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Solid waste generation prediction model framework using socioeconomic and demographic factors with real-time MSW collection data. 利用社会经济和人口因素以及实时 MSW 收集数据,建立固体废物产生预测模型框架。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-02-01 Epub Date: 2024-02-26 DOI: 10.1177/0734242X241231414
Laurie Fontaine, Robert Legros, Jean-Marc Frayret

This article proposes a framework for developing predictive models of end-of-life product flows, highlighting the importance of conducting thorough analyses before developing waste management and end-of-life product flow strategies. The framework emphasizes the importance of recognizing the nature and quality of the available data and finding a balance between model development time and detail requirements. It is designed to adapt to source material heterogeneity and address varying data availability scenarios, such as the presence or absence of radio frequency identification chips. A case study for the city of Gatineau is presented, showcasing the framework's application through agent-based simulation models in a geographic information systems environment. The study focuses on creating models of municipal solid waste generation based on socioeconomic and demographic factors and collection data to accurately predict the quantity and quality of waste streams, enabling municipalities to assess the environmental impact of their waste management strategies.

本文提出了一个开发报废产品流预测模型的框架,强调了在制定废物管理和报废产品流战略之前进行全面分析的重要性。该框架强调了认识可用数据的性质和质量以及在模型开发时间和细节要求之间找到平衡的重要性。该框架旨在适应源材料的异质性,并应对不同的数据可用性情况,例如是否存在射频识别芯片。本文介绍了加蒂诺市的一个案例研究,通过地理信息系统环境中基于代理的模拟模型,展示了该框架的应用。该研究的重点是根据社会经济和人口因素以及收集数据创建城市固体废物产生模型,以准确预测废物流的数量和质量,使市政当局能够评估其废物管理战略对环境的影响。
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引用次数: 0
Recycling solar-grade silicon from end-of-life photovoltaic modules by Al-Si solvent refining. 通过铝硅溶剂提炼从报废光伏组件中回收太阳能级硅。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-02-01 Epub Date: 2024-04-02 DOI: 10.1177/0734242X241241602
Yanlei Li, Yiheng Tuo, Debao Zhang, Xiaoman Lu, Huili Han, Lindong Liu

The development of the solar market has been fast in the past decades, and the number of photovoltaic module installations is large. The photovoltaic modules have a lifetime of about 25 years and need recovery after that. The aluminium-back surface field (Al-BSF) module is the first kind of large-scale installed module and will come to its end of life in the next few years. The recycling of silicon material in the Al-BSF module is investigated in this work. The components of the module are separated, and the silicon material in the module is collected and then purified by (aluminium-silicon) Al-Si solvent refining for reuse. It is found that Al-Si solvent refining removed key impurity elements, namely boron and phosphorus, in the collected silicon. Kinetics has a great effect on boron and phosphorus removal, and boron and phosphorus contents in purified silicon decrease with decreasing cooling rate. The boron and phosphorus contents in silicon are lowered to 0.28 and 0.03 ppmw, respectively, after two times of Al-Si solvent refining with the cooling rate of 5.55 * 10-4 K second-1, and it meets the requirement of solar-grade silicon.

过去几十年来,太阳能市场发展迅速,光伏组件安装量很大。光伏组件的使用寿命约为 25 年,之后需要回收。铝背表面电场(Al-BSF)组件是第一种大规模安装的组件,将在未来几年内寿终正寝。本研究对铝背表面场组件中硅材料的回收利用进行了调查。将组件的部件分离,收集组件中的硅材料,然后通过(铝-硅)铝-硅溶剂提纯进行再利用。研究发现,铝硅溶剂提纯可去除收集的硅中的主要杂质元素,即硼和磷。动力学对硼和磷的去除有很大影响,纯化硅中的硼和磷含量随着冷却速率的降低而减少。在冷却速率为 5.55 * 10-4 K 秒-1 时,经过两次铝硅溶剂精炼,硅中的硼和磷含量分别降至 0.28 和 0.03 ppmw,达到了太阳能级硅的要求。
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引用次数: 0
A systematic review of plastic recycling: technology, environmental impact and economic evaluation. 塑料回收的系统回顾:技术、环境影响和经济评价。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-18 DOI: 10.1177/0734242X241310658
Xiaoli Jiang, Buhe Bateer

In this systematic review, advancements in plastic recycling technologies, including mechanical, thermolysis, chemical and biological methods, are examined. Comparisons among recycling technologies have identified current research trends, including a focus on pretreatment technologies for waste materials and the development of new organic chemistry or biological techniques that enable recycling with minimal energy consumption. Existing environmental and economic studies are also compared. The findings highlight differences in the environmental characteristics of various recycling methods, including their ability to recover plastic resins, carbon footprint, electricity consumption and gas emissions. The comparisons also reveal the challenges associated with these methods: mechanical recycling often encounters economic barriers due to contamination and inefficiencies in sorting and cleaning processes; thermolysis is constrained by high energy demands and operational costs, whereas chemical and biological recycling faces limitations related to scalability and material costs. Additionally, current challenges, emerging research areas and future directions in plastic recycling are discussed. For example, the role of innovative techniques, such as artificial intelligence, in refining recycling processes is emphasized. The importance of incorporating circular economy principles in the integrated sustainable analysis of recycling processes is also highlighted. The innovative contribution of this review is to address both technological developments and their environmental and economic implications. The focus is placed on literature from the past 10 years to ensure coverage of the most recent advancements. Overall, the insights of this review article aim to guide researchers, policymakers and industry stakeholders in improving sustainable management practices for plastic waste.

在这篇系统的综述中,研究了塑料回收技术的进展,包括机械、热裂解、化学和生物方法。各种回收技术之间的比较确定了当前的研究趋势,包括侧重于废物预处理技术和开发新的有机化学或生物技术,使回收能够以最小的能源消耗。现有的环境和经济研究也进行了比较。研究结果强调了各种回收方法在环境特征上的差异,包括它们回收塑料树脂、碳足迹、电力消耗和气体排放的能力。这些比较也揭示了与这些方法相关的挑战:由于污染和分类和清洁过程中的效率低下,机械回收经常遇到经济障碍;热分解受到高能量需求和操作成本的限制,而化学和生物回收则面临着与可扩展性和材料成本相关的限制。此外,还讨论了塑料回收的当前挑战、新兴研究领域和未来发展方向。例如,强调了人工智能等创新技术在精炼回收过程中的作用。会议还强调了将循环经济原则纳入回收过程综合可持续分析的重要性。这项审查的创新贡献在于处理技术发展及其对环境和经济的影响。重点放在过去10年的文献上,以确保报道最新的进展。总的来说,这篇综述文章的见解旨在指导研究人员、政策制定者和行业利益相关者改善塑料废物的可持续管理实践。
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引用次数: 0
A comprehensive review of recycling and reusing methods for plastic waste focusing Indian scenario. 以印度为重点的塑料废物回收和再利用方法的综合审查。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-08 DOI: 10.1177/0734242X241308499
Kishor Kalauni, Ajitanshu Vedrtnam, Sahendra P Sharma, Abhishek Sharma, Shashikant Chaturvedi

Plastics are integral to modern life but present significant environmental and economic challenges due to ineffective waste management systems. This article provides a comprehensive review of global plastic waste management (PWM) strategies, focusing on advancements in processing technologies, policy frameworks and their practical applications. It highlights the role of the World Intellectual Property Organization (WIPO) and regulatory bodies across the United States, Canada, Europe, Britain, India, Japan, Australia and China in fostering sustainable PWM practices. The study evaluates key processing techniques, including pyrolysis, gasification, supercritical water conversion, plasma-assisted processes, mechanical reprocessing and landfilling, emphasizing their technological advancements, limitations and scalability. Supercritical water conversion (operating at >374°C and 22.1 MPa) and plasma-assisted processing (using ionized gas at >3000°C) are identified as advanced methods capable of converting plastics into simpler molecules or valuable by-products. However, these technologies face challenges such as high energy requirements, operational costs and limited scalability. Persistent issues, including microplastic pollution, environmental impacts and the chemical-intensive nature of certain processes, are critically analysed. Drawing on extensive reviews of patents, case studies and real-world implementations, the study also examines the reuse potential of plastic by-products in diverse industries and evaluates state-level PWM initiatives in India. This review provides actionable insights for policymakers, researchers and industry stakeholders, highlighting critical gaps and opportunities to enhance the sustainability and scalability of PWM systems. By addressing persistent challenges, it contributes to advancing a circular economy for plastics and sustainable waste management practices globally.

塑料是现代生活中不可或缺的一部分,但由于无效的废物管理系统,目前面临着重大的环境和经济挑战。本文全面回顾了全球塑料废物管理(PWM)战略,重点介绍了处理技术、政策框架及其实际应用方面的进展。报告强调了世界知识产权组织(WIPO)以及美国、加拿大、欧洲、英国、印度、日本、澳大利亚和中国的监管机构在促进可持续的PWM实践方面的作用。该研究评估了关键的处理技术,包括热解、气化、超临界水转化、等离子体辅助处理、机械后处理和垃圾填埋,强调了它们的技术进步、局限性和可扩展性。超临界水转化(在bbb374°C和22.1 MPa下运行)和等离子体辅助处理(在>3000°C下使用电离气体)被确定为能够将塑料转化为更简单的分子或有价值的副产品的先进方法。然而,这些技术面临着诸如高能源需求、运营成本和有限的可扩展性等挑战。持续存在的问题,包括微塑料污染、环境影响和某些过程的化学密集性质,都进行了严格的分析。通过对专利、案例研究和现实世界实施情况的广泛审查,该研究还考察了塑料副产品在不同行业的再利用潜力,并评估了印度各州的PWM计划。本综述为政策制定者、研究人员和行业利益相关者提供了可操作的见解,强调了提高PWM系统可持续性和可扩展性的关键差距和机会。通过应对持续存在的挑战,它有助于推动塑料循环经济和全球可持续废物管理实践。
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引用次数: 0
Thermoactivated cement from construction and demolition waste for pavement base stabilization: A case study in Brazil. 从建筑和拆除废物中提取热活性水泥用于路基稳定:巴西案例研究。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-01 Epub Date: 2024-02-21 DOI: 10.1177/0734242X241227370
Valdir M Pereira, Raphael Baldusco, Patricia B Silva, Valdecir A Quarcioni, Rosângela S Motta, Seiiti Suzuki, Sergio C Angulo

Construction and demolition waste (CDW) worldwide generation accounts 10 billion tonnes yearly. The major fraction is landfilled requiring innovative recycling methods to reduce the associated environmental impacts and to increase its circularity. Our study demonstrated the feasibility of using different CDW fines to develop recycled cements and optimized the content of CDW recycled cements with well-graded crushed stone (WGCS) for use as pavement base layer. We scaled up the study obtaining CDW cement and aggregates from a local recycling plant, as well as pilot pavement sections designed, constructed and field deflections measured. As results, the CDW cement pastes exhibited accumulated heat values of up to 111 J g-1 and achieved a compressive strength of approximately 16 MPa. The unconfined compressive strength and resilient modulus (RM) achieved using CDW cement and WGCS were 2-3 and >3000 MPa, respectively. The sections constructed using CDW cement exhibited intermediate behaviour compared to those obtained using reference materials (6% Portland cement-WGCS and a conventional granular base made using WGCS). The deflection decreased over time owing to the pozzolanic reaction.

全世界每年产生的建筑和拆除垃圾(CDW)达 100 亿吨。其中大部分被填埋,需要创新的回收方法来减少相关的环境影响并提高其循环性。我们的研究证明了使用不同的建筑垃圾废弃物细料开发再生水泥的可行性,并优化了建筑垃圾废弃物再生水泥与级配良好的碎石(WGCS)的含量,以用作路面基层。我们扩大了研究规模,从当地一家回收厂获得了煤渣水泥和集料,并设计、建造了试验路面断面,测量了现场挠度。结果显示,CDW 水泥浆的累积热值高达 111 J g-1,抗压强度约为 16 兆帕。使用 CDW 水泥和 WGCS 获得的无收缩抗压强度和弹性模量(RM)分别为 2-3 兆帕和大于 3000 兆帕。与使用参考材料(6% 硅酸盐水泥-WGCS 和使用 WGCS 制成的传统颗粒基底)相比,使用 CDW 水泥建造的断面表现出中等强度。由于发生了胶凝反应,挠度随着时间的推移而减小。
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引用次数: 0
Waste to energy, indispensable cornerstone for circular economy: A mini-review. 废物变能源,循环经济不可或缺的基石:小型回顾。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-01 Epub Date: 2024-01-29 DOI: 10.1177/0734242X241227376
Paul H Brunner, Leo S Morf

This mini-review aims at proving that waste-to-energy (WtE) is an essential cornerstone for circular economy (CE). Based on literature, the history of thermal waste treatment over the last 150 years is investigated, from open burning to WtE with resource recovery and final sink function. The results show that in the past incineration solved the issues it was designed for but often created new and sometimes even worse problems: The introduction of incineration in the 19th century improved urban sanitation, decreased waste volume and prolonged operational life of landfills. But it also polluted the environment, triggering an unprecedented scientific and engineering effort of all stakeholders. Today, WtE is one of the best investigated and optimized technologies in waste management. It enables the recovery of energy as heat and electric power and facilitates the 'cleaning' of cycles by the destruction of hazardous organic substances. Recent developments in resource recovery from WtE residues allow to recycle metals and, in the case of sewage sludge, even phosphorus by thermal recycling. Combined with carbon capture and storage technology, WtE stands for a quantifiable contribution to greenhouse gas reduction. Today, WtE is indispensable to reach the goals of CE, namely recycling of energy and materials, supplying safe final sinks for persistent organic substances and minimizing the need for sinks for hazardous inorganic substances.

本微型综述旨在证明废物变能源(WtE)是循环经济(CE)的重要基石。在文献的基础上,研究了过去 150 年来热废物处理的历史,从露天焚烧到具有资源回收和最终汇功能的 WtE。研究结果表明,过去的焚烧法解决了设计时所针对的问题,但往往会产生新的问题,有时甚至是更严重的问题:19 世纪引入的焚烧技术改善了城市卫生状况,减少了垃圾量,延长了垃圾填埋场的运行寿命。但同时也污染了环境,引发了所有利益相关方前所未有的科学和工程努力。如今,WtE 已成为废物管理领域研究和优化得最好的技术之一。它能够回收热能和电能,并通过销毁有害有机物促进循环的 "清洁"。从 WtE 剩余物中进行资源回收的最新进展使金属得以回收利用,在污水污泥的情况下,甚至可以通过热回收利用来回收磷。结合碳捕集与封存技术,WtE 对减少温室气体排放做出了可量化的贡献。如今,要实现 CE 目标,即能源和材料的循环利用、为持久性有机物质提供安全的最终汇以及最大限度地减少对有害无机物质汇的需求,WtE 是不可或缺的。
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引用次数: 0
Media exposure and plastic-reducing behaviours in China: The mediating effect of environmental concern and locus of control. 中国的媒体接触与减塑行为:环境关注和控制位置的中介效应。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-01 Epub Date: 2024-02-06 DOI: 10.1177/0734242X241227382
Yingying Li, Bairong Wang, Yong Li

The environmental problems caused by plastic pollution have increased at an astonishing speed. However, attempts to study the dynamics of plastic-reducing behaviours are few and far between. In this regard, based on the attitudinal-contextual-behavioural (ABC) theory of pro-environmental behaviours, this study conducts an online survey to analyse the functioning of media exposure on Chinese consumers' three types of plastic bag reducing behaviours during shopping, including saving inner plastic packaging bags by putting many goods into one bag, hand-carrying and bringing reusable bags. Employing the snowball sampling method, this study successfully collected 361 valid questionnaires for analysis. The findings of this study indicate that environmental concern and locus of control play mediating roles between media exposure and plastic-reducing behaviours. However, the study finds no supporting evidence for the mediating function of plastic pollution knowledge. These results have implications for plastic crisis managers and governmental officials. In designing media content for environmental education campaigns, it is advisable to prioritize strategies that evoke emotions over a sole focus on disseminating knowledge about plastic pollution.

塑料污染造成的环境问题正以惊人的速度加剧。然而,对减少塑料污染行为的动态研究却少之又少。为此,本研究基于亲环境行为的态度-情境-行为(ABC)理论,开展了一项在线调查,分析媒体曝光对中国消费者在购物过程中减少塑料袋使用的三种行为的影响,包括将多种商品装入一个塑料袋以节省内层塑料包装袋、手提和携带可重复使用的塑料袋。本研究采用 "滚雪球 "抽样方法,成功收集了 361 份有效问卷,并进行了分析。研究结果表明,环境关注和控制感在媒体接触与减少塑料包装行为之间起着中介作用。然而,研究没有发现塑料污染知识的中介作用的支持证据。这些结果对塑料危机管理者和政府官员具有启示意义。在为环境教育活动设计媒体内容时,最好优先考虑唤起情感的策略,而不是仅仅关注传播塑料污染知识。
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引用次数: 0
Social cost--benefit analysis of solid waste management options with application to Mumbai, India. 应用于印度孟买的固体废物管理方案的社会成本效益分析。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-01 Epub Date: 2024-02-22 DOI: 10.1177/0734242X241231401
Nishith Jardosh, Vinish Kathuria

Managing solid waste continues to be an environmental, technical and economic challenge, especially for developing countries. Though these countries' urban local bodies (ULBs) are moving up the waste management hierarchy, most waste is still openly dumped. One key reason for this choice is the non-accounting of (a) social costs associated with open dumping (OD) and (b) direct/indirect benefits of other options. The current study conducts a complete social cost-benefit analysis (SCBA) comparing OD to sanitary landfilling, composting, bio-methanation, incineration and gasification alternatives. The study finds that when only private costs/benefits are considered, a mix of OD and sanitary landfills is preferred; however, when external costs/benefits are factored in, the mix shifts towards alternatives like incineration and gasification. These learnings from the SCBA are then applied to Mumbai, which generates 9000 tonnes of waste daily. To determine the optimal mix for Mumbai ULB, a constrained optimization exercise is carried out considering the technical feasibility of the alternatives and the ULB's capital budget. The study finds that with the current practice of OD, the net present value (NPV) of the social costs over a 30-year horizon will be over US$ 6-9 billion. However, even if one-fifth of the ULB's capital budget is allocated towards other waste management alternatives, the mix would shift towards sophisticated technologies and the NPV of social costs would reduce to around half that amount.

固体废物管理仍然是一项环境、技术和经济挑战,尤其是对发展中国家而言。尽管这些国家的城市地方机构(ULBs)正在提升废物管理等级,但大多数废物仍被公开倾倒。造成这种选择的一个关键原因是没有考虑 (a) 与露天倾倒 (OD) 相关的社会成本和 (b) 其他选择的直接/间接效益。本研究对露天堆放与卫生填埋、堆肥、生物甲烷化、焚烧和气化替代方案进行了全面的社会成本效益分析(SCBA)。研究发现,如果只考虑私人成本/效益,则更倾向于将 OD 和卫生填埋混合使用;但如果将外部成本/效益考虑在内,则更倾向于焚烧和气化等替代品。这些从 SCBA 学到的知识随后被应用到孟买,孟买每天产生 9000 吨垃圾。为了确定孟买 ULB 的最佳组合,考虑到替代方案的技术可行性和 ULB 的资本预算,进行了限制性优化。研究发现,按照目前的 OD 做法,30 年的社会成本净现值 (NPV) 将超过 60-90 亿美元。然而,即使将 ULB 资本预算的五分之一分配给其他废物管理替代方案,其组合也将转向先进技术,社会成本的净现值将减少到该数额的一半左右。
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引用次数: 0
The evolutionary path of medical waste management research: Insights from co-citation and co-word analysis. 医疗废物管理研究的演变之路:共同引用和共同关键词分析的启示。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-01 Epub Date: 2024-02-14 DOI: 10.1177/0734242X241227378
Arif Soyler, Serhat Burmaoglu, Levent Bekir Kidak

Over the past decades, medical waste management (MWM) has evolved into a paramount global challenge, intertwining environmental sustainability and public health dimensions. This manuscript traces the paradigm shift from the foundational Basel Convention of 1989 to the significant sway of World Health Organization publications on contemporary debates. Utilizing a mixed approach strategy that blended qualitative and quantitative techniques, the research employed extensive literature review, co-citation and co-word analysis methodologies to ascertain the direction of contemporary trends in MWM. Within the scope of the research findings, current strategies reveal noticeable gaps, especially those that lack sound policy structures, comprehensive insights and effective operational frameworks. Co-citation evaluations spotlight predominant themes in academic references. Foremost among them are the socioeconomic factor, environmental significance, medical waste (MW) stabilization and sustainable society, sequenced by cluster magnitude. Co-word analysis unveils that, despite the long-standing presence of incineration plants, pyrolysis has, since 2016, prioritized environmental considerations. The recycling ethos peaked in 2014, but the sustainability paradigm burgeoned in 2020, with the 'circular economy' gaining momentum in 2021. Emerging trend analysis underscores the mounting significance of circular waste technologies and sustainability as indispensable solutions. Results demonstrate MW advancements and highlight emerging trends shaping the future of the field. The research concludes by accentuating the necessity of global collaborative efforts, integrating cutting-edge technologies and infusing sustainability and circularity tenets into societal frameworks to navigate MWM's intricate landscape. Future research trajectories, including wastewater governance, novel mobile waste disposal strategies and a cyclic waste classification paradigm, are proposed.

在过去的几十年里,医疗废物管理(MWM)已发展成为一项至关重要的全球性挑战,它将环境可持续性与公共卫生问题交织在一起。本手稿追溯了从 1989 年基础性《巴塞尔公约》到世界卫生组织出版物对当代辩论产生重大影响的范式转变。本研究采用混合方法策略,将定性和定量技术相结合,通过广泛的文献综述、共同引用和共同词汇分析方法来确定当代小型工程管理趋势的方向。在研究结果的范围内,当前的战略揭示了明显的差距,尤其是那些缺乏健全的政策结构、全面的见解和有效的运作框架的战略。共同引用评价突出了学术参考文献中的主要专题。其中最重要的是社会经济因素、环境意义、医疗废物(MW)稳定化和可持续社会,并按组群规模排序。共同关键词分析显示,尽管焚烧厂长期存在,但自 2016 年以来,热解技术已将环境因素列为优先考虑因素。回收利用的风气在 2014 年达到顶峰,但可持续发展模式在 2020 年迸发,"循环经济 "在 2021 年获得了发展势头。新趋势分析强调了循环废物技术和可持续发展作为不可或缺的解决方案所具有的日益重要的意义。研究结果表明了千年发展目标的进展,并强调了塑造该领域未来的新兴趋势。研究最后强调了全球合作的必要性,整合尖端技术,将可持续性和循环性原则纳入社会框架,以驾驭小型工程管理的复杂局面。研究还提出了未来的研究方向,包括废水治理、新型移动废物处理策略和循环废物分类范例。
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引用次数: 0
Recycling alkali lignin-derived biochar with adsorbed cadmium into cost-effective CdS/C photocatalyst for methylene blue removal. 将吸附了镉的碱木质衍生生物炭回收利用为具有成本效益的 CdS/C 光催化剂,用于去除亚甲基蓝。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-01-01 Epub Date: 2024-02-23 DOI: 10.1177/0734242X241231394
Peng Yu, Ronghao Zhuang, Hui Liu, Zhiguo Wang, Chun Zhang, Qiongchao Wang, Hongyu Sun, Wei Huang

Cadmium (Cd)-enriched adsorbents wastes possess great environmental risk due to their large-scale accumulation and toxicity in the natural environment. Recycling spent Cd-enriched adsorbents into efficient catalysts for advanced applications could address the environmental issues and attain the carbon neutral goal. Herein, a facile strategy is developed for the first time to reutilize the alkali lignin (AL)-derived biochar (ALB) absorbed with Cd into cadmium sulphide (CdS)/C composite for the efficient methylene blue (MB) removal. The ALB is initially treated with Cd-containing solution, then the recycling ALB samples with adsorbed Cd are converted to the final CdS/C composite using NaS2 as the sulphurizing reagent for vulcanization reaction. The optimal ALB400 demonstrates a high adsorption capacity of 576.0 mg g-1 for Cd removal. Then the converted CdS/C composite shows an efficient MB removal efficiency of 94%. The photodegradation mechanism is mainly attributed to carbon components in the CdS/C composite as electron acceptor promoting the separation of photoelectrons/holes and slowing down the abrasion of CdS particles. The enhanced charge transfer and contact between the carrier and the active site thus improves the removal performance and reusability. This work not only develops a method for removing Cd from wastewater effectively and achieving the waste resource utilization but also further offers a significant guidance to use other kinds of spent heavy metal removal adsorbents for the construction of low-cost and high value-added functional materials.

富镉(Cd)吸附剂废物在自然环境中的大规模积累和毒性具有极大的环境风险。将废弃的富镉吸附剂回收利用,制成先进应用的高效催化剂,可以解决环境问题,实现碳中和目标。本文首次开发了一种简便的策略,将吸收了镉的碱木素(AL)衍生生物炭(ALB)重新利用为硫化镉(CdS)/C 复合材料,用于高效去除亚甲基蓝(MB)。首先用含镉溶液处理 ALB,然后用 NaS2 作为硫化试剂进行硫化反应,将吸附了镉的回收 ALB 样品转化为最终的 CdS/C 复合材料。最佳 ALB400 对镉的吸附能力高达 576.0 mg g-1。转化后的 CdS/C 复合材料对甲基溴的去除率高达 94%。光降解机制主要归因于 CdS/C 复合材料中的碳成分作为电子受体,促进了光电子/空穴的分离,减缓了 CdS 粒子的磨损。载流子与活性位点之间的电荷转移和接触增强,从而提高了去除性能和可重复使用性。这项工作不仅开发了一种有效去除废水中镉的方法,实现了废物资源化利用,还为利用其他种类的废重金属去除吸附剂构建低成本、高附加值的功能材料提供了重要指导。
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引用次数: 0
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