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Effect of grain size and grain boundary type on intergranular stress corrosion cracking of austenitic stainless steel: A phase-field study 晶粒尺寸和晶界类型对奥氏体不锈钢晶间应力腐蚀开裂的影响:相场研究
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1016/j.corsci.2024.112557
Qionghuan Zeng, Yiming Chen, Zhongsheng Yang, Lei Zhang, Zhijun Wang, Lei Wang, Junjie Li, Jincheng Wang
A phase-field model coupled with polycrystalline microstructure is utilized to investigate the effect of grain size and grain boundary types on intergranular stress corrosion cracking in austenitic stainless steels. Considering the dilute solution environment, the free energy density of the two phases is hypothesized to be in parabolic form. The slower corrosion crack propagation rate in coarse-grained microstructures can be attributed to a higher frequency of transgranular cracking. Low-angle grain boundaries can effectively deflect intergranular corrosion cracks into grains with lower corrosion susceptibility, thereby impeding crack propagation. Twin boundaries mitigate corrosion crack propagation by reducing potential initiation sites.
本研究利用与多晶微观结构相耦合的相场模型来研究晶粒尺寸和晶界类型对奥氏体不锈钢晶间应力腐蚀开裂的影响。考虑到稀溶液环境,假设两相的自由能密度呈抛物线形式。粗晶粒微结构中的腐蚀裂纹扩展速度较慢,这是因为跨晶粒开裂的频率较高。低角度晶界能有效地将晶间腐蚀裂纹偏转到腐蚀敏感性较低的晶粒中,从而阻碍裂纹扩展。双晶界通过减少潜在的起始点来减缓腐蚀裂纹的扩展。
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引用次数: 0
An innovative strategy against oxide spallation of hot formed steels 防止热成型钢氧化物剥落的创新策略
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1016/j.corsci.2024.112554
Jingpei Nie , liwei Bai , Xiaoguang Yang , Zhichao Zhao , Yujing Fu , Zihe Liu , Xin Li , Ying Li , Hongliang Liu , Xue Zhang
Hot forming is a prominent technique to produce lightweight automotive steels. However, the generation of a weakly adhering oxide scale during hot forming and the subsequent post-processing of the scale pose a great threat to the shape precision of the product. Here, we propose a cost-effective solution to the spallation issue by incorporating minor silicate-molybdate additives into the rinse following pickling. The pre-deposited film serves as an effective barrier against high-temperature oxidation. Our innovative strategy enables the formation of an oxide scale that sticks to the substrate and paint layer, potentially eliminating the necessity for scale removal in industrial settings.
热成型是生产轻质汽车钢的一项重要技术。然而,热成型过程中产生的弱附着氧化鳞片以及随后对鳞片的后处理对产品的形状精度构成了极大威胁。在此,我们提出了一种解决剥落问题的经济有效的方法,即在酸洗后的冲洗中加入少量硅酸盐-钼酸盐添加剂。预先沉积的薄膜可有效阻挡高温氧化。我们的创新策略能够形成附着在基体和涂料层上的氧化物鳞片,从而消除了工业环境中清除鳞片的必要性。
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引用次数: 0
Comparison and study of the corrosion differences of bronze alloys in oxygen-free and oxygen-containing conditions 无氧和含氧条件下青铜合金腐蚀差异的比较与研究
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1016/j.corsci.2024.112553
Zhiheng Fan , Herong Zhou , Xiuyuan Wang , Jialiang Song , Jingrui Shi , Jiachang Chen
The study on the initial corrosion of duplex bronze alloy by dissolved oxygen in Cl-containing environment showed that bronze alloy was preferentially passivated in aerobic environment, and then Cu selectively dissolved. The corrosion rate first slowed down and then gradually accelerated. In contrast, the oxygen-free environment accelerates the reaction of Cu-Cl and Sn-Cl, forms a Cl- rich layer on the metal surface. This layer promotes the formation of Sn chloride, thereby inducing the stratification of Cu-Sn products. In this process, the acidification of the solution causes the metal to enter a self-circulating corrosion mechanism, but the corrosion rate remains low.
对含 Cl 环境中溶解氧对双相青铜合金的初始腐蚀研究表明,青铜合金在有氧环境中优先钝化,然后选择性地溶解 Cu。腐蚀速度先是减慢,然后逐渐加快。相反,无氧环境加速了 Cu-Cl 和 Sn-Cl 的反应,在金属表面形成富含 Cl- 的层。该层促进了氯化锡的形成,从而诱发了 Cu-Sn 产物的分层。在此过程中,溶液的酸化会使金属进入自循环腐蚀机制,但腐蚀速率仍然很低。
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引用次数: 0
A distinct role of microstructure on hot corrosion behaviour of additively manufactured IN718 微观结构对添加剂制造的 IN718 热腐蚀性能的独特作用
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1016/j.corsci.2024.112550
Venkateswararao Mannava , TT Saravanan , Singaravelu Rajan Sabari , NTBN Koundinya , A. Venugopal , SVSN Murty , B. Govind , M. Kamaraj , Ravi Sankar Kottada
The influence of LPBF-IN718 microstructure on hot corrosion behavior was studied at 650 °C. The H-IN718 with <001> oriented grains undergo more weight changes than V-IN718 with <110> oriented grains. Detailed characterization analysis corroborates that Rapp-Goto fluxing and sulphidation mechanisms are operating in LPBF-IN718 with 3SM. Further, GDOES confirms the sulphur gradient existence between Air/3SM and 3SM/H-IN718 interfaces. It suggests that <001> oriented grains serve as preferred sites for ion adsorption and reactions, which might facilitate the sulfur diffusion more effectively than other grain orientations. As a result, oxy-anions generated during sulfidation enhance the fluxing mechanism, thus increasing weight gain in H-IN718.
研究了 LPBF-IN718 微观结构对 650 °C 下热腐蚀行为的影响。晶粒取向为<001>的 H-IN718 比晶粒取向为<110>的 V-IN718 的重量变化更大。详细的表征分析证实,带有 3SM 的 LPBF-IN718 中存在拉普-戈托通量和硫化机制。此外,GDOES 证实了空气/3SM 和 3SM/H-IN718 界面之间存在硫梯度。这表明,<001>取向的晶粒是离子吸附和反应的首选场所,可能比其他取向的晶粒更有效地促进硫的扩散。因此,硫化过程中产生的氧阴离子增强了通量机制,从而增加了 H-IN718 的增重。
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引用次数: 0
Corrigendum to “Correlation between the microstructure and hydrogen embrittlement resistance in a precipitation-hardened martensitic stainless steel” [Corros. Sci. 182 (2021) 109260] 沉淀硬化马氏体不锈钢的微观结构与抗氢脆性能之间的相关性"[Corros. Sci.
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-31 DOI: 10.1016/j.corsci.2024.112535
Zhe Yang , Zhenbao Liu , Jianxiong Liang , Jie Su , Zhiyong Yang , Boning Zhang , Guangmin Sheng
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引用次数: 0
Effect of rare earth oxide (Pr4O7) second phase and fine grain on the corrosion behavior of Ti-0.3Mo-0.8Ni 稀土氧化物 (Pr4O7) 第二相和细晶粒对 Ti-0.3Mo-0.8Ni 腐蚀行为的影响
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-31 DOI: 10.1016/j.corsci.2024.112549
Chaowen Zheng, Qi Wang, Ruirun Chen, Wei Wei, Yanqing Su, Hengzhi Fu
The effect of grain refinement and second phase (Pr4O7) on the corrosion mechanism of the Ti-0.3Mo-0.8Ni was studied. The Pr4O7 nanophases are distributed in the α/β phase boundaries and the β phases (Pr ≤ 0.5 wt. %). Most of the Pr4O7 phases are distributed at the boundaries (Pr ≥ 1 wt. %). The Pr element refines the primary β grains. With the increment of Pr content, the passivation film becomes more stable, denser and thicker, which prolongs the decrease time of OCP, increases the corrosion potential and reduces the corrosion tendency. After the passivation film ruptures, the Pr4O7 aggravates the galvanic corrosion.
研究了晶粒细化和第二相(Pr4O7)对钛-0.3钼-0.8镍腐蚀机理的影响。Pr4O7 纳米相分布在 α/β 相边界和 β 相中(Pr ≤ 0.5 wt.%)。大部分的 Pr4O7 相分布在边界(Pr ≥ 1 重量 %)。镨元素细化了原β晶粒。随着 Pr 含量的增加,钝化膜变得更稳定、更致密、更厚,从而延长了 OCP 的下降时间,提高了腐蚀电位,降低了腐蚀倾向。钝化膜破裂后,Pr4O7 会加剧电化学腐蚀。
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引用次数: 0
Optimizing the surface quality of electrochemical machined Ni-based single crystal superalloy via manipulation of phase and dendrite dissolution 通过控制相和枝晶溶解优化电化学加工镍基单晶超级合金的表面质量
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1016/j.corsci.2024.112548
Yongxin Liu , Xiaowei Lei , Wenbo Du , Wenjing Yao , Nan Wang
The transpassive dissolution behaviors of Ni-based single crystal superalloy in 10 %NaCl, 10 %NaNO3, and mixed solution are investigated by using potentiodynamic polarization, scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The alloy exhibits opposite yet complementary dissolution characteristics in NaCl and NaNO3 solutions. The different responses of γ/γ′ phases to Cl and NO3 contribute to the opposite dissolution behaviors of dendrites and interdendritic regions. The surface flatness is noticeably enhanced in mixed solution due to the synchronous dissolution of the γ/γ′ phases. Our work paves the way for obtaining high-quality surface in electrochemical machining of single crystal superalloys.
利用电位极化、扫描电子显微镜、能量色散 X 射线光谱和 X 射线光电子能谱研究了镍基单晶超级合金在 10%NaCl、10%NaNO3 和混合溶液中的渗透溶解行为。合金在 NaCl 和 NaNO3 溶液中表现出相反但互补的溶解特性。γ/γ′相对 Cl- 和 NO3- 的不同反应导致了树枝状和树枝间区域相反的溶解行为。在混合溶液中,由于γ/γ′相的同步溶解,表面平整度明显提高。我们的研究为在单晶超合金的电化学加工中获得高质量的表面铺平了道路。
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引用次数: 0
Corrosion behavior and microstructural effects on passivation film mechanisms in forged Ti-5Al-5Mo-5V-1Cr-1Fe titanium alloy under laser surface remelting 激光表面重熔下锻造 Ti-5Al-5Mo-5V-1Cr-1Fe 钛合金的腐蚀行为和微结构对钝化膜机制的影响
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-28 DOI: 10.1016/j.corsci.2024.112542
Wenqi Lu , Yujing Liu , Xiang Wu , Xiaochun Liu , Jincheng Wang
This study examines the corrosion behavior of Ti-5Al-5Mo-5V-1Cr-1Fe (Ti-55511), comparing forged and LSRed (laser surface remelting) samples. LSR via 0.02 mm laser interval eliminates surface macro defects, enhances element homogenization, and converts primary and secondary α to β on forged Ti-55511 surface, yielding a thicker passivation film with higher stability than that of as-forged counterpart. This study investigates corrosion mechanisms by comparing the phase type, elemental homogeneity, grain size, morphology, and defects in relation to corrosion behavior. Galvanic corrosion predominates in the as-forged sample, with intensified pitting on the α phase and oxygen accumulation near α/β phase interface, while LSR-treated sample experiences β grain boundary corrosion.
本研究比较了锻造和 LSRed(激光表面重熔)样品,研究了 Ti-5Al-5Mo-5V-1Cr-1Fe (Ti-55511)的腐蚀行为。通过 0.02 毫米的激光间隔进行 LSR,可消除表面宏观缺陷,提高元素均匀性,并将锻造 Ti-55511 表面的初级和次级 α 转化为 β,从而获得比锻造样品更厚、稳定性更高的钝化膜。本研究通过比较相类型、元素均匀性、晶粒大小、形态和缺陷与腐蚀行为的关系,研究了腐蚀机理。电化学腐蚀在模锻样品中占主导地位,α相点蚀加剧,α/β相界面附近氧气积聚,而经过 LSR 处理的样品则出现了 β 晶界腐蚀。
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引用次数: 0
Generation and correction of machine learning interatomic potential for simulation of liquid metal corrosion with near experimental accuracy: A study for iron corrosion in liquid lead 生成和修正机器学习原子间势,以接近实验精度的方式模拟液态金属腐蚀:液态铅中的铁腐蚀研究
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-28 DOI: 10.1016/j.corsci.2024.112541
Seoyeon Bak, Takuji Oda
Molecular dynamics using a machine-learning (ML) potential trained by density functional theory (DFT) calculations is an emerging computational tool that enables accurate atomistic simulations of complex phenomena. Using iron corrosion in liquid lead as a test case, we show that although an as-trained ML potential still has significant error in simulating iron solubility due to the propagation of DFT errors, a simple correction can realize near experimental accuracy. This study provides a basic framework for the construction, correction, and use of ML potentials to facilitate their advanced and widespread applications for accurate atomistic simulations on liquid metal corrosion.
使用由密度泛函理论(DFT)计算训练的机器学习(ML)势的分子动力学是一种新兴的计算工具,可以对复杂现象进行精确的原子模拟。以铁在液态铅中的腐蚀为测试案例,我们发现尽管由于 DFT 误差的传播,经过训练的 ML 势在模拟铁的溶解度时仍存在显著误差,但通过简单的修正就能实现接近实验精度的结果。本研究为 ML 电位的构建、修正和使用提供了一个基本框架,以促进其在液态金属腐蚀的精确原子模拟中的先进和广泛应用。
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引用次数: 0
Insights into the stress corrosion cracking of M54 ultra-high-strength steel in the marine environments at varying temperatures by comparison of slow strain rate tensile and crack growth tests 通过对比慢应变速率拉伸试验和裂纹生长试验,深入了解不同温度下海洋环境中 M54 超高强度钢的应力腐蚀开裂情况
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-28 DOI: 10.1016/j.corsci.2024.112543
Lijin Dong , Guohan Zhang , Shuang Li , Chengchuan Wu , Hongli Wang , Huaibei Zheng , Qinying Wang
The stress corrosion cracking of M54 steel in marine environments at varying temperatures was investigated. The slow strain rate tensile tests show that increasing the temperature from 5 to 45°C leads to a 71.9 % and 77.4 % decrease in plastic elongation ratio and reduction in area ratio in full immersion environments, while only 7.8 % and 7.9 % in atmospheric environments. The da/dtII increases from 0.75 nm/s to 5.5 nm/s in atmospheric environments, but first decreases and then increases in full immersion environments. Compared to full immersion environments, the sufficient oxygen supply within the crack in atmospheric environments lowers da/dtII by 50–80 %.
研究了不同温度下海洋环境中 M54 钢的应力腐蚀开裂情况。慢应变速率拉伸试验表明,温度从 5°C 升至 45°C 会导致完全浸泡环境下塑性伸长率和面积比分别下降 71.9% 和 77.4%,而大气环境下仅下降 7.8% 和 7.9%。在大气环境中,da/dtII 从 0.75 nm/s 增至 5.5 nm/s,但在完全浸泡环境中,da/dtII 先减小后增大。与完全浸泡环境相比,大气环境中裂缝内充足的氧气供应可将 da/dtII 降低 50-80%。
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引用次数: 0
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Corrosion Science
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