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Study on the effectiveness and mechanism of antioxidant synergistic compounds in inhibiting coal spontaneous combustion 抗氧化协同化合物抑制煤自燃的效果及机理研究
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-21 DOI: 10.1016/j.combustflame.2026.114796
Yujia Huo , Xin He , Xin Huang , Hongqing Zhu , Xiaomeng Zhou
Aiming to address the limitations of traditional mine inhibitors, including low inhibition efficiency and insufficient responsiveness, an antioxidant synergistic composite inhibitor (P&C) was developed. First, water was selected as the solvent, magnesium chloride (MgCl₂) as the physical inhibitor, dibutyl hydroxytoluene (BHT) as the primary antioxidant, triphenyl phosphite (TPPI) as the auxiliary antioxidant, and polyethylene glycol (PEG-400) as the functional additive. Subsequently, the composite formulation was optimized using response surface methodology, and the inhibition performance of P&C was evaluated through synchronous thermal analysis, crossing-point temperature experiments, and low-temperature oxidation tests. Finally, the synergistic inhibition mechanism of P&C was investigated via quantum chemical calculations, supported by moisture absorption and retention experiments, BET analysis, in situ infrared spectroscopy, and in situ EPR experiments. The results indicate that the optimal inhibition effect was achieved when the concentrations of MgCl₂, BHT, TPPI, and PEG-400 are 10.26%, 3.15%, 2.09%, and 0.58%, respectively. P&C can significantly increase the crossing point temperature (CPT), characteristic temperature points, and apparent activation energy while reducing heat release, and the inhibition rate is notably higher than that of the conventional inhibitor CaCl₂. Mechanism analysis reveals that MgCl₂ suppresses oxygen diffusion through moisture absorption, cooling, and pore blockage; BHT and TPPI inhibit the chain reaction of coal spontaneous combustion by scavenging free radicals and decomposing peroxides; and PEG-400 enhances the dispersion and permeability of the components in P&C. The P&C system forms a synergistic physical–chemical inhibition effect: physical inhibition provides reaction time for chemical inhibition, while chemical inhibition maintains the stability of the physical inhibition layer. These findings offer new insights into the development of high-efficiency composite inhibitors and hold significant application potential for mine fire prevention.
针对传统矿用抑制剂缓蚀效率低、响应性差等缺点,研制了一种抗氧化增效复合抑制剂P&;C。首先,以水为溶剂,氯化镁(MgCl₂)为物理抑制剂,二丁基羟基甲苯(BHT)为主抗氧化剂,亚磷酸三苯酯(TPPI)为辅助抗氧化剂,聚乙二醇(PEG-400)为功能添加剂。随后,利用响应面法对复合配方进行优化,并通过同步热分析、交叉点温度实验和低温氧化实验对P&;C的缓蚀性能进行评价。最后,通过量子化学计算,结合吸湿保持实验、BET分析、原位红外光谱和原位EPR实验,研究了P&;C的协同抑制机理。结果表明,当MgCl 2、BHT、TPPI和PEG-400的浓度分别为10.26%、3.15%、2.09%和0.58%时,抑制效果最佳。P&;C可以显著提高过点温度(CPT)、特征温度点和表观活化能,同时减少放热,抑制率明显高于常规抑制剂cacl2。机理分析表明,MgCl₂通过吸湿、冷却和堵塞孔隙抑制氧扩散;BHT和TPPI通过清除自由基和分解过氧化物抑制煤自燃链式反应;PEG-400提高了P&;C中组分的分散性和渗透率。P&;C体系形成了一种协同的理化缓蚀效应:物理缓蚀为化学缓蚀提供了反应时间,而化学缓蚀则维持了物理缓蚀层的稳定性。这些发现为开发高效复合抑制剂提供了新的见解,并在矿井防火方面具有重要的应用潜力。
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引用次数: 0
Tuning energy release in boron-based energetic composites via gradient thickness control of surface fluoride layer by in situ polymerization 原位聚合对硼基含能复合材料表面氟层梯度厚度控制的能量释放调控
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-21 DOI: 10.1016/j.combustflame.2026.114784
Hongxia Zhang, Yaozhong Ran, Zhenyu Zhou, Jiawang Shuang, Jiaru Zhang, Fei Xiao, Chongwei An, Zhongliang Ma
Boron powder exhibits exceptionally high gravimetric and volumetric calorific values, granting boron-rich propellants a significantly higher theoretical specific impulse compared to conventional hydrocarbon-based fuels. However, its practical application is severely limited by difficult ignition and incomplete combustion, resulting from the inherent oxide layer on the boron surface. Addressing these combustion inefficiencies is therefore critical. In this work, a series of modified B@FP composites with gradient fluoropolymer coating thicknesses were successfully synthesized through in situ polymerization of 1H,1H,2H,2H-perfluorooctyl acrylate (FOA) onto boron powder, where the coating mass was precisely tailored by varying the FOA monomer concentration. The surface morphology, elemental distribution, chemical composition, and hydrophobicity of the B@FP composites were comprehensively characterized. Their oxidation behavior, ignition performance, and combustion dynamics were further investigated. The results indicate that the fluoropolymer coating significantly reduces the ignition temperature of boron while increasing both the combustion heat and total exothermic enthalpy. Moreover, in combustion systems with ammonium perchlorate (AP) as oxidizer, the B@FP-1/AP mixture demonstrated higher combustion temperatures and a more vigorous reaction. Ultimately, the effect of the modified boron composites on the combustion performance of composite propellants was thoroughly evaluated, providing valuable insights for enhancing energy release efficiency in boron-containing propellant systems.
硼粉具有极高的重量和体积热值,与传统的碳氢化合物燃料相比,富硼推进剂具有更高的理论比冲。然而,由于硼表面固有的氧化层导致点火困难和燃烧不完全,严重限制了其实际应用。因此,解决这些燃烧效率低下的问题至关重要。在本研究中,通过在硼粉上原位聚合1H,1H,2H,2H-全氟丙烯酸辛酯(FOA),并通过改变FOA单体浓度来精确调整涂层质量,成功合成了一系列具有梯度氟聚合物涂层厚度的改性B@FP复合材料。对B@FP复合材料的表面形貌、元素分布、化学组成和疏水性进行了全面表征。进一步研究了它们的氧化行为、点火性能和燃烧动力学。结果表明,含氟聚合物涂层显著降低了硼的着火温度,同时提高了燃烧热和总放热焓。此外,在以高氯酸铵(AP)作为氧化剂的燃烧系统中,B@FP-1/AP混合物表现出更高的燃烧温度和更强烈的反应。最后,全面评估了改性硼复合材料对复合推进剂燃烧性能的影响,为提高含硼推进剂系统的能量释放效率提供了有价值的见解。
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引用次数: 0
Burning velocity and burn time via particle image velocimetry and modeling for aluminum dust flames 燃烧速度和燃烧时间的粒子图像测速和建模的铝粉尘火焰
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-20 DOI: 10.1016/j.combustflame.2026.114795
Vidhan S. Malik , Christopher J. Pfützner , Brian T. Bojko , Vadim N. Gamezo , Michael J. Soo , Brian T. Fisher
Metal fuels are theoretically predicted to outperform conventional fuels such as methane and fossil fuels due to their higher energy density content. This paper seeks to quantify combustion properties of aluminum dust such as particle burning velocity, particle burn length, and particle burn time. The experimental work consists of stabilizing an aluminum-air flame in a counter-flow configuration to provide quasi-1D flame measurements. Particle Image Velocimetry (PIV) is used to extract time and length scales of interest. The results show that the gaseous flame speed increases with particle concentration from 0.2 m/s at 300 g/m3 to 0.5 m/s at 700 g/m3 while the particle burn time decreases from ∼4 ms to ∼2 ms and the particle burn length remains almost constant at ∼2–2.5 mm. The experimental results are analyzed using a 1D theoretical model describing particle ignition and combustion stability. A second model analyzes particle-particle interaction relative to powder concentration to reveal that a certain level of particle proximity is required for sustained flames, defined by the overlap of air spheres that surround particles. The 1D modeling results are further developed to incorporate stochastic diameters and spatial positioning in a 3D model where results reflect a non-zero probability of competition for oxygen at all concentration values signifying the importance of intermediate radicals such as AlO and radiation heat transfer.
理论上,由于金属燃料的能量密度较高,预计其性能将优于甲烷和化石燃料等传统燃料。本文旨在量化铝尘的燃烧特性,如颗粒燃烧速度、颗粒燃烧长度和颗粒燃烧时间。实验工作包括在逆流配置中稳定铝-空气火焰以提供准一维火焰测量。粒子图像测速(PIV)用于提取感兴趣的时间尺度和长度尺度。结果表明,气体火焰速度随颗粒浓度的增加而增加,从300 g/m3时的0.2 m/s增加到700 g/m3时的0.5 m/s,颗粒燃烧时间从~ 4 ms减少到~ 2 ms,颗粒燃烧长度基本保持在~ 2 ~ 2.5 mm。用一维理论模型对实验结果进行了分析,该模型描述了颗粒点火和燃烧稳定性。第二个模型分析了粒子与粉末浓度的相互作用,揭示了持续火焰需要一定程度的粒子接近,这是由围绕粒子的空气球体的重叠定义的。一维建模结果进一步发展,将随机直径和空间定位纳入三维模型,其结果反映了在所有浓度值下氧气竞争的非零概率,这表明中间自由基如AlO和辐射传热的重要性。
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引用次数: 0
Computational fluid dynamics analysis of flame dynamics in partial gravity environments in a rotating centrifuge 旋转离心机部分重力环境下火焰动力学的计算流体动力学分析
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-20 DOI: 10.1016/j.combustflame.2026.114808
Ankit Sharma , Arland Zatania Lojo , Ya-Ting T. Liao , Paul V. Ferkul , Michael C. Johnston
The safety of spacecraft and crew members is a critical concern for space research and exploration missions. It is already known that fire hazards in a microgravity environment present unique challenges, primarily due to the absence of buoyancy, which significantly alters fire behavior. The NASA’s Artemis program, which aims to send humans to the Moon, introduces a new set of challenges due to the Moon partial gravity compared to the Earth. This necessitates a better understanding of fire behavior in partial gravity conditions. However, conducting experiments in true partial gravity environments is challenging, and the use of centrifuges to create artificial partial gravity introduces complications, including the Coriolis force and limitations in chamber size. Consequently, there have been limited studies on flame dynamics in partial gravity. To address these challenges, this research employs Computational Fluid Dynamics (CFD) techniques to investigate flame behavior in a partial gravity environment created by a rotating centrifuge. The numerical model is validated against NASA's previous experiments and provides information on the effects of the Coriolis force and flow recirculation in the chamber. The analysis reveals that the interaction between buoyancy, Coriolis force, and flow recirculation plays a significant role in flame behavior. The flame tilt angle observed in both the experiments and the numerical results is caused by the combined effects of these forces and their variations along the flame length. In conclusion, this research contributes to our understanding of how flames behave in partial gravity environments created by rotating centrifuges. It emphasizes the complexity of flame dynamics in such conditions and provides valuable insights for future centrifuge experiments, with the goal of improving space exploration safety and understanding flame behavior in unique partial gravity environment.
航天器和机组人员的安全是空间研究和探索任务的关键问题。众所周知,在微重力环境下,火灾危险带来了独特的挑战,主要是由于缺乏浮力,这极大地改变了火灾行为。美国国家航空航天局(NASA)旨在将人类送上月球的阿尔忒弥斯(Artemis)计划,由于月球的部分重力与地球相比,带来了一系列新的挑战。这需要更好地理解在部分重力条件下的火灾行为。然而,在真正的部分重力环境中进行实验是具有挑战性的,使用离心机制造人工部分重力会带来并发症,包括科里奥利力和腔室尺寸的限制。因此,对部分重力下火焰动力学的研究非常有限。为了解决这些挑战,本研究采用计算流体动力学(CFD)技术来研究旋转离心机在部分重力环境下的火焰行为。该数值模型与NASA先前的实验进行了验证,并提供了关于科里奥利力和腔室内流动再循环影响的信息。分析表明,浮力、科里奥利力和流动再循环之间的相互作用对火焰行为有重要影响。实验和数值结果中观察到的火焰倾斜角是由这些力及其沿火焰长度变化的综合作用引起的。总之,这项研究有助于我们理解火焰在旋转离心机产生的部分重力环境中的行为。它强调了在这种条件下火焰动力学的复杂性,并为未来的离心机实验提供了有价值的见解,以提高空间探索的安全性和理解独特的部分重力环境下的火焰行为。
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引用次数: 0
Direct NO removal driven by dielectric barrier discharge: An experimental and kinetic modeling study 介质阻挡放电直接去除NO:实验与动力学模型研究
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-20 DOI: 10.1016/j.combustflame.2026.114790
Menglei Zheng , Yong Bao , Xianhui Chen , Xiaoyuan Zhang
Mitigating nitrogen oxide (NOx) pollution remains a formidable challenge amid the continued utilization of fossil fuels and the emergence of zero-carbon ammonia energy. Unlike the selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR), which require additional additives to remove NO, this study integrates experimental measurements and kinetic simulations to investigate the direct removal of NO driven by dielectric barrier discharge (DBD). A two-zone DBD platform is designed, and experimental studies are conducted for the NO/Ar system. The experimental results demonstrate that, in the absence of additives (e.g., NH3, O2), the system achieves 98 % NO removal efficiency, and an N2/O2 selectivity greater than 90 %. Furthermore, it is found that increasing the voltage is more effective in enhancing the removal of NO than increasing the number of plasma-reaction-zones. The rate constants of electron collision reactions are calculated by Bolsig+ solver, while those for the excited-state species are derived from the semi-empirical models such as the Fridman-Macheret α-model and the Schwartz-Slawsky Herzfeld (SSH) model. Ultimately, a kinetic model for the removal of NO by plasma is developed to reveal the reaction kinetics of NO removal under various conditions. Kinetic analysis show that electron collisions drive the Ar/NO to generate excited-state species (e.g., NO (ele), NO (vib), and NO+). Through plasma-related reactions, such as dissociative quenching reaction (Ar + NO = Ar + N + O) and dissociative recombination reaction (e + NO+ = N + O), N and O atoms are generated thereby converted into N2 and O2 through ground-state chemical reactions.
随着化石燃料的持续使用和零碳氨能源的出现,减少氮氧化物(NOx)污染仍然是一项艰巨的挑战。与选择性非催化还原(SNCR)和选择性催化还原(SCR)需要额外的添加剂来去除NO不同,本研究结合实验测量和动力学模拟来研究介质阻挡放电(DBD)驱动下直接去除NO的方法。设计了双区DBD平台,并对NO/Ar系统进行了实验研究。实验结果表明,在不添加添加剂(如NH3、O2)的情况下,该系统的NO去除率达到98%,N2/O2选择性大于90%。此外,我们还发现增加电压比增加等离子体反应区的数量更有效地促进了NO的去除。电子碰撞反应的速率常数由Bolsig+求解器计算,激发态种的速率常数由Fridman-Macheret α-模型和schwartz - slavsky Herzfeld (SSH)模型等半经验模型计算。最后,建立了等离子体去除NO的动力学模型,揭示了不同条件下去除NO的反应动力学。动力学分析表明,电子碰撞驱动Ar/NO生成激发态物质(如NO (ele)、NO (vib)和NO+)。通过等离子体相关反应,如解离猝灭反应(Ar + NO = Ar + N + O)和解离重组反应(e + NO+ = N + O),产生N和O原子,从而通过基态化学反应转化为N2和O2。
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引用次数: 0
Markstein number estimation using complete instability of downward propagating planar flames in acoustic field 声场中向下传播平面火焰完全不稳定性的Markstein数估计
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-19 DOI: 10.1016/j.combustflame.2026.114805
Arvind Kumar Ahirwar, Ajit Kumar Dubey
Markstein number (Ma) is an important parameter for premixed flames influencing flame speed and instabilities. This work presents a novel approach for estimating Ma using acoustic parametric instability of flames travelling downward in an open-closed tube. At a constant equivalence ratio, laminar burning velocity (SL) can be controlled by varying diluent fraction. In such an experiment, at sufficiently high SL, two types of thermo-acoustic instability are observed: primary instability (where the initial cellular flame transitions to a vibrating planar flame) and secondary instability (where the vibrating planar flame transitions to a vibrating turbulent flame due to parametric instability of the flame front). Upon further raising SL, to "critical SL", "complete instability" of flat flames is seen, indicating that the flat flame cannot be stabilized and the initial cellular flame transitions directly to parametric instability. An analytical model is used for calculating stability of planar flames in acoustic field. The width of stability region of planar flames becomes zero at the critical SL. This condition is utilized to indirectly obtain Ma for a known critical SL for methane, ethylene and propane flames diluted with N2 and CO2. The Ma estimated from this method are in very good agreement with Ma from literature obtained using growth rates of hydrodynamic instability. Previous attempts to find Ma using acoustic instability have used wavenumber and acoustic amplitude at the onset of parametric instability. These quantities have higher measurement uncertainty. The present method only needs knowledge of mixture composition at critical SL and thus the error bars are negligible. The method is also extended to mixtures other than the critical SL mixture. Acoustic instability is influenced by both flow strain and flame curvature, so the estimated Ma contains both effects unlike the counterflow flame (influenced by flow strain) and spherical flames (influenced by curvature).
Markstein数(Ma)是影响火焰速度和不稳定性的重要参数。这项工作提出了一种利用火焰在开闭管中向下传播的声学参数不稳定性来估计Ma的新方法。当当量比一定时,可以通过改变稀释剂分数来控制层流燃烧速度。在这样的实验中,在足够高的声压下,观察到两种类型的热声不稳定性:初级不稳定性(初始的细胞火焰转变为振动的平面火焰)和次级不稳定性(由于火焰锋面的参数不稳定性,振动的平面火焰转变为振动的湍流火焰)。当进一步提高SL至“临界SL”时,可以看到扁平火焰的“完全不稳定”,表明扁平火焰不能稳定,初始胞状火焰直接过渡到参数不稳定。用解析模型计算了平面火焰在声场中的稳定性。平面火焰的稳定区宽度在临界SL处变为零,利用这一条件可以间接求得已知的甲烷、乙烯和丙烷火焰的临界SL的Ma。用这种方法估计的Ma与用水动力不稳定性的增长率得到的文献中的Ma非常吻合。先前使用声学不稳定性来寻找Ma的尝试使用了参数不稳定性开始时的波数和声学振幅。这些量具有较高的测量不确定度。本方法只需要知道临界SL的混合物成分,因此误差条可以忽略不计。该方法也适用于临界SL混合物以外的混合物。声不稳定性同时受到流动应变和火焰曲率的影响,因此估计的Ma包含了与逆流火焰(受流动应变影响)和球形火焰(受曲率影响)不同的两种影响。
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引用次数: 0
Transient AlH distribution around a burning micron-sized Al droplet quantified by laser absorption imaging 激光吸收成像定量测定微米级铝液滴燃烧时AlH的瞬态分布
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-19 DOI: 10.1016/j.combustflame.2026.114789
Zhiyong Wu , Weitian Wang , Edouard Berrocal , Marcus Aldén , Zhongshan Li
This study presents the first direct measurement of aluminum monohydride (AlH) distribution and dynamics during aluminum combustion. Single micron-sized aluminum droplets were burned in a controlled H₂O/N₂/O₂ environment to ensure repeatable conditions. A dual-wavelength laser absorption imaging system is used to quantify the AlH concentration with high temporal and spatial resolution. The results show that AlH concentration peaks near the droplet surface and decreases from about 1.2% to a negligible level within the condensation layer. As combustion proceeds, AlH extends outward from the droplet surface, and its distribution area stabilizes approximately 12 ms after ignition. This work demonstrates a robust technique for AlH quantification and provides novel data which is critical to understand the aluminum combustion mechanism.
本研究首次对铝燃烧过程中一氢化铝(AlH)的分布和动力学进行了直接测量。单微米尺寸的铝液滴在受控的H₂O/N₂/O₂环境中燃烧,以确保可重复的条件。采用双波长激光吸收成像系统对AlH浓度进行定量分析,具有较高的时空分辨率。结果表明,AlH浓度在液滴表面附近达到峰值,在凝结层内从1.2%左右下降到可以忽略的水平。随着燃烧的进行,AlH从液滴表面向外延伸,其分布区域在点燃后约12ms稳定。这项工作展示了一种强大的AlH量化技术,并提供了新的数据,这对理解铝的燃烧机制至关重要。
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引用次数: 0
Experimental and numerical investigation on flashback of low-swirling hydrogen–air jet flames 低旋流氢气-空气射流火焰闪回的实验与数值研究
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-19 DOI: 10.1016/j.combustflame.2026.114792
Maho Kawai , Takeshi Shoji , Abhishek Lakshman Pillai , Shigeru Tachibana , Takeshi Yokomori , Ryoichi Kurose
Flashback of premixed hydrogen–air jet flames in a low-swirl burner (LSB) is investigated through experiments and Large-Eddy Simulations (LESs). The experiments include pressure measurements, high-speed chemiluminescence imaging of OH* radicals, and two-dimensional particle image velocimetry. The LESs are conducted on the same burner under various equivalence ratio conditions and are used to analyze local flame propagation dynamics. The experimental results show that core-flow flashback occurs after the lifted flame attaches to the burner exit periphery and then propagates upstream along the central region of the flow field, reflecting the characteristic velocity distribution in low-swirl burners. The LES results show that the regions on the flame surface where flashback is promoted are primarily governed by the local flow velocity, whereas the overall tendency for upstream flame propagation is influenced by the displacement speed. The analysis further shows that the relative contributions of reaction and diffusion to the displacement speed vary strongly across the flame thickness. Transient stagnations of upstream flame motion are also observed, together with a temporary reduction in the upstream-propagating flame surface area and a transition in the dominant pressure oscillation mode.
Novelty and significance statement
The present understanding of flashback in premixed low-swirl flames remains limited, particularly with respect to three-dimensional flame-structure dynamics. This study investigates flashback in low-swirling hydrogen–air jet flames using experiments and large-eddy simulations for the first time, to the best of the authors’ knowledge. This combined approach enables analysis of flame behavior as three-dimensional distributions that resolve variations across the flame thickness, rather than relying on representative or integral metrics. Local contributions from flow velocity, chemical reaction, and molecular diffusion to flame propagation are quantified, showing that their relative importance varies strongly across the flame thickness and along the flame surface. In addition, transient stagnation of upstream flame motion is associated with a temporary reduction of the flame area exhibiting upstream propagation and a transition of the dominant pressure-oscillation mode. These results link local flame structure, flow–flame interaction, and pressure dynamics in the flashback.
通过实验和大涡模拟研究了低旋流燃烧器中预混氢-空气射流火焰的闪回现象。实验包括压力测量、OH*自由基的高速化学发光成像和二维粒子图像测速。在不同的等效比条件下,对同一燃烧器进行了模拟实验,分析了火焰的局部传播动力学。实验结果表明,升力火焰附着在燃烧器出口外围后,沿流场中心区域向上游传播,出现了芯流闪回现象,反映了低旋流燃烧器的速度分布特征。结果表明,火焰表面上促进闪回的区域主要受局部流速的控制,而火焰上游传播的总体趋势受位移速度的影响。进一步分析表明,反应和扩散对位移速度的相对贡献在不同的火焰厚度上变化很大。还观察到上游火焰运动的短暂停滞,以及上游传播火焰表面积的暂时减少和主导压力振荡模式的转变。新颖性和意义声明目前对低旋预混火焰闪回的理解仍然有限,特别是在三维火焰结构动力学方面。据作者所知,本研究首次利用实验和大涡模拟研究了低旋氢-空气射流火焰中的闪回现象。这种结合的方法可以分析火焰行为的三维分布,解决火焰厚度的变化,而不是依赖于代表性或积分指标。流速、化学反应和分子扩散对火焰传播的局部贡献被量化,表明它们的相对重要性在火焰厚度和火焰表面上变化很大。此外,上游火焰运动的短暂停滞与火焰面积的暂时减少有关,表现出上游传播和主导压力振荡模式的转变。这些结果将闪回中局部火焰结构、流动-火焰相互作用和压力动力学联系起来。
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引用次数: 0
Conversion of Al2O3 on micron-sized Al-Si surface to Al-MOFs:Realizing dual-functional regulation of enhanced reactivity and energy release design 微米级Al-Si表面Al2O3转化为al- mof:实现增强反应性和能量释放设计的双功能调控
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-19 DOI: 10.1016/j.combustflame.2026.114811
Yuhao Wang , Shutao Wang , Shifa Cao , Zechun Tian , Jiayi Li , Henan Chang , Shuhong Ba
Compared with pure aluminum (Al) particles, aluminum-silicon (Al-Si) particles possess significant advantages, including lower ignition temperature, more thorough oxidation reaction, and more stable combustion process, making them highly promising candidate fuels for composite energetic materials. However, the incorporation of Si into Al results in more severe particle agglomeration, and the native Al2O3 layer on the surface impedes energy release. This study adopts a simple one-step method to in situ convert the Al2O3 on the surface of micron-sized Al-Si particles into an aluminum-based metal-organic frameworks (Al-MOFs), thus providing an effective approach to solving the above-mentioned problems. The reactivity of the modified samples is significantly enhanced, and the design of energy release can be achieved. The specific manifestations are as follows: Al-Si@Al-MOFs demonstrate a dynamic secondary combustion process accompanied by deflagration. Its combustion peak pressure and pressurization rate are 1.27 and 49.21 times those of pristine Al-Si, respectively. By regulating the coating amount of Al-MOFs, the design of energy release can be achieved. The modified samples show a notable improvement in specific impulse performance, which remains at a high level over a wide oxidizer-to-fuel (O/F) ratio range. Additionally, the static water contact angle of the modified samples increases significantly, indicating enhanced surface hydrophobicity and effectively improved anti-aging performance. This study has successfully constructed bifunctional energetic particles featuring precise design of energy release and high reactivity, providing a new strategy for the development of advanced aerospace fuels.
与纯铝(Al)颗粒相比,铝硅(Al- si)颗粒具有点火温度更低、氧化反应更彻底、燃烧过程更稳定等显著优势,是极具发展前景的复合含能材料候选燃料。然而,Si掺入Al会导致更严重的颗粒团聚,并且表面的原生Al2O3层阻碍了能量的释放。本研究采用简单的一步法将微米级Al-Si颗粒表面的Al2O3原位转化为铝基金属有机骨架(Al-MOFs),为解决上述问题提供了有效途径。改性后样品的反应性明显增强,可以实现能量释放的设计。具体表现如下:Al-Si@Al-MOFs演示了伴随爆燃的动态二次燃烧过程。燃烧峰值压力和加压率分别是原始Al-Si的1.27倍和49.21倍。通过调节al - mof的包覆量,可以实现能量释放的设计。改性后的样品在比冲性能上有了显著的改善,在较宽的氧化剂与燃料(O/F)比范围内保持在较高的水平。改性后样品的静水接触角明显增大,表明表面疏水性增强,抗老化性能有效提高。该研究成功构建了能量释放设计精确、反应性高的双功能高能粒子,为先进航空燃料的开发提供了新的策略。
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引用次数: 0
Cavity-enhanced combustion in a mach 6 axisymmetric scramjet 6马赫数轴对称超燃冲压发动机的空腔增强燃烧
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-19 DOI: 10.1016/j.combustflame.2026.114807
Xueni Yang , Tao Tang , Qinyuan Li , Wang Han , Rui Gu , Huifeng Chen , Yuhui Huang , Mingbo Sun , Hongbo Wang , Yixin Yang , Jiajian Zhu
The cavity-enhanced flow-combustion dynamics in axisymmetric scramjets at a Mach 6 flight condition is investigated through experimental and numerical methods. High-speed cameras and hydroxyl radical planar laser-induced fluorescence (OH-PLIF) are utilized in experiments for visual diagnostics of streamwise and spanwise flames within the cavity-based combustor, capturing both streamwise and spanwise instantaneous structures. Large eddy simulation (LES) is employed to reproduce this cavity-based flow field, and numerical comparisons are made with a non-cavity configuration. Experimental and computational results show that under the current conditions of high total temperature and long jet mixing distance, near-wall auto-ignition can achieve flame stabilization, exhibiting a jet wake flame stabilization mode. The near-wall reaction zone has been identified as a key flow structure, apart from the cavity recirculation zone, for enhancing fuel-air mixing. Within the cavity-equipped configuration, combustion is enhanced by the cavity, which provides a low-velocity recirculation zone to prolong fuel residence time, induces central shock waves, and supplies free radicals to the flame base. Additionally, the cavity intensifies combustion in the jet wake upstream of it and renders subsonic combustion dominant. Conversely, within the non-cavity combustor, combustion is self-sustained in the near-wall recirculation region, characterized by a prolonged, low-intensity heat release zone dominated by supersonic combustion.
通过实验和数值方法研究了轴对称超燃冲压发动机在6马赫飞行条件下的空腔增强流动燃烧动力学。高速摄像机和羟基自由基平面激光诱导荧光(OH-PLIF)在实验中用于对基于腔的燃烧室内沿流和沿展的火焰进行视觉诊断,捕获沿流和沿展的瞬时结构。采用大涡模拟(LES)模拟了这种基于空腔的流场,并与非空腔结构进行了数值比较。实验和计算结果表明,在当前总温度较高、射流混合距离较长的条件下,近壁自燃可以实现火焰稳定,表现为射流尾流火焰稳定模式。近壁反应区是除空腔再循环区外,提高燃料-空气混合性能的关键流动结构。在配备空腔的结构中,空腔提供了一个低速再循环区来延长燃料停留时间,诱导中心激波,并向火焰基提供自由基,从而增强了燃烧。此外,空腔加强了其上游射流尾流的燃烧,使亚音速燃烧占主导地位。相反,在非空腔燃烧室中,燃烧在近壁面再循环区域内是自我持续的,其特征是超声速燃烧主导的长时间低强度放热区。
{"title":"Cavity-enhanced combustion in a mach 6 axisymmetric scramjet","authors":"Xueni Yang ,&nbsp;Tao Tang ,&nbsp;Qinyuan Li ,&nbsp;Wang Han ,&nbsp;Rui Gu ,&nbsp;Huifeng Chen ,&nbsp;Yuhui Huang ,&nbsp;Mingbo Sun ,&nbsp;Hongbo Wang ,&nbsp;Yixin Yang ,&nbsp;Jiajian Zhu","doi":"10.1016/j.combustflame.2026.114807","DOIUrl":"10.1016/j.combustflame.2026.114807","url":null,"abstract":"<div><div>The cavity-enhanced flow-combustion dynamics in axisymmetric scramjets at a Mach 6 flight condition is investigated through experimental and numerical methods. High-speed cameras and hydroxyl radical planar laser-induced fluorescence (OH-PLIF) are utilized in experiments for visual diagnostics of streamwise and spanwise flames within the cavity-based combustor, capturing both streamwise and spanwise instantaneous structures. Large eddy simulation (LES) is employed to reproduce this cavity-based flow field, and numerical comparisons are made with a non-cavity configuration. Experimental and computational results show that under the current conditions of high total temperature and long jet mixing distance, near-wall auto-ignition can achieve flame stabilization, exhibiting a jet wake flame stabilization mode. The near-wall reaction zone has been identified as a key flow structure, apart from the cavity recirculation zone, for enhancing fuel-air mixing. Within the cavity-equipped configuration, combustion is enhanced by the cavity, which provides a low-velocity recirculation zone to prolong fuel residence time, induces central shock waves, and supplies free radicals to the flame base. Additionally, the cavity intensifies combustion in the jet wake upstream of it and renders subsonic combustion dominant. Conversely, within the non-cavity combustor, combustion is self-sustained in the near-wall recirculation region, characterized by a prolonged, low-intensity heat release zone dominated by supersonic combustion.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114807"},"PeriodicalIF":6.2,"publicationDate":"2026-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146036406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Combustion and Flame
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