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2014 IEEE 9th IberoAmerican Congress on Sensors最新文献

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Chitosan/bentonite nanocomposite: Preliminary studies of its potentiometric response to nitrate ions in water 壳聚糖/膨润土纳米复合材料对水中硝酸盐离子电位响应的初步研究
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995562
Moises Oviedo Mendoza, Erika Padilla Ortega, O. Arias de Fuentes, Y. Prokhorov, J. Gabriel Luna Barcenas
The scope of this work is to obtain and characterize a nanobiocomposite as Ion Selective Electrodes (ISE) for nitrate ion determination in water. This nanocomposite is based upon the intercalation of chitosan, a cationic biopolymer, in bentonite. Chitosan (CS)/bentonite nanocomposites were prepared by ionic exchange. The amino groups in the CS can be protonated in acidic solution and they can replace the interlayer cation on the clay surface. Nitrate (II) was added at the end of the preparation process for blocking the cationic exchange sites and enhance the potentiometric response to nitrate. Chitosan/bentonite films were obtained by solvent cast method. X-Ray Diffraction (XRD), X-Ray Photoelectron Spectroscopy (XPS) and Fourier-Transformed-Infrared Spectroscopy (FTIR) were used to characterize the nanocomposites. These studies confirm that the chitosan was intercalated into the bentonite interlayer spacing due to the electrostatic attraction between NH3+ groups and the negatively charge bentonite surface. These measurements confirm that there exist possibilities to reverse the ion exchange of this nanocomposite. Potentiometric measurements were performed using an Ag/AgCl reference electrode and an ISE with chitosan/bentonite membranes deposited on a graphite-epoxy electrode as a working electrode. A linear fitting was performed between 2×10-4M and 8×10-1M of concentration with a near Nernstian slope of -54.6 mV/dec. The selectivity towards some interfering ions was calculated according to the Separate Solution Method (SSM).
这项工作的范围是获得并表征纳米生物复合材料作为离子选择电极(ISE)用于水中硝酸盐离子的测定。这种纳米复合材料是基于壳聚糖的插入,一种阳离子生物聚合物,在膨润土。采用离子交换法制备了壳聚糖/膨润土纳米复合材料。CS中的氨基在酸性溶液中可以质子化,取代粘土表面的层间阳离子。在制备过程的最后加入硝酸盐(II),阻断阳离子交换位点,增强对硝酸盐的电位响应。采用溶剂浇铸法制备壳聚糖/膨润土薄膜。利用x射线衍射(XRD)、x射线光电子能谱(XPS)和傅里叶变换红外光谱(FTIR)对纳米复合材料进行表征。这些研究证实了壳聚糖是由于NH3+基团与带负电荷的膨润土表面之间的静电吸引作用而嵌入膨润土层间距的。这些测量结果证实,存在逆转这种纳米复合材料的离子交换的可能性。电位测量使用Ag/AgCl参比电极和ISE,在石墨-环氧电极上沉积壳聚糖/膨润土膜作为工作电极。在2×10-4M和8×10-1M之间进行了线性拟合,近似于-54.6 mV/dec的纳恩斯斜率。根据分离溶液法(SSM)计算了对某些干扰离子的选择性。
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引用次数: 7
Use of sensors in cheese manufacture and quality control 传感器在奶酪生产和质量控制中的应用
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995547
M. Gomes, J. A. Oliveira, E. M. Gaspar
This work intends to give a brief overview of sensors application for cheese. Besides discussing the main achievements on the field, it will show the main difficulties that still need to be overcome. Single sensors to follow milk coagulation and detection of specific target compounds are discussed, as well as how complex problems where more than one compound need to be followed, as during rancidity development, can be adequately followed by a single non-specific sensor. Electronic noses formed by a variety of non-specific sensors can be employed in the quality control and examples of well succeeded applications as well as others still under development are discussed.
本文就传感器在奶酪中的应用作一综述。除了讨论该领域的主要成就外,它还将展示仍需要克服的主要困难。讨论了跟踪牛奶凝固和检测特定目标化合物的单个传感器,以及在酸败发展过程中需要跟踪多个化合物的复杂问题如何能够由单个非特异性传感器充分跟踪。由各种非特异性传感器组成的电子鼻可用于质量控制,并讨论了成功应用的例子以及仍在开发中的其他应用。
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引用次数: 2
pH sensors based in TiO2 NTs arrays 基于TiO2纳米管阵列的pH传感器
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995523
P. Marques, G. Z. Monteiro, I. Pereyra, K. F. Albertin
pH sensor fabricated with TiO2 nanotube arrays with diameter and length controlled by the anodization voltage and time were obtained and characterized. The TiO2 nanotube arrays were obtained by Ti foil anodization in a NH4F organic solution with 20 and 40 V for 5, 15 and 25 min. pH sensors based on Ti2 NTs electrodes presented linear response respect to the pH value in the 4-10 pH range. The pH sensor with nanotubes obtained with 20V / 25 min presents a reproducible response and the best sensitivity value, 45.8 mV/pH. This TiO2 NTs pH sensor irradiated by UV shows a very stable response and a sensitivity value of 50.9 mV/pH close to Nernst equation (59 mV/pH).
制备了由阳极氧化电压和时间控制直径和长度的TiO2纳米管阵列制成的pH传感器并对其进行了表征。在NH4F有机溶液中,以20 V和40 V阳极氧化TiO2纳米管阵列,在4 ~ 10 pH范围内,基于TiO2纳米管电极的pH传感器对pH值呈线性响应。在20V / 25 min条件下获得的纳米管pH传感器具有可重复性,灵敏度最高为45.8 mV/pH。该TiO2 NTs pH传感器在紫外辐射下的响应非常稳定,灵敏度值为50.9 mV/pH,接近能思特方程(59 mV/pH)。
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引用次数: 1
Alcohols detection based on Pd-doped SnO2 sensors 基于pd掺杂SnO2传感器的醇类检测
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995514
A. L. Paredes-Doig, Maria del Rosario Sun-Kou, G. Comina
In this paper a series of sensors based on SnO2 doped by impregnation with Pd, with a ratio of 1% to 5% were prepared. These sensors have shown good sensitivity for different alcohols (ethanol, n-butanol and 1-octanol). The characterization of the doped SnO2 was performed using N2 adsorption-desorption by the Brunauer-Emmett-Teller (SBET) surface area analysis, and Scanning Electron Microscopy (SEM). The gas sensor's behaviour for different alcohol-vapours and different working temperature were analyzed. Although the fabrication technique does not give us a uniform and well shaped film, it was observed that the response signal of the sensor changes proportionally with the sensing temperature. The higher voltage response to ethanol was obtained with the sensor 5% Pd-SnO2 film, and also it has been obtained good signal reproducibility when alcohols (ethanol, n-butanol and 1-octanol) were measured under the same conditions.
本文制备了一系列以1% ~ 5%的Pd浸渍SnO2为基础的传感器。这些传感器对不同的醇(乙醇、正丁醇和辛醇)具有良好的灵敏度。通过brunauer - emmet - teller (SBET)表面积分析和扫描电子显微镜(SEM)对掺杂SnO2进行了N2吸附-解吸表征。分析了不同酒精蒸汽和不同工作温度下气体传感器的性能。虽然制作技术不能得到均匀且形状良好的薄膜,但观察到传感器的响应信号随传感温度成比例地变化。采用5% Pd-SnO2薄膜的传感器对乙醇具有较高的电压响应,在相同条件下对乙醇、正丁醇和辛醇等醇类进行测量,也具有良好的信号再现性。
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引用次数: 5
Wireless zero-power small displacement sensors 无线零功率小位移传感器
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995561
N. M. Cerón-Hurtado, Jordi Aguiló Llobet
Power consumption, flexibility, cost effectiveness and dimension reductions are the most important parameters to consider in many applications of the biomedical field and particularly implant devices. Echoing this trend, we present a passive, flexible and low cost wireless microsensor based on a LC tank circuit whose capacity varies with the deformation as a result of the area change shared between the interdigitated parallel plates capacitor. As a result, two types of micro-sensor are defined, simulated, fabricated and tested. The capacitors constitute a set of interdigitated gold plates laid on a COP (Cyclo Olefin Polymer) substrate and the planar microcoils are designed to take into account the spacing between the turns, the width and the number of turns over the COP substrate. The system is completed by an inductive reading subsystem and testing results show the scalability of the system. Using the fabricated demonstrator, we detect displacements in the range of tens of micrometers and resonance frequency variations 200 to 350MHz.
功耗、灵活性、成本效益和尺寸减小是生物医学领域的许多应用中需要考虑的最重要的参数,特别是植入装置。为了响应这一趋势,我们提出了一种基于LC槽电路的无源、柔性和低成本的无线微传感器,其容量随着交叉并联板电容器之间共享的面积变化而变化。因此,定义、模拟、制作和测试了两种类型的微传感器。电容器由一组交错排列的金板构成,放置在COP(环烯烃聚合物)衬底上,平面微线圈的设计考虑了COP衬底上匝数、宽度和匝数之间的间距。系统由感应读取子系统完成,测试结果表明了系统的可扩展性。利用制造的演示器,我们可以检测到几十微米范围内的位移和200到350MHz的谐振频率变化。
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引用次数: 1
Flow-injection amperometric sensor for quantification and speciation of iron 用于铁的定量和形态分析的流动注射安培传感器
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995519
Albert Saavedra, E. Cortón
In the bio-mining industry there are various compounds which need to be frequently monitored, one of which is iron, since its concentration can seriously affect the industrial process. This study describes the development of an electrochemical method of speciation and rapid quantification of iron in bio-mining processes conditions. Speciation and quantification was carried out in a flow injection system using techniques of cyclic voltammetry and chronoamperometry. The proposed and a standard method were used to compare the results obtained from simulated and real mixed (ferric/ferrous) samples. Cyclic voltammograms presented two peaks corresponding to the ferric ion reduction of and ferrous ion oxidation. Chronoamperometry allow the construction of calibration curves for both ions. Quantification of real and simulated samples showed acceptable levels of error compared to a standard method. The electrochemical method allowed in a simple and rapid way the speciation and quantification of iron in mixed samples, including real samples from acid mine drainage, which established the basis for the development of an automated process monitoring device.
在生物采矿工业中,有各种化合物需要经常监测,其中一种是铁,因为它的浓度会严重影响工业过程。本研究描述了生物采矿过程条件下铁的形态形成和快速定量的电化学方法的发展。在流动注射系统中使用循环伏安法和计时安培法进行形态和定量分析。用所提出的方法和标准方法比较了模拟和实际混合(铁/铁)样品的结果。循环伏安图出现两个峰,分别对应铁离子还原和亚铁离子氧化。计时安培法允许构建两种离子的校准曲线。与标准方法相比,真实和模拟样品的量化显示出可接受的误差水平。电化学方法可以以一种简单快速的方式对混合样品中的铁进行形态分析和定量分析,包括酸性矿井排水的实际样品,这为自动化过程监测装置的开发奠定了基础。
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引用次数: 0
Experimental evaluation of energy efficient algorithms for WSN using variable transmission powers 可变传输功率无线传感器网络节能算法的实验评估
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995507
Jose Mauricio Nava Auza, A. Branco, J.R. Boisson de Marca
The main source of power supply for Wireless Sensor Networks are batteries, which are limited in life-cycle, thus limiting the sensors lifetime. Due this fact, the energy efficiency network is becoming the main concern to be addressed by researchers. This work aims to implement two theoretical energy-saving algorithms for WSN, DTNBOR and DTRNG. These algorithms choose their transmissions powers dynamically. Results obtained from simulations and necessary adjustments, for proper operation in a real implementation will be showed.
无线传感器网络的主要供电来源是电池,电池的寿命周期有限,从而限制了传感器的使用寿命。由于这一事实,能源效率网络成为研究人员关注的主要问题。本工作旨在实现两种理论的无线传感器网络节能算法:DTNBOR和DTRNG。这些算法动态地选择传输功率。本文将给出仿真结果和必要的调整,以便在实际应用中正确操作。
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引用次数: 1
Water-in-diesel nanoemulsion by LTCC microfluidic devices 用LTCC微流控装置制备柴油水纳米乳
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995546
J. N. Schianti, M. Gongora-Rubio, Thais Aragão Horoiwa, N. N. Cerize, A. M. Oliveira
In this work we present the first results related to production of water nanoemulsion in diesel oil using microfluidic reactors as tool. We tested two different microreactors, a vortex and 3D serpentine geometry, varying parameters such as total flow rate, surfactant concentration and ratio between phases. It was observed water droplets sizes from 100 to 700 nm, and the stability was dependent of surfactant concentration. Higher flow rates offer smaller droplets sizes obtained in vortex device. However, with 3D serpentine we observed nanoemulsion with better stability.
在这项工作中,我们提出了有关用微流控反应器在柴油中生产水纳米乳的第一个结果。我们测试了两种不同的微反应器,涡旋和三维蛇形几何,不同的参数,如总流量,表面活性剂浓度和相间比。在100 ~ 700 nm范围内观察到水滴的大小,其稳定性与表面活性剂的浓度有关。在涡流装置中,流速越高,液滴尺寸越小。然而,我们观察到三维蛇纹石纳米乳具有更好的稳定性。
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引用次数: 3
TEOS and TEOS/HFE plasma thin films used in electrochemical measurements 用于电化学测量的TEOS和TEOS/HFE等离子体薄膜
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995510
L. Hernandez, M. L. P. Da Silva, R. R. Lima, F. L. Almeida, S. G. Santos Fo
TEOS and/or TEOS/HFE plasma polymerized thin films, exposed or non-exposed to ultraviolet (UVC) radiation, were obtained on gold electrodes and tested for electrochemical measurements. All films presented good performance on electrochemical measurements. The electronic signal does not change significantly after 24h on physiologic serum but thin TEOS films allow ion permeation. Thus, these films are useful as membranes to reference and measuring electrodes.
在金电极上获得TEOS和/或TEOS/HFE等离子体聚合薄膜,暴露或未暴露于紫外线(UVC)辐射下,并进行电化学测量。所有薄膜均表现出良好的电化学性能。生理血清24小时后电信号变化不明显,但TEOS薄膜允许离子渗透。因此,这些薄膜可用作参考和测量电极的膜。
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引用次数: 0
Design and implementation of a planar capacitive pressure sensor 平面电容式压力传感器的设计与实现
Pub Date : 2014-12-29 DOI: 10.1109/IBERSENSOR.2014.6995536
E. Unigarro, Alvaro U. Achury, J. Bohórquez, Jordi Sacristan Riquelme, F. Segura-Quijano
In this paper we present the implementation of a capacitive pressure sensor using interdigitated electrodes and a polymer cavity, the sensor functionality is based on the compression of a sealed cavity which changes the dielectric properties on top of two planar interdigitated electrodes (IDE). COMSOL was used to perform multiphysics simulations of the mechanical and electrical behavior of the sensor. The fabrication process of the sensor was made in tree steps: the interdigitated electrodes were fabricated using copper on a FR4 substrate, a sealed cavity of polydimethylsiloxane (PDMS) was built using FR4 molds, and finally the cavity and IDE were assembled with a thin layer of PDMS. The IDE electrodes are composed of 21 fingers and had a squared area of 11×11 mm, the PDMS cavity had an area of 11×11 mm with a height of 900 μm. A precision LCR meter (Agilent 4248A) was used to measure the capacitance variations caused by the pressure changes, the sensor was tested in the range of 0 to 40 psi and has a sensitivity of 3.35 fF/psi. Simulations were used to study the possibility of using functionalized polymers to increase the sensor sensitivity; the aim of this work is to present the design and fabrication process for a planar capacitive sensor, this design requires less fabrication steps than common micro-electromechanicals systems (MEMS) pressure sensors reducing the production costs of the pressure sensors, also allowing new types of integrations.
在本文中,我们提出了一种使用交错电极和聚合物腔的电容式压力传感器的实现,传感器的功能是基于压缩密封腔,从而改变两个平面交错电极(IDE)顶部的介电特性。使用COMSOL对传感器的机械和电气行为进行多物理场模拟。该传感器的制造过程分为三个步骤:在FR4衬底上使用铜制作交叉电极,使用FR4模具构建聚二甲基硅氧烷(PDMS)密封腔,最后用PDMS薄层组装腔和IDE。IDE电极由21指组成,平方面积为11×11 mm, PDMS腔面积为11×11 mm,高度为900 μm。采用精密LCR仪表(Agilent 4248A)测量压力变化引起的电容变化,该传感器的测试范围为0 ~ 40 psi,灵敏度为3.35 fF/psi。通过仿真研究了利用功能化聚合物提高传感器灵敏度的可能性;这项工作的目的是展示平面电容式传感器的设计和制造过程,这种设计比普通的微机电系统(MEMS)压力传感器需要更少的制造步骤,降低了压力传感器的生产成本,也允许新型集成。
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引用次数: 4
期刊
2014 IEEE 9th IberoAmerican Congress on Sensors
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