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Teion Kogaku (journal of The Cryogenic Society of Japan)最新文献

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Ex-situ PIT法 Nb3Al線材の作製と特性 Ex-situ PIT法Nb3Al线材的制备及特性
Pub Date : 2004-12-25 DOI: 10.2221/JCSJ.39.645
恭治 太刀川, 剛史 中陳, 祐哉 池田, 寛之 伊澤, 修 井戸原, 好明 井上
A15 Nb3Al has gained much interests for high-field and large-scale applications due to its excellent critical current density Jc and strain tolerance. However, the shift of Nb3Al composition from stoichiometry at temperatures below 1800°C causes difficulties in the fabrication of conductors with inherent Nb3Al characteristics. In this study, Nb3Al powders prepared by arc melting in an Ar / H2 atmosphere were encased in a sheath and fabricated into tapes through the ex-situ PIT (Powder in Tube) process. The present study revealed that the oxygen content in the Nb3Al powder plays a crucial role in yielding large Jc in the tape. Furthermore, the addition of Ag powder to the Nb3Al powder was found to appreciably enhance the Jc of the tape in lower fields. The superconducting performance of the tapes is discussed in relating to their structures.
A15 Nb3Al由于其优异的临界电流密度Jc和应变容限,在高场和大规模应用中受到了广泛的关注。然而,在1800°C以下的温度下,Nb3Al成分从化学计量的转变导致了具有固有Nb3Al特性的导体的制造困难。本研究将在Ar / H2气氛中电弧熔化制备的Nb3Al粉末包裹在护套中,并通过非原位PIT (Powder In Tube)工艺制成带状。本研究表明,Nb3Al粉末中的氧含量对带中产生大的Jc起着至关重要的作用。此外,在Nb3Al粉末中添加Ag粉末可以明显提高带的低场Jc。从结构上讨论了超导带的性能。
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引用次数: 0
YBCO coated conductor の臨界電流の応力(ひずみ)効果に与えるバッファー層の影響 缓冲层对YBCO coated conductor的临界电流应力(应变)效果的影响
Pub Date : 2004-11-25 DOI: 10.2221/JCSJ.39.547
菅野 未知央, 光造 長村, Werner Prussuit, 司 木吉, 伊藤 喜久男
The stress and strain dependence of the critical current (Ic) was examined for YBCO-coated conductors with IBAD-CeO2/YSZ or ISD-MgO buffer layers. For all samples, Ic increased as the stress was increased and reached a maximum. For larger tensile stress, Ic started to decrease. The reversibility of Ic showed a different behavior depending on the buffer layer. For the tape buffered with IBAD-CeO2/YSZ, Ic recovered to the initial value after the applied strain reached 0.30%. On the other hand, a smaller reversible strain was observed for the ISD-buffered tape. The difference of the reversible strain was discussed based on a microstructure observation. For all samples, quenching occurred at a strain of more than 0.30%. Compared to the stress-strain curve of composite tapes, it was confirmed that quenching strains were determined by the yield strain of the Hastelloy substrate. The strain scaling law for the present YBCO-coated conductors was found to be similar to that for A15-type superconductors.
研究了具有IBAD-CeO2/YSZ或ISD-MgO缓冲层的ybco涂层导体的临界电流(Ic)与应力和应变的关系。对于所有样品,Ic随着应力的增加而增加,并达到最大值。当拉伸应力较大时,Ic开始降低。Ic的可逆性随缓冲层的不同表现出不同的行为。对于IBAD-CeO2/YSZ缓冲带,当外加应变达到0.30%时,Ic恢复到初始值。另一方面,isd缓冲带的可逆应变较小。在显微组织观察的基础上,讨论了可逆应变的差异。所有试样在应变大于0.30%时均发生淬火。通过与复合带的应力-应变曲线的比较,证实了淬火应变是由哈氏合金基体的屈服应变决定的。发现ybco涂层导体的应变缩放规律与a15型超导体相似。
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引用次数: 0
YBCOのマルチ-プルーム・マルチ-ターンPLD成膜 YBCO的多-蒲鲁姆-多-转PLD成膜
Pub Date : 2004-11-25 DOI: 10.2221/JCSJ.39.553
智則 渡部, 礼二 栗木, 博幸 岩井, 成紀 宮田, 岳海 室賀, 顕 衣斐, 穣 山田, 融 塩原
We have investigated the high-speed deposition of YBa2Cu3O7-x (YBCO) using PLD on a CeO2-capped IBAD buffer layer. In order to speed up the coated conductor process, we introduced a continuous PLD system mainly consisting of high-power laser equipment and a vacuum chamber with a reel-to-reel substrate transfer system. The laser system was designed so that the laser beam scans YBCO targets during deposition and raises plural and discrete plumes (multi-plume). The aim of this is to perform high-speed production of YBCO layers. Although high laser pulse frequency deposition makes high-speed deposition possible, it causes roughening of the surface morphology and lowers the Jc. The multi-plume gave us a high Jc during low laser pulse frequency deposition and high-speed deposition at a higher frequency. The substrates were turned three times to enlarge the deposition area (multi-turn). Within 15 degrees aslant to a plume center, we obtained a high Jc for all turns. Using this multi-plume and multi-turn PLD equipment, we have succeeded in deposition of a 21m-long YBCO layer with a high end-to-end critical current (Ic) of 85 A and high Jc exceeding 1 MA/cm2. Ic data measured in 1.4m intervals showed good uniformity, with a standard deviation of 3.43%. This layer also showed high in-plane alignment, attaining 5.2 degrees of full-width-at-half-maximum as observed by X-ray phi scans. These results indicate the availability of utilizing multi-plume and multi-turn PLD for YBCO-coated conductor preparation.
我们研究了用PLD在ceo2覆盖的IBAD缓冲层上高速沉积YBa2Cu3O7-x (YBCO)。为了加快涂层导体的过程,我们引入了一个连续的PLD系统,主要由高功率激光设备和带卷轴到卷轴基板转移系统的真空室组成。激光系统的设计使激光束在沉积过程中扫描YBCO目标,并产生多重和离散羽流(多羽流)。这样做的目的是执行YBCO层的高速生产。虽然高激光脉冲频率沉积使高速沉积成为可能,但它会导致表面形貌粗糙化并降低Jc。在低激光脉冲频率沉积和高频率高速沉积时,多羽流给我们带来了高的Jc。将衬底旋转三次以扩大沉积面积(多圈)。在向羽流中心倾斜15度的范围内,我们获得了所有转弯的高Jc。利用这种多羽流和多匝PLD设备,我们成功地沉积了21米长的YBCO层,其端到端临界电流(Ic)高达85 a,高Jc超过1 MA/cm2。1.4m间隔测量的Ic数据均匀性好,标准差为3.43%。该层也显示出高度的面内对齐,通过x射线phi扫描观察到,达到5.2度的全宽半最大值。这些结果表明利用多羽、多匝PLD制备ybco涂层导体是可行的。
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引用次数: 4
SIM and TEM Micro-structure Observation of Defective Areas Determined by MO Imaging of YBCO-coated Conductors ybco涂层导体MO成像缺陷区的SIM和TEM微结构观察
Pub Date : 2004-11-25 DOI: 10.2221/JCSJ.39.541
H. Sasaki, T. Kato, Y. Sasaki, T. Hirayama, J. Matsuda, T. Izumi, Y. Shiohara, N. Kashima, S. Nagaya
Synopsis: We have developed a defect analysis procedure that combines a magneto-optical (MO) imaging system with scanning ion microscopy (SIM) and transmission electron microscopy (TEM). Low Ic areas of coated conductors were inspected using the MO imaging system. The defective area revealed in the MO image was prepared for cross-sectional SIM specimen using a focused Ga ion beam. The porous YBCO layers were found by SIM observation. Furthermore, defective areas were picked up using micro-sampling and then thinned using a focused Ga ion beam. TEM observation and energy dispersive X-ray spectroscopy indicated that the YBCO layers were composed of Y-rich phases and Ba-Cu-O.
摘要:我们开发了一种结合磁光(MO)成像系统与扫描离子显微镜(SIM)和透射电子显微镜(TEM)的缺陷分析程序。采用MO成像系统对涂层导体的低Ic区进行了检测。用聚焦的镓离子束制备了MO图像中显示的缺陷区域。通过SIM观察发现了多孔的YBCO层。此外,用微采样方法提取缺陷区域,然后用聚焦的镓离子束进行减薄。TEM观察和x射线能谱分析表明,YBCO层由富y相和Ba-Cu-O组成。
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引用次数: 0
IBAD-PLD法長尺YBCO線材の開発 —IBAD中間層上における自己配向PLD-CeO2キャップ層の長尺化— IBAD- pld法长度YBCO线材的开发—IBAD中间层上的自定向PLD-CeO2帽层的长度化—
Pub Date : 2004-11-25 DOI: 10.2221/JCSJ.39.529
岳海 室賀, 成紀 宮田, 智則 渡部, 顕 衣斐, 穣 山田, 輝郎 和泉, 融 塩原, 丈晴 加藤, 司 平山
We found that a PLD-CeO2 cap layer on an IBAD-Gd2Zr2O7 (GZO) tape can make a high grain alignment without ion-beam assistance such as the IBAD process. We call this phenomenon “self-epitaxy in a PLD-CeO2 cap layer”. At present, we are developing long tapes by the Reel-to-Reel process for the self-epitaxial PLD-CeO2 cap layer on an IBAD-GZO tape. A 108 m-long tape with a PLD-CeO2 cap layer was obtained. The delta phi values of the buffer layer were improved to 4.3-4.8 degrees of PLD-CeO2 from 13.3-14.0 degrees of IBAD-GZO. Although the fabrication rate of the PLD-CeO2 cap layer was as fast as 5-6 m/h, that of the IBAD-GZO was 1 m/h. Then, we tried to improve the overall fabrication rate of the total buffer layers using a thin IBAD layer and the self-epitaxial PLD-CeO2 cap layer. A PLD-CeO2 cap layer was deposited at a tape transfer speed of 2.5 m/h on a 55 m-long IBAD-GZO tape with the delta phi values of 23.1-24.0 degrees fabricated at 2 m/h, which was two times faster than the conventional IBAD process. As a result, the delta phi values of the PLD-CeO2 cap layer were in the range of 8.6-10.4 degrees. The fabrication rate throughout all of the processes for buffer layers was achieved to be 2 m/h. It was found that PLD-CeO2 was effective for enhancing both the fabrication rate and grain alignment.
我们发现,在IBAD- gd2zr2o7 (GZO)带上的PLD-CeO2帽层可以在没有离子束辅助(如IBAD工艺)的情况下实现高晶粒对准。我们称这种现象为“PLD-CeO2帽层中的自外延”。目前,我们正在利用Reel-to-Reel工艺开发IBAD-GZO磁带上自外延PLD-CeO2帽层的长磁带。得到了一个108 m长的带有PLD-CeO2帽层的胶带。缓冲层的δ phi值由iad - gzo的13.3 ~ 14.0°提高到PLD-CeO2的4.3 ~ 4.8°。PLD-CeO2帽层的制备速度可达5 ~ 6 m/h,而IBAD-GZO的制备速度为1 m/h。然后,我们尝试使用薄IBAD层和自外延PLD-CeO2帽层来提高总缓冲层的总体制造速度。在55 m长的iad - gzo带上以2.5 m/h的传输速度沉积了PLD-CeO2帽层,以2m /h的速度制备的δ phi值为23.1 ~ 24.0度,比传统的IBAD工艺快2倍。结果表明,PLD-CeO2帽层的δ phi值在8.6-10.4°范围内。缓冲层在所有工艺中的制造速度达到2米/小时。结果表明,PLD-CeO2能有效地提高材料的加工速度和晶粒取向。
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引用次数: 1
Evaluation of the Normal-zone Initiation and Propagation Characteristics of YBCO Tape YBCO带正常区起始和传播特性的评价
Pub Date : 2004-11-25 DOI: 10.2221/JCSJ.39.560
A. Ishiyama, M. Yanai, H. Ueda, Y. Iijima, T. Saitoh, Y. Shiohara
There are great expectations for YBCO tape as a “next-generation superconductor tape” because the Jc characteristic has better magnetic field dependence at high temperatures and/or in a high magnetic field. It is important to consider stability for superconducting applications; however, the stability criterion for YBCO has not yet been distinctly established. Thus, for the sake of establishing stability criterion for YBCO, we examined the normal-zone initiation and propagation characteristics of a YBCO tape sample experimentally and numerically, and the experimental results were compared with a simulation conducted utilizing a newly developed computer program based on the finite element method (FEM). We also investigated the influence of Ag stabilizer thickness and Hastelloy substrate on the transient thermal behavior of the YBCO tapes.
由于Jc特性在高温和/或高磁场下具有更好的磁场依赖性,因此人们对YBCO带作为“下一代超导体带”寄予厚望。考虑超导应用的稳定性是很重要的;然而,YBCO的稳定性标准尚未明确确立。因此,为了建立YBCO的稳定性判据,我们对YBCO带样的正常区起始和传播特性进行了实验和数值研究,并将实验结果与利用新开发的基于有限元法的计算机程序进行的模拟结果进行了比较。我们还研究了银稳定剂厚度和哈氏合金衬底对YBCO带的瞬态热行为的影响。
{"title":"Evaluation of the Normal-zone Initiation and Propagation Characteristics of YBCO Tape","authors":"A. Ishiyama, M. Yanai, H. Ueda, Y. Iijima, T. Saitoh, Y. Shiohara","doi":"10.2221/JCSJ.39.560","DOIUrl":"https://doi.org/10.2221/JCSJ.39.560","url":null,"abstract":"There are great expectations for YBCO tape as a “next-generation superconductor tape” because the Jc characteristic has better magnetic field dependence at high temperatures and/or in a high magnetic field. It is important to consider stability for superconducting applications; however, the stability criterion for YBCO has not yet been distinctly established. Thus, for the sake of establishing stability criterion for YBCO, we examined the normal-zone initiation and propagation characteristics of a YBCO tape sample experimentally and numerically, and the experimental results were compared with a simulation conducted utilizing a newly developed computer program based on the finite element method (FEM). We also investigated the influence of Ag stabilizer thickness and Hastelloy substrate on the transient thermal behavior of the YBCO tapes.","PeriodicalId":285677,"journal":{"name":"Teion Kogaku (journal of The Cryogenic Society of Japan)","volume":"517 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2004-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116239291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
「Nb3Sn線材の現状と将来展望—発見から50年を記念して—」特集によせて “Nb3Sn线材的现状与未来展望——纪念发现50年——”特集
Pub Date : 2004-09-25 DOI: 10.2221/JCSJ.39.376
浩明 熊倉
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引用次数: 1
Development of High-performance Magnetic Refrigerants and Recent Trend in Room-temperature Magnetic Cooling 高性能磁性制冷剂的发展及室温磁冷却的最新趋势
Pub Date : 2004-07-25 DOI: 10.2221/JCSJ.39.314
K. Fukamichi, A. Fujita
The development of new high-performance refrigerants has been highly desired from the viewpoints of energy efficiency and environmental safety. Recently, we developed promising magnetic refrigerant compounds La(Fe1-xSix)13 (0.86≤x≤0.90), that show the first-order of itinerant-electron metamagnetic transition from the paramagnetic state to the ferromagnetic state in applied magnetic fields. By adjusting the hydrogen concentration in La(Fe1-xSix)13Hy, the Curie temperature TC and the working temperature for cooling are controlled covering room temperature. Furthermore, the thermal conductivity of the present compounds is excellent. It should also be emphasized that the elements of the present compounds are very cheap economically and completely harmless to humans.
从能源效率和环境安全的角度来看,开发新型高性能制冷剂是人们迫切需要的。近年来,我们开发了一种很有前途的磁性制冷剂化合物La(Fe1-xSix)13(0.86≤x≤0.90),它在应用磁场中表现出从顺磁态到铁磁态的一级流动电子变磁跃迁。通过调节La(fe1 - x6)13Hy中氢气的浓度,可以在室温下控制居里温度TC和冷却工作温度。此外,本发明化合物的导热性优良。还应该强调的是,目前化合物的元素非常便宜,经济实惠,对人体完全无害。
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引用次数: 0
Mini-RT装置の設計・製作 Mini-RT设备的设计与制作
Pub Date : 2004-05-20 DOI: 10.2221/JCSJ.39.182
利行 三戸, 長門 柳, 雄一 小川, 惇二 森川, 大國 浩太郎, 成卓 岩熊, 俊夫 上出, 眞一 能瀬, 郁夫 伊藤, 滋夫 福居, 俊毅 長山, 純一 奥野
The use of a non-neutral plasma confinement device with a floating internal coil has been planned for the purpose of high-beta plasma confinement research at the University of Tokyo. A device known as the Mini-RT (Miniature Ring Trap) has been constructed as a joint research project between the University of Tokyo, NIFS and Kyushu University. In the experiment, a magnetic-levitation coil (floating coil) operated in a persistent current mode is levitated for 8 hours in a plasma vacuum vessel. The high-temperature superconducting (HTS) floating coil is wound with Bi-2223 tape, and has a diameter of 300 mm and an electromotive force of 50 kA. Since refrigerant cannot be fed to the coil during the plasma experiment, the coil is designed so that the temperature rise after 8 hours of levitation is less than 40 K as the result of considering the specific heat of the coil and incorporating a radiation shield. At the end of the daily plasma experiment, the coil is drawn down to the maintenance location at the bottom of the plasma vacuum vessel, and is re-cooled to 20 K. The engineering design points of the Mini-RT, such as the HTS floating coil, HTS persistent current switch (PCS), cooling system and excitation scheme are summarized.
东京大学计划使用带有浮动内部线圈的非中性等离子体约束装置进行高β等离子体约束研究。作为东京大学、NIFS和九州大学的联合研究项目,一种名为Mini-RT(微型环形陷阱)的设备已经被建造出来。在实验中,一个在持续电流模式下工作的磁悬浮线圈(浮圈)在等离子体真空容器中悬浮8小时。高温超导(HTS)浮圈采用Bi-2223胶带缠绕,直径为300mm,电动势为50ka。由于在等离子体实验中不能给线圈充注制冷剂,因此考虑到线圈的比热并加入辐射屏蔽,线圈在悬浮8小时后的温升小于40k。每日等离子体实验结束后,将线圈拉至等离子体真空容器底部的维护位置,重新冷却至20k。总结了Mini-RT的工程设计要点,如高温超导浮圈、高温超导恒流开关、冷却系统和励磁方案。
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引用次数: 1
Mini-RT装置用高温超伝導磁気浮上コイルの冷却・励磁試験 Mini-RT设备用高温超导磁悬浮线圈的冷却和励磁试验
Pub Date : 2004-05-20 DOI: 10.2221/JCSJ.39.201
長門 柳, 惇二 森川, 利行 三戸, 雄一 小川, 大國 浩太郎, 茂雄 山越, 成卓 岩熊, 俊夫 上出
A magnetically levitated superconducting coil device, Mini-RT, has been constructed using a high temperature superconductor (HTS) for the purpose of examining a new magnetic confinement scheme of high-beta non-neutral plasmas. The floating coil and persistent current switch (PCS) are wound with silver-sheathed Bi-2223 tapes, and they are operated in the temperature range of 20-40 K. After the basic properties of the main coil and HTS-PCS were examined in a liquid helium cryostat, the coil was installed into the vacuum chamber of the Mini-RT device. The HTS floating coil was then cooled by helium gas using GM cryo-coolers equipped with detachable transfer tubes. The excitation tests of the coil were carried out by supplying current from an external DC power supply through the detachable current feeder terminals as the HTS-PCS was turned off. The nominal operation condition was examined by overcoming many difficulties and the persistent current mode was tried by turning on the HTS-PCS. The decay time-constant was evaluated by maintaining the coil temperature for up to four days and the results were compared with calculations. The first magnetic levitation was also examined.
利用高温超导体(HTS)构造了一个磁悬浮超导线圈装置Mini-RT,用于研究高β非中性等离子体的新磁约束方案。浮圈和持续电流开关(PCS)采用银护Bi-2223胶带缠绕,工作温度范围为20- 40k。在液氦低温恒温器中检测主线圈和HTS-PCS的基本性能后,将线圈安装在Mini-RT装置的真空室中。然后使用配备可拆卸传输管的GM冷冻冷却器用氦气冷却HTS浮动线圈。当HTS-PCS关闭时,通过可拆卸的电流馈线端子从外部直流电源供电,进行线圈的励磁测试。克服重重困难,对标称运行条件进行了检验,并通过打开HTS-PCS进行了恒流模式的试验。通过保持线圈温度长达四天来评估衰减时间常数,并将结果与计算结果进行比较。第一次磁悬浮也进行了检验。
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引用次数: 0
期刊
Teion Kogaku (journal of The Cryogenic Society of Japan)
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