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A green top-emitting organic light-emitting device with single-mode resonance and improved performance by using WO3 capping layer 采用WO3封盖层制备了单模共振的绿色顶发射有机发光器件,提高了器件的性能
Pub Date : 2010-10-11 DOI: 10.1117/12.888233
Sai-na Wang, Wenqing Zhu, Xue Chen, F. Xu, Hong Xu, Xiao-Wen Zhang, Xifeng Li, Xueyin Jiang, Zhilin Zhang
A top-emitting organic light-emitting device (TOLED) with an architecture of Ag/Wo3/4,4'-bis[N -(1-naphthyl-1)-N-phenyl-amino]-biphenyl/tris-(8-hydroxyquinoline)aluminium(Alq3)/LiF/Al/semitransparent Ag/Capping layer 20~40nm WO3 as capping layer has been investigated and WO3 was demonstrated to be an effective capping layer and improve the luminance by a factor of 1.7 between the maximum and minimum transmittance of top contact. In this paper, the thicknesses of organic layers are calculated based on Fabry-Perot cavity theory. And with optimized, the top -emitting organic devices with single-mode resonance have a good ability such as a brightness of 40920cd/m2 at the current density of 600ma/cm2 and a maximum luminous efficiency of 7.32cd/A at 9145cd/m2.
研究了一种结构为Ag/ WO3 /4,4′-双[N -(1-萘基-1)-N-苯基-氨基]-联苯/三-(8-羟基喹啉)铝(Alq3)/LiF/Al/半透明Ag/覆盖层(20~40nm) WO3作为覆盖层的顶发射有机发光器件(TOLED), WO3是一种有效的覆盖层,其顶接触最大透过率与最小透过率之间的比值为1.7倍。本文基于法布里-珀罗空腔理论计算了有机层的厚度。优化后的单模谐振顶发射有机器件在电流密度为600ma/cm2时亮度可达40920cd/m2,在电流密度为9145cd/m2时最大发光效率可达7.32cd/ a。
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引用次数: 0
A novel remote plasma sputtering technique for depositing high-performance optical thin films 制备高性能光学薄膜的新型远程等离子溅射技术
Pub Date : 2010-10-11 DOI: 10.1117/12.888188
Y. Bu, Z. Liu, J. Dutson, M. Thwaites, N. Chen, Z. Cai
This paper describes a novel remote plasma sputtering technique for depositing optical thin films. This technology is based on generating intensive plasma remotely from the target and then magnetically steering the plasma to the target to realize the sputter deposition. It overcomes several of inherent limitations in conventional sputtering techniques and realizes the fully uniform erosion over the surface of the target and less target poison. This allows a uniform reaction in the plasma phase when performing reactive sputtering, leading to the formation and deposition of material with a uniform stoichiometry and gives pseudo-independence of target current and voltage. This pseudo-independence offers a great deal of flexibility with regard to the control of growth conditions and film properties, the benefits include control of stress, very low deposition rates for ultra thin films. By remote reactive sputtering, dense metal-oxide optical thin films (SiO2, Ta2O5, Nb2O5) with a high deposition rate, excellent optical properties are achieved. High process stability shows an excellent time terminating accuracy for multilayer coating thickness control. Typically, thin film thickness control to <±1% is accomplished simply using time. The multilayer coating, including anti-reflection, dichroic mirror and 2μm laser mirrors are presented.
本文介绍了一种新型的远程等离子溅射沉积光学薄膜的技术。该技术的基础是远程产生强等离子体,然后将等离子体磁导向目标,实现溅射沉积。它克服了传统溅射技术固有的一些局限性,实现了靶材表面完全均匀的腐蚀和较少的靶材毒性。当进行反应溅射时,这允许在等离子体阶段进行均匀的反应,导致具有均匀化学计量的材料的形成和沉积,并提供目标电流和电压的伪独立性。这种伪独立性在控制生长条件和薄膜性能方面提供了很大的灵活性,其好处包括控制应力,超薄膜的沉积速率非常低。通过远程反应溅射,制备了致密的金属氧化物光学薄膜(SiO2, Ta2O5, Nb2O5),沉积速率高,光学性能优异。工艺稳定性高,对多层涂层厚度控制具有优良的时间终止精度。通常,薄膜厚度控制在<±1%是简单地利用时间来完成的。提出了增透、二向色镜和2μm激光反射镜等多层涂层。
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引用次数: 1
Morphology and structure properties of columnar CsI films on optical fiber plate 光纤板上柱状CsI薄膜的形貌和结构特性
Pub Date : 2010-10-11 DOI: 10.1117/12.888348
Dalin Yao, M. Gu, Xiaolin Liu, Shi-ming Huang, Bo Liu, Chen Ni
Among scintillators, columnar CsI screens are used in applications detecting charged particles, UV light or X-ray for high energy physics and medical radiography. CsI scintillator can be grown in special microcolumnar form that preserves spatial resolution in thick coatings. We report on the columnar CsI films fabricated directly on optical-fiber plate by traditional vacuum deposition method. There morphology and structure were examined by scanning electron microscopy and X-ray diffraction. Properties of films depend on deposit condition are discussed.
在闪烁体中,柱状CsI屏幕用于检测带电粒子,紫外线或高能物理和医学放射照相的x射线。CsI闪烁体可以以特殊的微柱状形式生长,在厚涂层中保持空间分辨率。本文报道了用传统真空沉积法直接在光纤板上制备柱状CsI薄膜。用扫描电子显微镜和x射线衍射仪对其形貌和结构进行了观察。讨论了沉积条件对薄膜性能的影响。
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引用次数: 0
Electronic and optical properties of Bi3.25La0.75Ti3O12 and SrBi2-xNdxNb2O9 perovskite-type ferroelectric materials Bi3.25La0.75Ti3O12和SrBi2-xNdxNb2O9钙钛矿型铁电材料的电子和光学性质
Pub Date : 2010-10-11 DOI: 10.1117/12.888426
Z. Hu, J. Chu
The phase transitions and the temperature dependent electronic properties of Bi3.25La0.75Ti3O12 (BLT) film have been studied by transmittance spectra from 80 to 480 K. Anomalies of the optical constants are observed at 160 K and 300 K, which can be ascribed to the phase transitions. The optical properties of SrBi2-xNdxNb2O9 (SBNN) ceramics with the Nd concentrations from 0 to 0.2 have been investigated by Raman scattering spectra and spectroscopic ellipsometry. It can be found that the lattice vibrations slightly depend on the Nd concentrations. Moreover, the optical band gap linearly increases with the Nd concentrations due to charge compensation by the Nd doping.
利用80 ~ 480 K透射光谱研究了Bi3.25La0.75Ti3O12 (BLT)薄膜的相变和温度相关的电子特性。在160 K和300 K时观察到光学常数的异常,这可以归因于相变。利用拉曼散射光谱和椭圆偏振光谱研究了Nd浓度为0 ~ 0.2的SrBi2-xNdxNb2O9 (SBNN)陶瓷的光学性质。可以发现,晶格振动与Nd浓度有轻微的关系。此外,由于Nd掺杂的电荷补偿,光学带隙随Nd浓度线性增加。
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引用次数: 0
Effects of annealing on the structural properties of Cu(In,Ga)Se2 thin films prepared by RF sputtering 退火对射频溅射制备Cu(In,Ga)Se2薄膜结构性能的影响
Pub Date : 2010-10-11 DOI: 10.1117/12.888168
Gang Shi, J. Chu
Cu(In,Ga)Se2 (CIGS) thin films have been prepared by radio frequency (RF) magnetron sputtering from a CuIn0.8Ga0.2Se2 target. The effects of in-situ annealing in Ar atmosphere on phase structure, composition and surface morphology of the films have been investigated by X-ray diffraction (XRD), energy dispersive analysis of X-rays (EDAX), atomic force microscopy (AFM) and Raman spectroscopy. XRD patterns show that both as-deposited and annealed films have a chalcopyrite structure with strong (112) preferred orientation. The annealed films display a higher degree of crystallinity and smoother surface, while there is little difference in grain size for films annealed at temperatures ranging from 300°C to 500°C. Results of EDAX reveal that the films are near to stoichiometry. Raman spectrum of the films annealed at 300°C shows only the CIGS A1 mode peak indicating the formation of single-phase chalcopyrite with enhanced crystalline ordering. The films annealed at higher temperatures exhibit a non-chalcopyrite mode at around 260 cm-1 assigned to Cu2-xSe secondary phase which is detrimental to CIGS solar cells.
以CuIn0.8Ga0.2Se2为靶材,采用射频磁控溅射法制备了Cu(In,Ga)Se2 (CIGS)薄膜。利用x射线衍射(XRD)、x射线能谱分析(EDAX)、原子力显微镜(AFM)和拉曼光谱研究了原位退火对薄膜相结构、组成和表面形貌的影响。XRD谱图表明,沉积膜和退火膜均具有强(112)择优取向的黄铜矿结构。退火后的薄膜结晶度较高,表面光滑,而在300 ~ 500℃范围内退火后的薄膜晶粒尺寸差异不大。EDAX的结果表明,薄膜的化学计量值接近。在300℃退火后,薄膜的拉曼光谱仅显示CIGS A1模式峰,表明形成了晶体有序增强的单相黄铜矿。在较高温度下退火的薄膜在260 cm-1左右呈现非黄铜矿模式,分配给Cu2-xSe次级相,这对CIGS太阳能电池是有害的。
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引用次数: 0
Study of designing minus filters based on rugate theory 基于规则门理论的负滤波器设计研究
Pub Date : 2010-10-11 DOI: 10.1117/12.888187
Bai-sen Zhang, Mianjun Ma, Y. Xiong, Tao Chen, D. Wang, Chen Li, Miao Yang
The influence of the rugate filter index profile function parameters, such as refractive index amplitude, film thickness and reference wavelength on the minus filter transmission spectrum, were investigated in this paper. The results show that the rejection bandwidth was affected by the refractive index amplitude, the depth of attenuation region was influenced by the film thickness, and the position of cut-off wavelength was determined by the reference wavelength. The method using the Rugate theory to design minus filters was presented, and several kinds of minus filters were designed using the method.
研究了折射率振幅、薄膜厚度和参考波长等折射率函数参数对负滤光片透射谱的影响。结果表明:抑制带宽受折射率幅值影响,衰减区域深度受薄膜厚度影响,截止波长位置由参考波长决定。提出了利用Rugate理论设计负滤波器的方法,并利用该方法设计了几种类型的负滤波器。
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引用次数: 0
Preparation and investigation of Fe2O3-SiO2-CTAB transparent nano-composite films Fe2O3-SiO2-CTAB透明纳米复合膜的制备与研究
Pub Date : 2010-10-11 DOI: 10.1117/12.888177
Lin Li, Lanfang Yao, Shuo Wang, Ruiqing Xu, Linlin Tian, X. Fang
Fe2O3-SiO2-CTAB transparent nano-composite films were prepared by means of a two-step acid-catalyzed method and sol-gel process using surfactant cetyltrimethylammonium bromide (CTAB) as template and tetraethoxysilane (TEOS) as the starting material, iron nitrate Fe(NO3)3·9H2O as iron source material. Optical properties, structural and magnetic characteristics of the films were investigated by UV-visible spectra, FT-IR spectra and vibrating sample magnetometer (VSM). The transparency of the high temperature treated Fe2O3-SiO2-CTAB nano-composite films exceeds the glass substrate. It is also found that the saturation magnetization (Ms) of the films increases with the treating temperature. The magnetization measurements reveal that Fe2O3-SiO2-CTAB nano-composite films display normal ferromagnetic behaviors. It is also shown that the CTAB plays a key role in the optical and magnetic properties of Fe2O3-SiO2-CTAB composite films.
以表面活性剂十六烷基三甲基溴化铵(CTAB)为模板剂,四乙氧基硅烷(TEOS)为原料,硝酸铁Fe(NO3)3·9H2O为铁源材料,采用两步酸催化和溶胶-凝胶法制备了Fe2O3-SiO2-CTAB透明纳米复合薄膜。利用紫外可见光谱、傅里叶红外光谱和振动样品磁强计(VSM)研究了薄膜的光学性质、结构和磁性。经高温处理的Fe2O3-SiO2-CTAB纳米复合薄膜的透明度超过玻璃基板。膜的饱和磁化强度(Ms)随处理温度的升高而增大。磁化性能测试表明,Fe2O3-SiO2-CTAB纳米复合膜具有正常的铁磁行为。实验还表明,CTAB对Fe2O3-SiO2-CTAB复合薄膜的光学和磁性能起关键作用。
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引用次数: 0
Surface plasmon polaritons of multi-layered structures containing metamaterial 含有超材料的多层结构的表面等离子激元极化
Pub Date : 2010-10-11 DOI: 10.1117/12.888180
Li Wang, Guiqiang Du, Bingyuan Zhang, Changzheng Wang
Structures containing metamaterials are considered. We mainly investigate the influence of spacer layer's thickness and metamaterials's damping term to the dips appearing in the attenuated total reflection (ATR) spectrum. It is found that the layer thickness and material's damping term have great impact on the surface resonance modes and the dips which appear in ATR spectrum. The results show that in order to observe the dips by using ATR, for the metamaterials, we should select proper values of damping term and spacer's thickness.
考虑包含超材料的结构。我们主要研究了间隔层的厚度和超材料的阻尼项对衰减全反射(ATR)谱中出现的倾角的影响。研究发现,层厚和材料的阻尼项对表面共振模式和ATR谱出现的倾角有很大影响。结果表明,为了用ATR观察衰减,对于超材料,应选择合适的阻尼项和间隔层厚度。
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引用次数: 0
Preparation and optical properties of polycrystalline HgI2 thin films utilizing vertical deposition technique of chemistry 利用化学垂直沉积技术制备多晶HgI2薄膜及其光学性能
Pub Date : 2010-10-11 DOI: 10.1117/12.888249
Jie Zhou, W. Shi, Guang-pu Wei, Juan Qin, Linjun Wang, Jieli Chen
Mercuric Iodide (HgI2) is a promising semiconductor material for nuclear radiation detectors working at room temperature, especially for x-ray and γ-ray detectors. The influences of different growth temperatures on qualities of thin films were studied. The structure and optical properties of thin films were characterized by x-ray diffraction spectroscopy, metallography and UV-VIS spectrophotometer. Our results can be summarized as following: XRD analysis shows crystallinity of HgI2 in thin films depends mainly on the growth temperatures, that is, the XRD reflections become stronger with the decrease of the growth temperature. The optimum growth temperature for preparation of polycrystalline HgI2 thin film utilizing vertical deposition technique of chemistry is about 20°C. The corresponding thin film has a good uniformity with thickness of about 800 nm, perpendicular to the substrate along <001> direction. Based on its optical performance testing, our calculations found that HgI2 thin film grown at 20°C has a wide energy band gap of about 2.26 eV.
碘化汞(HgI2)是一种很有前途的半导体材料,可用于室温下的核辐射探测器,特别是x射线和γ射线探测器。研究了不同生长温度对薄膜质量的影响。采用x射线衍射、金相和紫外-可见分光光度计对薄膜的结构和光学性能进行了表征。我们的研究结果如下:XRD分析表明,薄膜中HgI2的结晶度主要取决于生长温度,即随着生长温度的降低,XRD反射变强。利用化学垂直沉积技术制备多晶HgI2薄膜的最佳生长温度约为20℃。相应的薄膜具有良好的均匀性,厚度约为800 nm,沿方向垂直于衬底。基于其光学性能测试,我们的计算发现,在20°C生长的HgI2薄膜具有约2.26 eV的宽能带隙。
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引用次数: 0
Multilayer coatings for optics in the extreme ultraviolet 极紫外光学用多层涂层
Pub Date : 2010-10-11 DOI: 10.1117/12.888463
J. Larruquert, M. Vidal-Dasilva, Sergio García-Cortés, L. R. Rodríguez-de Marcos, M. Fernández-Perea, J. Aznárez, J. A. Méndez
The strong absorption of materials in the extreme ultraviolet (EUV) above ~50 nm has precluded the development of efficient coatings. The development of novel coatings with improved EUV performance is presented. An extensive research was performed on the search and characterization of new materials with low absorption or high reflectance. Lanthanide series was found to be a source of materials with relatively low absorption in this range, where most materials in nature present a strong absorption. Other materials, such as SiO and B, have been found to have interesting properties for applications on EUV coatings. As a result, novel multilayers based on Yb, Al, and SiO have been developed with narrowband performance in the 50-92 nm range. In some cases, the difficulty of developing narrowband coatings in the EUV can be overcome by designing multilayers that address specific purposes, such as maximizing and/or minimizing the reflectance at two or more wavelengths or bands. In this direction, we are working towards the development of coatings that combine a relatively high reflectance in a desired EUV band with a low reflectance in another band, for applications in which the presence of the latter radiation may mask a weak EUV radiation source.
材料在~50 nm以上的极紫外光(EUV)中的强吸收阻碍了高效涂料的发展。介绍了提高极紫外性能的新型涂层的研究进展。对低吸收或高反射率新材料的寻找和表征进行了广泛的研究。在这个范围内,镧系元素被发现是吸收相对较低的材料来源,而自然界中大多数材料都有很强的吸收。其他材料,如SiO和B,已被发现在EUV涂层上具有有趣的性能。因此,基于Yb, Al和SiO的新型多层材料在50-92 nm范围内具有窄带性能。在某些情况下,可以通过设计满足特定目的的多层膜来克服在EUV中开发窄带涂层的困难,例如最大化和/或最小化两个或多个波长或波段的反射率。在这个方向上,我们正在努力开发一种涂层,将期望的极紫外波段的相对高反射率与另一波段的低反射率结合起来,用于后一种辐射可能掩盖弱极紫外辐射源的应用。
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引用次数: 0
期刊
International Conference on Thin Film Physics and Applications
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