Aiming to address the limitations of traditional mine inhibitors, including low inhibition efficiency and insufficient responsiveness, an antioxidant synergistic composite inhibitor (P&C) was developed. First, water was selected as the solvent, magnesium chloride (MgCl₂) as the physical inhibitor, dibutyl hydroxytoluene (BHT) as the primary antioxidant, triphenyl phosphite (TPPI) as the auxiliary antioxidant, and polyethylene glycol (PEG-400) as the functional additive. Subsequently, the composite formulation was optimized using response surface methodology, and the inhibition performance of P&C was evaluated through synchronous thermal analysis, crossing-point temperature experiments, and low-temperature oxidation tests. Finally, the synergistic inhibition mechanism of P&C was investigated via quantum chemical calculations, supported by moisture absorption and retention experiments, BET analysis, in situ infrared spectroscopy, and in situ EPR experiments. The results indicate that the optimal inhibition effect was achieved when the concentrations of MgCl₂, BHT, TPPI, and PEG-400 are 10.26%, 3.15%, 2.09%, and 0.58%, respectively. P&C can significantly increase the crossing point temperature (CPT), characteristic temperature points, and apparent activation energy while reducing heat release, and the inhibition rate is notably higher than that of the conventional inhibitor CaCl₂. Mechanism analysis reveals that MgCl₂ suppresses oxygen diffusion through moisture absorption, cooling, and pore blockage; BHT and TPPI inhibit the chain reaction of coal spontaneous combustion by scavenging free radicals and decomposing peroxides; and PEG-400 enhances the dispersion and permeability of the components in P&C. The P&C system forms a synergistic physical–chemical inhibition effect: physical inhibition provides reaction time for chemical inhibition, while chemical inhibition maintains the stability of the physical inhibition layer. These findings offer new insights into the development of high-efficiency composite inhibitors and hold significant application potential for mine fire prevention.
扫码关注我们
求助内容:
应助结果提醒方式:
