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Numerical Analysis of Flow Characteristics and Energy Dissipation on Flat and Pooled Stepped Spillways 平面和汇集式阶梯水道水流特性和能量消耗的数值分析
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.3390/w16182600
Umar Farooq, Shicheng Li, James Yang
The hydraulic performance of pooled stepped spillways has received less recognition compared to the traditional stepped spillways. Regarding the effectiveness of pooled stepped spillways in managing flow dynamics, previous studies have focused on investigating how different step configurations and varying chute angles can enhance energy dissipation in gravity flow over the chute. However, the potential for optimal performance and the importance of proper design have not been thoroughly explored in the existing literature. This study aims to explore new configurations of pooled stepped spillways and compare them to traditional stepped spillway designs to enhance hydraulic efficiency and maximize energy dissipation. The study examines two types of configurations of stepped spillways—two flat and two pooled configurations, each with ten steps. Using the computational Fluid Dynamics (CFD) technique, such as Volume of Fluid Method (VOF) and the realizable k-ε turbulence model for two-phase flow analysis with a 26.6° chute slope. Initially, the model was validated with experimental data by comparing various hydraulic parameters. These parameters include water depth, roller length, jump length, ratio of critical depth, and sequent depth. The hydraulic performance of both stepped geometric configurations was evaluated through numerical simulations to examine how the geometries of flat and pooled stepped spillways influence flow characteristics, energy dissipation, velocity, pressure distribution, and the Froude number at the downstream. The study analyzed downstream flow characteristics, maximum energy dissipation rates, depth-averaged velocity, static pressure, and pressure contours at the lateral direction under six different flow rates in flat and pooled stepped spillways. The findings indicate that flat-step configurations exhibit lower energy dissipation compared to pooled configurations. The relative energy loss of flow on pooled steps dissipates more energy than on flat steps. Furthermore, it is observed that the pooled configurations performed better for energy dissipation and flow stability compared to the flat configurations. The energy dissipation increased in pooled stepped spillways by 34.68% and 25.81%, respectively. Additionally, the depth-averaged flow velocity and pressure distribution decreased in case 2 and case 4 compared to the flat-step configurations.
与传统的阶梯式溢洪道相比,汇集式阶梯溢洪道的水力性能得到的认可较少。关于汇集式阶梯溢洪道在管理水流动态方面的有效性,以往的研究主要集中在研究不同的阶梯配置和不同的溜槽角度如何增强溜槽上重力流的能量消耗。然而,现有文献并未深入探讨优化性能的潜力和合理设计的重要性。本研究旨在探索汇集式阶梯溢洪道的新配置,并将其与传统的阶梯溢洪道设计进行比较,以提高水力效率并最大限度地消散能量。本研究考察了两种类型的阶梯式溢洪道配置--两种平式配置和两种汇集式配置,每种配置有十个阶梯。使用计算流体动力学(CFD)技术,如流体体积法(VOF)和可实现的 k-ε 湍流模型,对滑道坡度为 26.6°的两相流进行分析。最初,该模型通过比较各种水力参数与实验数据进行了验证。这些参数包括水深、滚筒长度、跳跃长度、临界深度比和顺序深度。通过数值模拟对两种阶梯式几何结构的水力性能进行了评估,以研究平面阶梯式溢洪道和汇集阶梯式溢洪道的几何结构如何影响下游的水流特性、能量耗散、流速、压力分布和弗劳德数。研究分析了平阶梯和汇集阶梯式溢洪道在六种不同流速条件下的下游流动特性、最大能量耗散率、深度平均流速、静压和横向压力等值线。研究结果表明,与汇集式结构相比,平阶梯结构的能量耗散较低。与平阶梯相比,汇集阶梯上水流的相对能量损失更多。此外,与平面结构相比,水池结构在能量耗散和流动稳定性方面表现更好。汇集式阶梯溢洪道的消能分别增加了 34.68% 和 25.81%。此外,与平面阶梯结构相比,情况 2 和情况 4 的深度平均流速和压力分布都有所下降。
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引用次数: 0
Effects of Ditch Water and Yellow River Irrigation on Saline–Alkali Characteristics of Soil and Paddy 沟渠水和黄河水灌溉对土壤和水稻盐碱特性的影响
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.3390/w16182598
Liqin Fan, Jingli Shen, Xu Wang, Yonghong Zhang
This study examined the agricultural water resource shortage and abundant ditch water resources in the Yinbei region of Ningxia. The effects of ditch water and Yellow River irrigation on the saline–alkali characteristics of soil and paddy were investigated using field monitoring and indoor detection methods in Pingluo County, Ningxia (106°31′ E, 38°51′ N). In addition to monitoring ditch water, four treatment groups were established: direct ditch water irrigation (T1), mixed ditch water and Yellow River water irrigation (T2), alternate ditch water and Yellow River water irrigation (T3), and irrigation solely with Yellow River water (CK). The results show the following: (1) The salinity of ditch water samples collected from the experimental field during the rice growth period was less than 1.60 g/L, and the pH of the samples was lower than 8.62; thus, they were classified as mildly brackish water. The application of ditch water irrigation did not result in soil saline–alkali aggravation and the accumulation of excessive amounts of heavy metals in soils and paddies in Pingluo County, Ningxia. (2) The rice yields for the CK, T1, T2, and T3 treatments were 10,437.5, 8318.4, 9182.1, and 9016.2 kg/hm2, respectively. Compared with Yellow River irrigation, the rice yields for the T1, T2, and T3 treatments were 20.3, 12.1, and 13.6% lower than that of CK, respectively, with minimal differences observed among them. Hence, under the condition of a water resource shortage in the Yellow River region, ditch water can be appropriately applied for mixed or alternate irrigation to ensure food security. This research has revealed the influences of ditch water irrigation on the saline–alkali properties of soil and the heavy metal contents of paddies.
本研究考察了宁夏银北地区农业水资源短缺和丰富的沟渠水资源。在宁夏平罗县(东经 106°31′,北纬 38°51′)采用田间监测和室内检测的方法,研究了沟渠水和黄河水灌溉对土壤和水稻盐碱特性的影响。除监测沟水外,还设立了四个处理组:沟水直接灌溉组(T1)、沟水与黄河水混合灌溉组(T2)、沟水与黄河水交替灌溉组(T3)和单纯黄河水灌溉组(CK)。结果如下(1) 在水稻生长期间从试验田采集的沟渠水样的盐度小于 1.60 g/L,pH 值小于 8.62,因此属于轻度咸水。在宁夏平罗县,沟水灌溉并未导致土壤盐碱化和土壤及稻田重金属超标。(2) CK、T1、T2 和 T3 处理的水稻产量分别为 10437.5、8318.4、9182.1 和 9016.2 kg/hm2。与黄河灌溉相比,T1、T2 和 T3 处理的水稻产量分别比长江灌溉低 20.3%、12.1% 和 13.6%,它们之间的差异极小。因此,在黄河流域水资源短缺的条件下,可以适当应用沟渠水进行混合灌溉或交替灌溉,以确保粮食安全。本研究揭示了渠水灌溉对稻田土壤盐碱性状和重金属含量的影响。
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引用次数: 0
Comprehensive Assessment of Climate Change Impacts on River Water Availability for Irrigation, Wheat Crop Area Coverage, and Irrigation Canal Hydraulic Capacity of Large-Scale Irrigation Scheme in Nepal 气候变化对尼泊尔大型灌溉计划的灌溉河水可用性、小麦作物覆盖面积和灌渠水力的综合影响评估
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.3390/w16182595
Santosh Kaini, Matthew Tom Harrison, Ted Gardner, Ashok K. Sharma
While atmospheric warming intensifies the global water cycle, regionalised effects of climate change on water loss, irrigation supply, and food security are highly variable. Here, we elucidate the impacts of the climate crisis on irrigation water availability and cropping area in Nepal’s largest irrigation scheme, the Sunsari Morang Irrigation Scheme (SMIS), by accounting for the hydraulic capacity of existing canal systems, and potential changes realised under future climates. To capture variability implicit in climate change projections, we invoke multiple Representative Concentration Pathways (RCPs; 4.5 and 8.5) across three time horizons (2016–2045, 2036–2065, and 2071–2100). We reveal that although climate change increases water availability to agriculture from December through March, the designed discharge of 60 m3/s would not be available in February-March for both RCPs under all three time horizons. Weed growth, silt deposition, and poor maintenance have reduced the current canal capacity from the design capacity of 60 m3/s to 53 m3/s up to 10.7 km from the canal intake (representing a 12% reduction in the discharge capacity of the canal). Canal flow is further reduced to 35 m3/s at 13.8 km from canal intake, representing a 27% reduction in flow capacity relative to the original design standards. Based on climate projections, and assuming ceteris paribus irrigation infrastructure, total wheat cropping area could increase by 12–19%, 23–27%, and 12–35% by 2016–2045, 2036–2065, and 2071–2100, respectively, due to increased water availability borne by the changing climate. The case for further investment in irrigation infrastructure via water diversion, or installation of efficient pumps at irrigation canal intakes is compelling. Such investment would catalyse a step-change in the agricultural economy that is urgently needed to sustain the Nepalese economy, and thus evoke beneficial cascading implications for global food security.
虽然大气变暖加剧了全球水循环,但气候变化对水资源损失、灌溉供应和粮食安全的区域化影响却千差万别。在此,我们通过考虑现有渠系的水利能力以及未来气候条件下可能发生的变化,阐明了气候危机对尼泊尔最大的灌溉计划--孙萨里-莫朗灌溉计划(Sunsari Morang Irrigation Scheme,SMIS)--的灌溉供水和种植面积的影响。为了捕捉气候变化预测中隐含的可变性,我们在三个时间跨度(2016-2045 年、2036-2065 年和 2071-2100 年)内引用了多种代表性浓度路径(RCPs;4.5 和 8.5)。我们发现,虽然气候变化增加了 12 月至 3 月的农业用水量,但在所有三个时间跨度下,两种 RCPs 在 2-3 月都无法达到 60 立方米/秒的设计排水量。杂草丛生、淤泥沉积和维护不善使运河目前的排水能力从设计的 60 立方米/秒下降到 53 立方米/秒,距离运河取水口长达 10.7 公里(相当于运河排水能力下降了 12%)。在距运河取水口 13.8 公里处,运河流量进一步降至 35 立方米/秒,与最初的设计标准相比,流量减少了 27%。根据气候预测,假设灌溉基础设施相同,到 2016-2045 年、2036-2065 年和 2071-2100 年,小麦总种植面积将分别增加 12%-19%、23%-27%和 12%-35%,原因是气候变化导致供水量增加。通过引水或在灌渠取水口安装高效水泵进一步投资灌溉基础设施的理由十分充分。这种投资将促进农业经济的逐步变革,而这正是维持尼泊尔经济的迫切需要,从而对全球粮食安全产生有益的连带影响。
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引用次数: 0
Climate Change Contributions to Water Conservation Capacity in the Upper Mekong River Basin 气候变化对湄公河上游流域水资源保护能力的影响
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.3390/w16182601
Yuanyuan Luo, Zhaodan Cao, Xiaoer Zhao, Chengqiu Wu
Investigations into the impacts of climate change on water conservation capacity in the upper Mekong River Basin (UMRB) are important for the region’s sustainability. However, quantitative studies on isolating the individual contribution of climate change to water conservation capacity are lacking. In this study, various data-driven SWAT models were developed to quantitatively analyze the unique impact of climate change on water conservation capacity in the UMRB. The results reveal the following: (1) From 1981 to 2020, the annual water conservation capacity ranged from 191.6 to 392.9 mm, showing significant seasonal differences with the values in the rainy season (218.6–420.3 mm) significantly higher than that in the dry season (−57.0–53.2 mm). (2) The contribution of climate change to water conservation capacity is generally negative, with the highest contribution (−65.2%) in the dry season, followed by the annual (−8.7%) and the rainy season (−8.1%). (3) Precipitation, followed by evaporation and surface runoff, emerged as the critical factor affecting water conservation capacity changes in the UMRB. This study can provide insights for water resources management and climate change adaptations in the UMRB and other similar regions in the world.
调查气候变化对湄公河上游流域(UMRB)水资源保护能力的影响对该地区的可持续发展非常重要。然而,目前还缺乏关于气候变化对水资源保护能力的单独影响的定量研究。本研究开发了多种数据驱动的 SWAT 模型,以定量分析气候变化对湄公河流域水资源保护能力的独特影响。结果如下(1)从 1981 年到 2020 年,年节水能力在 191.6 到 392.9 毫米之间,呈现明显的季节性差异,雨季节水能力(218.6-420.3 毫米)明显高于旱季节水能力(-57.0-53.2 毫米)。(2) 气候变化对节水能力的影响一般为负,旱季影响最大(-65.2%),其次是全年 (-8.7%)和雨季(-8.1%)。(3) 降水是影响乌马河流域节水能力变化的关键因素,其次是蒸发和地表径流。本研究可为乌姆兰盆地及世界其他类似地区的水资源管理和气候变化适应提供启示。
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引用次数: 0
Flood Modeling of the June 2023 Flooding of Léogâne City by the Overflow of the Rouyonne River in Haiti 2023 年 6 月海地鲁约讷河泛滥导致莱奥甘市洪水泛滥的洪水模拟
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.3390/w16182594
Rotchild Louis, Yves Zech, Adermus Joseph, Nyankona Gonomy, Sandra Soares-Frazao
Evaluating flood risk though numerical simulations in areas where hydrometric and bathymetric data are scarcely available is a challenge. This is, however, of paramount importance, particularly in urban areas, where huge losses of human life and extensive damage can occur. This paper focuses on the 2–3 June 2023 event at Léogâne in Haiti, where the Rouyonne River partly flooded the city. Water depths in the river have been recorded since April 2022, and a few discharges were measured manually, but these were not sufficient to produce a reliable rating curve. Using a uniform-flow assumption combined with the Bayesian rating curve (BaRatin) method, it was possible to extrapolate the existing data to higher discharges. From there, a rainfall–runoff relation was developed for the site using a distributed hydrological model, which allowed the discharge of the June 2023 event to be determined, which was estimated as twice the maximum conveying capacity of the river in the measurement section. Bathymetric data were obtained using drone-based photogrammetry, and two-dimensional simulations were carried out to represent the flooded area and the associated water depths. By comparing the water depths of 21 measured high-water marks with the simulation results, we obtained a Kling–Gupta Efficiency (KGE) and Nash–Sutcliffe Efficiency (NSE) values of 0.890 and 0.882, respectively. This allows us to conclude that even when only scarce official data are available, it is possible to use field data acquired by low-cost methodologies to build a model that is sufficiently accurate and that can be used by flood managers and decision makers to assess flood risk and vulnerability in Haiti.
在缺乏水文和测深数据的地区,通过数值模拟评估洪水风险是一项挑战。然而,这一点至关重要,尤其是在可能造成巨大人员伤亡和广泛破坏的城市地区。本文重点介绍 2023 年 6 月 2-3 日在海地莱奥甘发生的事件,当时鲁永河部分淹没了城市。自 2022 年 4 月以来,该河流的水深一直有记录,并且人工测量了一些排水量,但这些都不足以绘制出可靠的等级曲线。利用均匀流量假设结合贝叶斯等级曲线(BaRatin)方法,可以将现有数据推断为更高的排水量。在此基础上,利用分布式水文模型为该地点建立了降雨-径流关系,从而确定了 2023 年 6 月事件的排水量,估计为测量断面河流最大输送能力的两倍。利用无人机摄影测量获得了水深数据,并进行了二维模拟,以表示洪水淹没区域和相关水深。通过比较 21 个实测高水位线的水深和模拟结果,我们得出克林-古普塔效率(KGE)和纳什-苏特克里夫效率(NSE)值分别为 0.890 和 0.882。由此我们可以得出结论,即使只有稀缺的官方数据,也可以利用低成本方法获得的实地数据建立一个足够准确的模型,供洪水管理者和决策者用来评估海地的洪水风险和脆弱性。
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引用次数: 0
The Hydrologic Mitigation Effectiveness of Bioretention Basins in an Urban Area Prone to Flash Flooding 易受山洪暴发影响的城市地区生物蓄水池的水文缓解效果
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.3390/w16182597
Brian G. Laub, Eugene Von Bon, Lani May, Mel Garcia
The hydrologic performance and cost-effectiveness of green stormwater infrastructure (GSI) in climates with highly variable precipitation is an important subject in urban stormwater management. We measured the hydrologic effects of two bioretention basins in San Antonio, Texas, a growing city in a region prone to flash flooding. Pre-construction, inflow, and outflow hydrographs of the basins were compared to test whether the basins reduced peak flow magnitude and altered the metrics of flashiness, including rate of flow rise and fall. We determined the construction and annual maintenance cost of one basin and whether precipitation magnitude and antecedent moisture conditions altered hydrologic mitigation effectiveness. The basins reduced flashiness when comparing inflow to outflow and pre-construction to outflow hydrographs, including reducing peak flow magnitudes by >80% on average. Basin performance was not strongly affected by precipitation magnitude or antecedent conditions, though the range of precipitation magnitudes sampled was limited. Construction costs were higher than previously reported projects, but annual maintenance costs were similar and no higher than costs to maintain an equivalent landscaped area. Results indicate that bioretention basins effectively mitigate peak flow and flashiness, even in flash-flood-prone environments, which should benefit downstream ecosystems. The results provide a unique assessment of bioretention basin performance in flash-flood-prone environments and can inform the optimization of cost-effectiveness when implementing GSI at watershed scales in regions with current or future similar precipitation regimes.
在降水量变化很大的气候条件下,绿色雨水基础设施(GSI)的水文性能和成本效益是城市雨水管理的一个重要课题。我们测量了德克萨斯州圣安东尼奥市两个生物滞留池的水文效果,圣安东尼奥市是一个易受山洪暴发影响的成长型城市。我们比较了生物蓄水池施工前、流入和流出的水文图,以检验生物蓄水池是否降低了峰值流量,是否改变了山洪暴发的指标,包括流量上升和下降的速度。我们确定了一个流域的建设和年度维护成本,以及降水量和先期湿度条件是否会改变水文缓解效果。在比较流入与流出以及施工前与流出的水文图时,这些流域都降低了闪蒸度,包括平均降低了 80% 以上的峰值流量。虽然取样的降水量范围有限,但流域的性能并未受到降水量或先决条件的强烈影响。建造成本高于之前报告的项目,但每年的维护成本类似,不高于维护同等景观区域的成本。结果表明,生物滞留池即使在易发山洪的环境中也能有效缓解峰值流量和山洪暴发,这对下游生态系统应该是有益的。这些结果对生物蓄水池在易发山洪环境中的性能进行了独特的评估,并可为当前或未来降水量相似的地区在流域范围内实施 GSI 时优化成本效益提供参考。
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引用次数: 0
Assessing the Hydrologic Response of a Major Drinking Water Reservoir to Extreme Flood Events and Climate Change Using SWAT and OASIS 利用 SWAT 和 OASIS 评估一个主要饮用水水库对极端洪水事件和气候变化的水文响应
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-11 DOI: 10.3390/w16182572
Supria Paul, Soni M. Pradhanang, Thomas B. Boving
Extreme flood events present a significant challenge for operators and managers of large drinking water reservoirs. Detailed flood response analysis can predict the hydrology response of a reservoir to changing climate conditions and can aid in managing the reservoir in anticipation of extreme events. Herein, the Soil and Water Assessment Tool (SWAT), a watershed model, was used in conjunction with a reservoir management model, the Operational Analysis and Simulation of Integrated Systems (OASIS) model, to evaluate extreme flood events across a set of initial reservoir storage capacities across various CMIP6 climate scenarios. The SWAT model was calibrated and validated with PRISM climate data in conjunction with land and soil cover data and multi-site gauged stream discharges. The validated model demonstrated satisfactory performance (NSE = 0.55 and R2 = 0.56) for total reservoir inflow. The resulting inflow values from SWAT were utilized to set up a calibrated/validated OASIS model (NSE = 0.55 and R2 = 0.68). OASIS was then used to assess alternative operating rules for the reservoir under varying climate scenarios (RCP4.5 and RCP8.5) and extreme events (synthetic hurricanes). Focusing on a major reservoir in the Northeastern United States, the analysis of the reservoir response was based on (1) reservoir volume–elevation curve, (2) daily reservoir inflow, (3) daily precipitation, (4) spillway flow, and (5) reservoir evaporation. Projected future scenarios indicate a >20% increase in precipitation in April compared to historical records, coupled with likely reduced runoff from November to March. With extreme conditions most likely in the month of April, RCP4.5 and RCP8.5 projections suggest that most scenarios result in a 10–15% increase in the mean of 3D30Y runoff volumes, and a 150% increase under the most extreme conditions. For 7D30Y runoff volumes in April, the RCP4.5 and RCP8.5 analyses reveal an increased likelihood of the reservoir elevation reaching overspill flow levels during the latter half of the simulation period (2020 to 2080). Our findings indicate that simulations with SWAT coupled with OASIS can assist reservoir managers in regulating water levels in anticipation of extreme precipitation events.
极端洪水事件给大型饮用水水库的运营和管理者带来了巨大挑战。详细的洪水响应分析可以预测水库对不断变化的气候条件的水文响应,并有助于在预测极端事件时对水库进行管理。在本文中,水土评估工具(SWAT)这一流域模型与水库管理模型(综合系统运行分析与仿真模型(OASIS))结合使用,对各种 CMIP6 气候情景下一组初始水库库容的极端洪水事件进行了评估。SWAT 模型利用 PRISM 气候数据、土地和土壤覆盖数据以及多站点测量的溪流排水量进行了校准和验证。经过验证的模型在水库总流量方面表现令人满意(NSE = 0.55,R2 = 0.56)。利用 SWAT 得出的流入量值建立了校准/验证的 OASIS 模型(NSE = 0.55 和 R2 = 0.68)。然后,利用 OASIS 评估不同气候情景(RCP4.5 和 RCP8.5)和极端事件(合成飓风)下水库的替代运行规则。以美国东北部的一个主要水库为重点,对水库响应的分析基于 (1) 水库容积-高程曲线、(2) 每日水库流入量、(3) 每日降水量、(4) 溢洪道流量和 (5) 水库蒸发量。预测的未来情景表明,与历史记录相比,4 月份的降水量将增加 20%以上,同时 11 月至次年 3 月的径流量可能会减少。由于 4 月份最有可能出现极端情况,RCP4.5 和 RCP8.5 预测表明,大多数情况下,3D30Y 径流量的平均值会增加 10-15%,在最极端的情况下会增加 150%。对于 4 月份的 7D30Y 径流量,RCP4.5 和 RCP8.5 分析表明,在模拟期的后半段(2020 年至 2080 年),水库水位达到溢流水平的可能性增加。我们的研究结果表明,利用 SWAT 和 OASIS 进行模拟可以帮助水库管理者在预测极端降水事件时调节水位。
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引用次数: 0
Zinc Oxide/Moringa Oleifera Gum-Grafted L-Methionine-Functionalized Polyaniline Bionanocomposites for Water Purification 用于水净化的氧化锌/油橄榄树胶接枝 L-蛋氨酸功能化聚苯胺仿生复合材料
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-11 DOI: 10.3390/w16182576
Mohd Saquib Tanweer, Zafar Iqbal, Adil Majeed Rather, Masood Alam
This study evaluates the preparation of novel ternary functional adsorbents based on polyaniline, zinc oxide nanoparticles, and moringa oleifera gum to produce zinc oxide/Moringa oleifera gum-grafted L-methionine-functionalized polyaniline bionanocomposites (ZM-g-Pani) and employed to sequestrate divalent metal ions (Cd2+, Hg2+ and Pb2+) from wastewater samples. The morphological and structural properties of ZM-g-Pani were exploited using FT-IR, FE-SEM/EDS, TEM, and XRD. FT-IR and FE-SEM studies show that the as prepared nanocomposite has an abundant number of reactive groups and a porous structure, thus demonstrating outstanding divalent metal cation removal. FT-IR study confirms that the attachment of L-methionine to polyaniline is facilitated by the C-S linkage. Both TEM and FE-SEM techniques confirmed the clustered granules of ZnO over the surface of polyaniline, which ultimately provided more surface area to adsorb metal ions. The study demonstrated that Cd2+, Hg2+ and Pb2+ ions could undergo physical sorption and chemisorption simultaneously during the adsorption process. The maximum adsorption capacity was 840.33, 497.51, and 497.51 mg/g for Cd2+, Hg2+, and Pb2+, respectively. The impact of co-existing ions, including NO3–, PO43–, SO42–, Cl–, Na+, Cu2+, and Al3+, showed that there were no notable alterations in the adsorption of the selected metal ions with ZM-g-Pani. ZM-g-Pani showed eight successive regeneration cycles for Cd2+, Hg2+, and Pb2+ with more than 85% removal efficiency.
本研究评估了基于聚苯胺、纳米氧化锌颗粒和油杉树胶的新型三元功能吸附剂的制备情况,以制备氧化锌/油杉树胶接枝 L-蛋氨酸功能化聚苯胺仿生复合材料(ZM-g-Pani),并用于吸附废水样品中的二价金属离子(Cd2+、Hg2+ 和 Pb2+)。FT-IR 和 FE-SEM 研究表明,所制备的纳米复合材料具有大量的活性基团和多孔结构,因此对二价金属阳离子的去除效果显著。傅立叶变换红外光谱研究证实,L-蛋氨酸与聚苯胺的连接是通过 C-S 连接实现的。TEM 和 FE-SEM 技术都证实了聚苯胺表面的 ZnO 颗粒成簇,最终为吸附金属离子提供了更大的表面积。研究表明,在吸附过程中,Cd2+、Hg2+ 和 Pb2+ 离子可同时进行物理吸附和化学吸附。Cd2+、Hg2+ 和 Pb2+ 的最大吸附容量分别为 840.33、497.51 和 497.51 mg/g。共存离子(包括 NO3-、PO43-、SO42-、Cl-、Na+、Cu2+ 和 Al3+)的影响表明,ZM-g-Pani 对所选金属离子的吸附没有明显变化。ZM-g-Pani 对 Cd2+、Hg2+ 和 Pb2+ 连续进行了八次再生循环,去除率超过 85%。
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引用次数: 0
Common Carp (Cyprinus carpio) Reinvasion and Population Expansion in Lake Winona: A Modified Urban Floodplain Lake in Minnesota, USA 维诺纳湖中鲤鱼(Cyprinus carpio)的再入侵和种群扩张:美国明尼苏达州一个改良型城市洪泛区湖泊
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-11 DOI: 10.3390/w16182571
Neal D. Mundahl, Avery C. Schnaser, Christopher M. Kluzak, McKenzie L. Henkelman
Common or European carp (Cyprinus carpio) were eliminated from Lake Winona during a 1973 lake reclamation project. Multiple efforts to prevent their return and eliminate spawning opportunities have failed. Carp have remained in the lake for the past 50 years, but more recent observations of spawning activity in the lake suggest that their numbers have increased. We used shoreline electrofishing data from Lake Winona (2005–2021), along with carp abundance and effects models, to estimate the abundance of carp in Lake Winona, and to evaluate the need for future carp management within the lake. Carp size (mean TL = 614 mm, mean weight = 3.42 kg) did not differ between eastern and western basins, but densities were three times higher in the western basin (105 compared to 34 fish/hectare), and carp had significantly higher relative weights in the western (117%) versus the eastern (107%) basin. Carp biomass estimates for the eastern (116 kg/hectare) and western (360 kg/hectare) basins suggest that the lake may soon experience significant declines in macrophyte cover and other ecological damage associated with that loss. With an estimated adult carp population of >6900 fish and a carp biomass (23,750 kg) 1.5 times greater than the biomass of all carp killed during the 1973 reclamation, carp management activities (e.g., fish removal and spawning migration barriers) should be initiated soon to protect the Lake Winona game fish community.
在 1973 年的一次填湖工程中,鲤鱼(Cyprinus carpio)从维诺纳湖中消失。为防止鲤鱼返回并消除产卵机会而进行的多次努力均告失败。在过去的 50 年中,鲤鱼一直留在湖中,但最近对湖中产卵活动的观察表明,鲤鱼的数量有所增加。我们利用维诺纳湖(2005-2021 年)的沿岸电鱼数据以及鲤鱼丰度和效应模型,估算了维诺纳湖中鲤鱼的丰度,并评估了未来对湖中鲤鱼进行管理的必要性。东部流域和西部流域的鲤鱼体型(平均 TL = 614 毫米,平均重量 = 3.42 千克)没有差异,但西部流域的密度是东部流域的三倍(105 条/公顷,而东部流域为 34 条/公顷),而且西部流域的鲤鱼相对重量(117%)明显高于东部流域(107%)。东部流域(116 千克/公顷)和西部流域(360 千克/公顷)的鲤鱼生物量估计值表明,湖泊的大型植物覆盖率可能很快会大幅下降,并造成其他相关的生态破坏。据估计,鲤鱼成鱼数量超过 6900 尾,鲤鱼生物量(23,750 千克)是 1973 年填海期间被杀死的所有鲤鱼生物量的 1.5 倍,因此应尽快启动鲤鱼管理活动(如清除鱼类和产卵洄游障碍),以保护威诺纳湖的野生鱼类群落。
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引用次数: 0
Evolution and Quantitative Characterization of Stress and Displacement of Surrounding Rock Structure due to the Multiple Layers Backfill Mining under Loose Aquifers 松散含水层下多层回填采矿引起的围岩结构应力和位移的演变及定量表征
IF 3.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-11 DOI: 10.3390/w16182574
Jiawei Liu, Wanghua Sui
Backfill mining is an important means of ensuring the high efficiency and safety of the coal mining under thin bedrock and loose aquifers. Based on the case study of Taiping Coalmine, the theoretical analysis of entropy and numerical modeling methods are adopted to establish the visualization model of temporal–spatial cube of stress and displacement induced by the multiple layers backfill mining. Moreover, the quantitative characterization and measurement framework of symmetric KL-divergence is established based on information entropy and mutual information. The results show that: (1) The non-uniformity of stress and displacement is enhanced due to the multiple layers backfill mining, showing certain fluctuation characteristics. (2) The KL-divergence of stress to displacement is slightly greater than that of displacement to stress, and the hotspot distribution law of stress–displacement related efficiency is consistent with KL-divergence. (3) The hotspots of stress entropy and the gap between stress entropy and displacement entropy in multiple layers backfill mining decrease obviously. (4) Stress plays a main role in displacement, and displacement is a linkage response to stress due to the coordinated deformation. Multiple layers backfill mining results in an enhanced correlation degree and more chaotic state between stress and displacement. The results will provide engineering geological basis for optimal design and safe production of backfill mining under loose aquifers.
回填开采是保证薄基岩和松散含水层下煤炭高效安全开采的重要手段。基于太平煤矿的案例研究,采用熵的理论分析和数值建模方法,建立了多层回填开采诱发应力和位移的时空立方体可视化模型。此外,基于信息熵和互信息,建立了对称 KL-发散的定量表征和测量框架。结果表明(1)多层回填开采导致应力和位移的非均匀性增强,呈现出一定的波动特征。(2)应力与位移的 KL 发散略大于位移与应力的 KL 发散,应力与位移相关效率的热点分布规律与 KL 发散一致。(3)多层回填开采的应力熵热点及应力熵与位移熵的差距明显减小。(4)应力对位移起主要作用,位移是协调变形对应力的联动响应。多层回填开采使应力与位移之间的相关性增强,更趋于混沌状态。研究结果将为松散含水层下回填采矿的优化设计和安全生产提供工程地质依据。
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引用次数: 0
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