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Use of process simulation to obtain life cycle inventory data for LCA: A systematic review 利用工艺模拟获取生命周期清单数据用于生命周期评估:系统综述
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-24 DOI: 10.1016/j.cesys.2024.100215
Jannatul Ferdous , Farid Bensebaa , Kasun Hewage , Pankaj Bhowmik , Nathan Pelletier

Life Cycle Inventory (LCI) analysis is an essential and time-consuming phase of life cycle assessment (LCA). While primary data is among the most reliable and desirable data source types, it is often challenging to collect for industry-specific processes due to confidentiality concerns, in particular with respect to unique proprietary processes. In such cases, computer-based process simulation software can be used to fill gaps in inventory data based on mass and energy balances. While building process simulation models, engagement with industry is essential for verification of process models and validation of simulated data. Although process simulation-based life cycle inventory modelling is not a new research area, there has been no systematic review on this topic with respect to common methodological choices. To fill this gap, this systematic review aims to identify common practices in simulating LCI data using process simulation. Studies that used process simulation for LCI modelling were reviewed to identify the reasons for using process simulation, approaches for simulating LCI, software employed, validation processes, and processes to calculate and report uncertainty. Based on the review findings, a methodological framework was proposed to explain how process simulation-based LCI can be integrated with conventional LCA, specifically for industrial processes.

生命周期清单(LCI)分析是生命周期评估(LCA)的一个重要且耗时的阶段。虽然原始数据是最可靠、最理想的数据源类型之一,但由于保密问题,特别是对于独特的专有工艺,收集特定行业工艺的原始数据往往具有挑战性。在这种情况下,可以使用基于计算机的工艺模拟软件,根据质量和能量平衡来填补清单数据的空白。在建立工艺模拟模型时,与行业的合作对于验证工艺模型和确认模拟数据至关重要。虽然基于过程模拟的生命周期清单建模并不是一个新的研究领域,但在常见方法选择方面还没有系统性的综述。为了填补这一空白,本系统性综述旨在确定使用过程仿真模拟 LCI 数据的常见做法。对使用过程模拟进行 LCI 建模的研究进行了回顾,以确定使用过程模拟的原因、模拟 LCI 的方法、使用的软件、验证过程以及计算和报告不确定性的过程。根据审查结果,提出了一个方法框架,以解释如何将基于过程模拟的 LCI 与传统的生命周期评估相结合,特别是针对工业过程。
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引用次数: 0
Looking for the ecological transition of Mediterranean small ruminant sector. Characterization and main drivers of environmental performance of the Sardinian sheep farming systems 寻找地中海小反刍行业的生态转型。撒丁岛养羊系统环境绩效的特征和主要驱动因素
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-24 DOI: 10.1016/j.cesys.2024.100214
Enrico Vagnoni , Pasquale Arca , Mauro Decandia , Giovanni Molle , Gabriella Serra , Paola Sau , Mondina Francesca Lunesu , Claudio Porqueddu , Delia Cossu , Alberto Stanislao Atzori , Antonello Franca , Pierpaolo Duce

A Life Cycle Assessment (LCA) study was carried out to assess the environmental profile of the main Sardinian dairy sheep farming systems, with the scope to provide a detailed and robust baseline for the identification of effective mitigation solutions at farm level and to develop environmental strategies at regional scale. Both product- and area-based functional units (FUs) were adopted, considering sixteen impact categories and soil carbon sequestration estimates as well. Water Use, Climate Change, Land Use, Ecotoxicity Freshwater, Marine Eutrophication and Fossils Resource Use resulted the main impact categories, cumulatively contributing over 80% of the total environmental impact (single score). Environmental performances significantly varied according to the geo-pedological traits of the different sheep milk production areas and were driven by the farming systems’ structure and production level. The group of farms located in less fertile areas showed significantly worse environmental performance per kg of normalized milk for the impact categories Climate Change and Land Use, whereas no significant differences were observed for the remaining main impact categories. Considering the area-based FU, this farm group resulted less impacting for all main categories compared to the group of farms located in more plain and productive soils, with a significantly lower impact observed for Marine Eutrophication and Fossils Resource Use. Regardless of the FU used, feed supply management represented a key area of improvement, and soil carbon sequestration impact compensated the high GHG emission intensity of grassland-based farms despite the limited nutritional value of natural pasture. Regional strategies should be based on ecosystem services optimization and eco-innovative solutions tailored according to both the specific geo-pedological conditions and the production level of each farming system.

为评估撒丁岛主要奶羊养殖系统的环境状况,我们开展了一项生命周期评估(LCA)研究,目的是为确定农场层面的有效缓解方案和制定区域范围的环境战略提供详细而可靠的基准。研究采用了基于产品和面积的功能单位(FUs),并考虑了 16 个影响类别和土壤固碳估算。水利用、气候变化、土地利用、淡水生态毒性、海洋富营养化和化石资源利用是主要的影响类别,累计占总环境影响的 80% 以上(单项评分)。根据不同绵羊奶产区的地理植被特征,环境绩效存在明显差异,并受养殖系统结构和生产水平的影响。在气候变化和土地利用这两个影响类别中,位于较贫瘠地区的牧场组每公斤标准化牛奶的环境绩效明显较差,而在其余主要影响类别中则无明显差异。考虑到基于地区的 FU,与位于较平原和高产土壤的牧场组相比,该牧场组对所有主要类别的影响较小,海洋富营养化和化石资源利用的影响明显较小。尽管天然牧草的营养价值有限,但无论使用哪种饲料加工方法,饲料供应管理都是一个需要改进的关键领域,土壤固碳的影响弥补了草地农场温室气体排放强度高的问题。区域战略应以生态系统服务优化和生态创新解决方案为基础,根据具体的地理-植物条件和每个农业系统的生产水平量身定制。
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引用次数: 0
Quantifying energy footprint inequalities across different socio-economic segments in Spain 量化西班牙不同社会经济阶层的能源足迹不平等现象。
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-20 DOI: 10.1016/j.cesys.2024.100213
Ortzi Akizu-Gardoki , Estitxu Villamor , Erlantz Lizundia

To achieve the ambitious climate targets set for 2050, it is essential to understand the energy footprints resulting from different lifestyles. This research aims to analyse the variation in direct and embedded energy consumption across different Spanish autonomous communities and socio-economic segments. To do so, we combine the Global Multi-Regional Input-Output methodology (GMRIO) with microdata from Household Budget Surveys (HBS). The findings show that income, household size, and nationality significantly affect the energy footprint of individuals. High-income households have an energy footprint of up to 63.3 MWh·cap−1·yr−1, 75.0% higher than national average. Furthermore, individuals living alone show a 41.4% larger consumption than the national average. In contrast, households with foreign nationalities show an energy footprint of 24.7 MWh·cap−1·yr−1, a 31.8% reduction over national average. On the other hand, differences in gender, age, or municipality size do not play a significant role in energy footprint variations. The energy footprint and the Gross Domestic Product are significantly correlated, as wealthier regions have a TPEF of 17.6% above the national average, while poorer regions show a 31.6% decrease in footprint. Altogether, this work suggests ways to reduce energy consumption in lifestyles, providing specific actions in policy-making.

为实现 2050 年宏伟的气候目标,了解不同生活方式所产生的能源足迹至关重要。本研究旨在分析西班牙不同自治区和社会经济阶层在直接能源消耗和内含能源消耗方面的差异。为此,我们将全球多地区投入产出法(GMRIO)与家庭预算调查(HBS)的微观数据相结合。研究结果表明,收入、家庭规模和国籍对个人的能源足迹有重大影响。高收入家庭的能源足迹高达 63.3 MWh-cap-1-yr-1,比全国平均水平高出 75.0%。此外,独居家庭的能源消耗比全国平均水平高出 41.4%。相比之下,外国籍家庭的能源足迹为 24.7 兆瓦时-cap-1-年-1,比全国平均水平减少了 31.8%。另一方面,性别、年龄或城市规模的差异在能源足迹变化中的作用并不明显。能源足迹与国内生产总值有显著相关性,较富裕地区的 TPEF 比全国平均水平高出 17.6%,而较贫困地区的足迹则减少了 31.6%。总之,这项研究提出了减少生活方式中能源消耗的方法,为政策制定提供了具体行动。
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引用次数: 0
Development of a machine learning model to improve estimates of material stock and embodied emissions of roads 开发机器学习模型,改进对道路材料库存和内含排放的估算
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-14 DOI: 10.1016/j.cesys.2024.100211
Qiyu Liu , Johan Rootzén , Filip Johnsson

Material flow analysis is an important tool for estimating material flows and embedded emissions of transport infrastructure. Missing attributes tend to be a major barrier to accurate estimates. In this study a machine learning model is developed to estimate the missing data in a statistics dataset of roads, to enable a bottom-up material stock and flow analysis. The proposed approach was applied to the Swedish road network to predict missing data for road width in the statistical dataset. The predicted hybrid dataset was then used to estimate material stocks, flows, and embodied emissions from Year 2020 to Year 2045 using decarbonization scenarios with a supply chain perspective. The study demonstrates that machine learning models can be used to enable national-level material stock and flow analyses of roads. Multiple machine learning algorithms were tested, and the best performing model achieved an R2 value of 0.784. In the scenario-based analysis, the embodied emissions of Swedish roads could be reduced by up to 51% using available materials.

物质流分析是估算运输基础设施物质流和内含排放的重要工具。缺失属性往往是准确估算的主要障碍。本研究开发了一种机器学习模型,用于估算道路统计数据集中的缺失数据,以实现自下而上的材料存量和流量分析。所提出的方法被应用于瑞典道路网络,以预测统计数据集中道路宽度的缺失数据。然后,利用预测的混合数据集,从供应链的角度,采用去碳化情景,估算 2020 年至 2045 年的材料库存、流量和体现排放。该研究表明,机器学习模型可用于进行国家级道路材料存量和流量分析。对多种机器学习算法进行了测试,性能最好的模型达到了 0.784 的 R2 值。在基于情景的分析中,利用现有材料,瑞典道路的内含排放量最多可减少 51%。
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引用次数: 0
How digital platforms can be leveraged to enable closed material loops – An example of the steel supply chain 如何利用数字平台实现材料闭合循环--以钢铁供应链为例
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-14 DOI: 10.1016/j.cesys.2024.100212
Lukas Budde, Leonardo Laglia, Thomas Friedli

Increasing demands for limited natural resources accelerate rethinking their usage and processing. A focal point of interest lies in the steel industry, given its substantial contribution to emissions and the notable attribute of steel being fully recyclable. Hence, closing material loops to ensure the preservation of material value and supply security is of substantial importance. Yet, until today, supply chains are still characterized by interrupted information streams that prevent circular material flows. Digital platforms are attributed to overcoming these shortcomings due to their ability to moderate ecosystems and render technological connectivity. However, industrial companies lack knowledge of how digital platforms can be used to design closed material loops. Therefore, this paper is built on a longitudinal case study of a joint venture between a recycling and steel melting plant company aiming at creating a digital platform to close the material flow of steel. Six design priorities, structured along the three core building blocks of digital platform ecosystems and the four core dimensions of collective action theory (CAT), have been derived to guide managers in designing digital platforms for the CE-specific context. This study presently contributes to understanding the relationship between digital platforms and CE.

对有限自然资源的需求日益增长,加速了对其使用和加工的重新思考。钢铁行业是人们关注的焦点,因为该行业的排放量很大,而且钢铁具有完全可回收的显著特点。因此,闭合材料循环以确保材料价值的保存和供应安全至关重要。然而,直到今天,供应链的特点仍然是信息流中断,阻碍了材料的循环流动。数字平台因其缓和生态系统和提供技术连接的能力而被认为可以克服这些缺陷。然而,工业企业对如何利用数字平台设计闭合的材料循环缺乏了解。因此,本文以一个纵向案例研究为基础,研究了一家回收公司与钢铁熔炼厂之间的合资企业,该企业旨在创建一个数字平台,以实现钢铁材料的闭合循环。根据数字平台生态系统的三个核心构件和集体行动理论(CAT)的四个核心维度,得出了六个设计重点,以指导管理者在特定的消费电子背景下设计数字平台。目前,这项研究有助于理解数字平台与行政首长协调会之间的关系。
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引用次数: 0
Towards sustainable automobile ecosystem in India: Integrated analysis of technical, economic, and ESG dimensions 实现印度汽车生态系统的可持续发展:技术、经济和环境、社会和治理方面的综合分析
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-09 DOI: 10.1016/j.cesys.2024.100210
Prasanna G. Tillu , Abhijeet K. Digalwar , Sudhanshu Ranjan Singh , Ravi S. Reosekar

Global environmental concerns are leading to paradigm shift in the automobile eco-system. This comprehensive study of the automobile ecosystem, incorporates technical, economic, and environmental-social-governance (ESG) dimensions. An “integrated multi-criteria decision-making” (MCDM) methodology using “interpretive structural modelling” (ISM) and “fuzzy analytical hierarchy process” (FAHP) is deployed, The ISM models highlights prominent drivers and critical barriers, establishes their hierarchy, and depicts interrelationships. The FAHP rankings for drivers favours electric vehicles and hydrogen fuel vehicles over others, while barriers promote hybrids and alternate fuels like Biofuel, CNG/LNG. Unlike previous works, this study considers all eco-system factors, both critical drivers and barriers, and demonstrates hierarchy using a unique V-model. This is an innovative extension of V-model from traditional systems engineering to strategic project management domain. This holistic approach, in sync with the natural state of things, will enable government, industry, and academia in formulating a strategic framework towards future automobile sustainability.

全球对环境的关注正在导致汽车生态系统的模式转变。这项对汽车生态系统的综合研究包含了技术、经济和环境-社会治理(ESG)等方面。采用 "解释性结构建模"(ISM)和 "模糊分析层次过程"(FAHP)的 "综合多标准决策"(MCDM)方法。根据 FAHP 对驱动因素的排序,电动汽车和氢燃料汽车更受青睐,而障碍因素则促进了混合动力汽车和生物燃料、压缩天然气/液化天然气等替代燃料的发展。与以往的研究不同,本研究考虑了所有生态系统因素,包括关键驱动因素和障碍因素,并使用独特的 V 模型展示了层次结构。这是 V 模型从传统系统工程向战略项目管理领域的创新扩展。这种与自然状态同步的整体方法,将有助于政府、行业和学术界为未来汽车的可持续发展制定战略框架。
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引用次数: 0
Clustering olive oil mills through a spatial and economic GIS-based approach 通过基于空间和经济地理信息系统的方法对橄榄油厂进行分组
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-06 DOI: 10.1016/j.cesys.2024.100207
Giuseppe Modica , Angelo Pulvirenti , Daniela Spina , Salvatore Bracco , Mario D'Amico , Giuseppe Di Vita

Sicily ranks as the third-largest region in Italy for olive growing and olive oil production, holding the second position nationally regarding the number of active olive oil mills. This pioneering study integrates spatial and economic analyses to examine the geographical distribution of olive oil mills in Sicily and their relationship with the localization of olive groves. Using Local Indicators of Spatial Association (LISA), we conducted an advanced analysis of spatial patterns of olive oil mills, considering travel time on the road network. The adopted methodology addresses issues related to overestimation based on straight-line assumptions and the neglect of travel speed. Unlike traditional Euclidean distance approaches, our methodology provides a detailed understanding of the spatial relationships between olive oil mills and olive groves, revealing distinct patterns linked to elevation and proximity to olive groves. By linking profitability indicators with spatial clusters, we identify different thresholds of economic sustainability. Consequently, these findings contribute to a more comprehensive understanding of the olive oil industry, suggesting more environmentally sustainable practices. Policymakers, researchers, and industry stakeholders can leverage this knowledge to make informed decisions that foster the long-term sustainability of the olive oil sector.

西西里是意大利第三大橄榄种植和橄榄油生产地区,在全国范围内,活跃的橄榄油工厂数量位居第二。这项开创性的研究将空间分析和经济分析相结合,考察了西西里岛橄榄油工厂的地理分布及其与橄榄园本地化的关系。我们使用地方空间关联指标(LISA)对橄榄油厂的空间模式进行了高级分析,同时考虑到了公路网络上的旅行时间。所采用的方法解决了基于直线假设的高估和忽视旅行速度的问题。与传统的欧几里得距离方法不同,我们的方法可以详细了解橄榄油厂和橄榄园之间的空间关系,揭示与海拔高度和橄榄园距离有关的独特模式。通过将盈利指标与空间集群联系起来,我们确定了经济可持续性的不同阈值。因此,这些发现有助于人们更全面地了解橄榄油产业,并提出了更具环境可持续性的做法。政策制定者、研究人员和行业利益相关者可以利用这些知识做出明智的决策,促进橄榄油行业的长期可持续发展。
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引用次数: 0
Techno-economic and environmental assessment of dietary fibre extraction from soybean hulls 从大豆壳中提取膳食纤维的技术经济和环境评估
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-03 DOI: 10.1016/j.cesys.2024.100208
Ricardo Rebolledo-Leiva, Maria Teresa Moreira, Sara González-García

This research evaluates the economic and environmental feasibility of extracting dietary fibre (DF) from a by-product such as soybean hulls. Techno-economic (TEA) and life cycle assessment (LCA) were carried out to identify the critical factors that may limit the implementation of a potential biorefinery plant. The modelling of the process was carried out on the basis of mass and energy balances, as well as the characteristics of the required equipment. TEA indicators such as minimum selling price (MSP), fixed capital investment, manufacturing costs were evaluated. A cradle-to-gate LCA approach and a functional unit (FU) of 1 kg of product (85% DF content) were considered. Impact categories such as global warming (GW), eutrophication, eco-toxicity, among others, were analysed. The results indicate that the production capacity achieves the plateau at about 56 kt y−1, with an MSP value of 2.6 $·kg−1. Furthermore, the GW profile was 8.76 kg CO2eq per FU, and the main hotspot is the alkaline digestion stage due to the use of potassium hydroxide (KOH). Nevertheless, the management of the hulls from multi-product food plants and switching KOH production to renewable sources may reduce the profile in almost all categories analysed.

本研究评估了从大豆壳等副产品中提取膳食纤维 (DF) 的经济和环境可行性。研究人员进行了技术经济评估(TEA)和生命周期评估(LCA),以确定可能限制潜在生物精炼厂实施的关键因素。在质量和能量平衡以及所需设备特性的基础上建立了工艺模型。对最低销售价格 (MSP)、固定资本投资、制造成本等 TEA 指标进行了评估。考虑了从摇篮到终点的生命周期评估方法和 1 公斤产品(85% DF 含量)的功能单位 (FU)。对全球变暖(GW)、富营养化、生态毒性等影响类别进行了分析。结果表明,生产能力在约 56 kt y-1 时达到高点,MSP 值为 2.6 美元-kg-1。此外,全球升温潜能值为每燃料单位 8.76 千克二氧化碳当量,主要热点是使用氢氧化钾(KOH)的碱性消化阶段。不过,对多产品食品厂的谷壳进行管理,并将氢氧化钾的生产转为可再生来源,可减少几乎所有分析类别的全球升温潜能值。
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引用次数: 0
Life cycle assessment of active spring frost protection methods in viticulture: A framework to compare different technologies 葡萄栽培中春季主动防冻方法的生命周期评估:比较不同技术的框架
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-03 DOI: 10.1016/j.cesys.2024.100209
Vincent Baillet, Ronan Symoneaux, Christel Renaud-Gentié

In viticulture, the risk of spring frost is mainly due to earlier budbreak, increasing the vulnerability of buds and green organs to freezing temperatures. Active Spring Frost Protection Methods (ASFPMs) aim to mitigate this risk by increasing the temperature in the bud area. ASFPMs are often seen as highly labour-intensive and resource consuming practices. ASFPM technologies are diverse and influenced by different external drivers, affecting differently their application strategies and the required equipment for efficiency. This study proposes a framework for analysing and comparing ASFPMs’ potential environmental impacts using Life Cycle Assessment (LCA) methodology. We illustrate this proposal with an example: Winter cover, wind machine, sprinkler and anti-frost candles comparison in Loire Valley conditions. We modeled the attributional LCAs with Impact world + characterisation method using Abribalyse 3.1 and Ecoinvent 3.8 databases. Application and climatic scenarios were elaborated to set conditions of ASFPMs use. The overall combination of attributional LCAs and external scenarios designs a context-specific LCA. Required time of application for each ASFPM to protect 1 ha during frost hours was determined using linear regression of ASFPM application time in function of total seasonal frost hours based on a recent decade (2013–2023). Sensitivity analysis consisted in varying frost hours theoretically with a step of 1 unit, using the lowest and highest frost hour numbers from 2013 to 2023 as boundaries. Overall, the ranking between ASFPM environmental scores changes based on the theoretical frost duration. The implementation of context-specific elements allowed for the development of system boundaries in attributional LCA, enabling the analysis and comparison of different types of technologies. The framework of this study showed its relevance in the context of ASFPM technologies through a concrete example in Loire Valley viticulture. Future research may consider other contextual elements and ASFPM technologies. This framework could be used in different fields of study to analyse and compare contrasted technologies in terms of environmental impacts.

在葡萄栽培中,春季霜冻的风险主要是由于萌芽较早,增加了芽和绿色器官对低温的脆弱性。积极的春季防霜冻方法(ASFPM)旨在通过提高花蕾区的温度来降低这一风险。主动防春寒措施通常被视为高度劳动密集型和资源消耗型措施。ASFPM 技术多种多样,受到不同外部驱动因素的影响,对其应用策略和所需设备的效率产生不同的影响。本研究提出了一个使用生命周期评估(LCA)方法分析和比较 ASFPM 潜在环境影响的框架。我们举例说明这一建议:在卢瓦尔河谷条件下的冬季覆盖、风力机器、洒水器和防冻蜡烛比较。我们利用 Abribalyse 3.1 和 Ecoinvent 3.8 数据库,采用 "影响世界+特征描述 "方法建立了归因式生命周期评估模型。为了设定 ASFPM 的使用条件,我们详细制定了应用和气候情景。归因式生命周期评估和外部情景的总体组合设计了针对具体情况的生命周期评估。使用基于最近十年(2013-2023 年)的季节性霜冻总时长函数的 ASFPM 施用时间线性回归,确定了在霜冻期间保护 1 公顷土地所需的每种 ASFPM 施用时间。敏感性分析包括以 2013 年至 2023 年最低和最高霜冻小时数为界限,以 1 个单位的步长改变理论上的霜冻小时数。总体而言,ASFPM 环境得分之间的排名会根据理论上的霜冻持续时间发生变化。特定环境要素的实施允许在归因式生命周期评估中开发系统边界,从而能够对不同类型的技术进行分析和比较。本研究的框架通过卢瓦尔河谷葡萄栽培的一个具体实例,显示了其在 ASFPM 技术方面的相关性。未来的研究可以考虑其他背景因素和 ASFPM 技术。该框架可用于不同的研究领域,以分析和比较不同技术对环境的影响。
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引用次数: 0
Environmental assessment of cement production with added graphene 添加石墨烯的水泥生产环境评估
IF 6.1 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-28 DOI: 10.1016/j.cesys.2024.100206
Raphael Ricardo Zepon Tarpani , Akilu Yunusa-Kaltungo , Meini Su , Patrick Manu , Clara Man Cheung , Michael Watson , Paul Ladislaus , Alejandro Gallego-Schmid

Cement production significantly contributes to climate change, necessitating alternatives to mitigate the environmental impacts of this essential construction material. This study evaluates 18 environmental impacts of producing Ordinary Portland Cement (OPC) and Graphene (Gr) using life cycle assessment (LCA). Additionally, we explore whether mixing OPC and Gr can lower the life cycle environmental impacts of the final product (OPCGr). Our results show that OPC production in the United Kingdom generates 775 kg CO2 eq./t, 57% only from geogenic CO2 emissions. Gr production via electrochemical exfoliation in Australia results in 121,000–143,000 kg CO2 eq./t, primarily due to electricity generation. Using hydro and nuclear power (e.g., in Brazil and France) can sharply reduce these impacts (global warming potential in the range of 11,000–35,000 kg CO2 eq./t). Adding 0.02 wt% of Gr in powder form (Grpowder) from Australia to the OPC and assuming a 16.5% reduction in its usage due to increased strength, results in 674 kg CO2 eq./t OPCGr (a 13% reduction). However, some impact categories like marine eutrophication and freshwater ecotoxicity potentials increase sharply (>28%). Using Grpowder from Brazil and France further reduces the OPCGr global warming potential and the overall environmental footprint.

水泥生产极大地加剧了气候变化,因此有必要采用替代品来减轻这种重要建筑材料对环境的影响。本研究利用生命周期评估(LCA)评估了生产普通硅酸盐水泥(OPC)和石墨烯(Gr)对环境的 18 种影响。此外,我们还探讨了混合 OPC 和 Gr 能否降低最终产品(OPCGr)的生命周期环境影响。我们的研究结果表明,英国的 OPC 生产会产生 775 千克二氧化碳当量/吨,其中 57% 来自地源二氧化碳排放。在澳大利亚,通过电化学剥离法生产 Gr 会产生 121,000-143,000 kg CO2 eq./t,主要来自发电。使用水力和核能(例如在巴西和法国)可大幅减少这些影响(全球升温潜能值在 11,000-35,000 千克二氧化碳当量/吨之间)。在 OPC 中添加 0.02 wt% 的澳大利亚粉末状 Gr(Grpowder),并假设其使用量因强度增加而减少 16.5%,则 OPCGr 的二氧化碳当量为 674 千克/吨(减少 13%)。然而,某些影响类别,如海洋富营养化和淡水生态毒性潜力则急剧增加(28%)。使用来自巴西和法国的 Grpowder 进一步降低了 OPCGr 的全球升温潜能值和整体环境足迹。
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Cleaner Environmental Systems
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