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Shale Characterization Methods Using XRD, CEC, and LSM: Experimental Findings 利用 XRD、CEC 和 LSM 表征页岩的方法:实验结果
Pub Date : 2024-01-23 DOI: 10.23880/ppej-16000380
Alagoz E
Shale characterization is essential for understanding its potential as a hydrocarbon reservoir and for optimizing hydraulic fracturing operations. In this study, we evaluate the effectiveness of three methods for shale characterization: X-ray diffraction (XRD), cation exchange capacity (CEC), and linear swell meter (LSM). The study was conducted on a set of shale samples from a specific location. The samples were analyzed using XRD to determine their mineralogy, CEC to measure their ion exchange capacity, and LSM to assess their swelling properties. The results indicate that Clay stabilizers and KCl salt together perform much better. The concentrations of different additives can have a positive/negative effect on swelling. CEC values can be determined for each formation with the statistical method determined by using XRD results. Overall, the study highlights the potential of using a combination of XRD, CEC, and LSM for comprehensive shale characterization.
页岩表征对于了解其作为碳氢化合物储层的潜力以及优化水力压裂作业至关重要。在这项研究中,我们评估了三种页岩表征方法的有效性:X 射线衍射 (XRD)、阳离子交换容量 (CEC) 和线性膨胀仪 (LSM)。这项研究是针对特定地点的一组页岩样本进行的。使用 XRD 对样本进行了分析,以确定其矿物学性质;使用 CEC 测定其离子交换能力;使用 LSM 评估其膨胀特性。结果表明,粘土稳定剂和氯化钾盐一起使用效果更好。不同添加剂的浓度会对膨胀产生积极或消极的影响。通过使用 XRD 结果确定的统计方法,可以确定每个地层的 CEC 值。总之,该研究强调了结合使用 XRD、CEC 和 LSM 进行页岩综合表征的潜力。
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引用次数: 0
Combinational CO2 and Polymer Injections for EOR and CO2 Storage in Depleted Reservoirs: A Mini Review on Laboratory, Simulation and Field Studies 在枯竭储层中联合注入二氧化碳和聚合物进行 EOR 和二氧化碳封存:实验室、模拟和现场研究综述
Pub Date : 2024-01-23 DOI: 10.23880/ppej-16000382
Livinus A
Water-alternating-gas is commonly used in most of the existing enhanced oil recovery (EOR) projects in the world to regulate gas mobility and reduce fingering problems. Unfortunately, the expected recovery factor from most of the fields could not be attained with such EOR method. Development strategies of mature oil fields during the energy transition period may therefore involve the combination of polymer and CO2 injections to achieve incremental oil recovery and at the same time provide longterm geological storage solution for carbon. This paper therefore presents overview of the processes of polymer and CO2 floodings, and then highlights the overall benefits to be derived from the combination of CO2 and polymer flooding techniques in depleted hydrocarbon reservoirs, especially oil reservoirs. Reviews on studies related to the combinational CO2 and polymer injections are then carried out. Highlights of areas of the combinational CO2 and polymer injections needing more attention are also mentioned.
世界上大多数现有的提高石油采收率(EOR)项目都普遍采用水替代气体的方法,以调节气体流动性,减少指井问题。遗憾的是,大多数油田无法通过这种 EOR 方法达到预期的采收率。因此,在能源转型期,成熟油田的开发战略可能涉及聚合物和二氧化碳注入的结合,以实现增量采油,同时提供长期的碳地质封存解决方案。因此,本文概述了聚合物和二氧化碳注水的过程,然后强调了在枯竭碳氢化合物储层(尤其是油藏)中结合使用二氧化碳和聚合物注水技术的整体效益。然后对二氧化碳和聚合物联合注入的相关研究进行了综述。此外,还重点介绍了二氧化碳和聚合物联合注入技术需要更多关注的领域。
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引用次数: 0
How Oil and Gas Companies can derive C-Factors in the API RP 14E Erosional Velocity Models for their ‘Clean Service’ Pipelines 石油和天然气公司如何在 API RP 14E 侵蚀速度模型中为其 "清洁服务 "管道推导出 C 因子
Pub Date : 2023-10-05 DOI: 10.23880/ppej-16000364
Livinus A
In designing pipeline facilities for production and transportation of oil, hydrocarbon gases or non-hydrocarbon gases – CO2 and H2 , consideration is given to pipeline integrity, flow assurance, operation and health/safety issues. Erosion-corrosion of the inner pipeline wall and/or high-pressure losses is of great concern. For many years now, many oil and gas field operators have adopted the America Petroleum Institute recommended practice 14E (API RP 14E) equation to estimate the erosional velocity. Unfortunately, the C-factor (which is an empirical constant) in the API RP 14E equation has been generalized to all field conditions. In addition, there is no concrete scientific evidence behind the basis of its formulation, and various values have been adopted based on field and laboratory experiences. In this work, we present how oil and gas companies could formulate safer erosional velocity models for their sand free or ‘clean service’ pipelines, based on the velocities calculated for the equilibrium flow rate (that is, the intersection of vertical lift performance (VLP) and inflow performance relationship (IPR)). The developed erosional velocity models can be applied, and compared with in-house correlations, for erosional velocity predictions
在设计用于生产和运输石油、碳氢化合物气体或非碳氢化合物气体(二氧化碳和 H2)的管道设施时,需要考虑管道的完整性、流量保证、运行和健康/安全问题。管道内壁的腐蚀和/或高压损失是一个非常值得关注的问题。多年来,许多油气田运营商都采用美国石油学会推荐实践 14E (API RP 14E)方程来估算侵蚀速度。遗憾的是,API RP 14E 公式中的 C 因子(这是一个经验常数)已被普遍应用于所有油田条件。此外,其计算公式背后并没有具体的科学依据,人们根据现场和实验室经验采用了不同的数值。在这项工作中,我们介绍了油气公司如何根据平衡流速(即垂直提升性能(VLP)和流入性能关系(IPR)的交叉点)计算出的速度,为其无砂或 "清洁服务 "管道制定更安全的侵蚀速度模型。开发的侵蚀速度模型可用于侵蚀速度预测,并与内部相关数据进行比较
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引用次数: 0
Prediction of Vapor Liquid Equilibrium of Binary CO2-Contained Mixtures for Carbon Capture and Sequestration using Artificial Intelligence 利用人工智能预测用于碳捕集与封存的含二氧化碳二元混合物的汽液平衡
Pub Date : 2023-10-05 DOI: 10.23880/ppej-16000365
Rostami S
This research provides a comprehensive prediction using machine learning to predict vapor-liquid-equilibrium for CO2 - contained binary mixtures for carbon capture and sequestration projects. One of the best practices to lower the CO2 emissions in the atmosphere is Carbon Capture and Sequestration including capturing carbon dioxide from atmosphere and injecting it into the underground geological formations. One of the key elements in a successful project is to accurately model the phase equilibria which provides us on how the fluid or mixtures of the injected fluids will behave in certain pressures and temperatures underground. In this regard, different machine learning models have been implemented for the prediction. The data set consists experimental results of five different binary mixtures with CO2 presents in all of them. Then the results were compared to each other and the one with the highest accuracy was selected for each mixture. Peng Robinson equation of state was also used and compared with machine learning results. Finally, both machine learning and thermodynamic models were compared to experimental results to determine the accuracy. It was found out that thermodynamic model was unable to predict results for many data points while machine learning could predict results for most of the data points. Also, the accuracy of machine learning models was greatly better than thermodynamic model. In this research, a large data set including 748 data points is used on which machine learning models can be trained more accurate. Also, as a single machine learning model cannot predict accurate results for all mixtures, several models have been run on each mixture, and the one with the highest accuracy was selected for each CO2 -contained binary mixture which to our knowledge, has been never implemented.
这项研究利用机器学习提供了一种全面的预测方法,用于预测碳捕集与封存项目所含二氧化碳二元混合物的汽液平衡。碳捕集与封存是降低大气中二氧化碳排放量的最佳方法之一,包括捕集大气中的二氧化碳并将其注入地下地质构造。一个成功项目的关键因素之一是建立准确的相平衡模型,该模型可帮助我们了解注入的流体或流体混合物在地下一定压力和温度下的表现。为此,我们采用了不同的机器学习模型进行预测。数据集包括五种不同二元混合物的实验结果,所有混合物中都含有二氧化碳。然后将结果相互比较,为每种混合物选出准确度最高的模型。此外,还使用了彭-罗宾逊状态方程,并将其与机器学习结果进行了比较。最后,将机器学习模型和热力学模型与实验结果进行比较,以确定其准确性。结果发现,热力学模型无法预测许多数据点的结果,而机器学习可以预测大多数数据点的结果。此外,机器学习模型的准确性也大大优于热力学模型。本研究使用了一个包括 748 个数据点的大型数据集,在该数据集上训练的机器学习模型可以更加准确。此外,由于单一的机器学习模型无法预测所有混合物的准确结果,因此对每种混合物都运行了多个模型,并为每种含二氧化碳的二元混合物选择了准确度最高的模型。
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引用次数: 0
Pressurization Characteristics and Proppants Transport of Pulse Jet Fracturing with CFD-DEM Coupling Method 利用 CFD-DEM 耦合方法研究脉冲喷射压裂的加压特性和支撑剂传输
Pub Date : 2023-10-05 DOI: 10.23880/ppej-16000366
Cai C
Hydraulic jet fracturing, which integrates hydraulic sand jet perforation and hydraulic fracturing, is widely used in the stimulation of low permeability reservoir. However, due to the complexity of the fluid-solid interaction, the effect of pressurization characteristics and proppants transport in the perforation hole are still unclear. Therefore, in this paper, the pressurization characteristics and proppants transport of pulse jet fracturing are investigated under different pressure amplitude, angular velocity, average pressure, nozzle diameter and perforation diameter with the CFD-DEM (Computational Fluid Dynamics and Discrete Element Method) coupled method. Results indicates that the effect of pressure amplitude, average pressure are positively related to the maximum velocity and maximum total pressure, while the effect of nozzle diameter is positively correlated with the maximum velocity, and the maximum total pressure has a relatively small effect. The effect of perforation diameter is negatively related to maximum velocity. It can be seen that pulsed jet fracturing can effectively relieve the large number of proppants blocking present around the perforated inlet of a single section of the pulse jet fracturing model (SPJFM). But when the proppants are of a certain size and the nozzle diameter is very small, it is difficult for the proppants to enter the perforation. And the smaller the diameter of the perforation, the less proppant enters the perforation, and some of the proppant appears in the annular section. By reasonably designing the optimal parameters, the pulsed jet can maximize the pressurization, helping optimize jet fracturing application parameters.
水力喷射压裂集水力射砂射孔和水力压裂于一体,被广泛应用于低渗透储层的开采。然而,由于流固相互作用的复杂性,射孔孔内增压特性和支撑剂运移的影响尚不明确。因此,本文采用CFD-DEM(计算流体力学与离散元法)耦合方法,研究了不同压力幅值、角速度、平均压力、喷嘴直径和射孔直径下脉冲射流压裂的增压特性和支撑剂运移。结果表明,压力振幅、平均压力的影响与最大速度和最大总压呈正相关,而喷嘴直径的影响与最大速度呈正相关,对最大总压的影响相对较小。穿孔直径的影响与最大速度呈负相关。可见,脉冲射流压裂可以有效地解除脉冲射流压裂模型(SPJFM)单段射孔进口周围存在的大量支撑剂堵塞。但当支撑剂达到一定大小且喷嘴直径很小时,支撑剂很难进入射孔。而射孔直径越小,进入射孔的支撑剂越少,部分支撑剂会出现在环形区域。通过合理设计最佳参数,脉冲射流可以最大限度地提高压力,有助于优化射流压裂应用参数。
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引用次数: 0
An Approach to Assess the Impact of Polyanionic Cellulose (PACLV) Polymer and Nanoparticles on Rheology and Filtration Control of Water-Based Muds 评估聚阴离子纤维素(PACLV)聚合物和纳米颗粒对水基泥流变性和过滤控制影响的方法
Pub Date : 2023-10-05 DOI: 10.23880/ppej-16000363
Adeyemi Ga
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引用次数: 0
Targeting Goal Synergies and Transnational Partnerships for Petro-Energy Sustainability in Africa 瞄准目标协同作用和跨国伙伴关系,促进非洲石油能源的可持续性
Pub Date : 2023-10-05 DOI: 10.23880/ppej-16000362
Ejenavi Ol
Sustainability goals integration in a petro-context could be considered irreconcilable. Harnessing SD goal synergies in the African petroleum sector may even be supremely problematic. Africa still grapples with a knotty mix of convoluted challenges, ranging from poverty, insecurity, drought, to extreme underdevelopment. Having contributed the least to the global climate dilemma, Africa still must bear the brunt of negative climate impacts, whilst shouldering its daunting chunk of climate adaptation and mitigation commitments. Moreover, a huge dependency on fuel imports, escalating debt profile and funding shortfalls, plague many countries at the subregional levels. In a relentless chronicle of woes, the region exhibits the highest energy deficiencies whilst contending with excruciatingly prohibitive petroleum importation costs soaring over $100 Billion USD annually. Similarly, Africa’s annual investment projections for energy are an estimated $190 billion USD. The implication is that, whereas the region has to achieve SD target obligations, its most credible means of optimising goal synergies, should be via an approach that targets energy sustainability, which remains an indispensable driver of most sustainability goals. To achieve this aim, a continental prioritization of regional partnerships is advocated to engender a sustainable petroleum sector. This is deemed crucial because of the considerable benefits the sector wields towards SDGs actualization and its relevance as a viable connector and pivot towards cleaner energy transition.
将可持续发展目标融入石油行业可能被认为是不可调和的。在非洲石油部门利用可持续发展目标的协同作用甚至可能是个大问题。非洲仍然面临着各种错综复杂的挑战,从贫困、不安全、干旱到极度不发达,不一而足。非洲对全球气候困境的贡献最小,但仍然必须首当其冲地承受气候的负面影响,同时承担起适应和减缓气候影响的巨大义务。此外,对燃料进口的巨大依赖、不断攀升的债务状况和资金短缺也困扰着许多次区域国家。在一系列无休止的困境中,该地区的能源缺口最大,同时每年的石油进口成本高达 1000 多亿美元,令人望而却步。同样,非洲每年的能源投资预计约为 1900 亿美元。这意味着,尽管该地区必须实现可持续发展目标义务,但其优化目标协同作用的最可靠手段应是针对能源可持续性的方法,而能源可持续性仍是大多数可持续发展目标不可或缺的驱动力。为实现这一目标,我们主张在非洲大陆优先建立地区合作伙伴关系,以促进石油部门的可持续发展。这被认为是至关重要的,因为石油部门对可持续发展目标的实现具有相当大的益处,而且是实现清洁能源转型的可行连接点和支点。
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引用次数: 0
Comparative Evaluation of the Feasibility of Utilizing the Bakken Formation Oil and Gas Field Produced Water for Extraction of Critical Minerals and Salts, with a Focus on the Inyan Kara Formation: An Analysis of Salinity and Infrastructure 利用巴肯地层油气田采出水提取关键矿物质和盐类的可行性比较评估,重点关注伊尼扬卡拉地层:盐度和基础设施分析
Pub Date : 2023-10-05 DOI: 10.23880/ppej-16000367
Jakaria Md
This study compares the salt concentration and mineral composition of water from the Bakken Formation and the Inyan Kara Formation to assess their suitability for salt/critical minerals extraction. The results reveal that the Bakken Formation exhibits significantly higher levels of dissolved solids, calcium, magnesium, and chloride compared to the Inyan Kara Formation, indicating its potential suitability for salt/critical elements extraction. Conversely, the Inyan Kara Formation water displays higher bicarbonate concentrations, which may limit its applicability in certain salt extraction processes. The Bakken Formation proves more viable for water production due to its existing oil and gas infrastructure and abundant produced water from active and abandoned oil wells. This availability of produced water wells reduces the cost of critical mineral extraction and presents opportunities for water reuse or critical minerals sale, generating additional revenue that could offset recycling and disposal costs. In contrast, the absence of water production wells in the Inyan Kara Formation hinders its economic feasibility for salt/mineral extraction. The Inyan Kara Formation has a higher volume of water, but its lower salt content limits its usefulness for some purposes, especially in the energy industry for recovering rare earth minerals. Considering the higher mineralization, the concentration of key ions, and the presence of water production infrastructure, the Bakken Formation emerges as a more favorable choice for critical mineral extraction. However, factors like environmental impact and extraction costs should be considered in determining the most suitable formation. Despite data limitations, the study utilizes a valuable database to identify regional variations in salt concentrations for critical mineral extraction.
这项研究比较了来自巴肯地层和伊尼扬卡拉地层的水的盐浓度和矿物成分,以评估它们是否适合提取盐/关键矿物。研究结果表明,巴肯地层的溶解固体、钙、镁和氯化物含量明显高于伊尼扬卡拉地层,这表明巴肯地层可能适合提取盐分/关键元素。相反,伊尼扬卡拉地层的水显示出较高的碳酸氢盐浓度,这可能会限制其在某些盐提取工艺中的适用性。巴肯地层现有的石油和天然气基础设施,以及活跃和废弃油井的大量产水,证明其更适合于水的生产。这种产水井的可用性降低了关键矿物的提取成本,并为水的再利用或关键矿物的销售提供了机会,从而产生额外的收入,可以抵消回收和处理成本。相比之下,伊尼扬卡拉地层没有产水井,阻碍了盐/矿物开采的经济可行性。伊尼扬卡拉地层的含水量较高,但含盐量较低,这限制了其在某些方面的用途,特别是在能源行业回收稀土矿物。考虑到较高的矿化度、关键离子的浓度以及水生产基础设施的存在,巴肯地层成为提取关键矿物的更有利选择。不过,在确定最合适的地层时,还应考虑环境影响和提取成本等因素。尽管数据有限,但这项研究利用了一个宝贵的数据库来确定关键矿物提取的盐浓度区域差异。
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引用次数: 0
Predictive Models for Oil in Place for Oil Rim Reservoirs in the Niger Delta Using Machine Learning Approach 使用机器学习方法预测尼日尔三角洲石油环形储藏的就地取油模型
Pub Date : 2023-07-20 DOI: 10.23880/ppej-16000361
Livinus A
One of the key factors that analysts consider when calculating the economics of oil field development is the amount of oil in place (OIP). Conventional methods used for its estimation have some features affecting their predictive capabilities and applications. In addition, Oil bidders have limited time to evaluate and rank reservoirs from complex and large reservoir data packages - which sometimes fees are paid for their access. In this study, data-driven machine learning models - artificial neural network (ANN), support vector regression (SVR) and multiple linear regression (MLR) were developed for quick estimation of OIP for oil rim reservoirs in the Niger Delta. The models were evaluated using statistical error tools, and the results showed reasonable predictions. The sensitivity analysis performed on the selected input parameters showed that areal extent has the greatest impact on the estimation of the OIP with 29.94 %, oil formation volume factor has 22.74 % impact, oil column thickness was 16.61 %, m-factor has 13.29 %, water saturation was 9.01 %, and lastly porosity has 8.38 %. Comparison with recovery factor surrogate models existing in open literature were also carried out. The newly developed models can be helpful for oil bidders in ranking and evaluation of oil rim reservoirs in the Niger Delta.
在计算油田开发的经济效益时,分析人员考虑的关键因素之一是原油储量(OIP)。用于估算的传统方法有一些特点会影响其预测能力和应用。此外,石油竞标者从复杂而庞大的油藏数据包中对油藏进行评估和排序的时间有限,有时还需要支付一定的费用。本研究开发了数据驱动的机器学习模型--人工神经网络 (ANN)、支持向量回归 (SVR) 和多元线性回归 (MLR),用于快速估算尼日尔三角洲油缘油藏的 OIP。使用统计误差工具对模型进行了评估,结果显示预测合理。对所选输入参数进行的敏感性分析表明,面积对 OIP 估值的影响最大(29.94%),油层体积因子的影响为 22.74%,油柱厚度为 16.61%,米因子为 13.29%,水饱和度为 9.01%,最后是孔隙度为 8.38%。此外,还与公开文献中已有的采收率代用模型进行了比较。新开发的模型有助于石油竞标者对尼日尔三角洲的油缘储层进行排序和评估。
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引用次数: 0
Improving the Accuracy of Experimental Hydrate Equilibrium Point Determination: A Mini-Review 提高实验水合物平衡点测定的准确性:综述
Pub Date : 2023-07-20 DOI: 10.23880/ppej-16000355
Aminnaji M
Reliable gas hydrate equilibrium data is necessary to assess the severity of hydrate problems in the oil and gas industry and successfully implement the benefit of hydrate technologies in different areas such as hydrate-based CO2 capture and storage. Furthermore, the hydrate equilibrium point prediction models rely on tuning experimental data. In this mini-review, various techniques for hydrate dissociation point (DP) measurement either in the presence or absence of liquid water phase are discussed to improve the accuracy of the measurement. While both Visual and non-visual techniques can be used to measure hydrate DP, the non-visual isochore procedure is the most common technique. The stepwise heating procedure for hydrate dissociation to measure the DP is recommended due to its ability to improve accuracy and save time. However, it is essential to exercise caution during the data interpretation to avoid measuring inaccurate DP. In particular, considering the dissociation of various hydrate structures is crucial to enhance the accuracy of DP determination when employing non-visual techniques.
可靠的天然气水合物平衡数据对于评估油气行业中水合物问题的严重程度以及在不同领域(如基于水合物的二氧化碳捕获和储存)成功实施水合物技术的优势是必要的。此外,水合物平衡点预测模型依赖于实验数据的调整。在这篇综述中,讨论了在存在或不存在液态水相的情况下水合物解离点(DP)测量的各种技术,以提高测量的准确性。虽然目测和非目测技术都可用于测量水合物DP,但非目测等差法是最常用的技术。由于能够提高准确性和节省时间,建议采用逐步加热的方法来测量水合物解离的DP。然而,在数据解释过程中必须谨慎行事,以避免测量不准确的DP。特别是,考虑各种水合物结构的解离对于提高非视觉技术测定DP的准确性至关重要。
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引用次数: 0
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Petroleum & Petrochemical Engineering Journal
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