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2008 17th IEEE International Symposium on the Applications of Ferroelectrics最新文献

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Atomic scale chemical and structural characterization of internal interfaces with atom probe tomography 原子探针层析成像的内部界面的原子尺度化学和结构表征
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693792
B. Gorman
Many nanoscale material systems require both structural and compositional characterization in order to be able to fully predict their electrical, magnetic, or optoelectronic behaviors. Traditional characterization techniques such as (S)TEM, SIMS, and XPS currently lack either spatial or chemical resolution needed for characterization of nanoscale devices. 3-dimensional atom probe has recently been utilized to determine the chemical and structural abruptness in a variety of materials with sub-nm spatial resolution and ~10ppm chemical resolution. In this talk, recent work utilizing a laser pulsed local electrode atom probe (LEAP) for the characterization of Photovoltaic devices will be illustrated. Specifically, dopant and H depth profiling in <10nm thick a-Si layers has been illustrated with ~1018/ cm3 chemical resolution. Additionally, interfacial abruptness in III¿V PV devices with a quantum well active region is illustrated with <1nm spatial resolution. Grain boundary analysis in metallic and semiconducting materials is also illustrated following site-specific FIB specimen preparation. Finally, transparent conducting oxide top contact layers have been analyzed for phase separation and following direct-write Maskless Mesoscale Materials Deposition (M3D) processing from polymeric precursors. Utilizing the laser pulsed LEAP for the analysis of TCOs also has illustrated the possibilities for analyzing lower conductivity, transparent materials such as dielectrics. The limitations and possible future applications to dielectric and ferroelectric applications will be discussed.
许多纳米级材料系统需要结构和成分表征,以便能够完全预测其电、磁或光电行为。传统的表征技术,如(S)TEM, SIMS和XPS目前缺乏表征纳米级器件所需的空间或化学分辨率。近年来,三维原子探针已被用于亚纳米空间分辨率和~10ppm化学分辨率下测定各种材料的化学和结构突发性。在本次演讲中,将介绍利用激光脉冲局部电极原子探针(LEAP)表征光伏器件的最新工作。具体来说,在<10nm厚的a-Si层中,掺杂物和H深度分布以~1018/ cm3的化学分辨率进行了说明。此外,在<1nm的空间分辨率下,具有量子阱有源区的III - V光伏器件的界面突发性得到了说明。金属和半导体材料的晶界分析也在特定地点的FIB样品制备后进行说明。最后,分析了透明导电氧化物顶部接触层在聚合物前驱体的相分离和直接写入无掩膜中尺度材料沉积(M3D)加工中的应用。利用激光脉冲LEAP分析tco也说明了分析电导率较低、透明材料(如介电材料)的可能性。本文将讨论其在介电和铁电领域的局限性和可能的未来应用。
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引用次数: 0
A methodology to characterize device-level endurance in 1T1C (1-transistor and 1-capacitor) FRAM 表征1T1C(1晶体管和1电容器)FRAM器件级耐用性的方法
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693962
W. Ahn, D. Jung, Y.K. Hong, H.H. Kim, Y. Kang, S.K. Kang, H.S. Kim, J. Kim, W. Jung, J. Jung, H. Ko, D. Choi, S.Y. Kim, E.S. Lee, J.Y. Kang, C. Wei, S.Y. Lee, K. A, H. Jung
We present a mimicking methodology to describe device-level endurance in a 1T1C, 64 Mb FRAM (ferroelectric random access memory). Device-level endurance of FRAM must clarify all the issues raised from destructive read-out READ/WRITE. To explore endurance properties in a real-time operational situation, we have established a measurement set-up that covers asymmetric pulse chains corresponding to Data 1 (D1) and Data 0 (D0) READ/RESTORE over a frequency range from 1.0 to 7.7 MHz. The cycle-to-failure of 5.9 × 1024 cycles in an operational condition of 7.7 MHz and 85 °C, has been obtained from extrapolation to VDD = 2.0 V in a voltage acceleration. We compare testing results with those of D1¿D0 populations of bit-line potential.
我们提出了一种模拟方法来描述1T1C, 64 Mb FRAM(铁电随机存取存储器)的设备级耐用性。FRAM的设备级耐用性必须澄清由破坏性读出READ/WRITE引起的所有问题。为了探索实时操作情况下的持久性能,我们建立了一个测量装置,涵盖了在1.0至7.7 MHz的频率范围内,对应于数据1 (D1)和数据0 (D0) READ/RESTORE的非对称脉冲链。在电压加速条件下,通过外推VDD = 2.0 V,得到了7.7 MHz和85℃工作条件下5.9 × 1024个周期的失效周期。我们将测试结果与位线电位D1 ~ D0种群的测试结果进行了比较。
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引用次数: 1
Assembly and functionalization of 3D photonic crystals 三维光子晶体的组装与功能化
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693794
X. Yu, P. V. Braun
A number of approaches, including holography and self-assembly, have been proposed as pathways to large area periodic structures, however, for many applications, simple self-assembled structures are not sufficient. It remains unclear how to add function to such structures in an efficient fashion, be this introduction of aperiodic features such as optical cavities and waveguides, functional materials including ferroelectrics, metals, and quantum dots, or the incorporation of high refractive index materials, for example Si and GaAs. In this paper I will focus on our latest results on the use of electrochemical deposition to form three-dimensionally periodic structures out of Ni. Details on emission from these structures can be found in [1]. In my lecture, I will also discuss optical manipulation, and DNA-directed assembly as pathways to complex 3D structures.
许多方法,包括全息和自组装,已经被提出作为大面积周期结构的途径,然而,对于许多应用,简单的自组装结构是不够的。目前还不清楚如何以一种有效的方式向这种结构中添加功能,是引入非周期特征,如光腔和波导,功能材料,包括铁电体、金属和量子点,还是结合高折射率材料,如Si和GaAs。在本文中,我将重点介绍我们在利用电化学沉积形成镍的三维周期性结构方面的最新成果。这些结构的发射细节可在[1]中找到。在我的讲座中,我还将讨论光学操作和dna定向组装作为复杂3D结构的途径。
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引用次数: 1
Structure-property relations in multifunctional bismuth ferrite - lead titanate 多功能铋铁氧体-钛酸铅的结构-性能关系
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693781
A. Bell, T. Comyn, Mikael A. Khan, T. Stevenson, T. Burnett
Solid solutions of bismuth ferrite - lead titanate are proving to be of interest for a number of applications due to not only the potential for room temperature magnetoelectric coupling, but also due to the anomalous combination of large spontaneous strain and high Curie temperature at the morphotropic phase boundary. Here we report on progress in the magnetic characterization, the development of high temperature piezoelectric devices and the characterization of thin films for FeRAM applications.
铋铁氧体-钛酸铅的固溶体不仅具有室温磁电耦合的潜力,而且还具有大自发应变和高居里温度在致形相边界的异常组合,因此被证明是许多应用的兴趣。本文报告了FeRAM在磁性表征、高温压电器件的发展和薄膜表征方面的进展。
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引用次数: 0
Piezoelectric microgenerator - current status, challenges, and applications 压电微型发电机——现状、挑战和应用
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693938
Hyun-uk Kim, S. Priya
Piezoelectric energy harvesters are projected to be suitable energy sources for sensors and associated electronics used in industrial health monitoring, and aircraft structural health monitoring. This manuscript outlines the progress in developing the energy harvesting prototypes. It compares the progress made in the realization of piezoelectric microgenerators with that of electromagnetic and electrostatic generators and identifies the parameters that need to be reported in subsequent publications for rationale comparison.
预计压电能量采集器将成为工业健康监测和飞机结构健康监测中使用的传感器和相关电子设备的合适能源。本文概述了能量收集原型的开发进展。它比较了压电微型发电机与电磁和静电发电机在实现方面取得的进展,并确定了在后续出版物中需要报道的参数,以便进行基本原理比较。
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引用次数: 7
Finite size effects in ferroelectric nanocrystals: Myths & facts 铁电纳米晶体的有限尺寸效应:神话与事实
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693767
E. K. Akdoğan, A. Safari
A phenomenological intrinsic finite size effect model for a single domain, mechanically free, and surface charge compensated ABO3 (PbTiO3 or BaTiO3) nanocrystals undergoing a first order tetragonal¿cubic phase transition is propsoed. By using experimental particle size-dependent spontaneous polarization data for PbTiO3 and BaTiO3, free energy expansion coefficients coefficients up to the sixth order as a function of ¿ is computed in the range <150 nm. It will be shown that the thermodynamic potential is able to predict the size-induced phase transition as well as the metastable tetragonal phase in the cubic phase field rigorously. The free energy surface is then contructed, which describes the decrease in tetragonal phase stability with decreasing ¿ rigorously. The intrinsic dielectric and piezoelectric properties of single domain, mechanically free, and surface charge compensated PbTiO3 nanocrystals are then evaluated. It will be shown that a decrease in dielectric susceptibility at the transition temperature with decreasing particle size is commensurate with predictions of lattice dynamics considerations. It will also be shown that an anomalous increase in piezocharge coefficients near ~15 nm is predicted. Finite size effects will then be discusssed in terms of depolarization fields, surface effects, role of defects, among others and salient aspects of myths & facts in the published literature will be analyzed.
提出了一种单畴、机械自由、表面电荷补偿的ABO3 (PbTiO3或BaTiO3)纳米晶体经历一阶四方/立方相变的现象学本征有限尺寸效应模型。利用PbTiO3和BaTiO3随粒径变化的自发极化实验数据,计算了在< 150nm范围内自由能膨胀系数(系数为¿)的六阶函数。结果表明,热力学势能严格地预测立方相场中尺寸诱导的相变和亚稳四方相。然后构造了自由能面,它严格地描述了四方相稳定性随¿的减少而降低。然后评估了单畴、机械自由和表面电荷补偿的PbTiO3纳米晶体的固有介电和压电性能。结果表明,在转变温度下,随着颗粒尺寸的减小,介电磁化率的降低与晶格动力学考虑的预测是相称的。结果还表明,在~15 nm附近,压电系数会出现异常增加。然后将根据去极化场,表面效应,缺陷的作用等方面讨论有限尺寸效应,并分析已发表文献中的神话和事实的突出方面。
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引用次数: 0
Growth of potassium lithium niobate-tantalate single crystal for piezoelectric applications 压电型铌酸锂-钽酸钾单晶的生长
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693823
M. Adachi, K. Takeuchi, T. Karaki
(K,Li)NbO3 single crystals were successfully grown from a melt with potassium enriched composition under the condition of shallow temperature gradient using the TSSG technique. The growth was along the ¿100¿ direction in the pseudo-cubic phase. The crystal was allowed to grow laterally from around 10¿30h to obtain the cross section desired. The growing crystal was then lifted up above the melt surface or lifted intermittently at the rate of about 4mm/h, while the melt was cooled. Cracking occurred at the phase transition temperatures of 457 and 220°C for (K,Li)NbO3. Slow cooling fairly eliminated the cracking at the both phase transition points. The completeness of the poling was checked by the dielectric measurements. After poling, the dielectric constant reduced to be around 150.
利用TSSG技术,在浅温度梯度条件下,成功地从富钾熔体中生长出(K,Li)NbO3单晶。在拟立方相中沿¿100¿方向生长。晶体被允许从10 ~ 30小时左右横向生长以获得所需的横截面。当熔体冷却时,生长的晶体以约4mm/h的速度上升到熔体表面以上或间歇性上升。(K,Li)NbO3的相变温度分别为457℃和220℃。缓慢冷却完全消除了两个相变点的开裂。通过介电测量来检验极化的完整性。极化后,介电常数降至150左右。
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引用次数: 0
Ultrasound imaging arrays with improved transmit power capability 具有改进发射功率的超声成像阵列
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693873
M. Zipparo
Arrays optimized for conventional B-mode imaging applications are often limited in their ability to transmit power into the body, not by acoustic intensity limits but by face temperature maximums. Furthermore, new imaging modalities that use a long train of transmit pulses to remotely deposit a localized force on tissue are even more limited by array thermal considerations. Losses within the piezoceramic material are an important source of heat generation. Simply replacing the piezo material by one with lower losses will result in poorer imaging performance due to the physical properties and coarser microstructure of most low loss materials. This work describes the use of low loss piezoceramics exhibiting a microstructure that is ideal for forming into fine scale ultrasound arrays. Incorporating this material into multilayer ceramic and composite structures is shown to be an effective way to ameliorate the limitations of the base piezo and result in arrays with acoustic tank and imaging performance that is as good as or better than conventional imaging arrays made using a single layer of a conventional piezo. These arrays are also shown to exhibit reduced heating under equivalent electrical input power.
为传统的b模式成像应用优化的阵列通常在向体内传输能量的能力上受到限制,而不是受到声强限制,而是受到表面温度最大值的限制。此外,使用一长串发射脉冲远程在组织上沉积局部力的新成像模式受到阵列热因素的限制。压电陶瓷材料内部的损耗是产生热量的重要来源。由于大多数低损耗材料的物理性质和粗糙的微观结构,简单地用低损耗的压电材料替换压电材料会导致成像性能变差。这项工作描述了低损耗压电陶瓷的使用,展示了一种理想的微结构,可以形成精细的超声波阵列。将这种材料结合到多层陶瓷和复合结构中被证明是一种有效的方法,可以改善基础压电陶瓷的局限性,并产生具有声槽和成像性能的阵列,与使用单层传统压电陶瓷制成的传统成像阵列一样好或更好。这些阵列也显示出在等效电输入功率下发热减少。
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引用次数: 2
Mechanisms of aging in ferroelectrics: The orientation of dipoles versus the charge drift 铁电体老化机制:偶极子取向与电荷漂移
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693919
M. Morozov, D. Lupascu, Dragan Damjanovic
Two different scenarios of aging effect in perovskyte ferroelectrics are compared qualitatively and examined experimentally in Fe-doped Pb(Zr0.58Ti0.42)O3 (PZT) ceramics using dielectric spectroscopy.
对钙钛矿铁电体在两种不同情况下的老化效应进行了定性比较,并利用介电光谱技术在掺铁Pb(Zr0.58Ti0.42)O3 (PZT)陶瓷中进行了实验研究。
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引用次数: 1
Structural, dielectric, electric, and ferroelectric properties of different routes derived of Ba1-xSrxTiO3 (BSTO) ceramic Ba1-xSrxTiO3 (BSTO)陶瓷的结构、介电、电学和铁电性能
Pub Date : 2008-12-02 DOI: 10.1109/ISAF.2008.4693900
R. M. Valdes, R. Palai, R. Katiyar
Ba1-xSr3TiO3 (BSTO) is a suitable material for microelectronic device applications due to its high response of the dielectric permittivity an applied electric filed. We have investigated crystal structure, dielectric response, electrical conduction and ferroelectric properties of BSTO. Sol gel and solid state processing were used as routes for the synthesis of BSTO ceramics. The microstructures including grain size and phase analysis have been examined using SEM, X-ray diffraction, and Raman Spectroscopy. The chemical characterization was measured by EDS. From the temperature dependence of measured relative permittivity, loss tangent and, tunability at frequencies between 1 KHz to 1 MHz, the ferroelectric phase transition of BSTO-sg (x=0.4) was observed in ~ 238K, BST-ss (x=0.4) in 267K, and BST-sg & BST-ss (x=0.3) were observed both in ~312K.
Ba1-xSr3TiO3 (BSTO)由于其对外加电场的高介电常数响应而成为微电子器件应用的合适材料。我们研究了BSTO的晶体结构、介电响应、电导率和铁电性能。采用溶胶-凝胶法和固相法制备了BSTO陶瓷。利用扫描电镜、x射线衍射和拉曼光谱分析了其微观结构,包括晶粒尺寸和物相分析。用能谱仪测定了其化学性质。从测量的相对介电常数、损耗正切和1 KHz ~ 1 MHz频率可调性的温度依赖性来看,在~ 238K下观察到BSTO-sg (x=0.4)的铁电相变,在267K下观察到BST-ss (x=0.4)的铁电相变,在~312K下观察到BST-sg和BST-ss (x=0.3)的铁电相变。
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引用次数: 0
期刊
2008 17th IEEE International Symposium on the Applications of Ferroelectrics
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