Co-firing with other highly active fuels and partially dissociated ammonia (NH3) are the two attractive ways to enhance the combustion properties of NH3. In view of the ammonia/dimethyl ether/hydrogen (NH3/DME/H2) mixed combustion, it is necessary to explore the influence of different H2 sources in blends on combustion characteristics. This work conducted experiments and simulations to study the differences in flame propagation between NH3/DME/Air mixtures with partially dissociated NH3 and those with H2 addition. The flame morphology and laminar burning velocity (SL) of 80%NH3/20%DME/Air mixtures with various H2 additions (XH2 = 0-0.9) and NH3 cracking ratios (γ = 0-0.9) were measured at equivalence ratios of ϕ = 0.7-1.7 and normal temperature/pressure (Tu = 298 K, Pu = 0.1 MPa) using the spherical constant-volume combustion approach. By comparing the change of instability evaluation parameters with increasing H2 content, it can be inferred that the more wrinkles caused by the increase of H2 concentration are mainly due to the enhancement of hydrodynamic instability caused by the decreasing flame thickness, and the mixtures with H2 addition are more prone to flame instability than those with partially dissociated NH3. The results of the measured and predicted SL show that the partially dissociated NH3 in NH3/DME/Air mixtures can promote combustion to a higher extent than adding H2 directly due to the more H2 produced as γ = XH2, and the degree is more serious with the increase of H2 content. The results of decoupling thermal effect and chemical effect show that SL is mainly dominated by the chemical effect. Compared to the mixtures with H2 addition, the mixtures with partially dissociated NH3 have a stronger promoting effect on chemical effect, while a weaker effect on thermal effect. In addition, the combustion processes of these two kinds of mixtures are similar through sensitivity and reaction pathways analysis.
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