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Microstructure evolution, mechanical properties and wear resistance of Fe based bulk metallic glass consolidated via spark plasma sintering 火花等离子烧结固结铁基大块金属玻璃的显微组织演变、力学性能和耐磨性
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2026-01-01 DOI: 10.1016/j.intermet.2025.109145
M.R. Rezaei , R. Nazemnezhad , H. Vafaeenezhad , A. Fazli Sostani , A. Moradi Koopai
This study examines how spark plasma sintering (SPS) temperature and heating rate (in the presence of zirconium element) affect the densification behavior, microstructure, mechanical properties, and tribological behavior of Fe75Si15B5Zr5 metallic glass. Sintering took place in the supercooled liquid region of the metallic glass powder. The Archimedes method measured densification behavior. Scanning electron microscopy (SEM) provided detailed microstructural information and allowed qualitative evaluation of fracture toughness. X-ray diffraction handled phase analysis and quantified crystallization in the amorphous phase. Ball-on-disk wear testing evaluated tribological behavior, and Vickers microhardness testing assessed mechanical properties. Results revealed that higher sintering temperature increased both the crystallization degree of the amorphous phase and the densification rate. In contrast, heating rate produced mixed effects on crystallization and densification. The sample sintered at the highest temperature with the lowest heating rate exhibited the best fracture resistance and achieved the highest microhardness value of 1096 HV1. Across all samples, delamination of the tribological oxide layer was determined as the main wear mechanism.
本研究考察了火花等离子烧结(SPS)温度和加热速率(在锆元素存在的情况下)对Fe75Si15B5Zr5金属玻璃的致密化行为、微观结构、力学性能和摩擦学行为的影响。烧结发生在金属玻璃粉末的过冷液区。阿基米德方法测量致密化行为。扫描电子显微镜(SEM)提供了详细的微观结构信息,并允许定性评价断裂韧性。x射线衍射处理物相分析和非晶相的定量结晶。球盘磨损测试评估摩擦学行为,维氏显微硬度测试评估机械性能。结果表明,烧结温度越高,非晶相的结晶程度越高,致密化速度越快。加热速率对结晶和致密化的影响是混合的。在最高温度和最低加热速率下烧结的试样具有最佳的抗断裂性能,显微硬度达到最高的1096 HV1。在所有样品中,摩擦学氧化层的分层被确定为主要的磨损机制。
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引用次数: 0
Role of surface roughness in governing the mechanical, electrical, magnetic, and optical properties of amorphous Co40Fe40Gd20 thin films on flexible substrates 柔性基板上非晶Co40Fe40Gd20薄膜的机械、电学、磁学和光学性能受表面粗糙度的影响
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-06 DOI: 10.1016/j.intermet.2025.109090
Shih-Hung Lin , Yung-Huang Chang , Yuan-Tsung Chen , Xuan-Ming Su , Wen Chang , Huang-Wei Chang
Amorphous cobalt-iron-gadolinium (Co40Fe40Gd20) thin films with thicknesses of 10 nm–50 nm were deposited on flexible polyethylene terephthalate (PET) and polymethyl methacrylate (PMMA) substrates via direct-current (DC) magnetron sputtering and annealed at 40 °C and 80 °C to investigate the effects of film thickness, annealing temperature, and substrate type on structural, mechanical, electrical, magnetic, and optical properties. X-ray diffraction (XRD) confirmed the films remained amorphous under all conditions, due to the high gadolinium (Gd) content and limited thermal energy below the polymer glass transition temperatures. Atomic force microscopy (AFM) revealed substrate-dependent surface evolution, with PET films showing a decrease in roughness from 5.91 nm to 4.79 nm after 80 °C annealing, whereas PMMA films exhibited minimal roughness change. Surface energy increased with film thickness but decreased slightly upon annealing due to atomic rearrangement. Mechanical properties improved with both thickness and annealing. PET films reached a maximum Young's modulus of 22.58 GPa and hardness of 4.75 Gpa at 50 nm after 80 °C annealing, while PMMA films achieved 15.05 GPa modulus at 50 nm after 40 °C. Electrical measurements showed a significant reduction in sheet resistance from 7261 Ω/sq for as-deposited 10 nm films to 144 Ω/sq for 50 nm films annealed at 80 °C, with enhanced carrier mobility and concentration. Magnetic analysis confirmed in-plane soft magnetic behavior, with minor variations in coercivity (Hc) and saturation magnetization (Ms) influenced by stress relaxation and morphology-induced anisotropy. Magnetic force microscopy (MFM) indicated moderate annealing promoted ordered stripe domains, while higher temperatures induced domain coarsening. Optical characterization revealed transmittance decreased with thickness, reaching 40.68 % and 47.15 % at 10 nm on PET and PMMA at annealing 40 °C, whereas absorbance increased, indicating thickness-dominated optical behavior. These findings demonstrate that controlled annealing and thickness optimization enable precise tuning of surface roughness and multifunctional properties of CoFeGd amorphous films on flexible substrates, supporting their design for advanced flexible spintronic, electronic, and optoelectronic devices.
采用直流(DC)磁控溅射技术在柔性聚对苯二甲酸乙二醇酯(PET)和聚甲基丙烯酸甲酯(PMMA)衬底上沉积了厚度为10 nm - 50 nm的非晶钴铁钆(Co40Fe40Gd20)薄膜,并在40℃和80℃下退火,研究了薄膜厚度、退火温度和衬底类型对结构、机械、电学、磁学和光学性能的影响。x射线衍射(XRD)证实,由于钆(Gd)含量高,且低于聚合物玻璃化转变温度的热能有限,薄膜在所有条件下都保持无定形。原子力显微镜(AFM)显示,PET薄膜在80°C退火后,表面粗糙度从5.91 nm下降到4.79 nm,而PMMA薄膜的粗糙度变化很小。表面能随薄膜厚度的增加而增加,但退火后由于原子重排而略有下降。随着厚度和退火的增加,力学性能得到改善。PET薄膜经80℃退火后在50 nm处的最大杨氏模量为22.58 GPa,硬度为4.75 GPa, PMMA薄膜经40℃退火后在50 nm处的最大模量为15.05 GPa。电测量表明,在80°C退火的50 nm薄膜中,薄膜电阻从7261 Ω/sq显著降低到144 Ω/sq,载流子迁移率和浓度增强。磁性分析证实了面内软磁行为,矫顽力(Hc)和饱和磁化强度(Ms)受应力松弛和形态诱导的各向异性影响较小。磁力显微镜(MFM)显示,适度退火促进了有序条纹畴的形成,而高温则导致了条纹畴的粗化。光学特性表明,透射率随厚度的增加而降低,在PET和PMMA上,在40℃退火时,透射率在10 nm处分别达到40.68%和47.15%,而吸光度则增加,表明厚度主导光学行为。这些发现表明,控制退火和厚度优化可以精确调整柔性衬底上CoFeGd非晶膜的表面粗糙度和多功能特性,支持其设计先进的柔性自旋电子,电子和光电子器件。
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引用次数: 0
Extraordinary strength-ductility synergy in a novel high-entropy alloy via coupling multiple strengthening mechanisms 一种新型高熵合金在多重强化机制耦合下的超强强度-延性协同效应
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-11-29 DOI: 10.1016/j.intermet.2025.109094
Mohammad Sajad Mehranpour , Mohammad Javad Sohrabi , Alireza Kalhor , Ali Heydarinia , Saeed Sadeghpour , Hamed Mirzadeh , Kinga Rodak , Krzysztof Radwański , Reza Mahmudi , Hyoung Seop Kim
The dilemma of achieving a strength-ductility synergy is a highly sought-after topic in the high-entropy alloys (HEAs) realm. Even HEAs capable of breaking the strength-ductility trade-off typically suffer from relatively low yield stresses. This challenge was addressed in the present work by introducing the Co47Cr20Fe12.5Ni12.5Mo5Ti3 HEA, which exhibits high solid-solution strengthening and high friction stress due to its high Mo and Ti contents leading to a yield stress of 527 MPa. In addition, excellent work-hardening behavior is achieved through the activation of twinning-induced plasticity (TWIP), enabled by an adjusted stacking-fault energy (SFE). The synergistic action of the TWIP effect and strong dislocation-based hardening (strain hardening) leads to an ultimate tensile strength of 1156 MPa and exceptional total elongation of 74 %. Overall, the proposed Co-rich HEA exhibits a desirable combination of strength and ductility compared to the most competitive HEAs reported in the literature.
在高熵合金(HEAs)领域,实现强度-延性协同的困境是一个备受追捧的话题。即使是能够打破强度-延性平衡的HEAs通常也会遭受相对较低的屈服应力。本研究通过引入Co47Cr20Fe12.5Ni12.5Mo5Ti3 HEA来解决这一挑战,该HEA由于其高Mo和Ti含量而具有高固溶强化和高摩擦应力,导致屈服应力达到527 MPa。此外,通过调整堆叠故障能(SFE),激活孪晶诱导塑性(TWIP),实现了优异的加工硬化行为。TWIP效应和强位错硬化(应变硬化)的协同作用使合金的极限抗拉强度达到1156 MPa,总伸长率达到74%。总的来说,与文献中报道的最具竞争力的HEAs相比,所提出的富钴HEA具有理想的强度和延展性组合。
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引用次数: 0
Enhanced Fenton-like catalytic performance of Fe-based metallic glass by nitrogen microalloying 氮微合金化增强铁基金属玻璃类fenton催化性能
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-11-26 DOI: 10.1016/j.intermet.2025.109099
Lansong Yang , Peixin Fu , Chen Yang, Shixin Tan, Shun-Xing Liang, Yuanzheng Yang
Metallic glasses (MGs) have attracted extensive attention in functional applications due to their long-range disordered atomic arrangement, making them as promising Fenton-like catalysts for wastewater treatment. However, due to the compositional limitations imposed by glass-forming ability, promoting catalytic degradation ability of MGs while retaining their disordered structure becomes challenging in alloy design. Inspired by the regulation function of electronic structure combined with atomic size-dependent structural disordering by nitrogen (N), herein, the microalloying of 0.2 at.% N in Fe78Si9B13 MG is reported to show a significantly improved catalytic efficiency and stability for the degradation of rhodamine B (RhB) dye. Mechanistic investigations suggest that N microalloying effectively regulates the electron transfer efficiency and suppresses the surface coverage of oxides on Fe78Si9B13 MG, thereby exposing abundant active sites (Fe0) for degradation reaction. In addition, the refinement of post-reaction surface products contributes to a strong diffusion and capture of reactants (e.g. H2O2 and dye molecules), facilitating the H2O2 activation and radical generation for enhanced degradation stability. This study provides a new perspective for material design in MG catalysts.
金属玻璃(MGs)由于其远距离无序原子排列,在功能应用方面受到了广泛的关注,成为废水处理中很有前途的类fenton催化剂。然而,由于玻璃形成能力的限制,在保持镁合金无序结构的同时提高其催化降解能力成为合金设计的挑战。受氮(N)对电子结构的调控作用和与原子尺寸相关的结构无序性的启发,本文提出了0.2 at的微合金化。fe78si9b13mg中的% N对罗丹明B (RhB)染料的降解效率和稳定性有显著提高。机制研究表明,N微合金化有效调节了fe78si9b13mg的电子传递效率,抑制了氧化物的表面覆盖,从而暴露出丰富的活性位点(Fe0)进行降解反应。此外,反应后表面产物的细化有助于反应物(如H2O2和染料分子)的强扩散和捕获,促进H2O2的活化和自由基的生成,从而增强降解稳定性。本研究为MG催化剂的材料设计提供了新的思路。
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引用次数: 0
Enhanced magnetostriction of polycrystalline Fe-Ga alloy by trace Pr doping 微量Pr掺杂增强多晶Fe-Ga合金的磁致伸缩性能
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-27 DOI: 10.1016/j.intermet.2025.109138
Haizheng Yu , Te Yao , Jiande Liu , Zhenghua He , Hongbo Hao , Shengyuan Wang , Xunye Zhang , Siqian Zhang , Yuhui Sha , Xiaofei Zhu , Lijia Chen
Excellent magnetostriction in Fe-Ga alloy depends on the grain orientation and the characteristics of nanoheterogeneity. In this paper, a synergistic regulation of the preferred <100>-oriented texture and nano-sized L60 phase was obtained in arc-melting of polycrystalline (Fe81Ga19)100-xPrx alloys. A saturation magnetostriction (3/2λs) of (Fe81Ga19)99.95Pr0.05 alloy is improved to 374 ppm, representing a 160 % enhancement as compared to Fe81Ga19 alloy, approaching the magnetostriction of single crystals by rapid single crystal growth and Fe-Ga-RE thin sheets by secondary recrystallization. The effect of Pr element on the magnetostriction of Fe81Ga19 alloy is analyzed at the millimeter scale (grain orientation), micrometer scale (precipitation), and nanometer scale (nanoheterogeneity). The significant enhancement of the magnetostriction in (Fe81Ga19)99.95Pr0.05 alloy is attributed to the larger lattice distortion in the A2 matrix due to the dispersedly distributed nano-sized L60 phases in the entire columnar matrix grains with η texture.
Fe-Ga合金优异的磁致伸缩性能取决于晶粒取向和纳米非均质性。本文研究了多晶(Fe81Ga19)100-xPrx合金电弧熔炼过程中优选的<;100>;取向织构与纳米级L60相的协同调节。(Fe81Ga19)99.95Pr0.05合金的饱和磁致伸缩(3/2λs)达到374 ppm,比Fe81Ga19合金提高了160%,接近单晶的磁致伸缩(单晶快速生长)和Fe-Ga-RE薄片的二次再结晶。在毫米尺度(晶粒取向)、微米尺度(析出)和纳米尺度(纳米非均质性)上分析了Pr元素对Fe81Ga19合金磁致伸缩的影响。(Fe81Ga19)99.95Pr0.05合金的磁致伸缩显著增强是由于在具有η织构的整个柱状基体晶粒中分散分布的纳米级L60相使A2基体中的晶格畸变增大。
{"title":"Enhanced magnetostriction of polycrystalline Fe-Ga alloy by trace Pr doping","authors":"Haizheng Yu ,&nbsp;Te Yao ,&nbsp;Jiande Liu ,&nbsp;Zhenghua He ,&nbsp;Hongbo Hao ,&nbsp;Shengyuan Wang ,&nbsp;Xunye Zhang ,&nbsp;Siqian Zhang ,&nbsp;Yuhui Sha ,&nbsp;Xiaofei Zhu ,&nbsp;Lijia Chen","doi":"10.1016/j.intermet.2025.109138","DOIUrl":"10.1016/j.intermet.2025.109138","url":null,"abstract":"<div><div>Excellent magnetostriction in Fe-Ga alloy depends on the grain orientation and the characteristics of nanoheterogeneity. In this paper, a synergistic regulation of the preferred &lt;100&gt;-oriented texture and nano-sized L6<sub>0</sub> phase was obtained in arc-melting of polycrystalline (Fe<sub>81</sub>Ga<sub>19</sub>)<sub>100-<em>x</em></sub>Pr<sub><em>x</em></sub> alloys. A saturation magnetostriction (3/2<em>λ</em><sub>s</sub>) of (Fe<sub>81</sub>Ga<sub>19</sub>)<sub>99.95</sub>Pr<sub>0.05</sub> alloy is improved to 374 ppm, representing a 160 % enhancement as compared to Fe<sub>81</sub>Ga<sub>19</sub> alloy, approaching the magnetostriction of single crystals by rapid single crystal growth and Fe-Ga-RE thin sheets by secondary recrystallization. The effect of Pr element on the magnetostriction of Fe<sub>81</sub>Ga<sub>19</sub> alloy is analyzed at the millimeter scale (grain orientation), micrometer scale (precipitation), and nanometer scale (nanoheterogeneity). The significant enhancement of the magnetostriction in (Fe<sub>81</sub>Ga<sub>19</sub>)<sub>99.95</sub>Pr<sub>0.05</sub> alloy is attributed to the larger lattice distortion in the A2 matrix due to the dispersedly distributed nano-sized L6<sub>0</sub> phases in the entire columnar matrix grains with η texture.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"189 ","pages":"Article 109138"},"PeriodicalIF":4.8,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145836811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Co on microstructure and properties of iron-rich AlCoxCrFe2.5Ni (x = 0, 0.2, 0.5, 1.0) high entropy alloys Co对富铁AlCoxCrFe2.5Ni (x = 0,0.2, 0.5, 1.0)高熵合金组织和性能的影响
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-02-01 Epub Date: 2025-12-18 DOI: 10.1016/j.intermet.2025.109132
Guojin Zhang , Hongqiao Feng , Guanghang Shi , Yinong Wang , Xi Chen
To develop cost-effective and thermally stable iron-rich AlCoCrFeNi system high entropy alloys, this study systematically investigated the microstructure, mechanical properties, and phase stability of AlCoxCrFe2.5Ni (x = 0, 0.2, 0.5, 1.0) high entropy alloys. For x = 0, 0.2, and 0.5, the alloy exhibits a dendritic morphology. In the dendrite region, the matrix is the A2 (disordered BCC) phase, and the B2 (ordered BCC) phase exists as particles. In the interdendritic region, the A2 and B2 phases are arranged in a weave-like pattern. Notably, increasing the Co content reduces the dendritic area, and the dendritic morphology disappears entirely at x = 1.0. After annealing at 600 °C, 800 °C, 1000 °C, and 1200 °C for 5 h, it was found that lowering the Co content enhances phase stability, suppresses FCC phase precipitation, and mitigates high temperature softening. CALPHAD phase diagram calculations further confirm that when the alloy is Co-poor, the A2/B2 structure can be retained over a wide temperature range. When x = 0, the alloy achieves a high yield strength (1205 MPa) and compressive ductility (>50 %) at room temperature, while retaining good strength below 600 °C. The B2 particles have a remarkable strengthening effect. As the Co content decreases, the area of the high-strength dendritic regions containing B2 particles expands, which is the primary mechanism for the alloy's strength retention.
为了开发具有成本效益和热稳定性的富铁AlCoCrFeNi体系高熵合金,本研究系统地研究了AlCoxCrFe2.5Ni (x = 0,0.2, 0.5, 1.0)高熵合金的显微组织、力学性能和相稳定性。当x = 0、0.2和0.5时,合金呈现枝晶形态。在枝晶区,基体为A2(无序BCC)相,B2(有序BCC)相以颗粒形式存在。在枝晶间,A2相和B2相呈织状排列。值得注意的是,随着Co含量的增加,枝晶面积减小,在x = 1.0时枝晶形态完全消失。在600℃、800℃、1000℃和1200℃退火5 h后,发现降低Co含量提高了相稳定性,抑制了FCC相的析出,减轻了高温软化。calphhad相图计算进一步证实,当合金贫钴时,在较宽的温度范围内可以保持A2/B2结构。当x = 0时,合金在室温下具有较高的屈服强度(1205 MPa)和抗压塑性(> 50%),在600℃以下仍保持良好的强度。B2粒子具有显著的强化作用。随着Co含量的降低,含有B2粒子的高强度枝晶区域面积扩大,这是合金强度保持的主要机制。
{"title":"Effect of Co on microstructure and properties of iron-rich AlCoxCrFe2.5Ni (x = 0, 0.2, 0.5, 1.0) high entropy alloys","authors":"Guojin Zhang ,&nbsp;Hongqiao Feng ,&nbsp;Guanghang Shi ,&nbsp;Yinong Wang ,&nbsp;Xi Chen","doi":"10.1016/j.intermet.2025.109132","DOIUrl":"10.1016/j.intermet.2025.109132","url":null,"abstract":"<div><div>To develop cost-effective and thermally stable iron-rich AlCoCrFeNi system high entropy alloys, this study systematically investigated the microstructure, mechanical properties, and phase stability of AlCo<sub>x</sub>CrFe<sub>2.5</sub>Ni (x = 0, 0.2, 0.5, 1.0) high entropy alloys. For x = 0, 0.2, and 0.5, the alloy exhibits a dendritic morphology. In the dendrite region, the matrix is the A2 (disordered BCC) phase, and the B2 (ordered BCC) phase exists as particles. In the interdendritic region, the A2 and B2 phases are arranged in a weave-like pattern. Notably, increasing the Co content reduces the dendritic area, and the dendritic morphology disappears entirely at x = 1.0. After annealing at 600 °C, 800 °C, 1000 °C, and 1200 °C for 5 h, it was found that lowering the Co content enhances phase stability, suppresses FCC phase precipitation, and mitigates high temperature softening. CALPHAD phase diagram calculations further confirm that when the alloy is Co-poor, the A2/B2 structure can be retained over a wide temperature range. When x = 0, the alloy achieves a high yield strength (1205 MPa) and compressive ductility (&gt;50 %) at room temperature, while retaining good strength below 600 °C. The B2 particles have a remarkable strengthening effect. As the Co content decreases, the area of the high-strength dendritic regions containing B2 particles expands, which is the primary mechanism for the alloy's strength retention.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"189 ","pages":"Article 109132"},"PeriodicalIF":4.8,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145786552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coupling relationship between microstructure and high-temperature oxidation mechanism in alloying element-guided eutectic high-entropy alloys 元素导向共晶高熵合金显微组织与高温氧化机理的耦合关系
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-01-01 Epub Date: 2025-10-30 DOI: 10.1016/j.intermet.2025.109055
Shan Wang , Yan Cui , Yangchuan Cai , Xiaohua Wang , Jinyao Mu , Yan Zhao
This study investigates the high-temperature oxidation behavior of three high-entropy alloys (HEAs) with distinct eutectic microstructures: hypoeutectic FeCoNi2.0Cr1.2Mo0.2Nb0.5 (Nb0.5), eutectic FeCoNi2.0Cr1.2Mo0.2Nb0.63 (Nb0.63), and hypereutectic FeCoNi2.0Cr1.2Mo0.2Nb0.9 (Nb0.9). All three HEAs exhibit a dual-phase microstructure comprising FCC and HCP phases. The oxidation behavior was evaluated after 100 h of isothermal exposure at 600 °C and 800 °C. The results demonstrate that the oxidation kinetics of all alloys follow a parabolic rate law, indicating diffusion-controlled mechanisms. Characterization via XRD, XPS, and SEM revealed that the oxide scale is predominantly Cr2O3, which preferentially nucleates at grain boundaries and subsequently covers the entire surface. Among these, the Nb0.63 EHEA exhibited the highest oxidation resistance, rapidly forming a continuous and dense Cr2O3 scale in the initial oxidation stage, which effectively impeded the outward diffusion of metal ions and the inward diffusion of oxygen. During oxidation at 800 °C, acicular Nb-rich precipitates formed within the FCC phase of all three alloys. These precipitates act as more effective barriers against oxygen ion diffusion than the parent phase, further enhancing the oxidation resistance. This work elucidates the synergistic mechanism between the eutectic microstructure and precipitation behavior on the oxidation resistance of HEAs, providing a theoretical and experimental basis for designing novel high-entropy alloys with superior high-temperature oxidation resistance.
本文研究了三种不同共晶组织的高熵合金(HEAs)的高温氧化行为:亚共晶FeCoNi2.0Cr1.2Mo0.2Nb0.5 (Nb0.5)、共晶FeCoNi2.0Cr1.2Mo0.2Nb0.63 (Nb0.63)和过共晶FeCoNi2.0Cr1.2Mo0.2Nb0.9 (Nb0.9)。三种HEAs均表现为FCC相和HCP相的双相结构。在600°C和800°C等温暴露100 h后评估氧化行为。结果表明,所有合金的氧化动力学都遵循抛物线速率规律,表明了扩散控制机制。XRD、XPS和SEM表征表明,氧化垢主要为Cr2O3,在晶界处优先成核,随后覆盖整个表面。其中,Nb0.63 EHEA的抗氧化性最高,在氧化初期迅速形成连续致密的Cr2O3垢,有效地阻碍了金属离子向外扩散和氧向内扩散。在800℃氧化过程中,三种合金的FCC相均形成针状富铌析出物。这些沉淀比母相更有效地阻止氧离子扩散,进一步增强了抗氧化性。本研究阐明了共晶组织和析出行为对HEAs抗氧化性能的协同作用机制,为设计新型高熵高温抗氧化合金提供了理论和实验依据。
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引用次数: 0
Tailoring Si/Mn ratio to optimize magnetocaloric performance of FeCoNi-based high-entropy alloys 调整Si/Mn比以优化fecni基高熵合金的磁热性能
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-01-01 Epub Date: 2025-10-14 DOI: 10.1016/j.intermet.2025.109024
Xiaojiang Zhai , Xiaodong Si , Yunshan Dong , Yongsheng Liu
This study systematically investigates the influence of the Si/Mn ratio on the magnetocaloric properties of FeCoNiSixMn0.4-x (x = 0.1, 0.2, and 0.3) high-entropy alloys (HEAs) using a multi-scale computational approach. By combining special quasi-random structure (SQS) modeling, first-principles density functional theory (DFT) calculations, and atomic-scale magnetic simulations, we elucidate the synergistic effects of compositional disorder on the electronic structure and magnetic ordering. Key results indicate that increasing the Si content reduces the cell volume via atomic size effects and decreases the total magnetic moment, while significantly raising the Curie temperature (599–673 K) due to enhanced ferromagnetic exchange coupling. Under an applied field of 5 T, an optimized magnetocaloric response is observed: at x = 0.3, the magnetic entropy change exhibits a full width at half maximum of 2.61 J/(kg·K) along with a high relative cooling power (RCP = 515 J/kg), while a peak temperature-averaged entropy change (TEC) of 3.17 J/(kg·K) is achieved at x = 0.2 over a temperature span of 10 K (ΔTH-C = 10 K). The maximum half-peak width of the magnetic entropy change (δTFWHM) for this alloy system ranges from 156.0 K to 196.1 K. This work reveals an underlying composition–electronic–magnetic correlation mechanism, suggesting promising potential for designing high-temperature solid-state refrigeration materials with broad operational windows.
本研究采用多尺度计算方法系统地研究了Si/Mn比对FeCoNiSixMn0.4-x (x = 0.1, 0.2和0.3)高熵合金(HEAs)磁热性能的影响。通过结合特殊准随机结构(SQS)模型、第一性原理密度泛函理论(DFT)计算和原子尺度的磁性模拟,我们阐明了组成无序对电子结构和磁性有序的协同效应。关键结果表明,硅含量的增加通过原子尺寸效应减小了电池体积,降低了总磁矩,同时由于铁磁交换耦合增强而显著提高了居里温度(599 ~ 673 K)。在5 T的磁场下,观察到一个优化的磁热响应:当x = 0.3时,磁熵变化的全宽度为2.61 J/(kg·K),并具有较高的相对冷却功率(RCP = 515 J/kg),而当x = 0.2时,温度平均熵变化(TEC)的峰值为3.17 J/(kg·K),温度跨度为10 K (ΔTH-C = 10 K)。该合金体系的磁熵变化δTFWHM的最大半峰宽度为156.0 ~ 196.1 K。这项工作揭示了一种潜在的成分-电子-磁性相关机制,表明设计具有宽操作窗口的高温固态制冷材料具有很大的潜力。
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引用次数: 0
Texture control in new biomedical Nb30Ti30Zr30Cr5Mo5 medium entropy alloy through high temperature uniaxial compression for Young's modulus reduction 通过高温单轴压缩降低杨氏模量来控制新型生物医用Nb30Ti30Zr30Cr5Mo5中熵合金的织构
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-01-01 Epub Date: 2025-11-03 DOI: 10.1016/j.intermet.2025.109062
Pramote Thirathipviwat , Ryota Muraki , Wakaba Onuki , Daichi Minami , Jithin Vishnu , Ansheed Raheem , Kesavan Praveenkumar , Geetha Manivasagam , Equo Kobayashi , Makoto Hasegawa
In this study, we investigate the potential of texture control for preferred {001} orientation to reduce the Young's modulus in the new biomedical body-centered cubic (BCC) Nb30Ti30Zr30Cr5Mo5 MEA. The fabrication of {001} oriented grains on a compression plane is controlled by so-called preferential dynamic grain growth under high temperature uniaxial compression. The uniaxial compression is carried out at temperature between 1073 and 1473 K by a true strain rate between 1 × 10−4 – 1 × 10−2 s−1 until −1.0 in true strain. The microstructures after the compression at 1473 K are significantly developed by dynamic recrystallization. A decrease in true strain rate promotes a formation of {001} oriented grains due to enhanced preferential dynamic grain growth. The highest volume fraction of {001} texture (∼64 %) is observed after the compression at 1473 K under the strain rate of 5.0 × 10−4 s−1. An increase in volume fraction of {001} texture decrease the Young's modulus. The Young's modulus in this study can reduce as low as 68 GPa, compared with ∼93 GPa in the initial sample prior to high-temperature deformation.
在这项研究中,我们研究了优选{001}取向的织构控制在降低新型生物医学体心立方(BCC) Nb30Ti30Zr30Cr5Mo5 MEA中的杨氏模量的潜力。在高温单轴压缩下,在压缩平面上制备{001}取向晶粒是由所谓的优先动态晶粒生长控制的。在1073 ~ 1473 K的温度下,以1 × 10−4 ~ 1 × 10−2 s−1至−1.0的真应变速率进行单轴压缩。1473 K压缩后的显微组织以动态再结晶为主。真实应变速率的降低促进了{001}取向晶粒的形成,这是由于晶粒优先动态生长的增强。在1473 K、应变速率为5.0 × 10−4 s−1的压缩条件下,观察到{001}织构的最大体积分数(~ 64%)。{001}织构体积分数的增加降低了杨氏模量。与高温变形前初始样品的~ 93 GPa相比,本研究中的杨氏模量可降低至68 GPa。
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引用次数: 0
Microstructure and room- and high-temperature mechanical properties of a bimodal-structured as-extruded Al–La–Mg–Fe alloy with high Fe content 高铁含量Al-La-Mg-Fe挤压双模组织合金的显微组织和室温及高温力学性能
IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2026-01-01 Epub Date: 2025-11-04 DOI: 10.1016/j.intermet.2025.109066
Tao Ban , Zhi Wang , Liejun Li , Zhuoran Li , Jixiang Gao , Zhiwei Zou , Zhenyuan Hou , Yongji Chen , Xinkui Zhang , Zhengwu Peng
In this study, a bimodal-grained as-extruded Al–11.53La–3.41Mg–3.25Fe (wt.%) alloy was developed based on a near-eutectic Al–La system by incorporating a high Fe content and Mg solid solution. The as-extruded alloy exhibited good strength–toughness balance due to the synergistic effects of multiple strengthening mechanisms, including solid solution strengthening from Mg, Orowan strengthening induced by submicron- and micron-sized Al11La3 and Al13Fe4 phases, and high hetero-deformation-induced (HDI) strengthening arising from HDI stress at the interfaces between the matrix and intermetallics as well as between coarse and fine grains. In addition, a layered intermetallic compound was observed, consisting of an Al13(Fe, La)4 shell and an Al13Fe4 core, which is primarily attributed to the preferential solidification of the Al13Fe4 phase and the subsequent enrichment of La atoms. The layered intermetallic compound exhibited excellent coarsening resistance even at 500 °C, and in conjunction with the proven thermally stable strengthening phases (Al11La3 and Al13Fe4), it endowed the alloy with outstanding high-temperature mechanical properties, achieving a tensile strength of 155 ± 7 MPa and an elongation of 20.8 ± 3.4 % at 300 °C.
本研究在近共晶Al-La体系的基础上,结合高铁含量和Mg固溶体,制备了双晶挤压Al-11.53La-3.41Mg-3.25Fe (wt.%)合金。挤压态合金由于多种强化机制的协同作用,表现出良好的强度-韧性平衡,包括Mg的固溶强化、亚微米和微米尺寸的Al11La3和Al13Fe4相的Orowan强化以及基体与金属间化合物界面以及粗晶粒与细晶粒之间的HDI应力引起的高异质变形诱导(HDI)强化。此外,还观察到由Al13(Fe, La)4壳层和Al13Fe4核层组成的层状金属间化合物,这主要是由于Al13Fe4相优先凝固和随后的La原子富集所致。层状金属间化合物即使在500℃下也表现出优异的抗粗化性能,并与热稳定强化相(Al11La3和Al13Fe4)结合,使合金具有优异的高温力学性能,在300℃时抗拉强度为155±7 MPa,伸长率为20.8±3.4%。
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Intermetallics
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