首页 > 最新文献

Combustion and Flame最新文献

英文 中文
Differences between the effects of NH3 cracking and H2 addition on the flame propagation of NH3/DME/Air mixtures: An experimental and kinetic study NH3裂解与H2加入对NH3/二甲醚/空气混合物火焰传播影响的差异:实验与动力学研究
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-02-09 DOI: 10.1016/j.combustflame.2026.114858
Huizhen Li , Huahua Xiao
Co-firing with other highly active fuels and partially dissociated ammonia (NH3) are the two attractive ways to enhance the combustion properties of NH3. In view of the ammonia/dimethyl ether/hydrogen (NH3/DME/H2) mixed combustion, it is necessary to explore the influence of different H2 sources in blends on combustion characteristics. This work conducted experiments and simulations to study the differences in flame propagation between NH3/DME/Air mixtures with partially dissociated NH3 and those with H2 addition. The flame morphology and laminar burning velocity (SL) of 80%NH3/20%DME/Air mixtures with various H2 additions (XH2 = 0-0.9) and NH3 cracking ratios (γ = 0-0.9) were measured at equivalence ratios of ϕ = 0.7-1.7 and normal temperature/pressure (Tu = 298 K, Pu = 0.1 MPa) using the spherical constant-volume combustion approach. By comparing the change of instability evaluation parameters with increasing H2 content, it can be inferred that the more wrinkles caused by the increase of H2 concentration are mainly due to the enhancement of hydrodynamic instability caused by the decreasing flame thickness, and the mixtures with H2 addition are more prone to flame instability than those with partially dissociated NH3. The results of the measured and predicted SL show that the partially dissociated NH3 in NH3/DME/Air mixtures can promote combustion to a higher extent than adding H2 directly due to the more H2 produced as γ = XH2, and the degree is more serious with the increase of H2 content. The results of decoupling thermal effect and chemical effect show that SL is mainly dominated by the chemical effect. Compared to the mixtures with H2 addition, the mixtures with partially dissociated NH3 have a stronger promoting effect on chemical effect, while a weaker effect on thermal effect. In addition, the combustion processes of these two kinds of mixtures are similar through sensitivity and reaction pathways analysis.
与其他高活性燃料共烧和部分解离氨(NH3)是提高NH3燃烧性能的两种有吸引力的方法。针对氨/二甲醚/氢(NH3/二甲醚/H2)混合燃烧,有必要探讨混合物中不同H2源对燃烧特性的影响。本文通过实验和模拟研究了部分解离NH3与添加H2的NH3/二甲醚/空气混合物在火焰传播中的差异。在φ = 0.7 ~ 1.7的等效比和常温/常压(Tu = 298 K, Pu = 0.1 MPa)条件下,采用球形等体积燃烧法测量了不同H2添加量(XH2 = 0 ~ 0.9)和NH3裂解比(γ = 0 ~ 0.9)的80%NH3/20%二甲醚/空气混合物的火焰形态和层状燃烧速度(SL)。通过比较不稳定性评价参数随H2含量增加的变化,可以推断H2浓度增加引起的褶皱增多主要是由于火焰厚度减小引起的流体动力不稳定性增强,添加H2的混合物比部分解离NH3的混合物更容易发生火焰不稳定性。结果表明,NH3/二甲醚/空气混合物中部分解离的NH3比直接加入H2对燃烧的促进作用更大,因为其以γ = XH2的形式生成的H2更多,且随着H2含量的增加,促进作用更强。热效应和化学效应的解耦结果表明,热效应主要以化学效应为主。与加入H2的混合物相比,加入部分解离NH3的混合物对化学效应的促进作用更强,而对热效应的促进作用较弱。此外,通过灵敏度和反应路径分析,两种混合物的燃烧过程相似。
{"title":"Differences between the effects of NH3 cracking and H2 addition on the flame propagation of NH3/DME/Air mixtures: An experimental and kinetic study","authors":"Huizhen Li ,&nbsp;Huahua Xiao","doi":"10.1016/j.combustflame.2026.114858","DOIUrl":"10.1016/j.combustflame.2026.114858","url":null,"abstract":"<div><div>Co-firing with other highly active fuels and partially dissociated ammonia (NH<sub>3</sub>) are the two attractive ways to enhance the combustion properties of NH<sub>3</sub>. In view of the ammonia/dimethyl ether/hydrogen (NH<sub>3</sub>/DME/H<sub>2</sub>) mixed combustion, it is necessary to explore the influence of different H<sub>2</sub> sources in blends on combustion characteristics. This work conducted experiments and simulations to study the differences in flame propagation between NH<sub>3</sub>/DME/Air mixtures with partially dissociated NH<sub>3</sub> and those with H<sub>2</sub> addition. The flame morphology and laminar burning velocity (S<sub>L</sub>) of 80%NH<sub>3</sub>/20%DME/Air mixtures with various H<sub>2</sub> additions (X<sub>H2</sub> = 0-0.9) and NH<sub>3</sub> cracking ratios (γ = 0-0.9) were measured at equivalence ratios of ϕ = 0.7-1.7 and normal temperature/pressure (T<sub>u</sub> = 298 K, P<sub>u</sub> = 0.1 MPa) using the spherical constant-volume combustion approach. By comparing the change of instability evaluation parameters with increasing H<sub>2</sub> content, it can be inferred that the more wrinkles caused by the increase of H<sub>2</sub> concentration are mainly due to the enhancement of hydrodynamic instability caused by the decreasing flame thickness, and the mixtures with H<sub>2</sub> addition are more prone to flame instability than those with partially dissociated NH<sub>3</sub>. The results of the measured and predicted S<sub>L</sub> show that the partially dissociated NH<sub>3</sub> in NH<sub>3</sub>/DME/Air mixtures can promote combustion to a higher extent than adding H<sub>2</sub> directly due to the more H<sub>2</sub> produced as γ = X<sub>H2</sub>, and the degree is more serious with the increase of H<sub>2</sub> content. The results of decoupling thermal effect and chemical effect show that S<sub>L</sub> is mainly dominated by the chemical effect. Compared to the mixtures with H<sub>2</sub> addition, the mixtures with partially dissociated NH<sub>3</sub> have a stronger promoting effect on chemical effect, while a weaker effect on thermal effect. In addition, the combustion processes of these two kinds of mixtures are similar through sensitivity and reaction pathways analysis.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114858"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study of the effect of electrode geometry on the ignition and flame development of NH3/air mixtures in nanosecond plasma discharges 电极几何形状对纳秒等离子体放电中NH3/空气混合物点火和火焰发展影响的实验研究
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-01-21 DOI: 10.1016/j.combustflame.2026.114809
Jie Tian , Huichao Jing , Yong Xiong , Lu Wang , Yongqi Wang , Qingwu Zhao , Yong Cheng
This study experimentally investigates the discharge characteristics, ignition performance, and flame development law of NH3/air mixtures with respect to different electrode geometries, namely a pin-pin electrode (Electrode A), a conventional nanosecond surface dielectric barrier discharge (nSDBD) coaxial electrode (Electrode B), and a self-designed radiant multi-zone regulated nSDBD electrode (Electrode C). The effects of work state parameters, including initial pressure (1-3 bar), excess air coefficient λ (1.0-1.4), and initial temperature (333-393 K), were also analysed. Under the reference conditions (initial pressure of 2 bar, initial temperature of 363 K, and λ = 1.0), the results show that: Electrode A achieves the shortest flame development time (15.0 ms) relying on a single-point high energy density, but the flame morphology is irregular; Electrode B exhibits the worst combustion performance due to random discharge and dispersed energy, which easily leads to the extinction of flame kernels; Electrode C, through six symmetric conductive areas, realizes the synchronous fusion of multiple flame kernels and demonstrates the optimal stability and adaptability. Under a wide range of operating conditions, Electrode C shows excellent robustness: it still maintains stable multiple flame kernels at 3 bar (while the number of flame kernels of Electrode B decreases by more than 50%), and it is time to reach the standard heat release is 11% shorter than that of Electrode B; at λ = 1.4, the number of flame kernels of Electrode C is 2–3 times that of Electrode B; when the temperature changes, the fluctuation in the time for the combustion pressure peak to reach its maximum value is less than 5% (compared to 26% for Electrode B). This study reveals the mechanism by which electrode geometry influences plasma and ammonia ignition, confirms the advantages of Electrode C, and provides theoretical and technical support for optimizing plasma ignition systems for ammonia fuel.
实验研究了NH3/空气混合物在不同电极几何形状下的放电特性、着火性能和火焰发展规律,分别为:针脚电极(电极a)、传统纳秒表面介质阻挡放电(nSDBD)同轴电极(电极B)和自行设计的辐射多区调节nSDBD电极(电极C)。还分析了初始压力(1-3 bar)、过量空气系数λ(1.0-1.4)和初始温度(333-393 K)等工作状态参数的影响。在参考条件下(初始压力为2 bar,初始温度为363 K, λ = 1.0),结果表明:电极A依靠单点高能量密度获得的火焰发展时间最短(15.0 ms),但火焰形态不规则;电极B由于随机放电和能量分散,燃烧性能最差,容易导致火焰核熄灭;电极C通过6个对称导电区,实现了多个火焰核的同步融合,表现出最佳的稳定性和适应性。在广泛的工作条件下,电极C表现出优异的稳健性:在3bar时仍能保持稳定的多个火焰核(而电极B的火焰核数减少了50%以上),达到标准放热的时间比电极B短11%;λ = 1.4时,电极C的火焰核数是电极B的2-3倍;当温度发生变化时,燃烧压力峰值达到最大值的时间波动小于5% (B电极为26%)。本研究揭示了电极几何形状对等离子体和氨点火的影响机理,证实了C电极的优越性,为优化氨燃料等离子体点火系统提供了理论和技术支持。
{"title":"Experimental study of the effect of electrode geometry on the ignition and flame development of NH3/air mixtures in nanosecond plasma discharges","authors":"Jie Tian ,&nbsp;Huichao Jing ,&nbsp;Yong Xiong ,&nbsp;Lu Wang ,&nbsp;Yongqi Wang ,&nbsp;Qingwu Zhao ,&nbsp;Yong Cheng","doi":"10.1016/j.combustflame.2026.114809","DOIUrl":"10.1016/j.combustflame.2026.114809","url":null,"abstract":"<div><div>This study experimentally investigates the discharge characteristics, ignition performance, and flame development law of NH<sub>3</sub>/air mixtures with respect to different electrode geometries, namely a pin-pin electrode (Electrode A), a conventional nanosecond surface dielectric barrier discharge (nSDBD) coaxial electrode (Electrode B), and a self-designed radiant multi-zone regulated nSDBD electrode (Electrode C). The effects of work state parameters, including initial pressure (1-3 bar), excess air coefficient λ (1.0-1.4), and initial temperature (333-393 K), were also analysed. Under the reference conditions (initial pressure of 2 bar, initial temperature of 363 K, and λ = 1.0), the results show that: Electrode A achieves the shortest flame development time (15.0 ms) relying on a single-point high energy density, but the flame morphology is irregular; Electrode B exhibits the worst combustion performance due to random discharge and dispersed energy, which easily leads to the extinction of flame kernels; Electrode C, through six symmetric conductive areas, realizes the synchronous fusion of multiple flame kernels and demonstrates the optimal stability and adaptability. Under a wide range of operating conditions, Electrode C shows excellent robustness: it still maintains stable multiple flame kernels at 3 bar (while the number of flame kernels of Electrode B decreases by more than 50%), and it is time to reach the standard heat release is 11% shorter than that of Electrode B; at λ = 1.4, the number of flame kernels of Electrode C is 2–3 times that of Electrode B; when the temperature changes, the fluctuation in the time for the combustion pressure peak to reach its maximum value is less than 5% (compared to 26% for Electrode B). This study reveals the mechanism by which electrode geometry influences plasma and ammonia ignition, confirms the advantages of Electrode C, and provides theoretical and technical support for optimizing plasma ignition systems for ammonia fuel.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114809"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146036404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on the low-pressure hypergolic performance of catalytic and reactive fuels 催化和反应燃料低压自燃性能的实验研究
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-02-04 DOI: 10.1016/j.combustflame.2026.114812
Geng Li, Peng Chen, Zhan Zhong, Gangqiang Wu, Zhi Li, Peng Wang, Weidong Huang, Wansheng Nie
Hypergolic propellants are widely used in various spacecraft propulsion systems, and hydrogen peroxide has received increasing attention as an oxidizing agent for nontoxic green propellants. In this work, the ignition delay time and low-pressure hypergolic limit are measured during a jet collision test for a combination of catalytic fuel (N,N,N',N'-tetramethyl ethylenediamine (TMEDA)/N,N-dimethylethanolamine (DMEA)+ cupric acetate) and reactive fuel (triethylene glycol dimethyl ether+ sodium borohydride) with hydrogen peroxide under different nitrogen gas pressures. The test results reveal that at low pressure, the ignition delay of catalytic fuel increases exponentially with decreasing ambient pressure, and the ignition limit decreases with increasing catalyst content. The ignition delay time of the reactive fuel is shorter than that of the catalytic fuel, and although the evaporation phenomenon after mixing is more obvious when the ambient pressure is reduced, the amount of evaporation before ignition is small, the evaporation process has a minimal effect on the ignition process, and the ignition delay time of the reactive fuel remains almost unchanged. Moreover, at 5 kPa, the ignition delay increases due to the change in the hydrogen peroxide jet state. Calculations via the CEA method indicate that the specific impulse and density-specific impulse of the reactive fuel are essentially identical to those of the catalytic fuel and differ only marginally from conventional hypergolic fuels. These results indicate that environmental pressure exerts differing effects on the ignition delay of various fuel types, rendering reactive fuel more suitable for engine start-up under fluctuating environmental pressure conditions.
自燃推进剂广泛应用于各种航天器推进系统中,过氧化氢作为无毒绿色推进剂的氧化剂越来越受到人们的关注。本文对催化燃料(N,N,N′,N′-四甲基乙二胺(TMEDA)/N,N-二甲基乙醇胺(DMEA)+乙酸铜)和反应燃料(三甘醇二甲醚+硼氢化钠)与过氧化氢组合在不同氮气压力下的点火延迟时间和低压自燃极限进行了测试。试验结果表明,在低压条件下,催化燃料的点火延迟时间随环境压力的降低呈指数增长,点火极限随催化剂含量的增加而降低。反应燃料的点火延迟时间比催化燃料短,虽然在环境压力降低时混合后的蒸发现象更为明显,但点火前的蒸发量较小,蒸发过程对点火过程的影响最小,反应燃料的点火延迟时间几乎保持不变。此外,在5kpa时,由于双氧水射流状态的变化,点火延迟时间增加。通过CEA方法计算表明,反应燃料的比冲和密度比冲与催化燃料的比冲基本相同,与传统自燃燃料仅略有不同。结果表明,环境压力对不同燃料类型的点火延迟产生不同的影响,反应性燃料更适合在波动环境压力条件下启动发动机。
{"title":"Experimental study on the low-pressure hypergolic performance of catalytic and reactive fuels","authors":"Geng Li,&nbsp;Peng Chen,&nbsp;Zhan Zhong,&nbsp;Gangqiang Wu,&nbsp;Zhi Li,&nbsp;Peng Wang,&nbsp;Weidong Huang,&nbsp;Wansheng Nie","doi":"10.1016/j.combustflame.2026.114812","DOIUrl":"10.1016/j.combustflame.2026.114812","url":null,"abstract":"<div><div>Hypergolic propellants are widely used in various spacecraft propulsion systems, and hydrogen peroxide has received increasing attention as an oxidizing agent for nontoxic green propellants. In this work, the ignition delay time and low-pressure hypergolic limit are measured during a jet collision test for a combination of catalytic fuel (N,N,N',N'-tetramethyl ethylenediamine (TMEDA)/N,N-dimethylethanolamine (DMEA)+ cupric acetate) and reactive fuel (triethylene glycol dimethyl ether+ sodium borohydride) with hydrogen peroxide under different nitrogen gas pressures. The test results reveal that at low pressure, the ignition delay of catalytic fuel increases exponentially with decreasing ambient pressure, and the ignition limit decreases with increasing catalyst content. The ignition delay time of the reactive fuel is shorter than that of the catalytic fuel, and although the evaporation phenomenon after mixing is more obvious when the ambient pressure is reduced, the amount of evaporation before ignition is small, the evaporation process has a minimal effect on the ignition process, and the ignition delay time of the reactive fuel remains almost unchanged. Moreover, at 5 kPa, the ignition delay increases due to the change in the hydrogen peroxide jet state. Calculations via the CEA method indicate that the specific impulse and density-specific impulse of the reactive fuel are essentially identical to those of the catalytic fuel and differ only marginally from conventional hypergolic fuels. These results indicate that environmental pressure exerts differing effects on the ignition delay of various fuel types, rendering reactive fuel more suitable for engine start-up under fluctuating environmental pressure conditions.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114812"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146184670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of Combustion Instability in Multi-Nozzle Can Combustor via MIMO Thermoacoustic Model with Combined Fuel Staging 多喷嘴燃烧器燃烧不稳定性的多输入多输出热声模型分析
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-02-05 DOI: 10.1016/j.combustflame.2026.114842
Junwoo Jung , Vo Quang Sang , Jihwan Seong , Chae Hoon Sohn , Min Kuk Kim , Jeongjae Hwang , Won June Lee , Daesik Kim
Hydrogen co-firing and lean premixed combustion technologies in modern gas turbines have significantly increased concerns regarding combustion instability. Although fuel staging has emerged as an effective control method, existing studies have focused on individual staging approaches, limiting our understanding of the combined staging effects. In this study, a comprehensive thermoacoustic stability map was developed by simultaneously applying outer nozzle fuel staging and pilot injection under 30% hydrogen co-firing conditions, providing a predictive framework for multiparameter instability control. An integrated methodology combining experiments, computational fluid dynamics (CFD), and thermoacoustic modeling was employed to investigate the interaction effects between the pilot injection and outer nozzle fuel staging. Experimental investigations revealed that the combined effects of pilot injection and outer nozzle fuel staging on dynamic pressure amplitudes exhibited complex interdependencies that varied with operating conditions. CFD analysis identified the underlying physical mechanisms and showed that different staging parameters modify the flame structure and time delay characteristics of the outer nozzles in distinct ways. A multi-input multi-output (MIMO) thermoacoustic model was developed to construct a stability map that incorporates the time-delay variations of outer nozzles. The stability map successfully captured the effects of pilot injection and outer nozzle fuel staging on the combustion instability characteristics. This integrated framework provides a practical design tool for optimizing fuel staging strategies in hydrogen-compatible gas turbines.
现代燃气轮机中氢共燃和稀薄预混燃烧技术对燃烧不稳定性的关注显著增加。尽管燃料分期已成为一种有效的控制方法,但现有的研究主要集中在单个分期方法上,限制了我们对联合分期效应的理解。在本研究中,在30%氢共烧条件下,通过同时应用外喷嘴燃料分段和先导喷射,建立了综合热声稳定性图,为多参数不稳定性控制提供了预测框架。采用实验、计算流体力学(CFD)和热声建模相结合的方法,研究了先导喷射与外喷管燃料分级之间的相互作用。实验研究表明,驾驶员喷射和外喷嘴燃油分级对动压力幅值的综合影响表现出复杂的相互依赖性,并随操作条件的变化而变化。CFD分析发现了潜在的物理机制,并表明不同的分级参数以不同的方式改变了外喷嘴的火焰结构和延迟特性。建立了多输入多输出(MIMO)热声模型,构建了包含外喷嘴时滞变化的稳定性图。稳定性图成功地捕捉到了导喷和外喷口燃油分级对燃烧不稳定性的影响。该集成框架为优化氢兼容燃气轮机的燃料分级策略提供了实用的设计工具。
{"title":"Analysis of Combustion Instability in Multi-Nozzle Can Combustor via MIMO Thermoacoustic Model with Combined Fuel Staging","authors":"Junwoo Jung ,&nbsp;Vo Quang Sang ,&nbsp;Jihwan Seong ,&nbsp;Chae Hoon Sohn ,&nbsp;Min Kuk Kim ,&nbsp;Jeongjae Hwang ,&nbsp;Won June Lee ,&nbsp;Daesik Kim","doi":"10.1016/j.combustflame.2026.114842","DOIUrl":"10.1016/j.combustflame.2026.114842","url":null,"abstract":"<div><div>Hydrogen co-firing and lean premixed combustion technologies in modern gas turbines have significantly increased concerns regarding combustion instability. Although fuel staging has emerged as an effective control method, existing studies have focused on individual staging approaches, limiting our understanding of the combined staging effects. In this study, a comprehensive thermoacoustic stability map was developed by simultaneously applying outer nozzle fuel staging and pilot injection under 30% hydrogen co-firing conditions, providing a predictive framework for multiparameter instability control. An integrated methodology combining experiments, computational fluid dynamics (CFD), and thermoacoustic modeling was employed to investigate the interaction effects between the pilot injection and outer nozzle fuel staging. Experimental investigations revealed that the combined effects of pilot injection and outer nozzle fuel staging on dynamic pressure amplitudes exhibited complex interdependencies that varied with operating conditions. CFD analysis identified the underlying physical mechanisms and showed that different staging parameters modify the flame structure and time delay characteristics of the outer nozzles in distinct ways. A multi-input multi-output (MIMO) thermoacoustic model was developed to construct a stability map that incorporates the time-delay variations of outer nozzles. The stability map successfully captured the effects of pilot injection and outer nozzle fuel staging on the combustion instability characteristics. This integrated framework provides a practical design tool for optimizing fuel staging strategies in hydrogen-compatible gas turbines.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114842"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146184674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Is the NH3 + N2O = H3NO + N2 reaction important in ammonia oxidation by nitrous oxide or oxygen? 氨氧化过程中NH3 + N2O = H3NO + N2反应重要吗?
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-01-29 DOI: 10.1016/j.combustflame.2026.114824
Xiaoyang Lei , Xiao Liu , Bin Yang , Shuiqing Li
Nitrous oxide (N2O) is an important intermediate/pollutant in combustion, particularly in the case of ammonia. Meanwhile, it can also be used as oxidizer or additive in the oxidation of fuels or propellants. Many studies have been performed for ammonia oxidation by N2O or O2. Whereas, the answers for the two basic questions “what are the main consumption pathways of N2O in ammonia oxidation by N2O or O2?” and “why adding N2O can improve the reactivity of ammonia for combustion?” are still unknown. In this work, the direct reactions between NH3 and N2O are investigated by quantum-chemical and kinetic calculations. The computations indicate that the dominant pathway of the NH3 + N2O reaction is to directly produce a zwitterionic intermediate, H3NO, and N2 molecule via the O-attack mechanism. The H3NO intermediate is a metastable tautomer of hydroxylamine (NH2OH), and its detection and characterization in the gas phase is still a challenge for experimentalists. To evaluate the importance of the NH3 + N2O reaction in ammonia oxidation by N2O or O2, twelve combustion models of ammonia in literatures are modified by the computed reaction parameters. The simulations show that the NH3 + N2O = H3NO + N2 reaction plays an important role in the consumption of N2O during ammonia oxidation by N2O and O2. Therefore, this reaction should be much more considered in the development of ammonia combustion model.
氧化亚氮(N2O)是燃烧过程中重要的中间污染物,特别是在氨的情况下。同时,它还可以作为氧化剂或添加剂用于燃料或推进剂的氧化。对N2O或O2氧化氨进行了许多研究。然而,对于“N2O或O2在氨氧化过程中N2O的主要消耗途径是什么”和“为什么添加N2O可以提高氨的燃烧反应性”这两个基本问题的答案仍然未知。本文采用量子化学和动力学计算方法研究了NH3和N2O之间的直接反应。计算表明,NH3 + N2O反应的主要途径是通过o -攻击机制直接生成两性离子中间体H3NO和N2分子。H3NO中间体是羟胺(NH2OH)的亚稳态互变异构体,其在气相中的检测和表征仍然是实验工作者面临的挑战。为了评价NH3 + N2O反应在N2O或O2氧化氨中的重要性,利用计算得到的反应参数对文献中12种氨的燃烧模型进行了修正。模拟结果表明,NH3 + N2O = H3NO + N2反应在N2O和O2氧化氨过程中对N2O的消耗起重要作用。因此,在开发氨燃烧模型时应更多地考虑这一反应。
{"title":"Is the NH3 + N2O = H3NO + N2 reaction important in ammonia oxidation by nitrous oxide or oxygen?","authors":"Xiaoyang Lei ,&nbsp;Xiao Liu ,&nbsp;Bin Yang ,&nbsp;Shuiqing Li","doi":"10.1016/j.combustflame.2026.114824","DOIUrl":"10.1016/j.combustflame.2026.114824","url":null,"abstract":"<div><div>Nitrous oxide (N<sub>2</sub>O) is an important intermediate/pollutant in combustion, particularly in the case of ammonia. Meanwhile, it can also be used as oxidizer or additive in the oxidation of fuels or propellants. Many studies have been performed for ammonia oxidation by N<sub>2</sub>O or O<sub>2</sub>. Whereas, the answers for the two basic questions “what are the main consumption pathways of N<sub>2</sub>O in ammonia oxidation by N<sub>2</sub>O or O<sub>2</sub>?” and “why adding N<sub>2</sub>O can improve the reactivity of ammonia for combustion?” are still unknown. In this work, the direct reactions between NH<sub>3</sub> and N<sub>2</sub>O are investigated by quantum-chemical and kinetic calculations. The computations indicate that the dominant pathway of the NH<sub>3</sub> + N<sub>2</sub>O reaction is to directly produce a zwitterionic intermediate, H<sub>3</sub>NO, and N<sub>2</sub> molecule via the O-attack mechanism. The H<sub>3</sub>NO intermediate is a metastable tautomer of hydroxylamine (NH<sub>2</sub>OH), and its detection and characterization in the gas phase is still a challenge for experimentalists. To evaluate the importance of the NH<sub>3</sub> + N<sub>2</sub>O reaction in ammonia oxidation by N<sub>2</sub>O or O<sub>2</sub>, twelve combustion models of ammonia in literatures are modified by the computed reaction parameters. The simulations show that the NH<sub>3</sub> + N<sub>2</sub>O = H<sub>3</sub>NO + N<sub>2</sub> reaction plays an important role in the consumption of N<sub>2</sub>O during ammonia oxidation by N<sub>2</sub>O and O<sub>2</sub>. Therefore, this reaction should be much more considered in the development of ammonia combustion model.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114824"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146075184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of hydrogen enrichment on the autoignition and lift-off behavior of ammonia jet flames in hot coflows 富氢对热共流中氨射流火焰自燃和升空行为的影响
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-01-30 DOI: 10.1016/j.combustflame.2026.114820
Daeyoung Jun , Seo Hee Cho , V. Mahendra Reddy , Bok Jik Lee
Ammonia is a promising carbon-free fuel, but its low reactivity presents a limitation. To mitigate this, hydrogen enrichment can be considered. This experimental study investigates the combustion characteristics and lift-off behaviors of autoignited ammonia–hydrogen flames. A jet in a hot oxidant coflow burner is used to examine the impact of hydrogen enrichment on ammonia jets. The flames exhibit distinct regimes, including attached, lifted, decoupled lifted flames, and blowout, influenced by hydrogen content, jet Reynolds number, and oxygen concentration. As expected, increasing hydrogen content and oxygen concentration stabilized the flame, promoting attachment. Distinctly decoupled lifted flames were observed, characterized by the separation of laminar and turbulent flame branches at the break-up point due to local extinction induced by high strain from developing eddies. Furthermore, flame pocket evolution in lifted flames was analyzed using high-speed imaging, revealing that flame pockets either grew to form new flame bases or were extinguished. During extinction, local turbulent structures cause larger flame pockets to fragment into smaller ones, which are subsequently extinguished rapidly. Regarding the spatial distribution of flame pockets, both decreasing hydrogen content and increasing jet velocity led to a downstream axial shift of the flame pocket locations. In terms of the number of flame pockets, the hydrogen content exhibited a more pronounced effect than the jet velocity. To find the flame stabilization mechanism, several lift-off height models were considered. The large-scale mixing model with autoignition time provided the best prediction, suggesting that flame stabilization is primarily governed by the balance between mixing and autoignition kinetics rather than flame propagation. This was further verified by the blowout correlation.
Novelty and significance: The novelty of this study lies in its investigation of ammonia–hydrogen jet flames in hot coflow environments, focusing on the stabilization mechanism of binary fuels with autoignition. Hydrogen enrichment, widely used to compensate for ammonia’s low reactivity, introduces additional complexity due to the large disparity in transport properties, particularly diffusivity. This study examines flame behavior, the transient evolution of flame pockets, and evaluates the applicability of various lift-off correlations. A large-scale mixing model with the autoignition time of a uniform fuel mixture remains effective in predicting lift-off height, despite the pronounced differential diffusion between hydrogen and ammonia. The findings of the present study could provide valuable insights for applications involving ammonia–hydrogen jet combustion.
氨是一种很有前途的无碳燃料,但它的低反应性存在局限性。为了减轻这种情况,可以考虑氢富集。本实验研究了自燃氨氢火焰的燃烧特性和升空行为。利用热氧化剂共流燃烧器中的射流,研究了氢气富集对氨射流的影响。受氢含量、射流雷诺数和氧浓度的影响,火焰表现出不同的状态,包括附着、上升、解耦上升火焰和井喷。正如预期的那样,增加氢含量和氧浓度稳定了火焰,促进了附着。观察到明显解耦的上升火焰,其特征是由于发展中的涡流的高应变引起的局部消光,在破裂点处层流和湍流火焰分支分离。此外,利用高速成像技术分析了提升火焰中火焰袋的演变过程,发现火焰袋要么生长形成新的火焰基地,要么被熄灭。在熄灭过程中,局部湍流结构使较大的火焰袋破碎成较小的火焰袋,随后迅速熄灭。在火焰袋的空间分布上,降低氢含量和增加射流速度都会导致火焰袋位置向下游轴向移动。在火焰袋数方面,氢含量的影响比射流速度的影响更明显。为了找出火焰稳定机理,考虑了几种起飞高度模型。具有自燃时间的大尺度混合模型提供了最好的预测,表明火焰稳定主要取决于混合和自燃动力学之间的平衡,而不是火焰传播。井喷相关性进一步验证了这一点。新颖性与意义:本研究的新颖性在于对热共流环境下氨氢射流火焰进行了研究,重点研究了二元燃料自燃的稳定机理。氢富集被广泛用于弥补氨的低反应性,由于输运性质,特别是扩散性的巨大差异,引入了额外的复杂性。本研究考察了火焰行为,火焰袋的瞬态演化,并评估了各种起飞相关性的适用性。尽管氢气和氨气之间的扩散有明显的差异,但具有均匀燃料混合物自燃时间的大尺度混合模型仍然可以有效地预测起飞高度。本研究结果可为氨氢射流燃烧的应用提供有价值的见解。
{"title":"Effects of hydrogen enrichment on the autoignition and lift-off behavior of ammonia jet flames in hot coflows","authors":"Daeyoung Jun ,&nbsp;Seo Hee Cho ,&nbsp;V. Mahendra Reddy ,&nbsp;Bok Jik Lee","doi":"10.1016/j.combustflame.2026.114820","DOIUrl":"10.1016/j.combustflame.2026.114820","url":null,"abstract":"<div><div>Ammonia is a promising carbon-free fuel, but its low reactivity presents a limitation. To mitigate this, hydrogen enrichment can be considered. This experimental study investigates the combustion characteristics and lift-off behaviors of autoignited ammonia–hydrogen flames. A jet in a hot oxidant coflow burner is used to examine the impact of hydrogen enrichment on ammonia jets. The flames exhibit distinct regimes, including attached, lifted, decoupled lifted flames, and blowout, influenced by hydrogen content, jet Reynolds number, and oxygen concentration. As expected, increasing hydrogen content and oxygen concentration stabilized the flame, promoting attachment. Distinctly decoupled lifted flames were observed, characterized by the separation of laminar and turbulent flame branches at the break-up point due to local extinction induced by high strain from developing eddies. Furthermore, flame pocket evolution in lifted flames was analyzed using high-speed imaging, revealing that flame pockets either grew to form new flame bases or were extinguished. During extinction, local turbulent structures cause larger flame pockets to fragment into smaller ones, which are subsequently extinguished rapidly. Regarding the spatial distribution of flame pockets, both decreasing hydrogen content and increasing jet velocity led to a downstream axial shift of the flame pocket locations. In terms of the number of flame pockets, the hydrogen content exhibited a more pronounced effect than the jet velocity. To find the flame stabilization mechanism, several lift-off height models were considered. The large-scale mixing model with autoignition time provided the best prediction, suggesting that flame stabilization is primarily governed by the balance between mixing and autoignition kinetics rather than flame propagation. This was further verified by the blowout correlation.</div><div><strong>Novelty and significance</strong>: The novelty of this study lies in its investigation of ammonia–hydrogen jet flames in hot coflow environments, focusing on the stabilization mechanism of binary fuels with autoignition. Hydrogen enrichment, widely used to compensate for ammonia’s low reactivity, introduces additional complexity due to the large disparity in transport properties, particularly diffusivity. This study examines flame behavior, the transient evolution of flame pockets, and evaluates the applicability of various lift-off correlations. A large-scale mixing model with the autoignition time of a uniform fuel mixture remains effective in predicting lift-off height, despite the pronounced differential diffusion between hydrogen and ammonia. The findings of the present study could provide valuable insights for applications involving ammonia–hydrogen jet combustion.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114820"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146075143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flame Chemistry Workshop: a perspective on challenges and strategic actions in combustion experiments and chemical kinetics modeling 火焰化学研讨会:对燃烧实验和化学动力学建模的挑战和战略行动的看法
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-02-11 DOI: 10.1016/j.combustflame.2026.114863
B. Rotavera , L. Cai , F. Zhang , A. Comandini , N. Hansen , S.J. Klippenstein , B. Yang , M. Pelucchi
Continued progress in the development of predictive models for combustion chemistry—including ignition and flame behavior, species evolution, and combustion system performance—relies on overcoming enduring and emerging challenges in experimental measurements, theoretical formulations, and chemical kinetics mechanism construction. As combustion science continues to coincide with advances in sustainable fuels development, plasma technologies, and automated modeling capabilities, the need for coordinated, community-driven strategies is essential. The Flame Chemistry Workshop (FCWS), held biennially before the International Symposium on Combustion, serves as a dedicated platform to identify, consolidate, and address these challenges in a structured and collaborative manner.
This perspective arises from discussions at the 7th FCWS in Milan, Italy (2024), and presents a collective view of the critical barriers currently limiting progress. Across the five technical domains discussed during the 7th FCWS – sustainable fuels combustion, advanced diagnostics for combustion measurements, experiments and modeling in plasma combustion, artificial intelligence and automated methods for theory and mechanisms generation, and chemical kinetic models—a series of persistent and emerging scientific challenges were identified, highlighting the need for deeper integration between three areas: theory, experiments, and modeling. The present article concisely describes present challenges that were identified in each of the technical domains in an effort to streamline and coordinate solutions to accelerate progress in combustion science.
燃烧化学预测模型的持续发展——包括点火和火焰行为、物种进化和燃烧系统性能——依赖于克服实验测量、理论公式和化学动力学机制构建方面的持久和新出现的挑战。随着燃烧科学不断与可持续燃料开发、等离子体技术和自动化建模能力的进步相一致,对协调的、社区驱动的战略的需求是必不可少的。火焰化学研讨会(FCWS)每两年在国际燃烧研讨会之前举行一次,作为一个专门的平台,以结构化和协作的方式识别、巩固和解决这些挑战。这一观点源于在意大利米兰(2024年)举行的第七届FCWS的讨论,并提出了目前限制进展的关键障碍的集体观点。在第7届FCWS期间讨论的五个技术领域-可持续燃料燃烧,燃烧测量的先进诊断,等离子体燃烧的实验和建模,理论和机制生成的人工智能和自动化方法,以及化学动力学模型-确定了一系列持续和新兴的科学挑战,突出了理论,实验和建模这三个领域之间更深层次的整合的需要。本文简明地描述了目前的挑战,在每个技术领域确定的努力简化和协调解决方案,以加速燃烧科学的进步。
{"title":"Flame Chemistry Workshop: a perspective on challenges and strategic actions in combustion experiments and chemical kinetics modeling","authors":"B. Rotavera ,&nbsp;L. Cai ,&nbsp;F. Zhang ,&nbsp;A. Comandini ,&nbsp;N. Hansen ,&nbsp;S.J. Klippenstein ,&nbsp;B. Yang ,&nbsp;M. Pelucchi","doi":"10.1016/j.combustflame.2026.114863","DOIUrl":"10.1016/j.combustflame.2026.114863","url":null,"abstract":"<div><div>Continued progress in the development of predictive models for combustion chemistry—including ignition and flame behavior, species evolution, and combustion system performance—relies on overcoming enduring and emerging challenges in experimental measurements, theoretical formulations, and chemical kinetics mechanism construction. As combustion science continues to coincide with advances in sustainable fuels development, plasma technologies, and automated modeling capabilities, the need for coordinated, community-driven strategies is essential. The Flame Chemistry Workshop (FCWS), held biennially before the International Symposium on Combustion, serves as a dedicated platform to identify, consolidate, and address these challenges in a structured and collaborative manner.</div><div>This perspective arises from discussions at the 7th FCWS in Milan, Italy (2024), and presents a collective view of the critical barriers currently limiting progress. Across the five technical domains discussed during the 7th FCWS – sustainable fuels combustion, advanced diagnostics for combustion measurements, experiments and modeling in plasma combustion, artificial intelligence and automated methods for theory and mechanisms generation, and chemical kinetic models—a series of persistent and emerging scientific challenges were identified, highlighting the need for deeper integration between three areas: theory, experiments, and modeling. The present article concisely describes present challenges that were identified in each of the technical domains in an effort to streamline and coordinate solutions to accelerate progress in combustion science.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114863"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146184844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Time-dependent-bases with local CUR decomposition method for accelerating turbulent combustion simulations 加速湍流燃烧模拟的局部CUR分解时基方法
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-02-09 DOI: 10.1016/j.combustflame.2026.114848
Jae Jung Kim , Cristian E. Lacey , Jun Hyung Lee , Ki Sung Jung , Jacqueline H. Chen , Chun Sang Yoo
This study presents a novel reduced-order modeling framework, Time-Dependent Bases with Local CUR decomposition (TDB-L-CUR), designed to efficiently and accurately approximate the species transport equations in reacting flow simulations. The method extends the existing TDB-CUR approach for chemically reacting flows (Jung et al. Comput. Methods Appl. Mech. Engrg. 437 (2025) 117758), which leverages matrix decomposition techniques to form a global-in-space, time-dependent low-dimensional manifold. While TDB-CUR performs well in homogeneous systems, it may be less well-suited to spatially heterogeneous systems such as turbulent flames, where higher-rank approximations are typically required. The proposed TDB-L-CUR framework introduces two methodological extensions to the baseline approach. First, it applies unsupervised clustering to partition the physical domain into distinct regions, enabling spatially localized manifold construction, thereby reducing the rank required for the reduced-order representation. Second, it incorporates a computational singular perturbation (CSP)-based scheme for identifying and penalizing fast species, allowing for spatio-temporally adaptive mitigation of chemical stiffness. The proposed framework is validated on a hierarchy of test cases, including a one-dimensional premixed flame, a two-dimensional nonpremixed ignition case with vortex interaction, and a three-dimensional turbulent premixed flame. TDB-L-CUR significantly improves accuracy over TDB-CUR while further reducing computational cost. The fully on-the-fly formulation of TDB-L-CUR (i.e., requiring no offline training or prior knowledge) makes it a robust and scalable tool for reduced-order modeling of reactive flows.
Novelty and significance statement
The novelty of this work lies in two aspects. First, it establishes spatially localized manifolds that adapt to heterogeneous flow fields, thereby overcoming the accuracy loss and high rank demands that limit conventional global manifold approaches. Second, it provides automated, on-the-fly mitigation of stiffness by performing eigenvalue decomposition to evaluate chemical time scales, eliminating the need for offline training or prior knowledge. Taken together, these advances yield a reduced-order framework that is both accurate and computationally efficient, marking a significant step for reactive flow simulations.
本研究提出了一种新颖的降阶建模框架,TDB-L-CUR (Time-Dependent Bases with Local CUR decomposition),旨在有效、准确地近似反应流模拟中的物质输运方程。该方法扩展了现有的用于化学反应流动的TDB-CUR方法(Jung等人)。第一版。方法:。动力机械。工程学报。437(2025)117758),它利用矩阵分解技术来形成全局空间,时间依赖的低维流形。虽然TDB-CUR在均匀系统中表现良好,但它可能不太适合空间异构系统,如湍流火焰,在这些系统中通常需要更高阶的近似。提议的TDB-L-CUR框架引入了基线方法的两种方法扩展。首先,它应用无监督聚类将物理域划分为不同的区域,从而实现空间局部化的流形构造,从而降低了降阶表示所需的秩。其次,它结合了一种基于计算奇异摄动(CSP)的方案来识别和惩罚快速物种,从而允许对化学刚度进行时空适应性缓解。该框架在一维预混火焰、二维非预混点火旋涡和三维湍流预混火焰等实验用例上得到了验证。TDB-L-CUR显著提高了TDB-CUR的精度,同时进一步降低了计算成本。TDB-L-CUR的完全动态公式(即,不需要离线培训或先验知识)使其成为响应流的降阶建模的健壮且可扩展的工具。这部作品的新颖性体现在两个方面。首先,它建立了适应非均匀流场的空间局部流形,从而克服了传统全局流形方法的精度损失和高秩要求。其次,它通过执行特征值分解来评估化学时间尺度,从而消除了离线训练或先验知识的需要,从而提供了自动化的、实时的刚度缓解。综上所述,这些进步产生了一个既准确又计算效率高的降阶框架,标志着反应流模拟迈出了重要的一步。
{"title":"Time-dependent-bases with local CUR decomposition method for accelerating turbulent combustion simulations","authors":"Jae Jung Kim ,&nbsp;Cristian E. Lacey ,&nbsp;Jun Hyung Lee ,&nbsp;Ki Sung Jung ,&nbsp;Jacqueline H. Chen ,&nbsp;Chun Sang Yoo","doi":"10.1016/j.combustflame.2026.114848","DOIUrl":"10.1016/j.combustflame.2026.114848","url":null,"abstract":"<div><div>This study presents a novel reduced-order modeling framework, Time-Dependent Bases with Local CUR decomposition (TDB-L-CUR), designed to efficiently and accurately approximate the species transport equations in reacting flow simulations. The method extends the existing TDB-CUR approach for chemically reacting flows (Jung et al. <em>Comput. Methods Appl. Mech. Engrg. 437</em> (2025) 117758), which leverages matrix decomposition techniques to form a global-in-space, time-dependent low-dimensional manifold. While TDB-CUR performs well in homogeneous systems, it may be less well-suited to spatially heterogeneous systems such as turbulent flames, where higher-rank approximations are typically required. The proposed TDB-L-CUR framework introduces two methodological extensions to the baseline approach. First, it applies unsupervised clustering to partition the physical domain into distinct regions, enabling spatially localized manifold construction, thereby reducing the rank required for the reduced-order representation. Second, it incorporates a computational singular perturbation (CSP)-based scheme for identifying and penalizing fast species, allowing for spatio-temporally adaptive mitigation of chemical stiffness. The proposed framework is validated on a hierarchy of test cases, including a one-dimensional premixed flame, a two-dimensional nonpremixed ignition case with vortex interaction, and a three-dimensional turbulent premixed flame. TDB-L-CUR significantly improves accuracy over TDB-CUR while further reducing computational cost. The fully <em>on-the-fly</em> formulation of TDB-L-CUR (i.e., requiring no offline training or prior knowledge) makes it a robust and scalable tool for reduced-order modeling of reactive flows.</div><div><strong>Novelty and significance statement</strong></div><div>The novelty of this work lies in two aspects. First, it establishes spatially localized manifolds that adapt to heterogeneous flow fields, thereby overcoming the accuracy loss and high rank demands that limit conventional global manifold approaches. Second, it provides automated, <em>on-the-fly</em> mitigation of stiffness by performing eigenvalue decomposition to evaluate chemical time scales, eliminating the need for offline training or prior knowledge. Taken together, these advances yield a reduced-order framework that is both accurate and computationally efficient, marking a significant step for reactive flow simulations.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114848"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Markstein number estimation using complete instability of downward propagating planar flames in acoustic field 声场中向下传播平面火焰完全不稳定性的Markstein数估计
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-01-19 DOI: 10.1016/j.combustflame.2026.114805
Arvind Kumar Ahirwar, Ajit Kumar Dubey
Markstein number (Ma) is an important parameter for premixed flames influencing flame speed and instabilities. This work presents a novel approach for estimating Ma using acoustic parametric instability of flames travelling downward in an open-closed tube. At a constant equivalence ratio, laminar burning velocity (SL) can be controlled by varying diluent fraction. In such an experiment, at sufficiently high SL, two types of thermo-acoustic instability are observed: primary instability (where the initial cellular flame transitions to a vibrating planar flame) and secondary instability (where the vibrating planar flame transitions to a vibrating turbulent flame due to parametric instability of the flame front). Upon further raising SL, to "critical SL", "complete instability" of flat flames is seen, indicating that the flat flame cannot be stabilized and the initial cellular flame transitions directly to parametric instability. An analytical model is used for calculating stability of planar flames in acoustic field. The width of stability region of planar flames becomes zero at the critical SL. This condition is utilized to indirectly obtain Ma for a known critical SL for methane, ethylene and propane flames diluted with N2 and CO2. The Ma estimated from this method are in very good agreement with Ma from literature obtained using growth rates of hydrodynamic instability. Previous attempts to find Ma using acoustic instability have used wavenumber and acoustic amplitude at the onset of parametric instability. These quantities have higher measurement uncertainty. The present method only needs knowledge of mixture composition at critical SL and thus the error bars are negligible. The method is also extended to mixtures other than the critical SL mixture. Acoustic instability is influenced by both flow strain and flame curvature, so the estimated Ma contains both effects unlike the counterflow flame (influenced by flow strain) and spherical flames (influenced by curvature).
Markstein数(Ma)是影响火焰速度和不稳定性的重要参数。这项工作提出了一种利用火焰在开闭管中向下传播的声学参数不稳定性来估计Ma的新方法。当当量比一定时,可以通过改变稀释剂分数来控制层流燃烧速度。在这样的实验中,在足够高的声压下,观察到两种类型的热声不稳定性:初级不稳定性(初始的细胞火焰转变为振动的平面火焰)和次级不稳定性(由于火焰锋面的参数不稳定性,振动的平面火焰转变为振动的湍流火焰)。当进一步提高SL至“临界SL”时,可以看到扁平火焰的“完全不稳定”,表明扁平火焰不能稳定,初始胞状火焰直接过渡到参数不稳定。用解析模型计算了平面火焰在声场中的稳定性。平面火焰的稳定区宽度在临界SL处变为零,利用这一条件可以间接求得已知的甲烷、乙烯和丙烷火焰的临界SL的Ma。用这种方法估计的Ma与用水动力不稳定性的增长率得到的文献中的Ma非常吻合。先前使用声学不稳定性来寻找Ma的尝试使用了参数不稳定性开始时的波数和声学振幅。这些量具有较高的测量不确定度。本方法只需要知道临界SL的混合物成分,因此误差条可以忽略不计。该方法也适用于临界SL混合物以外的混合物。声不稳定性同时受到流动应变和火焰曲率的影响,因此估计的Ma包含了与逆流火焰(受流动应变影响)和球形火焰(受曲率影响)不同的两种影响。
{"title":"Markstein number estimation using complete instability of downward propagating planar flames in acoustic field","authors":"Arvind Kumar Ahirwar,&nbsp;Ajit Kumar Dubey","doi":"10.1016/j.combustflame.2026.114805","DOIUrl":"10.1016/j.combustflame.2026.114805","url":null,"abstract":"<div><div>Markstein number (Ma) is an important parameter for premixed flames influencing flame speed and instabilities. This work presents a novel approach for estimating Ma using acoustic parametric instability of flames travelling downward in an open-closed tube. At a constant equivalence ratio, laminar burning velocity (S<sub>L</sub>) can be controlled by varying diluent fraction. In such an experiment, at sufficiently high S<sub>L</sub>, two types of thermo-acoustic instability are observed: primary instability (where the initial cellular flame transitions to a vibrating planar flame) and secondary instability (where the vibrating planar flame transitions to a vibrating turbulent flame due to parametric instability of the flame front). Upon further raising S<sub>L</sub>, to \"critical S<sub>L</sub>\", \"complete instability\" of flat flames is seen, indicating that the flat flame cannot be stabilized and the initial cellular flame transitions directly to parametric instability. An analytical model is used for calculating stability of planar flames in acoustic field. The width of stability region of planar flames becomes zero at the critical S<sub>L</sub>. This condition is utilized to indirectly obtain Ma for a known critical S<sub>L</sub> for methane, ethylene and propane flames diluted with N<sub>2</sub> and CO<sub>2</sub>. The Ma estimated from this method are in very good agreement with Ma from literature obtained using growth rates of hydrodynamic instability. Previous attempts to find Ma using acoustic instability have used wavenumber and acoustic amplitude at the onset of parametric instability. These quantities have higher measurement uncertainty. The present method only needs knowledge of mixture composition at critical S<sub>L</sub> and thus the error bars are negligible. The method is also extended to mixtures other than the critical S<sub>L</sub> mixture. Acoustic instability is influenced by both flow strain and flame curvature, so the estimated Ma contains both effects unlike the counterflow flame (influenced by flow strain) and spherical flames (influenced by curvature).</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114805"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146036349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Burning velocity and burn time via particle image velocimetry and modeling for aluminum dust flames 燃烧速度和燃烧时间的粒子图像测速和建模的铝粉尘火焰
IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-04-01 Epub Date: 2026-01-20 DOI: 10.1016/j.combustflame.2026.114795
Vidhan S. Malik , Christopher J. Pfützner , Brian T. Bojko , Vadim N. Gamezo , Michael J. Soo , Brian T. Fisher
Metal fuels are theoretically predicted to outperform conventional fuels such as methane and fossil fuels due to their higher energy density content. This paper seeks to quantify combustion properties of aluminum dust such as particle burning velocity, particle burn length, and particle burn time. The experimental work consists of stabilizing an aluminum-air flame in a counter-flow configuration to provide quasi-1D flame measurements. Particle Image Velocimetry (PIV) is used to extract time and length scales of interest. The results show that the gaseous flame speed increases with particle concentration from 0.2 m/s at 300 g/m3 to 0.5 m/s at 700 g/m3 while the particle burn time decreases from ∼4 ms to ∼2 ms and the particle burn length remains almost constant at ∼2–2.5 mm. The experimental results are analyzed using a 1D theoretical model describing particle ignition and combustion stability. A second model analyzes particle-particle interaction relative to powder concentration to reveal that a certain level of particle proximity is required for sustained flames, defined by the overlap of air spheres that surround particles. The 1D modeling results are further developed to incorporate stochastic diameters and spatial positioning in a 3D model where results reflect a non-zero probability of competition for oxygen at all concentration values signifying the importance of intermediate radicals such as AlO and radiation heat transfer.
理论上,由于金属燃料的能量密度较高,预计其性能将优于甲烷和化石燃料等传统燃料。本文旨在量化铝尘的燃烧特性,如颗粒燃烧速度、颗粒燃烧长度和颗粒燃烧时间。实验工作包括在逆流配置中稳定铝-空气火焰以提供准一维火焰测量。粒子图像测速(PIV)用于提取感兴趣的时间尺度和长度尺度。结果表明,气体火焰速度随颗粒浓度的增加而增加,从300 g/m3时的0.2 m/s增加到700 g/m3时的0.5 m/s,颗粒燃烧时间从~ 4 ms减少到~ 2 ms,颗粒燃烧长度基本保持在~ 2 ~ 2.5 mm。用一维理论模型对实验结果进行了分析,该模型描述了颗粒点火和燃烧稳定性。第二个模型分析了粒子与粉末浓度的相互作用,揭示了持续火焰需要一定程度的粒子接近,这是由围绕粒子的空气球体的重叠定义的。一维建模结果进一步发展,将随机直径和空间定位纳入三维模型,其结果反映了在所有浓度值下氧气竞争的非零概率,这表明中间自由基如AlO和辐射传热的重要性。
{"title":"Burning velocity and burn time via particle image velocimetry and modeling for aluminum dust flames","authors":"Vidhan S. Malik ,&nbsp;Christopher J. Pfützner ,&nbsp;Brian T. Bojko ,&nbsp;Vadim N. Gamezo ,&nbsp;Michael J. Soo ,&nbsp;Brian T. Fisher","doi":"10.1016/j.combustflame.2026.114795","DOIUrl":"10.1016/j.combustflame.2026.114795","url":null,"abstract":"<div><div>Metal fuels are theoretically predicted to outperform conventional fuels such as methane and fossil fuels due to their higher energy density content. This paper seeks to quantify combustion properties of aluminum dust such as particle burning velocity, particle burn length, and particle burn time. The experimental work consists of stabilizing an aluminum-air flame in a counter-flow configuration to provide quasi-1D flame measurements. Particle Image Velocimetry (PIV) is used to extract time and length scales of interest. The results show that the gaseous flame speed increases with particle concentration from 0.2 m/s at 300 g/m<sup>3</sup> to 0.5 m/s at 700 g/m<sup>3</sup> while the particle burn time decreases from ∼4 ms to ∼2 ms and the particle burn length remains almost constant at ∼2–2.5 mm. The experimental results are analyzed using a 1D theoretical model describing particle ignition and combustion stability. A second model analyzes particle-particle interaction relative to powder concentration to reveal that a certain level of particle proximity is required for sustained flames, defined by the overlap of air spheres that surround particles. The 1D modeling results are further developed to incorporate stochastic diameters and spatial positioning in a 3D model where results reflect a non-zero probability of competition for oxygen at all concentration values signifying the importance of intermediate radicals such as AlO and radiation heat transfer.</div></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":"286 ","pages":"Article 114795"},"PeriodicalIF":6.2,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146036407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Combustion and Flame
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1