首页 > 最新文献

Corrosion Science最新文献

英文 中文
Exploring the mechanism of stress-induced passive layer degradation in additively manufactured Ni-Fe-Cr-based alloy 718 探索添加式制造的镍-铁-铬基 718 合金中应力诱导被动层降解的机理
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-20 DOI: 10.1016/j.corsci.2024.112523
Arshad Yazdanpanah , Reynier I. Revilla , Mattia Franceschi , Gioele Pagot , Mona Khodabakhshi , Iris De Graeve , Vito Di Noto , Manuele Dabalà , Sergio Lozano-Perez
This study explores the formation and degradation mechanisms of the passive layer on laser powder bed fusion (L-PBF) processed Ni-Fe-Cr-based alloy 718 using high-resolution submicron analysis and microcapillary electrochemical techniques. The findings provide new insights into passive layer breakdown under tensile loading, revealing the influence of microstructural characteristics, dislocation distribution, and mechanical stresses. Tensile loading caused oxide layer cracking near cell boundaries with higher dislocation density. Detachment of the oxide layer from the matrix created voids, allowing aggressive ions to penetrate, promoting crevice corrosion. Cell boundaries remained mostly intact, as metallic particles within the surface oxide layer.
本研究采用高分辨率亚微米分析和微毛细管电化学技术,探讨了激光粉末床熔化(L-PBF)加工的镍-铁-铬基合金 718 上被动层的形成和降解机制。研究结果为拉伸载荷下的被动层破坏提供了新的见解,揭示了微结构特征、位错分布和机械应力的影响。拉伸加载导致位错密度较高的晶胞边界附近的氧化层开裂。氧化层与基体脱离产生空隙,使侵蚀性离子得以渗透,从而促进缝隙腐蚀。晶胞边界大部分保持完好,表面氧化层中有金属颗粒。
{"title":"Exploring the mechanism of stress-induced passive layer degradation in additively manufactured Ni-Fe-Cr-based alloy 718","authors":"Arshad Yazdanpanah ,&nbsp;Reynier I. Revilla ,&nbsp;Mattia Franceschi ,&nbsp;Gioele Pagot ,&nbsp;Mona Khodabakhshi ,&nbsp;Iris De Graeve ,&nbsp;Vito Di Noto ,&nbsp;Manuele Dabalà ,&nbsp;Sergio Lozano-Perez","doi":"10.1016/j.corsci.2024.112523","DOIUrl":"10.1016/j.corsci.2024.112523","url":null,"abstract":"<div><div>This study explores the formation and degradation mechanisms of the passive layer on laser powder bed fusion (L-PBF) processed Ni-Fe-Cr-based alloy 718 using high-resolution submicron analysis and microcapillary electrochemical techniques. The findings provide new insights into passive layer breakdown under tensile loading, revealing the influence of microstructural characteristics, dislocation distribution, and mechanical stresses. Tensile loading caused oxide layer cracking near cell boundaries with higher dislocation density. Detachment of the oxide layer from the matrix created voids, allowing aggressive ions to penetrate, promoting crevice corrosion. Cell boundaries remained mostly intact, as metallic particles within the surface oxide layer.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112523"},"PeriodicalIF":7.4,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of friction stir welding on the localised corrosion behaviour of AA2060 T8E30 and AA2099 T83 Al-Li alloys 搅拌摩擦焊对 AA2060 T8E30 和 AA2099 T83 Al-Li 合金局部腐蚀行为的影响
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-19 DOI: 10.1016/j.corsci.2024.112519
Vishant Garg, Joost P.B. van Dam, Emmanouela Michailidou, Yaiza Gonzalez-Garcia
The effect of friction stir welding (FSW) on the microstructure and localised corrosion behaviour of the dissimilar weld of AA2099 T83 and AA2060 T8E30 alloys is investigated. FSW results in a drastic change in the microstructure thus altering their corrosion behaviour. The heat-affected region exhibits similar attack morphology to their respective base metal but is the most protected region. The stir zone (SZ) is the most susceptible to attack. During immersion of the entire weld, attack initiation occurs from the AA2060 SZ due to galvanic activity within the region caused by the overlap of the grains in the weld zone.
本研究探讨了搅拌摩擦焊(FSW)对 AA2099 T83 和 AA2060 T8E30 异种合金焊缝的微观结构和局部腐蚀行为的影响。FSW 导致微观结构发生剧烈变化,从而改变了它们的腐蚀行为。热影响区呈现出与各自基体金属相似的侵蚀形态,但却是受保护最严重的区域。搅拌区(SZ)最容易受到侵蚀。在整个焊缝的浸泡过程中,由于焊接区晶粒的重叠导致区域内的电偶活动,攻击从 AA2060 SZ 开始。
{"title":"Influence of friction stir welding on the localised corrosion behaviour of AA2060 T8E30 and AA2099 T83 Al-Li alloys","authors":"Vishant Garg,&nbsp;Joost P.B. van Dam,&nbsp;Emmanouela Michailidou,&nbsp;Yaiza Gonzalez-Garcia","doi":"10.1016/j.corsci.2024.112519","DOIUrl":"10.1016/j.corsci.2024.112519","url":null,"abstract":"<div><div>The effect of friction stir welding (FSW) on the microstructure and localised corrosion behaviour of the dissimilar weld of AA2099 T83 and AA2060 T8E30 alloys is investigated. FSW results in a drastic change in the microstructure thus altering their corrosion behaviour. The heat-affected region exhibits similar attack morphology to their respective base metal but is the most protected region. The stir zone (SZ) is the most susceptible to attack. During immersion of the entire weld, attack initiation occurs from the AA2060 SZ due to galvanic activity within the region caused by the overlap of the grains in the weld zone.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112519"},"PeriodicalIF":7.4,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure response and LBE corrosion behavior of the FeCrAlY coating after Au-ions irradiation 金离子照射后 FeCrAlY 涂层的微观结构响应和 LBE 腐蚀行为
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-19 DOI: 10.1016/j.corsci.2024.112521
Wei Zhang , Jiuguo Deng , Yilong Zhong , Hao Liu , Ziyao Long , Rongshuo Wang , Yudong Li , Guofeng Qu , Mingyang Zhou , Jijun Yang
The microstructure and LBE corrosion behavior of the irradiated (up to 110 dpa) Fe15Cr11Al0.5Y coatings were investigated. The surface roughness and hardness increased with the irradiation dose. Irradiation induces grain growth, and the grown grains contain many dislocations, but no segregation and voids. Irradiation accelerates the corrosion rate of the coating, and the irradiated coatings suffer from serious inward non-uniform growth of the Al2O3 layer. The reaction of Al2O3 with PbO promoted the formation of the outermost PbAl2O4 of the irradiated coating. A “competitive mechanism” was proposed to explain the evolution of the corrosion behavior of the irradiated coatings.
研究了经过辐照(最高 110 dpa)的 Fe15Cr11Al0.5Y 涂层的微观结构和 LBE 腐蚀行为。表面粗糙度和硬度随辐照剂量的增加而增加。辐照诱导晶粒长大,长大的晶粒含有许多位错,但没有偏析和空隙。辐照加快了涂层的腐蚀速度,辐照涂层的 Al2O3 层严重向内不均匀生长。Al2O3 与 PbO 的反应促进了辐照涂层最外层 PbAl2O4 的形成。提出了一种 "竞争机制 "来解释辐照涂层腐蚀行为的演变。
{"title":"Microstructure response and LBE corrosion behavior of the FeCrAlY coating after Au-ions irradiation","authors":"Wei Zhang ,&nbsp;Jiuguo Deng ,&nbsp;Yilong Zhong ,&nbsp;Hao Liu ,&nbsp;Ziyao Long ,&nbsp;Rongshuo Wang ,&nbsp;Yudong Li ,&nbsp;Guofeng Qu ,&nbsp;Mingyang Zhou ,&nbsp;Jijun Yang","doi":"10.1016/j.corsci.2024.112521","DOIUrl":"10.1016/j.corsci.2024.112521","url":null,"abstract":"<div><div>The microstructure and LBE corrosion behavior of the irradiated (up to 110 dpa) Fe15Cr11Al0.5Y coatings were investigated. The surface roughness and hardness increased with the irradiation dose. Irradiation induces grain growth, and the grown grains contain many dislocations, but no segregation and voids. Irradiation accelerates the corrosion rate of the coating, and the irradiated coatings suffer from serious inward non-uniform growth of the Al<sub>2</sub>O<sub>3</sub> layer. The reaction of Al<sub>2</sub>O<sub>3</sub> with PbO promoted the formation of the outermost PbAl<sub>2</sub>O<sub>4</sub> of the irradiated coating. A “competitive mechanism” was proposed to explain the evolution of the corrosion behavior of the irradiated coatings.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112521"},"PeriodicalIF":7.4,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Atomic-scale insight on nanostructures and electrochemical properties of (NiCrCo)82Ti9Al9 high-entropy alloy coatings by density functional theory calculations 通过密度泛函理论计算深入了解 (NiCrCo)82Ti9Al9 高熵合金镀层的纳米结构和电化学特性的原子尺度特性
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-18 DOI: 10.1016/j.corsci.2024.112522
Yuling Lu , Yuxing Peng , Xiangdong Chang , Zhiyuan Shi
(NiCrCo)82Ti9Al9 high−entropy alloy was attached to act as coating material by combining of laser cladding and laser remelting. In this study, the electrochemical properties of obtained HEA coatings were comparatively investigated using an electrochemical workstation, and the corrosion mechanism was revealed by the density functional theory calculations. The results show that the laser cladded HEA coating is mainly consisted of face-centered and body-centered cubic structures, and the face-centered cubic structure of the laser cladded HEA coating is transferred to the amorphous structure by laser remelting, which provides the stronger anti−corrosion capability compared with the face-centered cubic structure of HEA coating.
(NiCrCo)82Ti9Al9 高熵合金通过激光熔覆和激光重熔相结合的方法作为涂层材料。本研究利用电化学工作站对所获得的 HEA 涂层的电化学性能进行了比较研究,并通过密度泛函理论计算揭示了其腐蚀机理。结果表明,激光熔覆的 HEA 涂层主要由面心立方结构和体心立方结构组成,激光熔覆的 HEA 涂层的面心立方结构通过激光重熔转移到了非晶态结构,与面心立方结构的 HEA 涂层相比,非晶态结构的 HEA 涂层具有更强的抗腐蚀能力。
{"title":"Atomic-scale insight on nanostructures and electrochemical properties of (NiCrCo)82Ti9Al9 high-entropy alloy coatings by density functional theory calculations","authors":"Yuling Lu ,&nbsp;Yuxing Peng ,&nbsp;Xiangdong Chang ,&nbsp;Zhiyuan Shi","doi":"10.1016/j.corsci.2024.112522","DOIUrl":"10.1016/j.corsci.2024.112522","url":null,"abstract":"<div><div>(NiCrCo)<sub>82</sub>Ti<sub>9</sub>Al<sub>9</sub> high−entropy alloy was attached to act as coating material by combining of laser cladding and laser remelting. In this study, the electrochemical properties of obtained HEA coatings were comparatively investigated using an electrochemical workstation, and the corrosion mechanism was revealed by the density functional theory calculations. The results show that the laser cladded HEA coating is mainly consisted of face-centered and body-centered cubic structures, and the face-centered cubic structure of the laser cladded HEA coating is transferred to the amorphous structure by laser remelting, which provides the stronger anti−corrosion capability compared with the face-centered cubic structure of HEA coating.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112522"},"PeriodicalIF":7.4,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design of new β-type Ti alloys with outstanding corrosion and wear resistance for dental application 为牙科应用设计具有出色耐腐蚀性和耐磨性的新型 β 型钛合金
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-18 DOI: 10.1016/j.corsci.2024.112520
Haoqin Lin , Guangxu Zhang , Weimin Chen , Kaihong Zheng , Fuxing Yin
β-type Ti alloys have drawn extensive attention as potential metallic implants. In this work, the microstructure, corrosion behavior, and wear performance of Ti−17.3 Nb−1.8Fe (TNF) and Ti−22 Nb−30Zr−4Cr (TNZC) biomedical alloys were experimentally investigated, and CP−Ti and Ti6Al4V alloy were also used for comparisons. TNF and TNZC alloys after solution treatment at 1273 K showed a single β phase. It was found that TNF and TNZC alloys revealed better corrosion resistance than CP−Ti and Ti6Al4V alloy in different artificial saliva containing 0.15 wt% NaF with the pH values of 3.9 and 5.7, which could be ascribed to the formation of a double-layer passive film composed of multiple species oxides. Moreover, TNF and TNZC alloys exhibited higher wear resistance compared with CP−Ti and Ti6Al4V alloy, whose wear mechanism was adhesive wear and abrasive wear. The present results show that TNF and TNZC alloys are nice candidates for dental application.
β型钛合金作为潜在的金属植入物已引起广泛关注。本文通过实验研究了 Ti-17.3 Nb-1.8Fe (TNF)和 Ti-22 Nb-30Zr-4Cr (TNZC)生物医用合金的微观结构、腐蚀行为和磨损性能,并使用 CP-Ti 和 Ti6Al4V 合金进行对比。TNF 和 TNZC 合金在 1273 K 溶液处理后呈现单一的 β 相。研究发现,在 pH 值为 3.9 和 5.7、含 0.15 wt% NaF 的不同人工唾液中,TNF 和 TNZC 合金显示出比 CP-Ti 和 Ti6Al4V 合金更好的耐腐蚀性,这可能是由于形成了由多种氧化物组成的双层被动膜。此外,与 CP-Ti 和 Ti6Al4V 合金相比,TNF 和 TNZC 合金表现出更高的耐磨性,其磨损机制为粘着磨损和磨料磨损。本研究结果表明,TNF 和 TNZC 合金是牙科应用的理想材料。
{"title":"Design of new β-type Ti alloys with outstanding corrosion and wear resistance for dental application","authors":"Haoqin Lin ,&nbsp;Guangxu Zhang ,&nbsp;Weimin Chen ,&nbsp;Kaihong Zheng ,&nbsp;Fuxing Yin","doi":"10.1016/j.corsci.2024.112520","DOIUrl":"10.1016/j.corsci.2024.112520","url":null,"abstract":"<div><div><em>β</em>-type Ti alloys have drawn extensive attention as potential metallic implants. In this work, the microstructure, corrosion behavior, and wear performance of Ti−17.3 Nb−1.8Fe (TNF) and Ti−22 Nb−30Zr−4Cr (TNZC) biomedical alloys were experimentally investigated, and CP−Ti and Ti6Al4V alloy were also used for comparisons. TNF and TNZC alloys after solution treatment at 1273 K showed a single β phase. It was found that TNF and TNZC alloys revealed better corrosion resistance than CP−Ti and Ti6Al4V alloy in different artificial saliva containing 0.15 wt% NaF with the pH values of 3.9 and 5.7, which could be ascribed to the formation of a double-layer passive film composed of multiple species oxides. Moreover, TNF and TNZC alloys exhibited higher wear resistance compared with CP−Ti and Ti6Al4V alloy, whose wear mechanism was adhesive wear and abrasive wear. The present results show that TNF and TNZC alloys are nice candidates for dental application.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112520"},"PeriodicalIF":7.4,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion Inhibition of AZ31-xLi (x = 4, 8, 12) magnesium alloys in sodium chloride solutions by aqueous molybdate 钼酸盐水溶液对氯化钠溶液中 AZ31-xLi(x = 4、8、12)镁合金的缓蚀作用
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-18 DOI: 10.1016/j.corsci.2024.112513
Maria A. Osipenko , Andrei V. Paspelau , Aliaksandr A. Kasach , Jacek Ryl , Konrad Skowron , Janusz Adamiec , Irina I. Kurilo , Dzmitry S. Kharytonau
Corrosion of lithium-containing AZ31 magnesium alloys AZ31-xLi (x = 4, 8, and 12 wt%) has been examined in 0.05 M NaCl solution with and without 10–150 mM of Na2MoO4 inhibitor. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and dynamic electrochemical impedance spectroscopy (DEIS) measurements were used to correlate the phase composition and microstructure of the alloys with their corrosion propensity and effectiveness of the molybdate inhibitor, giving high inhibition efficiency (>85%) at concentrations higher than ca. 35 mM. Post-corrosion microstructure, Raman, and X-ray photoelectron spectroscopy analyses allowed to provide the inhibition mechanism of AZ31-xLi alloys by molybdate ions.
在含有或不含有 10-150 mM Na2MoO4 抑制剂的 0.05 M NaCl 溶液中,研究了含锂 AZ31 镁合金 AZ31-xLi(x = 4、8 和 12 wt%)的腐蚀情况。采用电位极化、电化学阻抗谱(EIS)和动态电化学阻抗谱(DEIS)测量方法,将合金的相组成和微观结构与其腐蚀倾向和钼酸盐抑制剂的有效性联系起来,当浓度高于约 35 mM 时,抑制效率高(85%)。腐蚀后的微观结构、拉曼光谱和 X 射线光电子能谱分析提供了钼酸盐离子对 AZ31-xLi 合金的抑制机制。
{"title":"Corrosion Inhibition of AZ31-xLi (x = 4, 8, 12) magnesium alloys in sodium chloride solutions by aqueous molybdate","authors":"Maria A. Osipenko ,&nbsp;Andrei V. Paspelau ,&nbsp;Aliaksandr A. Kasach ,&nbsp;Jacek Ryl ,&nbsp;Konrad Skowron ,&nbsp;Janusz Adamiec ,&nbsp;Irina I. Kurilo ,&nbsp;Dzmitry S. Kharytonau","doi":"10.1016/j.corsci.2024.112513","DOIUrl":"10.1016/j.corsci.2024.112513","url":null,"abstract":"<div><div>Corrosion of lithium-containing AZ31 magnesium alloys AZ31-<em>x</em>Li (<em>x</em> = 4, 8, and 12 wt%) has been examined in 0.05 M NaCl solution with and without 10–150 mM of Na<sub>2</sub>MoO<sub>4</sub> inhibitor. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and dynamic electrochemical impedance spectroscopy (DEIS) measurements were used to correlate the phase composition and microstructure of the alloys with their corrosion propensity and effectiveness of the molybdate inhibitor, giving high inhibition efficiency (&gt;85%) at concentrations higher than ca. 35 mM. Post-corrosion microstructure, Raman, and X-ray photoelectron spectroscopy analyses allowed to provide the inhibition mechanism of AZ31-<em>x</em>Li alloys by molybdate ions.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112513"},"PeriodicalIF":7.4,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Manipulating nano-WS2 aggregates in electroplated Ni coating to mitigate hydrogen embrittlement in X70 pipeline steel 操纵电镀镍涂层中的纳米 WS2 聚集体缓解 X70 管线钢中的氢脆现象
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-16 DOI: 10.1016/j.corsci.2024.112517
Jinxin Xue , Chilou Zhou , Pengzhi Dai , Xianhui Liu , Hao Wu , Xinfeng Li , Paul K. Chu
WS2 is a two-dimensional nanomaterial with significant potential for hydrogen barrier applications. Herein, WS2/Ni composite coatings were fabricated on X70 pipeline steel substrates via electrodeposition. The properties of the composite coatings were systematically examined by electrochemical hydrogen permeation tests, hydrogen evolution kinetics tests, SSRT, SKPFM, and FEM. The results indicate that varying the deposition time leads to changes in coating microstructure, which correspondingly influence hydrogen permeation performance. Furthermore, the hydrogen barrier mechanism of the WS2/Ni composite coatings involves two key processes: the inhibition of hydrogen evolution reactions on the coating surface and hydrogen adsorption by WS2 within the coating interior.
WS2 是一种二维纳米材料,在氢气阻隔方面具有巨大的应用潜力。本文通过电沉积法在 X70 管线钢基底上制备了 WS2/Ni 复合涂层。通过电化学氢渗透试验、氢演化动力学试验、SSRT、SKPFM 和有限元分析,对复合涂层的性能进行了系统检测。结果表明,改变沉积时间会导致涂层微观结构发生变化,从而相应地影响氢渗透性能。此外,WS2/Ni 复合涂层的阻氢机理涉及两个关键过程:涂层表面对氢演化反应的抑制和涂层内部 WS2 对氢的吸附。
{"title":"Manipulating nano-WS2 aggregates in electroplated Ni coating to mitigate hydrogen embrittlement in X70 pipeline steel","authors":"Jinxin Xue ,&nbsp;Chilou Zhou ,&nbsp;Pengzhi Dai ,&nbsp;Xianhui Liu ,&nbsp;Hao Wu ,&nbsp;Xinfeng Li ,&nbsp;Paul K. Chu","doi":"10.1016/j.corsci.2024.112517","DOIUrl":"10.1016/j.corsci.2024.112517","url":null,"abstract":"<div><div>WS<sub>2</sub> is a two-dimensional nanomaterial with significant potential for hydrogen barrier applications. Herein, WS<sub>2</sub>/Ni composite coatings were fabricated on X70 pipeline steel substrates via electrodeposition. The properties of the composite coatings were systematically examined by electrochemical hydrogen permeation tests, hydrogen evolution kinetics tests, SSRT, SKPFM, and FEM. The results indicate that varying the deposition time leads to changes in coating microstructure, which correspondingly influence hydrogen permeation performance. Furthermore, the hydrogen barrier mechanism of the WS<sub>2</sub>/Ni composite coatings involves two key processes: the inhibition of hydrogen evolution reactions on the coating surface and hydrogen adsorption by WS<sub>2</sub> within the coating interior.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112517"},"PeriodicalIF":7.4,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Observation of natural convection and particle ejection from stainless steel single pits 观察不锈钢单坑的自然对流和颗粒喷射
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-16 DOI: 10.1016/j.corsci.2024.112518
Lindsay Grandy , Robert Lacasse , Jonathan Ralph Adsetts , Christophe Hitz , Danny Chhin , Janine Mauzeroll
Single pits were visually and electrochemically followed during their growth on a S41500 martensitic SS microelectrode. Solid particles were observed ejecting from the growing pit and after extraction, EDX determined they were mostly iron-based hydroxides/oxides. These particles were carried by fluid flow originating from the pit at a velocity of 21 μm/s. Finite element modeling confirmed the observed flow speeds are achievable by natural convection due to metal ion density gradients. While the pit solution does not experience flow, the bulk solution pH was observed to decrease illustrating how natural convection affects the bulk solution chemistry.
对 S41500 马氏体 SS 微电极上的单个凹坑的生长过程进行了目测和电化学跟踪。观察到固体颗粒从生长的凹坑中喷出,提取后,EDX 确定它们主要是铁基氢氧化物/氧化物。这些颗粒被从凹坑中喷出的流体以 21 μm/s 的速度带走。有限元建模证实,由于金属离子密度梯度,自然对流可以达到观测到的流速。虽然矿坑溶液没有流动,但观察到溶液的 pH 值降低,这说明自然对流如何影响溶液的化学性质。
{"title":"Observation of natural convection and particle ejection from stainless steel single pits","authors":"Lindsay Grandy ,&nbsp;Robert Lacasse ,&nbsp;Jonathan Ralph Adsetts ,&nbsp;Christophe Hitz ,&nbsp;Danny Chhin ,&nbsp;Janine Mauzeroll","doi":"10.1016/j.corsci.2024.112518","DOIUrl":"10.1016/j.corsci.2024.112518","url":null,"abstract":"<div><div>Single pits were visually and electrochemically followed during their growth on a S41500 martensitic SS microelectrode. Solid particles were observed ejecting from the growing pit and after extraction, EDX determined they were mostly iron-based hydroxides/oxides. These particles were carried by fluid flow originating from the pit at a velocity of 21 μm/s. Finite element modeling confirmed the observed flow speeds are achievable by natural convection due to metal ion density gradients. While the pit solution does not experience flow, the bulk solution pH was observed to decrease illustrating how natural convection affects the bulk solution chemistry.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112518"},"PeriodicalIF":7.4,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coupling effect of precipitates and hydrogen on pitting corrosion of stainless steel: Low potential region around precipitates 析出物和氢对不锈钢点腐蚀的耦合效应:析出物周围的低电位区
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-16 DOI: 10.1016/j.corsci.2024.112514
Ming Liu , Lining Xu , Lijie Qiao , Yu Yan , Binglu Zhang , Xuehan Wang
The coupling effect of hydrogen and NbCrN precipitate on pitting initiation and propagation of stainless steel were studied. After hydrogen charging, HMT results showed that more hydrogen was enriched on and around the precipitates. According to In-situ SKPFM and immersion results, the Volta potential of the precipitates is higher than that of the matrix before and after hydrogen charging. However, after hydrogen charging, a low Volta potential region appeared around the precipitates. The enrichment of hydrogen around the precipitates, the low potential around the precipitates, and consequent galvanic coupling effect lead to pits preferentially initiating and developing around the precipitates.
研究了氢和 NbCrN 沉淀对不锈钢点蚀萌生和扩展的耦合效应。充氢后,HMT 结果表明,析出物上和周围富集了更多的氢。根据原位 SKPFM 和浸泡结果,充氢前后析出物的伏特电位均高于基体。然而,充氢后,沉淀物周围出现了低伏特电位区。析出物周围氢的富集、析出物周围的低电位以及由此产生的电偶效应导致凹坑优先在析出物周围形成和发展。
{"title":"Coupling effect of precipitates and hydrogen on pitting corrosion of stainless steel: Low potential region around precipitates","authors":"Ming Liu ,&nbsp;Lining Xu ,&nbsp;Lijie Qiao ,&nbsp;Yu Yan ,&nbsp;Binglu Zhang ,&nbsp;Xuehan Wang","doi":"10.1016/j.corsci.2024.112514","DOIUrl":"10.1016/j.corsci.2024.112514","url":null,"abstract":"<div><div>The coupling effect of hydrogen and NbCrN precipitate on pitting initiation and propagation of stainless steel were studied. After hydrogen charging, HMT results showed that more hydrogen was enriched on and around the precipitates. According to In-situ SKPFM and immersion results, the Volta potential of the precipitates is higher than that of the matrix before and after hydrogen charging. However, after hydrogen charging, a low Volta potential region appeared around the precipitates. The enrichment of hydrogen around the precipitates, the low potential around the precipitates, and consequent galvanic coupling effect lead to pits preferentially initiating and developing around the precipitates.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112514"},"PeriodicalIF":7.4,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion-life prediction model for 316L stainless steel under electronic special gases containing trace moisture employed in semiconductor manufacturing industry 316L 不锈钢在半导体制造业使用的含微量水分的电子特殊气体下的腐蚀寿命预测模型
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-15 DOI: 10.1016/j.corsci.2024.112510
Zhice Yang , Chaoran Ma , Yuxin Zhang , Zhuoyang Du , Peng Zhou , Yang Zhao , Tao Zhang , Fuhui Wang
Special gases with trace moisture cause the formation of dynamic acidic microdroplets (DMD), which results in corrosion of semiconductor manufacturing devices. In this study, a predictive model for corrosion damage in 316L stainless steel (SS) was developed by combining the DMD process and the pitting initiation model. The DMD process was modeled using the BET model to describe the moisture-to-solution conversion. The pitting initiation model was reconstructed by incorporating the Sridhar model, temporal corrosion model, and Macdonald model. Finally, the predicted results were validated by various experimental data, indicating that the prediction model was accurate and highly reliable.
含有微量水分的特殊气体会形成动态酸性微滴(DMD),从而导致半导体制造设备的腐蚀。本研究结合 DMD 过程和点蚀引发模型,开发了 316L 不锈钢 (SS) 腐蚀损伤预测模型。DMD 过程使用 BET 模型来描述水分到溶液的转化。结合 Sridhar 模型、时间腐蚀模型和 Macdonald 模型重建了点蚀引发模型。最后,各种实验数据对预测结果进行了验证,表明预测模型准确可靠。
{"title":"Corrosion-life prediction model for 316L stainless steel under electronic special gases containing trace moisture employed in semiconductor manufacturing industry","authors":"Zhice Yang ,&nbsp;Chaoran Ma ,&nbsp;Yuxin Zhang ,&nbsp;Zhuoyang Du ,&nbsp;Peng Zhou ,&nbsp;Yang Zhao ,&nbsp;Tao Zhang ,&nbsp;Fuhui Wang","doi":"10.1016/j.corsci.2024.112510","DOIUrl":"10.1016/j.corsci.2024.112510","url":null,"abstract":"<div><div>Special gases with trace moisture cause the formation of dynamic acidic microdroplets (DMD), which results in corrosion of semiconductor manufacturing devices. In this study, a predictive model for corrosion damage in 316L stainless steel (SS) was developed by combining the DMD process and the pitting initiation model. The DMD process was modeled using the BET model to describe the moisture-to-solution conversion. The pitting initiation model was reconstructed by incorporating the Sridhar model, temporal corrosion model, and Macdonald model. Finally, the predicted results were validated by various experimental data, indicating that the prediction model was accurate and highly reliable.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"241 ","pages":"Article 112510"},"PeriodicalIF":7.4,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Corrosion Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1