.01.562","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.01.562","url":null,"abstract":"Radiochemical purity testing of [153Sm]Sm-EDTMP usually uses the Thin Layer Chromatography method. The mobile phase used is a mixture of 25% ammonia and water. However, the lowest ratio of 25% ammonia in the mobile phase is unknown. Therefore, research related to the use of the lowest concentration in the radiochemical purity test of [153Sm]Sm-EDTMP is necessary. This research method includes labelling of EDTMP using Samarium-153, preparation of the mobile phase with variations in the concentration of 25% ammonia: water, radiochemical purity test and data analysis using t-test statistics. The results of this study are the concentration of 25% ammonia: water (1: 9) to (1: 200) still shows good separation with Rf of [153Sm]SmCl3 and [153Sm]Sm-EDTMP at 0.0, 1.0 respectively, whereas with a thinner concentration of ammonia indicates less optimal separation with Rf [153Sm]SmCl3 at 0.35 to 1.0. Comparison of concentrated ammonia concentrations of 1: 9 and dilute 1: 200 was performed using a statistical t-test. The results of the data analysis showed that the two methods were not significantly different, indicated by the t-value of 0.82 less than 2.78. The conclusion of this study is that the lowest concentration of 25% ammonia and water in the radiochemical purity test of [153Sm]Sm-EDTMP is 1: 200.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85437671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-14DOI: 10.21776/ub.jpacr.2021.010.01.577
Sarina Hanifah, Rusnadi Rusnadi, M. Amran
This work aims to study the removal of lead (II) from aqueous solutions with Ca-Alginate (CA) and Coffee-Calcium-Alginate (CCA). The coffee biomass were successfully prepared as the material to be encapsulated in calcium alginate. The characterization of the synthesized CA and CCA was performed using fourier transform infrared and scanning electron microscopy. The method used was batch study. Various factors which affected adsorption efficiency of lead (II) ions by CA and CCA, such as pH, agitation time, and adsorbent dose were investigated for determination of optimum experimental conditions. The result showed that CA and CCA had significant effects on adsorption of lead (ІІ) ions at pH = 4, agitation time of more than 120 min, and the adsorbent dose was 0.05 gram. Moreover, the Langmuir isotherm model showed that maximum adsorption capacity (qm) was 163.66 mg/g and 176.99 mg/g respectively for CA and CCA. The Langmuir isotherm was better described the adsorption equilibrium. Both of the adsorbent fitted to pseudo second order equations. These results demonstrated that CA and CCA show great potential to remove Pb(ІІ) ions from aqueous solutions.
{"title":"Coffee Biomass Encapsulated in Calcium Alginate as Material for Lead (II) Adsorption from Aqueous Solutions","authors":"Sarina Hanifah, Rusnadi Rusnadi, M. Amran","doi":"10.21776/ub.jpacr.2021.010.01.577","DOIUrl":"https://doi.org/10.21776/ub.jpacr.2021.010.01.577","url":null,"abstract":"This work aims to study the removal of lead (II) from aqueous solutions with Ca-Alginate (CA) and Coffee-Calcium-Alginate (CCA). The coffee biomass were successfully prepared as the material to be encapsulated in calcium alginate. The characterization of the synthesized CA and CCA was performed using fourier transform infrared and scanning electron microscopy. The method used was batch study. Various factors which affected adsorption efficiency of lead (II) ions by CA and CCA, such as pH, agitation time, and adsorbent dose were investigated for determination of optimum experimental conditions. The result showed that CA and CCA had significant effects on adsorption of lead (ІІ) ions at pH = 4, agitation time of more than 120 min, and the adsorbent dose was 0.05 gram. Moreover, the Langmuir isotherm model showed that maximum adsorption capacity (qm) was 163.66 mg/g and 176.99 mg/g respectively for CA and CCA. The Langmuir isotherm was better described the adsorption equilibrium. Both of the adsorbent fitted to pseudo second order equations. These results demonstrated that CA and CCA show great potential to remove Pb(ІІ) ions from aqueous solutions.","PeriodicalId":22728,"journal":{"name":"The Journal of Pure and Applied Chemistry Research","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74770415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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