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Flame structure of single aluminum droplets burning in hot steam-dominated flows 在热蒸汽主导流中燃烧的单个铝液滴的火焰结构
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-11 DOI: 10.1016/j.combustflame.2024.113838
Zhiyong Wu , Can Ruan , Yue Qiu , Mehdi Stiti , Shijie Xu , Niklas Jüngst , Edouard Berrocal , Marcus Aldén , Xue-Song Bai , Zhongshan Li
In this work, a specially designed experimental setup is employed to study the ignition and combustion of single aluminum droplets in hot steam-dominated flows. The transient burning behaviors of Al droplets of different sizes are characterized by simultaneously visualizing the flame incandescence and droplet shadowgraphs with two high-speed cameras at high magnification. The combustion process can be described in three stages: Al ignition and droplet generation, droplet evaporation and flame development, and steady combustion. During the steady combustion stage, a bright flame sheet, characterized by a narrow layer of dense nano-micron-sized alumina droplets, encapsulates the Al droplet core. The flame sheet composed of alumina droplets is located on a stagnation plane where the radial velocities relative to the droplet core are close to zero. The standoff ratio is around two, and it slightly decreases with the droplet size and increases with the oxygen content in the ambient gas. The thickness of the flame sheet (the alumina particle layer) is analyzed using Abel inversion of the projected profile of the flame incandescence and optical depth, revealing a thickness of about 50 μm for a burning droplet of a 550 μm diameter. Based on the shadowgraph images, the evaporation rate of the Al droplets is determined from the shrinking rate of the droplet projected area. Size-dependent evaporation rates are found to be related to different slip velocities, and the addition of oxygen to the oxidizer can significantly increase the evaporation rate. Finally, a conceptual model of a burning Al droplet in the steady combustion stage is proposed based on the experimental findings. The presented results provide novel datasets that contribute to model development and deepen the understanding of the physical and chemical processes involved in aluminum droplet combustion.
在这项工作中,我们采用了专门设计的实验装置来研究单个铝液滴在以热蒸汽为主的气流中的点火和燃烧。通过使用两台高倍率高速摄像机同时观察火焰炽焰和液滴阴影图,对不同尺寸铝液滴的瞬态燃烧行为进行了表征。燃烧过程可分为三个阶段:Al 点火和液滴生成、液滴蒸发和火焰发展以及稳定燃烧。在稳定燃烧阶段,以纳米级氧化铝液滴窄层为特征的明亮火焰片包裹着氧化铝液滴核心。由氧化铝液滴组成的火焰片位于一个相对于液滴核心的径向速度接近于零的停滞面上。对峙比约为 2,随着液滴大小的增大而略有减小,并随着环境气体中氧气含量的增加而增大。利用阿贝尔反演火焰炽热度和光学深度的投影轮廓,分析了火焰薄片(氧化铝颗粒层)的厚度,结果显示直径为 550 μm 的燃烧液滴的厚度约为 50 μm。根据阴影图图像,可通过液滴投影面积的收缩率确定铝液滴的蒸发率。研究发现,与尺寸相关的蒸发率与不同的滑移速度有关,在氧化剂中加入氧气可显著提高蒸发率。最后,根据实验结果提出了一个处于稳定燃烧阶段的燃烧铝液滴的概念模型。所展示的结果提供了新的数据集,有助于模型的开发,并加深了对铝液滴燃烧所涉及的物理和化学过程的理解。
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引用次数: 0
Computational investigation on the formation of liquid-fueled oblique detonation waves 液体燃料斜向爆轰波形成的计算研究
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-10 DOI: 10.1016/j.combustflame.2024.113839
Wenhao Wang , Zongmin Hu , Peng Zhang
Utilizing a two-phase supersonic chemically reacting flow solver with the Eulerian-Lagrangian method implemented in OpenFOAM, this study computationally investigates the formation of liquid-fueled oblique detonation waves (ODWs) within a pre-injection oblique detonation wave engine operating at an altitude of 30 km and a velocity of Mach 9. The inflow undergoes two-stage 12.5° compression, followed by uniform mixing with randomly distributed n-heptane droplets before entering the combustor. The study examines the effects of droplet breakup models, gas-liquid ratios, and on-wedge strips on the ODW formation. Results indicate that under the pure-droplet condition, the ODW fails to form within the combustor, irrespective of the breakup models used. However, increasing the proportion of n-heptane vapor in the fuel/air mixture facilitates the ODW formation, because the n-heptane vapor rapidly participates in the gaseous reactions, producing heat and accelerating the transition from low- to intermediate-temperature chemistry. Additionally, the presence of on-wedge strips enhances ODW formation by inducing a bow shock wave within the combustor, which significantly increases the temperature, directly triggering intermediate-temperature chemistry and subsequent heat-release reactions, thereby facilitating the formation of ODW.
本研究利用 OpenFOAM 中采用欧拉-拉格朗日方法的两相超音速化学反应流求解器,计算研究了在高度为 30 千米、速度为 9 马赫的预喷射斜爆轰波发动机内形成的液体燃料斜爆轰波(ODW)。流入气流经过两级 12.5° 压缩,然后与随机分布的正庚烷液滴均匀混合,最后进入燃烧器。研究考察了液滴破裂模型、气液比和边条对 ODW 形成的影响。结果表明,在纯液滴条件下,无论使用何种破裂模型,ODW 都无法在燃烧器内形成。然而,增加燃料/空气混合物中正庚烷蒸汽的比例会促进 ODW 的形成,因为正庚烷蒸汽会迅速参与气态反应,产生热量并加速从低温化学反应到中温化学反应的转变。此外,楔形条带的存在通过在燃烧器内引发弓形冲击波来增强 ODW 的形成,弓形冲击波会显著提高温度,直接引发中温化学反应和随后的热释放反应,从而促进 ODW 的形成。
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引用次数: 0
Features of lean premixed flame stabilized on a bluff-body with different temperature magnitude 在不同温度幅度的崖体上稳定的贫油预混火焰的特征
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-09 DOI: 10.1016/j.combustflame.2024.113840
Siqi Cai , Wenquan Yang , Lang Li, Jianlong Wan
The bluff-body is widely employed to improve the performance of the lean premixed combustion LPC which has advantages of high efficiency and low pollutant emissions. To further improve the LPC performance stabilized on the bluff-body, the effect of the bluff-body temperature on the lean premixed flame LPF feature near the flammability limit is studied here. The bluff-body temperature is controlled by the electrically heated rod or cooling water, and its values are set as ∼300 K (CB), naturally heat-conducting condition (NHB), 600 K (HB-600), and 900 K (HB-900), respectively. The experimental results show that the flammability limits and LPF behaviors in the case of CB and NHB are nearly the same because of the insignificant difference in the bluff-body temperature magnitude between them. The flammability limit can be significantly extended when the bluff-body temperature is heated to 900 K. Unexpectedly, the stable residual flame appears at the near-limit condition in the case of HB-900. It is the first time to observe the stable residual flame in the case of the fuel of Lewis number Le≈1.0. Then, the flame structures in the case of NHB, HB-600, and HB-900 are revealed numerically. It is found that the fresh reactant arrives at the flame primarily via diffusion rather than convection. The pre-heating effect on the fresh reactants and heat-loss effect to the bluff-body are also evaluated quantitatively. In the case of NHB, the flame can be classified to the adiabatic zone and mixed zone. By contrast, in the case of HB-600 and HB-900, the flame can be classified to the adiabatic zone, excess reaction zone, and weak reaction zone. This study expands our understanding on improving the LPC performance via controlling the bluff-body temperature.
崖体被广泛用于改善贫油预混燃烧 LPC 的性能,它具有高效率和低污染排放的优点。为了进一步提高稳定在崖体上的 LPC 性能,本文研究了崖体温度对可燃极限附近贫油预混火焰 LPF 特性的影响。崖体温度由电热棒或冷却水控制,其值分别设定为 300 K(CB)、自然导热条件(NHB)、600 K(HB-600)和 900 K(HB-900)。实验结果表明,CB 和 NHB 的可燃极限和 LPF 行为几乎相同,这是因为它们的崖体温度大小差异不大。令人意外的是,HB-900 在接近极限的条件下出现了稳定的残焰。这是首次在路易斯数 Le≈1.0 的燃料中观察到稳定残焰。然后,用数值方法揭示了 NHB、HB-600 和 HB-900 的火焰结构。研究发现,新鲜反应物主要通过扩散而非对流到达火焰。此外,还定量评估了新鲜反应物的预热效果和崖体的热损失效果。对于 NHB,火焰可分为绝热区和混合区。相比之下,HB-600 和 HB-900 的火焰可分为绝热区、过量反应区和弱反应区。这项研究拓展了我们对通过控制崖体温度改善 LPC 性能的理解。
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引用次数: 0
A hydrogen deflagration-jet flame coupled behavior in a ventilated confined space: Effects of ventilation area and leakage duration 通风密闭空间中的氢爆燃-喷射火焰耦合行为:通风面积和泄漏持续时间的影响
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-09 DOI: 10.1016/j.combustflame.2024.113842
Hongsheng Ma , Changjian Wang , Yang Li , Tao Du , Quan Li
Non-uniform hydrogen deflagrations were experimentally conducted in a ceiling ventilated chamber considering the effects of ventilation area Av and leakage duration tig. Two new coupled flame behaviors are observed. The first type of coupled flame structure involves the non-growing conical flame bubbles and jet flames, while the second type involves the growing ellipsoid flame bubbles and jet flames. A decrease in Av or an increase in tig promotes the evolution of first type of coupled flame behavior into the second type. The horizontal propagation of deflagration flames can be divided into three typical stages and the horizontal flame front undergoes a gradual decrease in speed and then a slight acceleration. The overpressure transient exhibits a double peak structure in under-ventilated cases. The overpressure peak P1 is induced by the coupled upward propagation of jet flames and initial flame bubbles. The overpressure peak P2 is related to the coupled flame behavior involving jet flame combustion and flame bubble expansion. The maximum overpressure and maximum pressure rise rate show a sharp upward trend as the first type of coupled flame structure evolves into the second type.
考虑到通风面积 Av 和泄漏持续时间 tig 的影响,在天花板通风室内进行了非均匀氢爆燃实验。观察到两种新的耦合火焰行为。第一种耦合火焰结构涉及不生长的锥形火焰气泡和喷射火焰,第二种耦合火焰结构涉及生长的椭圆形火焰气泡和喷射火焰。Av 值的降低或 tig 值的增加会促使第一种耦合火焰行为演变为第二种耦合火焰行为。爆燃火焰的水平传播可分为三个典型阶段,水平火焰前沿的速度逐渐下降,然后略有加速。在通风不足的情况下,过压瞬态呈现双峰结构。过压峰值 P1 是由喷射火焰和初始火焰气泡的耦合向上传播引起的。过压峰 P2 与喷射火焰燃烧和火焰气泡膨胀的耦合火焰行为有关。当第一种耦合火焰结构演变为第二种耦合火焰结构时,最大超压和最大压力上升率呈急剧上升趋势。
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引用次数: 0
Numerical sensitivity analysis of HTPB counterflow combustion using neural networks 利用神经网络对 HTPB 逆流燃烧进行数值敏感性分析
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-08 DOI: 10.1016/j.combustflame.2024.113829
Brian T. Bojko , Clayton M. Geipel , Brian T. Fisher , David A. Kessler
Solid fuel combustion requires pyrolysis gases to burn near its surface to provide enough heat feedback to decompose the solid and continue to provide the volatile gases required to sustain combustion. This coupled process defines the difficulty in sustaining solid fuel combustion in a variety of propulsion environments and necessitates a fundamental understanding of the physical processes in order to drive system design. This study explores the combustion of hydroxyl-terminated polybutadiene (HTPB) in a counterflow diffusion flame burner with 50% and 100% oxygen content and compares the regression rate and flame standoff to experimental data. A sensitivity analysis is pursued to identify the model parameters that need improvement and to help guide the next campaign of experiments. Neural networks are developed in a compact way as a means of providing quantitative results on the sensitivity of input parameters. Then a fully connected, deeper neural network is trained on the input parameters – oxidizer mole fraction, solid fuel heat of formation, pre-exponential factor of pyrolysis Arrhenius rate, molecular weight of pyrolysis species, oxidizer mass flux, separation distance, and the oxidizer temperature, – and shown to predict output variables – regression rate and flame standoff – within 90% and 95% accuracy respectively. This network is then used to create millions of data points with an overlapping parameter space for further statistical analysis and improvement of model parameters. In all, the data analysis presented using a neural network approach will help drive the design of experiments and is shown to increase the accuracy of the model in comparison to experimental measurements.
固体燃料燃烧需要热解气体在其表面附近燃烧,以提供足够的热反馈来分解固体,并继续提供维持燃烧所需的挥发性气体。这种耦合过程决定了在各种推进环境中维持固体燃料燃烧的难度,因此有必要从根本上了解物理过程,以推动系统设计。本研究探讨了羟基封端聚丁二烯(HTPB)在氧气含量为 50% 和 100% 的逆流扩散火焰燃烧器中的燃烧情况,并将回归率和火焰间距与实验数据进行了比较。通过敏感性分析,确定了需要改进的模型参数,并为下一步实验提供了指导。神经网络以一种紧凑的方式开发,作为提供输入参数敏感性定量结果的一种手段。然后,对输入参数(氧化剂摩尔分数、固体燃料形成热、热解阿伦尼乌斯速率的前指数因子、热解物种的分子量、氧化剂质量通量、分离距离和氧化剂温度)进行全连接的深度神经网络训练,结果表明,对输出变量(回归率和火焰间距)的预测准确率分别达到 90% 和 95%。然后,利用该网络创建具有重叠参数空间的数百万个数据点,用于进一步统计分析和改进模型参数。总之,利用神经网络方法进行的数据分析将有助于推动实验设计,并显示与实验测量结果相比,模型的准确性有所提高。
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引用次数: 0
A numerical study of internal transport in oxidizing liquid core–shell iron particles 氧化液体核壳铁粒子内部传输的数值研究
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-07 DOI: 10.1016/j.combustflame.2024.113826
Leon C. Thijs , Marie-Aline Van Ende , Jeroen A. van Oijen , Philip de Goey , XiaoCheng Mi
In an effort to improve the understanding of the rate-limiting mechanisms in liquid iron particle combustion, this study investigates the impact of internal transport within a core–shell structure. The two-dimensional axisymmetric transient continuum model as presented in previous publication (Thijs et al., 2023) is extended, such that the boundary layer between the particle and the gas, surface processes at the particle–gas interface, as well as the internal oxide layer within the particle, considering the transport of reactive O and Fe ions, are resolved. Information from the equilibrium phase diagram, which is included as supplementary data, is used to determine oxidation rate of the particle. The study reveals that finite-rate internal transport significantly alters the temperature evolution compared to models assuming infinitely fast transport. At elevated oxygen concentrations, internal transport becomes rate-limiting, restricting the maximum particle temperature. The core–shell assumption leads to a higher local oxidation degree at the particle–gas interface than the average in the particle, reducing the overall oxygen consumption rate. The maximum particle temperature is reached when heat loss exceeds heat release. Although internal transport limits the maximum temperature, the initial heating rate remains overestimated, suggesting that the initial phase is not solely limited by external oxygen diffusion, and the L2-gas surface is not at thermodynamic equilibrium. The model does not account for the particle size effect on maximum temperature as observed in some experiments. A hypothetical explanation is that internal convection, more pronounced in larger particles, may reduce the internal transport limitation, leading to higher maximum temperatures in larger particles.
Novelty and significance
This study advances the understanding of oxidation rate-limiting mechanisms in liquid iron particle combustion by numerically investigating the impact of internal transport within a core–shell structure. By using a two-dimensional axisymmetric transient continuum model, the research reveals that finite-rate internal transport significantly affects temperature evolution of an oxidizing micron-sized iron particle, particularly at elevated oxygen concentrations where it becomes rate-limiting. The findings demonstrate that a finite-rate internal transport leads to a higher local oxidation degree at the particle–gas interface, reducing the oxygen consumption rates. The study highlights that finite-rate internal transport limits the maximum particle temperature at elevated oxygen concentrations, a trend observed in isolated iron particle combustion experiments. Furthermore, this study provides a hypothetical explanation for the experimentally observed particle size effects on the maximum particle temperature, emphasizing the role of internal convection in larger particles
为了更好地理解液态铁粒子燃烧的限速机制,本研究调查了核壳结构内部传输的影响。对之前发表的论文(Thijs 等人,2023 年)中提出的二维轴对称瞬态连续模型进行了扩展,从而解决了颗粒与气体之间的边界层、颗粒与气体界面的表面过程以及颗粒内部的氧化层(考虑到活性 O 和铁离子的传输)问题。作为补充数据的平衡相图信息用于确定粒子的氧化率。研究表明,与假设无限快传输的模型相比,有限速率内部传输会显著改变温度的演变。在氧气浓度升高时,内部传输成为速率限制,从而限制了颗粒的最高温度。核壳假设导致颗粒与气体界面的局部氧化度高于颗粒内的平均氧化度,从而降低了整体氧气消耗率。当热量损失超过热量释放时,就会达到颗粒的最高温度。虽然内部传输限制了最高温度,但初始加热速率仍然被高估,这表明初始阶段并不完全受外部氧气扩散的限制,L2-气体表面也没有达到热力学平衡。该模型没有解释某些实验中观察到的颗粒大小对最高温度的影响。一种假设的解释是,内部对流在较大颗粒中更为明显,可能会减少内部传输限制,从而导致较大颗粒中的最高温度升高。新颖性和意义这项研究通过数值研究核壳结构内部传输的影响,推进了对液态铁颗粒燃烧中氧化率限制机制的理解。通过使用二维轴对称瞬态连续模型,研究揭示了有限速率内部传输会显著影响氧化微米级铁粒子的温度演变,尤其是在氧气浓度升高时,内部传输会成为速率限制因素。研究结果表明,有限速率内部传输会导致颗粒与气体界面的局部氧化程度升高,从而降低耗氧率。研究强调,有限速率内部传输限制了氧气浓度升高时颗粒的最高温度,这是在孤立铁颗粒燃烧实验中观察到的趋势。此外,这项研究还为实验观察到的颗粒大小对最大颗粒温度的影响提供了一种假设性解释,强调了内部对流在较大颗粒中的作用。
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引用次数: 0
Accurately measuring slowly propagating flame speeds: Application to ammonia/air flames 精确测量缓慢传播的火焰速度:氨/空气火焰的应用
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-06 DOI: 10.1016/j.combustflame.2024.113807
Joel Mathew, Justin K. Tavares, Jagannath Jayachandran
Environmental concerns have driven the development of alternative fuels and refrigerant working fluids with low global warming potential. Ammonia (NH3) is a potential zero-carbon fuel, while hydrofluorocarbons (HFCs) like R-32 and R-1234yf are being adopted as refrigerants. When mixed with air, these compounds can sustain slowly propagating flames with laminar flame speeds less than 10 cm/s. Unlike typical hydrocarbon-fueled flames, these slow flames are influenced by buoyancy-induced flow and radiation heat loss. In this study, we experimentally investigate the flame speeds of NH3/air mixtures using the constant-pressure spherically expanding flame method, while circumventing gravity-induced natural convection, and account for radiation-induced inward flow. To mitigate buoyant convection, a low-cost drop tower was built and used to study slow spherically expanding flames in free fall. A computational model (SRADIF) is utilized that combines thermodynamic equilibrium and finite rate optically thin limit radiation heat loss calculations to estimate the inward flow. The developed methodology is utilized to investigate slowly propagating NH3/air flames over a range of equivalence ratios. A systematic approach was undertaken to understand and quantify the errors that could arise when deriving the laminar flame speed. It was found that attempting to study slowly propagating flames in a static configuration, as opposed to in free fall, results in large differences in flame dynamics and subsequently all derived quantities. It is necessary to study slowly propagating flames in free-fall. Additionally, using experimental data that has not been corrected for radiation-induced flow leads to large errors in all derived quantities. Furthermore, direct comparisons of experimental measurements and detailed flame simulations are found to be necessary to determine if existing extrapolation approaches are applicable to these slowly propagating flames, which are challenging to study.
对环境的关注推动了全球变暖潜能值较低的替代燃料和制冷工作液的开发。氨(NH3)是一种潜在的零碳燃料,而 R-32 和 R-1234yf 等氢氟碳化物(HFC)正被用作制冷剂。当与空气混合时,这些化合物可以维持层燃速度小于 10 厘米/秒的缓慢传播火焰。与典型的碳氢化合物燃料火焰不同,这些慢速火焰受到浮力引起的流动和辐射热损失的影响。在本研究中,我们使用恒压球形膨胀火焰法对 NH3/空气混合物的火焰速度进行了实验研究,同时规避了重力引起的自然对流,并考虑了辐射引起的内向流动。为了减轻浮力对流,我们建造了一个低成本的落塔,用于研究自由落体中缓慢的球形膨胀火焰。利用计算模型(SRADIF)结合热力学平衡和有限速率光学薄极限辐射热损失计算来估算内流。所开发的方法可用于研究在一定当量比范围内缓慢传播的 NH3/空气火焰。我们采用了一种系统方法来了解和量化在推导层流火焰速度时可能产生的误差。研究发现,试图研究静态配置下的缓慢传播火焰,而不是自由落体状态下的缓慢传播火焰,会导致火焰动力学的巨大差异,进而导致所有推导出的量的巨大差异。因此有必要研究自由落体状态下缓慢传播的火焰。此外,使用未经辐射诱导流校正的实验数据会导致所有推导量出现较大误差。此外,有必要对实验测量结果和详细的火焰模拟结果进行直接比较,以确定现有的外推方法是否适用于这些缓慢传播的火焰,因为这些火焰的研究具有挑战性。
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引用次数: 0
Direct combustion noise: Nearfield and non-compactness influences on pressure–heat release coherence 直接燃烧噪声:近场和非紧凑性对压力-热量释放一致性的影响
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-05 DOI: 10.1016/j.combustflame.2024.113811
Sungyoung Ha, Tim Lieuwen
There are several mechanisms through which turbulent flames produce sound. In low Mach number, unconfined flows, direct combustion noise – i.e., unsteady gas expansion generated by heat release fluctuations – is known to be a dominant contributor. This study is motivated by the fact that in the farfield, the coherence between spatially integrated heat release fluctuations from acoustically compact flames and direct combustion noise is unity. This suggests that the role of direct combustion noise relative to other sources can be ascertained from the value of the coherence. However, in practice it is difficult to fully satisfy the requirements to achieve a unity coherence, even in cases where direct combustion noise is the dominant noise source. This paper explores the contribution of noncompactness and nearfield effects on coherence. For the noncompactness part, while it is often the case that flames are small relative to a wavelength, they are never infinitesimally small. For the nearfield aspect, it is often not possible or practical to obtain farfield measurements, particularly in confined environments. This paper presents calculations that quantify how these noncompactness and nearfield effects influence coherence values. These calculations provide guidance on frequency ranges over which direct combustion noise will lead to near-unity coherence values, as well as required distances and optimal angles for acoustic instrumentation.
Novelty and significance statement
This study presents a theoretical study on the coherence between heat release rate and acoustic pressure fluctuations, which has been mostly overlooked in prior literature. To the extent of the author’s knowledge, this is the first attempt that identify and investigate the inconsistencies between traditional theory and experimental literature on coherence. Results have implications for our previous understanding of the relationship between the heat release rate fluctuations and direct noise, aiding in future studies on combustion noise.
湍流火焰产生声音的机制有多种。众所周知,在低马赫数、无约束流动中,直接燃烧噪声(即由热释放波动产生的不稳定气体膨胀)是主要的影响因素。这项研究的动机是,在远场,声学紧凑火焰的空间综合热释放波动与直接燃烧噪声之间的一致性是统一的。这表明,直接燃烧噪声相对于其他声源的作用可以通过相干值来确定。然而,在实践中,即使在直接燃烧噪声是主要噪声源的情况下,也很难完全满足达到统一相干性的要求。本文探讨了非紧凑性和近场效应对相干性的影响。就非紧凑性而言,虽然火焰相对于波长来说通常很小,但它们永远不会小到无限小。在近场方面,通常不可能或无法获得远场测量结果,尤其是在密闭环境中。本文通过计算量化了这些非紧凑性和近场效应对相干值的影响。这些计算为直接燃烧噪声将导致接近统一相干值的频率范围,以及声学仪器所需的距离和最佳角度提供了指导。新颖性和重要性声明本研究提出了一项关于热释放率和声压波动之间相干性的理论研究,这在之前的文献中大多被忽视。就作者所知,这是首次尝试识别和研究相干性传统理论与实验文献之间的不一致性。研究结果对我们之前对热释放率波动与直接噪声之间关系的理解有一定影响,有助于今后对燃烧噪声的研究。
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引用次数: 0
Thermal oxidation, ignition, and combustion characterization of AP-, LP-, and KN- coated multi-metal composite powders in Air/H2O environments AP、LP 和 KN 涂层多金属复合粉末在空气/H2O 环境中的热氧化、点火和燃烧特性分析
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-05 DOI: 10.1016/j.combustflame.2024.113808
Wenke Zhang , Peihui Xu , Daolun Liang , Jianzhong Liu
Studying the ignition and combustion performances of modified aluminum-based metallic fuels in variable oxidizing atmospheres is highly important for large-scale space exploration. In this study, Al–B–Mg multi-metal composite powders (MMP) were prepared using the mechanical ball-milling method.It was coated respectively by ammonium perchlorate (AP), lithium perchlorate (LP), and potassium nitrate (KN) to obtain modified multi-metal composite powder fuels (AP@MMP, LP@MMP, and KN@MMP, respectively) by a recrystallization method. The samples were characterized and their thermal oxidation, ignition and combustion processes were investigated through a TG and laser-ignition experiment under Air/H2O environments. The results show that the MMP samples can potentially be called pure aluminum substitutes. All three samples exhibit fast ignition characteristics with ignition delay times of 2.95–6.75 ms in air. AP@MMP exhibits the highest ignition speed. The thermal oxidation, ignition, and combustion properties of all samples decayed with increasing water content in the atmosphere (Air→Air+H2O→H2O). AP@MMP exhibits a significantly more intense and stable combustion overall than LP@MMP and KN@MMP. This study expands the direction and application range of aluminum-based composite metal fuels, guiding their applications in Air/H2O environments.
研究改性铝基金属燃料在可变氧化气氛中的点火和燃烧性能对于大规模太空探索非常重要。本研究采用机械球磨法制备了铝-B-镁多金属复合粉末(MMP),并分别在其表面包覆了高氯酸铵(AP)、高氯酸锂(LP)和硝酸钾(KN),通过重结晶法获得了改性多金属复合粉末燃料(分别为AP@MMP、LP@MMP和KN@MMP)。通过气相色谱和激光点火实验对样品进行了表征,并研究了它们在空气/H2O 环境下的热氧化、点火和燃烧过程。结果表明,MMP 样品有可能被称为纯铝替代品。这三种样品都具有快速点火特性,在空气中的点火延迟时间为 2.95-6.75 毫秒。AP@MMP 的点火速度最快。所有样品的热氧化、点火和燃烧特性都随着空气中含水量的增加而降低(空气→空气+H2O→H2O)。与 LP@MMP 和 KN@MMP 相比,AP@MMP 的燃烧强度和稳定性明显更高。这项研究拓展了铝基复合金属燃料的发展方向和应用范围,引导其在空气/H2O 环境中的应用。
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引用次数: 0
Effect of cerium trifluoride on combustion properties of nano-aluminum powder 三氟化铈对纳米铝粉燃烧特性的影响
IF 5.8 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-11-05 DOI: 10.1016/j.combustflame.2024.113831
Yajun Wang, Wenyu Li, Ruihua Liu, Zhengliang Deng, Qiang Gan
To investigate the influence of cerium trifluoride (CeF3) on the combustion performance of nano aluminum powder (n-Al), different mass fractions of CeF3 were physically mixed into the n-Al powder. Research results show that CeF3 can significantly increase the main exothermic heat of n-Al powder. When the CeF3 content was 10 %, the heat release reached 9579.90 J·g‒1. However, as the CeF3 content increased, the heat release of the sample decreased. Thermal analysis results of Al/CeF3 and Al/CeO2 infer that this was due to the action of CeO2 generated by pre-ignition reaction for Al/CeF3–15. The presence of CeO2 inhibited the reaction degree of Al, thereby reducing the heat release. Meanwhile, as the proportion of CeF3 increased, the peak temperature of the main reaction exothermic peak was delayed, and more energy input was required for the oxidation of n-Al powder. Combustion experiments show that the addition of CeF3 greatly shortened the combustion time of n-Al powder, with the shortest time being 4.43 s. In addition, due to the excellent storage and release oxygen capability of CeO2, multiple micro-explosions occurred in the composite material during combustion.
为了研究三氟化铈(CeF3)对纳米铝粉(n-Al)燃烧性能的影响,将不同质量分数的 CeF3 物理混合到 n-Al 粉中。研究结果表明,CeF3 能显著提高 n-Al 粉末的主放热。当 CeF3 含量为 10 % 时,放热量达到 9579.90 J-g-1。然而,随着 CeF3 含量的增加,样品的放热量降低了。Al/CeF3 和 Al/CeO2 的热分析结果推断,这是由于 Al/CeF3-15 预点火反应产生的 CeO2 的作用。CeO2 的存在抑制了 Al 的反应程度,从而减少了热量的释放。同时,随着 CeF3 比例的增加,主反应放热峰的峰值温度推迟,正铝粉的氧化需要更多的能量输入。燃烧实验表明,CeF3 的加入大大缩短了 n-Al 粉末的燃烧时间,最短的时间为 4.43 秒。此外,由于 CeO2 具有优异的储氧和释氧能力,复合材料在燃烧过程中会发生多次微爆炸。
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Combustion and Flame
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