Pub Date : 2024-10-20DOI: 10.1016/j.corsci.2024.112523
Arshad Yazdanpanah , Reynier I. Revilla , Mattia Franceschi , Gioele Pagot , Mona Khodabakhshi , Iris De Graeve , Vito Di Noto , Manuele Dabalà , Sergio Lozano-Perez
This study explores the formation and degradation mechanisms of the passive layer on laser powder bed fusion (L-PBF) processed Ni-Fe-Cr-based alloy 718 using high-resolution submicron analysis and microcapillary electrochemical techniques. The findings provide new insights into passive layer breakdown under tensile loading, revealing the influence of microstructural characteristics, dislocation distribution, and mechanical stresses. Tensile loading caused oxide layer cracking near cell boundaries with higher dislocation density. Detachment of the oxide layer from the matrix created voids, allowing aggressive ions to penetrate, promoting crevice corrosion. Cell boundaries remained mostly intact, as metallic particles within the surface oxide layer.
{"title":"Exploring the mechanism of stress-induced passive layer degradation in additively manufactured Ni-Fe-Cr-based alloy 718","authors":"Arshad Yazdanpanah , Reynier I. Revilla , Mattia Franceschi , Gioele Pagot , Mona Khodabakhshi , Iris De Graeve , Vito Di Noto , Manuele Dabalà , Sergio Lozano-Perez","doi":"10.1016/j.corsci.2024.112523","DOIUrl":"10.1016/j.corsci.2024.112523","url":null,"abstract":"<div><div>This study explores the formation and degradation mechanisms of the passive layer on laser powder bed fusion (L-PBF) processed Ni-Fe-Cr-based alloy 718 using high-resolution submicron analysis and microcapillary electrochemical techniques. The findings provide new insights into passive layer breakdown under tensile loading, revealing the influence of microstructural characteristics, dislocation distribution, and mechanical stresses. Tensile loading caused oxide layer cracking near cell boundaries with higher dislocation density. Detachment of the oxide layer from the matrix created voids, allowing aggressive ions to penetrate, promoting crevice corrosion. Cell boundaries remained mostly intact, as metallic particles within the surface oxide layer.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112523"},"PeriodicalIF":7.4,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.corsci.2024.112519
Vishant Garg, Joost P.B. van Dam, Emmanouela Michailidou, Yaiza Gonzalez-Garcia
The effect of friction stir welding (FSW) on the microstructure and localised corrosion behaviour of the dissimilar weld of AA2099 T83 and AA2060 T8E30 alloys is investigated. FSW results in a drastic change in the microstructure thus altering their corrosion behaviour. The heat-affected region exhibits similar attack morphology to their respective base metal but is the most protected region. The stir zone (SZ) is the most susceptible to attack. During immersion of the entire weld, attack initiation occurs from the AA2060 SZ due to galvanic activity within the region caused by the overlap of the grains in the weld zone.
{"title":"Influence of friction stir welding on the localised corrosion behaviour of AA2060 T8E30 and AA2099 T83 Al-Li alloys","authors":"Vishant Garg, Joost P.B. van Dam, Emmanouela Michailidou, Yaiza Gonzalez-Garcia","doi":"10.1016/j.corsci.2024.112519","DOIUrl":"10.1016/j.corsci.2024.112519","url":null,"abstract":"<div><div>The effect of friction stir welding (FSW) on the microstructure and localised corrosion behaviour of the dissimilar weld of AA2099 T83 and AA2060 T8E30 alloys is investigated. FSW results in a drastic change in the microstructure thus altering their corrosion behaviour. The heat-affected region exhibits similar attack morphology to their respective base metal but is the most protected region. The stir zone (SZ) is the most susceptible to attack. During immersion of the entire weld, attack initiation occurs from the AA2060 SZ due to galvanic activity within the region caused by the overlap of the grains in the weld zone.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112519"},"PeriodicalIF":7.4,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.corsci.2024.112521
Wei Zhang , Jiuguo Deng , Yilong Zhong , Hao Liu , Ziyao Long , Rongshuo Wang , Yudong Li , Guofeng Qu , Mingyang Zhou , Jijun Yang
The microstructure and LBE corrosion behavior of the irradiated (up to 110 dpa) Fe15Cr11Al0.5Y coatings were investigated. The surface roughness and hardness increased with the irradiation dose. Irradiation induces grain growth, and the grown grains contain many dislocations, but no segregation and voids. Irradiation accelerates the corrosion rate of the coating, and the irradiated coatings suffer from serious inward non-uniform growth of the Al2O3 layer. The reaction of Al2O3 with PbO promoted the formation of the outermost PbAl2O4 of the irradiated coating. A “competitive mechanism” was proposed to explain the evolution of the corrosion behavior of the irradiated coatings.
{"title":"Microstructure response and LBE corrosion behavior of the FeCrAlY coating after Au-ions irradiation","authors":"Wei Zhang , Jiuguo Deng , Yilong Zhong , Hao Liu , Ziyao Long , Rongshuo Wang , Yudong Li , Guofeng Qu , Mingyang Zhou , Jijun Yang","doi":"10.1016/j.corsci.2024.112521","DOIUrl":"10.1016/j.corsci.2024.112521","url":null,"abstract":"<div><div>The microstructure and LBE corrosion behavior of the irradiated (up to 110 dpa) Fe15Cr11Al0.5Y coatings were investigated. The surface roughness and hardness increased with the irradiation dose. Irradiation induces grain growth, and the grown grains contain many dislocations, but no segregation and voids. Irradiation accelerates the corrosion rate of the coating, and the irradiated coatings suffer from serious inward non-uniform growth of the Al<sub>2</sub>O<sub>3</sub> layer. The reaction of Al<sub>2</sub>O<sub>3</sub> with PbO promoted the formation of the outermost PbAl<sub>2</sub>O<sub>4</sub> of the irradiated coating. A “competitive mechanism” was proposed to explain the evolution of the corrosion behavior of the irradiated coatings.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112521"},"PeriodicalIF":7.4,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-18DOI: 10.1016/j.corsci.2024.112522
Yuling Lu , Yuxing Peng , Xiangdong Chang , Zhiyuan Shi
(NiCrCo)82Ti9Al9 high−entropy alloy was attached to act as coating material by combining of laser cladding and laser remelting. In this study, the electrochemical properties of obtained HEA coatings were comparatively investigated using an electrochemical workstation, and the corrosion mechanism was revealed by the density functional theory calculations. The results show that the laser cladded HEA coating is mainly consisted of face-centered and body-centered cubic structures, and the face-centered cubic structure of the laser cladded HEA coating is transferred to the amorphous structure by laser remelting, which provides the stronger anti−corrosion capability compared with the face-centered cubic structure of HEA coating.
(NiCrCo)82Ti9Al9 高熵合金通过激光熔覆和激光重熔相结合的方法作为涂层材料。本研究利用电化学工作站对所获得的 HEA 涂层的电化学性能进行了比较研究,并通过密度泛函理论计算揭示了其腐蚀机理。结果表明,激光熔覆的 HEA 涂层主要由面心立方结构和体心立方结构组成,激光熔覆的 HEA 涂层的面心立方结构通过激光重熔转移到了非晶态结构,与面心立方结构的 HEA 涂层相比,非晶态结构的 HEA 涂层具有更强的抗腐蚀能力。
{"title":"Atomic-scale insight on nanostructures and electrochemical properties of (NiCrCo)82Ti9Al9 high-entropy alloy coatings by density functional theory calculations","authors":"Yuling Lu , Yuxing Peng , Xiangdong Chang , Zhiyuan Shi","doi":"10.1016/j.corsci.2024.112522","DOIUrl":"10.1016/j.corsci.2024.112522","url":null,"abstract":"<div><div>(NiCrCo)<sub>82</sub>Ti<sub>9</sub>Al<sub>9</sub> high−entropy alloy was attached to act as coating material by combining of laser cladding and laser remelting. In this study, the electrochemical properties of obtained HEA coatings were comparatively investigated using an electrochemical workstation, and the corrosion mechanism was revealed by the density functional theory calculations. The results show that the laser cladded HEA coating is mainly consisted of face-centered and body-centered cubic structures, and the face-centered cubic structure of the laser cladded HEA coating is transferred to the amorphous structure by laser remelting, which provides the stronger anti−corrosion capability compared with the face-centered cubic structure of HEA coating.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112522"},"PeriodicalIF":7.4,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
β-type Ti alloys have drawn extensive attention as potential metallic implants. In this work, the microstructure, corrosion behavior, and wear performance of Ti−17.3 Nb−1.8Fe (TNF) and Ti−22 Nb−30Zr−4Cr (TNZC) biomedical alloys were experimentally investigated, and CP−Ti and Ti6Al4V alloy were also used for comparisons. TNF and TNZC alloys after solution treatment at 1273 K showed a single β phase. It was found that TNF and TNZC alloys revealed better corrosion resistance than CP−Ti and Ti6Al4V alloy in different artificial saliva containing 0.15 wt% NaF with the pH values of 3.9 and 5.7, which could be ascribed to the formation of a double-layer passive film composed of multiple species oxides. Moreover, TNF and TNZC alloys exhibited higher wear resistance compared with CP−Ti and Ti6Al4V alloy, whose wear mechanism was adhesive wear and abrasive wear. The present results show that TNF and TNZC alloys are nice candidates for dental application.
{"title":"Design of new β-type Ti alloys with outstanding corrosion and wear resistance for dental application","authors":"Haoqin Lin , Guangxu Zhang , Weimin Chen , Kaihong Zheng , Fuxing Yin","doi":"10.1016/j.corsci.2024.112520","DOIUrl":"10.1016/j.corsci.2024.112520","url":null,"abstract":"<div><div><em>β</em>-type Ti alloys have drawn extensive attention as potential metallic implants. In this work, the microstructure, corrosion behavior, and wear performance of Ti−17.3 Nb−1.8Fe (TNF) and Ti−22 Nb−30Zr−4Cr (TNZC) biomedical alloys were experimentally investigated, and CP−Ti and Ti6Al4V alloy were also used for comparisons. TNF and TNZC alloys after solution treatment at 1273 K showed a single β phase. It was found that TNF and TNZC alloys revealed better corrosion resistance than CP−Ti and Ti6Al4V alloy in different artificial saliva containing 0.15 wt% NaF with the pH values of 3.9 and 5.7, which could be ascribed to the formation of a double-layer passive film composed of multiple species oxides. Moreover, TNF and TNZC alloys exhibited higher wear resistance compared with CP−Ti and Ti6Al4V alloy, whose wear mechanism was adhesive wear and abrasive wear. The present results show that TNF and TNZC alloys are nice candidates for dental application.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112520"},"PeriodicalIF":7.4,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-18DOI: 10.1016/j.corsci.2024.112513
Maria A. Osipenko , Andrei V. Paspelau , Aliaksandr A. Kasach , Jacek Ryl , Konrad Skowron , Janusz Adamiec , Irina I. Kurilo , Dzmitry S. Kharytonau
Corrosion of lithium-containing AZ31 magnesium alloys AZ31-xLi (x = 4, 8, and 12 wt%) has been examined in 0.05 M NaCl solution with and without 10–150 mM of Na2MoO4 inhibitor. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and dynamic electrochemical impedance spectroscopy (DEIS) measurements were used to correlate the phase composition and microstructure of the alloys with their corrosion propensity and effectiveness of the molybdate inhibitor, giving high inhibition efficiency (>85%) at concentrations higher than ca. 35 mM. Post-corrosion microstructure, Raman, and X-ray photoelectron spectroscopy analyses allowed to provide the inhibition mechanism of AZ31-xLi alloys by molybdate ions.
在含有或不含有 10-150 mM Na2MoO4 抑制剂的 0.05 M NaCl 溶液中,研究了含锂 AZ31 镁合金 AZ31-xLi(x = 4、8 和 12 wt%)的腐蚀情况。采用电位极化、电化学阻抗谱(EIS)和动态电化学阻抗谱(DEIS)测量方法,将合金的相组成和微观结构与其腐蚀倾向和钼酸盐抑制剂的有效性联系起来,当浓度高于约 35 mM 时,抑制效率高(85%)。腐蚀后的微观结构、拉曼光谱和 X 射线光电子能谱分析提供了钼酸盐离子对 AZ31-xLi 合金的抑制机制。
{"title":"Corrosion Inhibition of AZ31-xLi (x = 4, 8, 12) magnesium alloys in sodium chloride solutions by aqueous molybdate","authors":"Maria A. Osipenko , Andrei V. Paspelau , Aliaksandr A. Kasach , Jacek Ryl , Konrad Skowron , Janusz Adamiec , Irina I. Kurilo , Dzmitry S. Kharytonau","doi":"10.1016/j.corsci.2024.112513","DOIUrl":"10.1016/j.corsci.2024.112513","url":null,"abstract":"<div><div>Corrosion of lithium-containing AZ31 magnesium alloys AZ31-<em>x</em>Li (<em>x</em> = 4, 8, and 12 wt%) has been examined in 0.05 M NaCl solution with and without 10–150 mM of Na<sub>2</sub>MoO<sub>4</sub> inhibitor. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and dynamic electrochemical impedance spectroscopy (DEIS) measurements were used to correlate the phase composition and microstructure of the alloys with their corrosion propensity and effectiveness of the molybdate inhibitor, giving high inhibition efficiency (>85%) at concentrations higher than ca. 35 mM. Post-corrosion microstructure, Raman, and X-ray photoelectron spectroscopy analyses allowed to provide the inhibition mechanism of AZ31-<em>x</em>Li alloys by molybdate ions.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112513"},"PeriodicalIF":7.4,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-16DOI: 10.1016/j.corsci.2024.112517
Jinxin Xue , Chilou Zhou , Pengzhi Dai , Xianhui Liu , Hao Wu , Xinfeng Li , Paul K. Chu
WS2 is a two-dimensional nanomaterial with significant potential for hydrogen barrier applications. Herein, WS2/Ni composite coatings were fabricated on X70 pipeline steel substrates via electrodeposition. The properties of the composite coatings were systematically examined by electrochemical hydrogen permeation tests, hydrogen evolution kinetics tests, SSRT, SKPFM, and FEM. The results indicate that varying the deposition time leads to changes in coating microstructure, which correspondingly influence hydrogen permeation performance. Furthermore, the hydrogen barrier mechanism of the WS2/Ni composite coatings involves two key processes: the inhibition of hydrogen evolution reactions on the coating surface and hydrogen adsorption by WS2 within the coating interior.
{"title":"Manipulating nano-WS2 aggregates in electroplated Ni coating to mitigate hydrogen embrittlement in X70 pipeline steel","authors":"Jinxin Xue , Chilou Zhou , Pengzhi Dai , Xianhui Liu , Hao Wu , Xinfeng Li , Paul K. Chu","doi":"10.1016/j.corsci.2024.112517","DOIUrl":"10.1016/j.corsci.2024.112517","url":null,"abstract":"<div><div>WS<sub>2</sub> is a two-dimensional nanomaterial with significant potential for hydrogen barrier applications. Herein, WS<sub>2</sub>/Ni composite coatings were fabricated on X70 pipeline steel substrates via electrodeposition. The properties of the composite coatings were systematically examined by electrochemical hydrogen permeation tests, hydrogen evolution kinetics tests, SSRT, SKPFM, and FEM. The results indicate that varying the deposition time leads to changes in coating microstructure, which correspondingly influence hydrogen permeation performance. Furthermore, the hydrogen barrier mechanism of the WS<sub>2</sub>/Ni composite coatings involves two key processes: the inhibition of hydrogen evolution reactions on the coating surface and hydrogen adsorption by WS<sub>2</sub> within the coating interior.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112517"},"PeriodicalIF":7.4,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-16DOI: 10.1016/j.corsci.2024.112518
Lindsay Grandy , Robert Lacasse , Jonathan Ralph Adsetts , Christophe Hitz , Danny Chhin , Janine Mauzeroll
Single pits were visually and electrochemically followed during their growth on a S41500 martensitic SS microelectrode. Solid particles were observed ejecting from the growing pit and after extraction, EDX determined they were mostly iron-based hydroxides/oxides. These particles were carried by fluid flow originating from the pit at a velocity of 21 μm/s. Finite element modeling confirmed the observed flow speeds are achievable by natural convection due to metal ion density gradients. While the pit solution does not experience flow, the bulk solution pH was observed to decrease illustrating how natural convection affects the bulk solution chemistry.
{"title":"Observation of natural convection and particle ejection from stainless steel single pits","authors":"Lindsay Grandy , Robert Lacasse , Jonathan Ralph Adsetts , Christophe Hitz , Danny Chhin , Janine Mauzeroll","doi":"10.1016/j.corsci.2024.112518","DOIUrl":"10.1016/j.corsci.2024.112518","url":null,"abstract":"<div><div>Single pits were visually and electrochemically followed during their growth on a S41500 martensitic SS microelectrode. Solid particles were observed ejecting from the growing pit and after extraction, EDX determined they were mostly iron-based hydroxides/oxides. These particles were carried by fluid flow originating from the pit at a velocity of 21 μm/s. Finite element modeling confirmed the observed flow speeds are achievable by natural convection due to metal ion density gradients. While the pit solution does not experience flow, the bulk solution pH was observed to decrease illustrating how natural convection affects the bulk solution chemistry.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112518"},"PeriodicalIF":7.4,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-16DOI: 10.1016/j.corsci.2024.112514
Ming Liu , Lining Xu , Lijie Qiao , Yu Yan , Binglu Zhang , Xuehan Wang
The coupling effect of hydrogen and NbCrN precipitate on pitting initiation and propagation of stainless steel were studied. After hydrogen charging, HMT results showed that more hydrogen was enriched on and around the precipitates. According to In-situ SKPFM and immersion results, the Volta potential of the precipitates is higher than that of the matrix before and after hydrogen charging. However, after hydrogen charging, a low Volta potential region appeared around the precipitates. The enrichment of hydrogen around the precipitates, the low potential around the precipitates, and consequent galvanic coupling effect lead to pits preferentially initiating and developing around the precipitates.
{"title":"Coupling effect of precipitates and hydrogen on pitting corrosion of stainless steel: Low potential region around precipitates","authors":"Ming Liu , Lining Xu , Lijie Qiao , Yu Yan , Binglu Zhang , Xuehan Wang","doi":"10.1016/j.corsci.2024.112514","DOIUrl":"10.1016/j.corsci.2024.112514","url":null,"abstract":"<div><div>The coupling effect of hydrogen and NbCrN precipitate on pitting initiation and propagation of stainless steel were studied. After hydrogen charging, HMT results showed that more hydrogen was enriched on and around the precipitates. According to In-situ SKPFM and immersion results, the Volta potential of the precipitates is higher than that of the matrix before and after hydrogen charging. However, after hydrogen charging, a low Volta potential region appeared around the precipitates. The enrichment of hydrogen around the precipitates, the low potential around the precipitates, and consequent galvanic coupling effect lead to pits preferentially initiating and developing around the precipitates.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112514"},"PeriodicalIF":7.4,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-15DOI: 10.1016/j.corsci.2024.112510
Zhice Yang , Chaoran Ma , Yuxin Zhang , Zhuoyang Du , Peng Zhou , Yang Zhao , Tao Zhang , Fuhui Wang
Special gases with trace moisture cause the formation of dynamic acidic microdroplets (DMD), which results in corrosion of semiconductor manufacturing devices. In this study, a predictive model for corrosion damage in 316L stainless steel (SS) was developed by combining the DMD process and the pitting initiation model. The DMD process was modeled using the BET model to describe the moisture-to-solution conversion. The pitting initiation model was reconstructed by incorporating the Sridhar model, temporal corrosion model, and Macdonald model. Finally, the predicted results were validated by various experimental data, indicating that the prediction model was accurate and highly reliable.
{"title":"Corrosion-life prediction model for 316L stainless steel under electronic special gases containing trace moisture employed in semiconductor manufacturing industry","authors":"Zhice Yang , Chaoran Ma , Yuxin Zhang , Zhuoyang Du , Peng Zhou , Yang Zhao , Tao Zhang , Fuhui Wang","doi":"10.1016/j.corsci.2024.112510","DOIUrl":"10.1016/j.corsci.2024.112510","url":null,"abstract":"<div><div>Special gases with trace moisture cause the formation of dynamic acidic microdroplets (DMD), which results in corrosion of semiconductor manufacturing devices. In this study, a predictive model for corrosion damage in 316L stainless steel (SS) was developed by combining the DMD process and the pitting initiation model. The DMD process was modeled using the BET model to describe the moisture-to-solution conversion. The pitting initiation model was reconstructed by incorporating the Sridhar model, temporal corrosion model, and Macdonald model. Finally, the predicted results were validated by various experimental data, indicating that the prediction model was accurate and highly reliable.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112510"},"PeriodicalIF":7.4,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}