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2012 7th International Forum on Strategic Technology (IFOST)最新文献

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Formation of active surface of copper catalysts in methanol oxidation 甲醇氧化中铜催化剂活性表面的形成
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357480
A. Pestryakov, V. Lunin, O. Temkin, D. Derusova, N. Bogdanchikova, V. Petranovskii
Features of the process of methanol partial and deep oxidation on supported copper catalysts as compared with silver samples have been studied. The influence of supports of different acid-base nature and modifying additives of Zr, Ce, La and Cs oxides on electronic states of supported copper was investigated by the methods of diffuse reflectance electron spectroscopy, XRD and electron microscopy. By comparison of catalytic and spectroscopic data a conclusion on the nature of active sites of copper catalysts in this process has been made.
研究了负载型铜催化剂上甲醇部分氧化和深度氧化过程的特点,并与银样品进行了比较。采用漫反射电子能谱、XRD和电镜等方法研究了不同酸碱性质的载体和Zr、Ce、La、Cs氧化物改性添加剂对载体铜电子态的影响。通过对催化和光谱数据的比较,得出了铜催化剂在该过程中活性位点的性质。
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引用次数: 0
Mathematical modeling and steady states multiplicity analysis of methyl tert-butyl ether reactive distillation synthesis 甲基叔丁基醚反应精馏合成的数学建模及稳态多重性分析
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357495
M. A. Samborskaya, O. Mityanina, M. Gyngazova
This paper is devoted to forming the mathematical model of methyl tert-butyl ether (MTBE) production by means of reactive distillation. The model based on physicochemical principles of the process and can be used for further designing, researching and steady states multiplicity analysis.
建立了反应精馏法生产甲基叔丁基醚(MTBE)的数学模型。该模型基于该过程的物理化学原理,可用于进一步的设计、研究和稳态多重性分析。
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引用次数: 1
Investigation of the laws of ionizing radiation effect on the stability of the colloidal solutions of iron 电离辐射对铁胶体溶液稳定性影响规律的研究
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357492
L. R. Merinova, L. Shiyan, G. Remnev, A. Stepanov, M. Kaikanov, D. Voyno
In the paper, the effect of the pulse electron radiation on the stability of the colloidal iron solutions is studied. The work is performed on the standard test solutions which correspond to the real natural and waste water regarding their chemical composition. The irradiation was performed using the pulse accelerator TEA-500 with the electron energy 500 keV and pulse duration 60 ns. The dose was calculated using the potassium nitrate recommended for measuring the dose of the pulse electron radiation. The standard test solution used for radiation contained iron, silicon and humic substances ions in the correlation 5.6:20:2.2 mg/l, respectively. The solutions were subjected to radiation within the range of 0.6-5.0 Mrad. The efficiency of radiation was estimated by the variation in iron chromaticity and concentration in the initial and irradiated solution. The decrease in iron concentration and solution chromaticity after the radiation indicates the violation of the stability of the colloidal solution and the Fe(OH)3 coagulation sludge. To explain the interaction of the radiation with the colloidal particles, the water radiolysis mechanism was considered, since the most of the ionizing radiation energy is consumed for the interaction with the water forming a large spectrum of radiolysis products. In the paper we offer the interaction mechanism of hydrated electron and the colloidal particles on the ground that the hydrated electron has a much longer life compared to H and OH radicals and is formed with a large radiation-chemical output which is equal to 3.3÷3.5 ions per 100 eV. The lifetime of the hydrated electron is 2.3*10-4 s. Besides, the size of the hydrated electron is 0.38 nm that is much less than the size of micelle and because of these factors it interacts with the micelle nucleus. According to the literature data, the mechanism of the electron transfer to the micelle nucleus is accompanied with the violation of the double electrical layer, the destruction of the micelle forming the Fe(OH)3 sludge that was observed during the electron beam irradiation of the standard test colloidal solutions. In the paper we present the results on the effect of the ion nitrate on the kinetics of the variation in iron ion color and concentration in the standard test solution.
本文研究了脉冲电子辐射对胶体铁溶液稳定性的影响。这项工作是在标准测试溶液上进行的,这些溶液对应于真实的天然水和废水的化学成分。采用TEA-500脉冲加速器进行辐照,电子能量500 keV,脉冲持续时间60 ns。剂量是用硝酸钾来计算的,硝酸钾被推荐用于测量脉冲电子辐射的剂量。辐射标准试验溶液中铁、硅、腐殖质离子的相关系数分别为5.6:20:2.2 mg/l。溶液的辐照范围为0.6 ~ 5.0 Mrad。通过初始溶液和辐照溶液中铁的色度和浓度的变化来估计辐照效率。辐照后铁浓度和溶液色度的下降表明胶体溶液和Fe(OH)3混凝污泥的稳定性受到了破坏。为了解释辐射与胶体粒子的相互作用,考虑了水的辐射分解机制,因为大部分电离辐射能量被消耗在与水的相互作用中,形成了大谱的辐射分解产物。本文给出了水合电子与胶体粒子的相互作用机理,理由是水合电子的寿命比H和OH自由基长得多,形成的辐射化学输出大,相当于每100 eV 3.3÷3.5个离子。水合电子的寿命为2.3*10-4 s。此外,水合电子的尺寸为0.38 nm,远小于胶束的尺寸,由于这些因素,它与胶束核相互作用。根据文献数据,电子向胶束核转移的机制伴随着双电层的破坏,形成Fe(OH)3污泥的胶束被破坏,这是在标准测试胶体溶液的电子束辐照过程中观察到的。本文介绍了硝酸离子对标准试验溶液中铁离子颜色和浓度变化动力学的影响。
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引用次数: 2
Information system of bankruptcy risk management of an enterprise 企业破产风险管理信息系统
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357615
A. Zakharova, E. Telipenko
Issues of development of mathematical models and the software of Information System of Bankruptcy Risk Management of an enterprise (ISBRM) are considered in the paper. ISBRM implements a multilevel approach to bankruptcy risk management of an enterprise, based on three main phases: the identification of risk factors, the assessment of factors and bankruptcy risk level, the choice of risk minimization methods.
本文研究了企业破产风险管理信息系统(ISBRM)的数学模型和软件开发问题。ISBRM采用多层次的方法对企业进行破产风险管理,主要分为三个阶段:风险因素的识别、因素与破产风险水平的评估、风险最小化方法的选择。
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引用次数: 9
The comparison of model compaction method to make uniformly dense ceramic bodies 模型压实法制作均匀致密陶瓷体的比较
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357599
K. Oleg, D. Edgar, S. Vitaly, C. Prakorb
The “collector” method of uniaxial dry compacting homogeneously dense powdered bodies of complex shape without macroscopic defects has been developed. It was based on the self-alignment of uniform density regions within a green compact by design of special mold to reduce die-wall friction effects. An equation was proposed that determined the density differential throughout the height of a green compact, which depended on geometrical parameters, and required the controlled movement of die parts. The technique of pressing with the collector method has been developed and patented by TPU. Based on the principles of the collector method a compaction mold of spiral type was modeled for compaction of cylindrical compacts with two alternating, oppositely-moving parts of the passive shaping surface with sliders, twisted at an angle of 36 degrees. The process of powder compaction was simulated by finite element method. The simulation results of the deformation process in the compacts showed that the density of each layer distributed irregularly with the curvature of isosurfaces in the direction of movement of the punch. The results of comparative simulation showed that the statistical dispersion of local values of the deformation of the green compacts made by collector method with the mold of spiral type is reduced to 48% when compared with conventional static compaction and reduced to 5% when compared with collector compaction using the mold of non-spiral type. This method decreases the density gradients. It can be applied to manufacture ceramic articles from nanopowders like impellers and plates with longitudinal holes.
提出了一种无宏观缺陷、形状复杂、均质致密粉状体的单轴干燥压实“收集器”方法。它是基于自对准均匀密度区域内的绿色紧凑型设计的特殊模具,以减少模壁摩擦的影响。提出了一个方程,确定密度微分在整个绿色压块的高度,这取决于几何参数,并要求控制运动的模具零件。TPU开发了捕集剂加压技术,并申请了专利。基于集电极法原理,建立了一种螺旋型压实模具,该压实模具采用带滑块的被动成型表面的两个相互交替、相反运动的零件,以36度的角度旋转进行压实。采用有限元法对粉末压实过程进行了模拟。变形过程的仿真结果表明,各层密度在冲床运动方向上随等曲面曲率呈不规则分布。对比仿真结果表明,与常规静态压实相比,集热器法用螺旋型模具压实的绿坯局部变形值的统计离散度降低了48%,与采用非螺旋型模具的集热器压实相比,统计离散度降低了5%。这种方法减小了密度梯度。它可以应用于由纳米粉末制成的陶瓷制品,如叶轮和纵向孔板。
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引用次数: 4
A study of crystal structure and particle size of perovskite type La1−xCuxMnO3+δ (x≤0.1) compounds suspended in water 钙钛矿型La1−xCuxMnO3+δ (x≤0.1)悬浮物的晶体结构和粒径研究
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357545
G. Batdemberel, G. Oyungerel, S. Chadraabal, G. Tsermaa, P. Munkhbaatar
Nanosized La1-xCuxMnO3 (x≤0.1) was synthesized at different temperatures by using heteronuclear complexing method. X-ray diffraction analysis show that sample consists of two phases: La1-xCuxMnO3 (x≤0.1) having R3̅c space group with rhombohedral symmetrical structure and La2Cu2O5 having C2/c space group with monoclinic symmetrical structure. The results show the quantity of La1-xCuxMnO3 increase from 91.22 to 97.62%, while quantity of La2Cu2O5 compound decrease from 8.78 to 2.37% with rising of calcination temperature from 500°C to 900°C. The Photon Cross Correlation Spectroscopy (PCCS) was used to measure size distribution. The results reveal that particle mean diameter increases from (276±4) to (455±5)nm, particle specific surface area (Sv) decreases from 21.84 to 13.29 m2/cm3, particle size distribution equals to 55-761nm and particle surface and volume mean diameter (SMD, VMD) increase from 247 to 459nm.
采用异核络合法在不同温度下合成了纳米La1-xCuxMnO3 (x≤0.1)。x射线衍射分析表明,样品由两相组成:La1-xCuxMnO3 (x≤0.1)具有菱形对称结构的R3 /c空间群和La2Cu2O5具有单斜对称结构的C2/c空间群。结果表明:当煅烧温度从500℃升高到900℃时,La1-xCuxMnO3化合物的含量从91.22%增加到97.62%,La2Cu2O5化合物的含量从8.78%下降到2.37%;光子互关光谱(PCCS)用于测量尺寸分布。结果表明:颗粒平均直径从(276±4)nm增加到(455±5)nm,颗粒比表面积(Sv)从21.84减小到13.29 m2/cm3,粒径分布在55 ~ 761nm之间,颗粒表面和体积平均直径(SMD、VMD)从247增加到459nm。
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引用次数: 0
Mathematical model of the radial cross section of tree rings 树木年轮径向截面的数学模型
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357810
P. Akulov, V. Tartakovsky, Yu N. Lsaev, V. D. Nesvetailo, Y. Volkov, V. Popov
A mathematical model of tree rings in the form of an interference pattern is presented. The model allows retrospective reconstruction of continuous radial growth of a tree during the entire vegetation season. The radial dependence of the wood density is considered as a certain oscillation whose phase is a strictly increasing function of radius. The radial growth is defined as a monotonic function of time, inverse with respect to the phase. Algorithms for model analysis are based on the condition of dispersion causality. Experimental results are discussed.
提出了树木年轮干涉图样的数学模型。该模型允许在整个植被季节对树木的连续径向生长进行回顾性重建。木材密度的径向依赖关系被认为是一个一定的振荡,其相位是半径的严格递增函数。径向增长被定义为时间的单调函数,与相位成反比。模型分析算法是基于离散因果关系的条件。对实验结果进行了讨论。
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引用次数: 0
Development tools for common information space of distributed industrial company 分布式工业企业公共信息空间的开发工具
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357641
A. Kudinov, N. Markov, V. Veyber
Analysis of distributed industrial companies automation problems shows that most of the companies have a lot of stand-alone heterogeneous information systems and applications. It indicates to urgent problem of the system integration scientific basis establishing and, in practice, company's common information space development. This work presents original software tools for developing of common information space of distributed industrial company by means of information systems and applications data integration. Software tools principles of realization are offered and integrated model of enterprise industrial data is designed. The main components of the tools are a core and adapters that provide interaction between the core and the applications (or information systems). Algorithms of data integration participants coordination, data models structural matching, etc. are developed. The approach of data collecting from automated process control systems and delivering them to the top levels of enterprise management is offered. The results of developed algorithms and approach efficiency analysis are considered. The features of software tools architecture and development are described. The results of the software tools implementation within common information space development for oil and gas production company with big amount of remote fields are given.
对分布式工业企业自动化问题的分析表明,大多数企业都有大量独立的异构信息系统和应用。指出了系统集成科学基础的建立和企业共同信息空间开发在实践中的迫切问题。本文以信息系统与应用数据集成为手段,为分布式工业企业公共信息空间的开发提供了独创的软件工具。给出了软件工具的实现原理,设计了企业工业数据集成模型。工具的主要组件是核心和适配器,它们提供核心与应用程序(或信息系统)之间的交互。提出了数据集成、参与者协调、数据模型结构匹配等算法。提供了从自动化过程控制系统收集数据并将其交付给企业管理高层的方法。考虑了已开发算法和方法效率分析的结果。描述了软件工具体系结构和开发的特点。给出了在具有大量偏远油田的油气生产公司公共信息空间开发中软件工具的实现结果。
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引用次数: 0
Determination of kinetic characteristics of polycrystalline ferrites oxidation using TG analisis 用热重分析测定多晶铁氧体氧化的动力学特性
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357797
A. Surzhikov, T. Frangulyan, Serge Ghyngazov, O. Kazakovskaya, E. Lysenko
Using non-isothermal thermogravimetry (TG), the oxidation kinetics of oxygen-deficient lithium-titanium ferrospinel, Li0.649 Fe1.598 Ti0..5Zn0..2Mn0.051O4-δ, manufactured by ceramic engineering is investigated. The oxidation annealing of powder samples is performed in air. According to the X-ray phase analysis, the processes giving rise to variations in oxygen content occur within single-phase spinel structure. The experimental kinetic results are processed using the Netzsch Thermokinetics software. The oxidation rate constants and the effective coefficients of atmospheric oxygen diffusion into the ferrites are determined. The effective activation energy E of oxygen diffusion is found to be 1.95 eV. It is demonstrated that an increase in the oxygen non-stoichiometry parameter δ as a result of recovery annealing of ferrite powders in vacuum at T=1070 K for 2 hours gives rise to a slight decrease in E down to 1.89 eV. The activation energy of oxygen grain-boundary diffusion is identified by the electroconduction method. The resulting value 1.93 eV is fairly consistent with that obtained by TG.
采用非等温热重法(TG)研究了陶瓷工艺制备的缺氧锂钛尖晶石Li0.649 Fe1.598 Ti0. 5Zn0. 2Mn0.051O4-δ的氧化动力学。粉末样品的氧化退火在空气中进行。根据x射线相分析,引起氧含量变化的过程发生在单相尖晶石结构中。实验动力学结果用Netzsch热动力学软件处理。测定了氧化速率常数和大气氧向铁氧体扩散的有效系数。氧扩散的有效活化能E为1.95 eV。结果表明,铁素体粉末在T=1070 K真空条件下恢复退火2小时后,氧非化学计量参数δ增大,E略有下降,降至1.89 eV。用电导法确定了氧晶界扩散的活化能。所得值1.93 eV与热重法所得值相当一致。
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引用次数: 0
Bangladeshi Vehicle License Plate Detection method based on HSI color model and geometrical properties 基于HSI颜色模型和几何属性的孟加拉车牌检测方法
Pub Date : 2012-11-26 DOI: 10.1109/IFOST.2012.6357650
K. Deb, M. Hossen, M. I. Khan, M. R. Alam
Bangladeshi Vehicle License Plate Detection (BVLPD) plays an important and inevitable role in Vehicle License Plate Recognition (VLPR) system. The most challenging part of this method is to detect the region of the license plate from the vehicle image. In this paper, we propose an algorithm for analyzing the vehicle image to extract the LP position in the image of the vehicle. Initially, HSI color model is adopted to select a threshold for detecting candidate regions and then different geometrical properties of LP such as area, bounding box, aspect ratio are used to determine whether the candidate regions contain LP or not. Finally the candidate region is verified by intensity histogram. The proposed method is able to deal with candidate regions under different scale of the plate. In the experiment more than 100 images are used which are taken under different conditions such as uneven illumination, complex scenes, varied weather and varied distances from the vehicle to camera. The overall rate of success of the license plate detection algorithm is 85%.
孟加拉车牌检测(BVLPD)在车牌识别(VLPR)系统中起着重要而不可避免的作用。该方法最具挑战性的部分是从车辆图像中检测车牌区域。本文提出了一种车辆图像分析算法,提取车辆图像中的LP位置。首先采用HSI颜色模型选择检测候选区域的阈值,然后利用LP的不同几何属性如面积、边界框、纵横比来确定候选区域是否包含LP。最后利用强度直方图对候选区域进行验证。该方法能够处理不同尺度下的候选区域。在实验中,使用了100多张图像,这些图像是在不同的条件下拍摄的,例如光照不均匀、场景复杂、天气变化以及车辆到相机的距离变化。车牌检测算法的总体成功率为85%。
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引用次数: 19
期刊
2012 7th International Forum on Strategic Technology (IFOST)
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