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Project management and circular economy in agribusiness: A systematic literature review. 农业综合企业中的项目管理与循环经济:系统文献综述。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2023-12-30 DOI: 10.1177/0734242X231219643
José Luis Dalto, Luciano Ferreira da Silva, Renato Penha, Flavio Santino Bizarrias

This article aims to identify how project management can enable the introduction of circular economy (CE) in agribusiness. The methodological strategy used was the systematic literature review. The research corpus consisted of 70 articles selected from the Web of Science and Scopus databases. For screening, the Rayyan platform was used, and the analysis process was carried out by categorization and grouping of terms and concepts with the help of Excel software. The evidence shown the efforts to reduce agro-waste and how to transform them into by-products. Barriers, challenges, benefits and opportunities for making the CE viable in agribusiness are presented. Three ways of projecting the CE in agribusiness are identified: (1) project management processes in the integration of the CE in agribusiness, (2) innovative projects and new business models as drivers of the CE in agribusiness and (3) 4.0 technologies integrating the CE in agribusiness based on project management methodologies. Results are limited to terms used in search mechanisms. This research contributes towards identifying project management processes that can enable the CE in agribusiness, particularly by identifying the impacts of the CE in different business areas. The research also contributes in a practical way by providing insights on ways to make the CE viable in agribusiness through project management.

本文旨在确定项目管理如何能够在农业综合企业中引入循环经济(CE)。采用的方法策略是系统性文献综述。研究语料库包括从 Web of Science 和 Scopus 数据库中选取的 70 篇文章。在筛选过程中,使用了 Rayyan 平台,并借助 Excel 软件对术语和概念进行了分类和分组。证据显示了减少农业废弃物的努力以及如何将其转化为副产品。介绍了使农业综合企业中的消费电子可行的障碍、挑战、益处和机遇。确定了在农业综合企业中实施行政首长协调会的三种方法:(1) 在农业综合企业中整合消费电子的项目管理流程,(2) 作为农业综合企业中消费电子驱动力的创新项目和新商业模式,以及 (3) 基于项目管理方法在农业综合企业中整合消费电子的 4.0 技术。研究结果仅限于搜索机制中使用的术语。本研究有助于确定可促进农业企业行政首长协调会的项目管理流程,特别是通过确定行政首长协调会对不同业务领域的影响。本研究还提供了关于如何通过项目管理使行政首长协调会在农业综合企业中切实可行的见解,从而在实践中做出了贡献。
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引用次数: 0
Sustainable approach towards alternatives for the use of iron ore tailings in the construction sector using Data Envelopment Analysis methodology. 采用数据包络分析方法,以可持续的方式研究建筑行业使用铁矿石尾矿的替代方法。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-02-06 DOI: 10.1177/0734242X231219632
Werlley Cristiano de Oliveira, Samantha Rodrigues de Araújo, Lásara Fabrícia Rodrigues, João Flávio de Freitas Almeida

Iron ore tailings (IOTs) need to be properly managed to mitigate the environmental, social, and economic impacts of mining activities. To cope with this issue, we use data envelopment analysis (DEA) to evaluate alternatives for using IOT in the construction sector. The classical and weight restriction output-oriented DEA models were used in this analysis. The results show that the ranking of alternatives depends on the aspect being evaluated. Concrete block is the most environmentally friendly alternative when analysing both models. For both social and economic aspects, ceramics produced better results in the classical model, whereas Portland cement showed better outcomes in the weight restriction model. In this sense, the results suggest great potential for the use of IOT in the construction sector, enabling the reduction of risks and social and environmental impacts of tailings dams.

铁矿石尾矿(IOT)需要妥善管理,以减轻采矿活动对环境、社会和经济的影响。为了解决这个问题,我们使用数据包络分析法(DEA)来评估建筑行业使用 IOT 的替代方案。分析中使用了经典的和以权重限制为导向的产出 DEA 模型。结果表明,替代品的排序取决于所评估的方面。在对两种模型进行分析时,混凝土砌块是最环保的替代品。在社会和经济方面,陶瓷在经典模型中的结果更好,而波特兰水泥在重量限制模型中的结果更好。从这个意义上说,这些结果表明,物联网在建筑领域的应用具有巨大潜力,可以降低尾矿坝的风险和对社会及环境的影响。
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引用次数: 0
From dumping to circular economy: There is no success like failure. 从倾销到循环经济:没有失败就没有成功。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-19 DOI: 10.1177/0734242X231221084
Håkan Rylander, Anders Lagerkvist

Waste management has been developing in response to needs. The need to get rid of unwanted materials has always been a motivation but using the resource value of waste has also been a driver from the stone age and forwards. In affluent times not so much. Sanitation became a motivation with the discovery of pathogenic microorganisms in the mid-19th century, and after World War 2 (WW2) a strong focus on environmental protection developed, and in recent times, the resource aspect has received an interest despite material affluence. Legislation has been one of the drivers for recent developments, in the case of Sweden, the environmental protection legislation came in the late 1960s, and a few years later, the municipalities got the exclusive right to collect and manage household waste. Many local and regional waste management companies were established, owned by the municipalities. These organizations became agents of development, due to the increased scope and capacity. Adding to the environmental protection agenda, a renewed interest in waste as a resource was initiated by the oil crises of the 1970s, resulting in new waste incineration plants, with energy recovery, connected to already existing district heating networks. Mistakes, failures and alarms in the 1970s and the 1980s resulted in treatment method improvements and the establishment of source separation as an integral part of waste management. The waste management community stands strong today and is taking a more proactive role than before, which includes a stronger focus on communication with other stakeholders.

废物管理是根据需求而发展起来的。处理无用材料的需求一直是一个动力,但从石器时代开始,利用废物的资源价值也一直是一个驱动力。在富裕的时代,则不是这样。19 世纪中叶,随着病原微生物的发现,卫生成为了一种动力,第二次世界大战(WW2)后,人们开始强烈关注环境保护。立法是近期发展的推动力之一,就瑞典而言,环境保护立法于 20 世纪 60 年代末出台,几年后,市政当局获得了收集和管理生活垃圾的专属权利。许多由市政当局拥有的地方和地区废物管理公司应运而生。由于范围和能力的扩大,这些组织成为了发展的推动者。20 世纪 70 年代的石油危机使人们对垃圾这一资源重新产生了兴趣,并将其与现有的区域供热网络连接起来,新建了带有能源回收功能的垃圾焚烧厂。20 世纪 70 年代和 80 年代的失误、失败和警报导致了处理方法的改进,并将源头分类确立为废物管理不可分割的一部分。如今,废物管理界的力量十分强大,而且比以前更加积极主动,其中包括更加注重与其他利益相关者的沟通。
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引用次数: 0
Degradation processes of brominated flame retardants dispersed in high impact polystyrene under UV-visible radiation. 分散在高抗冲聚苯乙烯中的溴化阻燃剂在紫外可见光辐射下的降解过程。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2023-12-30 DOI: 10.1177/0734242X231219626
Hanene Oumeddour, Hussam Aldoori, Zohra Bouberka, Venkateswara Rao Mundlapati, Vikas Madhur, Corinne Foissac, Philippe Supiot, Yvain Carpentier, Michael Ziskind, Cristian Focsa, Ulrich Maschke

In order to protect human health and the environment, several regulations have been introduced in recent years to reduce or even eliminate the use of some brominated flame retardants (BFRs) due to their toxicity, persistence and bioaccumulation. Dispersions of these BFRs in polymers are widely used for various applications. In this report, four different brominated molecules, decabromodiphenyl ether (DBDE), hexabromocyclododecane (HBCDD), decabromodiphenyl ethane (DBDPE) and tris(tribromophenoxy)triazine (TTBPT), were dispersed in the solid matrix of an industrial polymer, high impact polystyrene (HIPS). The possibility of degradation of these BFRs within HIPS under UV-visible irradiation in ambient air was investigated. The degradation kinetics of DBDE and HBCDD were followed by Fourier transform infrared spectroscopy (FTIR) and high-resolution two-step laser mass spectrometry (L2MS). The thermal properties of the pristine and irradiated polymer matrix were monitored by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), which showed that these properties were globally preserved. Volatile photoproducts from the degradation of DBDE, DBDPE and TTBPT were identified by headspace gas chromatography/mass spectrometry analysis. Under the chosen experimental conditions, BFRs underwent rapid degradation after a few seconds of irradiation, with conversions exceeding 50% for HIPS/DBDE and HIPS/HBCDD systems.

由于某些溴化阻燃剂(BFRs)具有毒性、持久性和生物蓄积性,为了保护人类健康和环境,近年来已出台了多项法规来减少甚至消除它们的使用。这些溴化阻燃剂在聚合物中的分散体被广泛用于各种用途。在本报告中,四种不同的溴化分子--十溴二苯醚(DBDE)、六溴环十二烷(HBCDD)、十溴二苯乙烷(DBDPE)和三(三溴苯氧基)三嗪(TTBPT)被分散在工业聚合物--高抗冲聚苯乙烯(HIPS)的固体基质中。研究了这些溴化阻燃剂在环境空气中紫外可见光照射下在 HIPS 内降解的可能性。傅立叶变换红外光谱(FTIR)和高分辨率两步激光质谱(L2MS)跟踪了二溴二苯醚和六溴环十二烷的降解动力学。热重分析(TGA)和差示扫描量热法(DSC)监测了原始聚合物基体和辐照聚合物基体的热特性,结果表明这些特性在总体上得到了保留。顶空气相色谱/质谱分析鉴定了 DBDE、DBDPE 和 TTBPT 降解产生的挥发性光产物。在选定的实验条件下,溴化阻燃剂在辐照几秒钟后就会发生快速降解,HIPS/DBDE 和 HIPS/HBCDD 系统的转化率超过了 50%。
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引用次数: 0
Four-decades evolutionary development of municipal solid waste management in China: Implications for sustainable waste management and circular economy. 中国城市固体废物管理四十年的演变发展:对可持续废物管理和循环经济的影响。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-17 DOI: 10.1177/0734242X231221083
Tianxu Yu, Chenglin Liao, Nemanja Stanisavljevic, Lei Li, Xuya Peng, Xiaofeng Gao, Dongbei Yue, Xiaoming Wang

This study collected data on waste generation and management in China between 1979 and 2020 from government statistics and literature and reviewed the development of municipal solid waste (MSW) management in China. The extended stochastic impact by regression on population, affluence and technology (STIRPAT) model was employed to identify the driving forces of MSW generation, and the cointegration analysis showed that economy (0.35, t = -3.47), industrial structure (3.34, t = -20.77) and urbanization (-1.5, t = 5.678) were the significant socioeconomic driving forces in the long run. By employing the framework of evolutionary economics, this study then investigated the internal rules of long-term interaction between socioeconomic factors and MSW management. The results indicate that, in the long run, MSW management development can be viewed as an evolutionary process that includes a continuous adaptation to external socioeconomic factors and the co-evolution of internal institutions and technologies. Adaptation and diversity of institutions and technologies play an important role in achieving sustainable waste management and circular economy (CE). This study offers a novel evolutionary perspective for explaining dynamic changes of MSW management in China, as well as recommendations for emerging economies to achieve sustainable waste management and CE goals.

本研究从政府统计数据和文献中收集了 1979 年至 2020 年中国垃圾产生和管理的数据,并回顾了中国城市固体废物(MSW)管理的发展历程。采用人口、富裕程度和技术回归的扩展随机影响(STIRPAT)模型来识别城市固体废物产生的驱动力,协整分析表明,经济(0.35,t = -3.47)、产业结构(3.34,t = -20.77)和城市化(-1.5,t = 5.678)是长期内显著的社会经济驱动力。通过运用演化经济学框架,本研究探究了社会经济因素与城市生活垃圾管理之间长期互动的内在规律。研究结果表明,从长期来看,城市污水处理管理的发展可以被视为一个进化过程,包括对外部社会经济因素的不断适应以及内部制度和技术的共同进化。机构和技术的适应性和多样性在实现可持续废物管理和循环经济(CE)方面发挥着重要作用。本研究提供了一个新颖的演化视角来解释中国城市固体废物管理的动态变化,并为新兴经济体实现可持续废物管理和循环经济目标提供建议。
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引用次数: 0
How to influence food waste behaviour of urban residents? The combined effect of network embeddedness and incentive measures. 如何影响城市居民的食物浪费行为?网络嵌入性和激励措施的综合效应。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-09 DOI: 10.1177/0734242X231221082
Xiu Cheng, Jie Zhang, Linling Zhang

Residents' food waste is a key part of environmental sustainability and food security. This study investigates influencing factors in reducing food waste by constructing a conceptual model examining the relationship between network embeddedness (NE) and food waste behaviour (FWB), using questionnaire data from 853 urban residents in eastern China, as well as the moderating role of incentive measures (IMs). We find that NE consists of three dimensions: structural embeddedness, relational embeddedness and functional embeddedness. There is an inverted-U-shaped relationship between structural embeddedness and food waste reduction behaviour, whereas relational embeddedness and functional embeddedness positively correlate with food waste reduction behaviour. Furthermore, IMs significantly strengthen the inverted-U-shaped relationship between NE and food waste reduction behaviour. This article reveals the significance of NE and IMs in influencing FWB, expands the application fields of NE and provides valuable guidance for policymakers to better utilize policy interventions.

居民的食物浪费是环境可持续性和食品安全的关键部分。本研究利用中国东部 853 位城市居民的问卷调查数据,构建了一个概念模型,考察了网络嵌入性(NE)与食物浪费行为(FWB)之间的关系,以及激励措施(IMs)的调节作用,从而研究了减少食物浪费的影响因素。我们发现,网络嵌入性包括三个维度:结构嵌入性、关系嵌入性和功能嵌入性。结构嵌入度与减少食物浪费行为呈倒 "U "型关系,而关系嵌入度和功能嵌入度与减少食物浪费行为呈正相关。此外,IM 显著加强了 NE 与减少食物浪费行为之间的倒 U 型关系。本文揭示了NE和IM对食物浪费的重要影响,拓展了NE的应用领域,为政策制定者更好地利用政策干预措施提供了有价值的指导。
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引用次数: 0
Characterization of excavated plastic waste from an Indian dumpsite: Investigating extent of degradation and resource recovery potential. 印度垃圾场挖掘出的塑料废物的特征:调查降解程度和资源回收潜力。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-17 DOI: 10.1177/0734242X231219654
Roshan Vilasrao Mankhair, Ayush Singh, Munish K Chandel

In recent years, the concept of landfill mining has gained a lot of traction in India, and tonnes of plastic waste is being excavated. The present shift towards a circular economy necessitates to explore the use of excavated plastic waste as a source of valuable materials and energy. However, the physicochemical characteristics of plastic waste change due to the degradation and weathering process in landfills, making its valorization difficult. The current study investigates the change in physicochemical characteristics of plastic waste with age from an Indian dumpsite to identify the potential valorization options. In addition, a material and energy flow analysis was performed considering incineration treatment of plastic waste. The plastic waste ranged between 3.6 and 21% in the dumpsite and has almost doubled in recent decades, owing to the increase in plastic waste generation in India. Polyethylene (high- and low-density) accounted for approximately 66% of the excavated plastic waste and had a lot of adhered surface impurities. Mechanical pre-treatment using a shredder was effective in the removal of the adhered impurities with a recovery rate of 50-70% for polyethylene and a higher recovery of 70-90% for other types of plastic. Changes in the surface morphology of plastic waste with aging were observed through Scanning Electron Microscopy. The Fourier Transform Infrared Spectroscopy results confirmed low degradation levels for aged plastic waste, which is also confirmed through the high level of oxygen detected. The material and energy flow analysis revealed that incinerating one tonne of excavated plastic waste could produce approximately 1410 kWh of electricity.

近年来,垃圾填埋场采矿的概念在印度得到了广泛的推广,成吨的塑料垃圾被挖掘出来。在向循环经济转变的今天,有必要探索如何利用挖掘出的塑料垃圾作为有价值的材料和能源来源。然而,由于塑料垃圾在垃圾填埋场中的降解和风化过程,其物理化学特性会发生变化,因此很难实现其价值化。本研究调查了印度垃圾场中塑料垃圾的物理化学特性随时间的变化,以确定潜在的价值化方案。此外,考虑到塑料垃圾的焚烧处理,还进行了物质流和能量流分析。垃圾场中的塑料垃圾比例在 3.6% 到 21% 之间,由于印度塑料垃圾产生量的增加,近几十年来塑料垃圾的比例几乎翻了一番。聚乙烯(高密度和低密度)约占挖掘出的塑料垃圾的 66%,表面附着大量杂质。使用粉碎机进行机械预处理可有效去除附着的杂质,聚乙烯的回收率为 50-70%,其他类型塑料的回收率更高,为 70-90%。通过扫描电子显微镜观察到了塑料废物表面形态随着老化而发生的变化。傅立叶变换红外光谱分析结果证实,老化塑料垃圾的降解水平较低,这一点也通过检测到的高浓度氧气得到了证实。材料和能量流分析表明,焚烧一吨挖掘出的塑料废物可产生约 1410 千瓦时的电力。
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引用次数: 0
Promoting circular economy: The transformative impact of deposit refund systems. 促进循环经济:押金退还制度的变革性影响。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-10-24 DOI: 10.1177/0734242X241296617
Antonis A Zorpas
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引用次数: 0
Selection of a sustainable location for waste electrical and electronic equipment recycling plant using Entropy and Evaluation based on Distance from Average Solution. 利用熵和基于平均解距离的评估,为废弃电气和电子设备回收厂选择可持续的地点。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-31 DOI: 10.1177/0734242X231223903
Ayça Maden

The production and consumption of electronic goods have experienced a significant increase over the years, leading to a substantial surge in the global volume of electronic waste, commonly referred to as Waste Electrical and Electronic Equipment (WEEE). The selection of a sustainable location for WEEE recycling plants plays a crucial role in mitigating environmental concerns, preserving resources and promoting economic development. It signifies a proactive and responsible approach to electronic waste management in the contemporary world. To tackle the challenge of selecting sustainable locations for WEEE recycling plants, this study employed the Entropy and Entropy and Evaluation based on Distance from Average Solution (EDAS) methodologies, evaluating 10 alternative cities in Turkey based on 13 criteria. The selected criteria include land cost, personnel cost, energy cost, availability of labour, government support degree, tax preferences, road network accessibility, number of electronic equipment producers, existence of recycling plants, suitability of land use, population and availability of renewable resources (wind power and solar energy). The Entropy method was employed to calculate the weights assigned to each criterion, whereas the EDAS method was utilized to evaluate the decision alternatives. The results provide region-specific recommendations, such as Antalya for the Mediterranean region and Samsun for the Black Sea region. The literature lacks sufficient research on the selection of sustainable locations for WEEE recycling plants. Furthermore, the utilization of real data enhances the study's credibility and provides practical insights for decision-making. The selection of a sustainable location for a WEEE recycling plant in Turkey not only demonstrates the country's environmental commitment but also sets a global example for responsible waste management.

多年来,电子产品的生产和消费大幅增长,导致全球电子废物(通常称为废弃电气和电子设备(WEEE))数量激增。选择一个可持续发展的地点建立废弃电气和电子设备回收厂,对减轻环境问题、保护资源和促进经济发展起着至关重要的作用。它标志着当今世界在电子废物管理方面采取了积极主动和负责任的方法。为了应对为废弃电子电气设备回收厂选择可持续地点这一挑战,本研究采用了熵和熵以及基于平均解距离的评估(EDAS)方法,根据 13 项标准对土耳其的 10 个备选城市进行了评估。所选标准包括土地成本、人员成本、能源成本、劳动力可用性、政府支持程度、税收优惠、道路网络可达性、电子设备生产商数量、回收工厂的存在、土地使用的适宜性、人口和可再生资源(风能和太阳能)的可用性。采用熵值法计算每项标准的权重,同时采用 EDAS 法评估备选决策方案。结果提出了针对具体地区的建议,如地中海地区的安塔利亚和黑海地区的萨姆松。文献缺乏对废弃电子电气设备回收厂可持续选址的充分研究。此外,真实数据的使用提高了研究的可信度,并为决策提供了实用的见解。在土耳其选择一个可持续发展的地点建立废弃电子电器设备回收厂,不仅表明了该国对环境的承诺,也为负责任的废物管理树立了全球榜样。
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引用次数: 0
Mechanical strength changes of combustible municipal solid waste components during their early pyrolysis stage and mechanism analysis. 可燃城市固体废物成分在早期热解阶段的机械强度变化及机理分析。
IF 3.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-12-01 Epub Date: 2024-01-31 DOI: 10.1177/0734242X231219629
Yifan Jia, Dezhen Chen, Sijia Xu, Yuyan Hu, Guoan Yuan, Ruina Zhang, Weiwei Yu

Implementation of municipal solid waste (MSW) source segregation leads to a more convenient recycle of combustible MSW components. Textiles, plastics and papers are commonly available combustible components in MSW. Their shredding is conducive to resources recovery. But these components usually have high tensile strengths and are difficult to shred. To understand their mechanical strength changes in their early pyrolysis stage will help to address this problem. In this study, a universal electronic testing machine was used to determine the breaking strengths of the materials including cotton towel, polyethylene glycol terephthalate (PET), ivory board (IB), kraft paper (KP) and wool scarf in the temperature range of 30-250°C under N2 atmosphere, and the mechanisms of their strength changes were explored. The reaction force field molecular dynamics (ReaxFF-MD) simulation was used to explain the decomposition behaviours of different sugar groups of hemicellulose in cotton and paper and the change of van der Waals energy of wool during their early pyrolysis stages. The results showed that breaking strengths of all the combustible MSW components reduced as the temperature increased. The breaking strength of PET was found to have the highest descent rate with increasing temperature, then the descent rates of wool and cotton came as the second and third, respectively. Compared with cotton, the breaking strengths of KP and IB decreased more slowly. As the temperature increased, the breaking strength of cotton reduced mainly due to the decomposition of the glucuronic acid in hemicellulose, and the reduction was characterized by CO2 release. The breaking strength reduction of PET was caused by its molecular chain being relaxed. The breaking strength reduction of wool was firstly caused by the decrease in the van der Waals energy between its molecules, and then caused by molecular chain breaking. In addition, in order to understand the influence of material size on the breaking strength change during thermal treatment, the breaking strengths of cotton yarn bundles were correlated with their yarn number and temperature. This study lays the foundation for understanding changes in mechanical strengths of combustible MSW components during their early pyrolysis stage.

实施城市固体废物(MSW)源头分类可使可燃城市固体废物成分的回收利用更加方便。纺织品、塑料和纸张是城市固体废物中常见的可燃成分。将它们粉碎有利于资源回收。但这些成分通常具有较高的拉伸强度,很难粉碎。了解它们在早期热解阶段的机械强度变化将有助于解决这一问题。本研究采用万能电子试验机测定了棉毛巾、聚对苯二甲酸乙二酯(PET)、象牙板(IB)、牛皮纸(KP)和羊毛围巾等材料在 30-250°C 的温度范围内、N2 大气下的断裂强度,并探讨了其强度变化的机理。利用反应力场分子动力学(ReaxFF-MD)模拟解释了棉花和纸中半纤维素不同糖基的分解行为以及羊毛在热解早期的范德华能变化。结果表明,随着温度的升高,所有可燃都市固体废物成分的断裂强度都会降低。随着温度的升高,聚对苯二甲酸乙二酯的断裂强度下降率最高,羊毛和棉花的断裂强度下降率分别排在第二和第三位。与棉花相比,KP 和 IB 的断裂强度下降速度较慢。随着温度的升高,棉的断裂强度降低主要是由于半纤维素中的葡萄糖醛酸分解所致,其降低的特征是二氧化碳的释放。PET 的断裂强度降低是由于其分子链松弛所致。羊毛的断裂强度降低首先是由于其分子间的范德华能降低,然后是由于分子链断裂。此外,为了了解材料尺寸对热处理过程中断裂强度变化的影响,棉纱束的断裂强度与纱线支数和温度相关。这项研究为了解可燃都市固体废物成分在早期热解阶段的机械强度变化奠定了基础。
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引用次数: 0
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