Electrochemistry Communications最新文献_第6页

Modification of platinum surfaces with cerium species for promoting oxidative desorption of adsorbed sulfur 用铈修饰铂表面促进硫的氧化脱附

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-20 DOI: 10.1016/j.elecom.2025.108050

Tetsuro Morooka , Tamao Shishido , Takuya Nakanishi , Takuya Masuda

Adsorption of sulfur (S) significantly reduces the electrochemically active surface area of platinum (Pt) electrocatalysts in polymer electrolyte membrane fuel cells (PEMFCs), namely, S poisoning. Mitigation techniques against S poisoning are strongly desired for highly durable PEMFCs. A Pt single-crystal surface was demonstrated to be modified with cerium (Ce) species by being immersed in a Ce-containing aqueous solution with hydrogen (H₂) gas bubbling or potential holding at −0.2 V vs. Ag/AgCl. For a Ce-free Pt electrode, electrochemical responses characteristic of the adsorption/desorption of hydrogen and hydroxyl species at the bare Pt surface disappeared due to the adsorbed elemental sulfur, S_ad, while the oxidative desorption of S_ad from the Pt electrode occurred at around 0.80 V vs. Ag/AgCl. In contrast, for the Ce-modified Pt electrode, the oxidative desorption of S_ad occurred at a potential around 0.3 V which is less positive (more negative) than that of Ce-free Pt electrode, showing the enhanced oxidative desorption capability due to the presence of Ce species on the surface. While the Ce species was desorbed from the Pt electrode simultaneously with the oxidative desorption of S_ad, the Pt surface can be re-modified with the Ce species by H₂ gas bubbling or potential holding at −0.2 V vs. Ag/AgCl, which is a similar condition to that of anode of PEMFC under operations. Thus, the Ce-modification of Pt surfaces potentially acts as a practical mitigation measure against the S poisoning.

硫(S)的吸附显著降低了聚合物电解质膜燃料电池（pemfc）中铂（Pt）电催化剂的电化学活性表面积，即S中毒。对于高度耐用的pemfc，迫切需要针对S中毒的缓解技术。将Pt单晶表面浸泡在含Ce的水溶液中，使氢气（H2）鼓泡或电位保持在−0.2 V /Ag /AgCl下，证明了铈（Ce）可以修饰Pt单晶表面。对于无ce Pt电极，由于吸附了单质硫（Sad），裸Pt表面的氢和羟基的吸附/解吸特征消失，而在0.80 V /Ag /AgCl左右，Pt电极上的Sad发生氧化解吸。相比之下，对于Ce修饰的Pt电极，Sad的氧化脱附发生在0.3 V左右的电位下，该电位比无Ce修饰的Pt电极的正极电位少（负极电位多），表明由于表面存在Ce物质而增强了氧化脱附能力。Ce在Pt电极上的脱附过程与Sad的氧化脱附过程同时进行，通过H2气体鼓泡或电位保持在- 0.2 V vs. Ag/AgCl下，Ce可以在Pt表面进行再修饰，这与PEMFC阳极的操作条件相似。因此，铂表面的ce修饰有可能作为一种实际的缓解S中毒的措施。

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引用次数: 0

Research Progress of isoniazid electrochemical sensors 异烟肼电化学传感器的研究进展

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-08-28 DOI: 10.1016/j.elecom.2025.108038

Huanyu Che , Gaihua He , Xuekun Liu , Xin Guo , Chang Lei , Ye Liao

This paper reviews the research progress of isoniazid electrochemical sensors in recent years. As an important anti-tuberculosis drug, the rapid and sensitive detection of isoniazid is of great significance for clinical treatment and drug quality control. This paper first introduces the basic properties and detection requirements of isoniazid, then elaborates on the working principle of electrochemical sensors and their application in isoniazid detection, with a focus on discussing isoniazid electrochemical sensors with different modified materials. Finally, the future development direction of isoniazid sensors is prospected, providing valuable insights for future research.

本文综述了近年来异烟肼类电化学传感器的研究进展。异烟肼作为一种重要的抗结核药物，快速、灵敏的检测对临床治疗和药品质量控制具有重要意义。本文首先介绍了异烟肼的基本性质和检测要求，然后阐述了电化学传感器的工作原理及其在异烟肼检测中的应用，重点讨论了不同改性材料的异烟肼电化学传感器。最后，对异烟肼传感器的未来发展方向进行了展望，为今后的研究提供了有价值的见解。

引用次数: 0

High accuracy parameter estimation of solid oxide fuel cells using a surrogate assisted differential evolution with multi sampling mechanism 基于多采样机制的替代辅助差分演化的固体氧化物燃料电池高精度参数估计

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-26 DOI: 10.1016/j.elecom.2025.108060

Anil Parmar , Mohammad Aljaidi , Sanjeev Maheshwari , Arpita , Pradeep Jangir , Reena Jangid , Sandeep Kumar , Gaurav Kumar , Richa Rani , Mohammad Khishe

Solid Oxide Fuel Cells (SOFCs) represent a promising clean energy technology due to their high efficiency and fuel flexibility; however, accurate estimation of internal electrochemical parameters remains critical for achieving reliable system performance under diverse operating conditions. Traditional parameter identification methods often face challenges such as slow convergence, premature optimization stagnation, and computational inefficiency, especially when dealing with high-dimensional, nonlinear SOFC models. To overcome these issues, this study proposes a Surrogate-Assisted Differential Evolution with Multi-Sampling Mechanism (SADE-MSM) algorithm, integrating surrogate modeling, centroid sampling, global prescreening, and adaptive local search strategies to optimize SOFC parameters efficiently while minimizing expensive real function evaluations. The SADE-MSM approach was validated through extensive experimental studies involving ten different SOFC operational cases across varied temperatures and pressures, and its performance was benchmarked against nine leading metaheuristic algorithms. Results show that SADE-MSM consistently achieved the lowest mean squared error (MSE), fastest convergence rates, and highest robustness, outperforming all comparative methods in both accuracy and computational cost. Theoretically, these findings validate the effectiveness of hybrid surrogate-assisted evolutionary frameworks for complex multimodal optimization problems, while practically they demonstrate that SADE-MSM enables real-time SOFC parameter estimation suitable for applications in microgrids, hybrid renewable systems, and predictive control platforms. Readers benefit from a robust, efficient methodology that enhances SOFC modeling and operational reliability, while future work aims to extend SADE-MSM to fully dynamic, online optimization scenarios under real-world uncertainties such as system aging, transient loads, and sensor noise.

固体氧化物燃料电池（SOFCs）由于其高效率和燃料灵活性，代表了一种很有前途的清洁能源技术；然而，准确估计内部电化学参数对于在各种操作条件下实现可靠的系统性能仍然至关重要。传统的参数识别方法在处理高维非线性SOFC模型时，往往面临着收敛速度慢、优化停滞过早和计算效率低下等挑战。为了克服这些问题，本研究提出了一种基于多采样机制的代理辅助差分进化（SADE-MSM）算法，该算法集成了代理建模、质心采样、全局预筛选和自适应局部搜索策略，以有效地优化SOFC参数，同时最大限度地减少昂贵的真实函数评估。SADE-MSM方法通过在不同温度和压力下的10种不同SOFC操作案例进行了广泛的实验研究，并与9种领先的元启发式算法对其性能进行了基准测试。结果表明，SADE-MSM具有最小的均方误差（MSE）、最快的收敛速度和最高的鲁棒性，在精度和计算成本方面优于所有比较方法。从理论上讲，这些发现验证了混合代理辅助进化框架在复杂多模态优化问题中的有效性，而实际上，它们表明SADE-MSM能够实现适用于微电网、混合可再生系统和预测控制平台应用的实时SOFC参数估计。读者将受益于强大、高效的方法，增强SOFC建模和运行可靠性，而未来的工作旨在将sde - msm扩展到现实世界不确定性（如系统老化、瞬态负载和传感器噪声）下的完全动态、在线优化场景。

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引用次数: 0

Mechanically reinforced solid-state polymer electrolyte using illite filler for flexible all-solid-state Li-metal batteries 柔性全固态锂金属电池用伊利石填料机械增强固态聚合物电解质

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-08 DOI: 10.1016/j.elecom.2025.108046

Jaesub Lee , Jeong-Jin Yang , Beomgi Kim , Sunkyung You , Jae-Kwang Kim , Young-Ran Lee , Seongki Ahn , Jeha Kim , Hong-Il Kim

Solid-state electrolytes have attracted significant attention due to their high safety, mechanical stability, and compatibility with lithium metal anodes, making them a critical component in the development of next-generation all-solid-state batteries. Polymer-based solid electrolytes (PSEs) offer advantages such as flexibility, processability, and good interfacial contact with electrodes but suffer from low structural stability. In this study, PSEs were fabricated by photopolymerization from ethoxylated trimethylolpropane triacrylate and expanded illite (EI) functional filler. The PSEs synthesized with 4 wt% EI show a favorable ionic conductivity of 2.31 × 10⁻⁴ S cm⁻¹ at 25 °C and an all-solid-state Li/NCM622 coin cell using the PSE as the electrolyte delivered a discharge capacity of 129.5 mAh g⁻¹ at 0.1C with 98 % Coulombic efficiency. In addition, the EI-containing PSE exhibited improved mechanical strength, enabling the fabrication of a flexible all-solid-state Li-metal battery pouch cell. This study offers valuable insight into the design of PSEs using clay-based fillers.

固态电解质由于其高安全性、机械稳定性和与锂金属阳极的兼容性而引起了人们的极大关注，使其成为下一代全固态电池发展的关键部件。聚合物基固体电解质（pse）具有柔韧性、可加工性和与电极良好的界面接触等优点，但结构稳定性较低。本研究以乙氧基化三甲基丙烷三丙烯酸酯和膨胀伊利石（EI）功能填料为原料，采用光聚合法制备了pse。以4 wt% EI合成的PSE在25°C时的离子电导率为2.31 × 10−4 S cm−1，以PSE为电解质的全固态Li/NCM622纽扣电池在0.1C时的放电容量为129.5 mAh g−1，库仑效率为98%。此外，含有ei的PSE表现出更好的机械强度，使柔性全固态锂金属电池袋芯的制造成为可能。本研究为使用粘土基填料的聚乙烯基复合材料的设计提供了有价值的见解。

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引用次数: 0

Modeling current density and SoC distribution of all-solid-state lithium-ion batteries 模拟全固态锂离子电池的电流密度和荷电状态分布

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-23 DOI: 10.1016/j.elecom.2025.108056

Zhenya Wang , Dmitri L. Danilov , Jingjing Zhou , Meng Zheng , Yi Huang , Tao Chen , Rüdiger-A. Eichel , Peter H.L. Notten

Researchers have conducted in-depth investigations into lithium-ion battery models. However, a notable limitation of existing models lies in the assumption of infinitely conductive current collectors, which compromises simulation accuracy. Herein, we present a model that explicitly accounts for current collector resistance, employing Kirchhoff's circuit laws and a suitable discretization method to characterize the associated current density and SoC distribution in all-solid-state thin-film batteries. Simulation results demonstrate that the highest SoC occurs near the charging tab, leading to preferential full-charge in this region. Intriguingly, when charging is interrupted at this stage, the battery enters a self-balancing state: the state of charge SoC near the tab gradually decreases. At the same time, SoC in other regions increases, culminating in a homogeneous SoC across the entire battery. This phenomenon reflects the underlying process of lithium-ion redistribution. Additionally, a larger resistance disparity between cathodic and anodic current collectors creates an inhomogeneous current density distribution, thereby accelerating localized battery aging. The approach adopted by our model exhibits broad generality and can be readily adapted to other battery types.

研究人员对锂离子电池模型进行了深入调查。然而，现有模型的一个显着局限性在于假设无限导电集流器，这损害了模拟精度。本文采用Kirchhoff电路定律和合适的离散化方法，提出了一个明确考虑集电极电阻的模型，以表征全固态薄膜电池中相关的电流密度和SoC分布。仿真结果表明，最高荷电状态出现在充电片附近，导致该区域优先充满电。有趣的是，当充电在此阶段中断时，电池进入自平衡状态：标签附近的充电SoC状态逐渐减少。与此同时，其他区域的SoC也在增加，最终在整个电池中实现均匀的SoC。这种现象反映了锂离子再分配的潜在过程。此外，阴极和阳极集流器之间较大的电阻差造成电流密度分布不均匀，从而加速局部电池老化。我们的模型所采用的方法具有广泛的通用性，可以很容易地适用于其他类型的电池。

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引用次数: 0

Surface orientation dependent electrochemical stability of RuO2 and IrO2 under acidic oxygen evolution reaction 酸性析氧反应中RuO2和IrO2表面取向依赖性的电化学稳定性

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-20 DOI: 10.1016/j.elecom.2025.108048

Naomi Naraki, Yuto Okayama, Naoto Todoroki

Ru- and Ir-oxides have considerable attentions as acidic oxygen evolution electrocatalysts for polymer electrolyte membrane water electrolysis. However, there have been no reports of comparative study of electrochemical stability depending on the surface orientations. Here, we prepared the (hkl)-oriented (hkl = 110, 001, 100) RuO₂ and IrO₂ thin films on rutile-TiO₂ single crystal substrates by arc-plasma deposition and investigated the surface orientation dependence of electrochemical stability under oxygen evolution reaction (OER) in 0.1 M HClO₄. At the initial state, RuO₂ showed a lower OER overpotential and smaller Tafel slope compared to IrO₂ for all the surface orientations. However, the overpotential of RuO₂ steeply increased during chronopotentiometry (CP) measurements, while the overpotential increase for IrO₂ was significantly suppressed. After the CP measurement, the overpotential of IrO₂ became smaller than that of RuO₂ for all the surface orientation. RuO₂ shows orientation dependence on the stability number, i.e. ratio of total charges used for CP and dissolution amount of Ru or Ir, while the IrO₂ didn't show a clear trend. The results demonstrated that the surface orientation of both RuO₂ and IrO₂ affects not only the activity, but also the stability, and elemental dissolution and the influence is more significant for RuO₂.

Ru和ir氧化物作为聚合物电解质膜电解的酸性析氧电催化剂受到了广泛的关注。然而，目前还没有关于表面取向对电化学稳定性影响的比较研究报道。本文采用电弧等离子体沉积方法在金红石- tio2单晶衬底上制备了（hkl）取向（hkl = 110、001、100）的RuO2和IrO2薄膜，并在0.1 M HClO4中研究了表面取向对电化学稳定性的影响。在初始状态下，与IrO2相比，RuO2在所有表面取向上都表现出更低的OER过电位和更小的Tafel斜率。然而，在时间电位测量（CP）期间，RuO2过电位急剧增加，而IrO2过电位的增加明显受到抑制。CP测量后，在所有表面取向上，IrO2的过电位都小于RuO2。RuO2的取向依赖于稳定数，即CP的总电荷比与Ru或Ir的溶出量，而IrO2的取向依赖不明显。结果表明，RuO2和IrO2的表面取向不仅影响其活性，而且影响其稳定性，其中元素溶解对RuO2的影响更为显著。

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引用次数: 0

Pt-based electrocatalyst for hydrogen evolution in acidic electrolytes 酸性电解液中析氢的pt基电催化剂

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-25 DOI: 10.1016/j.elecom.2025.108057

Muhammad Yasin , Nisar Khan , Muhammad Murad , Kashif Ali , Zonish Zeb , Shandana Saleem , Zafran Ullah

Platinum (Pt) based electrocatalysts remain the gold standard for the hydrogen evolution reaction (HER) in acidic environments due to their optimal hydrogen adsorption-free energy (ΔG_H⁎ ≈ 0), high electrical conductivity, and superior chemical stability. However, the scarcity and high cost of Pt necessitate innovative strategies to reduce Pt loading while enhancing catalytic efficiency and long-term durability. This review systematically presents the recent advancements in Pt-based HER electrocatalysts, emphasizing mechanistic insights across the Volmer, Heyrovsky, and Tafel steps, and explores the influence of Pt’s electronic structure and nanostructuring on HER kinetics. Strategies such as alloying with transition metals (e.g., Ni, Co, Zn), developing single-atom catalysts (SACs), and engineering hybrid systems with supports like MXenes, graphene aerogels, and metal carbides are discussed in detail. These approaches optimize active site exposure, electronic modulation, and catalyst-support interactions to achieve high turnover frequencies, low overpotentials, and enhanced electrochemical stability under industrially relevant conditions. The review further highlights key performance indicators such as Tafel slope, mass activity, TOF, and stability, along with advanced synthesis methods, including atomic layer deposition and microwave-assisted reduction. Finally, current challenges in scalability, degradation resistance, and cost-performance trade-offs are evaluated, providing future directions toward sustainable, high-performance HER systems based on Pt. This comprehensive analysis aims to bridge the gap between fundamental catalyst design and practical hydrogen production technologies.

铂（Pt）基电催化剂由于其最佳的无氢吸附能（ΔGH ≈0）、高导电性和优异的化学稳定性，仍然是酸性环境下析氢反应（HER）的金标准。然而，铂的稀缺性和高成本需要创新的策略来减少铂的负载，同时提高催化效率和长期耐久性。本文系统地介绍了基于Pt的HER电催化剂的最新进展，强调了Volmer， Heyrovsky和Tafel步骤的机理见解，并探讨了Pt的电子结构和纳米结构对HER动力学的影响。本文详细讨论了过渡金属（如Ni、Co、Zn）合金化、单原子催化剂（SACs）开发以及MXenes、石墨烯气凝胶和金属碳化物等支撑材料的工程混合系统等策略。这些方法优化了活性位点暴露、电子调制和催化剂-载体相互作用，以实现高周转频率、低过电位，并在工业相关条件下增强了电化学稳定性。综述进一步强调了关键性能指标，如Tafel斜率、质量活性、TOF和稳定性，以及先进的合成方法，包括原子层沉积和微波辅助还原。最后，对当前在可扩展性、抗降解性和成本-性能权衡方面的挑战进行了评估，为基于Pt的可持续、高性能HER系统的未来发展方向提供了建议。这项综合分析旨在弥合基本催化剂设计与实际制氢技术之间的差距。

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引用次数: 0

Binder-free electrode based on Zn-doped Ni3S2 vertically grown 2-dimensional nanostructures on Ni foam with boosted electrochemical performance for energy storage applications 基于zno掺杂Ni3S2垂直生长二维纳米结构的无粘结剂电极在Ni泡沫上具有提高电化学性能的储能应用

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-25 DOI: 10.1016/j.elecom.2025.108058

Muhammad Saleem Akhtar , Zaeem Ur Rehman , Witold Chromiński , Gabriela Komorowska , Tomasz Wejrzanowski

Transition metal sulfides have drawn a lot of interest in the field of electrochemical energy storage. However, their performance is hampered due to the stacking faults during the electrode fabrication. In this study, we report the Zn-doped Ni₃S₂ vertically grown 2-dimensional nanostructures on the conductive nickel foam by a one-step, rapid, energy-efficient, and cost-effective microwave-assisted method. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HR-TEM) analyses confirmed the morphological and phase composition as initially identified by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical investigations substantiated the boosted performance of the electrode, an impressive specific capacitance value of 1984 F g⁻¹ and 5.95 F cm⁻² at a discharge current of 3 mA cm⁻². Later on, this electrode, when tested in a Swagelok cell as a positive electrode and graphene nano pellets as a negative electrode, achieved a maximum energy density of 45.5 Whkg⁻¹ and 910 Wkg⁻¹ power at a discharge current rate of 1 A g⁻¹. The pseudocapacitive characteristics of this binder-free nanostructured electrode, driven by reversible redox reactions, highlight their potential for high-performance energy storage applications.

过渡金属硫化物在电化学储能领域引起了广泛的关注。然而，由于电极在制造过程中存在堆积缺陷，影响了其性能。在这项研究中，我们报道了通过一步、快速、节能和经济的微波辅助方法在导电泡沫镍上垂直生长zn掺杂Ni3S2的二维纳米结构。透射电子显微镜（TEM）和高分辨率透射电子显微镜（HR-TEM）分析证实了最初通过扫描电子显微镜（SEM）和x射线衍射（XRD）鉴定的形态和相组成。电化学研究证实了电极的性能提高，在放电电流为3 mA cm−2时，比电容值为1984 F g−1和5.95 F cm−2。随后，该电极在世伟洛克电池中作为正极和石墨烯纳米颗粒作为负极进行测试，在放电电流为1 ag−1的情况下，获得了45.5 Whkg−1和910 Wkg−1的最大能量密度。这种无粘结剂纳米结构电极的赝电容特性，由可逆氧化还原反应驱动，突出了它们在高性能储能应用中的潜力。

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引用次数: 0

Synergistic interface of Nb-doped MoSe2 and NiTe heterostructure enables efficient electrocatalysis for hydrogen evolution 铌掺杂MoSe2和NiTe异质结构的协同界面实现了高效的析氢电催化

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-27 DOI: 10.1016/j.elecom.2025.108061

Ramaraj Sukanya , Raj Karthik , Abdullah Al Mahmud , Eithne Dempsey , Deivasigamani Ranjith Kumar , Carmel B. Breslin , Jae-Jin Shim

To support clean hydrogen energy, we present a niobium-doped molybdenum diselenide integrated with nickel telluride (Nb-MoSe₂–NiTe) heterostructure as an efficient electrocatalyst for the hydrogen evolution reaction (HER) in acidic media. Nb-doping modulates the electronic structure of MoSe₂, while NiTe contributes to enhanced conductivity and introduces additional active interfacial sites. Structural and surface characterizations confirm successful doping and heterostructure formation. The optimized Nb-MoSe₂–NiTe composition achieves a low overpotential of 395 mV at 50 mA/cm² and a Tafel slope of 242 mV/dec, along with a high ECSA of 377.5 cm². These enhancements result from synergistic interactions that promote charge transfer and hydrogen adsorption. The Nb-MoSe₂–NiTe offers a promising platform for cost-effective HER catalysis, demonstrating a rational strategy that integrates electronic and interfacial engineering for sustainable hydrogen production.

为了支持清洁氢能源，我们提出了一种掺杂铌的二硒化钼与碲化镍（Nb-MoSe2-NiTe）异质结构，作为酸性介质中析氢反应（HER）的高效电催化剂。铌掺杂调节了MoSe2的电子结构，而NiTe则有助于增强电导率并引入额外的活性界面位点。结构和表面表征证实了成功的掺杂和异质结构的形成。优化后的Nb-MoSe2-NiTe组合物在50 mA/cm2时的过电位为395 mV， Tafel斜率为242 mV/dec， ECSA高达377.5 cm2。这些增强是由于促进电荷转移和氢吸附的协同相互作用。Nb-MoSe2-NiTe为具有成本效益的HER催化提供了一个有前途的平台，展示了一种合理的策略，将电子和界面工程集成在一起，实现可持续的氢气生产。

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引用次数: 0

Exploring operational barriers in microbial fuel cells: Enhancing energy recovery from wastewater 探索微生物燃料电池的操作障碍：提高废水的能量回收

IF 4.2 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications

Pub Date : 2025-11-01 Epub Date: 2025-09-24 DOI: 10.1016/j.elecom.2025.108051

Behzad Kanani , Alireza Zahedi , Fatemeh Abtahi , Sepideh Abedi

In response to global demands for more efficient energy and water management amidst environmental crises, wastewater is increasingly valued not just as a waste product but as a potential source of renewable energy. Microbial Fuel Cells are at the forefront of this transformation, capable of directly converting organic substrates found in wastewater into electrical energy through the activity of electrogenic bacteria. This paper provides a comprehensive review of advancements over the past two decades in Microbial Fuel Cell technology, focusing on improvements in system design, material selection, and operational efficacy that reduce costs and enhance energy efficiency. It examines key factors including internal resistance, dissolved oxygen, conductivity, organic loading rate, and optimal conditions such as temperature (20–35 °C) and pH (6.3–7.8) in maximizing the performance of Microbial Fuel Cells. Despite significant technological advances, several barriers remain that prevent the widespread commercial application of Microbial Fuel Cells, including high investment costs and limited scalability. Addressing these challenges is crucial for realizing the full potential of Microbial Fuel Cells in sustainable wastewater management. This review underscores the critical operational parameters that influence Microbial Fuel Cell efficiency, proposing strategies to overcome existing limitations and enhance the energy recovery process.

在环境危机中，为了应对全球对更有效的能源和水管理的需求，废水不仅被视为废物，而且越来越被视为可再生能源的潜在来源。微生物燃料电池处于这一转变的前沿，能够通过发电细菌的活动直接将废水中的有机基质转化为电能。本文全面回顾了微生物燃料电池技术在过去二十年中的进展，重点介绍了系统设计、材料选择和操作效率方面的改进，这些改进降低了成本，提高了能源效率。它考察了微生物燃料电池性能最大化的关键因素，包括内阻、溶解氧、电导率、有机负载率和最佳条件，如温度（20-35°C）和pH（6.3-7.8）。尽管取得了重大的技术进步，但仍存在一些阻碍微生物燃料电池广泛商业应用的障碍，包括高投资成本和有限的可扩展性。解决这些挑战对于实现微生物燃料电池在可持续废水管理中的全部潜力至关重要。这篇综述强调了影响微生物燃料电池效率的关键操作参数，提出了克服现有限制和提高能量回收过程的策略。

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引用次数: 0