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2008 17th IEEE International Symposium on the Applications of Ferroelectrics最新文献

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Time-resolved measurement of structural changes in lead zirconate titanate ceramics under cyclic electric fields 循环电场作用下锆钛酸铅陶瓷结构变化的时间分辨测量
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693914
A. Pramanick, J. Nino, Jacob L. Jones
In order to understand the structural changes in piezoelectric materials, under dynamic electric fields, time-resolved diffraction experiments with stroboscopic data collection techniques are becoming more popular. Uses of neutron and synchrotron X-ray facilities for such experiments have been recently reported. However, implementation of stroboscopic techniques on laboratory X-ray diffractometers is necessary to develop a more comprehensive understanding of time-resolved structural changes in these materials. Here the authors report the application of a stroboscopic data collection technique on a laboratory X-ray diffractometer for in situ characterization of non-180° domain switching in La-doped Pb(Zr0.52Ti0.48)O3 ceramics under dynamic electric fields. Further, the variation of macroscopic material response under dynamic fields of different amplitudes is compared with the degree of non-180° domain switching observed through time-resolved X-ray diffraction (XRD).
为了了解压电材料在动态电场作用下的结构变化,采用频闪数据采集技术的时间分辨衍射实验越来越受欢迎。使用中子和同步加速器x射线设备进行这类实验最近有报道。然而,在实验室x射线衍射仪上实施频闪技术对于更全面地了解这些材料的时间分辨结构变化是必要的。在这里,作者报告了在实验室x射线衍射仪上应用频闪仪数据收集技术来原位表征la掺杂Pb(Zr0.52Ti0.48)O3陶瓷在动态电场下的非180°畴切换。此外,通过时间分辨x射线衍射(XRD),比较了不同振幅动态场下材料宏观响应的变化与非180°域切换的程度。
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引用次数: 0
Fabrication of BiFeO3 capacitor structures with reduced leakage current 低漏电流BiFeO3电容器结构的制备
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693777
N. M. Murari, A. Kumar, R. Thomas, R. Katiyar
Multi layered metal-insulator-metal (MIM) structures with BiFeO3 (BFO) and Ba0.25Sr0.75TiO3 (BST) thin films were fabricated by chemical solution deposition. Crystalline structure of BFO was recognized as rhombohedral and was not influenced by the BST intermediate layer. Compared to the homogenous BFO, in the heterostructures, coercivity increased and saturation magnetization reduced. BST intermediate layer between the substrate and BFO layer resulted in the leakage current reduction by 3 orders of magnitude. The frequency and temperature dependent dielectric properties showed space charge accumulation between the layer of BST and BFO, and hence Maxwell-Wagner type dispersion.
采用化学溶液沉积法制备了具有BiFeO3 (BFO)和Ba0.25Sr0.75TiO3 (BST)薄膜的多层金属-绝缘体-金属(MIM)结构。BFO的晶体结构为菱形,不受BST中间层的影响。与均相BFO相比,异质结构中矫顽力增加,饱和磁化强度降低。衬底与BFO层之间的BST中间层使漏电流降低了3个数量级。频率和温度相关的介电性质表现为BST和BFO层之间的空间电荷积累,从而导致Maxwell-Wagner型色散。
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引用次数: 3
Low temperature preparation of PbTiO3 ultrathin films deposited by PbO gas phase reaction sputtering PbO气相反应溅射低温制备PbTiO3超薄膜
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693844
Jiyoon Kim, S. Buhlmann, Moonkyu Park, Yunseok Kim, Yong Kwan Kim
In silicon integrated circuit technology, ferroelectric thin films have been importantly studied since they are the most promising materials for future non-volatile memory devices due to their fast switching speed and long-term retention time. PbTiO3 (PTO) is the one of the most suitable material for non-volatile memory devices, because it has the highest spontaneous polarization (PS) value. The subject of size effect on ferroelecticity has been of highest interest for many years to overcome the limit of memory density. As the ferroelectric film thickness decrease, it is possible to make small domain size of penetrating the film thickness direction. Another issue of ferroelectric thin film is reducing the preparation temperature, because the high temperature during the fabrication might degrade the bottom electrode, and leads to interface reaction between the ferroelectric film and Si substrate. To make thin and smooth PTO films, TiO2 was deposited on the Pt bottom electrode, and PbO gas phase reaction was carried out by static and rotation mode at a temperature as low as 450�??. TiO2 seed layer increase the number of active sites for PTO nucleation and, hence, allows crystallization of perovskite phase. To prepare PTO films below TC (493�??), PbO deposition power and target to substrate distance were controlled. As the temperature decreases, PbO layer was remained on the PTO surface, and it degraded the ferroelectric property of PTO films. However, it is possible to eliminate PbO layer on PTO films by reducing the PbO deposition power and increasing the target to sample distance until 100 mm. Zr buffer layer was inserted between PTO film and Pt bottom electrode to enhance the leakage property, and layer-by-layer preparation method was adopted to exclude the un-reacted TiO2. These methods enhance the switching property of PTO films. In summary, thin and smooth PTO ultra-thin films successfully deposited using the gas phase reaction sputtering below TC, and this method suggest us the possibility for high-density memory device.
在硅集成电路技术中,铁电薄膜由于其快速的开关速度和长期的保持时间而成为未来非易失性存储器件最有前途的材料,因此得到了重要的研究。PbTiO3 (PTO)具有最高的自发极化(PS)值,是最适合用于非易失性存储器件的材料之一。为了克服记忆密度的限制,铁电性的尺寸效应是多年来备受关注的课题。随着铁电薄膜厚度的减小,有可能使穿透薄膜厚度方向的畴尺寸变小。铁电薄膜的另一个问题是降低制备温度,因为制备过程中的高温可能会降解底电极,并导致铁电薄膜与Si衬底之间的界面反应。为了制备薄而光滑的PTO薄膜,在Pt底电极上沉积TiO2,在低至450℃的温度下通过静态和旋转方式进行PbO气相反应。TiO2种子层增加了PTO成核的活性位点数量,从而允许钙钛矿相的结晶。为了制备低于TC(493℃)的PTO薄膜,控制了PbO的沉积功率和靶与衬底的距离。随着温度的降低,PbO层残留在PTO表面,降低了PTO薄膜的铁电性能。然而,通过降低PbO沉积功率和增加靶样距离至100 mm,可以消除PbO膜上的PbO层。在PTO膜与Pt底电极之间插入Zr缓冲层以增强漏损性能,并采用逐层制备方法排除未反应的TiO2。这些方法提高了PTO薄膜的开关性能。综上所述,采用气相反应溅射的方法成功地沉积了薄而光滑的PTO超薄薄膜,为高密度存储器件提供了可能。
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引用次数: 0
CCVD thin film ferroelectric epitaxy and electrode/biasing structures performance effects on phase shifters and filters CCVD薄膜铁电外延和电极/偏置结构对移相器和滤波器性能的影响
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693850
A. Hunt, Zhiyong Zhao, Kwang Choi, D. Rajamani
This paper presents the combustion chemical vapor deposition (CCVD) growth and characterization of epitaxial BST films on sapphire. These thin films were used to fabricate phase shifters and tunable filters from 1GHz to 40GHz using planar gap capacitors. A 2:1 tunability was achieved for BST thin films under a DC bias of as low as 10 V and IMD as high as 50dBM can be achieved. Composition has a significant effect on loss and tunability with electrodes and bias structures also participating in performance. Coplanar waveguide (CPW) structures are fabricated onto BST are used to minimize electrode interface and better determine BST properties over frequency. S-parameters of the CPW were tested using a vector network analyzer, with dielectric constant and loss tangent being derived by comparing the measured data with electromagnetic (EM) simulation results. Optimization of the RF circuits, BST and electrodes have resulted in phase shifters with 60 to over 80 degrees/dB, tunable filters with 6 dB to less than 2 dB insertion loss, and good temperature stability.
本文介绍了蓝宝石外延BST薄膜的燃烧化学气相沉积(CCVD)生长和表征。这些薄膜被用来制作移相器和可调谐滤波器,频率从1GHz到40GHz。BST薄膜在低至10 V的直流偏置下实现了2:1的可调性,并且可以实现高达50dBM的IMD。组成对损耗和可调性有显著影响,电极和偏压结构也参与性能。共面波导(CPW)结构被制造到BST上,用于最小化电极界面和更好地确定BST的频率特性。利用矢量网络分析仪对CPW的s参数进行了测试,并将测量数据与电磁仿真结果进行了比较,得到了介电常数和损耗正切。射频电路、BST和电极的优化产生了60至80度/dB以上的移相器,插入损耗为6db至小于2db的可调谐滤波器,以及良好的温度稳定性。
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引用次数: 2
Electrical properties of VO2 thin films grown by PLD PLD生长VO2薄膜的电学性质
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693843
F. Mendoza, F. Fernandez
A set of electronic instrumentation was configured to perform measurements of resistivity and Hall coefficient based on the four-point van der Pauw technique. Measurements were performed on silicon wafer and vanadium dioxide thin films. The abrupt change in resistivity at the critical semiconductor to metal transition temperature, by up to five orders of magnitude, was verified for VO2 thin films grown by pulsed laser deposition on sapphire substrate, and lower for films grown on MgO on glass substrates. For the sample grown on sapphire other transport properties for, obtained through Hall effect measurements, were obtained.
基于四点范德波法,配置了一套电子仪器来测量电阻率和霍尔系数。对硅片和二氧化钒薄膜进行了测量。在蓝宝石衬底上脉冲激光沉积的VO2薄膜的电阻率突变高达5个数量级,而在玻璃衬底上生长的MgO薄膜的电阻率突变更低。对于生长在蓝宝石上的样品,通过霍尔效应测量获得了其他输运性质。
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引用次数: 1
Dielectric and acoustic properties of SrTiO3 - PMN solid solutions SrTiO3 - PMN固溶体的介电和声学特性
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693870
E. Smirnova, A. Sotnikov, V. Lemanov, M. Weihnacht
The study is devoted to the compositional evolution and interrelation of phases in SrTiO3 - PMN solid solution. Experimental evidences of an antiferrodistortive phase, a relaxor state and their coexistence are obtained.
研究了SrTiO3 - PMN固溶体中相的组成演变和相互关系。得到了反铁畸变相、弛豫态及其共存的实验证据。
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引用次数: 0
LiMn1.8 Mg0.2O4 spinel cathode material for Li ion rechargeable batteries 锂离子可充电电池用尖晶石正极材料LiMn1.8 mg0.2
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693795
R. Singhal, M. Tomar, J. G. Burgos, R. Katiyar
We have synthesized Mg doped lithium manganate spinel cathode material via sol-gel method (LiMn1.8 Mg0.2O4 ) for application in Li ion rechargeable batteries. The cathode material was annealed at different temperature from 500¿900°C. C. It was found that the best crystallinity of the powder was obtained at 800°C. The lattice parameters for the material annealed at 500, 600, 700, 800, and 900°C was found 8.1320 Å, 8.1423 Å, 8.1631 Å, 8.1630 Å, 8.1757 Å, respectively. The cyclic voltammetric studies reveal intercalation-deintercalation of Li ion from the cathode material. The initial discharge capacity of LiMn1.8 Mg0.2O4 cathode material was found to be about 120 mAh/g. The rate cycleability studies show a very stable nature of LiMn1.8 Mg0.2O4 cathode at higher discharge currents (0.5 and 1 mA/cm2).
采用溶胶-凝胶法合成了镁掺杂锰酸锂尖晶石正极材料(LiMn1.8 mg0.2),用于锂离子可充电电池。阴极材料在500 ~ 900℃不同温度下退火。C.发现粉末在800℃时结晶度最佳。材料在500、600、700、800和900℃退火后的晶格参数分别为8.1320 Å、8.1423 Å、8.1631 Å、8.1630 Å、8.1757 Å。循环伏安研究揭示了锂离子在正极材料中的嵌入-脱嵌。LiMn1.8 Mg0.2O4正极材料的初始放电容量约为120 mAh/g。速率可循环性研究表明,LiMn1.8 mg0.2阴极在较高的放电电流(0.5和1 mA/cm2)下具有非常稳定的性质。
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引用次数: 0
Ceramic-polymer composite for high energy density capacitors 高能量密度电容器用陶瓷-聚合物复合材料
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693733
J. Borchardt, J. Alexander, K. Slenes
he U.S. Department of Defense vision for future weapons systems requires the development of electrical pulsers that exceed current state-of-the-art in energy storage density by an order of magnitude or more. Capacitors made from composite dielectric materials consisting of ceramic nanoparticles in a polymer matrix show promise for attaining these goals. TPL Inc. and Sandia National Laboratories have teamed to investigate the limits of these new materials for use in high energy density and high power capacitor designs. The major challenges encountered thus far are quality control in the processing of the materials as well as mechanical stresses resulting from the thermal curing process while forming prototype capacitor devices. This paper reports on the development progress of the composite dielectric for high energy density capacitors.
美国国防部对未来武器系统的愿景要求开发比当前最先进的能量存储密度高出一个数量级或更多的电脉冲器。由聚合物基体中的陶瓷纳米颗粒组成的复合介电材料制成的电容器有望实现这些目标。TPL公司和桑迪亚国家实验室已经合作研究这些新材料在高能量密度和高功率电容器设计中使用的限制。到目前为止,遇到的主要挑战是材料加工中的质量控制,以及在形成原型电容器器件时由热固化过程产生的机械应力。本文报道了高能量密度电容器用复合介质的研究进展。
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引用次数: 8
Response surface measurement for BiFeO3-CoFe2O4 multiferroic nanocomposite BiFeO3-CoFe2O4多铁纳米复合材料的响应面测量
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693782
B. Piccione, J. Blendell, R. García
A thin film BiFeO3 - CoFe2O4 multiferroic nanocomposite has been investigated to determine the coupling between the two phases in a constrained film by combining piezoelectric force microscopy and an externally applied magnetic field. In addition, finite element modeling was carried out to fully explain the observed local piezoelectric response. The results of the experiments and modeling show that the mechanical contributions dominate the local response of the ferroelectric phase and that large regions of high response are due to the interactions of the microstructural features. Also, microstructures that would improve mulitferroic properties are suggested based on the modeled response of the nanocomposite.
采用压电显微镜和外加磁场相结合的方法,研究了一种BiFeO3 - CoFe2O4多铁纳米复合材料薄膜中两相之间的耦合。此外,还进行了有限元模拟,以充分解释观察到的局部压电响应。实验和模拟结果表明,力学作用主导了铁电相的局部响应,而大范围的高响应是由微观结构特征的相互作用引起的。此外,基于模拟的响应,提出了可以改善纳米复合材料多铁性能的微观结构。
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引用次数: 0
Optimized thermoelectrics for energy harvesting applications 用于能量收集应用的优化热电器件
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693950
J. Bierschenk
Bismuth telluride thermoelectric (TE) technology is well established in many small scale cooling applications including picnic boxes, auto seats, telecommunications lasers, military smart munitions and satellite applications. Applications using thermoelectric generators (TEGs) operating in reverse, for generating power from small ambient temperature differences are much less mature and not as well understood. Traditional bulk thermoelectric devices and thin film thermoelectric devices are not well suited for these low ¿T, low heat flux applications due to a mismatch between the TEG thermal resistance and the thermal resistance of the small natural convection heat sinks inherent to these energy harvesting applications. This paper will highlight the TE design characteristics for low ¿T energy harvesting TEGs. Performance comparisons between the new bulk TEG devices, traditional thermoelectrics and new thin film thermoelectric approaches will be provided.
碲化铋热电(TE)技术在许多小型冷却应用中得到了很好的应用,包括野餐盒、汽车座椅、电信激光器、军事智能弹药和卫星应用。使用反向工作的热电发电机(teg),利用微小的环境温差发电的应用还不太成熟,也不太为人所知。传统的块状热电器件和薄膜热电器件不太适合这些低温度、低热流通量的应用,因为这些能量收集应用中固有的TEG热阻和小型自然对流散热器的热阻之间存在不匹配。本文将重点介绍低碳能量收集teg的设计特点。将提供新的大块TEG器件,传统热电器件和新的薄膜热电方法之间的性能比较。
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引用次数: 25
期刊
2008 17th IEEE International Symposium on the Applications of Ferroelectrics
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