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Efficiency and effectiveness of systems for the treatment of domestic wastewater based on subsurface flow constructed wetlands in Jarabacoa, Dominican Republic 多米尼加共和国Jarabacoa地下流人工湿地处理生活污水系统的效率和效果
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-04 DOI: 10.1016/j.wse.2023.08.004
Yvelisse Pérez , Enmanuel Vargas , Daniel García-Cortés , William Hernández , Humberto Checo , Ulises Jáuregui-Haza

Constructed wetlands (CW) are well known nature-based systems for water treatment. This study evaluated the efficiency and effectiveness of seven domestic wastewater treatment systems based on horizontal flow CWs in Jarabacoa, the Dominican Republic. The results showed that the CWs were efficient in reducing the degree of contamination of wastewater to levels below the Dominican wastewater discharge standards for parameters such as the 5-day biochemical oxygen demand (BOD5) and chemical oxygen demand, but not for the removal of phosphorus and fecal coliforms. In addition, a horizontal flow subsurface wetland in the peri-urban area El Dorado was evaluated in terms of the performance of wastewater treatment in tropical climatic conditions. The concentrations of heavy metals, such as zinc, copper, chromium, and iron, were found to decrease in the effluent of the wetland, and the concentrations for nickel and manganese tended to increase. The levels of heavy metals in the effluent were lower than the limit values of the Dominican wastewater discharge standards. The construction cost of these facilities was around 200 USD per population equivalent, similar to the cost in other countries in the same region. This study suggested some solutions to the improved performance of CWs: selection of a microbial flora that guarantees the reduction of nitrates and nitrites to molecular nitrogen, use of endemic plants that bioaccumulate heavy metals, combination of constructed wetlands with filtration on activated carbon, and inclusion of water purification processes that allow to evaluate the reuse of treated water.

人工湿地(CW)是众所周知的基于自然的水处理系统。这项研究评估了多米尼加共和国哈拉瓦科阿以水平流式人工湿地为基础的七个生活废水处理系统的效率和效果。结果表明,在 5 天生化需氧量 (BOD5) 和化学需氧量等参数方面,化武处理系统能有效地将废水污染程度降低到低于多米尼加废水排放标准的水平,但在去除磷和粪大肠菌群方面却不尽人意。此外,还对埃尔多拉多城郊地区的一个水平流地下湿地在热带气候条件下的废水处理性能进行了评估。结果发现,湿地污水中锌、铜、铬和铁等重金属的浓度有所下降,而镍和锰的浓度则呈上升趋势。污水中的重金属含量低于多米尼加废水排放标准的限值。这些设施的建设成本约为 200 美元/人口当量,与同一地区其他国家的成本类似。这项研究提出了一些提高化学武器性能的解决方案:选择能确保将硝酸盐和亚硝酸盐还原为分子氮的微生物菌群,使用能对重金属进行生物累积的地方植物,将建造湿地与活性炭过滤相结合,以及纳入水净化工艺,以便对处理后水的再利用进行评估。
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引用次数: 0
Preparation and application of Ag–Ce–O composite metal oxide catalyst in catalytic ozonation for elimination of Reactive Black 5 dye from aqueous media Ag-Ce-O复合金属氧化物催化剂的制备及其在臭氧氧化去除水中活性黑5染料中的应用
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.08.005
Nikita P. Chokshi, Abhi Chauhan, Rahul Chhayani, Sandip Sharma, Jayesh P. Ruparelia

It is necessary to treat textile effluents before discharging them into natural water bodies as they harm the environment. Compared to conventional treatment methods, catalytic ozonation has gained attention due to its effectiveness in removing refractory organic pollutants. In this study, the coprecipitation method was used to synthesize a composite metal oxide of silver and cerium oxide, and the synthesized catalyst was used to eliminate the Reactive Black 5 (RB5) dye. X-ray diffraction, scanning electron microscopic, and Brunauer–Emmett–Teller surface area analyses were performed to characterize the synthesized catalyst. Afterwards, relevant experimental parameters, such as pH, ozone and catalyst dosages, and initial dye concentration, were investigated. The experiments revealed that the optimal experimental conditions were a pH value of 10, a catalyst dosage of 0.7 g/L, and an ozone dosage of 60 L/h. In these optimized conditions, the RB5 dye was entirely removed, and a chemical oxygen demand removal efficiency of 88% was achieved within a reaction time of 80 min. Furthermore, the recycling potential of the catalyst was tested for three cycles, and no deterioration in its activity was observed. Additionally, studies were conducted using a hydroxyl radical scavenger in order to understand the reaction pathway of the system. As a result, the indirect pathway was more dominant than the direct pathway in the system.

纺织污水会对环境造成危害,因此有必要在排放到自然水体之前对其进行处理。与传统的处理方法相比,催化臭氧法因其在去除难降解有机污染物方面的有效性而备受关注。本研究采用共沉淀法合成了银和氧化铈的复合金属氧化物,并利用合成的催化剂去除活性黑 5(RB5)染料。对合成的催化剂进行了 X 射线衍射、扫描电子显微镜和布鲁瑙尔-艾美特-泰勒表面积分析。随后,研究了相关的实验参数,如 pH 值、臭氧和催化剂用量以及初始染料浓度。实验结果表明,最佳实验条件为 pH 值为 10、催化剂用量为 0.7 g/L、臭氧用量为 60 L/h。在这些优化条件下,RB5 染料被完全去除,在 80 分钟的反应时间内,化学需氧量去除率达到 88%。此外,还对催化剂的回收潜力进行了三次循环测试,结果表明催化剂的活性没有下降。此外,还使用羟基自由基清除剂进行了研究,以了解该系统的反应途径。结果表明,在该系统中,间接途径比直接途径更占优势。
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引用次数: 0
Efficient degradation of dye pollutants in wastewater via photocatalysis using a magnetic zinc oxide/graphene/iron oxide-based catalyst 磁性氧化锌/石墨烯/氧化铁基催化剂光催化高效降解废水中的染料污染物
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.01.004
Piyawan Nuengmatcha , Arnannit Kuyyogsuy , Paweena Porrawatkul , Rungnapa Pimsen , Saksit Chanthai , Prawit Nuengmatcha

In this paper, we present a proof-of-concept study of the enhancement of photocatalytic activity via a combined strategy of fabricating a visible-light responsive ternary heterostructure and improving overall photostability by incorporating magnetic zinc oxide/graphene/iron oxide (ZGF). A solvothermal approach was used to synthesize the catalyst. X-ray diffraction (XRD), scanning electron microscopic, energy dispersive X-ray, transmission electron microscopic, vibrating sample magnetometric, and ultraviolet–visible diffuse reflectance spectroscopic techniques were used to characterize the synthesized samples. The obtained optimal Zn(NO3)2 concentration, temperature, and heating duration were 0.10 mol/L, 600°C, and 1 h, respectively. The XRD pattern revealed the presence of peaks corresponding to zinc oxide, graphene, and iron oxide, indicating that the ZGF catalyst was effectively synthesized. Furthermore, when the developed ZGF was used for methylene blue dye degradation, the optimum irradiation time, dye concentration, catalyst dosage, irradiation intensity, and solution pH were 90 min, 10 mg/L, 0.03 g/L, 100 W, and 8.0, respectively. Therefore, the synthesized ZGF system could be used as a catalyst to degrade dyes in wastewater samples. This hybrid nanocomposite consisting of zinc oxide, graphene, and iron oxide could also be used as an effective photocatalytic degrader for various dye pollutants.

在本文中,我们提出了一项概念验证研究,通过制造可见光响应三元异质结构和通过加入磁性氧化锌/石墨烯/氧化铁(ZGF)提高整体光稳定性的组合策略来增强光催化活性。采用溶剂热法合成催化剂。采用x射线衍射(XRD)、扫描电镜、能量色散x射线、透射电镜、振动样品磁强学、紫外-可见漫反射光谱等技术对合成样品进行表征。得到的最佳Zn(NO3)2浓度为0.10 mol/L,温度为600℃,加热时间为1 h。XRD谱图显示了氧化锌、石墨烯和氧化铁对应峰的存在,表明ZGF催化剂得到了有效的合成。制备的ZGF用于亚甲基蓝染料降解时,最佳辐照时间为90 min,最佳染料浓度为10 mg/L,最佳催化剂用量为0.03 g/L,最佳辐照强度为100 W,最佳溶液pH为8.0。因此,合成的ZGF体系可作为降解废水中染料的催化剂。这种由氧化锌、石墨烯和氧化铁组成的杂化纳米复合材料也可以作为各种染料污染物的有效光催化降解剂。
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引用次数: 4
Assessment of first-order-moment-based sample reconstruction method for design flood estimation in changing environment 基于一阶矩的样本重建方法在变化环境下的设计洪水估算评估
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.05.001
Yi-ming Hu, Zhong-min Liang, Yi-xin Huang, Jun Wang, Bin-quan Li

Estimating the design flood under nonstationary conditions is challenging. In this study, a sample reconstruction approach was developed to transform a nonstationary series into a stationary one in a future time window (FTW). In this approach, the first-order moment (EFTW) of an extreme flood series in the FTW was used, and two possible methods of estimating EFTW values in terms of point values and confidence intervals were developed. Three schemes were proposed to analyze the uncertainty of design flood estimation in terms of sample representativeness, uncertainty from EFTW estimation, and both factors, respectively. To investigate the performance of the sample reconstruction approach, synthesis experiments were designed based on the annual peak series of the Little Sugar Creek in the United States. The results showed that the sample reconstruction approach performed well when the high-order moment of the series did not change significantly in the specified FTW. Otherwise, its performance deteriorated. In addition, the uncertainty of design flood estimation caused by sample representativeness was greater than that caused by EFTW estimation.

估计非平稳条件下的设计洪水是一项具有挑战性的工作。在本研究中,开发了一种样本重建方法,将非平稳序列在未来时间窗(FTW)中转换为平稳序列。该方法利用极端洪水序列的一阶矩,提出了用点值和置信区间估计极端洪水序列一阶矩的两种可能方法。针对设计洪水估算的不确定性,分别从样本代表性、EFTW估算的不确定性和两者的不确定性三个方面提出了三种方案。为了考察样本重建方法的性能,以美国小糖溪(Little Sugar Creek)的年峰序列为基础设计了合成实验。结果表明,当序列的高阶矩在指定的FTW内变化不显著时,样本重构方法表现良好。否则,其性能会下降。此外,样本代表性对设计洪水估算的不确定性大于EFTW估算的不确定性。
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引用次数: 0
Impact of backwater on water surface profile in curved channels 回水对弯曲河道水面剖面的影响
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.04.006
Rui-hua Nie , Qi-hang Zhou , Wen-jie Li , Xing-nian Liu , Gang Xie , Lu Wang

Owing to extensive construction of dams, the impact of backwater on flow may lead to navigation or flood control issues in curved channels. To date, the impact of backwater on the water surface profile in curved channels remains unknown and requires investigation. In this study, experiments were conducted in a glass-walled recirculating flume with a length of 19.4 m, a width of 0.6 m, and a depth of 0.8 m, and the impact of backwater on the water surface profile in a 90° channel bend was investigated. The experimental results showed that the backwater degree had a significant impact on the transverse and longitudinal flow depth distributions in the bend. The transverse slope of the flow (Jr) increased linearly with an increase in the Froude number of the approach flow upstream of the bend. Jr increased with the longitudinal location parameter ξ when −0.2 < ξ < 0.5, and decreased with ξ when 0.5 < ξ < 1.2. Furthermore, the results showed that Jr asymptotically decreased to zero with an increase in the degree of backwater. An equation was formulated to estimate the transverse slope of the flow in a 90° bend in backwater zones.

由于水坝的广泛建设,回水对水流的影响可能导致弯曲河道的航行或防洪问题。迄今为止,回水对弯曲河道水面剖面的影响尚不清楚,需要进一步研究。本研究在长19.4 m、宽0.6 m、深0.8 m的玻璃壁循环水槽中进行实验,研究回水对90°弯道水面剖面的影响。实验结果表明,回水程度对弯道内横向和纵向流动深度分布均有显著影响。随着弯道上游进流弗劳德数的增加,流的横向斜率(Jr)呈线性增加。当- 0.2 <时,Jr随纵向位置参数ξ的增大而增大;ξ& lt;0.5, 0.5 <时随ξ值减小;ξ& lt;1.2. 结果表明,随着回水程度的增加,Jr逐渐减小到零。建立了一个方程来估计回流区90°弯道水流的横向斜率。
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引用次数: 0
Anthropogenic disturbance of aquatic biodiversity and water quality of an urban river in Penang, Malaysia 马来西亚槟城城市河流水生生物多样性和水质的人为干扰
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.01.003
Nur Azalina Suzianti Feisal , Noor Haziqah Kamaludin , Muhammad Firdaus Abdullah Sani , Dayang Khairulnisa Awang Ahmad , Mohd Azwan Ahmad , Nur Faiza Abdul Razak , Tengku Nilam Baizura Tengku Ibrahim

Malaysia's rapid economic and demographic development have placed negative pressure on its water supplies and the quality of the Juru River, which is close to the nation's capital and its major source of water. Healthy aquatic ecosystems are supported by physicochemical properties and biological diversity. This study evaluated the anthropogenic impacts on aquatic biodiversity, especially plankton, fish, and macrobenthos, as well as the water quality of the Juru River in the Penang area. Aquatic biodiversity and river water parameters were collected from ten sampling stations along the Juru River. Seven variables were used to assess the physicochemical environment: pH, temperature, total suspended solids (TSS), salinity, dissolved oxygen (DO), biochemical oxygen demand (BOD), and chemical oxygen demand. At each sampling station, the total number of plankton, fish, and macrobenthic taxa were counted and analyzed. The relationships between the physicochemical parameters and aquatic biodiversity were investigated with biotypological analysis, principal component analysis, hierarchical cluster analysis, and linear regression analysis. These analyses showed that the richness and diversity indices were generally influenced by salinity, temperature, TSS, BOD, and pH. The data obtained in this study supported the bioindicator concept. The findings, as they related to scientifically informed conservation, could serve as a model for Juru River management, as well as for river management throughout Malaysia and other tropical Asian countries.

马来西亚快速的经济和人口发展给其供水和Juru河的水质带来了负面压力,Juru河靠近该国的首都和主要水源。健康的水生生态系统是由物理化学性质和生物多样性支持的。本研究评估了人类活动对槟城地区巨鹭河水生生物多样性,特别是浮游生物、鱼类和大型底栖动物的影响,以及对水质的影响。在巨如河沿岸10个采样站采集了水生生物多样性和河流水质参数。采用pH、温度、总悬浮固体(TSS)、盐度、溶解氧(DO)、生化需氧量(BOD)和化学需氧量这7个变量来评价理化环境。在每个采样点,对浮游生物、鱼类和大型底栖动物分类群的总数进行了统计和分析。采用生物类型学分析、主成分分析、层次聚类分析和线性回归分析等方法研究了理化参数与水生生物多样性的关系。这些分析表明,丰富度和多样性指数普遍受盐度、温度、TSS、BOD和ph的影响,本研究获得的数据支持生物指标的概念。这些发现与科学保护有关,可以作为Juru河管理的模型,也可以作为马来西亚和其他热带亚洲国家河流管理的模型。
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引用次数: 4
Insights into remediation technology for malachite green wastewater treatment 孔雀石绿废水处理修复技术探讨
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.03.002
Peter Olusakin Oladoye , Timothy Oladiran Ajiboye , Wycliffe Chisutia Wanyonyi , Elizabeth Oyinkansola Omotola , Mayowa Ezekiel Oladipo

Malachite green (MG) dye is a common industrial dye and organic contaminant that can be found in (waste)water. Textile and food industries make use of MG as dyeing and food coloring agents, respectively. However, MG is both genotoxic and mutagenic. Hence, the elimination of MG from MG-laden-wastewater is germane. This review summarizes up-to-date researches that have been reported in literature as regards the decontamination of toxic MG wastewater. Various removal methods (adsorption, membrane, Fenton system, and heterogenous and homogeneous photodegradation) were discussed. Of the two basic technologies that are comprehensively explored and reviewed, chemical treatment methods are not as viable as physical removal methods, such as the adsorption technology, due to the lack of secondary pollutant production, simple design, low operation costs, and resource availability. This review also presents various practical knowledge gaps needed for large-scale applications of adsorptive removal methods for MG. It concludes by recommending further research on the techniques of cheap and simple decontamination of MG to get clean water.

孔雀绿(MG)染料是一种常见的工业染料,也是废水中常见的有机污染物。纺织和食品工业分别使用MG作为染色剂和食品着色剂。然而,MG具有遗传毒性和诱变性。因此,从含MG的废水中去除MG是密切相关的。本文综述了文献中关于有毒MG废水净化的最新研究。讨论了各种去除方法(吸附法、膜法、芬顿体系法、非均匀和均匀光降解法)。在全面探索和审查的两项基础技术中,由于缺乏二次污染物生产、设计简单、运行成本低、资源可用性,化学处理方法不如物理去除方法(如吸附技术)可行。这篇综述还提出了MG吸附去除方法大规模应用所需的各种实际知识空白。最后,建议进一步研究廉价、简单的MG净化技术,以获得清洁的水。
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引用次数: 4
Evaluation of toppling rock slopes using a composite cloud model with DEMATEL–CRITIC method 基于DEMATEL-CRITIC方法的复合云模型对倾倒岩质边坡的评价
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.04.002
Huan-ling Wang , Xu-fei Zhao , Hong-jie Chen , Kui Yi , Wei-chau Xie , Wei-ya Xu

Safety evaluation of toppling rock slopes developing in reservoir areas is crucial. To reduce the uncertainty of safety evaluation, this study developed a composite cloud model, which improved the combination weights of the decision-making trial and evaluation laboratory (DEMATEL) and criteria importance through intercriteria correlation (CRITIC) methods. A safety evaluation system was developed according to in situ monitoring data. The backward cloud generator was used to calculate the numerical characteristics of a cloud model of quantitative indices, and different virtual clouds were used to synthesize some clouds into a generalized one. The synthesized numerical characteristics were calculated to comprehensively evaluate the safety of toppling rock slopes. A case study of a toppling rock slope near the Huangdeng Hydropower Station in China was conducted using monitoring data collected since operation of the hydropower project began. The results indicated that the toppling rock slope was moderately safe with a low safety margin. The composite cloud model considers the fuzziness and randomness of safety evaluation and enables interchange between qualitative and quantitative knowledge. This study provides a new theoretical method for evaluating the safety of toppling rock slopes. It can aid in the predication, control, and even prevention of disasters.

库区倾倒岩质边坡发育的安全性评价至关重要。为了降低安全评价的不确定性,本研究建立了复合云模型,通过准则间相关性(CRITIC)方法提高了决策试验与评价实验室(DEMATEL)和准则重要性(criterion importance)的组合权重。根据现场监测数据,建立了安全评价体系。利用后向云生成器计算定量指标云模型的数值特征,并利用不同的虚拟云将一些云综合成一个广义云。通过计算综合数值特征,对岩体边坡的安全性进行综合评价。利用黄登水电站投产以来的监测数据,对黄登水电站附近某岩体垮塌边坡进行了实例分析。结果表明,该倾倒岩质边坡为中等安全边坡,安全裕度较低。复合云模型考虑了安全评价的模糊性和随机性,实现了定性知识和定量知识的相互交换。该研究为评价倾倒岩质边坡的安全性提供了一种新的理论方法。它可以帮助预测、控制甚至预防灾害。
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引用次数: 3
Greenhouse gas reduction of co-benefit-type wastewater treatment system for fish-processing industry: A real-scale case study in Indonesia 鱼加工行业协同效益型废水处理系统的温室气体减排:印度尼西亚的实际案例研究
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.03.001
Yoshiteru Hamatani , Takahiro Watari , Masashi Hatamoto , Takashi Yamaguchi , Tjandra Setiadi , Toshihiko Konda

This study examined the application of co-benefit-type wastewater treatment technology in the fish-processing industry. Given that there was a dearth of information on fish-processing industrial wastewater in Indonesia, site surveys were conducted. For the entire fish-processing industry throughout the country, the dissemination rate of wastewater treatment facilities was less than 50%. Using a co-benefit approach, a real-scale swim-bed technology (SBT) and a system combining an anaerobic baffled reactor (ABR) with SBT (ABR–SBT) were installed in a fishmeal processing factory in Bali, Indonesia, and the wastewater system process performance was evaluated. In a business-as-usual scenario, the estimated chemical oxygen demand load and greenhouse gas (GHG) emissions from wastewater from the Indonesian fish-processing industry were 33 000 tons per year and 220 000 tons of equivalent CO2 per year, respectively. On the other hand, the GHG emissions in the co-benefit scenarios of the SBT system and ABR–SBT system were 98 149 and 26 720 tons per year, respectively. Therefore, introducing co-benefit-type wastewater treatment to Indonesia’s fish-processing industry would significantly reduce pollution loads and GHG emissions.

本研究探讨了协同效益型废水处理技术在鱼类加工业中的应用。由于缺乏关于印度尼西亚鱼类加工工业废水的资料,因此进行了现场调查。对于全国整个鱼类加工业来说,污水处理设施的普及率不到50%。采用协同效益的方法,在印度尼西亚巴厘岛的一家鱼粉加工厂安装了实际规模的游泳床技术(SBT)和厌氧折流板反应器(ABR)与SBT (ABR - SBT)相结合的系统,并对废水系统的处理性能进行了评估。在一切照旧的情况下,印度尼西亚鱼类加工业废水的化学需氧量负荷和温室气体(GHG)排放量估计分别为每年3.3万吨和22万吨当量二氧化碳。SBT系统和ABR-SBT系统协同效益情景下的温室气体排放量分别为98 149和26 720 t /年。因此,在印度尼西亚的鱼类加工业中引入协同效益型废水处理将显著减少污染负荷和温室气体排放。
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引用次数: 1
Effect of Froude similitude deviation on curved channel simulations: A case study in the Middle Yangtze River 弗劳德相似偏差对弯曲河道模拟的影响——以长江中游为例
IF 4 Q1 WATER RESOURCES Pub Date : 2023-09-01 DOI: 10.1016/j.wse.2023.04.005
Xiao-ting Yang , Qian-qian Shang , Hui Xu , Guo-bin Li , Ya-jun Gao , Qi-lin Yang

Froude similitude and friction similitude are the two crucial similarity conditions that are often used in physical-scale modeling of rivers. However, models often deviate from Froude similitude when dealing with real-world situations. This study developed several fixed-bed river models with various curvatures to determine the effect of Froude similitude deviation on curved channel modeling. Models were constructed according to the characteristics of the Middle Yangtze River. Differences in longitudinal slope, transverse slope, and main stream line location were measured by varying Froude similitude deviation. The deviations of longitudinal slope and velocity were negligible because friction similitude was accounted for. The transverse slope varied significantly with the Froude similitude deviation, and the main stream line varied with the curvature and Froude similitude deviation. Formulae were derived to estimate the slope deviation. These analyses helped to clarify the feasibility of the method of Froude similitude deviation for curved channels.

弗劳德相似和摩擦相似是河流物理尺度建模中常用的两个关键相似条件。然而,在处理现实世界的情况时,模型经常偏离弗劳德相似。本研究建立了几种不同曲率的固定河床河流模型,以确定弗劳德相似偏差对弯曲河道建模的影响。根据长江中游的特点,建立了模型。通过不同的弗劳德相似偏差测量了纵向坡度、横向坡度和干流位置的差异。由于考虑了摩擦相似度,纵斜率和速度的偏差可以忽略不计。横向坡度随弗劳德相似偏差变化显著,主流线随曲率和弗劳德相似偏差变化显著。推导出估算斜率偏差的公式。这些分析有助于阐明弯曲通道的弗劳德相似偏差法的可行性。
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引用次数: 0
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