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Evolution of wetted and corroded areas on 8Cr4Mo4V bearing steel exposed to salt water contaminated lubricant oil 暴露在盐水污染润滑油中的 8Cr4Mo4V 轴承钢的润湿区和腐蚀区的演变情况
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-15 DOI: 10.1016/j.corsci.2024.112515
Wanjun He , Qunfeng Zeng , Qi Xiao , Zeming Pang , Yang Wu , Chao Yan , Shan Huang , Jian Zhuang , Jiahe Wang , Haolin Li , Xunkai Wei
Relationship between wetted and corroded areas on 8Cr4Mo4V bearing steel during exposure to salt water contaminated lubricant oil was explored by Monte Carlo simulation and corrosion experiment. Results show that locally corroded areas are initially scattered then connected and eventually merged due to droplet coalescence, and are resulted from galvanic, uniform and filiform corrosions, respectively. Droplet coalescence also redistributes wetted areas and activates de-wetting which interrupts transformation towards corrosion. Role of droplet coalescence in evolution of corroded areas is addressed. Combining two Monte Carlo models varied with droplet relaxation helps to predict the corroded areas' distribution after long-term exposure.
通过蒙特卡洛模拟和腐蚀实验,探讨了 8Cr4Mo4V 轴承钢在暴露于盐水污染的润滑油中时,润湿区和腐蚀区之间的关系。结果表明,由于液滴凝聚,局部腐蚀区域最初是分散的,然后连接起来,最终合并,分别是电化学腐蚀、均匀腐蚀和丝状腐蚀的结果。液滴凝聚还重新分配了润湿区域并激活了去湿,从而中断了向腐蚀的转化。本文探讨了液滴凝聚在腐蚀区域演变过程中的作用。结合两种与液滴松弛不同的蒙特卡洛模型,有助于预测长期暴露后腐蚀区域的分布。
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引用次数: 0
Analysis of hydrogen-induced cracking mechanism in quenching and partitioning steels 淬火钢和隔热钢的氢致开裂机理分析
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-15 DOI: 10.1016/j.corsci.2024.112516
Weiguo Li , Weijie Wu , Juanping Xu , Yao Zhou , Jinxu Li
Quenching and partitioning (Q&P) steels are extensively used in the automotive industry due to their exceptional strength and ductility. However, the impact of hydrogen embrittlement (HE) poses a huge challenge to the safe service of Q&P steels, highlighting the necessity to investigate the hydrogen-induced cracking mechanisms. This study investigates the hydrogen-induced failure mechanisms in Q&P steels through experiments and finite element simulations, focusing on microstructure, local stress heterogeneity, hydrogen distribution characteristics, and hydrogen-induced cracking. The results reveal that hydrogen cracking nucleation in Q&P steel is primarily due to the further accumulation of hydrogen in local high-stress martensitic/austenitic regions.
淬火和隔热(Q&P)钢因其卓越的强度和延展性而广泛应用于汽车行业。然而,氢脆(HE)的影响对 Q&P 钢的安全使用构成了巨大挑战,这凸显了研究氢致开裂机制的必要性。本研究通过实验和有限元模拟研究了 Q&P 钢的氢致失效机理,重点关注微观结构、局部应力异质性、氢分布特征和氢致开裂。结果表明,Q&P 钢的氢致开裂成核主要是由于氢在局部高应力马氏体/奥氏体区域的进一步积累。
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引用次数: 0
The impact fretting corrosion behavior and damage mechanism of Inconel 690TT under different impact forces in high temperature pressurized water 高温加压水中不同冲击力下 Inconel 690TT 的冲击烧蚀行为和破坏机理
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-12 DOI: 10.1016/j.corsci.2024.112507
W.W. Bian , Y.H. Lu , L.Z. Kang , X.F. Zhang , L. Xin , T. Shoji
The impact fretting corrosion of Inconel 690TT under different impact forces was investigated. The results indicated that there was a competitive relationship between formation of third body layer (TBL) and fragmentation of TBL caused by impact force. With the increase of impact forces, damage mechanism changed from adhesive wear to delamination wear, and crack initiation sites gradually shifted from TBL to internal oxidation zone in tribologically transformed structure (TTS) layer. Nanocrystalline boundaries and defects induced by impact force provided channels for internal oxidation. The formation mechanism of TTS was the combined effect of continuous dynamic recrystallization (cDRX) and twin-assisted cDRX.
研究了 Inconel 690TT 在不同冲击力下的冲击烧蚀。结果表明,第三体层(TBL)的形成与冲击力导致的第三体层破碎之间存在竞争关系。随着冲击力的增加,破坏机制从粘着磨损转变为分层磨损,裂纹起始点逐渐从第三体层(TBL)转移到摩擦学转换结构(TTS)层的内部氧化区。冲击力引起的纳米晶边界和缺陷为内部氧化提供了通道。TTS 的形成机制是连续动态再结晶(cDRX)和双辅助 cDRX 的共同作用。
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引用次数: 0
A novel insight into the enhanced electrochemical performance of Mg-air battery in mixed aqueous and organic electrolytes 在混合水溶液和有机电解质中提高镁空气电池电化学性能的新见解
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-11 DOI: 10.1016/j.corsci.2024.112512
Yuxin Zhou , Xiaopeng Lu , Antoine Seyeux , Jolanta Światowska , Fuhui Wang
A new strategy of utilizing mixtures of ethanol and complexing agents on Mg-air battery is investigated systematically. The presence of ethanol promotes formation of a dense inner layer with a high portion of oxide in the discharge film, leading to significantly enhanced utilization efficiency. The highest utilization efficiency of Mg anode has been increased from 53.6 % to 85.7 % and the discharge potential is decreased 300 mV, when discharges in mixed electrolyte. The adsorption/deposition of S-like species on metal surface is evidenced in ethanol and 5-sulfosalicylate acid containing solution, resulting in inhibition of the hydroxide-rich outer layer growth.
本文系统地研究了在镁空气电池中使用乙醇和络合剂混合物的新策略。乙醇的存在促进了放电膜中氧化物含量较高的致密内层的形成,从而显著提高了利用效率。在混合电解质中放电时,镁阳极的最高利用效率从 53.6% 提高到 85.7%,放电电位降低了 300 mV。在含乙醇和 5-磺基水杨酸的溶液中,S 类物质在金属表面的吸附/沉积得到了证实,从而抑制了富氢氧化物外层的生长。
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引用次数: 0
Assessing the impact of CPs transfer on corrosion behavior in the liquid lead-bismuth eutectic cooled system 评估氯化石蜡转移对液态铅铋共晶冷却体系中腐蚀行为的影响
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-11 DOI: 10.1016/j.corsci.2024.112511
Li Liu , Zheng Jia , Junjie Yuan , Ruiqi Bao , Haotian Luo , Hanyang Gu
A mass transfer model for corrosion products (CPs) in a liquid metal cooling system has been developed. The spatial variations in CPs concentration are determined by integrating the source term of the mass transfer model with models for radial iron dissolution, precipitation, particle deposition, and erosion. The model has been validated and verified using experimental data from a lead-cool loop and air. Subsequently, it has been applied to analyze the multi-modular lead-bismuth eutectic (LBE) loop. The results reveal the CPs transfer rate, CPs concentration distribution, overall corrosion characteristics, and the impact of CPs mass transfer on corrosion behavior.
我们建立了液态金属冷却系统中腐蚀产物(CPs)的传质模型。通过将传质模型的源项与径向铁溶解、沉淀、颗粒沉积和侵蚀模型相结合,确定了 CPs 浓度的空间变化。该模型通过铅冷回路和空气中的实验数据进行了验证。随后,该模型被用于分析多模块铅铋共晶(LBE)回路。结果揭示了氯化铋的传输速率、氯化铋浓度分布、整体腐蚀特征以及氯化铋传质对腐蚀行为的影响。
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引用次数: 0
Corrigendum to “High temperature oxidation resistance and thermodynamic properties of (TaNbZr)N and (TaNbZr)C quaternary ceramic coating” [Corros. Sci. 237 (2024) 112315] (TaNbZr)N和(TaNbZr)C四元陶瓷涂层的高温抗氧化性和热力学特性"[Corros. Sci.
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-11 DOI: 10.1016/j.corsci.2024.112509
Haiyang Yu , Wenping Liang , Qiang Miao , Mengjuan Yin , Yong Wang , Hongfei Liu , Hongmei Jin , Fengxia Wei , Na Gong
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引用次数: 0
Effects of hard anodizing on mechanical and electrochemical characteristics of aluminum alloys under tribocorrosion condition 硬质阳极氧化对摩擦腐蚀条件下铝合金机械和电化学特性的影响
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.corsci.2024.112503
Dong-Ho Shin , Seong-Jong Kim
In this research, the effects of hard anodizing on the mechanical and electrochemical characteristics of aluminum alloys under tribocorrosion conditions was investigated. Compared with dry conditions, friction coefficient of aluminum alloys under tribocorrosion conditions increased, whereas that of hard anodized specimens decreased. This was attributed to corrosive ions in the solution corroding the transfer film of the counter-body and tribofilm of the hard anodized specimen. In potentiodynamic polarization experiments under tribocorrosion conditions, the aluminum alloys exhibited high current density with applied load. However, at potentials above –0.05 V, current density decreased and was reversed. This is believed to be due to the corrosive ions preferentially reacting with the generated wear debris, thereby reducing the oxidation reaction with wear track. However, the current density of the hard anodized specimens increased with load and potential. In addition, the increasing rate in the wear width and depth was significant under tribocorrosion conditions (Width: 42.65 %, Depth: 32.63 %). This is due to the cavitation and fluid impact generated during friction/wear accelerating the cracking and damage of the hard anodizing film with the brittleness and porousity. However, the tribocorrosion resistance of the hard anodized aluminum alloy was improved by more than 97 %.
本研究调查了硬质阳极氧化对摩擦腐蚀条件下铝合金机械和电化学特性的影响。与干燥条件相比,摩擦腐蚀条件下铝合金的摩擦系数增大,而硬质阳极氧化试样的摩擦系数减小。这归因于溶液中的腐蚀性离子腐蚀了硬质阳极氧化试样的对体和三膜的转移膜。在摩擦腐蚀条件下进行的电位极化实验中,铝合金在施加负载时表现出很高的电流密度。然而,当电位高于 -0.05 V 时,电流密度下降并发生逆转。这被认为是由于腐蚀离子优先与产生的磨损碎片发生反应,从而减少了与磨损轨迹的氧化反应。然而,硬质阳极氧化试样的电流密度随着负载和电位的增加而增加。此外,在摩擦腐蚀条件下,磨损宽度和深度的增加率也很明显(宽度:42.65 %,深度:32.63 %)。这是由于摩擦/磨损过程中产生的气穴和流体冲击加速了脆性和多孔性硬阳极氧化膜的开裂和损坏。不过,硬质阳极氧化铝合金的耐摩擦腐蚀性能提高了 97% 以上。
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引用次数: 0
Effect of elastic stress on anodic dissolution behavior of TA2 弹性应力对 TA2 阳极溶解行为的影响
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.corsci.2024.112506
Qiu-Yu Huang, Xin-Ran Li, Yu-Hua Xiao, Jia-Xing Li, Fa-He Cao
The anodic dissolution behaviors of TA2 under elastic stress in acidic 3.5 % NaCl solution with or without 5 mM NaF were investigated using in-situ scanning electrochemical microscopy (SECM), along with polarization curve, SEM and AFM. The results indicated that the dissolution of the passive film in 3.5 % NaCl solution was accelerated under 100 MPa, and more resistant to dissolve under 200 MPa. In presence of 5 mM NaF, the stress intensified the dissolution of the matrix. Specifically, 100 MPa stress increased the corrosion difference between different grains, while 200 MPa stress made the corrosion of TA2 more uniform.
利用原位扫描电化学显微镜(SECM)、极化曲线、扫描电镜和原子力显微镜研究了 TA2 在酸性 3.5 % NaCl 溶液(含或不含 5 mM NaF)中弹性应力作用下的阳极溶解行为。结果表明,在 3.5 % NaCl 溶液中,被动膜在 100 MPa 压力下加速溶解,在 200 MPa 压力下更难溶解。在 5 mM NaF 的存在下,应力加剧了基质的溶解。具体来说,100 兆帕应力增加了不同晶粒之间的腐蚀差异,而 200 兆帕应力则使 TA2 的腐蚀更加均匀。
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引用次数: 0
Microstructure and localized corrosion properties of 2219 aluminum alloy manufactured by additive friction stir deposition 添加式搅拌摩擦沉积法制造的 2219 铝合金的微观结构和局部腐蚀特性
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.corsci.2024.112508
Zikang Wang , Hongchang Qian , Weiwei Chang , Zhihao Yu , Qian Qiao , Min Zhou , Dawei Guo , Dawei Zhang , Chi Tat Kwok , Lap Mou Tam
Multi-layer 2219 aluminum alloy samples were successfully fabricated using additive friction stir deposition (AFSD). AFSD deposition reduced grain size and the size of intermetallic Al2Cu particles, but greatly increased the amount of Al2Cu particles. More Al2Cu particles increased the number of galvanic microcells on alloy surface and at the grain boundaries, which promoted the localized corrosion and improved the intergranular corrosion sensitivity of AFSD alloy. Subsequent T6 heat treatment had little effect on grain size but enhanced the corrosion resistance of AFSD alloy, primarily attributed to the reduction in Al2Cu particles and the elimination of dislocations within grains.
利用添加剂搅拌摩擦沉积(AFSD)成功制备了多层 2219 铝合金样品。AFSD 沉积减小了晶粒尺寸和金属间 Al2Cu 颗粒的尺寸,但大大增加了 Al2Cu 颗粒的数量。更多的 Al2Cu 颗粒增加了合金表面和晶界的电化微电池数量,从而促进了局部腐蚀并提高了 AFSD 合金的晶间腐蚀敏感性。随后的 T6 热处理对晶粒大小影响不大,但却增强了 AFSD 合金的耐腐蚀性,这主要归功于 Al2Cu 颗粒的减少和晶粒内位错的消除。
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引用次数: 0
Micro-alloying of Sm with rolling for synergetic corrosion resistance and mechanical properties of Mg-Al-Sn-Ca-Mn alloys 通过轧制微合金化 Sm 实现 Mg-Al-Sn-Ca-Mn 合金的协同耐腐蚀性和机械性能
IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-08 DOI: 10.1016/j.corsci.2024.112502
Jiawei He , Dawei Wang , Fuyong Cao , Xun Zhang , Cheng Wang , Jin Xu , Xiaoli Zhou , Yajie Yang , Yipeng Gao , Min Zha
Micro Sm alloying coupling with four-pass rotary rolling is conducted to synergize the corrosion resistance and mechanical properties of Mg-Al-Sn-Ca-Mn alloys. Micro Sm alloying weakens the galvanic corrosion. Rolling process refines the grains, intensifies the basal texture and promotes dispersed second phase particles, thereby contributing to forming a uniform and protective corrosion product film, and enhancing the mechanical strength and ductility. As a result, rolled Mg-Al-Sn-Ca-Mn-Sm alloy exhibits a synergy of mechanical properties and corrosion resistance, i.e., an UTS of 271 MPa, YS of 204 MPa, elongation to failure of 18 %, and a low corrosion rate of 0.85 mm y−1.
将微钐合金化与四道旋转轧制耦合在一起,可协同提高镁铝锰钴锰合金的耐腐蚀性和机械性能。微Sm合金化可减弱电化学腐蚀。轧制过程细化了晶粒,强化了基底纹理,促进了第二相颗粒的分散,从而有助于形成均匀的腐蚀保护膜,并提高了机械强度和延展性。因此,轧制 Mg-Al-Sn-Ca-Mn-Sm 合金具有协同的机械性能和耐腐蚀性,即 UTS 为 271 兆帕,YS 为 204 兆帕,破坏伸长率为 18%,腐蚀速率低至 0.85 毫米 y-1。
{"title":"Micro-alloying of Sm with rolling for synergetic corrosion resistance and mechanical properties of Mg-Al-Sn-Ca-Mn alloys","authors":"Jiawei He ,&nbsp;Dawei Wang ,&nbsp;Fuyong Cao ,&nbsp;Xun Zhang ,&nbsp;Cheng Wang ,&nbsp;Jin Xu ,&nbsp;Xiaoli Zhou ,&nbsp;Yajie Yang ,&nbsp;Yipeng Gao ,&nbsp;Min Zha","doi":"10.1016/j.corsci.2024.112502","DOIUrl":"10.1016/j.corsci.2024.112502","url":null,"abstract":"<div><div>Micro Sm alloying coupling with four-pass rotary rolling is conducted to synergize the corrosion resistance and mechanical properties of Mg-Al-Sn-Ca-Mn alloys. Micro Sm alloying weakens the galvanic corrosion. Rolling process refines the grains, intensifies the basal texture and promotes dispersed second phase particles, thereby contributing to forming a uniform and protective corrosion product film, and enhancing the mechanical strength and ductility. As a result, rolled Mg-Al-Sn-Ca-Mn-Sm alloy exhibits a synergy of mechanical properties and corrosion resistance, <em>i.e.</em>, an UTS of 271 MPa, YS of 204 MPa, elongation to failure of 18 %, and a low corrosion rate of 0.85 mm y<sup>−1</sup>.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"240 ","pages":"Article 112502"},"PeriodicalIF":7.4,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142421239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Corrosion Science
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