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Mathematical Modeling Investigation of V+5 Ion Removal from Wastewater by Nanographene Oxide 纳米氧化石墨烯去除废水中V+5离子的数学模型研究
Pub Date : 2023-01-11 DOI: 10.23880/ppej-16000336
H. Mh
The objective of this work is to remove Vanadium V+5 ions from wastewater by batch adsorption utilizing Nano Graphene Oxide (NGO) since Vanadium presents a hazardous concern due to its effect on biological systems; According to the International Agency for Research on Cancer (IARC), vanadium V+5 ions are a potential human carcinogen. In the adsorption process, the effects of temperature (20-50)°C and initial concentration effect (100-800) mg L-1 were investigated. The adsorption isotherms were identified using a simulated aqueous solution of the V+5 ions and a kinetic and thermodynamic sorption analysis. Both the Langmuir and Freundlich isotherm models were used to fit the data. Due to the correlation coefficient (R2) of 0.999, analyses showed that the Adsorption of V+5 ions by NGO followed the Langmuir model. Kinetic models analyzed Intra Particle Diffusion, Pseudo First & Second Order Models revealed that an Intra-Particle Diffusion model was followed. Thermodynamically, The Adsorption processes were exothermic, random, and spontaneous, all shown by the negative values for Enthalpy ∆H, Entropy ∆S, and Gibbs free Energy ∆G.
这项工作的目的是通过利用纳米氧化石墨烯(NGO)批量吸附从废水中去除钒V+5离子,因为钒由于其对生物系统的影响而存在危险问题;根据国际癌症研究机构(IARC),钒V+5离子是一种潜在的人类致癌物。在吸附过程中,考察了温度(20 ~ 50)℃和初始浓度(100 ~ 800)mg L-1对吸附效果的影响。通过模拟V+5离子的水溶液,确定了吸附等温线,并进行了吸附动力学和热力学分析。使用Langmuir和Freundlich等温线模型来拟合数据。相关系数(R2)为0.999,表明NGO对V+5离子的吸附符合Langmuir模型。动力学模型分析了颗粒内扩散,伪一阶和伪二阶模型分析了颗粒内扩散模型。热力学上,吸附过程是放热的、随机的和自发的,均表现为焓∆H、熵∆S和吉布斯自由能∆G的负值。
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引用次数: 0
Production, Characterization, and Exergy Analysis of the Soybean Biodiesel Produced by Laboratory Scale 实验室规模生产大豆生物柴油的生产、表征和能量分析
Pub Date : 2023-01-11 DOI: 10.23880/ppej-16000328
Rios Mas
The world's hegemonic energy model is mostly based on the burning of fossil fuels. The heavy reliance on oil, coal, and natural gas for power generation as well as the pollution resulting from burning such fuels is a growing global concern. Biodiesel from the transesterification of vegetable oils is a promising alternative source for diesel engines. The ANP, National Agency of Petroleum, Natural Gas and Biofuels, regulates fuels in Brazil. In this work, soybean biodiesel was produced on a laboratory scale through an alkaline transesterification reaction. An analysis of the exegetic efficiency of the process, the physical-chemical characterization of biodiesel, and a brief discussion on the following parameters were carried out: higher and lower calorific value, water content, specific mass at 20°C, kinematic viscosity at 40°C, acidity index and oxidative stability, verifying the adequacy to the parameters of ANP Resolutions nº 45/2014 and nº 798/2019. Considering the exergetic efficiency of 63.42% and the physical-chemical characterization, despite the non-conformities in water content and oxidative stability, soybean biodiesel proved to be a satisfactory alternative for renewable fuel.
世界霸权的能源模式主要建立在燃烧化石燃料的基础上。对石油、煤炭和天然气发电的严重依赖以及燃烧这些燃料造成的污染日益成为全球关注的问题。植物油酯交换制备的生物柴油是一种很有前途的柴油发动机替代燃料。ANP,即国家石油、天然气和生物燃料局,负责监管巴西的燃料。在本研究中,通过碱性酯交换反应在实验室规模上制备了大豆生物柴油。分析了该工艺的高效能、生物柴油的理化特性,并对以下参数进行了简要讨论:高热值和低热值、水分含量、20°C时的比质量、40°C时的运动粘度、酸度指数和氧化稳定性,验证了ANP决议nº45/2014和nº798/2019参数的充分性。考虑到63.42%的火用效率和理化性质,尽管大豆生物柴油在含水量和氧化稳定性方面存在差异,但证明大豆生物柴油是一种令人满意的可再生燃料替代品。
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引用次数: 0
A Comparative Study on Appraisal of Lithological Boundaries and Litho-Models Using Well Log Data at Bhogpara Oil Field in Assam of NE India 利用测井资料评价印度东北部阿萨姆邦博格帕拉油田岩性边界与岩性模型的对比研究
Pub Date : 2023-01-11 DOI: 10.23880/ppej-16000335
Accurate assessment of bed boundaries at a drill site is a crucial step for reservoir characterization. Generally, the interpreters in oil industries carry out such analysis through expensive softwares based on their experiences and geological knowledge in the study area. However, identifying bed boundaries using traditional interpretation is tedious. In this study, we adopted a synergistic approach of Walsh transform and a bed boundary demarcation technique to discriminate the lithological boundaries in Bhogpara oil field of Assam in NE India. This bed boundary detection technique was tested over self-potential (SP), gamma ray (GR) and laterolog deep resistivity (LLD) logs. Initially, we detected the possible lithological boundaries from GR log variations and hence proposed a lithological model as per the knowledge of traditional log interpretation techniques. Subsequently, Walsh low pass filter was applied to the self-potential (SP), GR and LLD logs to obtain their step function. Afterward, the step functions of logs were processed through the boundary detection algorithm to find out the possible thick and thin beds. Further, bed correlation was made among the Walsh-detected boundaries for the studied wells of the Bhogpara oil field. Finally, a bed boundary model was generated using the boundaries picked from the Walsh-based approach. Our analysis exhibit that the model generated from Walsh boundaries more explicitly envisaged the possible heterogeneity. Traditionally we discriminated the minimum bed thickness of the order of 5.15 m, whereas, from the Walsh-based approach we obtained thin bed of the order of 3.2 m. This proposed bed boundary assessment technique is also helpful in understanding the position of subsurface rock layers as well as possible thick and thin beds when we don’t have any pre-received core information.
准确评估钻井现场的地层边界是油藏表征的关键步骤。一般来说,石油行业的解释人员根据他们在研究区域的经验和地质知识,通过昂贵的软件进行这种分析。然而,使用传统的解释来确定地层边界是很繁琐的。在这项研究中,我们采用了Walsh变换和层界划分技术的协同方法来识别印度东北部阿萨姆邦Bhogpara油田的岩性边界。通过自电位测井(SP)、伽马测井(GR)和侧向深电阻率测井(LLD)对该床层边界探测技术进行了测试。首先,我们从GR测井变化中发现了可能的岩性边界,并根据传统测井解释技术的知识提出了岩性模型。随后,对自电位(SP)、GR和LLD日志进行Walsh低通滤波,得到它们的阶跃函数。然后,通过边界检测算法对原木的阶跃函数进行处理,找出可能的厚层和薄层。此外,对Bhogpara油田研究井的沃尔什探测边界进行了层位对比。最后,利用基于walsh的方法提取的边界生成层界模型。我们的分析表明,由沃尔什边界生成的模型更明确地设想了可能的异质性。传统方法判别最小层厚约为5.15 m,而基于walsh的方法得到的薄层厚度约为3.2 m。当我们没有任何预先接收到的岩心信息时,所提出的床层边界评价技术也有助于了解地下岩层的位置以及可能的厚层和薄层。
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引用次数: 0
Stress Analysis of Pipe-In-Pipe Systems under Free Span for Deep Water Pipeline Applications 深水管道自由跨下管中管系统的应力分析
Pub Date : 2023-01-11 DOI: 10.23880/ppej-16000325
Njuguna J
This study examined the phenomena of free span for a pipe -in- pipe (PIP) system for pipeline application. Two different span length of 8 and 30 meters are modelled and simulated using nonlinear stress analysis. The effect of pressure, temperature and gravity on the PIP system are determined and compared with conventional single pipeline. From the results obtained, it is clear that the finite element analysis (FEA) results correlated very well with those calculated using analytical methods. Percentage differences were generally less than 10%, with some discrepancies which were due to assumption of thin-walled theory which assumes a radial stress equals to zero, whereas the FEA calculates a non- zero radial stress. The key finding in this study demonstrated the strong potentials of PIP system in terms of structural reliability for deepwater pipeline application. Specifically, the 30m single pipe in free span (with pressure and temperature) deflected 205.1mm, more than double the corresponding PIP. This knowledge can be beneficial to selection and design considerations for pipeline system responses to both the gravity, thermal and pressure loading as well as the potential failure modes that may results in a typical scenario. Various theoretical calculations of stresses are used to validate the finding in this study of the single pipe and PIP models for flat seabed and free span.
本文研究了管道应用中的管中管(PIP)系统的自由跨现象。采用非线性应力分析方法对8米和30米两种不同跨度进行了建模和模拟。确定了压力、温度和重力对PIP系统的影响,并与常规单管进行了比较。从得到的结果可以清楚地看出,有限元分析(FEA)结果与解析方法计算的结果具有很好的相关性。百分比差异一般小于10%,其中一些差异是由于薄壁理论假设径向应力等于零,而有限元计算的是非零径向应力。本研究的关键发现表明,PIP系统在深水管道结构可靠性方面具有很强的应用潜力。其中,30m单管自由跨(带压力和温度)挠曲205.1mm,是相应PIP的两倍多。这些知识有助于选择和设计管道系统对重力、热和压力载荷的响应,以及可能导致典型情况的潜在失效模式。各种应力的理论计算被用来验证在本研究中发现的单管和PIP模型的平坦海床和自由跨度。
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引用次数: 0
Analyzing the Effects of Drillstring Speed on Bottom Hole Assembly Vibration in S-Shape Directional Wells: A Comprehensive Sensitivity Analysis s形定向井钻柱转速对井底钻具组合振动影响的综合敏感性分析
Pub Date : 2023-01-11 DOI: 10.23880/ppej-16000337
The main objective of this article is to do a comprehensive sensitivity analysis so as to study the influence of rotational speeds on the drillstring and BHA vibrations in well ZB-290 of s-shape well profile. This study is an extention of our reseach work of drillstring vibrations that were previously implemented to identify, analyze and control the resulting vibration in Zubair field wells. This well (ZB-290) has been drilled in Zubair field. Furthermore, recorded time-based vibration data and the vibration logs of this well to perform this analysis. BHAs forces, stresses, displacements, torque, and moments have been successfully identified and analysed taking into account the change of drilling speed. Drilling performance and future well designs will be enhanced based on the previous and this work.
本文的主要目的是对ZB-290井s形井眼进行综合灵敏度分析,研究转速对钻柱和钻具组合振动的影响。该研究是我们之前对钻柱振动研究工作的延伸,该研究主要用于识别、分析和控制Zubair油田油井的振动。这口井(ZB-290)已经在Zubair油田钻探。此外,还记录了该井的基于时间的振动数据和振动测井来进行分析。考虑到钻井速度的变化,bha的力、应力、位移、扭矩和力矩已被成功识别和分析。钻井性能和未来的井设计将在以往和本工作的基础上得到改进。
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引用次数: 0
Evaluation of Micro-Distillation Methodology in Obtaining the Oil Distillation Curve Using Design of Experiments 用实验设计评价微蒸馏法获得石油蒸馏曲线
Pub Date : 2022-10-20 DOI: 10.23880/ppej-16000315
Chrisman Ecan
In the evaluation of petroleum, the true boiling point (TBP) curve stands out among the characterization analyzes, as it is fundamental to assist in decision making such as pricing, royalty payment and petroleum valuation. This is possible by defining the yields of petroleum derivatives obtained as a function of their true boiling points. Its obtainment can partially conducted by applying the ASTM D2892 methodology, for fractions with temperatures up to 673 kelvin. Requiring a minimum volume of 1200 mL of oil and an average time of 48 hours. The present work aims to evaluate the feasibility of applying micro-distillation in the construction of the TBP curve, with volume and time reduction using reference oil. For this, established experiments will conducted according to the application of experiment planning and their results will compared with the curve obtained under standard conditions by ASTM D2892. The variables studied were distillation column size, heating rate control and magnetic bar shape. As a result, two conditions provided adjustment to the validation curve across the entire length of the conventional TBP ASTM curve, with the possibility of using columns of different sizes, minimum sample volume of 700 mL and reduction of total time to 16 hours and 40 minutes.
在石油评价中,真沸点(TBP)曲线在特征分析中脱颖而出,因为它是协助定价、特许权使用费支付和石油估值等决策的基础。这可以通过将石油衍生物的产率定义为其真实沸点的函数来实现。它的获得可以部分地通过应用ASTM D2892方法进行,对于温度高达673开尔文的分数。需要最少1200毫升的油和平均48小时的时间。本研究的目的是评价微蒸馏在构建TBP曲线中应用的可行性,同时减少参考油的体积和时间。为此,将根据实验计划的应用进行已建立的实验,并将实验结果与ASTM D2892在标准条件下得到的曲线进行比较。研究了精馏塔尺寸、加热速率控制和磁棒形状。结果,两种条件提供了在传统TBP ASTM曲线的整个长度上对验证曲线的调整,可以使用不同尺寸的色谱柱,最小样本量为700 mL,总时间减少到16小时40分钟。
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引用次数: 0
Experimental Viscosity Data for Binary and Ternary Systems of Arab Heavy Crude Oil and Diluents 阿拉伯重质原油和稀释剂二元和三元体系的实验粘度数据
Pub Date : 2022-10-20 DOI: 10.23880/ppej-16000312
Miadonye A
To meet the global exponential demand for crude oil, development of unconventional crude oil deposits is essential but the major limitation is seen in pipeline transportation, given its exceptionally high viscosity. Saudi Aramco is the world’s leading crude oil producer with a significant contribution of Arab Heavy crude oil in the total production mix. In this paper, we have measured the viscosities of both binary and ternary mixtures of this heavy oil crude for the first time, using toluene and natural gas condensate fluids over temperatures encountered in pipeline transportation. Our study shows that both binary and ternary systems show excellent viscosity reduction characteristics with increase in viscosity index with temperature. The degree of viscosity reduction shows polynomial trends with excellent fits that facilitated the determination of the wax appearance temperature using differential calculus approach. The range of experimental temperature in this study and the excellent viscosity reduction characteristics of the systems testify to the suitability of our experimental data for pipeline transportation planning
为了满足全球对原油的指数级需求,非常规原油储量的开发至关重要,但由于其极高的粘度,主要限制在管道运输方面。沙特阿美公司是世界领先的原油生产商,其阿拉伯重质原油在其总产量中占有重要地位。在本文中,我们首次使用甲苯和天然气凝析液在管道运输中遇到的温度下测量了这种稠油原油的二元和三元混合物的粘度。我们的研究表明,二元和三元体系都表现出优异的粘度降低特性,粘度指数随温度的升高而增加。粘度降低程度表现为多项式趋势,具有良好的拟合性,便于用微分法确定蜡的外观温度。本研究的实验温度范围和系统优异的降粘特性证明了我们的实验数据对管道运输规划的适用性
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引用次数: 0
Reservoir Description, Diagenesis and Reservoir Quality of the Deep Marine Sediments in the Propagation Stage of Rift Basin 裂谷盆地扩张期深海沉积物储层描述、成岩作用及储层质量
Pub Date : 2022-10-20 DOI: 10.23880/ppej-16000316
Kassem Aa
The exploration and exploitation of the downthrown side of the productive upthrown Pre-rifting reservoirs at the Gulf of Suez marked bring a renaissance to the rift basin Exploration. This work documents the reservoir performance, trap geometry, and structural style of the downthrown deep marine stratigraphic entrapment. In addition, it outlines the requirements necessary beyond the production mitigations and limits. To gain better understanding of Asl Formation (deep marine) reservoir characteristics early in the exploration program, Asl Formation was cored in the north October J-5 well. A continuous 366- foot (112m) core was recovered including the main reservoir interval, which is producing over 12,000 barrel of oil per day. The J-5 Asl Formation has been interpreted as a synthetic, mixed clastic-carbonate turbidity deposit. Three major lithofacies described are recognizable on electric log. These are sandstone, shale and carbonates. The sandstones dominate the lower portion of the core and are the main oil producing section. Sandstone porosity and permeability range from 17 to 27% and 30 millidarcies to 3 darcies, respectively. Compared to the sandstone, the carbonate turbidites have poorer reservoir quality. They dominate the upper portion of the core and are composed of coarse fossil debris, silica framework grains and rock fragments. Horizontal and vertical permeabilities with rock types. Both the sandstone and carbonate sections of the J-5 core have experienced a complex diagenetic history. Deposition of the cored interval was initiated by a convulsive geological event such as flashflood or earthquake. These events would likely generate sufficient energy for mobilization of onshore and/or near shore sediments into multiple gravity flows having regional extent. The reservoir quality is controlled by a combination of primary depositional fabric and subsequent diagenetic modification. This research work can guide future exploration of reservoir-prone deep marine deposits in the Red Sea Rift and provide a reference for the subsurface deep-water reservoir quality analysis in the propagation stage in the Rift Basins.
苏伊士湾高产隆起前裂谷油藏下陷侧的勘探开发标志着裂谷盆地勘探的复兴。这项工作记录了下倾深海地层圈闭的储层性能、圈闭几何形状和构造样式。此外,它还概述了生产缓解和限制之外的必要要求。为了在勘探早期更好地了解Asl组(深海)储层特征,在10月J-5井北部进行了Asl组取心。包括主储层在内,连续开采了366英尺(112米)的岩心,该岩心的日产量超过1.2万桶。J-5 Asl组被认为是一个合成的碎屑-碳酸盐混合浊积矿床。在电测井上可以识别出描述的三种主要岩相。这些是砂岩,页岩和碳酸盐岩。砂岩在岩心下部占主导地位,是主要的产油部位。砂岩孔隙度为17 ~ 27%,渗透率为30 ~ 3毫达尔达尔。与砂岩相比,碳酸盐岩浊积岩的储层质量较差。它们主要位于岩心的上部,由粗糙的化石碎屑、硅骨架颗粒和岩石碎屑组成。岩石类型的水平和垂直渗透率。歼5岩心砂岩段和碳酸盐岩段均经历了复杂的成岩历史。岩心层段的沉积是由剧烈的地质事件,如山洪或地震引起的。这些事件可能会产生足够的能量,将岸上和/或近岸沉积物动员成具有区域范围的多重重力流。储层质量受原生沉积构造和后续成岩改造的综合控制。该研究工作可指导今后红海裂谷深海相油气藏的勘探,并为裂谷盆地扩展阶段的地下深水储层质量分析提供参考。
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引用次数: 0
Improvement of Oil Recovery in Hydrocarbon Fields by Developing Polymeric Gel-Forming Composition 开发聚合物成胶组合物提高油田采收率
Pub Date : 2022-10-20 DOI: 10.23880/ppej-16000314
AL-Obaidi Sh
The paper presents the results of laboratory and field experiments on a developed polymer gel-forming composition “PSB” that enhances oil recovery. In this composition, two aqueous solutions are used: a polymeric gelling agent and an inorganic crosslinker. An alternating injection of solutions that are mixed directly in the reservoir allows a bulk gel to be formed that blocks water or gas breakthroughs. This leads to an increase in oil production, and a decrease in water cut, resulting in more efficient wells. On five wells in a hydrocarbon field that was located within the Permian-Carboniferous deposits, a series of field tests were conducted. It has been observed that wells treated with this developed polymer gel-forming composition “PSB” show a decrease in water cut, a decrease in liquid flow rates, and an increase in oil production. This technology led to an increase in oil flow rates of 5 tonnes per day per well (2 times) and a decrease in water cut of 10-40%, confirming its effectiveness. According to the values of the cumulative effect as of February 2016, this effect continues to increase oil production by 20-600 tons per well.
本文介绍了一种提高采收率的聚合物凝胶形成成分“PSB”的实验室和现场实验结果。在该组合物中,使用两种水溶液:聚合物胶凝剂和无机交联剂。直接在储层中混合的溶液交替注入,可以形成大块凝胶,阻止水或气体的突破。这可以提高产油量,降低含水率,从而提高井的效率。在位于二叠纪-石炭纪沉积层的油气油田的五口井中,进行了一系列的现场测试。研究发现,使用该聚合物凝胶形成组合物“PSB”处理的井,含水率降低,液体流速降低,产油量增加。该技术使每口井每天的产油量增加了5吨(2次),含水率降低了10-40%,证实了该技术的有效性。根据截至2016年2月的累积效应值,这种效应继续使每口井的石油产量增加20-600吨。
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引用次数: 0
The Bakken and Three Forks Formations Daily Crude Oil Production per Well Prediction Based on Support Vector Regression 基于支持向量回归的Bakken和Three Forks地层单井日产油量预测
Pub Date : 2022-10-20 DOI: 10.23880/ppej-16000317
Ebere F
In the oil and gas industry, there is a major challenge to accurately predict the crude oil production due to the complexity and sophistication of the subsurface conditions. Production forecasting is highly limited by the non-linearity between hydrocarbon production and any relevant petrophysical parameter. Trying to use just the conventional mathematical approaches might give inaccurate result because of the numerous assumptions employed by this approach. Therefore, there is a huge need to develop a reliable prediction model of hydrocarbon production. This will surely assist Petroleum Engineers to have a better understanding of the entire reservoir behavior to solve, evaluate, and optimize its overall performance. Utilizing data driven models which is the machine learning techniques can help to predict crude oil production with much more acceptable accuracy. In this paper, Python-Support Vector Regression and Orange-Linear Regression have been implemented to build the models that predict the daily oil production of a well in Bakken-Three Forks Formations. The statistical data for the Bakken-Three Forks formation oil production was from North Dakota Industrial Commission (NDIC) website. An open-source visual programmingbased data mining software Orange was used to train a multi-linear regression model of 817 datasets with addition of 200 lines of code algorithm written in Python which is a high-level programming language. Combination of these two software models gave a more robust and accurate predictions compared to the conventional method of using just a software model by others. The models developed can practically estimate the Daily oil production of a well in Bakken-Three Forks Formations. The R2 obtained is 0.98 from the low performance value of 0.35, the MAE became 10.593 and RMSE is 16.593 for SVR and linear regression with a cross validation of 10 folds for the 70% train dataset and 30 % test dataset shows MSE value of 2.826, RMSE of 1.681, MAE of 1.045 and R2 value of 0.998. The performance of this SVR model indicate that this developed model can be used to predict the Daily oil produced per well accurately with the supervised algorithm. The values obtained from the Orange-Linear regression show better performance when compared with the SVR and validates the values obtained from the Python Support Vector Regression from the model criteria evaluation of the results.
在油气行业,由于地下条件的复杂性和复杂性,准确预测原油产量是一个重大挑战。油气产量与任何相关岩石物性参数之间的非线性极大地限制了产量预测。试图仅仅使用传统的数学方法可能会得到不准确的结果,因为这种方法采用了许多假设。因此,迫切需要建立可靠的油气产量预测模型。这将有助于石油工程师更好地了解整个油藏的动态,从而解决、评估和优化其整体性能。利用数据驱动模型,即机器学习技术,可以帮助以更高的可接受精度预测原油产量。本文应用python -支持向量回归和orange -线性回归建立了Bakken-Three Forks地层一口井的日产油量预测模型。Bakken-Three Forks地层产油量统计数据来自北达科他州工业委员会(NDIC)网站。使用开源的基于可视化编程的数据挖掘软件Orange对817个数据集的多线性回归模型进行训练,并添加了200行用高级编程语言Python编写的代码算法。这两种软件模型的结合相比于仅使用其他软件模型的传统方法,给出了更稳健和准确的预测。所建立的模型可以实际地估计Bakken-Three Forks地层一口井的日产油量。对于70%训练集和30%测试集,经过10倍交叉验证的SVR和线性回归得到的MAE为10.593,RMSE为16.593,MSE为2.826,RMSE为1.681,MAE为1.045,R2为0.998。该支持向量回归模型的性能表明,该模型可以用监督算法准确预测单井日产油量。与SVR相比,从橙色线性回归获得的值显示出更好的性能,并从模型标准评估结果中验证了从Python支持向量回归获得的值。
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引用次数: 0
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Petroleum & Petrochemical Engineering Journal
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