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Transduction Using Functional Materials: Basic Science and Understanding at the U. S. Naval Research Laboratory 使用功能材料的转导:美国海军研究实验室的基础科学和理解
V. Degiorgi, P. Finkel, Lauren M. Garten, M. Staruch
Recently NRL researchers have embarked on a basic research effort “Tuning Giant Magnetoelectric Properties in Phase Transformation Multiferroics” focused on multifunctional materials for energy transduction and conversion. Multiferroic materials combine at least two coupled ferroic properties and are used in multiple applications including magnetic field sensors, energy harvesting devices, non-volatile memory and antennas. There are very few single phase multiferroic materials, and they normally have relatively low magnetoelectric (ME) coupling coefficient. In contrast, engineered materials such as ME composites fabricated from piezoelectric and magnetostrictive materials can show multiple orders of magnitudes increase in the ME coupling coefficient. The optimal design of ME composites would lead to conditions of maximum response (strain, induced voltage, or field) with minimum applied electric or magnetic fields, providing advanced materials for transduction, sensing, energy harvesting and other applications. That is why NRL researchers are working on piezoelectric materials with enhanced properties due to a phase transformation that would minimize the stimuli needed to achieve large strains. Key to the successful design and fabrication of ME composites is an understanding of interface characteristics as well as individual material components. In this paper we will review the current status of work at NRL on engineered multiferroic composites comprised of piezoelectric and magnetostrictive materials coupled through strain. There are still many open questions about the interfacial properties as well as the individual component materials. Details will be presented from recent work on material characterization under repetitive cycling, interface characteristics, and stress/electric/thermal effects on driving the phase transition in a relaxor ferroelectric single crystal.
最近,NRL的研究人员开始了一项基础研究工作——“在相变多铁质中调谐巨磁电特性”,重点研究用于能量转导和转换的多功能材料。多铁性材料结合了至少两种耦合的铁性,并用于多种应用,包括磁场传感器、能量收集装置、非易失性存储器和天线。单相多铁性材料很少,通常具有较低的磁电耦合系数。相比之下,工程材料,如由压电和磁致伸缩材料制成的ME复合材料,其ME耦合系数可以增加多个数量级。ME复合材料的优化设计将以最小的外加电场或磁场达到最大的响应条件(应变、感应电压或场),为转导、传感、能量收集和其他应用提供先进的材料。这就是为什么NRL的研究人员正在研究具有增强性能的压电材料,因为相变可以最大限度地减少实现大应变所需的刺激。成功设计和制造ME复合材料的关键是对界面特性以及单个材料组件的理解。本文将综述NRL在由压电材料和磁致伸缩材料通过应变耦合组成的工程多铁复合材料方面的研究现状。关于界面特性和单个组件材料的特性仍有许多悬而未决的问题。将详细介绍最近在重复循环下的材料表征,界面特性以及驱动弛豫铁电单晶相变的应力/电/热效应方面的工作。
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引用次数: 0
An FE Based Surrogate Model for Predicting the Impact of a SMA Twist System on the Helicopter Performance 基于有限元的SMA扭转系统对直升机性能影响预测代理模型
S. Ameduri, A. Concilio, Rohin K. Majeti
This work focuses on a surrogate predictive model, conceived to estimate the impact on blade twist law of a Shape Memory Alloy actuation system. The basic idea is to integrate the pre-existing blade structure with a pre-twisted SMA tube. Due to the specific property of recovering deformation during phase transition, the SMA element can transmit angular deformations and alter the original twist to improve performance when required. The model includes two main modules. The first one targets the SMA actuator and simulates the transmission of twist against some critical parameters (tube extension and location along the blade span and level of activation). The second module receives as input the modified twist law and the updated mechanical features due to the SMA and gives in output an estimate of the performance produced by the system. After an overview on input and output parameters and their cross link, a description of the SMA predicting core is provided. A parameterization is then organized to illustrate the impact of the morphing system onto the blade and on the twist law. On this basis, an additional parameterization is implemented, now focusing on the effects on performance of the proposed system.
这项工作的重点是一个代理预测模型,设想估计对叶片扭曲规律的影响形状记忆合金驱动系统。其基本思路是将原有的叶片结构与预扭SMA管相结合。由于在相变过程中恢复变形的特性,SMA元件可以传递角变形,并在需要时改变原始捻度以提高性能。该模型包括两个主要模块。第一个以SMA致动器为目标,根据一些关键参数(管的长度和沿叶片跨度的位置以及激活水平)模拟扭转的传递。第二个模块接收作为输入的修正扭转定律和更新的机械特征,由于SMA,并在输出中给出系统产生的性能估计。在概述了输入和输出参数及其交联之后,给出了SMA预测核心的描述。然后组织了一个参数化来说明变形系统对叶片和扭转规律的影响。在此基础上,实现了一个额外的参数化,现在重点关注对所建议系统性能的影响。
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引用次数: 4
DNA Nanotechnologies for the Design of Bio-Inspired Soft Nanocomposites With Reversible Rigidity DNA纳米技术用于设计具有可逆刚性的仿生软纳米复合材料
T. Calais, T. Stalin, V. S. Joseph, P. Alvarado
Structures and mechanisms in soft robotics are primarily based on chemically versatile species such as hydrogels, polymers, or elastomers, thus offering great potential for the design of adaptive core properties. In particular, tunable rigidity is highly desirable to enable control of soft grippers or for advanced robot locomotion. However, most of the strategies explored so far rely on mechanisms, such as phase transitions or shape memory effects, that require heavy external hardware or have a limited range of tunable rigidity. In this work, we propose a novel strategy inspired by the sea cucumber dermis mechanism. High aspect ratio carbon nanotubes (CNTs) are reversibly interconnected by DNA oligonucleotides within a polyacrylamide (PAAm) hydrogel. The combination of the excellent mechanical properties of CNTs and the reversible hybridization of DNA strands into a stable double-helicoidal structure allowed the reversible tunability of mechanical properties over one order of magnitude (from ∼100 Pa to ∼1 kPa) within minutes by increasing the temperature beyond the melting temperature of DNA strands (∼50 °C). First, the functionalization strategy of CNTs with DNA strands is described and characterized. The aggregation of CNTs driven by the DNA hybridization is then demonstrated. The mechanical properties of hydrogels functionalized with CNTs are finally analyzed using rheology measurements.
软机器人的结构和机制主要基于化学上通用的物质,如水凝胶、聚合物或弹性体,因此为自适应核心特性的设计提供了巨大的潜力。特别是,可调刚度是非常可取的,以使控制软抓手或先进的机器人运动。然而,迄今为止探索的大多数策略都依赖于机制,例如相变或形状记忆效应,这些机制需要大量的外部硬件或具有有限的可调刚度范围。在这项工作中,我们提出了一种受海参真皮层机制启发的新策略。高纵横比碳纳米管(CNTs)在聚丙烯酰胺(PAAm)水凝胶中通过DNA寡核苷酸可逆地相互连接。CNTs优异的机械性能与DNA链可逆杂交形成稳定的双螺旋结构相结合,通过将温度提高到DNA链的熔化温度(~ 50℃)以上,可以在几分钟内实现机械性能的可逆可调性超过一个数量级(从~ 100 Pa到~ 1 kPa)。首先,对碳纳米管与DNA链的功能化策略进行了描述和表征。然后证明了由DNA杂交驱动的碳纳米管聚集。最后通过流变学测量分析了CNTs功能化水凝胶的力学性能。
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引用次数: 1
A Piezocomposite Solid-State Rotor: Theoretical Analysis of Thrust and Efficiency Metrics 一种压电复合材料固态转子:推力和效率指标的理论分析
Taís Carneiro Ferreira de Castro, O. Bilgen
This paper presents a summary on the ongoing research and development of a solid-state piezoelectric composite rotor design for use in rotary systems. The paper focuses on the theoretical analysis of a two-bladed rotor with varying parameters such as flight speed, blade pitch angle, and rotational speed. XROTOR, a blade element method based software, is used for analysis. The two-dimensional aerodynamic characteristics are acquired from the previous research on a Macro-Fiber Composite actuated simply supported thin airfoil. A set of simulations are conducted to determine the best geometric configuration, so the piezoelectric increase in thrust is maximized. The proposed hub-rotor system has the potential to be implemented in unmanned-aerial-vehicles such as single-rotor, tandem-rotor, multi-copter, and ducted-fan rotorcraft, or other rotating systems such as wind turbines, turbine engines, and marine propellers. This paper presents a summary of previous findings on a solid-state rotor prototype, and a new investigation on the theoretical aerodynamic behavior.
本文综述了用于旋转系统的固态压电复合转子设计的研究和发展。本文主要对飞行速度、桨叶俯仰角和转速等参数变化时的双叶旋翼进行了理论分析。采用基于叶片单元法的XROTOR软件进行分析。通过对宏纤维复合材料驱动简支薄翼型的研究,获得了二维气动特性。通过一组仿真来确定最佳几何构型,使压电式推力增量最大化。所提出的轮毂-旋翼系统有潜力应用于无人飞行器,如单旋翼、串联旋翼、多旋翼和导管风扇旋翼机,或其他旋转系统,如风力涡轮机、涡轮发动机和船用螺旋桨。本文综述了固态转子原型机的研究成果,并对其理论气动性能进行了新的研究。
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引用次数: 0
Totipotent Cellularly-Inspired Materials 全能细胞启发材料
Samuel I. Mattern-Schain, Mary-Anne Nguyen, Tayler M. Schimel, J. Manuel, Joshua J. Maraj, D. Leo, E. Freeman, S. Lenaghan, S. A. Sarles
This work draws inspiration from totipotent cellular systems to design smart materials whose compositions and properties can be learned or evolved. Totipotency refers to the inherent genetic potential of a single cell to adapt and produce all types of differentiated cells within an organism. To study this principal and apply it synthetically, tissue-like compartmentalized assemblies are constructed via lipid membrane-separated aqueous droplets in a hydrophobic medium through the droplet interface bilayer (DIB) method. Within our droplets, we explore synthetic totipotency via cell-free reactions including actin polymerization and cell free protein synthesis (CFPS). The transcription and translation of our CFPS reactions are controlled by stimuli-responsive riboswitches (RS). Via this scheme, adaptable material properties and functions are achieved in vitro via protein production from cell-free machinery administered through RS governance. Here, we present thermally or chemically-triggered riboswitches for orthogonal production of representative fluorescent protein products, as well functional proteins. To characterize the material properties of target proteins, we study the formation of polymerized actin shells to stabilize organically-encased droplets and span DIBs. We present a modified protocol for chemically-triggered actin polymerization as well as a thermally triggered actin RS. We characterize theophylline (TP)-triggered production of alpha hemolysin (α-HL) through CFPS and synthesized an organic-soluble trigger that can be sensed from the oil phase by a RS in an aqueous bioreactor droplet. We also demonstrate increased droplet conductivity when CFPS α-HL products are incorporated in DIBs. This interdisciplinary work involves cell culture, gene expression, organic synthesis, vesicle formation, protein quantification, tensiometry, droplet aspiration, microplate fluorescence/absorption experiments, fluorescent microscopy, and electrophysiology. This project is an essential design analysis for creating smart, soft materials using synthetic biology and provides motivation for artificial tissues capable of adapting in response to external stimuli.
这项工作从全能细胞系统中获得灵感,设计出成分和性能可以学习或进化的智能材料。全能性指的是单个细胞内在的遗传潜能,能够适应并产生生物体内所有类型的分化细胞。为了研究并综合应用这一原理,采用液滴界面双层(DIB)方法,在疏水介质中以脂膜分离的水滴为载体构建了类组织的区隔化组装体。在我们的液滴中,我们通过无细胞反应探索合成全能性,包括肌动蛋白聚合和无细胞蛋白质合成(CFPS)。我们的CFPS反应的转录和翻译是由刺激反应性核糖开关(RS)控制的。通过这种方案,适应性材料的特性和功能通过RS管理下的无细胞机器在体外产生蛋白质来实现。在这里,我们提出了热或化学触发的核糖体开关,用于正交生产代表性荧光蛋白产品,以及功能蛋白。为了表征靶蛋白的材料特性,我们研究了聚合肌动蛋白壳的形成,以稳定有机包裹的液滴和跨dib。我们提出了一种改进的化学触发肌动蛋白聚合和热触发肌动蛋白聚合的方案。我们通过CFPS表征了茶碱(TP)触发α溶血素(α-HL)的产生,并合成了一种有机可溶性触发物,可以在水生物反应器液滴中通过RS从油相检测。当CFPS α-HL产物加入到dib中时,我们也证明了液滴导电性的提高。这项跨学科的工作涉及细胞培养、基因表达、有机合成、囊泡形成、蛋白质定量、张力测定、液滴滴吸、微孔板荧光/吸收实验、荧光显微镜和电生理学。该项目是利用合成生物学创造智能、柔软材料的基本设计分析,并为能够适应外部刺激的人工组织提供动力。
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引用次数: 1
Feedback Control of SMA-Wires for Position Determination: A Comparison of the Behavior Under Vacuum and Standard Conditions 用于位置确定的sma线的反馈控制:真空和标准条件下的行为比较
R. Roj, P. Dültgen, F. Schummer, S. Langbein
The possibilities of a technical application of the shape memory effect are comprehensive and widespread. Besides the usage of arbitrary geometries, e.g. in the medical sector, especially wires are of great interest for unlocking mechanisms or other kinds of actuators. One of the challenges of the application of shape memory alloys (SMA) is the small deformation factor that prevents actuations with large travels. A second property that is usually seen as a disadvantage is the thermal dependence of the position. It leads to the necessity of comparably high electrical power for holding a location, as the cooling has to be compensated constantly. Therefore, SMA are usually not in use for such applications. For special environments, this effect can still be an advantage. By using an SMA driven positioning actuator in vacuum, the low loss of heat leads to a very precise and low power consuming alignment. Such actuators can be used for example in satellites. This paper presents an analysis of the properties under atmospheric conditions in comparison to the behavior in vacuum. Along with a comprehensive interpretation of the experimental results, further characteristics, like the functional and structural fatigue, are presented in detail.
形状记忆效应技术应用的可能性是全面和广泛的。除了任意几何形状的使用,例如在医疗部门,特别是电线对于解锁机制或其他类型的执行器非常感兴趣。形状记忆合金(SMA)应用的挑战之一是小的变形系数,这阻碍了大行程的驱动。第二个通常被视为缺点的性质是位置的热依赖性。这导致需要相当高的电力来保持一个位置,因为冷却必须不断补偿。因此,SMA通常不用于此类应用。对于特殊环境,这种效果仍然是一种优势。通过在真空中使用SMA驱动的定位执行器,低热量损失导致非常精确和低功耗的校准。这种致动器可用于例如卫星。本文分析了其在大气条件下的性能,并与在真空条件下的性能进行了比较。随着实验结果的综合解释,进一步的特征,如功能和结构疲劳,详细介绍。
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引用次数: 1
Towards Highly Reconfigurable Carbon Fiber Composite 迈向高度可重构碳纤维复合材料
A. Casalotti, G. Lanzara, Matthew P. Snyder
This article discusses an approach to develop innovative carbon fiber composites that have the capability to change shape according to a prescribed input. The approach is based on the study of specific stacking sequences of unidirectional fiber plies cured on a curved mold. The effects of the above-mentioned aspects are investigated on the manufactured specimen. The combined thermo-mechanical response is investigated by performing mechanical tests at various prescribed temperatures and the intensity of the shape change is evaluated together with the corresponding stiffness variation. The experimental campaign is mostly devoted to characterize the response of the manufactured sample and demonstrate the great capability of the proposed approach to develop a smart material with enhanced shape and stiffness variation according the prescribed input.
本文讨论了一种开发创新碳纤维复合材料的方法,该复合材料具有根据规定输入改变形状的能力。该方法是基于在弯曲模具上固化单向纤维层的特定堆叠顺序的研究。研究了上述各方面对试样的影响。通过在不同的规定温度下进行力学试验,研究了热-力联合响应,并评估了形状变化的强度以及相应的刚度变化。实验活动主要致力于表征制造样品的响应,并证明所提出的方法能够根据规定的输入开发具有增强形状和刚度变化的智能材料。
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引用次数: 1
Preliminary Experimental Investigation of Control Parameters for the Electroresistive Heating of SMA Knitted Textiles SMA针织物电阻加热控制参数的初步实验研究
Rachel Marbaker, B. Utter, K. Eschen, J. Abel
Knitted textiles manufactured from shape memory alloy (SMA) monofilaments possess advanced capabilities for distributed and complex actuation and are suited for a range of emerging needs in aerospace, biomedical, and robotics applications. In general, high currents for short periods of time provide sufficient electroresistive (Joule) heat to cause SMA wires to transform to austenite. However, SMA knitted textiles are difficult to electroresistively heat because the interlocking knit structure short-circuits the flow of current, causing localized overheating and isolating the transformation of the material along the current path. One approach for heating SMA knitted textiles is to drive pulses of high current between pairs of electrodes positioned across horizontal courses (rows) of knitted loops. This research presents a preliminary experimental investigation of the effects of factors related to electroresistive heating for SMA knitted textiles. A design of experiments analysis with two levels of four factors was conducted using a 24–1 fractional factorial design. The factors included the voltage of the power supply connected to the current amplifiers; a geometric factor defining the horizontal spacing of the electrodes attached to the knit sample; and two waveform factors: On Cycles and Off/On Cycles, which defined the length of time each current amplifier was enabled and disabled. Actuation performance was quantified by the actuation displacement and actuation force of the knit sample. Preliminary results suggest that voltage is the most influential factor, but also indicate that interactions between the geometric and waveform factors have significant effects on the heating and actuation performance. The characterization of these factor interactions has the potential to inform optimal electroresistive heating approaches for SMA knitted textiles, enabling integration into applications such as wearable technologies where convective heating is not practical.
由形状记忆合金(SMA)单丝制造的针织纺织品具有先进的分布式和复杂驱动能力,适用于航空航天,生物医学和机器人应用中的一系列新兴需求。一般来说,短时间的高电流提供足够的电阻(焦耳)热,使SMA丝转变为奥氏体。然而,SMA针织物很难电阻加热,因为联锁的针织结构使电流短路,导致局部过热并隔离材料沿着电流路径的转变。加热SMA针织物的一种方法是驱动位于针织物环的水平路线(行)上的电极对之间的大电流脉冲。本研究对SMA针织物电阻加热相关因素的影响进行了初步的实验研究。采用24-1分数因子设计,进行两水平四因子试验分析设计。这些因素包括连接到电流放大器的电源电压;定义附着在编织样品上的电极的水平间距的几何因子;和两个波形因素:开周期和关/开周期,它定义了每个电流放大器被启用和禁用的时间长度。通过织物试样的驱动位移和驱动力来量化驱动性能。初步结果表明,电压是影响最大的因素,但几何和波形因素之间的相互作用对加热和驱动性能有显著影响。这些因素相互作用的表征有可能为SMA针织纺织品的最佳电阻加热方法提供信息,使其能够集成到诸如对流加热不可用的可穿戴技术等应用中。
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引用次数: 1
Implementation and Investigation of a Compact, Powerful System for Diagnosis and Control of Shape Memory Alloys in Technical Applications 一种结构紧凑、功能强大的形状记忆合金技术应用诊断与控制系统的实现与研究
M. Kaiser, Nils Neblung, M. Gurka
In this paper we present the development, implementation and testing of a compact system for diagnosis and control of actuators based on metallic shape memory alloys (SMA). Using NiTi-SMA, very compact, cost-effective and lightweight actuation systems can be realized. In applications where the SMA is activated by internal Joule heating or its condition is diagnosed by the self-sensing of its electrical resistance, an electrical system capable of reliably measuring very small resistance changes (< 1 ohm) without affecting the phase-state of the SMA is required. In addition, the system must offer the possibility to evaluate the nonlinear, hysteresis-afflicted behavior of the SMA and to handle this difficulty, e.g. utilizing a model-based control. This paper presents a simple compact and adaptive system based on a microcontroller that meets these requirements. Detailed functional tests were carried out with the system to establish a correlation between the change in electrical resistance in the range < 200 mOhm and the current strain state of the actuator. For this purpose, a first series of tests was performed, with the SMA wires working against a constant load. In a second tests series, the SMA wires worked against springs of different stiffness. The use of a microcontroller enables simple implementation of different control strategies. The control system for the non-linear resistance change utilizes a fuzzy logic which divides the control algorithm into three regimes. In the regime of the martensitic phase transformation a PI-controller is used. The state of actuators with an absolute electrical resistance < 1 Ohm and a resistance change < 200 mohm associated with the phase transformation can be precisely measured and controlled with an accuracy < 10 mohm. The system can be configured with little effort for different tasks and shape memory systems of different sizes. Furthermore, it is possible to implement more complex control algorithms up to model-based controllers.
本文介绍了一种基于金属形状记忆合金(SMA)的紧凑型致动器诊断与控制系统的开发、实现和测试。使用NiTi-SMA,可以实现非常紧凑、经济、轻便的驱动系统。在SMA通过内部焦耳加热激活或通过其电阻的自感知来诊断其状况的应用中,需要能够可靠地测量非常小的电阻变化(< 1欧姆)而不影响SMA的相态的电气系统。此外,系统必须提供评估SMA的非线性、迟滞行为的可能性,并处理这一困难,例如利用基于模型的控制。本文提出了一种基于单片机的简单紧凑的自适应系统,满足了这些要求。对该系统进行了详细的功能测试,建立了< 200 mOhm范围内电阻变化与执行器电流应变状态之间的相关性。为此,首先进行了一系列测试,SMA钢丝在恒定负载下工作。在第二个测试系列中,SMA钢丝与不同刚度的弹簧一起工作。使用微控制器可以简单地实现不同的控制策略。非线性电阻变化的控制系统采用模糊逻辑,将控制算法分为三种状态。在马氏体相变过程中,采用pi控制器。对于绝对电阻< 1欧姆和与相变相关的电阻变化< 200欧姆的致动器状态,可以精确测量和控制,精度< 10欧姆。该系统可以轻松配置不同的任务和不同大小的形状记忆系统。此外,还可以实现更复杂的控制算法,甚至是基于模型的控制器。
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引用次数: 0
Nanocomposite Coating for Strain Monitoring 应变监测用纳米复合涂层
Erika Magnafico, F. Poli, A. Casalotti, G. Lanzara
In recent years carbon nanotubes (CNTs) have been widely used for the realization of polymeric matrix nanocomposites for strain monitoring applications in civil, biomedical and aerospace engineering. In fact, by embedding CNTs in an insulated polymer matrix, it is possible to realize a conductive nanocomposite with piezoresistive behaviour which allows to monitor the occurring strains through an electrical resistance change. In this work a conductive coating made of Multi-Walled Carbon Nanotubes (MWNTs) and PolymethylMethacrilate (PMMA) is fabricated and is applied onto a fiberglass structure surface. In order to characterize the electrical behaviour of the coating and its capability to sense strain, an experimental campaign is carried out by applying a voltage to the manufactured coating. Its variations throughout the surface in the longitudinal and transverse directions are then evaluated to identify the electric field distribution and its dependence on strain.
近年来,碳纳米管(CNTs)被广泛用于实现聚合物基纳米复合材料在民用、生物医学和航空航天工程中的应变监测应用。事实上,通过在绝缘聚合物基体中嵌入碳纳米管,可以实现具有压阻行为的导电纳米复合材料,从而可以通过电阻变化来监测发生的应变。在这项工作中,制造了一种由多壁碳纳米管(MWNTs)和聚甲基丙烯酸甲酯(PMMA)制成的导电涂层,并将其应用于玻璃纤维结构表面。为了表征涂层的电学性能及其感应应变的能力,通过对制造的涂层施加电压来进行实验。然后评估其在纵向和横向上在整个表面上的变化,以确定电场分布及其对应变的依赖。
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引用次数: 0
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ASME 2019 Conference on Smart Materials, Adaptive Structures and Intelligent Systems
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