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Recycling potential of cobalt metal from end-of-life new energy passenger vehicles in China. 中国新能源乘用车报废金属钴的回收潜力。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-31 DOI: 10.1177/0734242X231219650
Li Yang, Sun Liangfang, Liu Yanhui, Ye Zuoyi

The growing demand for new energy vehicles (NEVs) has resulted in a corresponding increase in demand for cobalt as a critical material. It is crucial to estimate the cobalt resource recycling potential of China's NEV industry to ensure a balance between the supply and demand for cobalt metal minerals. This article is based on using the historical data of the new energy passenger vehicle (NEPV) sales volume from 2013 to 2022 to estimate the NEPV sales volume from 2023 to 2035. On this basis, the Weibull distribution was used to analyse the different sales scenarios (low sales and high sales) of NEPVs in China, and the recycling potential of cobalt metal in NEPVs was evaluated under three battery life scenarios (8, 10 and 12 years) from 2023 to 2035. Based on the above scenarios, in 2035, the greatest recycling potential of cobalt is predicted to be 166.9 kilotonnes, with economic values of CNY 49.01-94.60 billion. Moreover, the extent to which the recycling potential of cobalt can cover the market demand for NEPVs was analysed. Our analysis concluded that recycling cobalt as a secondary supply has emerged as a necessary solution to supplement the primary supply, which can make a significant contribution to alleviating the pressure of the supply and demand.

随着新能源汽车(NEV)需求的不断增长,对关键材料钴的需求也相应增加。估算中国新能源汽车产业的钴资源回收潜力对于确保钴金属矿产的供需平衡至关重要。本文基于 2013 年至 2022 年新能源乘用车(NEPV)销量的历史数据,对 2023 年至 2035 年的 NEPV 销量进行估算。在此基础上,利用威布尔分布分析了中国新能源乘用车的不同销量情景(低销量和高销量),并评估了 2023 年至 2035 年三种电池寿命情景(8 年、10 年和 12 年)下新能源乘用车中金属钴的回收潜力。根据上述情景预测,2035 年钴的最大回收潜力为 166.9 千吨,经济价值为 490.1-946.0 亿元人民币。此外,我们还分析了钴的回收潜力能在多大程度上满足 NEPV 的市场需求。我们的分析得出结论,回收钴作为二次供应已成为补充一次供应的必要解决方案,可为缓解供需压力做出重大贡献。
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引用次数: 0
Deposit pickers in the Nordic: The role of deposit-refund systems for waste pickers in Stockholm. 北欧的拾荒者:斯德哥尔摩拾荒者的押金退还制度的作用。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-28 DOI: 10.1177/0734242X241297574
Nils Johansson

This article examines a specific subtype of informal waste picking: deposit picking. Despite its global prevalence, waste picking has neither been extensively studied in the Nordic countries nor in the context of a deposit-refund system. Through interviews and text analyses of waste pickers in Stockholm, Sweden, similarities and differences between deposit picking and traditional waste picking are uncovered. For example, unlike other waste materials, the income from deposits is stable. The focus on beverage containers and the ability of reverse vending machines to sort the containers, lowers the knowledge threshold to begin the activity. The lightweight nature of beverage containers makes collection mobile, and deposit pickers often carry only a bag. The deposit pickers are mainly older, poor and male. Similar to traditional waste pickers, deposit pickers are central to the formal waste system, but their work is invisible, and foreign deposit pickers, in particular, are stigmatized. The dual invisibility of their labour and contributions, coupled with their independence from formal social systems, highlights the need for internal organization and representation within the formal systems.

这篇文章探讨了一个特定的子类型的非正式废物采摘:存款采摘。尽管它的全球流行,垃圾采摘既没有在北欧国家广泛研究,也没有在存款退款制度的背景下。通过对瑞典斯德哥尔摩拾荒者的访谈和文本分析,揭示了押金拾荒与传统拾荒的异同。例如,与其他废物不同,存款的收入是稳定的。对饮料容器的关注和反向自动售货机对容器进行分类的能力,降低了开始活动的知识门槛。饮料容器的重量轻,使得收集移动,和存款采摘往往只携带一个袋子。挑选存款的人主要是老年人、穷人和男性。与传统的拾荒者类似,拾荒者是正式废物系统的核心,但他们的工作是隐形的,尤其是外国拾荒者,受到了污名化。他们的劳动和贡献的双重隐形,加上他们独立于正式的社会制度,突出了正式制度内部组织和代表的必要性。
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引用次数: 0
Ecological compensation for cross-regional domestic waste treatment: A stochastic differential game perspective. 跨区域生活垃圾处理的生态补偿:一个随机微分博弈视角。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-28 DOI: 10.1177/0734242X241299099
Mengdi Li, Chuanfeng Han, Lingpeng Meng, Zhiguo Shao, Pihui Liu

The implementation of ecological compensation for cross-regional domestic waste treatment is beneficial for balancing the interests of waste generation districts and waste treatment districts. This paper introduces dynamic differential games to capture the temporal evolution and adjustment of strategies, examining dynamic game strategies under different compensation scenarios (non-horizontal ecological compensation, horizontal ecological compensation and fully shared ecological compensation). A new interest distribution model is proposed, with empirical analysis conducted using Shanghai as a case study to validate the reliability and feasibility of the model. The findings indicate: (1) Government intervention combined with horizontal ecological compensation significantly improves waste management efficiency and urban welfare. The compensation mechanism fosters regional cooperation, optimizes resource allocation, reduces decision-making conflicts and enhances overall processing effectiveness. (2) Without a compensation mechanism, high costs in export regions and low benefits in import regions result in low cooperation willingness. The ecological compensation mechanism enhances willingness to cooperate by fairly distributing costs and benefits, optimizing long-term cooperation and overall gains. (3) Complete shared ecological compensation is optimal, though partial shared mechanisms are also effective in practice. Proper interest and ecological compensation ratios can significantly improve waste management efficiency and urban environment, strengthening long-term cooperation. The study theoretically expands the dynamic optimization and cooperation mechanism analysis in waste management, provides solutions for environmental policy formulation in cross-regional waste handling and offers new perspectives and tools for addressing complex issues in cross-regional environmental governance, including targeted policy recommendations with practical significance for enhancing cross-regional waste management.

实施跨区域生活垃圾处理生态补偿,有利于平衡垃圾产生区和垃圾处理区的利益。本文引入动态差分对策,考察了不同补偿情景(非水平生态补偿、水平生态补偿和完全共享生态补偿)下的动态博弈策略。提出了一种新的利益分配模型,并以上海市为例进行了实证分析,验证了模型的可靠性和可行性。研究结果表明:(1)政府干预与横向生态补偿相结合,显著提高了城市垃圾管理效率和城市福利。补偿机制促进了区域合作,优化了资源配置,减少了决策冲突,提高了整体处理效率。(2)由于缺乏补偿机制,出口地区成本高,进口地区效益低,导致合作意愿低。生态补偿机制通过公平分配成本和收益,优化长期合作和整体收益,增强合作意愿。(3)完全共享的生态补偿是最优的,但部分共享机制在实践中也是有效的。适当的利息和生态补偿比例可以显著提高废物管理效率和城市环境,加强长期合作。本研究在理论上拓展了废物管理的动态优化与合作机制分析,为跨区域废物处理的环境政策制定提供了解决方案,为解决跨区域环境治理中的复杂问题提供了新的视角和工具,包括有针对性的政策建议,对加强跨区域废物管理具有现实意义。
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引用次数: 0
Microplastics' impact on soil health and quality: Effect of incubation time and soil properties in soil fertility and pollution extent under the circular economy concept. 微塑料对土壤健康和质量的影响:在循环经济理念下,培养时间和土壤性质对土壤肥力和污染程度的影响。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-22 DOI: 10.1177/0734242X241299110
Evangelia E Golia, Vasiliki Liava, Dimitrios S Achilias, Jose Navarro-Pedreño, Antonis A Zorpas, John Bethanis, Stella Girousi

The aim of the present study is to highlight the effect of two commonly used plastics, polyethylene (PE) and polyethylene terephthalate (PET), on the quality and health indices of soil. To this end, a pot experiment was carried out using two soils, one acidic and one alkaline. The soil samples were collected from rural areas of central and Northern Greece and had similar particle size composition and almost equal copper (Cu), zinc (Zn), cadmium (Cd) and lead (Pb) concentrations. PE and PET microplastics (MPs) were added into the soil samples in two ratios (2% and 4% v/v) and remained in the soils for 20, 60 and 120 days. Then, the changes in the properties, nutrients, potentially toxic elements and health indicators of the soil samples were measured. PE addition at 4% v/v caused the maximum increase in trace element availability when it remained in the soil sample for 120 days. In contrast, PET addition caused a maximum decrease in the DTPA-extractable concentration of toxic elements (Cd and Pb), after 120 days of incubation in acid and alkaline soil. The present work provides a fresh perspective evaluating MPs from unwanted waste to materials with potential positive benefits, enhancing the circular economy approach to soil systems. Knowledge of the MPs present in soils, along with physicochemical soil properties, including their nutrient and toxic element content, are critical aspects that need to be addressed to ensure that soil quality and health are not adversely affected.

本研究旨在强调聚乙烯(PE)和聚对苯二甲酸乙二酯(PET)这两种常用塑料对土壤质量和健康指数的影响。为此,我们使用酸性和碱性两种土壤进行了盆栽实验。土壤样本采集自希腊中部和北部的农村地区,其粒度组成相似,铜(Cu)、锌(Zn)、镉(Cd)和铅(Pb)的浓度几乎相同。PE 和 PET 微塑料(MPs)以两种比例(2% 和 4% v/v)添加到土壤样本中,并在土壤中保留 20、60 和 120 天。然后,测量土壤样本的性质、养分、潜在有毒元素和健康指标的变化。当 4% v/v 的 PE 在土壤样本中保留 120 天时,微量元素的可用性增加最大。与此相反,在酸性和碱性土壤中培养 120 天后,PET 的添加使有毒元素(镉和铅)的 DTPA 可萃取浓度下降幅度最大。本研究提供了一个全新的视角,评估从无用废物到具有潜在积极效益的材料的 MPs,从而加强土壤系统的循环经济方法。要确保土壤质量和健康不受不利影响,就必须了解土壤中存在的 MPs 以及土壤理化性质,包括其养分和有毒元素含量。
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引用次数: 0
A review on European sustainable practices in end-of-life vehicles management. 欧洲报废汽车管理可持续做法回顾。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-19 DOI: 10.1177/0734242X241299098
Francesco Arpino, Idiano D'Adamo, Massimo Gastaldi, Shabbir H Gheewala

The management of end-of-life vehicles (ELVs) has become a significant environmental and economic challenge due to the substantial volumes of hazardous waste generated. This article analyses sustainable practices in ELV management across Europe, with a focus on contributions to the circular economy. The systematic literature review, conducted for articles published in the period 2016-2024, identifies five topics: (1) policy and regulatory frameworks evaluations and suggestions; (2) economic and environmental benefits through optimization modelling; (3) trends and performances analysis; (4) advanced treatment technologies and their impact and (5) economic and environmental impacts assessments. The findings highlight the importance of state-of-the-art recycling processes and coordinated stakeholder efforts in improving ELV management outcomes. In addition, the correlation between ELVs recycling and gross domestic product (GDP) was analysed. Data analysis for 27 European countries in the period 2016-2021 shows a moderate correlation. Specifically, countries with stronger economies tend to produce more ELVs, distinguishing two clusters when GDP is 35,000 € per capita. By adopting best practices and innovative approaches, European countries can enhance their ELV management systems, support a more circular economy and sustainable development. This work highlights the possible correlation between GDP per capita and ELV recycling rates across the European Union, the identification of economic clusters, and the critical role that advanced recycling technologies play in improving sustainability.

由于产生大量有害废物,报废汽车(ELV)的管理已成为一项重大的环境和经济挑战。本文分析了欧洲报废汽车管理的可持续实践,重点关注对循环经济的贡献。本文对 2016-2024 年间发表的文章进行了系统的文献综述,确定了五个主题:(1)政策和监管框架评估及建议;(2)通过优化建模实现经济和环境效益;(3)趋势和性能分析;(4)先进处理技术及其影响;(5)经济和环境影响评估。研究结果凸显了最先进的回收工艺和利益相关方协调努力在改善 ELV 管理成果方面的重要性。此外,还分析了 ELV 回收与国内生产总值(GDP)之间的相关性。对 2016-2021 年期间 27 个欧洲国家的数据分析显示,两者之间存在适度的相关性。具体而言,经济实力较强的国家倾向于生产更多的 ELV,当人均 GDP 为 35,000 欧元时,可分为两个集群。通过采用最佳实践和创新方法,欧洲国家可以加强其 ELV 管理系统,支持更加循环的经济和可持续发展。这项工作强调了欧盟各国人均国内生产总值与 ELV 回收率之间可能存在的相关性、经济集群的识别以及先进回收技术在改善可持续性方面发挥的关键作用。
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引用次数: 0
Shifting perceptions of informal operators in the service and value chains: A retrospective of 40 years of observation and advocacy for informal recyclers and waste service providers, through the eyes of five global participant-researchers. 改变对服务和价值链中非正规经营者的看法:通过五位全球参与式研究者的视角,回顾 40 年来对非正规回收者和废物服务提供者的观察和宣传。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-19 DOI: 10.1177/0734242X241280076
Michael Simpson, Kwaku Oduro-Appiah, Ellen Gunsilius, Sonia Maria Dias, Anne Scheinberg

This article offers a reflective retrospective of the literature and practice on the informal waste and recycling sector. The authors have joined to share our experience and knowledge on the interface between the formal solid waste sector and informal recyclers and operators. Together, we discuss where this discourse has come from, where it is now, and where we, as practitioners, think it is going. We share our understanding of the waste and recycling sectors and how informality within them functions. The retrospective covers nearly 40 years of research, practice, advocacy, action, writing and intervention. The main storyline is how the public and private solid waste authorities and service providers relate to informal operators in both recycling ('the (private) value chains') and waste management ('the (public) service chain'). The recurring theme is how engaged scholarship and practice have interacted with, modified and improved the position of informal operators and workers and contributed to positive outcomes in both service and value chains. Throughout the period covered by this retrospective, opinions and framing on all sides have shifted substantially through the years, whereas the economic activities of informal recyclers and informal waste collection service providers have remained largely unchanged. Although we refer to both scientific and operational documents, we do not have the ambition to produce a scientific paper. Rather, we follow other authors of the special issue in referring to ourselves as involved witnesses who share a commitment to improving waste and recycling practices at the boundary of formal and informal systems.

本文对非正规废物和回收部门的文献和实践进行了反思性回顾。作者们共同分享了我们在正规固体废物部门与非正规回收者和经营者之间的经验和知识。我们一起讨论了这一讨论的起源、现状,以及我们作为实践者认为这一讨论将走向何方。我们分享了我们对废物和回收行业的理解,以及非正规性在其中是如何发挥作用的。回顾展涵盖了近 40 年的研究、实践、宣传、行动、写作和干预。主要故事情节是公共和私营固体废物管理机构和服务提供商如何与回收("(私营)价值链")和废物管理("(公共)服务链")中的非正规经营者建立联系。反复出现的主题是,参与性学术研究和实践如何与非正规经营者和工人的地位相互作用,如何改变和提高他们的地位,如何促进服务链和价值链取得积极成果。在本次回顾所涵盖的整个时期,各方的观点和框架多年来发生了很大变化,而非正规回收商和非正规废物收集服务提供商的经济活动却基本保持不变。尽管我们参考了科学和业务文件,但我们并没有撰写科学论文的雄心。相反,我们效仿本特刊的其他作者,将自己称为参与其中的见证者,共同致力于改善正规和非正规系统交界处的废物和回收做法。
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引用次数: 0
Developing WasteSAM: A novel approach for accurate construction waste image segmentation to facilitate efficient recycling. 开发 WasteSAM:准确分割建筑垃圾图像以促进有效回收的新方法。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-18 DOI: 10.1177/0734242X241290743
Seokjae Heo, Seunguk Na

The escalating volume of construction activities and resultant waste generation underscores the imperative for developing sophisticated segmentation models to facilitate efficient sorting and recycling processes. This study introduces WasteSAM, an enhanced iteration of the segment anything model (SAM), specifically tailored to address the intricate complexities inherent in construction waste imagery. Drawing upon a comprehensive dataset comprising over 15,000 masks representing five distinct categories of construction materials, WasteSAM exhibits notably superior segmentation capabilities. Quantitative analysis demonstrates significant performance improvements, with WasteSAM outperforming the original SAM model by an average of 23.9% in dice similarity coefficient and 30.0% in normalized surface distance metrics. The integration of stereo-image techniques in refining the training dataset has facilitated WasteSAM in more accurately discerning the three-dimensional structure of waste materials, thereby augmenting the precision of waste classification. Noteworthy is the model's adeptness in handling intricate textures and patterns across diverse imaging modalities, including varying lighting conditions and complex object interactions. While showing promising results, this study also highlights the need for high-quality, diverse datasets that reflect real-world construction site complexities, rather than merely larger datasets.

不断攀升的建筑活动量和由此产生的废弃物凸显了开发先进的细分模型以促进高效分类和回收流程的必要性。本研究介绍了 WasteSAM,它是分段任何模型(SAM)的增强迭代,专门用于解决建筑垃圾图像中固有的错综复杂问题。WasteSAM 利用由 15,000 多个掩模组成的综合数据集,代表了五种不同类别的建筑材料,显示出明显优越的分割能力。定量分析表明,WasteSAM 的性能有了显著提高,在骰子相似系数和归一化表面距离指标上,WasteSAM 平均分别比原始 SAM 模型高出 23.9% 和 30.0%。在完善训练数据集时融入立体图像技术,有助于 WasteSAM 更准确地辨别废物材料的三维结构,从而提高废物分类的精确度。值得注意的是,该模型善于处理各种成像模式下的复杂纹理和图案,包括不同的光照条件和复杂的物体相互作用。这项研究在显示出良好结果的同时,也强调了对反映真实世界建筑工地复杂性的高质量、多样化数据集的需求,而不仅仅是较大的数据集。
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引用次数: 0
Risk minimizing framework for solar photovoltaics. 太阳能光伏发电风险最小化框架。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-18 DOI: 10.1177/0734242X241291938
Preeti Nain, Mainak Bhattacharya, Arun Kumar

The complexity of risk assessment and the challenges in decision-making often impede the application of various models to renewable energy systems. This study introduces a comprehensive framework designed to streamline this process, facilitating informed decisions regarding the estimation of risks associated with solar photovoltaic (PV) technologies. Leveraging data and information available in the literature, the framework is particularly useful for manufacturers in selecting materials that balance low environmental risk with high efficiency. The framework emphasizes early-stage risk minimization by integrating changes during PV development, thereby promoting cleaner production systems. It's interconnected components encompass various approaches to risk assessment, control, and management, providing a structured methodology for risk reduction. Based on available information, the defined steps guide users through evaluating and mitigating risks. Applying risk minimization by metal substitution approach lowers the oral-ingestion and dermal-contact risk by a magnitude of four and six times, respectively. This framework will guide regulatory bodies throughout each step of the product life cycle, suggesting necessary changes and assessment strategies aligned with the perspectives of various stakeholders. By facilitating the identification and implementation of the most effective risk management strategies, the framework aims to advance the development of sustainable and safe PV technologies.

风险评估的复杂性和决策方面的挑战往往阻碍各种模型在可再生能源系统中的应用。本研究介绍了一个旨在简化这一过程的综合框架,有助于就太阳能光伏(PV)技术的相关风险评估做出明智的决策。利用文献中的数据和信息,该框架尤其有助于制造商选择兼顾低环境风险和高效率的材料。该框架强调通过整合光伏开发过程中的变化,将早期阶段的风险降至最低,从而促进清洁生产系统的发展。该框架的各个组成部分相互关联,涵盖了风险评估、控制和管理的各种方法,为降低风险提供了结构化方法。在现有信息的基础上,确定的步骤指导用户评估和降低风险。通过金属替代方法实现风险最小化,可将口腔摄入和皮肤接触风险分别降低四倍和六倍。该框架将在产品生命周期的每一个步骤中为监管机构提供指导,根据各利益相关方的观点提出必要的变更和评估策略。通过促进确定和实施最有效的风险管理战略,该框架旨在推动可持续和安全光伏技术的发展。
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引用次数: 0
Optimizing food waste anaerobic digestion in Kuwait: Experimental insights and empirical modelling using artificial neural networks. 优化科威特的厨余厌氧发酵:利用人工神经网络的实验见解和经验建模。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-13 DOI: 10.1177/0734242X241294247
Jean H El Achkar, Suad Al Radhwan, Ahmed M Al-Otaibi, Abdul Md Mazid

This study investigates, for the first time, the anaerobic digestion of food waste in Kuwait to optimize methane production through a combination of artificial neural network (ANN) modelling and continuous reactor experiments. The ANN model, utilizing eight hidden neurons and a 70-20-10 split for training, validation and testing sets, yielded mean squared error values of 0.0056, 0.0048 and 0.0059 and coefficient of determination (R²) values of 0.9942, 0.9986 and 0.9892, respectively. Methane percentages in biogas were predicted using six parameters: biomass type, pH, organic loading rate (OLR), hydraulic retention time (HRT), temperature and reactor volume. To validate the ANN results, continuous reactor experiments were conducted under an OLR of 3 kg VS m⁻³ d⁻¹ and HRT of 20 days at varying temperatures (35°C, 40°C, 45°C, 50°C and 55°C). The experiments demonstrated optimal methane production in the mesophilic range, with ANN predictions closely aligning with experimental data up to 45°C. However, deviations were observed at higher temperatures, particularly under thermophilic conditions beyond 50°C. This study provides novel insights into waste-to-energy initiatives in Kuwait and highlights the potential of integrating computational models with empirical data to enhance biogas production processes.

本研究首次通过人工神经网络(ANN)建模和连续反应器实验相结合的方法,对科威特餐厨垃圾厌氧消化进行了调查,以优化甲烷生产。人工神经网络模型采用 8 个隐藏神经元,训练集、验证集和测试集按 70-20-10 的比例分配,平均平方误差值分别为 0.0056、0.0048 和 0.0059,决定系数 (R²) 分别为 0.9942、0.9986 和 0.9892。通过生物质类型、pH 值、有机负荷率 (OLR)、水力停留时间 (HRT)、温度和反应器容积这六个参数,预测了沼气中甲烷的百分比。为了验证 ANN 的结果,在不同温度(35°C、40°C、45°C、50°C 和 55°C)条件下进行了连续反应器实验,OLR 为 3 kg VS m-³ d-¹,HRT 为 20 天。实验表明,在中嗜酸性范围内甲烷产量最佳,ANN 预测值与 45°C 以下的实验数据非常吻合。然而,在更高温度下,特别是在超过 50°C 的嗜热条件下,出现了偏差。这项研究为科威特的废物变能源计划提供了新的见解,并强调了将计算模型与经验数据相结合以提高沼气生产工艺的潜力。
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引用次数: 0
Realization of quasi-steady-state piled smouldering using sequential operation chambers for industrial treatment of biomass wastes. 利用顺序运行室实现准稳态堆垛烟熏,用于生物质废物的工业处理。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-11-10 DOI: 10.1177/0734242X241290766
Wentao Zhao, Guangxin Yu, Ehsan Elahi, Junmeng Cai, Frank Behrendt, Thomas Schliermann, Fang He

Piled smouldering has great potential for treatment and utilization of biomass wastes. However, its unsteady-state nature limits its industrial utilization, as well as treatment of smoke. This article addresses this issue by proposing the sequential operation of numerous smouldering chambers to realize steady- or quasi-steady-state piled smouldering. The superposition characteristics of sequential unsteady-state curves were analysed theoretically, and a code was developed to determine an appropriate number of piled chambers at an allowance oscillation percentage. Smouldering experiments were performed on a single mini chamber (length × width × height: 340 × 140 × 140 mm3) containing piled wood pellets mixed with wood powder. The superposition of sequential burning rate curves was demonstrated using the code based on the mass loss data of experiments. Analysis shows that the perfect-steady state is possible given the superposition value of the burning rate curve is a constant in this proposed system. Experiments show that the molar ratio of CO/CO2 in smoke is almost a constant around 0.5 during densely piled smouldering, showing the great potential for self-sustained burning out the smoke. Based on the experimental results, the calculation results show that the relative oscillation range of burning rate (OSC) decreases from 75% to 3% while increasing the number of chambers from 2 to 7. This work provides a novel technology to enable quasi-steady-state smouldering for industrial utilization.

堆放式烟熏在处理和利用生物质废物方面具有巨大潜力。然而,其非稳态特性限制了其工业利用以及烟气处理。本文针对这一问题,提出了通过多个烟熏室的顺序运行来实现稳态或准稳态堆垛烟熏的方法。文章从理论上分析了顺序非稳态曲线的叠加特性,并开发了一套代码,以确定在允许振荡百分比下的适当堆放室数量。在一个装有混合了木粉的堆积木粒的小型燃烧室(长 × 宽 × 高:340 × 140 × 140 立方毫米)上进行了烟熏实验。根据实验的质量损失数据,利用代码演示了连续燃烧速率曲线的叠加。分析表明,在该拟议系统中,燃烧速率曲线的叠加值是一个常数,因此完全稳态是可能的。实验表明,在密集堆放的烟熏过程中,烟雾中 CO/CO2 的摩尔比几乎恒定在 0.5 左右,显示出烟雾自持燃烧的巨大潜力。在实验结果的基础上,计算结果表明,当燃烧室数量从 2 个增加到 7 个时,燃烧速率(OSC)的相对振荡范围从 75% 减小到 3%。这项工作为工业利用准稳态烟化提供了一种新技术。
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引用次数: 0
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Waste Management & Research
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