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Analysis of the Effect of Separate Collection on the Composition of Mixed Municipal Solid Waste in Italy 意大利分类收集对混合城市固体废物组成的影响分析
Pub Date : 2020-08-18 DOI: 10.2174/1874123102014010063
P. Calabrò, D. Pangallo
Separate collection of municipal solid waste (MSW) is mandatory in Italy, and an increasingly higher standard of efficiency is applied; in fact, the target value set by regulation is 65%. In the last 20 years, separate collection efficiency increased from 9.4% with 80% national MSW landfilled, and only one region was over 25% separate collection to 58.1% with 22% national MSW landfilled and 12 of 20 regions over 55% separate collection. However, significant differences are present in the three Italian macro regions (North, Center and South). This paper analyzes the composition of waste carried in most Italian regions to evaluate the effect of separate collection on the composition of mixed municipal solid waste (unsorted). Moreover, a regression analysis on the same data allows to assess this latter as a function of separate collection efficiency.
在意大利,城市固体废物的分类收集是强制性的,并采用了越来越高的效率标准;事实上,法规设定的目标值是65%。近20年来,城市垃圾分类收集效率从9.4%(全国垃圾填埋率80%)、1个超过25%的地区上升到58.1%(全国垃圾填埋率22%),20个地区中有12个超过55%。然而,意大利的三个宏观区域(北部、中部和南部)存在显著差异。本文分析了意大利大多数地区携带的废物组成,以评估分类收集对混合城市固体废物(未分类)组成的影响。此外,对同一数据进行回归分析,可以评估后者作为单独收集效率的函数。
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引用次数: 9
Poly (Adenine) Modified Graphene-Based Voltammetric Sensor for the Electrochemical Determination of Catechol, Hydroquinone and Resorcinol 聚腺嘌呤修饰石墨烯伏安传感器电化学测定儿茶酚、对苯二酚和间苯二酚
Pub Date : 2020-07-06 DOI: 10.2174/1874123102014010052
J. G. Manjunatha
This paper presents the application of Poly (Adenine) Modified Graphene Paste Electrode (PAMGPE) for the analysis of Catechol (CC) with Resorcinol (RC) and Hydroquinone (HQ) by a voltammetric technique. Electropolymerization technique was utilized for the modification of the sensor surface. The electrode surface was characterized by Field Emission Scanning Electron Microscopy (FE-SEM). Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) were used to study the redox behavior of CC, RC and HQ. Oxidation peak current of CC increased linearly with the concentration of CC in the range from 2×10-6- 8×10-6 M and 1×10-5-1.5 ×10-4 M with a detection limit of 2.4×10-7 M. The practical application of the developed sensor was verified as exact for the determination of CC in water sample. The stability, repeatability, and reproducibility of the developed electrode were studied and established good characteristics. Furthermore, the PAMGPE was examined for the simultaneous determination of CC, RC and HQ.
本文介绍了聚腺嘌呤修饰石墨烯糊电极(PAMGPE)在邻苯二酚(CC)、间苯二酚(RC)和对苯二酚(HQ)的伏安分析中的应用。利用电聚合技术对传感器表面进行修饰。采用场发射扫描电镜(FE-SEM)对电极表面进行了表征。采用循环伏安法(CV)和差分脉冲伏安法(DPV)研究了CC、RC和HQ的氧化还原行为。在2×10-6 ~ 8×10-6 M和1×10-5-1.5 ×10-4 M范围内,CC的氧化峰电流随CC浓度线性增加,检出限为2.4×10-7 M,验证了该传感器对水样中CC的测定是准确的。研究了该电极的稳定性、重复性和再现性,并建立了良好的特性。此外,PAMGPE用于同时测定CC、RC和HQ。
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引用次数: 36
Current and Future Global Lithium Production Till 2025 到2025年全球锂产量的现状和未来
Pub Date : 2020-06-29 DOI: 10.2174/1874123102014010036
Daniel Calisaya-Azpilcueta, Sebastián Herrera-León, L. Cisternas
The production of lithium is growing continuously, and ensuring its stable supply is crucial for the growth of global economy. Therefore, to avoid a potential supply risk, it is necessary to determine the requirements for the implementation of current and planned lithium mining projects in order to meet the forecasted demand of lithium. In this paper, the capability of global lithium production to meet the uncertain, high or low level, demand by 2025, is analyzed. The global lithium supply is simulated considering three alternatives: no new projects in the portfolio, committed projects, and uncommitted projects. Two scenarios for estimating the growth rate of lithium production in the future are analyzed: a regular growth rate and a growth rate assuming the use in full capacity of lithium production by major suppliers. The results show that the total capacity of production covers the low-level demand. However, it is not enough to cover the high-level demand for lithium. Therefore, new projects are necessary. On the other hand, results considering all the possible projects show that the demand is exceeded, which suggests that intermediate scenarios could cover the demand by 100%. It is expected that a low-carbon economy may be projected soon, and assuming the high-level demand of lithium, then a combination of committed projects and uncommitted projects should be considered.
锂的产量持续增长,确保锂的稳定供应对全球经济增长至关重要。因此,为了避免潜在的供应风险,有必要确定当前和计划中的锂开采项目的实施要求,以满足预测的锂需求。本文分析了到2025年全球锂生产满足不确定、高或低水平需求的能力。全球锂供应模拟考虑了三种替代方案:投资组合中没有新项目、已承诺项目和未承诺项目。分析了预测未来锂生产增长率的两种情景:常规增长率和假设主要供应商的锂生产满负荷使用的增长率。结果表明:总生产能力覆盖了低水平需求;然而,这还不足以满足对锂的高需求。因此,新的项目是必要的。另一方面,考虑所有可能项目的结果表明,需求是超过的,这表明中间情景可以覆盖100%的需求。预计低碳经济可能很快就会出现,并且假设锂的高需求,那么应该考虑将承诺项目和未承诺项目结合起来。
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引用次数: 3
A Binary Mixture of Sesame And Castor Oil as an Ecofriendly Corrosion Inhibitor of Mild Steel In Crude Oil 麻麻油与蓖麻油二元混合物在原油中对低碳钢的环保型缓蚀剂研究
Pub Date : 2020-04-22 DOI: 10.2174/1874123102014010025
Tomiwa I. Oguntade, Christiana S. Ita, Olabode Sanmi, D. Oyekunle
Investigation of corrosion prevention techniques in oilfield applications is essential due to the occurrence of persistent corrosion problems, which largely contribute to huge production expenses of oil and gas exploration around the world. However, suitable corrosion control measures can help avert several potential disasters that can result in crucial issues, including environmental pollution, water resource, negative social impacts, and loss of life. Corrosion exists in oilfields at all stages, including surface to downhole and in processing facilities. It occurs as perforations in tanks, pipelines, tubing, casing as well as other equipment [1, 2]. Corrosion problems are typically linked to equipment maintenance and operating
由于腐蚀问题的持续发生,在很大程度上造成了世界范围内油气勘探的巨大生产费用,因此研究油田应用中的防腐技术是必不可少的。然而,适当的腐蚀控制措施可以帮助避免一些可能导致关键问题的潜在灾害,包括环境污染、水资源、负面社会影响和生命损失。腐蚀存在于油田的各个阶段,包括地面到井下以及加工设施。它发生在储罐、管道、油管、套管以及其他设备的射孔中[1,2]。腐蚀问题通常与设备维护和操作有关
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引用次数: 4
Effect of Varying Drying Temperature on the Soluble Sugar and Nutritional Content of Banana 不同干燥温度对香蕉可溶性糖及营养成分的影响
Pub Date : 2020-04-21 DOI: 10.2174/1874123102014010011
E. Alagbe, Y. S. Amlabu, E. O. Daniel, M. Ojewumi
In this work, the effect of drying temperature on the available carbohydrate is investigated. Nigerian climate favours the cultivation of banana and it is a ready fruit delight in almost all homes. Hybrids and polypoids of the species musa acuminata and musa balbisiana are very common. Unfortunately, post-harvest losses of 40 – 60%, of this energy rich fruit are encountered yearly. Drying is an age long method of preservation which has stood the test of time. Bananas are known to possess high carbohydrates with low glycaemic index which makes it a healthy fruit or snack. To determine the optimum drying temperature for the drying of Banana fruit. The banana fruit was peeled and sliced to about 5 mm thick and dried in a tray dryer at varying temperatures of 40 °C, 50 °C, 60 °C and 70 °C. The control sample was air dried at the average prevailing temperature of 30 °C. Results obtained showed that increased drying temperature favoured more loss of moisture from the samples and in turn, favoured an increase in the available carbohydrate in the dried fruit. The ash, fat and crude fibre content marginally changed with drying temperature. The optimum temperature for treated and untreated samples, from the results obtained, were 60 °C and 70 °C respectively. Drying impacts positively on the available sugar in the Banana fruit.
本文研究了干燥温度对有效碳水化合物的影响。尼日利亚的气候有利于香蕉的种植,它是几乎所有家庭的现成水果。尖musa acuminata和musa balbisiana的杂交和息肉是非常常见的。不幸的是,这种富含能量的水果在收获后损失了40% - 60%。干燥是一种经得起时间考验的长期保存方法。众所周知,香蕉含有高碳水化合物和低血糖指数,这使它成为一种健康的水果或零食。目的:确定香蕉果实干燥的最佳干燥温度。香蕉果实去皮切片至5mm厚左右,在40℃、50℃、60℃、70℃的不同温度下,在托盘式干燥机中干燥。对照样品在平均盛行温度30℃下风干。结果表明,提高干燥温度有利于样品水分的更多损失,反过来,有利于干果中有效碳水化合物的增加。灰分、脂肪和粗纤维含量随干燥温度变化不大。结果表明,处理后样品和未处理样品的最佳温度分别为60℃和70℃。干燥对香蕉果实中的有效糖有积极的影响。
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引用次数: 3
Review and Improvement of the Finite Moment Problem 有限矩问题的回顾与改进
Pub Date : 2020-04-21 DOI: 10.2174/1874123102014010017
F. Hjouj, M. Jouini
Background: This paper reviews the Particle Size Distribution (PSD) problem in detail. Mathematically, the problem faced while recovering a function from a finite number of its geometric moments has been discussed with the help of the Spline Theory. Undoubtedly, the splines play a major role in the theory of interpolation and approximation in many fields of pure and applied sciences. B-Splines form a practical basis for the piecewise polynomials of the desired degree. A high degree of accuracy has been obtained in recovering a function within the first ten to fifteen geometric moments. The proposed approximation formula has been tested on several types of synthetic functions. This work highlights some advantages, such as the use of a practical basis for the approximating space, the exactness of computing the moments of these basis functions and the reduction of the size along with an appropriate transformation of the resulting linear system for stability. Objective: The aim is to recover a function from a finite number of its geometric moments. Methods: The main tool is the Spline Theory. Undoubtedly, the role of splines in the theory of interpolation and approximation in many fields of pure and applied sciences has been wellestablished. B-Splines form a practical basis for the piecewise polynomials of the desired degree. Results: A high degree of accuracy has been obtained in recovering a function within the first ten to fifteen geometric moments. The proposed approximation formula is tested on several types of synthetic functions. Conclusion: This work highlights some advantages, such as the use of a practical basis for the approximating space, the exactness of computing the moments of these basic functions and the reduction of the size along with the data transformation of the resulting linear system for stability.
背景:本文对颗粒尺寸分布(PSD)问题进行了详细的综述。在数学上,利用样条理论讨论了从有限个几何矩中恢复函数所面临的问题。毫无疑问,样条曲线在纯科学和应用科学的许多领域的插值和近似理论中起着重要的作用。b样条为期望次数的分段多项式提供了实用的基础。在恢复前10到15个几何矩内的函数时,获得了很高的精度。所提出的近似公式已在几种类型的合成函数上进行了检验。这项工作突出了一些优点,例如使用实用的基来逼近空间,计算这些基函数的矩的准确性,以及减小大小以及对所得到的线性系统进行适当的变换以保持稳定性。目的:目的是从有限的几何矩中恢复一个函数。方法:以样条理论为主要工具。毫无疑问,在纯科学和应用科学的许多领域中,样条在插值和近似理论中的作用已经得到了很好的确立。b样条为期望次数的分段多项式提供了实用的基础。结果:在恢复前10到15个几何矩内的函数时获得了很高的精度。在几种类型的综合函数上对所提出的近似公式进行了检验。结论:本工作突出了一些优点,如使用实用的基础来逼近空间,计算这些基本函数的矩的准确性,以及减小线性系统的大小以及对结果进行数据变换以保持稳定性。
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引用次数: 13
New Analytical and Numerical Solutions of the Particle Breakup Process 粒子破碎过程的新解析解和数值解
Pub Date : 2020-03-20 DOI: 10.2174/1874123102014010001
A. Hasseine, M. Hlawitschka, Waid Omar, H. Bart
Objective: In this work, we obtained the analytical and approximate solutions of the population balance equations (PBEs) involving the breakup process in batch and continuous flow by applying the Adomian decomposition method and piecewise continuous basis functions, respectively. Methods: The key to the advanced numerical method is to represent the number distribution function of the dispersed phase through the orthogonal Chebyshev basis polynomials. It is a straightforward and effective method that has the advantage of simultaneously giving the distribution and the different required moments. Therefore, it does not require the construction of the distribution from moments computations obtained by the transformation of the initial problem and the lost information. Results: The performance of this numerical approach is evaluated by solving breakup equation and comparison against analytical solutions obtained from the Adomian decomposition method, which generally allows the analysis of this approach. Conclusion: The numerical results obtained by the present numerical method were compared with the new analytical solutions of the PBE. It was found that both piecewise continuous basis functions and analytical solutions have comparable results.
目的:利用Adomian分解法和分段连续基函数分别得到了涉及间歇和连续流分解过程的种群平衡方程的解析解和近似解。方法先进数值方法的关键是用正交切比雪夫基多项式表示分散相的数分布函数。该方法具有同时给出分布和不同所需矩的优点,是一种简单有效的方法。因此,它不需要从初始问题和丢失信息的变换得到的矩量计算中构造分布。结果:通过求解破裂方程并与Adomian分解方法得到的解析解进行比较,对该数值方法的性能进行了评价,Adomian分解方法通常允许对该方法进行分析。结论:本文数值方法得到的数值结果与新的PBE解析解进行了比较。结果表明,分段连续基函数与解析解具有可比性。
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引用次数: 2
Synthesis of Molecularly Imprinted Polymers for the Selective Extraction /Removal of 2,4,6-trichlorophenol 选择性萃取/去除2,4,6-三氯苯酚的分子印迹聚合物的合成
Pub Date : 2019-12-31 DOI: 10.2174/1874123101912010122
S. Bhawani, Salman Bakhtiar, S. Shafqat
The resulted polymers were characterized by scanning electron microscopy (SEM), EDX, Fourier-transform infrared spectroscopy(FT-IR) and BET. The batch binding assay was carried out to select the most selective polymer in terms of binding efficiency towards the target template. The adsorption parameters such as initial concentration, dosage of polymer, pH effect and selectivity with structural analogues were determined . The selectivity of MIP towards the 2, 4, 6-TCP was higher as compared to its structural analogue melamine with a good adsorption efficiency. Furthermore, the MIP as an extracting material was applied for extraction of 2, 4, 6-trichlorophenol from the spiked blood serum (88%) and river water sample (94%). The results showed that the optimized MIP could successfully extract 2,4,6-TCP from the blood serum and river water.
采用扫描电镜(SEM)、EDX、傅里叶变换红外光谱(FT-IR)和BET对聚合物进行了表征。批量结合实验是为了选择最具选择性的聚合物对目标模板的结合效率。测定了聚合物的初始浓度、用量、pH效应和结构类似物的选择性等吸附参数。与结构类似物三聚氰胺相比,MIP对2,4,6 - tcp的选择性更高,吸附效率较好。此外,将MIP作为提取材料,应用于从加标血清(88%)和河流水样(94%)中提取2,4,6 -三氯酚。结果表明,优化后的MIP能成功地从血清和河水中提取2,4,6- tcp。
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引用次数: 3
Experimental Study on Rational Water Injection Rate in Continental Sandstone Reservoirs 陆相砂岩油藏合理注水速率实验研究
Pub Date : 2019-11-15 DOI: 10.2174/1874123101913010114
Manping Yang, Lu Jiang, Shuxiang Guo, Liming Zheng, L. Meng
Objective: In this paper, an experimental model of water flooding was designed and manufactured, and experiments on high permeability and low permeability models were carried out. Methods: The relationship between injection rate, injection pore volume multiple and oil displacement efficiency, injection rate, injection pore volume multiple and water content in two kinds of permeability was analyzed. Results: There is a certain relationship between oil displacement efficiency and water injection speed. There is a reasonable water injection speed, which can achieve the highest oil displacement efficiency. The lower the permeability the lower will be the reasonable injection rate . In the reasonable range of water injection rate, the injection rate increases gradually, and the best oil displacement effect can be obtained. Conclusion: Through analysis, it was concluded that the oil displacement efficiency of artificial rocks with various water injection rates was different even in the same permeability experimental model. It was indicated that the water flooding recovery of the reservoir can be improved by using the method of strong injection and strong production in the middle and later stage of development.
目的:设计并制作了水驱实验模型,并进行了高渗模型和低渗模型实验。方法:分析两种渗透率下注入速率、注入孔隙体积倍数与驱油效率、注入速率、注入孔隙体积倍数与含水率的关系。结果:驱油效率与注水速度之间存在一定的关系。有合理的注水速度,可以达到最高的驱油效率。渗透率越低,合理的注入速度越低。在注水速率的合理范围内,注水速率逐渐增大,可获得最佳驱油效果。结论:通过分析得出,即使在相同渗透率实验模型下,不同注水速度下的人工岩石驱油效率也是不同的。研究表明,在开发中后期采用强注强采的方法可以提高油藏的水驱采收率。
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引用次数: 0
Integrated Reservoir Characterisation for Petrophysical Flow Units Evaluation and Performance Prediction 岩石物性流动单元评价与动态预测综合储层表征
Pub Date : 2019-10-29 DOI: 10.2174/1874123101913010097
A. Evans, Aidoo Borsah Abraham, Brantson Eric Thompson
An improved understanding of complex clastic reservoirs has led to more detailed reservoir description using integrated approach. In this study, we implemented cluster analysis, geostatistical methods, reservoir quality indicator technique and reservoir simulation to characterize clastic system with complex pore architecture and heterogeneity. Model based clustering technique from Ward’s analytical algorithm was utilised to transform relationship between core and calculated well logs for paraflow units (PFUs) classification in terms of porosity, permeability and pore throat radius of the reservoir. The architecture of the reservoir at pore scale is described using flow zone indicator (FZI) values and the significant flow units characterized adopting the reservoir quality index (RQI) method. The reservoir porosity, permeability, oil saturation and pressure for delineated flow units were distributed stochastically in 2D numerical models utilising geostatistical conditional simulation. In addition, production behaviour of the field is predicted using history matching. Dynamic models were built for field water cut (FWCT), total field water production (FWPT) and field gas-oil-ratio (FGOR) and history matched, considering a number of simulation runs. Results obtained showed a satisfactory match between the proposed models and history data, describing the production behaviour of the field. The average FWCT peaked at 78.9% with FWPT of 10 MMSTB. Consequently, high FGOR of 6.8 MSCF/STB was obtained. The integrated reservoir characterisation approach used in this study has provided the framework for defining productive zones and a better understanding of flow characteristics including spatial distribution of continuous and discrete reservoir properties for performance prediction of sandstone reservoir.
随着对复杂碎屑岩储层认识的提高,利用综合方法对储层进行了更详细的描述。采用聚类分析、地质统计学方法、储层质量指标技术和储层模拟等方法对具有复杂孔隙结构和非均质性的碎屑体系进行了表征。利用Ward分析算法中的基于模型的聚类技术对岩心和计算测井曲线之间的关系进行转换,根据储层的孔隙度、渗透率和孔喉半径对旁流单元(pfu)进行分类。利用流动区指标(FZI)值和储层质量指数(RQI)表征的显著流动单元描述了孔隙尺度下储层的结构。利用地质统计条件模拟技术,在二维数值模型中随机分布了圈定流动单元的储层孔隙度、渗透率、含油饱和度和压力。此外,利用历史匹配预测油田的生产动态。考虑到多次模拟运行,建立了油田含水率(FWCT)、油田总产量(FWPT)、油田气油比(FGOR)和历史匹配的动态模型。所获得的结果表明,所提出的模型与历史数据之间的匹配令人满意,描述了该油田的生产行为。平均FWCT峰值为78.9%,FWPT为10mmstb。因此,获得了6.8 MSCF/STB的高FGOR。本研究中使用的综合油藏表征方法为定义生产区域和更好地理解流动特征提供了框架,包括连续和离散油藏性质的空间分布,用于砂岩油藏的动态预测。
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引用次数: 4
期刊
The Open Chemical Engineering Journal
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