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Hydraulic characteristics of a large rotation-angle baffle-drop shaft through synergetic discharge from dry and wet sides 大转角折流轴干湿侧协同泄油的水力特性
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-08-23 DOI: 10.1016/j.wse.2024.08.002
Pei-de Liang , Jun Chen , Teng Wu , Jing Yan
To enhance the operational capacity and space utilization of baffle-drop shafts, this study improved the traditional baffle-drop shaft by expanding the wet-side space, incorporating large rotation-angle baffles, and installing overflow holes in the dividing wall. A three-dimensional turbulent model was developed using ANSYS Fluent to simulate the hydraulic characteristics of both traditional and new baffle-drop shafts across various flow rates. The simulation results demonstrated that the new shaft design allowed for discharge from both the wet and dry sides, significantly improving operational capacity, with the dry side capable of handling 40% of the inlet flow. Compared to the traditional shaft, the new design reduced shaft wall pressures and decreased the mean and standard deviation of pressure on typical baffles by 21% and 63%, respectively, therefore enhancing structural safety. Additionally, the new shaft achieved a 2%–12% higher energy dissipation rate than the traditional shaft across different flow rates. This study offers valuable insights for the design and optimization of drop shafts in deep tunnel drainage systems.
为提高降流竖井的运行能力和空间利用率,本研究对传统降流竖井进行了改进,扩大湿侧空间,加装大转角挡板,并在隔墙加设溢流孔。利用ANSYS Fluent软件建立了三维湍流模型,模拟了传统和新型折流轴在不同流量下的水力特性。模拟结果表明,新的竖井设计允许从湿侧和干侧排放,显著提高了运行能力,干侧能够处理40%的进口流量。与传统竖井相比,新设计降低了井壁压力,使典型挡板压力均值和标准差分别降低了21%和63%,从而提高了结构安全性。此外,在不同流量下,新型轴的能量耗散率比传统轴高2%-12%。该研究为深埋隧洞排水系统落井的设计与优化提供了有价值的见解。
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引用次数: 0
Comprehensive analysis of characteristics of dry–wet events and their transitions in Uttar Pradesh, India 印度北方邦干湿事件及其转变特征的综合分析
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-06-26 DOI: 10.1016/j.wse.2024.06.003
Shivani Gond , Ashish Kumar Agnihotri , Nitesh Gupta , P.K.S. Dikshit
Understanding the occurrence and characteristics of dry and wet events is crucial for effective disaster prevention, resource management, and risk reduction in vulnerable regions. This study analyzed the spatiotemporal patterns of dry–wet events and their transition characteristics in Uttar Pradesh, India. The standardized precipitation evapotranspiration index (SPEI) at a monthly timescale was utilized to identify hotspot regions vulnerable to concurrent and frequent dry and wet events and their transitions. The severity, duration, and intensity of dry and wet events were characterized with the run theory over SPEI time series data from 18 synoptic stations in Uttar Pradesh over 48 years (1971–2018), sourced from the Indian Institute of Tropical Meteorology and the India Meteorological Department. Multiple assessment methods were utilized to examine the interaction of these extreme events, considering characteristics such as wet–dry ratio, average transition time, and rapid transition times from wet to dry events and from dry to wet events. Average wet durations ranged from 1.27 to 1.58 months, and average dry durations ranged from 1.29 to 1.82 months. Rapid transition times from dry to wet events ranged from 2.5 to 4.1 months, and those for wet-to-dry events ranged from 2.1 to 5.3 months. The eastern region experienced a significantly high number of dry events, while the western and Bundelkhand regions experienced more intense dry events. In contrast, the eastern region had intense wet events. This research on the occurrence of dry–wet events and their transitions can provide valuable insights for government decision-making and disaster prevention and reduction efforts.
了解干湿灾害的发生和特征对脆弱地区有效的防灾、资源管理和降低风险至关重要。本研究分析了印度北方邦干湿事件的时空格局及其过渡特征。利用月尺度的标准化降水蒸散发指数(SPEI)识别干湿事件多发多发的热点地区及其转变。利用运行理论分析了北方邦18个天气站48年(1971-2018年)的SPEI时间序列数据,分析了干湿事件的严重程度、持续时间和强度,数据来源为印度热带气象研究所和印度气象部门。考虑干湿比、平均过渡时间、从湿事件到干事件和从干事件到湿事件的快速过渡时间等特征,采用多种评估方法来研究这些极端事件的相互作用。平均湿润期为1.27至1.58个月,平均干旱期为1.29至1.82个月。从干事件到湿事件的快速转变时间为2.5 ~ 4.1个月,从湿事件到干事件的快速转变时间为2.1 ~ 5.3个月。东部地区经历了大量的干旱事件,而西部和本德尔坎德地区经历了更强烈的干旱事件。相比之下,东部地区有强烈的潮湿事件。研究干湿事件的发生及其转变,可以为政府决策和防灾减灾工作提供有价值的见解。
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引用次数: 0
Perspectives on risk analysis and control for real-time operation of flood control systems 防洪系统实时运行的风险分析与控制视角
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-06-26 DOI: 10.1016/j.wse.2024.06.002
Juan Chen , Lu Zhang , Guo-zhi Li , Ping-an Zhong
Flood control operation, a non-engineering measure, can efficiently manage flood disasters within a river basin. However, numerous uncertainties exit in the real-time operation of flood control systems, creating risks in decision-making. As an efficient tool to mitigate these risks, risk management has garnered increasing attention in real-time flood control operation. This communication offers a series of suggestions for future research concerning risk management in real-time flood control operation, including risk assessment, risk diagnosis, and risk control methods.
防洪运行作为一种非工程措施,可以有效管理流域内的洪水灾害。然而,防洪系统的实时运行存在诸多不确定性,给决策带来风险。作为降低这些风险的有效工具,风险管理在实时防洪运行中日益受到重视。本文就实时洪水控制运行中的风险管理,包括风险评估、风险诊断和风险控制方法,提出了一系列未来研究建议。
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引用次数: 0
Trichoderma aureoviride hyphal pellets embedded in corncob-sodium alginate matrix for efficient uranium(VI) biosorption from aqueous solutions 包埋在玉米芯-海藻酸钠基质中的金黄色毛霉菌菌丝颗粒从水溶液中高效生物吸附铀(VI)
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-06-08 DOI: 10.1016/j.wse.2024.06.001
Min Li , Bo Liang , Jie-ming Liu , Jin Zhang , Bin Wang , Jie Shang
The discharge of effluents containing uranium (U) ions into aquatic ecosystems poses significant risks to both human health and marine organisms. This study investigated the biosorption of U(VI) ions from aqueous solutions using corncob-sodium alginate (SA)-immobilized Trichoderma aureoviride hyphal pellets. Experimental parameters, including initial solution pH, initial concentration, temperature, and contact time, were systematically examined to understand their influence on the bioadsorption process. Results showed that the corncob-SA-immobilized T. aureoviride hyphal pellets exhibited maximum uranium biosorption capacity at an initial pH of 6.23 and a contact time of 12 h. The equilibrium data aligned with the Langmuir isotherm model, with a maximum biosorption capacity of 105.60 mg/g at 301 K. Moreover, biosorption kinetics followed the pseudo-second-order kinetic model. In terms of thermodynamic parameters, the changes in Gibbs-free energy (ΔG°) were determined to be −4.29 kJ/mol at 301 K, the changes in enthalpy (ΔH°) were 46.88 kJ/mol, and the changes in entropy (ΔS°) was 164.98 J/(mol·K). Notably, the adsorbed U(VI) could be efficiently desorbed using Na2CO3, with a maximum readsorption efficiency of 53.6%. Scanning electron microscopic (SEM) analysis revealed U(VI) ion binding onto the hyphal pellet surface. This study underscores the efficacy of corncob-SA-immobilized T. aureoviride hyphal pellets as a cost-effective and environmentally favorable biosorbent material for removing U(VI) from aquatic ecosystems.
向水生生态系统排放含铀(U)离子的污水对人类健康和海洋生物构成重大风险。研究了玉米芯-海藻酸钠-固定化金黄色木霉菌丝球对水溶液中U(VI)离子的生物吸附。实验参数包括初始溶液pH、初始浓度、温度和接触时间,以系统地了解它们对生物吸附过程的影响。结果表明,玉米芯sa固定化金黄色葡萄球菌菌丝球在初始pH为6.23、接触时间为12 h时,对铀的最大吸附量为105.60 mg/g,符合Langmuir等温线模型。生物吸附动力学遵循准二级动力学模型。热力学参数方面,在301 K下,Gibbs-free能(ΔG°)的变化为- 4.29 kJ/mol,焓(ΔH°)的变化为46.88 kJ/mol,熵(ΔS°)的变化为164.98 J/(mol·K)。值得注意的是,吸附后的U(VI)可被Na2CO3有效解吸,再吸附效率最高可达53.6%。扫描电镜(SEM)分析显示,菌丝颗粒表面有U(VI)离子结合。本研究强调了玉米芯sa固定化金黄色葡萄球菌菌丝球作为一种经济高效、环境友好的生物吸附材料去除水生生态系统中U(VI)的效果。
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引用次数: 0
Microbial community diversity during algal inhibition using slow-release microcapsules of tea polyphenols 使用茶多酚缓释微胶囊抑制藻类生长过程中的微生物群落多样性
IF 4 Q1 WATER RESOURCES Pub Date : 2024-05-23 DOI: 10.1016/j.wse.2024.05.004
Li-xiao Ni , Yuan-yi Fang , Cun-hao Du , Jia-jia Wang , Cheng-jie Zhu , Chu Xu , Shi-yin Li , Jian Xu , Xu-qing Chen , Hua Su

Harmful algal blooms (HABs) resulting from eutrophication pose a major threat to ecosystems and human health, necessitating effective control measures. Allelochemicals have shown their importance in slowing down algal proliferation due to their proven efficacy and low ecological impacts. In this study, allelopathy tea polyphenols (TPs) and β-cyclodextrin were combined to prepare slow-release algicidal microcapsules, and the diversity of microbial community in the algal inhibition process was analyzed. Results showed that TP slow-release microcapsules had strong algicidal activity. When against Microcystis aeruginosa within 20 d, their constant inhibitory rate was up to 99% compared to the control group. Microbial diversity decreased with an increase in algae density, and the species richness and diversity of algae increased under the stress of TP slow-release microcapsules. The redundancy analysis showed that the environmental factors with impacts on the abundance and diversity of bacterial communities in descending order were dissolved oxygen, pH, and temperature. This study provides a theoretical basis for the application of TP slow-release microcapsules to actual water.

富营养化导致的有害藻华(HABs)对生态系统和人类健康构成重大威胁,必须采取有效的控制措施。等位化学物质因其公认的功效和较低的生态影响,在减缓藻类增殖方面显示出其重要性。本研究将等位基因茶多酚(TPs)与β-环糊精结合,制备了缓释杀藻微胶囊,并分析了抑藻过程中微生物群落的多样性。结果表明,TP 缓释微胶囊具有很强的杀藻活性。与对照组相比,在 20 d 内对铜绿微囊藻的持续抑制率高达 99%。微生物多样性随藻类密度的增加而降低,而在 TP 缓释微胶囊的胁迫下,藻类的物种丰富度和多样性均有所增加。冗余分析表明,对细菌群落丰度和多样性有影响的环境因素依次为溶解氧、pH 值和温度。该研究为 TP 缓释微胶囊在实际水体中的应用提供了理论依据。
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引用次数: 0
Superior decomposition of xenobiotic RB5 dye using three-dimensional electrochemical treatment: Response surface methodology modelling, artificial intelligence, and machine learning-based optimisation approaches 利用三维电化学处理技术优化异生物 RB5 染料的分解:响应面方法建模、人工智能和基于机器学习的优化方法
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-05-23 DOI: 10.1016/j.wse.2024.05.003
Voravich Ganthavee, Antoine P. Trzcinski
The highly efficient electrochemical treatment technology for dye-polluted wastewater is one of hot research topics in industrial wastewater treatment. This study reported a three-dimensional electrochemical treatment process integrating graphite intercalation compound (GIC) adsorption, direct anodic oxidation, and ·OH oxidation for decolourising Reactive Black 5 (RB5) from aqueous solutions. The electrochemical process was optimised using the novel progressive central composite design–response surface methodology (CCD–NPRSM), hybrid artificial neural network–extreme gradient boosting (hybrid ANN–XGBoost), and classification and regression trees (CART). CCD–NPRSM and hybrid ANN–XGBoost were employed to minimise errors in evaluating the electrochemical process involving three manipulated operational parameters: current density, electrolysis (treatment) time, and initial dye concentration. The optimised decolourisation efficiencies were 99.30%, 96.63%, and 99.14% for CCD–NPRSM, hybrid ANN–XGBoost, and CART, respectively, compared to the 98.46% RB5 removal rate observed experimentally under optimum conditions: approximately 20 mA/cm2 of current density, 20 min of electrolysis time, and 65 mg/L of RB5. The optimised mineralisation efficiencies ranged between 89% and 92% for different models based on total organic carbon (TOC). Experimental studies confirmed that the predictive efficiency of optimised models ranked in the descending order of hybrid ANN–XGBoost, CCD–NPRSM, and CART. Model validation using analysis of variance (ANOVA) revealed that hybrid ANN–XGBoost had a mean squared error (MSE) and a coefficient of determination (R2) of approximately 0.014 and 0.998, respectively, for the RB5 removal efficiency, outperforming CCD–NPRSM with MSE and R2 of 0.518 and 0.998, respectively. Overall, the hybrid ANN–XGBoost approach is the most feasible technique for assessing the electrochemical treatment efficiency in RB5 dye wastewater decolourisation.
染料废水的高效电化学处理技术是工业废水处理领域的研究热点之一。本文报道了一种集石墨插层化合物(GIC)吸附、直接阳极氧化和·OH氧化为一体的三维电化学处理工艺,用于脱色活性黑5 (RB5)的水溶液。采用新型渐进式中心复合设计-响应面法(CCD-NPRSM)、混合人工神经网络-极端梯度增强法(hybrid ANN-XGBoost)和分类与回归树(CART)对电化学过程进行了优化。采用CCD-NPRSM和混合型ANN-XGBoost来最大限度地减少评估电化学过程的误差,包括三个操作参数:电流密度、电解(处理)时间和初始染料浓度。优化后的CCD-NPRSM、ANN-XGBoost和CART的脱色效率分别为99.30%、96.63%和99.14%,而实验结果显示,在最佳条件下,电流密度约为20 mA/cm2,电解时间为20 min, RB5浓度为65 mg/L,脱色率为98.46%。基于总有机碳(TOC)的不同模型,优化的矿化效率在89%到92%之间。实验研究证实,优化后模型的预测效率依次为ANN-XGBoost、CCD-NPRSM和CART混合模型。方差分析(ANOVA)表明,混合ANN-XGBoost去除RB5的均方误差(MSE)和决定系数(R2)分别约为0.014和0.998,优于CCD-NPRSM, MSE和R2分别为0.518和0.998。综上所述,ANN-XGBoost混合方法是评估RB5染料废水脱色电化学处理效率的最可行技术。
{"title":"Superior decomposition of xenobiotic RB5 dye using three-dimensional electrochemical treatment: Response surface methodology modelling, artificial intelligence, and machine learning-based optimisation approaches","authors":"Voravich Ganthavee,&nbsp;Antoine P. Trzcinski","doi":"10.1016/j.wse.2024.05.003","DOIUrl":"10.1016/j.wse.2024.05.003","url":null,"abstract":"<div><div>The highly efficient electrochemical treatment technology for dye-polluted wastewater is one of hot research topics in industrial wastewater treatment. This study reported a three-dimensional electrochemical treatment process integrating graphite intercalation compound (GIC) adsorption, direct anodic oxidation, and ·OH oxidation for decolourising Reactive Black 5 (RB5) from aqueous solutions. The electrochemical process was optimised using the novel progressive central composite design–response surface methodology (CCD–NPRSM), hybrid artificial neural network–extreme gradient boosting (hybrid ANN–XGBoost), and classification and regression trees (CART). CCD–NPRSM and hybrid ANN–XGBoost were employed to minimise errors in evaluating the electrochemical process involving three manipulated operational parameters: current density, electrolysis (treatment) time, and initial dye concentration. The optimised decolourisation efficiencies were 99.30%, 96.63%, and 99.14% for CCD–NPRSM, hybrid ANN–XGBoost, and CART, respectively, compared to the 98.46% RB5 removal rate observed experimentally under optimum conditions: approximately 20 mA/cm<sup>2</sup> of current density, 20 min of electrolysis time, and 65 mg/L of RB5. The optimised mineralisation efficiencies ranged between 89% and 92% for different models based on total organic carbon (TOC). Experimental studies confirmed that the predictive efficiency of optimised models ranked in the descending order of hybrid ANN–XGBoost, CCD–NPRSM, and CART. Model validation using analysis of variance (ANOVA) revealed that hybrid ANN–XGBoost had a mean squared error (MSE) and a coefficient of determination (<em>R</em><sup>2</sup>) of approximately 0.014 and 0.998, respectively, for the RB5 removal efficiency, outperforming CCD–NPRSM with MSE and <em>R</em><sup>2</sup> of 0.518 and 0.998, respectively. Overall, the hybrid ANN–XGBoost approach is the most feasible technique for assessing the electrochemical treatment efficiency in RB5 dye wastewater decolourisation.</div></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"18 1","pages":"Pages 1-10"},"PeriodicalIF":3.7,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141136406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biodegradation of cresyl diphenyl phosphate in anaerobic activated sludge: Degradation characteristics, microbial community succession, and toxicity assessment 厌氧活性污泥中磷酸甲酚二苯酯的生物降解:降解特征、微生物群落演替和毒性评估
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-05-17 DOI: 10.1016/j.wse.2024.05.002
Chen-xue Jiang , Ying Li , Chi Yao , Jing Li , Ke Jing , Sui-sui Zhang , Cheng Liu , Lian-fang Zhao
Cresyl diphenyl phosphate (CDP), an emerging aryl organophosphate ester (OPE), exhibits potential toxic effects and is frequently found in diverse environmental media, thereby raising concerns about environmental pollution. Biodegradation demonstrates substantial potential for CDP removal from the environment. This study investigated the biodegradation mechanisms of CDP using anaerobic activated sludge (AnAS). The biodegradation of 1-mg/L CDP followed a first-order kinetic model with a degradation kinetic constant of 0.943 d−1, and the addition of different electron acceptors affected the degradation rate. High-resolution mass spectrometry identified seven transformation products (TPs) of CDP. The pathways of CDP degradation in anaerobic conditions were proposed, with carboxylation products being the most dominant intermediate products. The structure of the anaerobic microbial community at different degradation time points in CDP-amended microcosms was examined. The linear discriminant analysis (LDA) of effect size (LEfSe) potentially underscored the pivotal role of Methyloversatilis in CDP biodegradation. Zebrafish embryotoxicity experiments revealed both lethal and morphogenetic impacts of CDP on zebrafish embryos. The survival rate, hatching rate, and body length indicators of zebrafish embryos underscored the detoxification of CDP and its resultant intermediates by AnAS. This study offers new insights into the fate and biodegradation mechanisms of CDP in wastewater treatment plants.
磷酸甲酚二苯酯(CDP)是一种新兴的芳基有机磷酸酯(OPE),具有潜在的毒性作用,经常出现在各种环境介质中,因此引起了人们对环境污染的关注。生物降解显示了从环境中去除CDP的巨大潜力。研究了厌氧活性污泥(AnAS)对CDP的生物降解机理。1 mg/L CDP的生物降解符合一级动力学模型,降解动力学常数为0.943 d−1,不同电子受体的加入对降解速率有影响。高分辨率质谱法鉴定出CDP的7个转化产物。提出了厌氧条件下CDP降解的途径,其中羧基化产物是最主要的中间产物。考察了在不同降解时间点上经cdp修饰的微生物群落的厌氧菌群结构。效应大小(LEfSe)的线性判别分析(LDA)可能强调了甲基多面蛋白在CDP生物降解中的关键作用。斑马鱼胚胎毒性实验揭示了CDP对斑马鱼胚胎的致死性和形态发生性影响。斑马鱼胚胎的存活率、孵化率和体长指标强调了AnAS对CDP及其产生的中间体的解毒作用。该研究为污水处理厂CDP的命运和生物降解机制提供了新的见解。
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引用次数: 0
Influence of breach parameter models on hazard classification of off-stream reservoirs 破损参数模型对离流水库危险性分类的影响
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-05-13 DOI: 10.1016/j.wse.2024.05.001
Nathalia Silva-Cancino , Fernando Salazar , Ernest Bladé , Marcos Sanz-Ramos
The classification of dams or off-stream reservoirs concerning potential hazards in the event of failure often involves the use of two-dimensional hydraulic models for computing floodwave effects. These models necessitate defining breach geometry and formation time, for which various parametric models have been proposed. These models yield different values for average breach width, time of failure, and consequently, peak flows, as demonstrated by several researchers. This study analyzed the effect of selecting a breach parametric model on the hydraulic variables, potential damages, and hazard classification of structures. Three common parametric models were compared using a set of synthetic cases and a real off-stream reservoir. Results indicated significant effects of model choice. Material erodibility exerted a significant impact, surpassing that of failure mode. Other factors, such as the Manning coefficient, significantly affected the results. Utilizing an inadequate model or lacking information on dike material can lead to overly conservative or underestimated outcomes, thereby affecting hazard classification.
大坝或下游水库的分类涉及到在发生破坏时的潜在危险,通常涉及到使用二维水力模型来计算洪波效应。这些模型需要定义裂缝的几何形状和形成时间,为此提出了各种参数模型。正如几位研究者所证明的那样,这些模型对平均缺口宽度、破坏时间以及峰值流量产生了不同的值。分析了裂缝参数模型的选择对结构水力变量、潜在损伤和危险分类的影响。通过一组综合实例和一个实际离河水库,对三种常用参数模型进行了比较。结果表明,模型选择的影响显著。材料可蚀性的影响大于破坏模式的影响。其他因素,如曼宁系数,对结果有显著影响。利用不充分的模型或缺乏堤防材料信息可能导致结果过于保守或低估,从而影响危险分类。
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引用次数: 0
Hydrological responses to permafrost degradation on Tibetan Plateau under changing climate 气候变化下青藏高原冻土退化的水文响应
IF 4 Q1 WATER RESOURCES Pub Date : 2024-04-15 DOI: 10.1016/j.wse.2024.04.002
Xue-gao Chen , Zhong-bo Yu , Hui Lin , Tong-qing Shen , Peng Jiang

The Tibetan Plateau (TP) has undergone significant warming and humidification in recent years, resulting in rapid permafrost degradation and spatiotemporal variations in hydrological processes, such as subsurface water transport, hydrothermal conversion, and runoff generation. Understanding the mechanisms of hydrological processes in permafrost areas under changing climate is crucial for accurately evaluating hydrological responses on the TP. This study comprehensively discusses the permafrost hydrological processes of the TP under changing climate. Topics include climate conditions and permafrost states, subsurface water transport under freeze–thaw conditions, development of thermokarst lakes and hydrothermal processes, and runoff response during permafrost degradation. This study offers a comprehensive understanding of permafrost changes and their hydrological responses, contributing significantly to water security and sustainable development on the TP.

近年来,青藏高原(TP)经历了显著的变暖和增湿,导致冻土快速退化和水文过程的时空变化,如地下水传输、热液转换和径流生成。了解气候变化下永久冻土区的水文过程机制对于准确评估冻土带的水文响应至关重要。本研究全面讨论了气候变化下的永久冻土水文过程。主题包括气候条件和永久冻土状态、冻融条件下的地下水传输、热钾湖的发展和热液过程以及永久冻土退化过程中的径流响应。这项研究提供了对永久冻土变化及其水文响应的全面了解,对永久冻土带的水安全和可持续发展做出了重大贡献。
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引用次数: 0
Effective removal of fluoride and arsenic from groundwater via integrated biosorption and membrane ultrafiltration 通过综合生物吸附和膜超滤有效去除地下水中的氟和砷
IF 3.7 Q1 WATER RESOURCES Pub Date : 2024-04-04 DOI: 10.1016/j.wse.2024.04.001
Bukke Vani , Mannem Hymavathi , Swayampakula Kalyani , Nivedita Sahu , Sundergopal Sridhar
Fluoride (F) and arsenic, present as As(III) and As(V), are widespread toxins in groundwater across India, as well as in other countries or regions like Pakistan, China, Kenya, Africa, Thailand, and Latin America. Their presence in water resources poses significant environmental and health risks, including fluorosis and arsenicosis. To address this issue, this study developed an integrated process combining biosorbents and ultrafiltration (UF) for the removal of F, As, and turbidity from contaminated water. Laboratory-scale adsorption experiments were conducted using low-cost biosorbents with different biosorbent dosages, specifically Moringa oleifera seed powder (MSP) and sorghum bicolor husk (SBH), along with sand as a binding medium. F and As concentrations ranging from 2 to 10 mg/L and 3 to 12 mg/L, respectively, were investigated. Biosorbents and their different combinations were tested to determine their efficacy in removing dissolved F and As. The results showed that a blend of 10-g/L MSP with SBH achieved the highest F (97.20%) and As (78.63%) removal efficiencies. Subsequent treatment with a UF membrane effectively reduced turbidity and colloidal impurities in the treated water, achieving a maximum turbidity removal efficiency of 95.40%. Equilibrium kinetic and isotherm models were employed to analyze the experimental data, demonstrating good fit. Preliminary cost analysis indicated that the hybrid technology is economically viable and suitable for the separation of hazardous contaminants from aqueous solutions. This study underscores the potential of inexpensive biosorption technologies in providing clean and safe drinking water, particularly in industrial, rural, and urban areas.
氟化物(F−)和砷,以as (III)和as (V)的形式存在,是印度以及巴基斯坦、中国、肯尼亚、非洲、泰国和拉丁美洲等其他国家或地区地下水中广泛存在的毒素。它们在水资源中的存在构成了重大的环境和健康风险,包括氟中毒和砷中毒。为了解决这一问题,本研究开发了一种结合生物吸附剂和超滤(UF)的综合工艺,用于去除污染水中的F−,As和浊度。以Moringa oleifera种子粉(MSP)和高粱双色壳(SBH)为研究对象,以沙子为吸附介质,采用低成本、不同用量的生物吸附剂进行了实验室规模的吸附实验。F−和As浓度分别为2 ~ 10mg /L和3 ~ 12mg /L。对生物吸附剂及其不同组合进行了测试,以确定其去除溶解的F−和As的功效。结果表明,10 g/L MSP与SBH的混合去除率最高,分别为97.20%和78.63%。后续超滤膜处理有效降低了处理水中的浊度和胶体杂质,最大浊度去除率达95.40%。采用平衡动力学模型和等温线模型对实验数据进行了分析,结果表明拟合良好。初步的成本分析表明,混合技术在经济上是可行的,适用于从水溶液中分离有害污染物。这项研究强调了廉价生物吸附技术在提供清洁和安全饮用水方面的潜力,特别是在工业、农村和城市地区。
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引用次数: 0
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Water science and engineering
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