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Spatial diversion and coordination of flood water for an urban flood control project in Suzhou, China 中国苏州城市防洪工程的洪水空间分流与协调
IF 4 Q1 Engineering Pub Date : 2023-11-11 DOI: 10.1016/j.wse.2023.11.002
Yu Xu , You-peng Xu , Qiang Wang , Yue-feng Wang , Chao Gao

Suzhou City, located in the Yangtze River Delta in China, is prone to flooding due to a complex combination of natural factors, including its monsoon climate, low elevation, and tidally influenced position, as well as intensive human activities. The Large Encirclement Flood Control Project (LEFCP) was launched to cope with serious floods in the urban area. This project changed the spatiotemporal pattern of flood processes and caused spatial diversion of floods from the urban area to the outskirts of the city. Therefore, this study developed a distributed flood simulation model in order to understand this transition of flood processes. The results revealed that the LEFCP effectively protected the urban areas from floods, but the present scheduling schemes resulted in the spatial diversion of floods to the outskirts of the city. With rainstorm frequencies of 10.0% to 0.5%, the water level differences between two representative water level stations (Miduqiao (MDQ) and Fengqiao (FQ)) located inside and outside the LEFCP area, ranged from 0.75 m to 0.24 m and from 1.80 m to 1.58 m, respectively. In addition, the flood safety margin at MDQ and the duration with the water level exceeding the warning water level at FQ ranged from 0.95 m to 0.43 m and from 4 h to 22 h, respectively. Rational scheduling schemes for the hydraulic facilities of the LEFCP in extreme precipitation cases were developed according to flood simulations under seven scheduling scenarios. This helps to regulate the spatial flood diversion caused by the LEFCP during extreme precipitation.

苏州市位于中国长江三角洲地区,由于季风气候、低海拔、潮汐影响位置等复杂的自然因素以及密集的人类活动,该市很容易发生洪涝灾害。为应对城区严重的洪涝灾害,中国启动了大型环城防洪工程(LEFCP)。该工程改变了洪水过程的时空格局,导致洪水从城区向郊区转移。因此,本研究开发了分布式洪水模拟模型,以了解洪水过程的这种转变。结果显示,LEFCP 有效地保护了城区免受洪水侵袭,但目前的调度方案导致洪水在空间上向城市郊区分流。在暴雨频率为 10.0%至 0.5%的情况下,位于 LEFCP 区域内外的两个代表性水位站(密渡桥水位站(MDQ)和枫桥水位站(FQ))的水位差分别为 0.75 米至 0.24 米和 1.80 米至 1.58 米。此外,MDQ 的洪水安全裕度和 FQ 的水位超过警戒水位的持续时间分别为 0.95 m 至 0.43 m 和 4 h 至 22 h。根据七种调度方案下的洪水模拟,制定了在极端降水情况下的 LEFCP 水利设施合理调度方案。这有助于在极端降水情况下调节荔湾区排涝站的空间分洪能力。
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引用次数: 0
Numerical modeling of a mooring line system for an offshore floating wind turbine in Vietnamese sea conditions using nonlinear materials 利用非线性材料对越南海况下海上浮式风力涡轮机的系泊线系统进行数值建模
IF 4 Q1 Engineering Pub Date : 2023-10-31 DOI: 10.1016/j.wse.2023.10.004
Hien Hau Pham

The offshore renewable energy industry has been developing farms of floating offshore wind turbines in water depths up to 100 m. In Vietnam, floating offshore wind turbines have been developed to increase the production of clean and sustainable energy. The mooring system, which is used to keep the turbine stable and ensure the safety and economic efficiency of wind power production, is an important part of a floating offshore wind turbine. Appropriate selection of the mooring type and mooring line material can reduce the risks arising from the motion of wind turbines. Different types of mooring line material have been simulated and compared in order to determine the optimal type with the minimum motion risk for a floating wind turbine. This study focused on numerical modeling of semi-taut mooring systems using nonlinear materials for a semi-submersible wind turbine. Several modeling approaches common to current practice were applied. Hydrodynamic analysis was performed to investigate the motion of the response amplitude operators of the floating wind turbine. Dynamic analysis of mooring systems was performed using a time domain to obtain the tension responses of mooring lines under the ultimate limit states and fatigue limit states in Vietnamese sea conditions. The results showed that the use of nonlinear materials (polyester and/or nylon) for mooring systems can minimize the movement of the turbine and save costs. The use of synthetic fibers can reduce the maximum tension in mooring lines and the length of mooring lines. However, synthetic fiber ropes showed highly nonlinear load elongation properties, which were difficult to simulate using numerical software. The comparison of the characteristics of polyester and nylon mooring lines showed that the maximum and mean tensions of the nylon line were less than those of the polyester line. In addition, the un-stretched length of the polyester line was greater than that of the nylon line under the same mean tension load. Therefore, nylon material is recommended for the mooring lines of a floating offshore wind turbine.

近海可再生能源行业一直在开发水深达 100 米的浮式近海风力涡轮机发电场。在越南,浮式近海风力涡轮机的开发旨在提高清洁和可持续能源的产量。系泊系统是浮式海上风力涡轮机的重要组成部分,用于保持涡轮机稳定,确保风力发电的安全和经济效益。适当选择系泊类型和系泊线材料可以降低风力涡轮机运动带来的风险。对不同类型的系泊线材料进行了模拟和比较,以确定对浮式风力涡轮机来说运动风险最小的最佳类型。本研究的重点是使用非线性材料对半潜风力涡轮机的半锚定系泊系统进行数值建模。研究采用了当前实践中常见的几种建模方法。进行了水动力分析,以研究浮动风力涡轮机响应振幅算子的运动。使用时域对系泊系统进行了动态分析,以获得越南海况下系泊线在极限状态和疲劳极限状态下的张力响应。结果表明,使用非线性材料(聚酯和/或尼龙)制作系泊系统可以最大限度地减少涡轮机的移动,并节约成本。使用合成纤维可以减少系泊缆绳的最大张力和系泊缆绳的长度。然而,合成纤维绳索具有高度非线性的负载伸长特性,难以用数值软件进行模拟。对聚酯系泊缆绳和尼龙系泊缆绳的特性进行比较后发现,尼龙系泊缆绳的最大张力和平均张力均小于聚酯系泊缆绳。此外,在相同的平均拉力负荷下,聚酯缆绳的未拉伸长度大于尼龙缆绳。因此,建议使用尼龙材料制作海上风力涡轮机的系泊缆线。
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引用次数: 0
Monitoring and evaluation of the water quality of the Lower Neches River, Texas, USA 美国得克萨斯州内奇斯河下游水质监测与评估
IF 4 Q1 Engineering Pub Date : 2023-10-28 DOI: 10.1016/j.wse.2023.10.002
Qin Qian , Mengjie He , Frank Sun , Xinyu Liu

Increasing bacteria levels in the Lower Neches River caused by Hurricane Harvey has been of a serious concern. This study is to analyze the historical water sampling measurements and real-time water quality data collected with wireless sensors to monitor and evaluate water quality under different hydrological and hydraulic conditions. The statistical and Pearson correlation analysis on historical water samples determines that alkalinity, chloride, hardness, conductivity, and pH are highly correlated, and they decrease with increasing flow rate due to dilution. The flow rate has positive correlations with Escherichia coli, total suspended solids, and turbidity, which demonstrates that runoff is one of the causes of the elevated bacteria and sediment loadings in the river. The correlation between E. coli and turbidity indicates that turbidity greater than 45 nephelometric turbidity units in the Neches River can serve as a proxy for E. coli to indicate the bacterial outbreak. A series of statistical tools and an innovative two-layer data smoothing filter are developed to detect outliers, fill missing values, and filter spikes of the sensor measurements. The correlation analysis on the sensor data illustrates that the elevated sediment/bacteria/algae in the river is either caused by the first flush rain and heavy rain events in December to March or practices of land use and land cover. Therefore, utilizing sensor measurements along with rainfall and discharge data is recommended to monitor and evaluate water quality, then in turn to provide early alerts on water resources management decisions.

哈维飓风导致内奇斯河下游的细菌含量不断增加,引起了人们的严重关注。本研究旨在分析历史水样测量数据和利用无线传感器收集的实时水质数据,以监测和评估不同水文和水力条件下的水质。通过对历史水样进行统计和皮尔逊相关分析,确定碱度、氯化物、硬度、电导率和 pH 值高度相关,并且由于稀释作用,它们随着流速的增加而降低。流速与大肠埃希氏菌、总悬浮固体和浊度呈正相关,这表明径流是导致河流中细菌和沉积物负荷增加的原因之一。大肠杆菌与浑浊度之间的相关性表明,内奇斯河里浑浊度大于 45 新浊度单位的大肠杆菌可以作为细菌爆发的替代物。开发了一系列统计工具和创新的双层数据平滑滤波器,用于检测异常值、填补缺失值和过滤传感器测量值的尖峰。对传感器数据进行的相关性分析表明,河流中沉积物/细菌/藻类增多的原因可能是 12 月至 3 月的首冲雨和暴雨,也可能是土地利用和土地覆盖的做法。因此,建议利用传感器测量数据以及降雨和排水数据来监测和评估水质,进而为水资源管理决策提供早期预警。
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引用次数: 0
Contributors to tidal duration asymmetry with varied coastline configurations on western shelf of Yellow Sea 黄海西部大陆架不同海岸线配置导致潮汐持续时间不对称的因素
IF 4 Q1 Engineering Pub Date : 2023-10-27 DOI: 10.1016/j.wse.2023.09.006
Xi Feng , Zheng Li , Hui Feng , Jia-yan Yang , Shou-peng Xie , Wei-bing Feng

Coastal management in China is confronted with an urgent choice between natural restoration and maintenance of existing seawalls and reclaimed land for economic development. A key criterion for making this decision is the resilience to coastal flooding, which depends on the ability to predict tidal level. Tidal duration asymmetry (TDA) is a key parameter in determination of the arrival and duration of flood tides. This study selected the western inner shelf of the Yellow Sea (WYS) as the study area and investigated the responses of TDA to different shoreline configurations and relative sea level rise. The responses of TDA to shoreline reconstruction yielded spatial variability locally and remotely. In the nearshore area, the responses of TDA to the complex ocean environment mainly originated from the combined functions of reflection, bottom friction, and advection, which controlled the energy transfer from M2 or S2 constituents to their overtides or compound tides. The sensitivity of TDA to coastline typologies was not limited to coastal waters but could stretch over the entire inner shelf. The vulnerability of tidal responses was due to the displacement of the M2 amphidrome of the Kelvin wave on the WYS, which in turn changed tidal energy fluxes over the regime. The relative sea level rise could intensify the feedback of TDA to seawalls and land reclamation.

中国的海岸管理面临着一个紧迫的选择,即自然恢复和维护现有海堤与填海造地以发展经济。做出这一决定的一个关键标准是抵御沿海洪水的能力,而这取决于预测潮位的能力。潮汐持续时间不对称(TDA)是确定洪潮到来和持续时间的关键参数。本研究选择黄海西部内陆架(WYS)作为研究区域,调查了潮汐持续时间不对称对不同海岸线配置和相对海平面上升的响应。TDA 对海岸线重建的响应在局部和远距离上都具有空间变异性。在近岸区域,TDA 对复杂海洋环境的响应主要来源于反射、海底摩擦和平流的综合作用,这些作用控制着 M2 或 S2 成分向其潮汐或复合潮汐的能量传递。TDA 对海岸线类型的敏感性并不局限于沿岸水域,而是可以延伸到整个内陆架。潮汐响应的脆弱性是由于开尔文波的 M2 两性波在 WYS 上的位移,这反过来又改变了该系统的潮汐能量通量。海平面的相对上升可能会加强潮汐发展区对海堤和填海造地的反馈作用。
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引用次数: 0
Efficient removal of Cr(VI) by polydopamine-modified lignin from aqueous solution: Batch and XAFS studies 多巴胺改性木质素从水溶液中高效去除六价铬:批量和 XAFS 研究
IF 4 Q1 Engineering Pub Date : 2023-10-26 DOI: 10.1016/j.wse.2023.10.003
Xiao-jie Guo , Wei-kang Fu , Jing-yuan Ma , Bo-jun Xi , Chen Wang , Meng-yao Guan

Lignocellulose has the potential to become a bio-based adsorbent due to its biodegradability and renewability. In this study, a novel polydopamine-functionalized-lignin (lignin@PDA), prepared via self-polymerization of dopamine (PDA) on lignin, was used as a bio-based adsorbent for rapid scavenging of hexavalent chromium (Cr(VI)). The morphology, functional groups, crystalline structure, and chemical composition of lignin@PDA were characterized with a scanning electron microscope–energy dispersive spectrometer, Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The Cr(VI) adsorption process of lignin@PDA was studied using batch experiments as a function of pH, ionic strength, adsorbent dose, and contact time at room temperature. The adsorption rate of lignin@PDA was five times greater than that of the unmodified lignin, with a maximum adsorption capacity of 102.6 mg/g in an acidic medium. The adsorption of Cr(VI) on lignin@PDA fit the pseudo-second-order equation and the Freundlich model, indicating that the adsorption process was mainly dominated by chemisorption and surface complexation. The thermodynamic parameters showed that adsorption of Cr(VI) on lignin@PDA was an endothermic and spontaneous process. The X-ray absorption fine structure results showed that sorption and reduction of Cr(VI) into Cr(III) occurred simultaneously on lignin. Moreover, PDA coating not only improved the reactivity of lignin but also promoted the complete reduction of Cr(VI) by lignin. According to these results, polydopamine-functionalized-lignin is a promising bio-based adsorbent for immobilization of Cr(VI) from wastewater.

木质纤维素具有生物降解性和可再生性,因此有潜力成为一种生物基吸附剂。本研究利用多巴胺(PDA)在木质素上的自聚合反应制备了一种新型的多巴胺功能化木质素(木质素@PDA),并将其用作快速清除六价铬(Cr(VI))的生物基吸附剂。利用扫描电子显微镜-能量色散光谱仪、傅立叶变换红外光谱、X 射线衍射和 X 射线光电子能谱对木质素@PDA 的形态、官能团、晶体结构和化学成分进行了表征。在室温下,利用批次实验研究了木质素@PDA 的 Cr(VI) 吸附过程与 pH 值、离子强度、吸附剂剂量和接触时间的函数关系。在酸性介质中,木质素@PDA 的吸附速率是未改性木质素的五倍,最大吸附容量为 102.6 mg/g。木质素@PDA对Cr(VI)的吸附符合假二阶方程和Freundlich模型,表明吸附过程主要以化学吸附和表面络合为主。热力学参数表明,木质素@PDA对Cr(VI)的吸附是一个自发的内热过程。X 射线吸收精细结构结果表明,木质素上同时发生了将 Cr(VI)吸附和还原成 Cr(III)的过程。此外,PDA 涂层不仅提高了木质素的反应活性,还促进了木质素对 Cr(VI) 的完全还原。根据这些结果,聚多巴胺功能化木质素是一种很有前景的固定废水中六价铬的生物基吸附剂。
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引用次数: 0
Sensitivity analysis of factors affecting gravity dam anti-sliding stability along a foundation surface using Sobol method 用Sobol法对重力坝沿基面抗滑稳定性影响因素进行敏感性分析
IF 4 Q1 Engineering Pub Date : 2023-10-11 DOI: 10.1016/j.wse.2023.10.001
Bo Xu, Shi-da Wang

The anti-sliding stability of a gravity dam along its foundation surface is a key problem in the design of gravity dams. In this study, a sensitivity analysis framework was proposed for investigating the factors affecting gravity dam anti-sliding stability along the foundation surface. According to the design specifications, the loads and factors affecting the stability of a gravity dam were comprehensively selected. Afterwards, the sensitivity of the factors was preliminarily analyzed using the Sobol method with Latin hypercube sampling. Then, the results of the sensitivity analysis were verified with those obtained using the Garson method. Finally, the effects of different sampling methods, probability distribution types of factor samples, and ranges of factor values on the analysis results were evaluated. A case study of a typical gravity dam in Yunnan Province of China showed that the dominant factors affecting the gravity dam anti-sliding stability were the anti-shear cohesion, upstream and downstream water levels, anti-shear friction coefficient, uplift pressure reduction coefficient, concrete density, and silt height. Choice of sampling methods showed no significant effect, but the probability distribution type and the range of factor values greatly affected the analysis results. Therefore, these two elements should be sufficiently considered to improve the reliability of the dam anti-sliding stability analysis.

重力坝沿坝基面的抗滑稳定性是重力坝设计中的关键问题。本文提出了影响重力坝沿基面抗滑稳定性因素的敏感性分析框架。根据设计规范,综合选取了某重力坝的荷载及影响稳定性的因素。然后,采用拉丁超立方抽样的Sobol方法对各因素的敏感性进行了初步分析。然后,将灵敏度分析结果与Garson方法的结果进行了验证。最后,评价了不同抽样方法、因子样本的概率分布类型和因子值的取值范围对分析结果的影响。以云南某典型重力坝为例研究表明,影响重力坝抗滑稳定性的主要因素是抗剪黏聚力、上下游水位、抗剪摩擦系数、上拔压减阻系数、混凝土密度和粉砂高度。抽样方法的选择对分析结果影响不显著,但概率分布类型和因子值的取值范围对分析结果影响较大。因此,应充分考虑这两个因素,以提高大坝抗滑稳定性分析的可靠性。
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引用次数: 0
Numerical three-dimensional modeling of earthen dam piping failure 土坝管道溃坝的三维数值建模
IF 4 Q1 Engineering Pub Date : 2023-09-29 DOI: 10.1016/j.wse.2023.09.008
Zhengang Wang

A physically-based numerical three-dimensional earthen dam piping failure model is developed for homogeneous and zoned soil dams. This model is an erosion model, coupled with force/moment equilibrium analyses. Orifice flow and two-dimensional (2D) shallow water equations (SWE) are solved to simulate dam break flows at different breaching stages. Erosion rates of different soils with different construction compaction efforts are calculated using corresponding erosion formulae. The dam's real shape, soil properties, and surrounding area are programmed. Large outer 2D-SWE grids are used to control upstream and downstream hydraulic conditions and control the boundary conditions of orifice flow, and inner 2D-SWE flow is used to scour soil and perform force/moment equilibrium analyses. This model is validated using the European Commission IMPACT (Investigation of Extreme Flood Processes and Uncertainty) Test #5 in Norway, Teton Dam failure in Idaho, USA, and Quail Creek Dike failure in Utah, USA. All calculated peak outflows are within 10% errors of observed values. Simulation results show that, for a V-shaped dam like Teton Dam, a piping breach location at the abutment tends to result in a smaller peak breach outflow than the piping breach location at the dam's center; and if Teton Dam had broken from its center for internal erosion, a peak outflow of 117 851 m3/s, which is 81% larger than the peak outflow of 65 120 m3/s released from its right abutment, would have been released from Teton Dam. A lower piping inlet elevation tends to cause a faster/earlier piping breach than a higher piping inlet elevation.

针对均质土坝和带状土坝开发了基于物理的三维土坝管道溃坝数值模型。该模型是一个侵蚀模型,并结合了力/力矩平衡分析。通过求解孔口流和二维浅水方程(SWE)来模拟不同溃坝阶段的溃坝流。使用相应的侵蚀公式计算了不同施工压实力度下不同土壤的侵蚀率。对大坝的实际形状、土壤特性和周围区域进行了编程。外部大型 2D-SWE 网格用于控制上下游水力条件和控制孔口流的边界条件,内部 2D-SWE 流用于冲刷土壤和进行力/力矩平衡分析。该模型通过欧洲委员会在挪威进行的 IMPACT(极端洪水过程和不确定性调查)5 号试验、美国爱达荷州的 Teton 大坝溃坝和美国犹他州的 Quail Creek 堤坝溃坝进行了验证。所有计算出的洪峰流量与观测值的误差都在 10%以内。模拟结果表明,对于像泰顿大坝这样的 V 型大坝,位于坝基的管道破损位置往往会比位于大坝中心的管道破损位置产生较小的峰值破损流出量;如果泰顿大坝因内部侵蚀而从其中心破损,那么泰顿大坝将释放出 117 851 立方米/秒的峰值流出量,比从其右侧坝基释放出的 65 120 立方米/秒的峰值流出量大 81%。与较高的管道入口标高相比,较低的管道入口标高往往会导致更快/更早的管道破裂。
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引用次数: 0
Survey on performance of vertical slot and nature-like fishways at Angu hydropower station, Southwest China 中国西南安谷水电站竖槽和仿自然鱼道性能调查
IF 4 Q1 Engineering Pub Date : 2023-09-28 DOI: 10.1016/j.wse.2023.09.007
Jun-jian Sun , Jia-yue Shi , Qi Zhang , Xiao-tao Shi , Jun-jun Tan

To restore dam-blocked natural fish migratory passages, a growing number of artificial fishways have been built in water conservancy and hydropower projects in China. The Angu hydropower station involved diverse important fish habitats in the lower reaches of the Daduhe River in Southwest China. Therefore, a vertical slot fishway (VSF) and a nature-like fishway (NLF) were built near the backwater area of the reservoir to connect the upstream and downstream habitats. Hydrodynamic and aquatic ecological surveys were conducted after the completion of the project to estimate the fish passing effect of the two fishways. The results indicated that both fishways were in effective operation and could maintain the desired hydrodynamic conditions and be used by several local fish species. During the survey, 149 fish from 15 species and 111 fish from 17 species were captured by the traps in the VSF and NLF, respectively, while 1 263 fish from 27 species were found in the downstream area. Some species captured in the VSF were not found in the NLF, and vice versa, which implied the different preferences of fish. Meanwhile, 3 789 signals including 2 099 upward ones and 1 690 downward ones were monitored with an ultrasonic fish detector at the inlet of the VSF. These findings revealed the characteristics of fish species observed in and near the fishways and provided valuable insights into the different fish passing capabilities of VSF and NLF.

为了恢复被大坝阻断的天然鱼类洄游通道,中国在水利水电工程中修建了越来越多的人工鱼道。安谷水电站涉及中国西南部大渡河下游多种重要的鱼类栖息地。因此,在水库回水区附近修建了一条垂直缝隙式鱼道(VSF)和一条仿自然鱼道(NLF),以连接上下游栖息地。工程完工后进行了水动力和水生态调查,以估算两条鱼道的过鱼效果。结果表明,两条鱼道都能有效运行,并能保持理想的水动力条件,而且当地的一些鱼类也能利用。調查期間,在船隻碇泊區和北大嶼山魚類通 道的魚網分別捕獲 15 個品種的 149 條魚類和 17 個品種的 111 條魚 類,而在下游地區則捕獲 27 個品種的 1 263 條魚類。一些在甚深水域捕获的鱼种在北大嶼山渔场没有发现,反之亦然,这意味着鱼类的喜好不同。同时,在贮水池入口处使用超声波探鱼器监测了 3 789 个信号,包括 2 099 个向上的信号和 1 690 个向下的信号。这些研究结果揭示了在鱼道内和鱼道附近观察到的鱼类特征,并为了解伶仃洋浅滩和北大西洋浅滩不同的鱼类通过能力提供了宝贵的信息。
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引用次数: 0
Deformation prediction model of concrete face rockfill dams based on an improved random forest model 基于改进随机森林模型的面板堆石坝变形预测模型
IF 4 Q1 Engineering Pub Date : 2023-09-17 DOI: 10.1016/j.wse.2023.09.005
Yan-long Li , Qiao-gang Yin , Ye Zhang , Heng Zhou

The unique structure and complex deformation characteristics of concrete face rockfill dams (CFRDs) create safety monitoring challenges. This study developed an improved random forest (IRF) model for dam health monitoring modeling by replacing the decision tree in the random forest (RF) model with a novel M5' model tree algorithm. The factors affecting dam deformation were preliminarily selected using the statistical model, and the grey relational degree theory was utilized to reduce the dimensions of model input variables. Finally, a deformation prediction model of CFRDs was established using the IRF model. The ten-fold cross-validation method was used to quantitatively analyze the parameters affecting the IRF algorithm. The performance of the established model was verified using data from three specific measurement points on the Jishixia dam and compared with other dam deformation prediction models. At point ES-10, the performance evaluation indices of the IRF model were superior to those of the M5' model tree and RF models and the classical support vector regression (SVR) and back propagation (BP) neural network models, indicating the satisfactory performance of the IRF model. The IRF model also outperformed the SVR and BP models in settlement prediction at points ES2-8 and ES4-10, demonstrating its strong anti-interference and generalization capabilities. This study has developed a novel method for forecasting and analyzing dam settlements with practical significance. Moreover, the established IRF model can also provide guidance for modeling health monitoring of other structures.

混凝土面板堆石坝独特的结构和复杂的变形特性给安全监测带来了挑战。本文提出了一种改进的随机森林(IRF)模型,将随机森林(RF)模型中的决策树替换为一种新的M5'模型树算法。利用统计模型对影响大坝变形的因素进行初步选择,并利用灰色关联度理论对模型输入变量进行降维。最后,利用IRF模型建立了cfrd的变形预测模型。采用十重交叉验证法定量分析影响IRF算法的参数。利用鸡石峡大坝三个具体测点的数据,并与其他大坝变形预测模型进行了对比,验证了所建模型的有效性。在ES-10点,IRF模型的性能评价指标优于M5模型树和RF模型以及经典的支持向量回归(SVR)和反向传播(BP)神经网络模型,表明IRF模型的性能令人满意。在ES2-8和ES4-10点的沉降预测中,IRF模型也优于SVR和BP模型,显示出较强的抗干扰能力和泛化能力。本研究为大坝沉降预测与分析提供了一种具有实际意义的新方法。此外,所建立的IRF模型也可为其他结构的健康监测建模提供指导。
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引用次数: 0
Green synthesis of silver nanoparticles using aqueous leaf extract of Saussurea obvallata for efficient catalytic reduction of nitrophenol, antioxidant, and antibacterial activity 利用荞麦叶水提取物绿色合成银纳米粒子,用于高效催化还原硝基苯酚、抗氧化和抗菌活性
IF 4 Q1 Engineering Pub Date : 2023-09-15 DOI: 10.1016/j.wse.2023.09.004
P.S.R. Vidya Sagar , Dharmasoth Ramadevi , Keloth Basavaiah , Sathish Mohan Botsa

Of several noble metal nanoparticles, silver nanoparticles (AgNPs) have attracted special attention due to their distinct properties, such as favorable electrical conductivity, chemical stability, and catalytic and antibacterial activities. Green synthesis of AgNPs using plant extracts containing phytochemical agents has attracted considerable interest. This environmentally friendly approach is more biocompatible and cost-efficient and has the capability of supporting large-scale synthesis. This study developed an eco-friendly method for the preparation of AgNPs using the aqueous leaf extract of Saussurea obvallata as reducing and capping agents. Ultraviolet visible spectroscopy (UV–Vis), Fourier transform infrared spectroscopy (FTIR), Raman, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) analyses were conducted to characterize the synthesized AgNPs. The morphology of AgNPs was found to be spherical with an average crystallite size of 12 nm and a maximum absorbance at 410 nm. 10 mg of AgNPs had potential to reduce 4-nitrophenol to 4-aminophenol in 16 min and exhibited strong biological activities against the Gram-negative bacteria Escherichia coli (12 mm) and Gram-positive bacteria Enterococcus faecalis (13 mm). The antioxidant activity of the synthesized AgNPs was investigated against the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging and exhibited up to 61.21% ± 0.02% at an AgNPs concentration of 500 μg/mL.

在几种贵金属纳米粒子中,银纳米粒子(AgNPs)因其独特的性质,如良好的导电性、化学稳定性、催化和抗菌活性等,引起了人们的特别关注。利用含有植物化学制剂的植物提取物绿色合成 AgNPs 引起了人们的极大兴趣。这种环境友好型方法具有更好的生物相容性和成本效益,并且能够支持大规模合成。本研究开发了一种生态友好型制备 AgNPs 的方法,该方法使用钝叶绍氏栲胶水溶液作为还原剂和封端剂。对合成的 AgNPs 进行了紫外可见光谱(UV-Vis)、傅立叶变换红外光谱(FTIR)、拉曼光谱、X 射线衍射(XRD)、X 射线光电子能谱(XPS)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)分析。结果发现,AgNPs 的形态为球形,平均晶粒大小为 12 纳米,最大吸光度为 410 纳米。10 毫克 AgNPs 可在 16 分钟内将 4-硝基苯酚还原成 4-氨基苯酚,并对革兰氏阴性菌大肠杆菌(12 毫米)和革兰氏阳性菌粪肠球菌(13 毫米)表现出很强的生物活性。在 AgNPs 浓度为 500 μg/mL 时,对 2,2-二苯基-1-苦基肼(DPPH)自由基清除的抗氧化活性高达 61.21% ± 0.02%。
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引用次数: 0
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Water science and engineering
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